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Worksheet Chemo G 12 Unit Tu 22 2016
Worksheet Chemo G 12 Unit Tu 22 2016
What would be the electromotive force (emf) of the cell constructed between these two
electrodes? A. 1.1OV B. 0.42V C. -l.lO V D. -0.42V
27.Which equation represents an oxidation - reduction reaction?
A.H2SO4+2NH3 (NH4)2SO4 C. 2K2CrO4+ H2S04 Cr2O7+K2SO4 + H2O
B.H2SO4 +Na2CO3 Na2SO4+H2O + CO2 D. H2SO4 + CU CuSO4 +2H2O+SO2
28.An electrochemical cell constructed for the reaction:
Cu2+(aq)+M(s) Cu(s)+M2+(aq)
Has an E0 cell= 0.75V. The standard reduction E0 red potential for
A Cu2+(aq) is 0.34V. What is the standard reduction potential for ( M+2 (g)/ M ?
A. -1.09V B. -0.41OV C.O.4lOV D.1.09V
29.What is the correct order when the substances 02,H20,OF2, and H202 are arranged in order of
increasing oxidation number for Oxygen? A. O2, H2O, OF2, H2O2
B. H2O, H2O2, O2, OF2 C. H2O2, O2, H2O, OF2 D. OF2, O2, H2O2, H2O
30.Consider the standard voltaic (or galvanic) cell: Fe, Fe versus, Au, Au3+. Which answer
2+
identifies the cathode and gives the E0 red for the cell?
Given EO (Au3+ /Au) = 1.50 V, E0 (Fe2+/Fe) = -0.44V .
A. Fe, -0.44V B. Au, 1.06V C. Au, 1.94V D. Fe, 1.94V
31.What kind of energy is converted in galvanic cell?
A. Chemical energy is converted into electrical energy
B. Chemical energy is converted to heat
C. Chemical energy is obtained from heat
D. Electrical energy is converted into chemical energy
32. The decreasing order of electrochemical characteristics of some metals is given as :
Mg Al Zn Cu Ag . What will happen if a cooper spoon is used to stir a solution of
aluminum nitrate (Al (NO3)3) ?
A. There is no reaction C. The spoon will get coated with aluminum
B. The solution becomes blue D. An alloy of cooper and aluminum is formed
33.A solution in an electrolytic cell contains Cu2+ (Eo = 0.34 V), Ag+ (Eo = 0.80 V), and Zn2+
(Eo = -0.76 V). If the voltage is initially very low and slowly increased, in which order
will the metals be plated out onto the cathode?
A. Zn2+ Cu2+ Ag+ B. Ag+ Zn2+ Cu2+
C. Cu2+ Zn2+ Ag+ C. Ag+ Cu2+ Zn2+
34. During the electrolysis of an aqueous solution of copper sulphate using platinum electrodes,
the reaction takes place at the anode is
A. CU2+ +2e- CU B. CU CU2++2e-
C. 2H2O 4H+ + O2 +4e- D. 4H+ + O2 +4e- H2O
2+ ¿¿
35. Standard electrode potential for Sn4 +¿/ Sn ¿ couple is +0.15v and that for the Cr 3+¿/ Cr¿ couple
is -0.74v. These two couples in their standard state are connected to make a spontaneous
electrochemical reaction. The cell potential will be
A. +1.83v B. +1.19v C. +0.89v D. +0.18v
36.What mass of magnesium is plated out upon electrolysis from molten MgCl2 using a current
of 60 A for a period of 4000 seconds? A. 30g B. 24g C. 60g D. 72g
+ 2+
37.For a voltaic (or galvanic) cell using Ag, Ag (1.0 M) and Zn, Zn (1.0 M) half -cells, which
of the following statements is incorrect?
