Advanced Test – 01 (Paper – 1) Arjuna JEE (2023) 11/09/2022

CHEMISTRY

SECTION-A 11. Select the correct statement(s)

Integer Type (Numerical Value) (1–8)
1. A given sample of pure iron gains 10% of its weight
on partially rusting to form Fe2O3. If the fraction of
the iron converted to Fe2O3 is ‘x’, then the value of
30 times ‘x’ is (Fe = 56)
12. For which sets of elements, “diagonal relationship”
2. A proton and an electron, both at rest initially,
combines to form a hydrogen atom in the ground
state. A single photon is emitted in this process. The
wavelength (in nm) of emitted photon is
3. Calculate the effective nuclear charge for the
outermost electron of oxygen atom.
13. In which of the following arrangements is/are the
4. If there were 8 periods in the periodic table and each
orbital could have maximum 5 electrons, then how
many maximum number of elements would be
present in period 8?
5. Calculate the effective nuclear charge for a 3d-
electron of nickel atom.
(1) Size of H– is larger than F–
(2) Rb is more electropositive compared to Ca
(3) Na+ is more electronegative than Na
(4) Cl– is more electronegative than F
exists?
(1) B, Si
(2) Li, Mg
(3) B, Mg
(4) Be, Al
order correct according to the property indicated
against it?
(1) Increasing size: Al3+ < Mg2+ < Na+ < F–
(2) Increasing I.E.1 : B < C < O < N
(3) Increasing E.A.1 : I < Br < F < Cl
(4) Increasing metallic radius : Li < Na < K < Rb

6. Based on VSEPR theory, the number of 90° 14. Which of the following molecule(s) is/are having
F—Br—F angles in a molecule of BrF5 is pyramidal structure?
(1) PCl3 (2) XeO3
7. How many maximum atoms of IF7 are present in the
same plane? (3) NH3 (4) PCl+2

8. The compound MX6 is octahedral. Find the number

SECTION-C
ˆ − X 90° angles in the compound.
of X − M
Matrix Match Type (15–18)
SECTION-B 15. A volume of 50 ml of the hydrocarbons given in
Column I is burnt completely at 400 K and 1 atm
One or More than One Correct Type (9–14)
and the volumes of products formed at 400 K and 1
9. A quantity of 0.22 g of a gas occupies a volume of atm are given in Column II. Match the hydrocarbons
112 ml at pressure of 1 atm and temperature of 273 (Column I) with the suitable products (Column II).
K. The gas may be
Column-I Column-II
(1) nitrogen dioxide
(2) nitrous oxide (I) CH4 (P) 100 ml of CO2
(3) carbon dioxide (II) C2H6 (Q) 100 ml of H2O
(4) propane (III) C2H4 (R) 150 ml of H2O
(IV) C3H4 (S) 150 ml of CO2
10. The energy of an electron in the fi rst Bohr's orbit of
H-atom is –13.6 eV. The possible energy value(s) of (T) 50 ml of CO2
the excited state(s) for electrons in Bohr's orbits to (1) I → Q; II → R; III → P; IV → S
hydrogen is (2) I → Q,T; II → P,R; III → P,Q; IV → Q,S
(1) –3.4 eV (2) –10.2 eV (3) I → P; II → R; III → Q; IV → S
(3) –1.51 eV (4) −0.85 eV (4) I → Q,T; II → P; III →; IV → S
16. Match the columns. 17. Match the columns.
Column-I Column-II Column-I Column-II
(I) Orbital with equal number (P) 3d 2 2 (I) Zinc (P) Solid at room temperature
x −y (II) Hg (Q) Transition element
of radial and angular nodes (III) Cr (R) d-block element
(II) Orbitals with number of (Q) 2pz (S) Liquid at room temperature
radial nodes less than the (1) I → P,R; II → R,S; III → P,Q,R
number of angular nodes (2) I → R; II → S; III → Q
(III) Orbitals with zero radial (R) 3px (3) I → S,R; II → P,S; III → Q,R
nodes but two angular (4) I → P,R; II → Q; III → S,R
nodes
(S) 5dxy 18. Match the columns.
(1) I → S; II → R,P; III → Q Column-I Column-II
(2) I → P; II → Q,P; III → S (I) sp-hybridization (P) CO2
(3) I → R,S; II → Q,P; III → P (II) sp2-hybridization (Q) CS2
(4) I → R; II → S; III → P,Q (III) sp3-hybridization (R) SnCl4
(IV) sp3d-hybridization (S) NO3−
(T) AsF5
(1) I → R,S; II → P; III → R; IV → Q
(2) I → P; II → Q; III → R; IV → R
(3) I → R; II → P; III → Q; IV → S
(4) I → R,S; II → Q,P; III → P; IV → T
 ANSWER KEY

10. (1, 3, 4)
1. (7)
11. (1, 2, 3)
2. (91.17)
12. (1, 2, 4)
3. (4.55)
13. (1, 2, 3, 4)
4. (125)
14. (1, 2, 3)
5. (7.55)
15. (2)
6. (0)
16. (3)
7. (6)
17. (1)
8. (12)
18. (4)
9. (2, 3, 4)
 Hints and Solution
1. (7) 9. (2, 3, 4)
3 0.22
2Fe + O2 → Fe2O3 Molar mass of gas =  22400 = 44
2 112
consider 100 gm
x 10. (1, 3, 4)
(100 – x) → 
2 n = 1
 x 1  n2
(100 − x) + 56 160  2 = 100
 
x = 0.233 11. (1, 2, 3)
H– > F– [true]
2. (91.17) [larger]
(1, 2, 3) all are correct statements.
1240
= = 91.17 nm
13.6 12. (1, 2, 4)
B and Mg do not show diagonal relationship.
3. (4.55)
O : 1s22s22p4 13. (1, 2, 3, 4)
 = 5 × 0.35 + 2 × 0.85 = 3.45 IE1 of N > 0, due to half-filled nature in N.
Zeff = 8 – 3.45 = 4.55
14. (1, 2, 3)
4. (125)
Possible subshells are present in the 8th period: 8s 7d
6f 5g 8p
Total electrons = 5 + 25 + 35 + 45 + 15 = 125

5. (7.55)
Ni : 1s22s22p63s23p63d84s2 15. (2)
Zeff = 28 – 20.45= 7.55 At 400 K and 1 atm, H2O will be in vapour form.
CH4 + 2O2 → CO2 + 2H2O(g)
6. (0) 50 mL 50 mL 100 mL
BrF5 due to L.P. repulsion, 90° bond angle will be
zero. 16. (3)
Orbital Radial nodes Angular nodes
7. (6) 3d 0 2
IF7  pentagonal bipyramidal [sp3d3] 2p 0 1
3p 1 1
8. (12) 5d 2 2

17. (1)
Zn and Hg are not transition elements because in
their ground state and in the most stable oxidation
state configuration, “nd” is completely filled.

18. (4)

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