D.B.

ASSOCIATES
SUBJECT : CHEMISTRY Class : XII Date : / /2022

01) Cr, Ru, Co, Mn, Fe. How many cannot form hydrides 08) Aqua - regia is a mixture of
(1) 2 (2) 3 (1) Equal volumes of conc. NHO3 and conc. HCl
(3) 4 (4) 5 (2) 3 volumes of conc. HNO3 and 1 volume of conc.
02) Which atomic orbitals are involved int eh hybridisation HCl
that leads to the formation of a square planar complex (3) Equal volumes of conc. HNO3 and conc. H2SO4
(1) s, px, py, dz2 (2) s, px, py, dx2–y2 (4) 3 volumes of conc. HCl and 1 volume of conc.
(3) s, px, py,dyz (4) s, px, pz, dxy HNO3
03) In P4O10 molecule each phosphorous is surrounded 09) Among the following correct statement is
by......Oxygen atoms.
(1) Oxidation state of nitrogen in NCl3 is +3
(1) 3 (2) 4
(3) 5 (4) 6 (2) Shape of PCl5 molecule is pyramidal
04) List - I (Oxy acid) List - II (anhydride) (3) NH3 is used in the manufacture of HNO3 by
A) HNO2 1) P4O6 Ostwald process
B) H3PO3 2) N2O4 (4) Covalency of nitrogen in N2O5 is five
C) HNO3 3) P4O10 10) Which of the following is wrong regarding nitrogen ?
D) HNO2 + HNO3 4) N2O3
(a) The extent of nitrogen present in air is 78%.
5) N2O5
The correct match is (b) Nitrogen atoms in nitrogen molecules linked with
A B C D double bond.
(1) 4 1 5 2 (c) The bond dissociation enthylpy of nitrogen is
(2) 4 1 5 3 945.4 KJ per mole
(3) 4 3 5 2 (d) Chile salt petre is the mineral of nitrogen.
(4) 4 1 3 2 (1) Only a and b (2) Only c
05) PCl3 + H2O  X + HCl, Here ‘X’ is oxoacid of
phosphorus. Its basicity is (3) Only b (4) Only c and d

(1) 4 (2) 3 11) Statement - A : H3PO2 has more reducing behaviour

than H3PO3
(3) 2 (4) 1
Statement - B : H3PO2 has two P-H bonds where
06) In P4 molecule, the bond angle and the covalency of as H3PO3 has one P - H bond
phosphorous are
(1) Both A and B is true
(1) 1090281 and 3 (2) 600 and 3
(2) Both A and B are false
(3) 1200 and 4 (4) 600 and 6
(3) A is true and B is false
07) Correct statement of the following
(4) A is false and B is true
(1) Basic nature of hydrides increases from NH3 to
BiH3. 12) When AgCl is dissolved in ammonia solution then
the cation formed is
(2) Stability of hydrides increases from NH3 to NiH3.
(3) Reducing ability decreases from NH3 to BiH3. (1) Ag+ (2) NH 4