A. The zinc electrode is the anode
B. Electrons ill flow through the external circuit from the zinc electrode to the silver elecrode.
C. The mass of the zinc electrode will increase as the operates.
D. Reduction occurs at the zinc electrode as the operates.
38.For the galvanic cell shown below, which one of the following statements is correct?
A. At the zinc electrode, zinc ions are formed
B. The electrode potential is measured by the voltmeter
C. The following reaction takes place at the magnesium electrode Mg2+ + 2e- Mg
D. Electrons flow from zinc electrode to the magnesium electrode
39.What is the purpose of a salt bridge in an electrochemical cell?
A. To provide a source of ions to react at the anode and cathode.
B. to maintain electrical neutrality in a half -cell through migration of ions
C. To provide means of electrons to travel from the cathode to the anode
D. To provide means of electrons to travel from the anode to the cathode
40.The standard cell potential (E0) for the reaction below is 1.10V. What is the cell potential for
this reaction when Cu2+ = 1 x 10-5 M and Zn2+ = 1M ?
Zn(s) + Cu2+(aq) Zn2+(aq) + Cu (s)
A. 1.10 B. 0.95 C. 1.20 D. 1.35
41.Which of the following statements is true?
A The more positive the value of Ered0, the greater the driving force for reduction
B. The more exothermic the value of Ered0, the greater the driving force for reduction
C. The more endothermic the value of Ered0, the greater the driving force for reduction
D. The more negative the value of Ered0, the greater the driving force for reduction
42.Which of the following types of elements are good oxidizing agents?
A. Alkali metals B. Halogens C. Lanthanides D. Transition elements.
43. Which of the following is NOT true about the electrolysis of copper sulphate solution using
copper electrodes? A. Copper metal is deposited at the cathode
B. The concentration of copper at the cathode decreases
C. The copper metal dissolves leaving electrons at cathode
D. the impure copper at anode is turned to pure copper at the cathode
44.Of the following, which is the WEAKEST oxidizing agent?
A. HNO3 (aq) B. H2O2 (aq) C. I2 (s) D. Mg(s)
45.Which of the following metals CANNOT be electroplated on to the surface of another metal
using an aqueous electrolyte? A. Ag B. Cu C. Ni D. Mg
46.Which of the following statements is true in the electrolytic decomposition of water?
A. Oxygen is formed at both the anode and the cathode
B. Hydrogen is formed at both the anode and the cathode
C. Hydrogen is formed at the cathode and oxygen is formed at the anode
D, Hydrogen is formed at the anode and oxygen is formed at the cathode
47.When an electric current is passed through a solution of potassium iodide (KI) containing
some phenolphthalein indicator, a brown color is observed at one of the electrodes. Which one of
the following reactions is occurring at this electrode?
A. 2H2O + 4I-2I2 + 2OH- + H2 + 2e- C. KI + I- + K
B. 2H2O + 2e- H2 + 2OH - D. 2I- I2 + 2e-
48.What is the half- reaction that occurs at the anode during the electrolysis of molten sodium
bromide? A. 2Br- Br2 + 2e- B. Br2 + 2e- 2Br
C. Na + e Na
+ -
D. Na Na +
+ e-
49.Chlorine has an oxidation number of +5 in: A. NaClO B. NaClO3 C. NaClO2 D. NaClO4
50.When a sodium chromate (Na2CrO4) solution is acidified, its is converted to:
A. Cr(s) B. Cr2O72- C. CrO3 D. Cr2O3
51.During the electrolysis of a concentrated aqueous solution of NaCl, what substance is formed
at the cathode? A. Hydrogen B. Oxygen C. Chlorine D. Sodium
52.In a voltaic cell, electrons flow from the………….to the………. A. Salt bridge, anode
B. Salt bridge, cathode C. Anode, salt bridge D. Anode, cathode
53. During the electrolysis of CuSO4(aq)using carbon electrodes, which of the following is
the correct half reaction for the anode electrode? A. Cu+(aq) + 2e- Cu(s)
- -
B. 4OH (aq) 2H2O(l) + 4e C. 2H2O(L) O2(g) + 4H (aq) + 4e-
+
What is the value of E when [Cu2+ ] is equal to 0.040M and [Fe2+] is equal to 0.40M
A. 0.72 V B. 0.75 V C. 0.81V D. 0.84V
11. For the electrochemical cell represented by :
Zn/ZnSO4(aq) //CuSO4(aq) /Cu(s)
The standard reduction potentials for Cu2+/Cu and Zn2+/Zn are + 0.34 and –0.76V, respectively ,
What will be the cell reaction that occurs spontaneously and its cell voltage ? A.Cu+ Zn 2+ =
Cu2+ + Zn & 1.10v C. Cu2++ Zn2+ = Zn + Cu & 0.42v B.Zn + Cu2+ = Zn2+ + Cu
2+ 2+
& 0.42v D. Cu + Zn = Cu + Zn & 1.10v
12. What product (s) is formed during the electrolysis of a concentrated aqueous solution of
sodium chloride?
