Chemical Kinetics + Surface Chemistry + Polymer + Phase Equilibrium + Chemical Bonding + Coordination + GOC + Stereochemistry + Aromaticity + Substitution Reactions + Elimination Reactions + Carbocation QI. Which molecule has Zero Bond order? (a) Ht (b) He (©) Hel @ Hes Q2. The reaction rate of a self-catalyzed polyesterification reaction is given as Acooll _ K{COOHP[OH]. If [MJo is the initial concentratiOn of 1 and carboxyl monomers, then the degree of polymerization, [N] is gi 19) 1. = 2[M]our ¢ MO diagram of a metal complex with trigonal rbitals which remain non-bonding are: (NET June 2019) dy and dy 3.d2y?and dy 4. de and dyz Q4. The correct set of information is (NET June 2019) 1. [Mn(H20)6]?* : Uobserved = Uspin; [Co(H20)o]** : Paramagnetic 2. [Mn(H20)o}** : Uosserved > Uspiny [Co(H20)6]** : Diamagnetic 3. [Mn(H20)o]?* : Uobserved = Uspins [Co(H20)o]** : Diamagnetic 4, [Mn(H20)o]2* : Usbserved > Uspin; [CO(H:0)o}** : Paramagnetic GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 9350031871Q5. The degree of polymerization () and the fraction of monomer consumed (P) for a polymerization reaction are related as (NET June 2019) 1, = I/L-p 2. = I/l+p 3. = Ip 4, = I/p? Q6. If the half-life of a reaction is inversely proportional to the square of the coneentration of the reactant, the order of the reaction is 19) 1.0 2.1 3.2 4.3 Q7. The allowed transition in an atomic system is 19) 1.3FiDs 2.3F'Ds 4.3Fs D2 ionship between ae Bi (NET June 2019) H CH; B 1. Homomets, (identical) 2. Enantiomers 3. Diastereomers 4, Conformers Q9. Oy" is (NET June 2019) 1. having a shorter O-O bond length than that in Or 2. a stronger oxidizing agent than O2 3. IR active GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 93500318714. unable to abstract proton from weak acids QI0. The major product formed in the following reaction is (NET Dee. 2019) BF3 OE2 lyzed unimolecular reaction, at very low and very high ‘ould be, respectively (NET Dec. 2019) (3) 0,1 1,1 QI2. The correct match of spin-only magnetic moment for the complexes cis- [Fe(phen)sNCS-N)2] (A) and [Fe(phen)s]Ch: (B) at 300 K is (phen = 1,10-phenanthroline) (NET Dec. 2019) (1) 4.89 BM for both A and B (2) 0 BM for both A and B (3) 4.89 BM for A and 0 BM for B (4) 0 BM for A and 4.89 BM for B Gi chemistry @ichemistry.online — [ jchemistryoosagmail.com prereersarQ13. The oxidation of NO to NO; occurs via the mechanism given below. ky ky 2NO N02 k NO; + 0; ———>_ 2N02 (NET Dee. 2019) d[NO>]/dt in the presence of large excess of O2 can be written as (1) 2k\(NO)? (2) 2kika(NO)*(O2) (3) ki/ka(NOP* (NO)* Q14. Ina polymer of N monomer units, the oot mean square ends is proportional to (DN? Q)N (3) N°? QIS. The sp is/are (AL Answer is (1) Aand C ies for which the shapes (geo dicted by VSEPR, theory (NET Dec. 2019) (3)Conly (4) AandB configuration of the following compounds is (NET Dee. 2019) GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com prereersar() EM IER (2) EM; Its (3) EP; TR (4) EP; 1S. QI7. The correct order of basicity of the following anions is (NET Dec. 2019) e goo? or 2 2 CH.NO, CHJCN No, No, A 8 c D (1) B>A>C>D (2) D>B>C>A (3) C>D>B>A QI8. The magnitude of bond angles in gaseous NF3, SbBS a1 (1) NF3>SbF3>SbCl3. (2) SbCl3>SbE3>! (3) SbF:>SbCI;>NF3 (NET Dec. 2019) al_ decarboxylation of the following (NET Dec. 2019) —~ 2 coum N c B A (1) CBA (2) C>A>B (3) A>C>B (4) BOA GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 935003187120. Correct order of extinction coefficient values of the visible absorption bands for the following species is (NET Dec. 2019) (1) [Cr(H:0)6}** > [Mn(H:0)s)** > Chlorophyll > [NiCl4> (2) Chlorophyll > [NiCls]” > [Cr(H20)«]?