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Ebook Chem 2 Chemistry in Your World 2Nd Edition Hogg Solutions Manual Full Chapter PDF
Ebook Chem 2 Chemistry in Your World 2Nd Edition Hogg Solutions Manual Full Chapter PDF
1. Definitions
a. Excess hydronium ion, [H3O1+] > [OH1−], pH < 7
b. Excess hydroxide ion, [H3O1+1 < [OH1−], pH > 7
c. Equal amounts of hydronium and hydroxide, pH = 7 and [H3O1+1 = [OH1−]
2. Neutralization is the chemical reaction that occurs between acids and bases. Acids provide
protons while Arrhenius bases provide OH1−(aq) and they combine to form H2O(l).
3. A salt is the substance formed between the anion of an acid and the cation of a base.
4. Definitions
a. A substance that gives up a proton, H+, such as HCl(aq) or HNO3(aq).
b. A substance that can accept a proton like OH−. H+(aq) + OH−(aq) H2O
c. The hydronium ion has the formula H3O1+, It is a water molecule with an H O H
H
extra proton bonded to one of the unshared pairs on the oxygen.
d. The hydroxide ion has the formula OH−. It is typically released by bases such as
potassium hydroxide, KOH.
5. Definitions
a. measures the fraction of molecules that ionize
b. ionizes 100%
c. ionizes 100%
d. only partially ionized, majority of acid molecules are still intact
e. partially ionized, the majority of base molecules or ions are still intact
6. Acidic solutions at 25°C have a pH below 7. This is often expressed as a range from 0 to 7.
The reality is that the pH can be less than 0 (a negative number) if [H3O1+] is greater than 1
Molar. [H3O1+] molarities > 1M are common for strong acids and for more concentrated
solutions of acid. Usually pH is not even used for these; the molarity is just stated instead.
7. pH above 7
8. Acid-base qualities of familiar materials
a. Vinegar, acidic
b. Citrus fruits, acidic
c. Aspirin, acidic
d. Black coffee, acidic
9. a. acidic b. acidic c. basic d. basic e. acidic f. basic
10. Tests for acidity/basicity
a. sour taste, acid
b. bitter taste, base
1
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Chapter 9 CHEM2
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Chapter 9 CHEM2
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CHEM2 Instructor’s Manual
40.0 g NaOH
0.501 moles NaOH 20.0 g NaOH
1 mol NaOH
39. a. The pH for a 1 × 10-2 M HCl solution can be figured two ways. pH = −log[H3O1+]; pH =
−log 1 × 10−2 ; pH = 2The graphical relationship shown above can be used to get the
same result.
b. The pH for a 1 × 10−3 M HNO3 solution can be figured two ways. The [H3O1+] = 0.001;
pH = −log [H3O1+]; pH = −log 1 × 10−3; pH = 3The graphical relationship shown above
can be used to get the same result.
40. pH calculations
a. pH = 11
b. pH = 3
41. Using the relationship pH = –log[H3O+], the pH of the solution is 3.
42. Using a calculator and the relationship pH = –log[H3O+],the pH is calculated to be 7.6. Using
the bracketing method, the hydronium concentration can be estimated to be greater than 1 ×
10–8 M and less than 1 × 10–7 M. These correspond to pH values of 8 and 7. The pH is
expected to be closer to 7 than to 8.
43. Concentration conversions The molarity of the hydronium ion = [H3O1+]= 10−pH
a. pH = 1 ; [H3O1+] = 10−pH; [H3O1+] = 10−1 = 1 × 10−1 or 0.1
b. pH = 0 ; [H3O1+] = 10−pH; [H3O1+] = 10−0 = 1 × 10−0 or 1
c. pH = 5 ; [H3O1+] = 10−pH; [H3O1+] = 10−5 = 1 × 10−5 or 0.00001
d. pH = 3 ; [H3O1+] = 10−pH; [H3O1+] = 10−3 = 1 × 10−3 or 0.001
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Chapter 9 CHEM2
45. 75 mL
46. HBr(aq) + LiOH(aq) H2O + LiBr(aq)
The mol ratio is: 1 mol HBr = 1 mol LiOH For a neutral solution, the mols of LiOH and mols
of HBr must be equal. The set up to figure the volume in milliliters is
0.45 mol LiOH 1 mol HBr 1L 1000 mL
= mL HBr solution = 90. mL
1 1 mol LiOH 0.50 mol HBr 1L
47. The pH scale is a logarithmic scale and is not linear. Doubling the concentration of base
therefore does not double the pH. (In fact, it increases the pH by log(2) = 0.3.)
