Kinematics Classes Deoria

Lic - 2 near Star hospital Raghav Nagar Deoria

Sample set - 01
CLASS 12 - CHEMISTRY

Time Allowed : 180 mins Maximum Marks : 70

General Instructions:
Read the following instructions carefully.
i. There are33 questions in this question paper with internal choice.
ii. SECTION A consists of 16 multiple - choice questions carrying 1 mark each.
iii. SECTION B consists of 5 very short answer questions carrying 2 marks each.
iv. SECTION C consists of 7 short answer questions carrying 3 marks each.
v. SECTION D consists of 2 case - based questions carrying 4 marks each.
vi. SECTION E consists of 3 long answer questions carrying 5 marks each.
vii. All questions are compulsory.
viii. Use of log tables and calculators is not allowed.

Section A Column I Column II

(a) Hypertonic (i) NaCl.

(b) Hypotonic (ii) Solution having

1) The reaction given below:
higher osmotic
pressure than other
is called: solution.
[1]
(c) Isotonic (iii) Solution
having lower
a) None of these osmotic pressure
b) Wurtz - Fittig reaction than other solution.
c) Wurtz reaction
d) Fittig reaction (d) Electrolyte (iv) Solutions
having same
osmotic pressure.
2) The helix structure of proteins is stabilized by:
[1]
a) Disulphide bond b) Peptide bond [1]
c) Van der Waals forces d) Hydrogen bond a) (a) - (ii), (b) - (iv), (c) - (iii), (d) - (i)
3) The conversion of an alkyl halide into alcohol by aqueous b) (a) - (i), (b) - (ii), (c) - (iii), (d) - (iv)
NaOH is classified as c) (a) - (iv), (b) - (iii), (c) - (ii), (d) - (i)
[1] d) (a) - (ii), (b) - (iii), (c) - (iv), (d) - (i)
7) Toluene reacts with a halogen in the presence of iron (III)
chloride giving ortho and para halo compounds. The reaction
a) A dehydrohalogenation reaction is
b) A substitution reaction [1]
c) An addition reaction
d) A dehydration reaction a) Nucleophilic substitution reaction
b) Free radical addition reaction
c) Electrophilic elimination reaction
4) For making a distinction between 2 – pentanone and 3 – d) Electrophilic substitution reaction
pentanone the reagent to be employed is: 8) Which of the following is a strong oxidising agent?
[1] (At. No. Mn = 25, Zn = 30, Cr = 24, Sc = 21)
a) K2 Cr2 O7 /H2 SO4 b) SeO2 [1]
c) Zn – Hg/HCl d) Iodine/NaOH a) Cr3+ b) Mn3+
5) Which among the following is an example of photochemistry c) Zn2+ d) Sc3+
used in our daily life? 9) The reaction2A → B is first order in A with a rate constant
[1] of 2.8 determining 10–2 s–1 . How long will it take for A to
decrease from 0.88 M to 0.14 M?
[1]
a) In photography a) 76 s b) 44 s
b) In inversion of cane sugar c) 66 s d) 50 s
c) All of these
10) The reagent which does not react with both acetone and
d) In decomposition of hydrogen peroxide
benzaldehyde.
[1]
6) Match the items given in column I with that in column II: a) Sodium hydrogensulphite
 b) Phenyl hydrazine a) Both A and R are true and R is the correct explanation
c) Fehling’s solution of A.
d) Grignard reagent b) Both A and R are true but R is not the correct expla-
nation of A.
11) An organic compound containing oxygen, upon oxidation
c) A is true but R is false.
forms a carboxylic acid as the only organic product with its
d) A is false but R is true.
molecular mass higher by 14 units. The organic compound
is . Section B
[1]
a) A ketone b) A primary alcohol 17) i. Write the IUPAC name of the following complex:
c) An aldehyde d) A secondary alcohol [Co (NH3 )5 Cl]2+
ii. Write the formula for the following complex:
12) Which of the following compounds is the weakest Brönsted Potassium tetrachloronickelate (II)
base? [2]
[1] 18) Assign reason for each of the following:
i. Transition elements exhibit paramagnetic behaviour.
ii. Co2+ is easily oxidised in the presence of a strong
ligands.
a) [2]
19) Answer the following: [2]
(a) Define rate of reaction?
[1]
b) (b) Identify the order of reaction from the following rate
constant:
k = 2.3 × 10−5 L mol−1 s−1
[1]
c)
20) What happens when
i. A pressure greater than osmotic pressure is applied on
the solution side separated from solvent by a semiper-
d) meable membrane?
ii. Acetone is added to pure ethanol?
13) Assertion: Fructose has a total of 16 optical isomers. [2]
Reason: There are total of 3 asymmetric centers.
[1] OR