* > [Mn(H20)6}* (3) [NiClu] > Chlorophyll > [Cr(H20)5]2* > [Mn(H20)«]2* (4) Chlorophyll > [Cr(H20)]2* > [NiCls]** > [Mn(H20)«]2* Q21. The ion having the highest bond order is c, 2019) (1) No* (2) Ox (3) No* OS Q22. The major product formed in the following reactiot 'T Dec2019) — 6) s t-Bu (4) EBs chemistry @ichemistryoniine [| jehenisryonssgnaitcon @ $s8ssso08Q23. The IUPAC name of the following compound is (NET June 2017) \ . (a) 9-borabicyclo[3.3.1 Jnoname (b) 1-borabicyel6[3.3s! | (c) 9-borabicyclo[3.3.0]octance (2) I borabie 0) Q24. The correct order of pKa values for the following, NI ie 2017) (a) PhNH;* * C>B (2) C>ASB (3) BDA (4) B>ADC 26, IUPAC nomenclature of following propellane is (NET June 2018) Ax GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com prereersar(a) tricyclof1.1.1.02Jpentane (b) tricyclof11.1.0.1'}pentane (©) tricyclof1.1.1!5.0'SJpentane (d) tricyclo[ 1.1.1.0! ]pentane Q27. Among SiCls, P(O)Chs, NF5, trans- [SnCl.(py)2] (py = pyridline), those with zero dipole moment are (NET Dec. 2018) 1. SiCly and NF 2. SiCls, P(O)CIs and trans-SnCla(py)2 3. SiCly and trans-SnCl(py)2 4. NF3 and trans-SnCly(py)2 Q28. The characters of LUMO of CN’ and O> respectively, are c, 2018) 1. og and mt 2. my and oy e 3. my and ou 4. ou and my Q29. In the energy profile diagram of the reacti fe species A would correspond siti (NET Dec. 2018) no Ww Reaction co-ordinate @l I (Iv GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com sosogsis72Q30. In IR spectra, the stretching frequency (in cm) of the carbonyl group of the following compounds is in the order (NET Dee. 2018) B : 1, B>A>C 2. A>C>B 3. B>C>A 4. C>B>A ls ATK, 1. B>A>C . A>C>B 3. B>C>A 4.C>B>A Q32. Among the following, the optically active compound is (NET Dee. 2018) GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com prereersarQ33. Among the following reactions(s) which provide(s) 1-butene as the major product is (are) (NET Dec. 2018) ee 1BuOK ‘6 — eBUOK » Ago . A and C 4.C and D Q34. Am 1g, the compound that will have highest rate for nucleophilic echanism is, (NET Dec. 2018) GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 9350031871Q35. For a second-order reaction, the straight line among the following plots is: 1. [X] versus time 2. 1/[X] versus time 3. log[X] versus 1/time 4. log[X] versus time (NET Dee. 2018) Q36. The activation energy of a reaction reduces by 12 kcal mol in the presence of an enzyme at 300 K . Assuming pseudo-first order kinetics, calculate the factor byywhich the reaction rate is increased. [Given: R = 2 cal K! mol! 1, 2x10 2.1.02 3.8.7x10° Q37. The dispersity of a polymeric sample is 1. /? 2. ?/ trans-[M(H20),Cl2] > [M(H20)¢]* 2. [M(H20)6]** > cis-[M(H20)sClo] > trans-[M(H20).Clo] 3. trans-[M(H20)4Clo]}> cis-[M(H20)sCl2] > [M(H20)6]** 4. [M(H20)6]** > cis-[M(H20)4Cl]~trans-[M(H20)4Clo] Q40, Langmuir adsorption isotherm for the dissociative adsorption of D2 (p = partial pressure of D2 and k = ratio of rate constants for adsorption and desorption) is: GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 93500318711.0 =kp/l+kp 2.0 =K/I+kp 3.0=(kp)!/1+(kp)"2 4. 6 = (p/L-+kp)!2 (NET Dec. 2018) Q41. K is the effective first-order rate constant of the following unimolecular reaction 4+M—4= 44M ka 42 4P (NET Dec. 201; The slope and intercept of the plot of 1/k vs 1/[M] are 4x 10° and r ively. The value of k-i/k2 is: 1, 2x105 2. 0.5x10* 3. 