48. Sodium bicarbonate is a weak base. Since it can be used to lessen the effect of a bee sting, it
must do so by reacting with an acid that is present in the bee venom, leading to
neutralization.
49. No. Mixture is basic; 0.0035 mols of KOH remain after all HCl has been neutralized.
50. When acidic and basic solutions are mixed, a neutralization reaction occurs. First write the
balanced equation for the neutralization. HI(aq) + NaOH(aq) → H2O + NaI(aq) Find the
number of mols of solute in each given amount of solution. The mols of NaOH in 100 mL of
1.5 M NaOH is figured using the relation;
mols of base = molarity base × volume of solution mol of NaOH =
1.5 mole NaOH 100 mL 1 liter
1 liter 1 1000 mL = 0.15 mol NaOH rounded to 2 significant digits.
mols of acid = molarity of acid × volume of solution
0.50 mole HI 31 mL 1 liter
mols of HI = 1 liter 1 1000 mL = 0.016 mol HI rounded to 2 significant
digits.
The #mol of the base, NaOH, exceeds the #mols of acid, HI. Since the mol ratio in the
balanced equation is 1:1, 0.016 mol HI will react with 0.016 mol NaOH. There will be 0.13
mol NaOH left over and the final solution will be basic.
51. To calculate the molarity of the caffeine, the number of moles of caffeine needs to be
determined:
1g 1 mol
50 mg 2.6 104 mols
1000 mg 194.19 g
Then, the molarity can be calculated:
2.6 104 mol
Molarity (M) 7.3 104 M
0.355 L
52. Because buffers protect against large changes in pH by absorbing acid or base, the initial pH
of one solution could be measured before and after the addition a small amount of acid or
base. If the addition were to result in a significant change in pH, then the tested solution is
not a buffer.
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CHEM2 Instructor’s Manual
53. Aluminum hydroxide does not alter the pH of pure water, so it must not dissolve to produce
hydroxide ions, which would be necessary for a change in pH to occur. In fact, this is exactly
the case. Al(OH)3 is very insoluble in water.
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The Project Gutenberg eBook of From ploughshare to
pulpit
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eBook.
Language: English
FROM PLOUGHSHARE TO
PULPIT
A Tale of the Battle of Life
BY
SECOND EDITION.
London
JAMES NISBET & CO.
21 BERNERS STREET
TO
MY OLD PROFESSOR
SIR WM. D. GEDDES
PRINCIPAL OF ABERDEEN UNIVERSITY
BY
THE AUTHOR
CONTENTS
BOOK I.
BOOK II.
BOOK III.
CHAPTER I
CHAPTER II
The farm-steading of Kilbuie lay fully four miles back from the river,
into the interior of the wild and beautiful country, a country but little known
to the wandering Englishman, but romantic enough in all conscience, and
rendered famous if only from the fact that here Robert the Bruce lay long in
hiding before he made his grand and successful attempt to secure his
kingdom and free his land from the tyranny of the Saxon invader. It is a
country of hills and dells, of wood and water, lochs and roaring streams; a
country almost every acre of which has been in days long gone by a battle-
field; and hardly can you walk a mile here without stumbling upon the ruins
of some feudal castle. Could these strongholds but speak, what tales we
should have to listen to—tales that would cause our very heart’s blood to
tingle, and nervous cold to run down our spines!
Although four miles from the river and about the same distance from a
railway station, the farm was not over a quarter of a mile from a main road,
being connected therewith by a level straight road, with a ditch at each side,
called the “long loanings.” On each side the fields, level and green, were
spread out, and all were surrounded by sturdy stone fences called dikes. A
dike in England means a ditch, in Scotland it signifies a wall of loose stones
—that is, stones built up without any lime.
The fields around Kilbuie were not, however, all level. By no means.
There were hills on the farm so steep that it taxed all the ingenuity of the
men to plough or harrow them.
A word about the steading itself. There was in front the square-built
unpretentious square house, with bow windows below, and a good old-
fashioned garden in front, a garden in which grew vegetables of all kinds,
bar potatoes, and whose borders round about were filled with gooseberry
and rose trees time about, with fine old-fashioned flowers between. Behind
the house was the steading proper, and which was similar to those we see in
England, with one most important exception, a dirty dunghill did not lie
between the living house and the cattle houses. This is an unsanitary
arrangement never beheld in Scotland. Such places are kept well away from
the stable, byre, and dwelling-house.
