CBI Colony, Kavuri Hills, Madhapur, Hyderabad, TS-500081

Sec: Sr.MPC-S2
Time: 3 Hrs. Max Marks: 30M

Name of the Student: ……………………………… ID No:

Answer all the questions 5 x 2 = 10 M

1. Calculate the spin only magnetic moment of Feaq2  ion.
2 2
2. Why Zn is diamagnetic whereas Mn is paramagnetic?
3. CuSO4 .5H2O is blue in colour where as anhydrous CuSO4 is colourless. Why ?
4. What are the ambident nucleophiles?
5. What is mischmetal? Give its composition and uses

Answer any FIVE Questions 5 x 4 = 20M

6. Write the characteristic properties of transition elements.

7. Explain Werner’s theory of co-ordination compounds with suitable examples.
8. Using IUPAC write the formulae for the following:
(i) Tetrahydroxozincate(II)ion (ii) Hexaamminecobalt(III)sulphate
(iii) Potassiumtetrachloropalladate(II) (iv) Potassiumtrioxalatochromate(III)
9. Define the following:
(a) Racemic mixture (b) Retention of configuration (c) Enantiomers
10. Explain the mechanism of Nucleophilic unimolecular substitution SN 1 reaction with one
example and Nucleophilic bimolecular substitution SN 2 reaction with one example.
11. Explain the following: a) Wurtz Reaction b) Williamson Synthesis