(4) Bond angle decreases from NH3 to BiH3. (3) [Ag(NH3)]+ (4) [Ag(NH3)2]+
13) Which is not correct regarding ozone ? 20) Boiling points of PH3, AsH3 and SbH3 are 185.5K,
(1) ix oxidises PbS to PbSO4 210.6K and 254.6K respectively. Boiling point of
NH3 can be expected to be
(2) It is a pale blue coloured gas
(1) 238.5 K (2) 268.5K
(3) Water solubility of O3 is more than that of O2
(4) Bleaching action of O3 is due to reduction. (3) 170.2K (4) 200K
14) Group 16 element with the highest and least electron 21) Sulphur exhibit +6 oxidation state when it undergo
affinities are respectively the hybridisation
(1) Oxygen and Tellurium (1) sp3 or sp (2) sp2 or sp3d2
(2) Sulpur and Oxygen (3) sp3d or sp3d2 (4) sp or sp3d2
(3) Sulphur and Tellurium 22) The molar conductance of 0.001 M acetic acid is
(4) Sulphur and Selenium 50 ohm–1 cm2 mol–1. The maximum value of molar
conductance of acetic acid is 250 ohm–1 cm2 mol–1
15) Identify correct statements
what is the degree of dissociation () of acetic acid
A) In cyclo S6, the ring adopts boat form
(1) 0.5 (2) 0.2 (3) 0.3 (4) 0.4
B) The order of oxidising nature is HNO3 > H2SO4
23) Which is the most basic ?
> H3PO4
C) The transition temperature of  and  - sulphurs (1) NH3 (2) NCl3 (3) N (SiH3)3 (4) NF3
is 369K 24) SO2 acts as ___ and TeO2 acts as__
D) Ozone is diamagnetic and oxygen is paramagnetic (1) Oxidising agent, reducing agent
in nature (2) Reducing agent, Oxidising agent
(1) A, B, C, D (2) B, C, D only
(3) Reducing agent, Reducing agent
(3) A, B, C only (4) B, C only
(4) Oxidising agent, Oxidising agent
16) Oxygen is divalent where as sulphur exhibit variable
valencies of 2, 4 and 6 due to 25) The O – O bond length and O – O bond angle in O3
are
(1) Sulphur being more electronegative than oxygen
(1) 128 pm, 1170 (2) 128 pm, 1200
(2) Sulphur is a bigger atom
(3) 128 Å, 1170 (4) 128Å, 1200
(3) Ionisation potential of sulphur is more
(4) Presence of vacant d-orbitals in the valence shell 26 With which of the following dioxygen doesn’t react ?
of sulphur (1) Au (2) Pt (3) Ne (4) All
17) Which of the following reactions is not possible 27) Regarding ozone the incorrect statement is
(1) 3SO 2  O3  3SO3 (1) Pure ozone is pale blue gas, dark blue liquid and
violet black solid.
(2) H 2 O 2  O3  H 2 O  2O 2 (2) Tailign of mercry is an example of oxidizing
(3) 2HF  O3  H 2O  F2  O 2 property of ozone
(3) 2O3  3O 2 H  284 kJ
(4) BaO 2  O3  BaO  2O 2
(4) Ozone is thermodynamically less stable than
18) When ammonia reacts with excess of chlorine, the
oxygen
products formed are
(1) N2 + NH4Cl (2) NCl3 + HCl 28) Which of the following cannot be reduced by SO2 ?
(3) NCl3 + N2 (4) NH4Cl + NCl3 (1) Fe2(SO4)3 (2) KMnO4
19) Regarding N2O, the wrong statement is (3) K2Cr2O7 (4) H2S
(1) It is called laughing gas 29) Which form of sulphur shows paramagnetic
(2) In it, the oxidation state of nitrogen is +1 behaviour ?
(3) It is a linear molecule (1) Solid state cyclic S8 (2) Solid state cyclo S6
(4) It is prepared by heating ammonium nitrite (3) Vapour state S2 (4) Vapour state S8
30) x
SO 2(g)  Cl 2(g)  P4
 y 

 Z. What are x, y and 38) The number of unpaired electrons in ground state.
1st, 2nd and 3rd excited states of halogen (other than
z? fluorine) are respectively
(1) V2O5, SOCl2, PCl5 (1) 2, 3, 4, 7 (2) 2, 4, 6, 7
(2) Charcoal, SOCl2, PCl3
(3) 1, 3, 5, 7 (4) 0, 1, 3, 5
(3) Charcoal, SO2Cl, PCl5
39) Incorrect match is
(4) Fe, SO2Cl2, PCl5
(1) F2 - Yellow coloured gas
31) The key step in the manufacture of sulphuric acid by
contact process is (2) Cl2 - Greenish yellow coloured gas
V2 O5 (3) I2 - Violet coloured solid
(1) 2SO 2(g)  O 2(g)   2SO3(g)
(4) Br2 - Reddish brown solid