a) If both Assertion and Reason are right and Reason is
the right explanation of Assertion.
b) If both Assertion and Reason are right but Reason is
not the right explanation of Assertion.
c) If Assertion is right but Reason is wrong.
d) If both Assertion and Reason are wrong.
State Raoult’s law for a solution containing volatile compo-
nents. Write two characteristics of the solution which obey
Raoult’s law at all concentrations.
[2]
21) Write the reagents required in the following reactions :
i. CH2 =CH - CH2 OH −→ CH2 =CH - CHO
?

ii. CH3 - COOH −→ CH3 - CONH2 .

?
14) Assertion (A): The α - hydrogen atom in carbonyl com-
pounds is less acidic. [2]
Reason (R): The anion formed after the loss of α - hydrogen Section C
atom is resonance stabilised.
[1] 22) Calculate the emf of the following cell:
Zn (s) | Zn2+ (0·01 M) || (0·001 M) Ag+ | Ag (s)
a) Both A and R are true and R is the correct explanation Given : E⊖ = - 0·76 V and
Zn2+ /Zn
of A.
E⊖ = +0·80 V
b) Both A and R are true but R is not the correct expla- Ag+ /Ag

nation of A. [log 2 = 0·3010, log 3 = 0·4771, log 10 = 1]

c) A is true but R is false. [3]
d) A is false but R is true. 23) A reaction is of first order in reactant A and of second order
in reactant B. How is the rate of this reaction affected when
15) Assertion (A):KCN reacts with methyl chloride to give methyl i. The concentration of B alone is increased to three times?
isocyanide. ii. The concentrations of A as well as B are doubled?
Reason (R): CN– is an ambident nucleophile. [3]
[1] 24) Explain why is ortho nitrophenol more acidic than ortho
methoxyphenol?
a) Both A and R are true and R is the correct explanation
[3]
of A.
b) Both A and R are true but R is not the correct expla- OR
nation of A.
Draw the structure and name the product formed if the fol-
c) A is true but R is false.
lowing alcohols are oxidized. Assume that an excess of
d) A is false but R is true.
oxidizing agent is used.
16) Assertion (A):With HI at 373 K, ter - butyl methyl ether i. CH3 CH2 CH2 CH2 OH
gives ter - butyl iodide and methanol. ii. 2 - Butanol
Reason (R):The reaction occurs by SN 2 mechanism. iii. 2 - methylpropanol
[1] [3]
25) Predict the products of the following reactions: (a) What will happen if a plant cell kept in a hypertonic
H N −N H2
i. CH3 − CH | CH3 = O −−2−−−−−→ ? solution?
ii. C6 H5 - CH3 −−−−−−−−−−−→ ?
(i)KM nO4 /KOH (b) Blood cells are isotonic with 0.9% sodium chloride solu-
+(ii)H tion. What happens if we place blood cells in a solution
containing in 1.2% sodium chloride solution?
(c) What happens when the external pressure applied be-
iii.
comes more than the osmotic pressure of solution?
[3]
26) Conductivity of 2× 10 - 3 M methanoic acid is 8 × 10 - 5 OR
S cm–1 . Calculate its molar conductivity and degree of
(d) Which mechanisms helps in the transportation of water
dissociation if Λom for methanoic acid is 404 S cm2 mol - 1 .
in a plant?
[3]
27) Discuss the mechanism of SN 1 reaction of haloalkanes. Section E
[3]
28) i. Write two advantages of H2 - O2 fuel cell over ordinary 31) Attempt any five of the following: [5]
cell. (a) What are the products of hydrolysis of sucrose?
ii. Equilibrium constant (Kc ) for the given cell reaction is [1]
10. Calculate E ◦cell . (b) Which of the two components of starch is water soluble?
A(s) + B 2+ (aq) ⇀
↽ A2+ (aq) + B(s)
[1]
[3]
(c) What are polypeptides?
Section D
[1]
29) Read the text carefully and answer the questions: The transi- (d) Define the following term: Anomers.