32«105 Q42. The decomposition mechanism of ozone is (NET Dec. 2018) a a 0,+02420, If ki[O2] <'Tig (B)3A2e—>'T2 (C) 32g 'Ex (D) 32g! Arg (Given; ato1 Q49. For an enzyme catalyzed reaction, the plot of inverse of initial rate against inverse of initial substrate concentration is linear with slope 0.16 s and intercept 2.12 mol"! L s. The estimated value of Michaelis constant (in mol L’!, rounded off to two decimal places) is__ (GATE 2020) GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com sosogsis72Q50. Fluorescence quantum yield and fluorescence lifetime of a molecules are 0.4 and 5 x 10°s, respectively. If the fluorescence decay rate constant is Y x 107 s, the value of Y (rounded off to nearest integer ) is, (GATE 2020) Q51. A solution containing a metal complex absorbs at 480 nm with molar extinction coefficient of 15,000 L mol cm. If the path length of the cell is 1.0 cm and transmittance is 20.5%, the concentration (in mol L*!) of the metal complex is: 1. 1.37x105 2, 2.29x105 3. 4.59x10° 4, 8.75: Q52. Absolute stereochemistry of the given col (A) 4aR, 8aS. (B) 4aR, 8aR (C) 4aS, 8aS (D) 4aS, 8aR Q53. The normal boiling point of a compound (X) is 350 K (heat of vaporization, AvayH, = 30 KJ mol"), The pressure required to boil “X” at 300 K is Torr. (Round off to two decimal places) GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 9350031871(Ignore the temperature variation of AyapH; Gas constant R = 8.31 J mol! K*! and 1 atm = 760 Torr) (GATE 2019) Q54. For a bimolecular gas phase reaction P + Q — R, the pre-exponential factor is 1 x 1015 dm’ mol s. The standard entropy of activation at 25°C is _ JK'mol'. (Round off to two decimal points) (The standard concentration c" = 1 mol dm; Planck constant h = 6.62 x 10°" Js; Boltzmann constant ka = 1.38 x 1079 J K"!; Gas constant R= 8.31 J mol-'K"') Q55. The specific rotation of optically pure (R)-2-borobutane is™ sample of 2-bromobutane exhibited a specific rotation dP-8: (+)-enantiomer present in this sample is, Q56. Ci the following t ible first order reactions at temperature T. where k1 and k2 are the rate constants and their values are 5x107and 15x10? min", respectively, at temperature T. If the initial concentration of the reactant P is 4 mol L , then the concentration of product R after 10 min of reaction is___mol L!. (Round off to two decimal places) (GATE 2019) GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 9350031871(Assuming only P is present at the beginning of the reactions). Q57. Among the following compounds, a normal spinel is (A) MgFe20, (B) ZnFe20s (C) CoFe204 (D) CuFe204 (GATE 2019) Q58. Among the following compounds, the number of é6my optical activity at room temperature is. Q59. The Ay value of [Ni(H20)6]* is 8500cm'. The Ay values for [NiCl6]* and [Ni(NHs3)6]°* compound to [Ni(H20)«]** are (GATE 2019) (A) higher and lower, respectively (B) lower and higher, respectively (©) higher in both complex ions, (D) lower in both complex ions, GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 9350031871Q60. In Freundlich isotherm, a linear relationship is obtained in the plot of (e = surface coverage and p = partial pressure of the gas) (GATE 2019) (A) 0 vs p. (B) In (0) vs In(p). (C) In (0) vs p. (D) 0 vs In(p). Q61. Micelle formation is accompanied by the ( 019) (A) decrease in overall entropy due to ordering. (B) increase in overall entropy mostly due to inc 1 Entropy. (GATE 2019) Pressure (attn) TAT 2S 29815 ‘Temperature (K) GAs chemistry @chemistry.ontine [4 jchemistryo0sagmail.com sosogsis72(A) At 200 K, on increasing the pressure from 1 to $0 atm, CO2 gas condenses to liquid (B) itis not possible to obtain liquid CO> from gaseous CO» below 5.11 atm. (C) Both liquid and gas phase of CO; coexist at 298.15 K and 67 atm. (D) With increasing pressure, the melting point of solid CO: increases. GA chemistry @ichemistry.ontine [4 jchemistryo0sagmail.com 9350031871