(2) 4FeS2  11O 2 
 2Fe 2 O 3  3SO 2 40) Halogen that cannot oxidize other halides from their
solutions is
(3) 3SO 2  O3  3SO3
(1) Bromine (2) Iodine
(4) SO3  H 2 O  H 2SO 4
(3) Chlorine (4) Fluorine
32) Correct match among the following is
41) Which of the following is used to remove arsenic
(1) Bond dissociation enthalpy - Cl2 > Br2 > F2 > I2 impurities in contact process of manufacturing
(2) Electron gain enthalpy - Cl > F > Br > I sulphuric acid ?
(3) Oxidising power - F2 > Cl2 > Br2 > I2 (1) Galatinous Fe2O3.xH2O
(4) All are correct (2) Gelatinous Al(OH)3
33) Which of the following reaction is not feasible ? (3) Galatinous KMnO4
(1) 2I 2  2H 2 O  4I   4I   O 2 (4) Acidified K2Cr2O7
42) Which of the following statement is not true ?
(2) 2F2  2H 2O  4HF  O 2
(1) HF is stronger acid than HCl
(3) 3F2  3H 2 O  6HF  O3
(2) Among halide ions, iodide is the most powerful
(4) Cl 2  H 2 O  HCl  HClO reducing agent
(3) Fluorine is the only halogen that does not show
34) Strongest hydrohalic acid is
variable oxidation states
(1) HF (2) HI
(4) HOCl is stronger acid than HOBr
(3) HCl (4) HBr
43) Which among the following factors is the most
35) Which of the following is a true statement regarding important in making fluorine the strongest oxidizing
Fluorine halogen
(1) low enthalpy of dissociation of F – F bond
(1) electron effinity
(2) high hydration enthalpy of F– ion
(2) bond dissociation energy
(3) high SRP value
(3) electro negativity
(4) all of these
(4) ionization enthalpy
36) Which of the following is not the mineral of fluorine?
44) Reducing power of halogen acids is in the order
(1) Fluorspar (2) Carnalite
(1) HF > HCl > HBr > HI
(3) Fluorapatite (4) Cryolite
(2) HF < HCl < HBr < HI
37) The halogen present in seaweeds is
(3) HCl < HF < HBr < HI
(1) Iodine (2) Fluorine
(4) HCl > HF > HI > HBr
(3) Chlorine (4) Bromine
45) Which of the following is incorrect order 55) Cl2O is an anhydride of
(1) oxidizing power : F2 > Cl2 > Br2 > I2 (1) HClO4 (2) HOCl
(2) bond dissociation energy : F2 > Cl2 > Br2 > I2 (3) Cl2O3 (4) HClO2
(3) acidic property in water : HI > HBr > HCl > HF 56) Increasing order of Cl – O bond length of oxoacids
(4) electron negativity : fluorine > chlorine > bromine of chlorine is
> iodine (1) HOCl < HClO2 < HClO3 < HClO4
46) Chlorine can not be prepared from
(2) HClO4 < HClO3 < HClO2 < HClO
(1) MnO2 + HCl(conc)
(3) HClO3 < HOCl < HClO2 < HClO4
(2) KMnO4 + HCl(conc)
(4) HOCl < HClO4 < HClO3 < HClO2
(3) O3 + HCl
57) The electron affinity values (in KJ.mol–) of three
(4) KCl + Br2
halogens x, y and z respectively are -349, -333 and
47) Diamagnetic oxide of chlorine is -325. Then x,y and z respectively are
(1) ClO3 (2) Cl2O6 (1) Fluorine, Chlorine and Bromine
(3) Cl2O5 (4) Cl2O7 (2) Chlorine, Fluorine and Bromine
48) The catalyst used in Deacon’s process for Cl2 is (3) Chlorine, Bromine and Fluorine
(1) Al2O3 (2) AlCl3
(4) Bromine, Chlorine and Fluorine
(3) CuCl2 (4) MnO2
58) Mustard gas among the following
49) Bleaching powder is an example of
(1) CHCl3 (2) COCl2
(1) an acidic salt (2) a complex salt
(3) CCl3NO2 (4) (CH2 – CH2Cl)2S
(3) a double salt (4) a mixed salt
59) The decreasing order of stability of halogen oxides
50) Gaseous HCl is a poor conductor of electricity, while
is as follows
its aqueous solution is a good conductor. This is
because (1) Cl > Br > I (2) Br > Cl > I
(1) H2O is a good conductor of electricity (3) I > Cl > Br (4) Cl > I > Br
(2) a gas cannot conduct electricity, but a liquid can 60) Which is not the correct match against the property
(3) HCl ionizes in aqueous solution shown
(4) it is insoluble in water (1) Electronegativity (decreasing order) F > Cl > Br
>I
51) Which element is extracted commercially by the
electrolysis of an aqueous solution of one of its (2) Oxidizing power (decreasing order) Cl2 > F2 >
compounds Br2 > I2
(1) sodium (2) aluminium (3) Bond dissociation enthalpy (decreasing order)
(3) chlorine (4) potassium Cl2 > Br2 > F2 > I2
52) The mixture of HCl and HNO3 made in 3 : 1 ratio (4) Electrode potentials (decreasing order) F2 > Cl2
contains > Br2 > I2
(1) ClO2 (2) NOCl (3) NCl3 (4) N2O4 61) Which of the following is correct regarding solubility
of Iodine ?
53) Fluorine absorbs_____portion of light and appears
yellow (1) I2 dissolves more in C6H6
(1) Yellow (2) Green (3) Violet (4) Red (2) I2 dissolves more in water
