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Manufacturing Notes For Revision
Manufacturing Notes For Revision
Advantages of FORMING
1. Fast way of changing the shape of the part
2. Usually done using cheap raw materials on a strength-to-
weight basis (mild steel)
Cold Working
- Plastic deformation < recrystallisation temp
- Material is work hardened
- Work hardening: ↓ the recrystallisation temp
- Grains are elongated in the same direction of the Cold Work
Hot Working
- Plastic deformation > recrystallisation temp
- Material is annealed
*Anneal is to heat a metal and then let it cool at a specific rate, removing impurities,
increasing metal ductility and reducing its hardness*
- Upper limit is technically melting point
- Ideal temperature should be low to minimize oxidation (metal oxides are brittle,
leaves poor surface finish)
- Grains are broken up and reformed as smaller grains (recrystallize) due to heat input
- Final grains are non-directional
0.80 – 0.90 Agricultural steels, knives, spring steels, punches and dies,
chisels, rivet sets, shear blades, rock drills, music wire,
mower blades
0.90 – 1.00 Springs, knives, dies, music wire
1.20 – 1.30 Files
1.30 – 1.40 Saws, boring tools
Cast Iron 2.0 - 4.0 Engine cylinder blocks, cylinder sleeves, exhaust extractors,
piston rings, machine tool base, lamp posts, medals
Cold Working
Advantages Disadvantages
- ↑ Strength in the direction of cold - Some metals too brittle
work - Work hardening makes subsequent
- ↑ Surface hardness operations difficult
- ↑ wear resistance - Large parts + high strength metal
- Good dimensional tolerances and alloys need much time & energy to
surface finish (finishing operations work
not needed) - ↓ Corrosion resistance, ↑ electrical
- Small parts can be shaped quickly resistance, changes magnetic
- No heat required properties
- Needs subsequent annealing to
relieve stress caused by work
hardening
- ↓ Strength in the direction
perpendicular of cold work
Hot Working
Advantages Disadvantages
- ↓ danger of metal cracking - Steels with Sulphur are brittle when
- Can work larger sections, shapes hot (need to add manganese)
without ruptures and tears - Weaker than Cold Working (in the
- For brittle metals (Zn, Mo, Mg, W) direction of the cold work) as work
- Grain refinement possible to hardening achieves higher strength
produce tougher material from 3 - Oxide layer
steps - Dimensional control difficult
1. Grain growth as ↑ temp 1. Metal contraction
2. Small grains produced at 2. Oxide scales on surface
recrystallisation temp - Expensive, high maintenance,
3. Grain size controlled by dangerous
controlling temperature - Requires accurate temp control due
- No strain hardening, no annealing to uneven heating
(cheaper) - Lubrication required
- Less power needed, can use smaller - Loss of carbon from environment to
machines the workplace
- Repairs casting defects (blow-holes, - Dies are expensive: required to be
porosity) made of tungsten/ molybdenum hot
- Improves ductility as material working steels
becomes more homogenous
1. Better diffusion of alloy
constituents
2. Breaks up and distributes more
evenly brittle films/ particles of
hard constituents
- Faster than cold working
Directional Properties:
- Differences in strength, electrical resistance, magnetic properties, hardness,
corrosion resistance in metals with different directions.
- Due to cold working
- Annealing (heating above the recrystallisation temp) will cause differences to
disappear, making directional properties even
Annealing:
- Elimination of directional properties
- Elimination of phase change effects
- Stress relief (tempering if controlled)
Small Rolls
Advantages Disadvantages
- Cheaper to replace than large rolls - Weaker than larger rolls
- Can be produced from tungsten - Can be made from Cast iron, cast or
carbide (harder and more wear forged steel
resistant compared to steel) - Cold rolls are smoother to give
smooth finish. Hot rolls are rougher
- Rolling Procedure:
i. Soak hot ingots in puts to achieve uniform temperature through the metal
ii. Hot roll into blooms (cross-section > 15cm^2), billets (cross-section 4-15cm^2) or
slabs (6-40mm thick)
*Material must be below a certain thickness before can be cold rolled*
iii. Decide if hot-rolled or cold-rolled product is desired
iv. If cold rolled product is desired, wait for metal to cool to room temperature
v. Clean the surface by pickling the metal in acid to remove oxide layer, wash with
acetone, before rolling the metal down to the desired thickness at room
temperature.
