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03 - MetE 414-Steelmaking 2 - Fall 2023
03 - MetE 414-Steelmaking 2 - Fall 2023
Steelmaking-2
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CaO + S → CaS + O
CaC2 + S → CaS + 2C2
Mg + S → MgS
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Approximately 30% of
the charge is scrap steel,
which is added to control
the temperature, and to
recycle steel.
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BOF OXYGEN LANCE
The oxygen lance, its design and blowing program related to blow velocity and lance height program plays
an important role in oxygen converting, affects the rate and oxidation order of iron melt constituents,
formation of iron droplets and their emulsification in the slag, slag foaming, splashing and sculling
phenomena. Lance tip and nozzle design play an important role in maximizing the control over the blow
but also in extending the lance life. The formation and stability of slag foam during the blow is greatly
dependent on oxygen jets from the lance. The lance design and control of blowing rate and lance height
during the blow play an important role in the refining of iron melt from impurities, but affect also
postcombustion degree and refractory lining wear. The lance tip of a typical modern oxygen lance consists
of 4–7 nozzles. Supersonic oxygen jets through the nozzles form cone streamline with expansion angle
from 20 to 30.
There are various lance designs
focusing to increase the
postcombustion of CO by blowing
oxygen through nozzles directed
to furnace atmosphere instead of
iron bath surface.
Oxygen flow rate is normally on a
level 6–10 m3 min-1 ton-1 of iron
melt and oxygen pressure 1–1.5
MPa. Service life of oxygen lance
is typically 400–600 heats.
Schematic presentation of LD/BOF
with conventional lance (a) and with
lance provided with postcombustion 7
nozzles (b).
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MAIN REACTIONS IN BOF
In basic oxygen steelmaking, the main targets are to decrease the carbon content of the liquid metal to
the required level and to reach the end temperature appropriate for further treatment of the steel.
These two targets are usually imposing the blowing practice.
Additionally, minor components (Si, Mn, P, Ti, V, etc.) in the metallic charge tend to oxidize forming
oxides, which then form slag jointly with burnt lime and other fluxes added into the converter.
Formation of slag and foaming slag–metal–gas emulsion are very essential phenomena in the converter
process.
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STEELMAKING:
ELECTRIC ARC FURNACE (EAF)
Most of the electric arc furnaces use alternate current (AC). Nevertheless, in the 1990s,
active interest was targeted at development of direct current (DC) EAFs. The drivers were
less electrode consumption, less energy consumption, and less flickering.
Not all the expectations of the DC EAFs were met. The benefit of lower electrode
consumption is offset by the higher specific cost of large diameter electrodes. Some of the
anode designs have had a short life. The chopper technology had higher losses, higher
equipment costs, lower reliability, and excessive maintenance cost compared with
thyristor rectifier.
(1) Transformer, (2) flexible cable connection, (3) electrode arms, (4) electrodes clamping, (5)
arms, (6) cooled off-gas duct, (7) cooled panels, (8) structure, (9) basculating structure, (10)
rack, (11) cooled roof, (12) basculating device, and (13) hydraulic group. 12
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The refining step usually does not require full power, which with already flat bath could be dangerous
for the lining. At that time, the foaming of the slag is a must. For the slag to foam, the production of
CO gas is necessary, by means of the injection of carbon and oxygen through lances or burners. For
foaming purposes, several carbonaceous materials are useful, depending on local cost and availability:
anthracite, petroleum coke, coke breeze.
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REFINING IN EAF
For most steelmaking operations, refining in the EAF is limited to dephosphorization, decarburization,
and temperature adjustment. Phosphorus in the charge could be at higher than usual levels for DRI,
HBI, pig iron, and hot metal, depending on the iron ore source. Some steels require particularly low P
levels to avoid too high ductile/brittle transition temperature or tempering brittleness. From the
equilibrium point of view, lower temperatures, high slag basicity, and high oxidation of the bath favor
dephosphorization. Slag/metal interaction is important from a kinetic point of view but is not always
attainable in the EAF.
Decarburization is carried out as a refining task. If the charge is 100% scrap, carbon in the metallic
charge should be relatively low. This is not the case when charging a high percentage of DRI (if
produced in a gas-based unit), HBI, pig iron, or hot metal, with carbon contents between 1.6 and 4.5.
Usually, due to productivity reasons, steelmakers prefer to achieve a carbon content of around 0.05
before tapping. Lower contents may imply a too high oxidation level.