54) HCl gas can be dried by passing over (3) I2 dissolves to an equal extent in both C6H6 and
(1) quicklime (2) sodalime water
(3) caustic potash sticks (4) Conc. H2SO4 (4) It does not dissolves both in C6H6 and H2O
62) Which of the following reaction is not feasible 70) How many P-P bonds are there in P4
(1) 4 (2) 3 (3) 2 (4) 6
(1) F2  2Cl 
 2F  Cl 2
71) 3.55 grams of gaseous chlorine atoms get converted
(2) Cl 2  2F  
 2Cl  F2 to chloride ions by iberating 34.9 KJ. Electron gain
enthalpy of chlorine is ___KJ/mole
(3) Br2  2I  
 2Br   I 2 (1) -34.9 (2) -349
(3) -3.49 (4) -700
(4) Cl 2  2Br  
 2Cl  Br2
72) Statement-I : F2 is better oxidizing agent than Cl2
63) Which one is most basic Statement -II : HI is strongest acid and strongest
(1) F– (2) Cl– (3) Br– (4) I– reducing agent among hydridies of 17th group
(1) Statement - I and Statement-II are true
64) Identify the products X and Y in the following reaction
(2) Statement-I is true but Statement-II is false.
Na 2S2 O 3  Cl 2 
 X  2HCl  Y (3) Statement-I is false but Statement-II is true.
(1) Na2SO3 and S (2) Na2S and Na2SO3 (4) Statement-I and Statement-II are false
(3) Na2SO4 and S (4) Na2S and S 73) Statement-A : Transition elements show variable
oxidation states
65) The acidic character of hypohalous acids vary in the
following order Statement-B : Energy difference between ns and
(n-1)d electrons is meagre
(1) HClO > HIO > HBrO
(1) Both statements (A) and (B) are correct
(2) HBrO > HClO > HIO
(2) Both statements (A) and (B) are incorrect
(3) HIO > HBrO > HClO
(3) Statement (A) is correct but Statement (B) is
(4) HClO > HBrO > HIO incorrect
66) Which of the following is not an electrophile ? (4) Statement (A) is incorrct but Statement (B) is
correct
(1) (CH3)4N+ (2) Cl+
74) Statement-A: E0 Value of Fe+3/Fe+2 is less than
(3) :CCl2 (4) AlCl3 expected
67) Which of the following is not true about nucleophile Statement-B: Fe+3 is stable due to d5 configuration
(1) Donates an electron pair to an electrophile to (1) Both statements (A) and (B) are correct
form a chemical bond
(2) Both statements (A) and (B) are incorrect
(2) Nucleophiles are proton acceptors
(3) Nucleohiles are Lewis acids (3) Statement (A) is correct but statement (B) is
incorrect
(4) A nucleophile gets attracted to a full or partial
positive charge (4) Statement (A) is incorrect but statement (B) is
correct
68) Which halide ion is the best nucleophile in dimethyl
sulphoxide solution 75) Which of the following will not have a magnetic
moment of 3.9 B.M
(1) I– (2) F– (3) Cl– (4) Br–
69) Incorrect statement regardig rhomic and monoclinic (1) V+2 (2) Cr+3 (3) Co+2 (4) Mn+3
sulphur is 76) The transitional metal which form green compound
(1) Density of rhombic sulphur is greater than in +3 oxidation state and yellow orange compound
monoclinic sulphur in +6 oxidation state is
(2) Melting point of monoclinic sulphur is more (1) Fe (2) Ni (3) Cr (4) Co
(3) Monoclinic sulphur is thermodynamically most 77) Which of the following ions exhibits maximum
stable allotrope magnetic moment ?
(4) Both rhombic sulphur and monoclinic sulphur as S8 (1) Mn+2 (2) Fe+2 (3) Ti+2 (4) Cr+3
78) Which of the following is an interstitial compound ? 87) The correct IUPAC name for the compound Co
(1) NH3 (2) PedCl2 (NH3)4 Cl(ONO)Cl is
(1) Tetraaminechloridonitrito-N-coba (III) chloride
(3) TiH (4) ZnCl2
(2) Chloridonitrito-O-tetraamminecobalt (II) chloride
79) Which set of elements among the following are called
non-transitional elements ? (3) Dichloridonitrito-O-tetraamminecobalt (III)
(1) Cu, Ag and Au (2) Fe, Co and Ni (4) Tetraamminechloridonitrito-O-cobalt (III) chloride
(3) Zn, Cd and Hg (4) Re, Os and Ir 88) The hypothetical complex triamminedaqua-
chloridcobalt(III) chloride can be represented as :
80) In which of the following ions, the colour is not due
to d-d transition ? (1) CoCl(NH3)3 (H2O)2
(1) [Ti(H2O)6]+3 (2) [CoF6]–3 (2) Co(NH3)3 (H2O)Cl3
(3) Co(NH3)3(H2O)2ClCl2
(3) CrO 4 2 (4) [Cu(NH3)4]+2
(4) Co(NH3)3 (H2O)3 Cl3
81) Which among the following is incorrect statement ?
89) EAN a metal carbonyl M (CO)x is 36. If atomic
(1) Catalytic behavior of transition metals can be number of metal M is 26, what is the value of x ?
explained by Intermediate compound formation (1) 4 (2) 8 (3) 5 (4) 6
theory
90) The complex Cr(H2)4Br2Cl gives the test for :
(2) Mn+3 acts as strong oxidant becaue of having
high positive E0 value for Mn+3 ? Mm+2 (1) Br– (2) Cl–