Extrusion
- Metal (billet) is forced to flow and take on the shape of an opening, called a “die”
- Similar to toothpaste squeezed out of an opening of a tube
- Extrusion diameter > 10mm
- Steel can be extruded but rolling uses less energy
- Must be done hot
Direct extrusion:
- Forward extrusion (metal is squeezed in the same direction as applied force)
Indirect extrusion:
- Backward/ reverse extrusion (metal emerges from the die in opposite direction to
the applied force)
- No friction between billet and cylinder walls
Impact extrusion:
- Sudden blow of a punch
- Ideal for soft metals like Aluminum
- Copper & Copper alloys need to be heated up to 600 deg C (hot impact extrusion)
Hot extrusion:
- Metal is preheated to just below melting point to lower yield strength
- Equipment needs to be preserved as it is subjected to high temperature
- Lubrication required:
i. Low temperature: Mg, Al, Cu Alloys
Oil/ graphite mix
ii. High temperature: Steel
Molten glass
- Useful for making long pieces of uniform cross-section (and generally Aluminum-
based sections)
- Maximum cross sections:
i. Aluminum: 60cm circular diameter
ii. Steel: 15cm circular diameter
- Economical way to produce small parts in large quantities
Cold extrusion:
- Done at room temperature
- Needs to be completed fast as metal gets hot due to work hardening
Hydrostatic Extrusion:
- Extruding Brittle metals
- Achieving high reduction of cross-sectional areas
Tensile Drawing
- Secondary process after Hot extrusion or Hot rolling
- Applications
i. Reduce the cross-section of bars and tubes
ii. Produce high performance bars and seamless tubes of High Strength &
Straightness
- Must be done Cold (If done hot, material will not be able to withstand tensile force
and break longitudinally into two pieces)
- Mainly for ductile materials in tension (Al, Cu, Cu alloys)
- Gives rise to directional properties (done below recrystallisation temp)
- Higher tensile strength (in direction of drawing)
- May result in surface defects
- Lubricant needs to be used:
i. Molybdenum Disulphate (function under tremendous pressure)
- Limits:
i. Soft materials & Hollow: Al or Cu alloys
10cm diameter
ii. High tensile strength & Solid: Medium/High carbon steels
30mm diameter
- Procedure:
i. Hot rolled stock is de-scaled and cleaned by pickling in acid to prepare it for
drawing
ii. Leading end of the piece is tapered for insertion through the die and pulled
through
iii. Pressure against the die > yield strength of work material
- Dies: The mold to produce the desired shape (nozzle)
i. Tensile drawing dies must be made of hard, strong, wear resistant material
(hardened alloy steel, cemented carbide, tungsten carbide, cubic boron
nitride, diamond)
ii. Reduction in cross-section area per mass < 40%
iii. If reduction in cross-section area per mass > 40%, need successive passes
iv. Mandrel is needed to create central hole for hollow tubes
Forging
- Metal is deformed by sudden blows, like a blacksmith making weapons, or using a
very high pressure to squeeze it between dies
Forging
Advantages
- Durable
- Reliable
- Strong, Tough, High fatigue strength, High Surface Hardness, High wear resistance
- Dense
- Applications:
i. Crank shafts, connecting rods, knives, forks, spoons, keys
- Flow lines:
i. Squeezing action forces metal to flow in certain directions
ii. Fibrous structure created (not the same as directional property, which can be
removed by annealing)
iii. To remove fibrous structure, metal needs to be melted and casted again
iv. Similar to cold roll:
Strength & Ductility increases significantly along these lines of flow
- Die:
i. Closed:
Force applied to entire surface of the part (stamp the whole area)
Metal flow into the cavity (holes & craters), restricting sideways
motion of the workpiece
ii. Open:
Compressive forces are applied locally on different parts of the metal
stock (press multiple areas one by one)
- Equipment:
i. Primitive method of forging is smith forging (hand forging) where the hot
metal part is manually hammered on an anvil
- Types of forging:
i. Hammer forging:
Uses hydraulic hammer
ii. Drop forging:
Using kinetic energy from high height dropped on a stationary anvil
iii. Press forging:
Pressure is used to squeeze cold or pre-heated workpiece to shape
