Yashpatil TG ~ @bohring_bot

Sec: XI-IIT-IR Date : 10-07-2023

Time : 3 Hrs. FTM – 2 Max.Marks:300

KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
B A A A C A A A C B
11 12 13 14 15 16 17 18 19 20
A A B B A A A C D D
21 22 23 24 25 26 27 28 29 30
–1 2 1 5 2 3 5 1 8 6

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
A D A A A C C B D A
41 42 43 44 45 46 47 48 49 50
C A A A C B C B A C
51 52 53 54 55 56 57 58 59 60
0 20 144 1125 4 320 2 2 2 46

MATHEMATICS
61 62 63 64 65 66 67 68 69 70
D C A C B A A D A A
71 72 73 74 75 76 77 78 79 80
C A D A A A B A A D
81 82 83 84 85 86 87 88 89 90
45 1024 -12 64 15 20 60 1 4 43
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023

Hints & Solution

iˆ ˆj kˆ
1. (B)  
A B  1 1 0
2. (A)
0 1 1
m

v = iˆ( 1  0)  ˆj ( 1  0)  kˆ(1  0)
d dm dV =  iˆ  ˆj  kˆ
 
 m V   1
= 0.8 + 0.4 | A  B | 3 , nˆ  (iˆ  ˆj  kˆ)
3
= 1.2 %
 b  MLT1 . 11. (A)
1

2
3. (A) yx
only (i) and (ii) are correct statements.  1 
4. (A) d  x 2 
   dy
1
1  2 1 1 3 / 2
c  3a  2b     x = x
dx dx 2 2
5. (C) Correct option is (A)
h = ML2 T–1
c = MºLT–1 12. (A)
f = ha cb Td y  e2 x
MLT–2 = (ML2T–1)a (L–T–1)b Td dy d (e2 x ) 2dx
a = 1, a = 1, b = – 1, d = – 2    2e2 x
2a + b = 1 dx d (2 x) dx
– a – b + d = – 2. 13. (B)
6. (A) y  sin 2
     
A BC  C  B A dy d (sin 2 ) 2d
 
d d (2 ) d
C 2  A2  B 2  2 AB cos (180  )
= cos 2 2
 A2  B 2  C 2  Correct option is (B)
  cos 1  
 2 AB  14. (B)
7.(A) 2 x  12  16  0 y = 25x2 + 5 – 10x
2 x  28 For maxima/minima
dy 1
x  14  50x  10  0  x 
dx 5
8. (A) 2
d y
 50 > 0; minima
dx 2
 1  1
ymin = 25   + 5 – 10 × = 1 + 5 – 2 = 4
 25  5
15. (A)
9. (C)
  16. (A)
Area of parallelogram  | A  B | y = x 2 cos x
10. (B) 
 dy
A B = x2(–sinx) + cos x  2x
nˆ    dx
| A B | = 2xcosx – x2 sin x