A. Cl2 B. Cl2(g) and H2(g) C. NaOH(aq) and Cl2(g) D. Cl2(g) , H2(g) and NaOH(aq)
13. In the reaction : Pb + PbO2(s) + H2SO4(aq) → 2PbSO4 (s) +2H2O(l) which substance
behaves as the oxidizing agent ? A. Pb B. PbSO4 C. PbO2 D. H2SO4
14. What mass of magnesium (Mg) is produced in the electrolysis of molten MgCl2 if a
current of 7.50 x 102 A is passed through the molten salt for 1.00 hour ?
A.3.4 x 102g B. 9.92 x 102g C. 1.7 x 102g D. 4.96 x 102g
15. During the electroLysis of CuSO4(aq) using carbon electrodes, which of the following is the
correct half reaction for the anode electrode ?
A. Cu2+ (aq) + 2e- → Cu(s) C. SO42-(g) + O2(g) + 4H+(aq) → SO42-(aq) + 2H2O(1)
B. 2H2O(1) → O2(g) + 4H+(aq) + 4e- D. 4OH-(aq) →2H2O(1) + O2(g) + 4e-
16. During the electrolysis of a concentrated aqueous solution of NaCl, What substance is
formed at the cathode ?A. Chlorine B. hydrogen C. oxygen D. sodium
17.. In a voltaic cell, electrons flow from the ____ to the _______
A. Anode , cathode B. salt bridge , anode C. anode , salt bridge D. salt bridge ,cathode
18.How long has a current of 3 ampere to be applied through a solution of silver nitrate to coat
metal surface of 80cm2 with 0.005cm thick layer ? Density of silver = 10.5 gcm-3
A. 476s B. 1252s C. 683s D. 1028s
19.What is the standard cell potential of the oxidation of ammonia, given below ?
4NH3 + 3O2 →2N2 + 6H2O ∆ G0 = -1356KJ
A. 7.02V B. 3.51V C. 1.17V D. 14.04V
108.Two electrolytic cells were placed in series one of AgNO3 and the other of CuSO4If 1.273g
Ag is deposited , how much Cu was deposited at the same time ?