Usually hydraulically operated, mechanical for small pieces
iv. Upset forging:
For non-uniformed cross-sectional area (Bolts, nails, rivets, gear
blanks)
Compression along its length
Upsets the preheated metal by exerting an axial pressure
Degree of upsetting of the stock at a certain portion is controlled by a
shaped cavity in the gripping die
v. Roll forging:
Reduces cross-section of short lengths of bar stock to make levers,
axles, drills, leaf springs
Cross section is change/ Thickness is reduced
Stock length increases
Similar to rolling but the stock doesn’t completely pass through the
rolls
Drop Forging
Advantages
- Superior mechanical properties due to fibrous structure
- High rate of production
- High density of product
- Cheaper
Press Forging > Drop Forging
Advantages
- Smoother Surface
- Better tolerances and accurate dimensions
- Good penetration of pressure
- Quieter
- More uniform structural quality
- Fast, automate, large scale production
- Allowance: difference between the resulting hole and the punch diameters
i. When a hole is punched, plastic deformation will occur in the sheet metal
ii. Resulting hole < Punch
- Types of Sheering:
i. Blanking: After punching with a circular punch, we take the circular part
Blanked part must be larger than the punch by the allowance
ii. Piercing: After punching a square sheet with a circular punch, we take the
square with the circular hole part
Pierced hole is smaller than the punch by the allowance
iii. Stamping: both blank and pierce
iv. Shearing: Cut in a straight line or curve across a strip, sheet or bar
Welding
- Melting the liquid metal over area that needs to be joint or applying pressure
- Ideally, joint part should be indistinguishable
- Perfect welding is hard due to surface oxide layers (except in vacuum)
- Types of welding:
i. Fusion welding: Melt the metal so that the two parts to be joined flow into
each other
ii. Pressure welding: Compress parts together either hot or cold to cause plastic
deformation
iii. Fusion welding with filler: Used in most engineering applications
- Choice of filler rod:
i. Should be same composition and cooled at the same slow rate for
homogenous weld
- Weld zone will cool faster because it is hotter
- Heat Affected Zones: the area near the welded part
i. Overheated Zone (>1000 deg C)
ii. Annealing Zone (900-1000 deg C)
iii. Transition Zone (700-900 deg C)
- Welding Steel: If carbon content > 0.3%, fusion zone may be brittle due to
martensite (Requires heat treatment)
*Steel can be joint using riveting, bolting with fasteners, adhesives, interference fits*
*Drawing can be done after welding, but a particular grade of stainless steel must be used
that is low in carbon and very ductile*
Welding
Defects
- Dimensional Defects:
i. Warpage (distortion due to thermal stresses)
ii. Incorrect weld size and profile (due to poor welding technique)
- Structural Defects:
i. Porosity (Gases released in the metal)
ii. Inclusions (Oxides, slag)
iii. Incomplete fusion of parent metal (insufficient temperature, poor manipulation
of heat source, inadequate removal of oxide films)
iv. Lack of penetration (binding metal needs to penetrate and root itself within the
pieces that it is binding)
v. Cracking (lack of pre-heating or post-heating causes cracking and chipping)
vi. Surface defects (holes / irregularity)
Advantages Disadvantages
- Quick & Convenient - Dependent on human factors
- Permanent & Strong (skilled workmanship, consistency)
- Light (no bolts and nuts) - Clean surface needed
- Easy to make prototype - Fixtures needed (hold parts
- Cheap (no need to machine) together during welding process)
- Does not interrupt stress flow - Defects are common
design - Heat treatment needed
- Almost all metals can be welded - Quality control methods need to be
implemented to check for defects:
i. Visual inspection (not reliable)
ii. Radiographic inspection
iii. Supersonic inspection
iv. Holographic inspection
- Welding Flux: Powder, grains or paste to protect the weld joint from atmosphere
during welding
i. Separates molten metal with atmosphere
ii. Remove impurities
iii. Slag blanket
iv. Stabilizes the arc
v. Reduces Oxides
vi. Forms plasma for the arc current
vii. Reduces splatter of the weld metal
