Scribd Logo
Upload

Welcome to Scribd!

  • 8 views

    UV Visible Spectroscopy Notes - ChemContent

    Uploaded by

    naveen

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content

    You might also like

    UV Visible Spectroscopy Notes - ChemContent

    Uploaded by

    naveen
    8 views22 pages

    Copyright

    © © All Rights Reserved

    Available Formats

    PDF or read online from Scribd

    Did you find this document useful?

    Is this content inappropriate?

    Report this Document

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    8 views22 pages

    UV Visible Spectroscopy Notes - ChemContent

    Uploaded by

    naveen

    Copyright:

    © All Rights Reserved
    Download as PDF or read online from Scribd
    Flag for inappropriate content
    Download as pdf
    of 22
    W-vrsieLe spectro Scopy Exectromagnetic Radtation. Chauntevag UH) Vaccum i a midi OV ge 08 _ Mialige. z 2 @) 2es-loo nm Weo-see nm Peuivity > Stuctwu dutenminesion a) UU ant Gur) Rater t Suensisieccsion 2 OME) Role LHpic] aby ditecton CQuantitatlve Analysis) gor c modaculs so give UV- vibr Spectr Jt Shoutd Juttdiid dio Smposttant Condition. “t) It Showd Pome a Chaormetophoe C Trani sion] iy Thott Shoutd be change Gp the Electronic clipata moment dining Qnienection @ife motecutle with FMR- selection Pile} F book Te [eotouy (updated 23! The chytomo phos. uo ct 4uncttonad Gawup usnich can nt apronuiig] pbrenved tnt ight dom OV cend visibse 20Nge* —er : a SEE aa n-at a 2 200m ' w on =} vaceturn UV ‘eet, oot {n=} 9pm Enegy > hon The Chowmophosie wite be function gswup ustuich can Liew abaasiption band dua to n—n# and m—K* freinniltion. - Bince A-oF , anf p n—on® deonnittons Suqutsed stooleert don. 03 vi <200nm , % fhagncanccecumnR| tremotecue tthe Gisoh, Hoxane canbe Utilize Oh & SOdvect in Uy visk Spectro Scopy. 3x2 : © Hance Uv-vis specroscopy us podmau SS? ot oubos. omd Conjugatid doula Bene with omd wlthotee Ye non Bondi ng, Etodtren ca ‘ 7o=0 Chen¥ FORE tre} ace) Parameters OF UV-VIs, SPECTROSCOPY UT Nor OF ABSORPTION BAND IN UU-Vrs. REGION /RENGE W DEPENDENT &) INDEPEN DENT pre ‘. Cand : i oo Dependent Chotomo phose En dlapenclar Chrromophore & A modocule can give mote ton one adsosipHon Signo forom lb fFerwuct dBpericlent omd | Gnolependst Chreormopneste pomeut ip He moodecuse, Excepted . ; to ushowbrostpstion Aignod ou Net Sixeds 800 yoo coe : tp ¥ most Gntense pups tne ususlly We Merect OS epee Trnpor tant ctbiotpaion signad e om j Anobysta- Jos. Quarttertiv 4 Quounti fotlve Aneugst & Post TroON | OF. SEGNALS!> she positon oy Bigneds db Uveules Lpe Known ar” Ajmax ¢ tn Ranometer- 4 : i _. The wave Wangth @t Which fue molecule abso maximum Nor of Photons: The jinx fosr ce pescticuton tmotecute can be menusod by Cobtertnad) maoniyung Khe Abrostbance of diliuk SoUrbion at Affect Wavelength + Pevex As the value of Amox Siveh Gnfrrmation abet the Envgy Gap bi Alsctromic Snovy “vets clus “tp. Congugation tre Erungy Gerp byw Blecdroruic Envy caved leosuoenihe, Steaultting Hue Shesuases the Prax [ Red Dritt, Batnochstomic sheer] congiyation Tes Cote of Subrance ‘Tes Fisanciein »(Rea ©) INTeNsrry oF SrqwAts!