| Section Examination on Molecular Spectroscopy Course ( form D ) department: “| Name: Choose the correct answer: 1. The mass spectrum of 2-bromopropane showed the following peaks at M/Z : 2.122, 107,43 b,122,107,45 © 124, 122,109,107,43, d.124,122,109,107,45,43 2. The ration of intensities between M and M#2 in 2-chloropropane is: bat 13 a33 3. The IR (m-1 ) spectra for phenol & cyclohexanol show absorption bands for c-o bond stretching at wavenumber v tale peal ac > that for cyclohexanol, L a ee Z b) for phenol < that for cyclohexanol ~, ©) for phenol = that for cyclohexanol phenol The oxygen nature of organic sample with molecular formula CnHmO that showed neither bands at ©1700 nor broad bands at =2550- 3400 em-1 may be: a.ketonic b. Alcoholic eric d.Aldehydic 5. Intramolecular hydrogen bonding to C=0 results in: in the wave number of the ‘wave number of the C=0 stretch stretch Calculate the Amax of the following compound : MM 6. A. 287m 8. 385 nm ~A 290m oe D. 327mm ° Calculate the Amax of the following compound : A a) 210nm : v b) 318nm s 2 a K Y ¢) 323. am 7 \q d) 328nm chs - at eL 8. How many signals are observed in the H-NMR of monophenyl acetylene: FX ad b2 63 Oa cHSCOCW ECR c Hel » What are the expected multiplicity of the following compound CH3COOH(CL)CHCI2 : oO adita b. sda @sa asta OW, t-c v 0. Which of the following nuclei can not give NMR spectrum: a.13¢ 7 19, d.31p Best wishes ©) ©) _c| Cc CamScanner 2 92 4>g.uaall