Oxidizing Stage:
❑ As soon as the liquid metal forms, oxidizing stage starts. At this stage
excessive carbon, phosphorous, silicon and manganese oxidize.
❑ Also oxygen can be blown at this stage.
❑ Basic oxidizing slag which is composed of CaO (lime) and FeO is used.
❑ What is slag? A molten mixture of oxides on the top of liquid iron.
Removal of Phosphorus:
❑ The oxides formed are absorbed by the slag. The removal of phosphorus is
at this stage.
❑ If the slag containing P is not removed, then it may return back to liquid
steel.
❑ Why phosphorus must be removed?
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SECONDARY STEELMAKING:
LADDLE FURNACE PROCESS (LF)
The ladle furnace (LF) makes it possible
to divide the steel melting operations,
carried out in EAF, from those of treatment
and refining. The liquid steel produced by
the EAF is poured into the ladle, which
serves as a reactor for metallurgical
operations at the treatment stations. The
ladle is transported under the LF hood,
where alloying and reheating operations are
performed to target values for the next
process station.
Steel, when poured into a teeming ladle, has
an oxygen content of 0.04-0.1 wt%. This would
cause blow holes if the steel were allowed to
solidify.
• This is removed by adding aluminum,
ferrosilicon, or carbon to precipitate the
oxygen as part of a condensed oxide.
• When aluminum is the deoxidizing agent the
steel will have fine grained tendencies;
this is attributed to the very fine distribution of
aluminum oxide which acts as nuclei to
promote a fine grained structure. 19
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REFINING IN LF - I
❑ Molten steel in a ladle may be treated (refined) in a device called Ladle
Furnace (LF).
❑ The ladle is transported to the Ladle Furnace stand where it is placed
under a cover equipped with three graphite electrodes.
❑ There is a porous ceramic plug at the bottom for argon supply.
REFINING IN LF - II
Reducing Stage:
❑ New slag composed mainly of lime (CaO), CaF2 (as slag fluidizer) is added
at this stage for formation of basic reducing conditions. Basic slag is a slag
containing mainly basic oxides: CaO, MgO, MnO, FeO.
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DEOXIDATION OF STEEL - I
❑ The dissolved oxygen in steel will yield a poor quality ingot.
❑ Therefore, the oxygen must be taken out with the help of elements which
have a higher affinity for oxygen: Aluminum and ferro-silicon
Al + O >>> Al2O3 Si + O >>> SiO2
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DEOXIDATION OF STEEL - II
❑ Other de-oxidation elements used: Mn, Ca and Ce. These reactions cause
formation of fine ceramic particles. It is expected that the non-metallic
inclusions flow to the surface, i.e. to the slag.
❑ Then diffusion de-oxidation can help. When the oxygen activity in the slag
is reduced oxygen ions dissolved in steel begin to diffuse from the steel
into the slag, and the equilibrium conditions are restored. In other words,
deoxidation of slag results in deoxidation of the steel. Carbon (coke),
silicone, aluminum and other elements are used for slag deoxidation.
https://www.youtube.com/watch?v=k_mfMFKrsTI
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ALLOYING OF STEEL
Common Alloying Elements in Steel, Their Influences, and Applications
Chapter-1-6---Secondary-Steelmaking_2014_Treatise-on-Process-Metallurgy 25
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VACUUM DEGASSING (VD)
Vacuum degassing is a procedure that is used to improve the internal cleanliness of steel after the initial
melt has occurred. The principle of the process is to reduce the atmospheric pressure above the liquid
steel in the vacuum remelt furnace. The pressure over the molten steel is reduced to approximately 1 mm
of mercury (Hg). Generally, the vacuum degassing furnace is fitted with a vacuum-tight lid over the molten
steel, and the degassing procedure is started.
This method of cleaning the steel will not remove all of the potential gaseous impurities present, but it
will remove approximately 50% of the gaseous impurities down to a level of approximately 30 ppm of
oxygen and down to approximately 2.5 ppm of hydrogen.
The RH process (Ruhrstahl–Heraeus) is Schematic of RH degassing and
literally a circulation process: it has two tank degassing equipment
snorkels or legs. Steel from the ladle is
raised along one leg to the vacuum
chamber and then it falls back through
the second leg into the ladle after short
degassing passage over the bottom of the
vacuum chamber.
Ladle degassing is principally the easiest
way to make vacuum treatment. There
the ladle is put inside a vacuum chamber
(tank) or alternatively there is vacuum-
tight lid set on the ladle. Anyway vacuum
is pumped inside the space so that the
ladle top is under vacuum.