(3) Cr+2 acts as strong reductant because of having (3) Cr3+ (4) Br– or Cl– both
negative E0 value for Cr+3 / Cr+2 91) Which of the following complexes will be dehydrated
(4) Steel is a non ferrous alloy to relatively minimum extent by conc. H2SO2 under
identical condition ?
82) Which one of the following statements related to
lanthanons is incorrect ? (1) Cr(H2O)5 Cl3Cl2. H2O

(1) All the lanthanons are less reactive than aluminium (2) Cr(H2O)4 Cl2Cl.2H2O

(2) Ce (+4) solutions are widely used as oxidizing (3) Cr(H2O)6Cl3

agent in volumetric analysis (4) CrCl3 (H2O)3 3H2O
(3) Europium shows +2 oxidation state 92) On adding AgNO3 solution to a solution of Pt(NH3)3
(4) The basic strength decreases as the ionic radius Cl3 Cl, the percentage of total chloride ion precipitate
decreases from Pr to Lu for hydroxides is

83) Which Lanthanoid series metal has largest atomic (1) 100 (2) 75 (3) 50 (4) 25
radii ? 93) A complex of platinum, ammonia and chloride
(1) Ce (2) Fe2+ produces four ions per molecule in the solution. The
structure consistent with the observation is
(3) La (4) Eu
(1) Pt(NH3)4Cl4 (2) Pt(NH3)2Cl4
84) Which aquated ion is not green in color ?
(3) Pt(NH3)5Cl4 (4) Pt(NH3)4Cl4
(1) V3+ (2) Fe2+ (3) Ni2+ (4) Eu
94) One mole of Co(NH3)5Cl3 gives 3 moles of ions on
85) Which of the following is the best oxidizing agent in dissolution in water. One mole of this reacts with
aqueous medium as per SRP values ? two moles of AgNO3 to give two moles of AgCl.
(1) Ce4+ (2) Co3+ (3) Mn3+ (4) MnO 4 The complex is :
(1) Co (NH3)4 Cl2Cl.NH3
86) The formula of the complex tris (ethylenediamine)
cobalt (III) sulphate is : (2) Co (NH3)4 Cl2Cl.NH3
(1) Co(en)2 SO4 (2) Co(en)3SO4 (3) Co (NH3)5 ClCl2
(3) Co(en)3SO4 (4) [Co(en)3]2(SO4)3 (4) Co (NH3)3 Cl3Cl.NH3
95) For the correct assignment of electronic configuration 105) Which among the following is incorrect statement ?
of a complex, the valence bond theory often requires (1) Interstitial compounds are more reactive than
the measurement of constituents
(1) molar conductance (2) optical activity (2) Magnetic moment of Ti+2 is 2.828BM
(3) magnetic moment (4) dipole moment
(3) MnO 4 1 has purple colour due to charge transfer
96) The complex ion which has no ‘d’ electrons in the
phenomena
central metal atom is :
(4) Order of third ionization potential is Mn > Fe
(1) [MnO4]– (2) Co (NH3)6
106) In the compounds H3, N2O, TeF4, PCl3, SF4. how
(3) Fe(CN)6 (4) Cr(H2O)6
many are solids
97) How many chelates are in Ca(EDTA) ion between
