‘One nictotine? ~ | pee en © a4 ©) None of these ; 2. A 1.50 g sample of an ore containing silver was dissolved. and all of the Ag ‘was converted to 0,124 g of Ag.S. What ‘was the percentage of silver in the ore? ; i | a) 641% dhy > a aes b) 7.20% 3 eae ay * d) 10.8% Ys Lg ) None of these a OS 3. What volume of hydrogen gas at 28.0°C and 675. mmtig is produced by reacting 13.8 g of Mg with excess HCI? ‘Mag(s) + 2HCi(aq) > MgClx{aq) + He) a) 147 b) 7.891, ©) 128L, @) 1S8L €) None of these 4, What is the Na’ ion concentration in the ‘solution formed by mixing 20, mL of 0.10 'M.Na,SO, solution with 50. mL of 0.30 M ‘NasPOs solution? 5 ile _ Oa af taht as enn SS at. with a gas at 3.50. alm ee ee ee septs 0.954 atm eal )> els, Oe £ & 128atm reel a8 ¢. None of these. TT 6. Which of the following represent an ‘appropriate Lewis structure of BrO2"” + be yl -. Which gas-phase atom in its ground state has exactly thre¢ unpaired electrons? a) Se b) Fe °) Co 4) Se ©) None of these e _s What is the predicted geometry of BrOy"? fe 0 Ben b) Linear 3 Trigonal planar d) Tetrahedral e) None of these"E) Nowe of these AN. The first ionization energy of Na is 498.9 os Wemol'. What is the longest wavctengih of light that could remove an electron from Na atom? D240 m 44m d) 4.14<10° m ©) None of these 18. What value is the ch for a valence electron of the calcium atom? a ») ® 9 8 here ao Page 6 of 16 9. What isthe geometry of the IBrz ion’? a) Linear ©) Mg 1) Beat with a bond angle of about 90° d) Ar ith a bond angie of about 109° i - 3 aoa tio Merson 14. Of the atoms listed, which has the largest €) None of these third ionization energy? YO.What is the ground state electron a) Ca ‘configuration of N” ion? b) Mg ¢ cA x d) Si lo 48.From a consideration of the Lewis nie | formal charges? losest estimate of Zen 1 “The What is the electron configuration for the im atom? ab [Ar] asisg* Tar) 4s'3a° Bepese?Page 7 of 16 AK In the hydrogen spectrum, what is the 23. Select the correct molecule restpcture fot of Tight associated with the n = Po." — a) 1.097 nm =~ 109 1273\, al - a (by 364.9 nm er ears 10% m = = . ™ 6x 107 m te \ 4 S , 24. Which of the following compounds en ofthe following is nonpolar’ contains only one unshared pair of valence oo electrons? cs aw sl @ xD uo \h 5 roe ye ©) CH i” a Bas d) NaCl us * cae 20. For the elements Cs, F, and Cl, the order ©) Bets e Of increasing electronegativity is 28, What is the temperature of NO; gas if the PeCl \ \ oh) fu G ‘ as \b iz Quen a CY) ocaahedral, 35 6 © Deperment of Chemisty, Sasol ot Saeage and Technology, Nazarbayev Universiy © 2016 ftPage 9 of 36 32, A reaction is found to have the rate law Rate = MAY[B). Which set of data is ‘consistent with this finding? fA] 1B] (molrL) | (moti) mn} 0010 | 0.010 0.010 0.020, 0.020 oe ee tena aD ¢) None of these 33. When sucrose, Dj, is dissolved in HO in the presence of an acid reacts according to the equation C 4+ HO =» 2 CiH4):05 with a rate Law of Rate = M{CysH:20)}. If 3.00 g of sucrose decreases 10 2.70 g in 2.50 hours in the presence of a certain concentration of an ‘acid catalyst, what is the half-life for this Teaction under these same conditions? ) 12.5 hours b) 16.4 hours ©) 23.7 hours 4) 37.9 hours €) None of these 34. Consider the reaction carried out at constant volume: $02x(g) + Oxg) = 25048). For initial concentrations of SO2 and O2 of 2.0 Mand 15 M, respectively, the equilibrium O: =~ wr a cata Department of Chemistry, School of Science and Technology, @ 390K i ) TK gee aw Alee)=; oe concentration is 0.80 M. What is the value of K, for this reaction? 3) 68 b)29 034 d)O1S ¢) None of these 38. For the decomposition of ammonia to nitrogen and hydrogen, the equilibrium constant i147 10° at 298 K. Calculate the temperature at which K= 02.38 0.01, For this reaction, AH? ‘emot ! a) 9K Oy he b) EK K ) 32K 36, The reaction betwe and gaseous iodine results in boron triiodide, Bh(g) and _hydrogeniodide, Hi(g), Hf the equilibrium constant of this reaction is 2.04 x 10° at 298K, what will be the equilibrium const (where AF? = 264.8 ki/mol and R= 8.314 Jimol.K). i s Ae atid woe Ce (E] Cp 1.15 x 10" ) 17x10" ©) None of these Ue cok MB Patbayev Universi © 2016 Th ps + Ale.)37. For the reacti 3H: +N2—2NHy AH? =-97 kiemot! ‘The Hz and No bond energies are 436 and 941 KJemor'', respectively, What is the bond energy of a single €) None of these & 38, What is the specific heat Substance if 2.41x10" When 10.00 moles of H2(g) reacts with 5.000 mol of Ox(g) to form 10.00 mol of H20() at 25°C and a constant pressure of 1,00 atm. If 683.0 KJ of heat are released during this reaction, and PAV is equal to - 37.00 ks, then AH? = +683.0 kJ and AE® = +720.0 KJ.Page 12 of 16 49. Using the values in the table below feported at 25°C, determine AH"rxm at 400°C for the hydrogenation of acetylene toethane: CoH (g) + 2 Hz (g) — CHa (2) Com met)