viii. Electrical Insulation to the electrode
ix. Adds alloying elements to the weld
Gas Welding
- Oxygen & Acetylene supply connect to flame
Gas Welding
Advantages
- Equipment is cheap, portable & versatile
- No electrical supply needed
- Can weld thin sheets (< 2mm) because temperatures <<< arc welding
Arc Welding
- Uses an Electric arc between electrode and workpiece
- Electrode:
i. Doubles as a filler rod (provide filler material)
ii. Filler melts
iii. Electrode must be advanced enough to maintain the arc gap
- Can achieve temperatures of 6000 deg C
- Rod should be coated with flux (powder, paste or neutral gas form)
- Arc stream:
i. Electrical discharge through a path of ionized particles (plasma)
- Applications:
i. Thickness > 2mm
ii. Faster welding (localized heating) with greater penetration depth
iii. Materials with high heat conductivity (Al & Cu Alloys)
Friction Welding
- Rotating shaft is chucked in a lathe, pressed against a stationary metal blank
- Friction heats up the shaft/ blank interface
- Rotation stops, leaving metallic joints to cool and get welded together
Friction Welding
Advantages Disadvantages
- Can join dissimilar metals - Only for welding round sections that
- Fast can be clamped (shafts & pipes)
Resistance Welding
- Electrodes press the parts together and carry electricity through them
- Electrodes must have lower resistance than the workpiece
- Applications:
i. Sheet metal of the same thickness
ii. Workpieces of higher resistance to concentrate heat
iii. Able to weld two different types of metals together (prone to weld defects
and galvanic corrosion)
- Types of resistance welding:
i. Spot welding:
Resistance welding 1 spot at a time
Spot welding aluminum is hard as Al is a good conductor of electricity,
Al oxide formed hinders electrical conduction, Copper electrodes alloy
with Al easily, wearing out quickly
ii. Seam welding:
Form a water-tight or air-tight seal to form a continuous seam
Resistance Weld
Advantages Disadvantages
- Heat is localized - Initial equipment cost can be high
- Fast - Difficult to join sheets of different
- No filler metal needed thicknesses
- Easily automated for large scale
production
*Casting does not produce a “Seam” – which is for welding, but produces a “Parting Line”
instead*
*
Sand Casting
- Uses a furnace to melt the metal
- Any metal that can flow easily can be sand casted
- Grain size and properties can be controlled by adjusting cooling rate
Sand Casting
Advantages Disadvantages
- No limit to the size of mold (can - Rough surface due to sand mold
produce large parts) - 1 mold for 1 cast
- Cheap - Slow process (NOT for large scale
- No directional properties production)
- Can produce complicated shapes - Poor dimensional tolerances (metal
- Produces almost finished shape shrinks on solidification and then
(little machining required, just for again on cooling)
dimensional accuracy and smooth
surface)
- Defects Causes:
i. Badly prepared pattern
ii. Poor Design
iii. Poor casting technique
- Defects:
i. Blow hole: A cavity at cope surface
Formed by evolved gas that cannot flow through the mold
ii. Scar: A shallow blow
Occurs on flat surface (blows occur on convex surface)
iii. Blister: scar within a thin layer of metal covering it
iv. Porosity: Small holes throughout the entire casting
Present within the dendritic network of the cast microstructure
v. Drop: irregularly shaped projection on the cope surface
Results from a cavity formed in the cope surface
Caused when the vibration of the cope causes sand to break loose
vi. Inclusions and dirt:
If in large quantities may weaken the material
vii. Wash or cut: Low projection in the drag occurring in bottom gated castings
Too much metal flows through one gate and molding sand are not
hard or wear resistant enough
Eroded sand becomes dirt in the casting
*Problem with sand casting steels is not the high melting point but that molten steel doesn’t
flow well*
*Steels are difficult to die cast as die needs to have higher melting point than steel –
Commonly using graphite as it is cheap*
Centrifugal Casting
- For casting Large Pipes but mainly hollow objects
- The mold is rotating, so the molten metal is casted on the walls of the mold, forming
a hollow shape
