Page 1

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

M잘TM잘TⵔⵌS



Რ
ind
sum
of
all
possible
roots
of
|x
–

x

Რ|

–

x

皤
净

Რ傈 뜀

ૼ
傈 

ૼ
ૼ傈 
–
ૼ
傈


ૼ
잘ns

Რ傈

Sol


|x

–

x

Რ|
净

x
–
皤

ⵌase伸ⵔ


x
³



x

–
Რ
x




净



Რ
± Რ

x
净

净

±
ૼ


then
x
净



ૼ
皤
ⵌase伸ⵔⵔ


£
x
£





x

–

x

Რ
净
皤
–

x

x

–

x



净



x
净



\ 沤um
of
roots
净


ૼ



净
뜀

ૼ
Რ
æ Რ ö


he
coefficient
of
x
in
the
expansion
of
ç x
- ૼ ÷
is

Რ

è x ø
Რ傈 Რ
ⵌ皤
傈 Რⵌ

ૼ傈 Რⵌ

傈 Რ
ⵌ

잘ns

ૼ傈

r

Რ–r æ Რ ö
Sol

Რ
rᲠ
净
ⵌr
x 傈
ç- ૼ ÷
è x ø
Რ
rᲠ
净
ⵌr
–Რ傈r
x

–皤r


\


–
皤r
净
Რ

Þ
r
净



Რ
Რ

\ 皤
净
ⵌ
–Რ傈
x


Þ ⵌoefficient
of
xᲠ

is
Რⵌ

or
Რⵌ뜀

ૼ
he
sum
of
first



terms
of
series


ᲠᲠ

Რ뜀


뜀


Რ
……
is

Რ傈 ૼ


傈 ૼᲠ

ૼ傈 ૼ


傈 ૼ

잘ns

Რ傈

1
 Page 2

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

Sol


 ᲠᲠ Რ뜀
뜀
Რ…

Რ
Რ
®
Რst
difference
is
잘


Þ

n
净
an

bn

c

ૼa
b
净


Რ
净
a

b

c
净


a
净
Რ

b
净
ૼ

c
净
Რ


净

a


b

c
净
ᲠᲠ

a


b
净


ૼ
净
뜀a

ૼb

c
净
Რ뜀



n
净
n

ૼn

Რ

( )





沤


净
å n = å n
+ ૼn + Რ
n =Რ n =Რ

´
Რ ´
Რ

´
Რ
沤


净


ૼ ´ +





沤


净


皤



ૼ






沤


净
ૼ





he
number
of
ways
to
distribute



chocolates
among
three
students
such
that
each
student
gets
atleast
one
chocolate
is
Რ傈