- The gntemity oy dignas ty ckimectay amocitited with pomniGinity op Fle chronte dromattion. thot mecena selection Sule > SPIN SELECTION RvE ES TON RULE 2 SymmETRY. SeLEC the Sntennityy og L2ynag can be expsiemed eee Lopgiciee bees of Malose cub Aosthsivity oot Lxtenaton CAFTEES Absosbanre of @ Sotuticn having. Conc: Lmage Per Lebre cub opticat path Langth Lom. 30 AbtempHon. coet#icvent lel Binte the eabsostbance 4 moteatle tr governed by Abaoxptton Jour [ Ce Bees - Lambe outa] So we fin meonuxe matoor Ab sompitivity 04 Sample OG Mmosncute thing cline Kotution ot Singse wave Lenyth - Cuimitation + cy -pinutics tii trae chorommetic aegict BESO AMnbent4 9, : 9 Vo-4m sotutton 24oom Omg) « " O56r= C.to 3x) Oiser to © = 562 mot Lt emt > The freeman meyor olectding facto for igh emd dow cibavsipitivity ub selection sue. Selection Sule t= Electronic tramition € ‘oO Spin fone bidden. Not allowed Lio-3] 6 Symmetsty fosebidder. wot ® Allvwed Lot = (05 Singtue to Singdet —» pin attowed Aingtt sto hiNUt 9 Spin -fonbbidden. TI-N* symmety quowed N= AE symmetry fusubidden Cay AL non Bmding Rf Anii Bonedeng, xf) symm Merion Teh eA, Oncentugated System Le fran et stl of moteaue 217 uncon’ @ FA Range adl7 N= AR > 225-200 nm [eow Amayd TI—A* 4 200-250 nM CHAN) Anas] molt BUR Amax Same sf el of ak Absompity A et clifferenctan FR tad # Dug dy Higheltfference uh +u2 moist cbaosbititity pH enciacte gounsi n-a* and aA-n* ttamitton cow differ iy. “Even tray hove Close vel of Amax- Symmesites 2 Setotiion Rude fallow aad ie Wat > Synmety abloured “hey > Symmemry forsbidiedd As the Symmemy oF Motecute cheesey due’ do dirtesuston on Stee Henchance , Motor cobnvovpitivity, for - N* ccsucnes erd N- A Incoucnes- Rotery peste : : foot Conmugated Adkenes.crnd Censugatia’SC=D Compounds "He Expected. Amay can be Caltuloeetd “on Hee henie og Wood wand -fischen Suule. pipatie moment (From #1 8) s Ph Ip Ph / Tr 1 ; ae Binteacked Geome od n-aF " eee gon No Stesue Hindeanre CPssuoR? jesus Hindrance ¢ Mon Masner3 € 2 430000 € - door : Uv-vies Lpeckrostopy uo dre most cyppowociaete Jachnique fer the cis and bans gaiuivencs on the bonis vg di FRexonce din tho Gbrorbance Hesieleut= : Hate a os ome oy tome bm pypercroremee SLE i L Hyperchsiemie Shirt _—9 Red shift Cpathwennert Hrysocmernt isnt | Wi FA) H(etue shir) pbserbance we Ruble dor: Jpaaie / parent system Butacltens ~S ausaatien system Hy c CQ) é Ga Gudaaien system - Butacien System Mo.Laend.s— AG terrae ZI SE eee eee eCeSeace Cy cule Areyouic p—t—_, . Homo anmueot, ... Hetero annul > Exo cycite > Endo Cycle cloubts Bond oD Homo annul Reteuo annueot CO. Exo Cyclic ex? Hee “4 - Qde Fro endo ee Endo T D., EXO R ing Resiclue Aakye Go1oup Buda-di ena * 2 Hetero Ryttictort > LExO- : Lendo - > 3 Ring Residue LAER Govup WE Rus for bienes cmd Todenes () Base Valu foy Butaciens - 914 nm TAcyoLe) : ® Homo Aptuaian ctteno > gngnm @ Hetero Annular cliers 9 215-nm IMmcswamaukts Adee Substidided oF Ring Reriduac + +5 Exccyctic double Bond +5 : Eater conyugated clouble Bond » +30 pet doubts Bond Bani’ 9 Retere cinuteor = 215 3Ring Resictu’ = 18 2 Aokye tte L Exo = 5 Teel amas == gle hm eerste ane ur An Osiganic — HYdsocanbones modecute Shows Strong cubsonbance ot 2U5 nm whith us the ‘most PStobabte Sdvuctune- w co & 215 +20+10 = 245nm 21S + 1545 = 25M © CO ® CO ' 2SQH20F10.= 283 psg¢ los 263 Compounds WE Putt for qe B UnSaterretted Comborys 5 ketones = 2I5RM Cy Foor Six membored Cyctse ss # Unscunescut O. fx =cHg—k 8 ft x= cs aism Mist Abs nm y= OW,OR 19FDM @ fos Five memberted Cyetic ketone s = 2o2nm