A. 0.374 B. 0.0118 C. 0.748 D. 0.954
109 Consider the following redox reaction 2MnO4- + 3ClO3- + H2O à 3ClO4- + 2MnO2 + 2OH-
The reducing agent is A. H2O B. ClO3- C. MnO2 D. MnO4-
110. Vanadium metal, V, reacts spontaneously with Cd2+, but not with Ti2+. Based on these
results, the order of oxidizing agents, from strongest to weakest, is
A. Cd2+, V2+, Ti2+ B. V2+, Ti2+ , Cd2+ C. Ti2+, Cd2+, V2+ D. Ti2+, V2+, Cd2+
111. Which of the following best accounts for the fact that a galvanic cell based on the reaction
represented below will generate electricity
Cl2(g) + 2 I-(aq) → 2Cl-(aq) + I2(aq)
A. Cl2 can easily lose two electrons. B. Cl2 is a stronger oxidizing agent than I2
C.I atoms have more electrons than atoms of Cl. D. I- is a more stable species than I2
112. When the equation
…H+(aq) + ……NO-(aq) + …..Cr2O7 2-(aq) → …..Cr3+(aq)+ NO2…… H2O (l)
is balanced and all coefficients are reduced to lowest whole- number terms, the coefficient for
H2O(l) is A. 12 B.13 C. 15 D. none
113. During a cathodic protection, the sacrificial anode. A. accepts electrons from the protected
metal. B. reacts spontaneously with the protected metal. C. oxidizes more readily than the
protected metal. D. causes the protected metal to become an anode.
114. When electroplating an iron medallion with nickel A. the medallion is an anode.
B. the cathode is pure nickel. C.the solution contains Ni2+ D. the anode reaction is Ni2++2e →Ni
115. Which of the following is capable of acting both as an oxidizing agent and a reducing
agent? A. H+ B. Na+ C. Sn2+ D. MnO4-
116 Which of the following involves a non-spontaneous redox reaction?
A. fuel cell B. electroplating C. redox titration D. carbon dry cell
117. Which of the following represents a redox reaction?
A. CaCO3 à CaO + CO2 B. SiCl4 + 2Mg à Si + 2MgCl2
C. 2NaOH + H2SO4 à 2H2O + Na2SO4 D. AgBr + 2S2O32- à Ag(S2O3)23- + Br-
ANSWER QUESTION NUMBER 118 TO 126 BASED ON THE FOLLOWING GIVEN
STANDARD REDUCTION POTENTIAL
Mn2+/Mn=-1.18V Mg2+/Mg= -2.37V Al3+/Al= -1.66V Ni2+/Ni= -0.25V
Zn2+/Zn= -0.76V Cu2+/Cu= +0.34V Fe2+/Fe= -0.44V Pb2+/Pb= -0.13V
118.among the following which metal can be plated out first: A. Mn B. Mg C. Zn D. Pb
119. The following metals are suitable for uses as sacrificial anodes to protect against corrosion
of underground iron pipes except:- A. Mn B. Mg C. Al D. Pb
120. What would happen if you replace section of damaged iron pipe with copper pipe?
A. Facilitates resting of iron B. Prevent or hinders corrosion of iron
C. Copper metal scarifies itself by being oxidized D. Copper pipe is expensive
121. Which of the following cation is best oxidizing agent? A. Mn2+ B. Al3+ C. Zn2+ D. Mg2+
122. Among the following which one is the best electron accepter?
A. Mg2+ B. Fe2+ C. Mn2+ D. Zn2+
123. Among the following galvanic cell reaction which one is not proceeds spontaneously?
A. Mn2+(aq) + Al(s) → Mn(s) + Al3+(q) B. Fe(s) + Cu2+(aq) → Fe2+(aq) + Cu(s)
C. Zn(s) + Cu2+(aq) → Zn2+(aq) + Cu(s) D. None
124. What is the free energy (∆G) when the following galvanic cell reaction are balanced
Mn2+(aq) + Al(s) ↔ Mn(s) + Al3+(aq)
A. -2.78 x 105J/mole B. 2.78 x 105J/mole C. -9.26 x 104J/mole D. 926 x 104J/mole
125. For the reaction Ni2+(aq) + Fe(s) → Ni(s) + Fe2+(aq) what is the standard cell potential?
A. -0.69v B. -0.19v C. 0.19 D. 0.69
126. For the cell reaction Zn(s) + Fe (aq) ↔ Zn2+(aq) + Fe(s) what would be the emf this cell
2+
rxn when 0.5M Zn2+ and 0.5M Fe2+ solution are used? A. -0.32v B. 0.32v C. 1.2v D. none