tion metals when exposed to oxygen at low and intermediate [1]
temperatures form thin, protective oxide films of up to some
thousands of Angstroms in thickness. Transition metal oxides (e) What is the difference between a glycosidic linkage and
lie between the extremes of ionic and covalent binary com- a peptide linkage?
pounds formed by elements from the left or right side of the [1]
periodic table. They range from metallic to semiconducting (f) Write the full forms of DNA and RNA.
and deviate by both large and small degrees from stoichiom- [1]
etry. Since d - electron bonding levels are involved, the (g) Of the two bases named below, which one is present
cations - exist in various valence states and hence give rise in RNA and which one is present in DNA?
to a large number of oxides. The crystal structures are often
i. Thymine
classified by considering a cubic or hexagonal close - packed
ii. Uracil
lattice of one set of ions with the other set of ions filling the
octahedral or tetrahedral interstices. The actual oxide struc- [1]
tures, however, generally show departures from such regular 32) Give the oxidation state, d - orbital occupation and coor-
arrays due in part to distortions caused by packing of ions dination number of the central metal ion in the following
of different size and to ligand field effects. These distortions complexes:
depend not only on the number of d - electrons but also i. K3 [Co(C2 O4 )3 ]
on the valence and the position of the transition metal in a ii. Cis− [Cr(en)2 Cl2 ] Cl
period or group. [4] iii. (N H4 )2 [CoF4 ]
(a) Why does copper, which is in first series of transition iv. [M n(H2 O)6 ] SO4
metal exhibits +1 oxidation state most frequently? [5]

OR OR
(b) Crystal structure of oxides of transition metals often Write the IUPAC names of the following coordination com-
show defects. Given reason. pounds:
(c) The lowest oxide of transition metal is basic. Why? i. [Co (N H3 ) 6] Cl3
(d) The variability in oxidation states of d - block different ii. [Co(N H3 )5 Cl] Cl2
from that of the p - block elements. Explain. iii. K3 [F e(CN )6 ]
iv. K3 [F e(C2 O4 )3 ]
30) Read the text carefully and answer the questions: Many
v. K2 [P dCl4 ]
chemical and biological processes depend on osmosis, the
vi. [P t(N H3 )2 Cl (N H2 CH3 )] Cl
selective passage of solvent molecules through the porous
[5]
membrane from a dilute solution to a more concentrated one.
33) Give reasons:
The osmotic pressureπ depends on molar concentration of
i. Aniline does not undergo Friedal - Crafts reaction.
the solution (π = CRT). If two solutions are of equal solute
ii. Aromatic primary amines cannot be prepared by
concentration and, hence, have the same osmotic pressure,
Gabriel’s phthalimide synthesis.
they are said to be isotonic. If two solutions are of unequal
iii. Aliphatic amines are stronger bases than ammonia.
osmotic pressures, the more concentrated solution is said to
[5]
be hypertonic and the more diluted solution is described as
hypotonic. OR
Osmosis is the major mechanism, for transporting water up-
ward in the plants. Transpiration is the leaves supports the i. Write one chemical reaction for each
transport mechanism of water. The osmotic pressure of sea- i. Carbylamine reaction
water is about 30 atm; this is the pressure that must be ii. Acetylation reaction
applied to the seawater (separated from pure water using a ii. Write structure of N,N - ethylmethylethanamide
semi - permeable membrane) to get drinking water. [4] [5]