Centrifugal Casting
Advantages
- Centrifugal castings are of finer grain size because of fast cooling (tougher)
- Cleaner castings (slag and dross segregate towards the inner radius which can be
removed afterwards)
- Highly dense structure (defect free)
- Automation available
- Can cast pipes accurately
Continuous Casting
- Metal is melted in a furnace before allowed to solidify in a water-cooled rotating
graphite mold (low friction)
- Cast metal moves down continuously at a rate controlled by take-up rollers
- Continuously casted metal can be hot rolled into products immediately after
solidification
- For Cu & Cu alloys, all steels, Zn, Al & Al Alloys, Cast Iron
- Applications:
i. Make blooms, billets, slabs without having to cast ingots first
Continuous Casting
Advantages
- Fully automated
- Molds/Dies are relatively cheap
- Porous, unsound & impure castings can be recycled (no wastage)
- Physical properties and surface finished are usually adequate for immediate
application
- Quick and convenient process to prepare metals for secondary hot-working
operations (Rolling, extrusion, forging)
- Secondary operations can utilize existing heat in solidified metal
Investment Casting
Advantages Disadvantages
- Extremely good surface finish - Expensive method
- Can cast complicated shapes - Castings cannot be too large
- No need to machine subsequently
(especially for steels and hard alloys
that are hard to machine)
- Wide range of alloys can be
investment casted (Steels, Bronze,
Nickel-based alloys, titanium
magnetic materials, stainless steels)
- Close tolerances achievable even for
high melting point metals that need
to cool down from the melt through
a large temperature range
*Usually for 10,000 < Quantity < 100,000 to maximize economy of scale due to its cost*
Powder Metallurgy
Advantages Disadvantages
- High melting point metals can be - High cost of raw materials
fabricated below their melting - Dies must be simple (complex
points shapes need several punches)
- Non-metallic constituents can be - Size of product limited by size of
introduced and their contents dies (products < 15kg)
controlled - Storage of powders is difficult
- Special Structural effects: (prevent oxidation)
i. Controlled Porosity - Powder size may be inconsistent
ii. Lamellar structure - Products could be brittle (porosity
iii. Composite structure lowers tensile strength, ductility,
iv. Controlled density fatigue endurance limit)
- Good dispersion in alloys - Difficult to handle low MP metals as
- High purity of metal they tend to melt when sintered
- Low machining costs (do not need - Slight shrinkage on sintering and
subsequent machining) cooling to room temperature
- Close tolerances - Can’t be cold worked (due to
- No waste material (scrap) brittleness)
- High speed production for small
parts
- Uniform Composition
*The welded joint is the discontinuity that limits the strength of the tube (its weak spots) *
2. Hollow extrusion
- Applications:
i. Making high performance seamless tubes and pipes
ii. Usually for Aluminum tubes and good conductors of electricity (Al, Cu, Brass)
iii. Usually for large hole with thin walls
3. Mannesmann process
- Method:
i. Heat a round billet and pass it between two tapered rollers to open a central
hole
ii. Pierce the hole with a stationary mandrel that is free to rotate while feeding
the red-hot billet forward
- Applications
i. Making reliable tubes and pipes of any size (no limits)
ii. For tubes that MUST not have a weld joint
iii. Usually for a small hole in a very thick wall
EDM
Advantages Disadvantages
- Can machine any hard material - Material & Electrode must be
- Products are completely blur free conducting
- Close tolerances (a few microns), - Electrode wear resulting in products
↓ current ↑ accuracy of poor dimensional tolerances
- No mechanical strains induced in - Slow metal removal rate
the workpiece - Recast surface layer has high
- Can machine intricate residual stresses and high roughness
configurations, narrow slots, blind (needs to reduce rate of metal
cavities, small and deep holes removal)
- Can produce sharper corners than
conventional machining
(0.05mm~0.1mm)
Wire-Cut EDM
- Conducting material is cut using a wire
- Dielectric can be EDM oil or de-ionized water