(1) 6 (2) 3
ligand and Ca2+ ?
(3) 2 (4) 4
(1) 6 (2) 5 (3) 4 (4) 3
107) Incorrect statement is
98) Which of the following is steel hard ?
(1) oxidizing power of Conc.HNO3 > Conc.H2SO4
(1) Eu (2) Pr (3) Yb (4) Sm
> H3PO4
99) Which of the following doesn’t show +4 oxidation
(2) SF6 is an insulator an SF4 is a fluorinating agent
states as MO2 ?
(3) Bond angle in ozone is 117o
(1) Pr (2) Nd (3) Dy (4) Gd
(4) SO2 resembles CO2 in all its chemical properties
100) Which of the following shows half filled configuration
in +2 ? Eu (2) Sm (3) Tm (4) Yb 108) The hydrolysis product of ClF3 are
101) The composition of alloy misch metal is ? (1) HF & HClO2 (2) Hf & HCl
(1) 50% lanthanoids + 45% Fe+ traces of C, S, Ca (3) HF & HClO4 (4) HF & HClO
and Al
109) The correct order of increasing basic nature of the
(2) 5% lanthanoids + 95% Fe+ traces of C, S, Ca oxy anions of chlorine is
and Al
(3) 95% lanthanoids + 5% Fe+ traces of C, S, Ca (1) ClO  ClO2  ClO3  ClO4
and Al
(2) ClO 3  ClO   ClO 2  ClO 4
(4) 60% lanthanoids + 40 Fe+ traces of C, S, Ca
and Al (3) ClO 4  ClO 3  ClO 2  ClO 
102) Among the following transition metals, the maximum
number of oxidation states is exhibited by (4) ClO 3  ClO 2  ClO   ClO 4
(1) Mn (Z = 25) (2) Fe (Z = 26)
110) In the reaction of noble metal, platinum with aquaregia
(3) Cr (Z = 24) (4) Ti (Z = 22) the complex [PtCl6]2– is formed. In this reaction mole
103) Because of lanthanoid contraction, which of the ratio of Pt and NO 3 ions is ______
following pairs of elements have nearly same atomic
radii ? (Numbers in parenthesis are atomic numbers) (1) 1 : 1 (2) 2 : 1
(1) Zr (4) and Hf (72) (2) Zr (40) and Ta (73) (3) 8 : 9 (4) 3 : 4
(3) Ti (22) and Zr (40) (4) Zr (40) and Nb (41) 111) Which of the following on thermal decomposition
104) The correct order of ionic radii of Y3+, La3+, Eu3+ does not evolve dioxygen ?
and Lu3+ is (1) KClO3 (2) KMnO4
3+ 3+ 3+ 3+
(1) Y < La < Eu < Lu (3) Pb (NO3)2 (4) NH4NO3
3+ 3+ 3+ 3+
(2) Lu < Y < Eu < La 112) Which of the single bond has more bond energy
(3) Lu3+ < Eu3+ < La3+ < Y3+
(1) N – N (2) P – P
(4) La3+ < Eu3+ < Lu3+ < Y3+
(3) As – As (4) Sb – Sb
113) When excess NH3 reacts with chlorine, the gas 119) The number of bridging CO ligand(s) and Co - Co
evolved is ‘X’. The ‘X’ is also produced by the (bonds) in Co2 (CO)8 respectively are
following reaction (1) 0 and 2 (2) 2 and 0

(1) KMnO 4   (3) 4 and 0 (4) 2 and 1

(2) (NH 4 ) 2 Cr2 O 7   120) The lanthanide ion that would show colour is
(1) Sm+3 (2) La3+
(3) NaCl  H 2SO 4 