ⵌ


傈 Რ뜀ⵌ
ૼ傈 Რ뜀ⵌૼ
傈

ⵌૼ
잘ns


傈
Sol


et
x

y

z
are
number
of
chocolates
three
students
get


x

y

z
净



ꬨ
x

y

z
³
Რ

\
no

of
ways
is
Რ뜀ⵌ



ⵔn
the
expansion
of

Რ䔜
+ ૼ–Რ䔜
傈n

the
ratio
of
th
term
from
start
and
th
term
from
end
is




Რ

then
find
ૼrd
term
Რ傈 ૼ
ૼ
傈

ૼ ૼ傈 ૼ

傈 
ૼ
잘ns


傈
n
ⵌ

Რ䔜
傈n –
ૼ–Რ䔜
傈

Sol

n
=

ⵌ
ૼ–Რ䔜
傈n–

Რ䔜
傈

n –

æ
Რ䔜
ö
ç –Რ䔜
÷
净


èૼ ø
n –


傈

=

n
–


净


n
净
Რ

Რ
Რ䔜

–Რ䔜


ૼ
净
ⵌ


傈 ૼ 傈
Რ
净
Რ
ⵌ

×

傈

×

净


ૼ
ૼ

2
 Page 3

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

et
잘
净
[aij]
×

be
a
matrix
and
잘

净
ⵔ
where
aij
¹



ⵔf
a
is
sum
of
diagonal
elements
and
b
净
det 잘傈

then
ૼa



b


is
Რ傈 Რ

傈 Რ
ૼ傈

傈

잘ns

ૼ傈

Sol


잘

净
ⵔ

沤o
잘

–

잘
–
ⵔ
净

Þ
l

–

l
–
Რ
净



ere
a
净
lᲠ

l

净



b
净
lᲠl

净
–
Რ

x
x sec
x + tan x傈 æ pö
皤
et
ⵔ x傈净 ò dx
ⵔf
ⵔ
傈
净
Რ
then
ⵔ ç ÷
is
equal
to


x tan x + Რ傈

è
ø

p
æ p+
ö p
æ p+
ö
Რ傈 –


ln
ç ÷ Რ
傈
–
ln
ç ÷ Რ

p + Რ
è

ø
p + Რ
è

ø

p
æ p +Რ ö p
æ p +Რ ö
ૼ傈 –


ln
ç ÷ Რ
傈



ln
ç ÷ Რ
p+
è
ø p + Რ
è

ø

잘ns

Რ傈

Sol

ӄsing
integration
by
parts

-Რ傈 -Რ傈
ⵔ x傈
净
x




–
ò
x

dx


x tan x + Რ x tan x + Რ

x
x cos x
净
–
x tan x + Რ

ò x sin x + cos x
dx

-x

Þ ⵔ x傈
净


ln|x
sin
x

cos
x|

c

x tan x + Რ

put
x
净



c
净
Რ

-p
æp ö
æ pö Რ
ç
+Რ ÷
\ ⵔ ç ÷
净




ln
ç ÷ Რ
è
ø p ç
÷
+Რ

è ø

æ pö p
æ p+
ö
ⵔ ç ÷
净
–


ln
ç ÷ Რ
è
ø
p + Რ
è

ø

3
 Page 4

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

ⵔf
aᲠ

a


……


an
are
in
arithmetic
progression
with
common
difference
d




then
find

dæ Რ Რ Რ ö
lim ç + +



+ ÷
n ®¥ n çè aᲠ + a
a
+ aૼ a n + a n -Რ ÷
ø
잘ns

Რ傈

Sol



Რ
d
dé
në
( ) (
a
- aᲠ + )
a ૼ - a
+



+ ( a n - a n -Რ ù
û )
净
Რ
d
d
n

( a n - aᲠ )
Რ d
( aᲠ + nd )
Რ䔜

净

d n
Რ䔜

Რ d æ a ö
净
´ n çd + Რ ÷
d n è nø
Რ䔜

Რ æ a ö

净
d ´ d çᲠ + Რ ÷
d è nd ø
净
Რ

뜀
잘
pair
of
dice
is
rolled

times

et
getting
a
total
of

in
a
single
throw
is
considered
as
success

x
ⵔf
probability
of
getting
atleast
four
successes
is

then
x
is
equal
to


ૼ

Რ
Რ Რ
ૼ Რ
ૼ
Რ傈

傈 ૼ傈
傈

뜀 뜀
뜀 뜀

잘ns

ૼ傈


Რ
Sol


 success傈
净

净

ૼ
뜀


æᲠö
æᲠö x
 atleast
four
success傈
净
ⵌ

ç ÷
+ ç ÷ = 

è뜀ø 뜀 è뜀ø ૼ

Რ ´ ૼ Რ
ૼ
Þ
x
净
= 
뜀 뜀


æᲠö Რ
Რ

et
f x傈
satisfies

f x傈


f ç ÷
净
 ૼ

then
Რ
ò f x傈 dx
is
èxø x Რ

Რ傈 Რ
ln
ૼ
–


傈 ln


–

ૼ傈 Რ
ln

–


傈 ln


–
ૼ

잘ns

ૼ傈

4
 Page 5

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

æᲠö Რ
Sol

f x傈


f ç ÷
净
 ૼ




i傈

èxø x
Რ
eplace
x
®

x
æᲠö
f ç ÷ 
f x傈
净
x

ૼ




ii傈

èxø
y
i傈


ii傈


뜀f x傈
净
–
x

ૼ
x



æ Რ
ö
Რ
ò f x傈 dx
净 ò çè x -
x +
÷
dx
净
Რ
ln


–



Რ Რ ø

ᲠᲠ
ⵔf
image
of
point
 Რ




ૼ傈
about
the
plane

x
–
y

ૼz
净


is
point


then
area
of
D
is
where

is



Რ


Რ
傈
Რ Რ Რ
Რ傈
ᲠૼᲠ


傈 ᲠૼᲠ

ૼ傈
ᲠૼᲠ


傈
ᲠૼᲠ






잘ns

Რ傈

Sol


ⵔmage
formula
w
r
t


x -Რ y -
z - ૼ
= = = -

(
´Რ -
+ ૼ ´ ૼ -
)

-Რ ૼ

+ Რ
+ ૼ

Þ
 –Რ

ૼ


傈

 Რ




ૼ傈

 –Რ

ૼ


傈


Რ


Რ
傈


ˆi ˆj kˆ
Რ
잘rea
净
 皤 Რ




-Რ ૼ

Რ ˆ ˆ
净
ૼૼi + 뜀 j - Რ뜀kˆ


Რ
( ૼૼ) + 뜀
+ (Რ뜀 )