It spoke well, I think, for Farmer M‘Crae’s kindliness of heart and
manner, that none of his servants had left him for the last four years, nor
were thinking of leaving him even now. You see, he never was a tyrant, and
he as often as not took Jamie into consultation before carrying out any plan
or beginning any new piece of work. Farmer M‘Crae was not much over
forty, though his son was eighteen. He had married very young, but it seems
never had had reason to repent it, for he was always happy and cheerful,
even in situations where other men might have been much cast down, as
during his recent terrible losses of cattle and corn. There were just two
things, however, that Kilbuie insisted on: one was the presence of all the
servants and family in the best room every evening to family worship; a
chapter read from the Book of Books; a prayer and short dissertation from
Norman Macleod’s book. That was all, short and simple, and every one felt
the better for it. The son’s name was simple enough in all conscience. It was
Sandie.
There were few more handsome lads in all the parish round than Sandie.
You might have taken him to be two-and-twenty from his build and general
deportment, and from the incipient whisker on his cheek and hair on his
upper lip. His cheeks and lips were the rosiest ever seen, while his very blue
eyes sparkled with ruddy health. Yet had he many ways that might have
been called almost childish.
That evening, for instance, before the accident to the minister’s trap,
Sandie entered the best room, where, near to the fire—the evenings are cold
even in May in the far north of Scotland—his gentle mother sat knitting.
He took a low stool, and, seating himself by her knee, laid his head in
her lap.
He had a little book in his hand, a Latin classic, Virgil to wit; but though
his forefinger retained his place, he was not looking at it now. He was
gazing at the fire. He gazed thus for some time, while his mother smoothed
his brow with her soft hands.
“Is my laddie tired?”
“I dinna know, mother. Sometimes I’m happy and hopeful that I’ll take a
bursary,[2] at other times I’m dull and wae and think I won’t.”
“Weel, laddie, you maun keep up your heart and pray.”
“Oh, yes, of course, mother, but I must work as well as pray. I think
you’d better do the principal part of the praying, and I’ll do the work. The
Lord is more likely to listen to you, mother, than to sinful me.”
“Whisht! Sandie; whisht! laddie. But pray I do, mornin’, noon, and
nicht. Ay, and my boy is clever, too. I’ll hear him preachin’ yet in one of the
best pulpits in a’ broad Scotland. And oh! Sandie, that will be a happy,
happy day to me.”
The thoughts of it caused the tears to flow to the good lady’s eyes, and a
lump to rise in her throat that for the time being effectually arrested speech.
“Well, mother, you see it’s like this. Work as I may, I come upon bits o’
hitches here and there that I can’t get over. I have nobody to help me, and
can’t afford a tutor. Again, you see I have nobody else to compare my
knowledge with. In the parish of Drumlade here, our minister is too old; I
wouldn’t think of worrying him, and I don’t know Mackenzie of Belhaven,
though they do say he is very clever, and was in his day a first bursar at
King’s College in Auld Aberdeen.”
“Well, live in hope, my boy, and work awa’.”
“That is just what I mean to do.”
“And may be the Lord will raise you up a frien’.”
“Who can tell?”
Sandie was silent for a while. Then he raised himself up till his glance
could meet that of his mother.
“O mother, dear,” he said gleefully, “won’t it be nice when I’m a
minister, and when I get a call! It must be to some bonnie country parish,
mother. I couldn’t stand the noisy town. I must hear the wild birds sing, see
the wild flowers bloom, and listen to the winds sighing through the pine-
trees. I must be near a stream where on bonnie summer evenings I can fish
and read. My manse must be a bonnie one, too, surrounded by trees and fine
old-fashioned gardens. Mother, I already can hear the church-bell ringing
on the Sabbath morn, and I can see you and father—for, of course, you both
will live with me—coming arm in arm through the auld kirkyard to the
church-door, and slowly up the passage to your pew beneath the pulpit
stairs. Oh, it will be a happy life! But now, mother, I’m off to my study, to
struggle another hour or two with Virgil. I’ll be in again in time for supper.
Ta-ta, mother.”
And off strode Sandie, and his mother resumed her knitting, the tear,
however, still glancing in her eye.
CHAPTER III