    Exo cloubts Bond = tS Extra. cbwte Bond = 430 Ring Revicuus / Adkye Group = Preece Aa +10 Bo +12 L> 18 fo 18 MY Extra doubt, Bond Un also ma'eing Homoaneuton Sung +hon ncoummout ey +39 wit be Olppticceb de culong with +30- Oui A Ketone wor Iknown to: ~Rave ’ one eg Tsomerie géuctwe Biven below ste ~ the Compounds Shows ‘max. Qu nm in GHson Uhich un +he poribte &ructuse: Qerticgiidqi = 23enm~ @ i a = NO Conjugation Sp Not apptieible for WE Rule » NO conmtigeution for WF Rule CHe : Hey yar 18, Erte 30 __— 295 ag Bad nr Bad nm When thew coe Mose thon One for XB unsoturaisd Corbon Hemo? nordeting, opHon for co He Bonic System ety Setoct He Ayste Renidusl valut sv Ring, Ruricluc- we Pave m having, hégniss Nov oy Alkye Gnoup omd BY = 215 B= 12FID eee : “7 .238nm “Bw = go= ts pe Vers 16 Extras BO Hemeannultr = 39 ieee hoes 324 nm- eee a SowveNnT EFFECT © mo ‘jhe potooty oF 7 yt and_ A CMa waned / cet be tp Fhe, Sotiowing ender Pounscity oder n>w>T Tes, posbouny. otyeut the gnterrect¥on Cd Non- Boneting. Gn Poesence og Bosect S cutting fue movetimurn Stet getton ostbitad > imum SH oy Non- Bondin gq ergy Duvets —— q Non-posoor Satvent = > CPoseut Sadvent) RBuwe Shire ENE 1. “. Non. podese a / “Postar Satveut | ~ Le >e J CRed Shiry) .. 4 obsenved for n- 7 dransition, Blue 2héfe Can be ent System, By changing Non- potevi to . Pott Sou y ybsewed hy fos W—n® dransition, Red Shirt mn be oO Somvert Systemr changing Non- padinr cto potovt _ ENS TRUMEN TATION (2 UV. Specdvum’ photometer U2 Composed ON Fontowing Pefenence component = [Senee}—{] Mone Cho meter Sowice ~O0 Hy dmogen Jounp “b er uv or Hydsiogen clischage Jatmp ® butewdum Lamp 2fUv ®& Tungston Lamp . 4 for Vxs- “Tongston Hoogen Lemp O Zenon Asie Lamp 5 for Both. Monochowmertoy > *® Poutsm B Rotating Psutsm * GG Steuttiing A Ne } eae / \ sear Yoo | Diamond -Gstettt'ng 5 Monten -Covrertting, u Mote inpertive pow eT Detector i> : the mon Detectos; for Uv-vts Spectro photome! © do = : : GW) Photo- dlode. detector. ti) Photo- cUlode clrurenge detector [PBA] > Range 3 fei Benzene and lexivaetves Amax for i td Sh. Genusat dhe. Bands fer Bengene sing cou. cust st co “ty Paria ‘amd B Bands - pootcl Bands con. be obsenued ot only, ond Ly2eonm fer un congugctted system: o Band > Q5onm- 280m | € > 2eo-teor] Para. Band > Qoonm— 2250 [er en seme]

    You might also like