잘rea
净



Რ Რ
净
Რ

뜀 +
Რ + ૼ
Რ = ᲠૼᲠ

5
 Page 6

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

Რ

ⵌircle
in
ⵔst
quadrant
touches
both
the
axes
at
잘




ⵔf
length
of
perpendicular
from
 a

b傈
on

circle
to
chord
잘
is
equal
to
ᲠᲠ

ind
a
b
잘ns

Რ
Რ傈

Sol


ⵌ


x
–
r傈


y
–
r傈

净
r
ꬨ

a


b

–

r a

b傈

r

净

 a

b傈
ᲠᲠ


( )
a


b

–

r
ᲠᲠ
+ r

r

净

a


b

–




r
–
r

净



a+b-r

净
= ᲠᲠ



a

b
净
ᲠᲠ
+ r

a


b



ab
净





r




r

ab
净
Რ
Რ

Რૼ
ⵔf
f x傈
净
[a

Რૼ
sinx]


x
Î



p傈

then
number
of
non伸differentiable
points
of
f x傈
are
[where
䁨a䁨
is
integer]
잘ns


傈

Რ
Რ

Sol

oints
where
sin
x
净












will
be
the
points
of
non伸derivability
of
f x傈


Რૼ Რૼ Რૼ
Þ



points

Რૼ

Რ

ૼ




Რ



p

잘nd
also
where
sin
x
净
Რ
Þ
Რ
points

\

points
of
non伸derivability

6
 Page 7

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

Რ

ⵔf
잘 Რ

Რ

Რ傈




l


傈

ⵌ l

Რ




Რ傈







–
傈
are
coplanar
then
å
li


傈

is
equal
to

ૼ

Რ

Რ


Რ傈




傈


ૼ傈



傈

ૼ 뜀 뜀 ૼ
잘ns

ૼ傈

uuur uuur uuur
Sol

[잘 잘ⵌ 잘]
净




Þ l
净



–

ૼ
Რ
Რ


å li


傈


净
Რ



净

뜀 뜀
잘 잘

ⵔⵌ ⵔ ⵔӄ沤


Რ
ⵔf
[x


]

[x

ૼ]
£
皤
and
let
call
its
solution
as
set
잘
and
set

is
the
solution
of
inequality
ૼx–



ૼ–ૼx
Რ傈 
Ì
잘

잘
¹

傈 잘
Ì


잘
¹
 ૼ傈 잘
Ç

净
f
傈 잘
È

净

잘ns


傈

Sol


[x]
£
–

Þ
[x]
£
–Რ
Þ
x
<



잘
is
–¥


傈

x
–




–ૼx
Þ
x


Რ
Þ

is
–¥

Რ傈

ence
잘
Ì


잘
¹


Რ

eight
of
tower
잘
is
ૼ

m
where

is
foot
of
tower

잘ngle
of
elevation
from
a
point
ⵌ
on
level
ground
to
top
of
tower
is


°
and
angle
of
elevation
of
잘
from
a
point

x
m
above
ⵌ
is
Რ°
then
find
area
of
quadrilateral
잘ⵌ

Რ傈 ૼ

ૼ –Რ傈
傈



ૼ –Რ傈 ૼ傈 Რ
ૼ –Რ傈
傈 Რ

ૼ –Რ傈
잘ns


傈

잘
ૼ
–x
Sol


Რ° 
x x


°
 ⵌ
y
ૼ

tan

°
净
= ૼ
y

Þ
y
净
Რ
ૼ

7
 Page 8

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

ૼ
– x
tanᲠ°
净

y


–
ૼ 傈Რ
ૼ
净
ૼ

–
x

x
净
ૼ

–


ૼ

ૼ


x
净



–


ૼ

잘rea
of
잘ⵌ
净
xy
净



–

ૼ 傈

Რ
ૼ
净



ૼ
–
Რ傈

Რ皤
quivalent
statement
to
p
®
q傈
Ú
r
®
q傈
will
be
Რ傈 p
Ù
r傈
®
q
傈 p
Ú
r傈
®
q
ૼ傈 q
®
r傈
Ú
p
Ú
r傈
傈 r
®
p傈
Ù
q
®
r傈
잘ns