Page 2
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023
17. (A)
4
dx 4 4 27. (5)
2 x   n x 2  n 2  n2 | B |  7 2  (24 ) 2  625  25
Unit vector in the direction of A will be
18. (C) ˆ ˆ
ˆ  3i  4 j
A
3P 5
tan  
P  ˆ ˆ
  60 So required vector = 25  3 i  4 j   15ˆi  20 ˆj
 5 
19. (D) 28. (1)
ˆ ˆ  3Pi,
Pi,2Pj, ˆ  4Pjˆ If one side is x then other side will be 20-x
Resultant of all forces = 2Piˆ  2Pjˆ So area of rectangle is A= x(20-x)
For maxima /minima dA/dx =0
R 2 2 P
29. (8)
20. (D)   
  r  F  (7ˆi  3ˆj  kˆ )(3ˆi  ˆj  5 kˆ )
21. (–1) ˆi ˆj kˆ
All zero to right of last non-zero digit in a 
  7 3 1  14ˆi  38 ˆj  16 kˆ
number having no decimal point are not
3 1 5
significant so 4100 has 2 significant figure.
22. (2) 30. (6)
L 2 2
let x  2 Here  0.2    0.6   a 2 1
T
or a 2 1  0.04  0.36  0.6
x L T
 100   100  2  100  a  0.6
x L T
= 0.2% + 2  4% 31. (A)
= 0.2% + 8% CH 4  x  4  0  x  4
= 8.2% CH3Cl  x  3  1  0  x  2
23. (1) CH2Cl2  x  2  2  0  x  0
24. (5) CHCl3  x  1  3  0  x  2
Component of 2iˆ  3 ˆj along iˆ  ˆj CCl4  x  4  0  x  4
(iˆ  ˆj )
 (2iˆ  3 ˆj )  (iˆ  ˆj )
[iˆ  ˆj ]2 32. (D)
(2  3)(iˆ  ˆj ) 5(iˆ  ˆj ) Br20  Br  Reduction
 = ;x=5 5
( 1  1) 2 2 Br20  Br O5 Oxidation
25. (2) 33. (A)
[T] = [Padbtc] = [ML-1T-2]a Here
[ML -3]b [ML2T-2]c 6 4 3
 6 
Cr 2 O72   SO 2  Cr 2  S O4 
Equating power both side we get  3
a+b+c=0 4 3
–a – 3b + 2c = 0 So, Cr  Cr (Reduction)
4
–2a – 2c = 1 SO 2  SO42  (Oxidation)
Solving these equation we have  . N .  3  2  (6  2)  6
5 1 1
a   , b  and c  6 4 3 6
6 2 3 Cr 2 O72  3 SO 2  Cr 2  SO 4 
 3
26. (3)
 . N .  3  6  3  4  6
Ay 1 1
cos      Net change in oxidation number is 0.
A (1) 2  (1) 2  ( 2 ) 2 2 Now, to balance oxygen and hydrogen
  = 120°
Page 2
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023
K 2Cr2O7  3SO2  2 K   Cr2 ( SO4 )3  H 2 O 37. (C)
∵ Right side is deficient in 1 oxygen. 69.5
O  4.34 2
Now, left side is deficient in 2 Hydrogen so 16
we add 1 H2SO4 30.5
N  2.17 1
 K2Cr2O7 3SO2  H2SO4  K2SO4  Cr2 (SO4 )  H2O 14
34. (A) EF  N1O2 EFM  92
20 MFM 92
Weight of solute  400   80 g n  2
100 EFM 46
Amount of solute remaining = 80-50=30g MF  N 2 O4
Mass of solution remaining = 400 – 50 = 350
38. (B)
wsolute 30
%concentration  100   100 O.N. of N in HNO2 is +3
wsolution 350 Max. O.N. of N is +5
=8.57% Min. O.N. of N is –3
35. (A) Thus O.N. of N in HNO2 can show an
When 56 g of N2 + 10g of H2 is taken as a increase or decrease as the case may be.
combination then dihydrogen (H2)act as a limiting That is why HNO2 acts as oxidant and
reagent in the reaction. reductant both.
N2 ( g )  3H 2 ( g )  2 NH 3 ( g ) O.N. of N in HNO3 is +5,
2 14g 3 2g 2(14  3)g Hence it can act only as an oxidant.
28g 6g 34g 39. (D)
28g N2 requires 6g H2 gas. 24
C 24 2
6g 12
56g of N2 requires  56 g  12 g of H2
28 g H 4 4 4
12g of H2 gas required for 56g of N2 gas but 1
Only 10 g of H2 gas is present in option (a). O 32 32 16 2
Hence, H2 gas is the limiting reagent.
In option(b), i.e. 35g of N2 + 8g of H2. C2 H4 O2
As 28g N2 requires 6g of H2.
EF  CH 2O
6g
35g N2 requires  35 g H 2  7.5 g of H2. 40. (A)
28 g 0.0835 moles  1g H
Here, H2 gas does not act as limiting reagent since
7.5g of H2 1
1 moles  g H
Gas is required for 35g of N2 and of H2 is present in 0.835
reaction mixture.  11.97 g H
Mass of H2 left unreacted = 8 -7.5g of H2.
=05g of H2  12 g H
Similarly, in option (c) and (d), H2 does not act as 41. (C)
limiting reagent. 4 Al  3O2  2 Al2O3
For 14g of N2 + 4g of H2.
As we know 28g of N2 reacts with 6g of H2.
4 3
  2 1.5moles
For 28g of N2+6g of H2, i.e. 28g of N2 reacts with 6g 3 2
of H2 54g
(by equation I). 42. (A)
36. (C) 1 ltr Solution Contains 1170g HCl
14  1 n 1170
5.37  100 M    32
M V 36.5
=260.7 43. (A)
Facts
44. (A)
Mass of urea = 5 g
Molecular mass of urea = 60