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REMOVAL OF GASES IN VD
❑ The ladle is put in a vacuum environment, so that the dissolved gases like
O, N, H can be taken out.
❑ This means that less amount of de-oxidation additives and much cleaner
steel
Argon Treatment:
❑ Argon gas is blown into the ladle. The gas bubbles act as nucleation agent
for the dissolved gases. De-oxidation is carried out. It also helps stirring
the liquid steel
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EFFECT OF HYDROGEN IN STEEL
Why Hydrogen is harmful?
1. If the hydrogen content of the molten steel exceeds the solubility limit of
hydrogen in solid iron, the hydrogen will be rejected during solidification,
and this leads to pinhole formation and porosity in steel.
2. Just a few parts per million of hydrogen dissolved in steel can cause
hairline cracks (flakes), hydrogen embrittlement, hydrogen blistering and
loss of tensile ductility, particularly in large steel castings ingots, blooms
and slabs.
https://www.youtube.com/watch?v=ey0q-N57ngQ
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INGOT CASTING PROCESS CYCLE
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STEEL INGOT TYPES BASED ON STEEL DEOXIDATION - I
Depending on the amount of gas evolved during solidification, three types of steel ingots can
be produced: killed, semi-killed, and rimmed.
I. Killed Steel. Killed steel is a fully deoxidized steel; that is, oxygen is removed and the
associated porosity is thus eliminated. In the deoxidation process, the dissolved oxygen in
the molten metal is made to react with elements such as aluminum, silicon, manganese,
and vanadium that have been added to the melt. These elements have an affinity for
oxygen and form metallic oxides. If aluminum is used, the product is called aluminum-
killed steel. The term killed comes from the fact that the steel lies quietly after being
poured into the mold.
II. Semikilled Steel. Semi-killed steel is a partially deoxidized steel. It contains some porosity
(generally in the upper central section of the ingot), but it has little or no pipe. As a result,
scrap is reduced. Although the piping in semiskilled steels is less, this advantage is offset
by the presence of porosity in that region. Semi-killed steels are economical to produce.
III. Rimmed Steel. In a rimmed steel, which generally has a low carbon content (less than
0.15%), the evolved gases are only partially killed (or controlled) by the addition of other
elements, such as aluminum. The gases produce blowholes along the outer rim of the
ingot--hence the term rimmed. Rimmed steels have little or no piping, and they have a
ductile skin with good surface finish. However, if they are not controlled properly,
blowholes may break through the skin. Furthermore, impurities and inclusions tend to
segregate toward the center of the ingot. Thus, products made from this steel may be
defective, and thorough inspection is essential.
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STEEL INGOT TYPES BASED ON STEEL DEOXIDATION - II
IV. Capped Steel. Production of capped steel is a variation of rimmed steel production
practice. The rimming action is allowed to begin normally but is then terminated after
about 1 minute by sealing the mold with a cast-iron cap. In steels with carbon content
greater than 0.15%, the capped ingot practice is usually applied to the production of
sheet, strip, wire, and bars.
Killed steel marked N°1, semi-killed steel marked N°2, capped steel N°5, and rimmed steel N°7.
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https://www.youtube.com/watch?v=d-72gc6I-_E
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TYPES OF CONTINUOUS CASTING MACHINES (CCMs)
1. Simple vertical casters
2. Bent casters with straight mold (“vertical bending casters”)
2.1. with bending and straightening of the solid strand
2.2. with bending while there is liquid inside the strand and straightening with the solid strand
2.3. bending and straightening while there is still liquid inside the strand
3. Bow-type casters with curved mold
3.1. with straightening of the solid strand
3.2. with straightening while there is still liquid inside the strand
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SEMI-FINISHED PRODUCTS OF CONTINUOUS CASTING
Type dimensions of continuously cast semi-finished products
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ROLLED PRODUCTS
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REDUCTION RATIO DURING ROLLING
• Rolling, the most widely used deformation process, consists of passing a piece of metal
between two rolls; a reduction in thickness results from compressive stresses exerted by
the rolls
https://www.youtube.com/watch?v=6xnKmt_gsLs
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PROS VS. CONS OF OPEN DIE FORGING
OPEN-DIE FORGING PROS
• Little or no tooling cost
• Reduced lead time
• A variety of size options, from a few centimeters to nearly 100 feet
https://www.youtube.com/watch?v=XTU0Z-FkhtU 45