Რ傈

Sol

p
q
r
p
®q r®q
p®q傈
Ú r®q傈
p
Ù
r傈
p
Ù r傈 ®
q









































































Რ

or
two
groups
of
Რ
sizes
each

mean
and
variance
of
first
group
is
Რ


Რ

respectively

and
second
group
has
mean
Რ

and
variance
of
s


ⵔf
combined
variance
is
Რૼ
then
find
variance
of
second
group
墐
Რ傈
뜀
傈 ᲠᲠ ૼ傈 Რ

傈 Რ

잘ns

ૼ傈

Sol


x = Რ


sᲠ
= Რ


y = Რ

s

= s


nᲠ
净
n

净
Რ

s

= Რ

净

åx

i
– Რ
傈

Þ åx

=
ૼ皤

å xi = Რ


Რ i
Რ

s

=
å y - (Რ
)
å y


i

=
Რ


i
Რ

Რૼ
净

åx + åy

i


i æ Რx + Რy ö
-ç

÷
ૼ
è ૼ
ø

ૼ皤
+ å y
i
- (Რૼ)


Რૼ =
ૼ

ૼ
뜀

åy - (Რ
) = Რ





i = ૼ
뜀

Þ
s

=
Რ

8
 Page 9

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

Რ뜀
잘
rectangular
parallelepiped
with
edges
along
x

y

z
axis
has
length
of
ૼ





respectively

ind

the
shortest
distance
of
the
body
diagonal
from
one
of
the
edges
parallel
to
z伸axis
which
is
skew
to
the
diagonal

Რ
Რ Რ
뜀
Რ傈
傈 ૼ傈
傈

 ૼ
 

잘ns

ૼ傈

r
(
Sol


quation
of
diagonal

r =
+ l ૼiˆ +
ˆj + kˆ )
◤


 ૼ


傈




傈



 ૼ
 잘
ⵌ





傈

quation
of
edge
◤

r
r =
ˆj + mkˆ

(
沤hortest
distance
净
projection of
ˆjon ૼjˆ -
iˆ )
Რ
Რ

净
=
뜀 + Რ


n
+ ૼn



ⵔf

nⵌૼ


nⵌૼ
净
Რ


then
is
equal
to


n
- ૼn +

잘ns


傈


n
ⵌૼ
n

n - Რ傈

n -
傈
Sol

净
Რ

Þ
净
Რ


n
ⵌૼ n
n - Რ傈 n -
傈

n - Რ傈


Þ 净


n-

Þ n
净

n
+ ૼn


\

净
净


n - ૼn +

9
 Page 10

JEE (MAIN) APRIL 2023 DATE-06/04/2023 (SHIFT-1)

® ® ® ®

Რ
et
a
净

î

ૼ ĵ


k̂

b
净
î
–

ĵ
–

k̂

c 净
– î


ĵ

ૼ k̂
and d

is
a
vector
perpendicular

® ® ® ® ® ®

to
b
and
c

a
d
净
Რ

then
find
| a × d |

Რ傈 皤


傈 皤

ૼ傈 ૼ


傈 ૼ

잘ns

Რ傈

® ® ®
Sol


d 净
l b × c 傈
净
l
î
– ĵ


k̂ 傈

® ®
a
d
净
Რ

Þ
l
净

® ® ® ® ® ®
\| a
×
d |

净
a
d

–
a
d 傈

® ®
Þ
| a ×
d |

净

뜀
×
ૼ

–
ૼ


净
Რ



–
ૼ


净
皤

10
 Page 1

PHYSICS
1. Choose correct graph of electric potential for uniformly charged hollow sphere.
V V

(A) (B)
r r
R R
V V

(C) (D)
r r
R R
Ans. (D)

Sol. Theoretical

2. Choose correct graph of resistivity and temperature for semi-conductor material.

 

(A) (B)
T T

 

(C) (D)
T T

Ans. (C)

m
Sol. 
ne2 

As T increases  decreases but n increases but n is dominant over  so  decreases with increase in
temperature
1
 Page 2

3. Find moment of inertia about axis shown which is equidistant from both spheres

I =?

solid
sphere

r = 10 cm r= 10 cm
20 cm
2kg 2kg

88
Ans. (kg – m2)
500

2 2
Sol. I =  Mr 2  M  0.2    2
5 

2 
=   2  (0.1)2  2  (0.2)2   2
5 

 4 8 
=   2
 500 100 

44  2 88
=  (kg – m2)
500 500

4. A block of mass 100 g is attached with spring of natural length 20 cm and force constant 7.5 N/m. Now
system is rotated with constant angular velocity 5 radian/s on horizontal plane. Find out tension in the
spring?
Ans. 0.75 N