Page 3
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023
5 51. (0)
Number of moles of urea   0.083
60 C  O2  Co2 ( g )
Mass of solvent = (225 – 5) = 220 g 12 32 44 g
 Molality of the solution  1mole  1mole  1mole
12 32 44
Number of moles of solute
1000  
Mass of solvent in gram
0 0
0.083
  1000  0.378 52. (20)
220 In CH4,
45. (C) mole of carbon = 1
Mass of substance = 0.5 g mole of hydrogen = 4
Mass of solvent = 25 g  % of carbon by mole in
 Percentage of the substance (w/w) 1
0.5 CH 4   100  20%
=  100  1.96 1 4
0.5  25 53. (144)
46. (B) 12 12 amu
Volume of alcohol = 20 cm3  144 amu
Volume of water = 80 cm3
54. (1125)
 Percentage of alcohol
E.R L.R
20
  100  20 2H 2  O2  2 H 2O
20  80
47. (C) 100 g 100 g
Molarity of Cl– = 3 (molarity of FeCl3 100
M  M 2
 3  
 30  10 100
48. (B)  50moles
32
nH 2O  nNaCl  n
 moles
Moleofsolute n 0
m  1000
wt.ofsolvent (kg ) n 18
2 100
1 
  1000  55.55m 1 32
18
100
49. (A)  moles
XA n 16
Mole fraction of A i.e.  A 100
X H 2 O nH 2 O   18
16
nH 2 O
So X H 2O   112.5 g ``````
Total moles 55. (4)
XA n E.R L.R
Now  A
X H 2O nH 2 O A  2B  C
and molality 5 8 
n  1000 X A  1000 0.2  1000
 A    13.9 5 8 1
nH 2O  18 X H 2O  18 0.8  18 L.R  8  4 moles
1 2 2
50. (C) 56. (320)
Molarity S  O2  SO2
98  10  1.84
  18.4M 5 moles  1 5  5Moles
Gmm
 5  64
(% w/ w)(d) 10
{M  } (d in g / ml.)  320 g
Mol. mass ofsolute

Page 4
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023
57. (2)  120  30  90
1
67. (A)
ab bc
ICl3 I  3 Given b2  ac, x  ,y 
2 2
x  (1)  3  0 a  1 Consider
x3 2 a c 2a 2c 2a 2c
    
58. (2) x y  a  b   b  c  a  ac ac  c

6.02  1022 1  a c
 2 2
 23
  0.2  a  c 
6.02 10 1/ 2  
H2 68. (D)
Mole = M  V Since the numbers are in A.P.
100  10–3 = 0.8  V  28 = 32 sin 2 –1 + 34 - 2 sin 2
V = 0.125 9 sin2 81
or 28   sin2  , where x = 9sin 2 
59. (2) 3 9
2
120 Or x  84x  243  0
M or (x – 81) (x – 3) = 0  x  81 or 3
60
(1000  120)  x  9sin2  81,3 or 92 ,91/2
 103  2 M
1.12  sin 2  2 or1/ 2
60. (46) since sin 2 cannot be greater than 1 so we
Mole fraction of H2O = 1 – 0.25 = 0.75 choose
X C2 H5OH nC2 H 5OH 1
 sin 2 =
X C2H 5OH  X H 2O nC2 H5OH  nH 2O 2
Hence the terms in A.P. are
or 30 , 14, 27 i.e. 1, 14, 27.
0.25  46  T5  a  4d = 1 + 4.13 = 53
wt.%   100  46%
0.25  46  0.75  18 69. (A)
61. (D) The given sum S = (x + y) + (x2 + xy +y2)
n( X  Y )  n( x )  n(Y )  n( X  Y ) +.......
= 28 + 32 - 50 = 10 1
62. (C) x  y  x 2
   
 y 2  x 3  y 3  x 4  y 4  ....  
We can write the given equation as
1
 1 1  1  1  1 ........... 
log 2  x 2 4 8 16 4 x  y  x 2
 
 x3  ....  y 2  y 3  .... 
 
 log 2  x 2   4  x 2  2 4  x  4 1  x2 y2 
  
63. (A)  x  y  1 x 1 y 
A    n  A  0 1  x 2  y 2  x 2 y  xy 2  x  y  xy
  
n  P  A    2 n  A  2 0  1 xy 1  x 1  y   1  x 1  y 
64. (C) 70. (A)
If the numbers by x, y, z then  3, 2   R
1/x = log23,1/y = log2 2.3 = 1 + log23, 71. (C)
1/z = log2 (4 × 3) = 2 + log2 3 which are in A.P. n  A  B   n  A   n  B  n  A  B 
 x, y, z are in H.P.
65. (B) We have, 70  37  52  n  A  B 
4+5=9>8, 5+4=9>8, 5+5=10>8 72. (A)
66. (A) Since AM  HM
n     200, n  C1   120, n  C2   50, xyz

