AnalyticalChemistryLab

FourthYearMajorChemistryL
: ‫االسم‬ abReport
Groupno :4‫ك‬
‫ع بدالغني محمود عبدالغنى‬
Titleofexperiment:Potentiometrictitrationsusingglasselectrode

LabReport No(1) RoundNo(1)

Aimoftheexperiment
Verificationof glass electrodeequation
Requirements
Materialsand Equipment. Chemicals
Combination glass NaOH
electrode.pH-meter. HClNa2
Magnetic CO3
stirrer.Stir bar. NaOH
Glassburet
Erlenmeyerflasksandbeakers

Procedure:
Preparation of stock
solutions:250 ml solution of 0.1
M NaOH250ml solutionof0.1M
HCl
250mlsolutionof0.1MNa2CO3

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 AnalyticalChemistryLab
FourthYearMajorChemistryL
abReport

Part I- StandardizationofHClusingNa2CO3
1. Transferexactly30mLofNa2CO3 into50mlbeaker>
2. Immersetheglass electrodeintothesolution and placeastirbarintothebeaker>
3. Record thepHreadingof thepHmeter.
4. Titrate Na2CO3 solution with HCl and record the pH change after each addition (also
Recordthe mV change). ( Note: two inflection breaks will be observed in this titration and You
need toadd smallincrementsaroundeachendpoint).
5. Tabulateyourdataand plot agraph ofthefirst derivative(plot∆pH/∆volumeversusVolume).
6. Fromtheend pointofthetitration andtheconcentration ofNa2CO3,calculatetheconcHCl
Part II- PotentiometrictitrationofNaOHwithHC
1. ConcObtain about100mLof0.1MHClin aclean,drybeaker.This beakershould
belabeled.Neverpourany solutionbackinto thisbeaker.
2. Rinseyourburetwithdistilledwater.Thenuseasmallamountofthe0.lMHClsolutiontorinsetheb
uret.
3. Fill the buret to some point higher than the markings with the HCl solution and then
CarefullylettheHClsolution outinto awastecontaineruntilthebottom ofthemeniscusson the0.00
line.
4. Placea100 mLbeakerundertheburet containing50mlof0.1 MNaOH.
5. Carefully drop a magnetic stirring bar into the beaker containing the NaOH solution. Set
thebeaker on the magnetic stirring motor and position the buret containing the HCl solution
andthepHelectrode.
6. Carefullyturn on thestirringmotorandmakesurethatthestirringbardoes
nothittheElectrode.Adjust thestirring speed asdirected by yourteacher.
7. Measureandrecord thepHofthesolution beforeanyHClhas been added.
8. Add 2.0 mL of HCl solution carefully from the buret. Record the pH when it has Stabilized.
Addanother 1.0 mL of HCl and record the pH. Continue adding NaOH in 2.0mL increments
untilyou haveobtaineda pHreading lessthan2.
9. RemovethepHelectrodefromthesolution,rinseitwithdistilledwater,andstoreitasDirectedbyyourte
acher.
10. Thesolutionsmaybediscardeddownthesink.Rinsetheburetswithdistilled
waterandPlaceitupsidedownintheburet holderto drain

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FourthYearMajorChemistryL
abReport

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 AnalyticalChemistryLab
FourthYearMajorChemistryL
abReport

Experimentwork

Results:
Forpart1 :

End point of HCL at 6.08

mlVol. of Na2Co3 30ml of
0.1MMV)hcl=MV)na2co3
M x 6.08 = 0.1 x
30M)hcl=0.49342
M

For Part2:

End point at 54
mlVol.ofNaoh30ml
MV)hcl=MV )naoh
0.49342 x 54= 30 x
MM)naoh=0.8881M

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 AnalyticalChemistryLab
FourthYearMajorChemistryL
abReport

Comment:

Glasselectrodeequationveified.

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 AnalyticalChemistryLab
FourthYearMajorChemistryL
abReport