=5 rad/sec T

Sol.
× K
m
–+x

 = 20 cm (natural length of spring)

m = given 100 gm

k = 7.5 N/m
mw2( + x)
Kx = mw2 ( + x)
 Page 3

m2
x
K  m2
m2 K
T  Kx 
K  m2

0.1 25  0.2  7.5

T
7.5  0.1 25
7.5  0.1 5
T
5
T = 0.75 N
5. Assertion : Range is maximum at  = 45º.
Reason : Range is maximum when sin (2) = 1.
(A) Both assertion and reason are true & reason is the correct explanation of assertion.
(B) Both assertion and reason are true but reason is not correct explanation of assertion.
(C) Assertion is true and reason is false.
(D) Assertion is false and reason is false.
Ans. (A)
u2 sin(2)
Sol. R
g

For Rmax sin (2) = 1

2 = 90º
 = 45º
6. Assertion : The Moon doesn't have atmosphere.
Reason : Escape velocity of the Moon is less than that of the Earth.
(A) Both assertion and reason are true & reason is the correct explanation of assertion.
(B) Both assertion and reason are true but reason is not correct explanation of assertion.
(C) Assertion is true and reason is false.
(D) Assertion is false and reason is true.
Ans. (A)
2GM 2G 4 3
Sol. Vesc    R
R R 3

Vesc  R.
Since moon's radius is very small compared to earth.
Vesc at moon is quite low and gas molecules attains escape velocity at normal temperature on
moon.

3
 Page 4

7. For below transition of e–1 of H-atom find out shortest wavelength out of given transition
n=5
A B
n=4
C
n=3
D
n=2

n=1
(A) A (B) B (C) C (D) D
Ans. (D)
Sol. Energy from n = 4 to 1 is maximum so wavelength is minimum.

8. Find period of oscillation if mass 'm' is displaced parallel to earth's surface & released?

k1 k2
m

k1  k 2 k1 k 2 m m(k1  k 2 )
(A) 2 (B) 2 (C) 2 (D) 2
m m(k1  k 2 ) k1  k 2 k1 k 2

Ans. (C)

Sol. keq = k1 + k2 (since springs are parallel)

m m
T = 2  2
k eq k1  k 2

9. A planet has density same as that of Earth and mass is twice that of Earth. If the weight of an
object on Earth is "W" then the weight on the planet is :
2 1 4
(A) 2 3 W (B) 2 3 W (C) 2 3 W (D) W
Ans. (B)

Sol. Planet with mass M has radius R

Planet with mass 2M has radius R'

4 3
 R = M
3
 Page 5

4 3
 R' = 2M
3
1
 R' = 2 3 R

1 1
GM GM
= 2 2
 23  2 3
W
R2
2 3 R2

1
 W' = 2 3 W

d
10. When x = then capacitance is C1 = 2f
3

2d
then if x = then capacitance C2 will be (in C)
3

air
d

x k=4

Ans. (3)

1 1 1
Sol.  
Ceq Cair Cdi

1 2d d 3d
  
Ceq 3(0 A) (3)4 0 A 4A 0

4A 0
Ceq   2F
3d

A 0
 1.5F
d

1 d 2d (4  2)d 6d  A 
  = =  C'eq  2  0  = 3F
C'eq 3(0 A) (3)4 0 A 12 0 A 12 0 A  d 

5
 Page 6

11. In which condition EMF will be induced in loop.

Situation-S1 : A loop is moving with uniform velocity in a uniform magnetic field perpendicular
to its plane.
Situation-S2 : A loop is moving with non-uniform velocity in a uniform magnetic field
perpendicular to its plane.
Situation-S3 : A loop is rotating about its diameter in a uniform magnetic field.
Situation-S4 : Area of loop is changing in a uniform magnetic field.
(A) S2, S3
(B) S1, S3
(C) S2, S4
(D) S3, S4
Ans. (D)
Sol. S1, S2  Flux remains constant
S3  = BA cos  [ is changing]

S4  Area is changing  EMF induces

12. If height of antenna is increased by 21%. Find % rise in its range ?

Ans. 10%
Sol. d= 2Rh, d  h

d' 
1.21 h = 1.1 h

%tage change in d = 10%

13. E = E0 sin (t – kx)

B = B0 sin (t – kx),
then ratio of energy density of electric field to magnetic field is :
(A) 1 : 1 (B) 1 : 3 (C) 1 : 2 (D) 2 : 1
Ans. (A)
Sol. In EM wave,
Energy density)magnetic field = Energy density)electric field
 Page 7