- Wire can typically only be used once
- Applications:
i. Machining hard conducting materials
ii. High precision machining (teeth of gears < 1mm in diameter)
iii. Machining complicated profiles including bevels
*Used generally for difficult to machine alloys (Ni, high Cr steels, Titanium, beryllium,
hardened steels*
- Electrolyte
i. Good electrical conductivity
ii. Removes sludge of metal oxides or hydroxides formed during de-plating
process
iii. Prevents overheating of electrodes
ECG
Advantages
- Good surface finish
- Good tolerance
- Low mechanical and thermal stresses on workpiece
- No surface cracks
- Yields as high tool life in workpiece as tools ground by conventional means
LBM
Disadvantages
- Deep holes have tapered sides due to blasting effects of laser
- LBM equipment are expensive
- Surface produced usually rough
1. Acetal (Poly-Acetyl)
- Very high strength
- Cannot stand boiling water
- Used to replace metals in load bearing components
- Applications
i. Zippers, Screws, aerosol containers, machine housings, plumbing fixtures,
shower heads, bearings, handles of kitchen utensils, fan blades, gears,
artificial heart valves
2. Acrylic
- Most transparent plastic available
- Transmit over 90% of light
- Applications
i. Outdoor signboards, aircraft windows, car lights (fiber optics), contact lenses
(hard type), TV and computer screens
ii. Basically, anything transparent and needs decent strength
3. Cellulosics
- Extremely cheap plastic
- Cellulose fibers from wood or cotton
- Transparent unless altered
- Made from plant matter (attackable by termites)
4. Fluorocarbons
- Expensive
- Heavy
- Can withstand high temperature and corrosive environments
- Low coefficient of friction and low surface energy (non-stick)
- Types of Fluorocarbons:
i. Tetrafluoroethylene (TFE), used to make Polytetrafluorethylene (PTFE)
ii. Chlorotrifluoroethylene
- Applications
i. Coating for electrical wires that generate a lot of heat
ii. Internal pipe lining for corrosion resistance
iii. Non-stick frying pan lining, rice cooker lining, tape for sealing pipes
iv. Solid lubricant (sheet form) for moving parts
v. Laminated and interlayered with other fabrics (fiber glass, polypropylene,
aramid, polyphenylene, sulfide, acrylic, polyester)
5. Polyamides
- Types of polyamides
i. Nylons
Solid form used to replace metals in load bearing applications (if
dimensions are not critical
Yarn or fabric form used for clothing, stockings, swimsuits, umbrellas,
fishing lines, reinforcing material for composites
Foam form used for kitchen sponges
ii. Aramids
High strength and stiffness
Used for reinforced plastic helmets, bulletproof vests
6. Polyesters
- Types of polyesters
i. Polycarbonate
ii. Polysulfone
iii. Polyethylene terephthalate
iv. Polybutylene terephthalate
- Applications
i. Commodities that need impact strength + transparency
ii. Cash/identity/smart cards, CDs, electric sockets, computer diskettes,
sterilizable milk bottles, surgical instruments (can withstand boiling water)
7. Polyolefins
- 2nd cheapest plastic in Singapore
- Corrosion resistant, waxy surface, non-toxic
- Types of polyolefins
i. Polyethylene
Very Light and cannot stand boiling water
ii. Polypropylene
Floats in water, stronger, more expensive, can stand boiling water
- Applications
i. Low Density Polyethylene
Non-toxic & chemically inert
Household and kitchen stuff
Grocery bags
Tupperware, containers, plastic cups, pails flexible toys, squeeze
bottles
ii. High Density Polyethylene
Bottle crates
Tool boxes
Rubbish bins
Recycling bins
Army water bottles
iii. Ultra-high molecular weight polyethylene
Very wear resistant surfaces (surgical implants in the shoulder or hip)
Low density PE is translucent
High density PE is opaque
iv. Polypropylene
Luggage cases
Kitchenware that must withstand boiling water
Washing machine parts
Electric kettles
Toys
Pipes carrying drinking water
8. Polyurethane
- Solid form
- Like a piece of rubber
- Applications
i. Conveyor belts
ii. Molds for rubber pad forming
iii. Durex
9. Styrene
- Cheap
- Brittle
- Transparent
- Low & Sub-Zero Temperature
- Non toxic
- Types of Co-polymers
i. Acrylonitrile butadiene styrene (ABS)
Opaque
Impact resistant
Cannot stand boiling water
Extremely high impact strength