3
3 1 1 1
n  C1  C2   30  
x y z
n  C1  C21   n  C1   n  C1  C2 

Page 5
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023
a 3 1 1 1 9 2c
  or      2A  r  1 d
3 1 1 1 x y z a r
 
x y z Multiply (i), (ii) and (iii) by q – r, r – p and p – q
73. (D) respectively and add
We given, a5  a20  a1  a24 ,a10  a15  a1  a24 a
  q  r   0
Hence the given relations reduce to, p
3  a1,  a24   225 , giving a1  a 24  75
79. (A)
Since a and b are unequal,
Hence S24= a2  b2
n  a 2b 2
  a  l    24 / 2  a1  a24   12  75  900 2
2 (A.M. > G.M. for unequal numbers)
74. (A)  a2  b2  2ab
A B A B 2 Similarly b 2 + c 2 > 2bc and c 2 + a 2 > 2ca
2 
AB 2AB H Hence 2 (a 2 + b 2 + c 2 ) > 2 (ab + bc + ca)
2 2n  ab  bc  ca  1
 E  1  1  1  ...  1  80. (D)
H H
75. (A) B  C  {4}
n  AB   n  A  B   n  A  B  81. (45)
30
1
 n(A)  n(B)  2n  A  B  =50 S   Ai  n ( S )   5 30  15
i 1 10
76. (A) n
1 n
Let r be the common ratio then b = ar, c = ar2 and Again,S   B j  n (S )  (3  n)  .
logca, logbc, logab are in A.P. j 1 9 3
loge a loge c loge b n
, , are in A.P Thus  15  n  45
loge c loge b loge a 3
loge a log a  2loge r loge a  loge r 82. (1024)
So , e ,
loge a  2loge r loge a  loge r loge a Given t3  ar 2 4
are in A.P Product of first terms =
loge r
Putting x (a)(ar )(ar 2 )(ar 3 )(ar 4 )  a 5r 10
loge a
We get  (ar 2 )5  45  1024
1 1  2x 83. (-12)
, ,1  x are in A.P a+ ar = 12; ar2 + ar3 =48
1  2x 1  x
2 1  2x  84. (64)
1
  1  x   2
2n  n
1  x  1  2x 
85. (15)
 2x 3  3x 2  3x  0
n (A  B C )= 5, n (B  A C )= 6, n (A  B) = 4
since a, b, c are distinct so , so
 2x 2  3x  3  0 n (A) = n (A  B) + n (A  B C ) = 4+5 = 9
1 1 n (B) = n (A  B) + n (B  A C )  6  4  10
4
 
x  3  33 then 1  x  
1  2x 
3,
n (A  B) = n (A) + n (B) - n (A  B)
so the common differences of A.P. is 3/2. 86. (20)
77. (B) Let the numbers be a, ar, ar2 and sum = 70
both x and y are odd  a (1  r  r 2 )  70  (1)
78. (A)
p it is given that 4 a, 5ar , 4 ar 2 are in A.P
Sp  [2A  p  1 d]  a
2
2a
  2A  p  1 d …..(i)
p
2b
  2A   q  1 d ….(ii)
q

Page 6
 Yashpatil TG ~ @bohring_bot
Narayana IIT Academy XI_IIT _IR _ FTM – 2_10/07/2023
 2(5ar )  4a  4ar 2  5r  2  2r 2 3
  2  12t  3, ( where t  3x )
 2r 2  5r  2  0  (2r  1)( r  2)  0 t
1  3  2t  12t 2  3t 12t 2  5t  3  0
 r =2, put r =2 in (1), than a=10
2   4t  3 3t  1  0
1 3 1 3
put r = in (1), then a = 40  t  ,  3x  3x  0 
2 4 3 4
 The numbers are 10,20,40 or 40,20,10.  3
 x  log 3    1  log 3 4
 4
87. (60)
n (S  F) = n (S) + n (F) - n (S  F) 90. (43)
. n (C) = 21, n (H) = 26, n (F) = 29,
 n (S  F) = 20 + 50 -10 = 60 n (H  C) = 14, n (H  F) = 15
88. (1) n (F  C) = 12, n (F  C  H) = 8
(1,3) need to be adjoined to make the relation
Total no. of players = n (C  H  F) = 43
transitive
n
Thus 15  n =45
89. (4) 3
1
1, log 3 (31 x  2), log3 (4.3x  1) arein A.P
2
 log 3 (31 x  2) 1  log 3 (4.3 x  1)
 log 3 (31 x  2)  log3 3  log 3 (4.3x  1)
 log 3 (31 x  2)  log3 3(4.3x  1)
 (31 x  2)  3(4.3x  1)
 3.3 x  2  12.3x  3

Page 7