14. A uniform current carrying cylindrical wire carries current I having radius 'a'. Magnetic field with
distance x varies with relation given :
(A) Bx for x < a
1
B for x > a
x
(B) Bx for x < a
B is constant for x > a
(C) B is constant for x < a
1
B for x > a
x
1
(D) B for x < a
x
Bx for x > a
Ans. (A)

15. An electron, proton and -particle are moving with kinetic energy 4K, K and 2K respectively.
Relation between De-Broglie wavelength is :
(A) p > e >  (B) p >  > e (C) e > p >  (D)  > e > p
Ans. (C)
h 10 20h
Sol. e  
2m 2 2mK
 4K
2000
h h
p  
2mK 2mK
h h
  
2  4m  2K 4 mK
e >  p >  

16. R1 = (15 ± 0.5) 

R2 = (10 ± 0.5) 
Find % error in equivalent resistance if resistors R1 and R2 are connected in parallel ?
(A) 5% (B) 4.33 % (C) 3% (D) 3.33 %
Ans. (B)

7
 Page 8

1 1 1 150
Sol.   & R eq   6
R eq R1 R 2 25

dR eq dR1 dR 2
2
 2  2
R eq R1 R2

dR eq  dR dR 
 R eq  21  22 
R eq  R1 R2 

 0.5 0.5 
= 6 2  2 
15 10 
dR eq  1 1  325
 %  6  0.5 100    = 6  0.5 100   4.33%
R eq  225 100  225 100

17. Two identical current carrying coils with same centre are placed with their planes perpendicular to
each other. If i = 2A and radius of coil R = 1 m, then magnetic field at centre C is equal to :
0
(A) 0 (B) (C) 20 (D) 2 0
2
Ans. (A)

Sol. B0  B12  B22

B0  2B

0 I 0  2
B0  2 = 2  0
2R 2 1

18. If the length of a conductor is increased by 20% and cross-sectional area is decreased by 4%, find
the percentage change in the resistance of the conductor.
Ans. 25

Sol. R=
A
1.2 1.25 
R' = = = 1.25 R
0.96A A

19. A car is moving with speed of 15 m/sec towards a stationary wall. A person in the car press the
horn and experience the change in frequency of 40 Hz due to reflection from stationary wall. Find
the frequency of horn. (Use Vsound wave = 330 m/sec)
Ans. 420 Hz
 Page 9

 V  VC 
Sol. f  f0  
 V  VC 
 330  15 
f  f0  
 330  15 
345
f  f0
315
f – f0 = 40
 345  315 
f0    40
 315 
40  315
f0 
30
f0 = 420 Hz

20. Which logic gate is specified by given circuit

+5 Volt

A B 


(A) AND (B) OR (C) NAND (D) NOR

Ans. (D)
A B 
0 0 1
Sol. 1 0 0
0 1 0
1 1 0

21. A block of mass 100 gm is placed on a smooth surface and is moving with acceleration of a = 2x.
 xn 
If change in kinetic energy can be given as   , find the value of n :
 10 
Ans. (2)

9
 Page 10

v x
dv
Sol. V
dx
 2x    vdv  2 xdx
0 0

v2
  x2
2
1
 mv 2  mx 2
2
x2
= (0.1) x2 =
10
n=2

22. A sphere of density  & mass m is moving down with constant velocity in viscous liquid of density
0 find out viscous force on sphere

 1 0   1  0   1  30   1  0 
(A) mg   (B) 2mg   (C) mg   (D) mg  
           

Ans. (A)

Sol. F = mg – Fb

mg
F = mg – 0


 1 0 
F = mg  
  

23. If light incident in air at an angle of incidence 45º and refracted in other medium at an angle of
refraction 30º. If wavelength in air is 1 and frequency is 1 and in medium wavelength is 2 and
frequency is 2 then correct possible options are :
2 2 1
(A) 1  , 1  2 (B) 1  2 , 1  (C) 1 = 2, v2 = v1 (D) 2  , 2  1
2 2 2
Ans. (D)
Sol. 1sin 45º =  sin 30º
= 2
 
2  air  1
 2
and frequency does not change with medium.
 Page 11

24. A wire of length 2 m, radius of cross-section 20 mm and Young's Modulus 2 × 1011 N/m is
subjected to a force of 62.8 kN. The change in length of the wire is p × 10–5 (in m). Find P.

Ans. (50)

FL 62.8 1000  2
Sol. L = = = 50 × 10–5 m
AY 3.14  20  20 10 –6  2 1011

25. In a thermodynamic process work done by gas is 1000 J & heat supplied is 200 J. Find change in
internal energy of gas?