ii. Styrene acrylonitrile (SAN)
Transparent
Can stand boiling water
More brittle than ABS
- Applications for Solid polystyrene
i. Cleaning toilet bowls and tiles
ii. Toilet articles
iii. Toys
iv. Refrigerator parts
v. Frozen food containers
vi. Rigid transparent ice-cube trays
- Applications for Foam Polystyrene (Styrofoam)
i. Packaging, floats, insulators
Thermosetting Resins
- Can be used at higher temperatures than thermoplastics
- Generally brittle unless filled
- Transparent/Translucent unless filled with other materials to improve their impact
resistance
1. Amino Plastics
- Hard surface
- Wear resistant
- Strong
- Types:
i. Urea formaldehyde
ii. Melamine formaldehyde
- Application
i. Urea formaldehyde
Electric sockets
Wood glue
Surface tends to get stained
ii. Melamine formaldehyde
Dishware (replacement for China, porcelain, ceramics)
Chopsticks (replacement for ivory)
Coatings for stoves, refrigerators, tabletops
Melamine foam (sponges)
iii. Stain resistant
2. Caseins
- Obtained from milk products
- Seldom used nowadays
- Applications
i. Old buttons, mahjong tiles, knitting needles
3. Epoxy
- High strength
- Chemically inert, corrosion resistant
- Expensive
- Tends to be brittle unless filled
- Dimensionally stable
- Applications
i. Excellent adhesives (used for surface coatings)
ii. Corrosion and abrasion resistant (containers, pipes, tanks that contain
corrosive fluids)
iii. Can be filled with carbon, glass, graphite fibers to make composites of high
specific strength (helicopter blades, aircraft parts)
4. Phenolic
- Extremely hard and brittle unless filled
- Chemical, Electrical & Heat resistance
- Applications
i. Handles, furniture, insulators, tanks, electric sockets, hand tools
5. Polyesters
- Good weathering characteristics
- Corrosion resistance
- Applications
i. Automobile bodies, Boat hulls, Chemical storage tanks, Building panels,
aircraft body components
6. Polyurethane
- Unlike Styrofoam
- Flexible and last much longer
- More expensive
- Good shock absorber
- Application
i. Replacement for natural sponges
ii. Mattresses
iii. Fillings in airplane sections, lining materials in winter clothing
7. Silicone
- Soft and Rubbery
- Replacement for rubber if high temperatures are encountered
- Cures at room temperature in the presence of oxygen (large objects, joining/sealing
purposes)
- Applications
i. Electrical insulation
ii. Gaskets, O-rings
iii. Contact lenses (soft type)
iv. Protective coatings, sterilizable products
v. Dies for die casting Low Melting point metals like (Tin, lead, zinc and their
alloys)
Injection Molding
- Similar to hot chamber die casting
- Extremely convenient large-scale production (>5000)
*Injection mold is only possible for thermosets if material does not solidify before entering
the die cavity*
- Method:
i. Hopper is loaded with plastic resin in the form of grains
ii. Resin is heated to soften it as it is fed through an Archimedean screw until it
enters the mold
iii. Resin solidifies in the water-cooled mold
iv. Plastic product is ejected
v. Gates and runners are removed
- Mold is the most expensive component of the cost of production
- Final plastic product must be easily ejected from the cavity
- Surface finish of the product depends largely on the mold surface finish
- Cavities are finished using electro-discharge machining (EDM)
Extrusion
- Same as metal extrusion
- Applications
i. Rods, pipes, sheets of uniform cross section
ii. Coatings around wires and cables
iii. Thin films to be used alone and as coatings for paper, cloth
Blow Molding
- For making thin-walled hollow thermoplastic parts that have an opening
- Application
i. Milk bottles, Shampoo bottles
ii. Polyethylene bags
- Method
i. An extruded tube of thermoplastic called a “parison” is placed between the
jaws of a mold
ii. Mold is closed
iii. Pressure from compressed air forces the material against the mold wall to
form a hollow object
Rotation Molding
- Similar to centrifugal casting but rotated in two mutually perpendicular directions
- Cheap but very slow method (for <100 pieces)
- Method:
i. Place plastic resin in metal mold
ii. Heat the mold to soften the plastic
iii. Rotate mold about two perpendicular axes to spread resin evenly over the
internal mold surface