(3) Lu+3 (4) Gd+3
(4) MnO 2  HCl 
 121) Which of the following is radioactive lanthanoid
114) What is the correct electronic configuration of the (1) Pr (2) Pm
central metal atom in K4[Fe(CN6] based on crystal (3) Tb (4) Tm
field theory
122) The radius of La+3 (At. NO 57) is 1.06 Å. Which of
(1) t 42g e g2 (2) t 62g e 0g the following given values will be closes to the radius
of Lu+3 ?
(3) t 3g e32g (4) t 4g e 22g (1) 1.60 Å (2) 1.40 Å
115) The isomers(s) of [Co(NH3)4Cl2] that has /have a (3) 1.06 Å (4) 0.85 Å
Cl – Co – Cl angle of 90o is/are
123) The atomic number of V, Cr, Mn and Fe are 23, 24,
(1) meridonal and trans 25 and 26. Which one of these may be expected to
(2) cis and trans have the highest second ionization energy ?
(3) trans only (1) Cr (2) Mn
(4) cis only (3) Fe (4) V
116) Complex ‘X’ of composition Cr(H2O)6 Cln has a spin 124) The transition element that has lowest enthalpy of
only magnetic moment of 3.83 BM. It reacts with atomization.
AgNO3 and shows geometrical isomerism. The
(1) Zn (2) Cu
IUPAC name of X is
(3) V (4) Fe
(1) Tetraaquadichloridochromium(III) chloride
dihydrate 125) Which of the following is the electronic configuration
(2) Hexa aqua chromium (III) chloride of Th (Z = 90).

(3) Dichlorido tetra aqua chromium (IV) chloride (1) [Rn] 6d27s2 (2) [Rn] 5f16d17s2
dihydrate (3) [Rn] 5f26d17s2 (4) [Rn] 5f26d17s2
(4) Tetra aqua dichlorido chromium (IV) chloride 126) Which of the following is expected to be acidic ?
dihydrate
(1) Cr2O (2) CrO2
117) The spin - only magnetic moment and CFSE of
[Fe(CN)6]–3 respectively are (Ignore pairing energy) (3) Cr2O3 (4) CrO3
(1) 2.84 BM amd –1.6 0 127) Which of the following is not true about Werner’s
coordination theory ?
(2) 5.92 BM and 0
(1) Metal atom has primary valency and secondary
(3) 1.73 BM and –20
valency
(4) 0 BM and –2.4 0
(2) Primary valency may be satisfied by only negative
118) The difference in the number of unpaired electrons ions
of a metal ion in its high-spin and low spin octahedral
complexes is two. Then the metal ion is (3) Secondary valency is satisfied by only neutral
molecules
(1) Fe3+ (2) Co2+
(4) Secondary valency gives the streochemistry of
(3) CO2+ (4) Mn2+
the complex.
128) Number of hydrogen bonded water molecule in 136) H2SO4 cannot act as
CrCl3, 6H2O and CuSO4.5H2O respectively. (1) an acid (2) reducing agent
(1) 0, 1 (2) 0, 4 (3) oxidising agent (3) dehydrating agent
(3) 1, 1 (4) 1, 4 137) Chile salt petre contains iodine in the form of
129) In cold milk lime reacts with chlorine to form an (1) NaI (2) NaIO3
important constituent ‘X’ of bleaching powder. Here
‘X’ is a (3) NaIO4 (4) CaI2
(1) Chlorite (2) Hypochlorite 138) Which of the following arrangements gives the correct
order of increasing basic character of the conjugate
(3) Chlorate (4) Perchlorate bases of the oxoacids of chlorine ?
130) Number of moles of KMnO4 required to oxidize one
mole of Fe(C2O4) in acidic medium is (1) ClO 3  ClO 4  ClO 2  ClO 

(1) 0.6 (2) 0.167 (2) ClO 4  ClO 3  ClO   ClO 2

(3) 0.2 (4) 0.4
(3) ClO   ClO 2  ClO 3  ClO 4
131) The catalyst used to convert alkanes containing 6 to
10 carbon atoms into benzene and its homologous (4) ClO 4  ClO 3  ClO 2  ClO 
at nearly 600o C are :
139) The type of hybrid orbitals used by chlorine atom in
(1) Cr2O3 and Al2O3 (2) HCl and AlCl3
ClO 2
(3) H2SO4 and HF (4) BF3
(1) sp3 (2) sp2 (3) sp (4) sp3d
132) Statement-I: NH 4 ion is more stable than PH 4 ion
140) Match the following
Statement-II: NH3 can form H-bonding with water
but not PH3. List - I List - II
(1) Both I and II are true 1) IF7 A) T shape
(2) Both I and II are false
2) CIF B) square pyramidal
(3) I si true and II si false
(4) I is false and II is true 3) BrF3 C) pentagonal bipyamidal
133) 10.8 g of an oxide of Nitrogen ‘X’ contained 2.8 g 4) BrF5 D) Linear
of Nitrogen and g of oxygen. Regarding that oxide
(1) 1 - C 2 - D 3 - A 4 - B
‘X’, the wrong statement is
(2) 1 - C 2 - D 3 - B 4 - A
(1) ‘X’ the anhydride of HNO2
(2) In ‘X’ the oxidation number of Nitrogen is +5 (3) 1 - B 2 - D 3 - C 4 - A