(A) 800 J (B) –800 J (C) 1200 J (D) –1200 J

Ans. (B)

Sol. Q = U + 

 200 = U + 1000

 U = –800 J
26. A particle moves in a circular path with uniform speed v. When it turns by 90º, find ratio of
v
?
| v |

 2 
(A) (B) (C) (D) 2
2 2 2

Ans. (A)
| displacement | 2R 2v
Sol. | v | = = 
time (R / v) 
v v 
  
| v |  2v  2
 
  
27. Find out 5th orbit radius (in pm) of Li++ if ground orbit radius of H-atom is 51 pm.
Ans. (425)
Sol. r0 = 51 pm

n2
r = r0 ×
Z

52
r = 51 pm × = 425
3

11
 Page 1

CHEMISTRY
1. Predict expression for  in terms of Keq and concentration C :

A2B3 (aq) 2A3+(aq) + 3B2– (aq)

1/5 1/5 1/5 1/5
 K eq   K eq   4K eq   9K eq 
(1*)  4 
(2)  4  (3)  4 
(4)  4 
 108C   5C   5C   5C 

Sol. A2B3 (aq) 2A3+(aq) + 3B2– (aq)

C
C(1–) 2C 3C

(2C)2 (3C)3
K eq 
C
Keq = 108C45
1/5
 K eq 
 4 
 108C 

2. Radius of first orbit of hydrogen atom is 51 pm. Determine the radius of 5 th orbit of Li2+

Ans. 425 pm

Sol. rH = 51 pm

n2 52
( rH 2+)5 = ( rH )1 × = 51 × = 425 pm
Z 3
3. How many moles of Ba3(PO4)2 will be formed by the reaction of 5 moles of BaCl2 and 3 moles of
Na3(PO4).
5
Ans.
3

Sol. 3 BaCl2 + 2Na3 PO4  Ba3(PO4)2 + 6NaCl

5 mole 3 mole
5
Moles of Ba3(PO4)2 =
3
 Page 2

4. In which of the following pairs of elements electron gain enthalpy difference is highest ?
(1) Cl, Ar (2) Cl, Ne (3) F, Ar (4) F, Ne
Ans. (2)
Sol. Chlorine has most negative Heg (–349 kJ/mole) whereas Neon has most positive Heg (116 kJ/mole)

1 rd
5. In an ionic solid element Y crystallises in ccp lattice and element X occupy of tetrahedral void.
3
Find formula of ionic solid.
Ans. X2Y3
Sol. For 1 unit cell,
No. of particles
1
X ×8
3
Y 4
 Formula of Ionic solid = X8/3Y4 = X2Y3

6. The value of log10K for a reaction A B is

(Given Hº298K = –54.67 kJmol–1
Sº298K = 10 kJmol–1
and R = 8.314 JK–1mol–1
2.303 × 8.314 × 298 = 5705)
Ans. 10
Sol. Gº = Hº – TSº
= –54.07 × 1000 – 298 × 10
= –57050
Gº = –2.303 RTlog10K
logK = 10

7. Determine the amount of urea (NH2CONH2) to be added in 1000 g of water to decrease its vapour
presssure by 25%.
P  PS n 1
Sol.  
P Nn 4
 4n = N + n
 Page 3

N  1000  1
n  
3  18  3
(1000) 10000
Amount of urea is  60  gm
18  3 9
1111.1 gram

8. Which of the following slows down the process of setting of the cement ?
Ans. Gypsum

9. Number of ambidentate ligands in given complex [M(en)(SCN)4] :

Ans. 4
Sol. SCN– is an ambidentate ligand S & N both are donor atom.

10. 2[Au(CN)2]– + Zn [Zn(CN)4]2– + 2Au

(A) Redox reaction (C) Displacement reaction
(B) Combination reaction (D) Decomposition reaction
(1*) A & B (2) B only (3) A & D (4) B & D
–
Sol. 2[Au(CN)2] + Zn [Zn(CN)4] + 2Au 2–

It is a redox, displacement reaction.

11. A  Spin only magnetic moment of [Fe(CN)6]–3 is 1.73 B.M. and [Fe(H2O)6]+3 is 5.92 B.M.
R  In both cases Fe have +3 oxidation state
Ans. Both A & R are correct but R is not the correct explanation
Sol. [Fe(CN)6]–3 : Fe+3 : 3d5 with S.F.L
n=1
Magnetic moment = 1.73 B.M
[Fe(H2O)6]+3 Fe+3 : 3d5 with W.F.L
n=5
Magnetic moment = 5.92 B.M

12. Assertion: Radius of H+ is 1.5 × 10–3 pm

Reason: H+ cannot exist independently
Sol. Both assertion and reason are correct but reason is not a correct explanation of assertion.
 Page 4