iv. Cool mold with water spray to solidify plastic part
v. Open mold and remove the hollow plastic part
vi. Remove flash at the parting line
Calendaring
- Similar to rolling of metals (for making PVC sheets)
- Method
i. Squeeze softened thermoplastic resin between rolls to form a continuous
thin film or sheet
ii. Can produce sheets much thinner than those produced by extrusion
- Applications
i. Shower curtains, raincoats, ground sheets
Thermoforming
- Follow up procedure to convert sheets that have just been calendared into other
shapes
- Similar to metal forming
- Method:
i. Heat plastic sheet to soften it
ii. Form sheet between male and female molds to give desired shape
*Molds made of Aluminum or steel mounted on hydraulic or pneumatic press*
- Applications:
i. Polystyrene trays for packaging chocolates and sweets
ii. Ping pong balls are formed as hemispheres using match molds, before the
two halves are adhesively joint together
Compression Molding
- Similar to press forging
- Method:
i. Place an excess of the measured quantity (by 20-30%) of thermosetting resin
or solid preform in a mold
ii. Compact resin under heat
iii. Molten resin fills cavity, undergoes chemical reaction and hardens to
permanent form
iv. Mold is opened and part is ejected, flash removed along parting line
*Parting line is formed from the die of the mold*
Transfer molding
- Same as compression molding, with difference that solid resin preform is first put in
a transfer pot where it is heated under pressure until it melts
- Molten resin is then forced from transfer pot into mold cavity
Transfer Mold
Advantages over compression mold
- Products have no flash (require less finishing)
- Mold many products simultaneously using many runners from one transfer pot
- Can mold small intricate parts that are difficult to compression mold
Reaction Injection Molding (RIM)
- Cross between injecting molding and Compression molding
- Method
i. Two liquid components of a thermosetting resin are mixed and introduced
into the mold cavity of an injection molding machine
ii. Resin solidifies by chemical reaction
- Application
i. Molding rubber tires
Casting
- Similar to casting of metals
- Thermoplastics solidify in the mold on cooling
- Thermosets solidify in the mold by chemical reaction
- Slow process (small scale production)
- Common casting resins:
i. Acrylic, Thermosetting plastics, silicone, epoxies, phenolics, thermosetting
polyurethane
- Applications
i. Acrylic sheets and plates, tubing, rods, phenolic billiard balls, jewelry,
imitation marble, furniture parts, automotive and aircraft parts
Plastisol Molding
- Mixture of finely ground resin (PVC) and plasticizers
- Method
i. For PVC heat the part that needs coating to 150 deg C
ii. Leave to dry in an oven above 180 deg C
iii. Plastisol will solidify and form a layer around the part
iv. Raw material is a slurry consisting of PVC particles suspended in liquid
organic compound
v. Liquid evaporates upon being heated but not the PVC
vi. PVC coats the workpiece
- Applications
i. To coat wires with PVC
ii. To coat handles of hand tools
Laminating
- Method for thermosets:
i. Layers of sheets or fabric are impregnated with a liquid thermosetting resin
ii. Assemble layers to get required thickness
iii. Apply heat and pressure (150-180 deg C, 7-14 MPa)
*Hardeners (catalysts) can be used, heat is not required*
- Method for thermoplastics
i. Same as thermosets
ii. After the sheets are fused together, must be allowed to solidify by cooling
before removal
- Applications:
i. Tabletops, silent running gears, furniture, wall and ceiling panels
Reinforced Molding
- For making composites
- Method:
i. Similar to laminating but not restricted to plane flat sheets
ii. Can also be compression molded
- Applications
i. Wall panels, aircraft sections, safety helmets, large containers, boat hulls,
automobile parts
Foam molding
- Add air or gas to plastic resin to form a sponge-like material
- Common foam materials
i. Polystyrene
ii. Thermosetting polyurethane
iii. Cellulose acetate
iv. Epoxy
v. Silicone
vi. Phenolic
vii. PVC
- Types of Foam
i. Rigid foam (Styrofoam)
ii. Flexible foam
- Method of foaming
i. Mechanical
ii. Physical
iii. Chemical
- Applications
i. Floatation
ii. Packaging
iii. Cushioning
iv. Insulation