(3) ‘X’ is a planar molecule (4) 1 - D 2 - B 3 - A 4 - C

(4) ‘X’ contains covalent bonds and dative bonds 141) Consider the following reaction
134) The shape of XeOF4 according to VSEPR theory is 3Cl2 + 6NaOH   5 NaCl + A + 3H2O The
(1) Trigonal bipyramidal oxidation state of chlorine int he product A is

(2) Octahedral (1) +5 (2) +4

(3) Pentagonal planar (3) +3 (4) +1

(4) Square pyramidal 142) Incorrect reaction of the following is


135) Incorrect match is (1) Li 2 CO 3   Li 2 O  CO 2
(1) S – S linkage - H2S2O6 
(2) NaNO 3   Na 2 O  NO 2  O 2
(2) S – O – S linkage - H2S2O7

(3) Mg(NO 3 ) 2   MgO  NO 2  O 2
(3) O – O linkage - H2S2O8

(4) S – O – O – S linkage - H2S2O5 (4) CaCO 3   CaO  CO 2
143) The 3d element with least metallic radius is
(1) Zn (2) Mn
(3) Ni (4) Cu
144) Statement-A: CuI2 is not stable
Statement-B : Cu+2 will oxidize I– to Iodine
(1) Both statements (A) and (B) are correct
(2) Both statements (A) and (B) are incorrect
(3) Statement (A) is correct but statement (B) is
incorrect
(4) Statement (A) is incorrect but statement (B) is
correct
145) Which of the following statements in not correct
(1) Copper liberates hydrogen from acids
(2) In its higher oxidation states, manganese forms
stable compounds with oxygen
(3) Mn3+ and Co3+ are oxidising agents in aqueous
solution
(4) Ti2+ and Cr2+ are reducing agents in aqueous
solution
146) The following oxide is used in the estimation of carbon
monoxide
(1) Cl2O7 (2) I2O7
(3) Cl2O5 (4) I2O5
 INORGANIC CHEMISTRY
XII - Answer Key
Ques. 1 2 3 4 5 6 7 8 9 10
Ans. 3 2 2 1 3 2 4 4 3 3
Ques. 11 12 13 14 15 16 17 18 19 20
Ans. 1 4 4 2 2 4 3 2 4 1
Ques. 21 22 23 24 25 26 27 28 29 30
Ans. 2 2 1 2 1 4 3 4 3 3
Ques. 31 32 33 34 35 36 37 38 39 40
Ans. 1 4 1 2 4 2 1 3 4 2
Ques. 41 42 43 44 45 46 47 48 49 50
Ans. 1 1 2 2 2 4 2 3 4 3
Ques. 51 52 53 54 55 56 57 58 59 60
Ans. 3 2 3 4 2 2 2 4 3 2
Ques. 61 62 63 64 65 66 67 68 69 70
Ans. 1 2 1 3 4 1 3 2 3 4
Ques. 71 72 73 74 75 76 77 78 79 80
Ans. 2 1 1 1 4 3 1 3 3 3
Ques. 81 82 83 84 85 86 87 88 89 90
Ans. 4 1 4 4 2 4 4 2 3 2
Ques. 91 92 93 94 95 96 97 98 99 100
Ans. 3 4 3 3 3 1 2 4 4 1
Ques. 101 102 103 104 105 106 107 108 109 110
Ans. 3 1 2 2 1 3 4 1 3 4
Ques. 111 112 113 114 115 116 117 118 119 120
Ans. 4 2 2 2 4 1 3 2 4 1
Ques. 121 122 123 124 125 126 127 128 129 130
Ans. 2 4 1 2 1 4 3 1 2 1
Ques. 131 132 133 134 135 136 137 138 139 140
Ans. 1 1 1 1 4 4 2 2 2 4
Ques. 141 142 143 144 145 146
Ans. 1 1 2 3 1 1