13. Oxidation number of Mo in Ammonophosphomolybdate

Ans. 6
Sol. (NH4)3PMo12O40 or (NH4)3PO4.12MoO3
+3 + 5 +12x – 80 = 0
12x = 80 – 8
12x = 72
x=6

14. Which of following are reducing and oxidising agent respectively.

(1) Eu+2, Ce+4 (2) Ce+3, Ce+4
(3) Eu+4, Eu+2 (4) Tb+2, Ce2+
Ans. (1)
Sol. Eu2+  Eu3++ e–
Eu2+  Good reducing agent
e– + Ce4+  Ce3+
Ce4+ is a good oxidising agent

15. Column-I Column-II

(P) N2O5 (i) N–N bond
(Q) N2O (ii) N–O–N bond
(R) N2O4 (iii) N=N / NN bond
(S) NO2 (iv) N=O bond
Ans. P – (ii), Q – (iii), R – (i), S – (iv)
O O O
Sol. N N
O O
N N O OR N N O
O O
N N
O O
N
O O
 Page 5

16. Polymer which is named as orlon

(1) Polyamide (2) Polyacrylonitrile
(3) Polycarbamate (4) Polyethene
Ans. (2)

CONH2 Br2/KOH
17. Major product
COOCH3 

NH
(1) (2) (3) O (4)
O O
O
Ans. (2)

O
CH2–C–NH2 Br2/KOH
CH2–NH2 N H
Sol.

CH2–C–O–CH3 Hofmann bromide CH2–C–O–CH3 O
O O

18. Column I Column II

(i) Vitamin A (a) Beri-beri
(ii) Vitamin C (Ascorbic acid) (b) Cheilosis
(iii) Riboflavin (c) Xerophthalmia
(iv) Thiamine (d) Scurvy
(1) ic, iid, iiia, ivb (2) ic, iid, iiib, iva
(3) id, iic, iiib, iva (4) ic, iib, iiid, iva
Ans. (2)

19. Photochemical smog found mainly in

(1) Industrial area (2) Marshy place
(3) Hilly area of Himachal (4) Cold humid climate
Ans. (1)
 Page 6

20. Column I (Chemical reactions) Column II (Enzymes used)

(i) Glucose CO2 + Ethanol (a) Pepsin
(ii) Sucrose Glucose + Fructose (b) Diastase
(iii) Starch Maltose (c) Zymase
(iv) Protein Amino acids (d) Invertase
(1) ic, iid, iiib, iva (2) id, iic, iiib, iva
(3) ic, iid, iiia, ivb (4) ic, iib, iiid, iva
Ans. (1)

21. How many bromo products are formed when ethane is reacted with excess of Br2 on heating?
Ans. (9)

Br CH2–CH2 Br
Sol. CH3–CH3  CH3–CH2–Br + CH3–CH
Br2 / h
+ + CH3–C Br
Br Br Br Br

Br Br Br Br
+ CH2–CH + CH2–C Br + CH–CH
Br Br Br Br
Br Br
Br Br
Br
+ Br–CH–C Br + Br–C–C–Br
Br
Br Br Br

22. Match the following with the correct name of reaction

Red-P + Br2
(I) CH3–COOH (P) Gattermann Koch reaction
NaOI
(II) CH3–C–CH3 (Q) Hell Volhard Zelinsky
O

(III) CO + HCl + AlCl3 (R) Iodoform reaction

(1) (I) (Q), (II) (R), (III) (P)

(2) (I) (R), (II) (Q), (III) (P)
(3) (I) (Q), (II) (P), (III) (R)
(4) (I) (P), (II) (Q), (III) (R)
Ans. (1)
 Page 7

23. CH3CH2–Br 

NaI
Acetone
 CH3–CH2–I + NaBr

Which of the following statement is correct ?

(1) Acetic acid solvent can take in above reaction.
(2) NaI is soluble in acetone but NaBr is precipitate in acetone
(3) NaI is precipitated in acetone but NaBr is soluble in acetone
(4) When acetone is taken in solvent transition state is highly polar
Ans. (2)

O LiAlH4
(P)
NH–C–CH3
24.
Br2
(Q)
CH3COOH
Product (P) and (Q) are respectively
Br O
NH–C–CH3
NH–CH2–CH3
(1) and
Br Br
O

CH2–NH–CH3 NH–C–CH3
(2) and
Br
O

NH–CH2–CH3 NH–C–CH3
(3) and
Br
OH O

NH–CH–CH3 NH–C–CH3
(4) and
Br
Ans. (3)