ww6 lo1 24

Expt. No. 14

EXPERIMENT: 5

AM: J0 detect anion and cation in the givern salt.

PRE PARATION OF Na, Co, fxTRACT

t 7ake 1 part of salt and 3 pavts of solid Na, c0,.

2 Add 15-20 ml dis tilled water to it.
3 Boil and filter it.

4 he filtrate obtained is the Na, Co, cxt ract.

FOR ANION

ExPERI MENT 0BSERVA TION INFERENCE

o salt, add Colourless, pungentt Smell Gas evolve d is

COTC. H, S0, and qas is evolved which No, And No,
Heat. changes to light brown LOn (s Sus ptc ted.
fumes in tensify on
adding Cu turnings.
(1. for NO;

|Neutalise Na, Co, Brown Ting apptarS at

Ltxtract ucing dil.the juncticn of the can filmed
 Data

Expt.No. lage io. 15

acctic acid and two liquids.

add frcshly prepa
-red cqual volum.
lof fexrous sulphate|
soln. and add
Conc. H, So4 along
|the side of the
test tube.

FOR CATION

PREPARATION ORIGUNAL SOLUTIoN

Oxiginal soln. is pepare d in distilled watr.

ExPERIMENT 08SERVATION INFERFNCE

1:To salt, add Nalt NO Observa tion, No punge 7er0

solr. and teat. -nt smelling qas is Qbsent.
tvolved.

Jo Origin al soln. white ppt. is obtaincd. Gr0up 1 is

add dilute H, soy. present.

CT for Pb*
Diss olye the white Yello PPt. is Pb
Ppl. (n hot wates obtained, (onfimed.
and add KI soln. to it.
 Date
Expt. No.
Page No. 16

RESULT

he given salt Contans : CATIoN: PB

ANIoN

Teacher's Signature
 Expt. No.
Date
05|01|24
Page No. 17

EXPERIMEN:6
AIM: Jo detect anian And cation the qiven Salt.
PREPARATION 0F Na, Co3 f xTRACT

1: Jake 11 part of salt & 3 parts of solid Na, co,.

2 Add 15- 20 ml of distilled wNater.
3 Boil it & filtey it.
4 he filtrate obtacncds Na, co, extract.
FOR ANION

ExPE RIMENT 0BSERYA TUON INFERENCE

Neutra lise Na,CO3

white ppt. is obtain So Ion Con fimed
extract with dil.-ed which is lnsoluble
|HCL and add in all mincral acids
BaCl, soln. to it.

FOR CATION

PREPARATI0N ORIGINAL SoLUTI0 N

ure
Expt. No. Dato

P'age No. 18

Original So In. is
prepared in dis tilled wate.
ExERIMENT O BSERVATION
INFERE NCE
Salt t Na0H t 4
No 0bser Va tion. Xero goup is
absent.
Iao ori9inal soln, add| No obseTva tion.
40up I is
dil. HCl absent.

fass H, s qas thygugh Black ppt. is

filttate of qrcup I. obtained. present.
(1 fax Cu : Diss ol ve the black ppt minimum amt.
0f dil. HNO, 0Y hot 33/. 33/ ConC. HN0, and
divide itán to 2 parts.

|To finst part, add Chocolate brown Cu' ion is

potassiu m fero cyanidd ppt. is obtained. Con firmed.
soln. i.C. Ky Lfe (CN),]
soln.
Cu 0n s
blue son. is
To second part, add| Deep obtained.
NH OH soln. Ln excesS. Cenfimd.
CATION: Cu2
com tains : CATION
ReSULT , qiven salt
he oiven
AN NON: So,

anature
 Data
Expt. No. 07 0540<2a
Page No. 19

ExrERIMENI -1
AIM: To de tect Cation and anion n the qiveTn salt.
PREPARA TION 0F NeC03 ExTRACT

1 Jake 1 paxt 0f salt and 3 parts of solid Na, C0g

2" Add 15- 20 ml of distilled watex to it.

. Boil it and filtex it.

4. he filtrate obtained is Na, co, extract.

FOR ANION

INFEREN CE
ExPE RIME NT 0BSERVATION

7o salt, add dill Colourless, vintgar like VapouIr of cH, co0H

are evolved.
evolved
|smelling gar is
H, soy.
which turns most blue
litmus xed.

C1 for CH, Co0

colour is CH, Co0 ion is
Nutralise Na,cO; Wine Confirmed.
dil. obtained which turns
extract with
LHCL and add to Ie ddich bxouwn pptl
oGcihers Signature
 Expt. No. Date

Page No. 20

ncutral fecl4 (ferrid

Jit.
chloride) soln. to heating
FOR CATION

PREPARA TION OF 0RiGINAL SoLUTI0N

Oxiqinal solm ic prepared in distilled wowater.

FxPERIMENT 0BSER YATION INFERENCE

Salt t Na0H t No obseIYatin. exo q1oup absent.

To original soln., NO observatiom. GIOup I is
add dil. HCL. absent

1o the filtrat ofl No obser vaticn. q1up I is absent.

qrgup I, Pas h,s gas.
Boil off H,s qas Gelatincus white ppt. G10up TI is
|fTom filtrate of
is obtained. preent.
910upI . Coolit and
add conc. HN0, and
then cool and add
pinch of NH, CL follst
Fed by excess of
NH, OHSoln.
 Date
Expt. No.
Paye No. 21

C1: for AL"

|Dissolve the Ppt. in

ldil. HCl and divide White ppt. appearr
which dissolvS on
it an to 2 par ts. To ad ding excess Na0H.
fist part, add
Na OH <oln. drop by
|drop.
To second part, add Afloating blue lake AL" im is
a few diopf of blue is obtained. Confitmed
Litmus soln. and
add NH4 0H dropuise.

RESUL T

he 9iven salt Con tains : CA TION:

ANION : (H,c00
 Date
Expt. No.
Page No. 22

ExPERI MENI : 8
AIM: To detect
anion and cation in the qiven
salt.
PREPARATiON Na, C03 ExTRACT

1 Jake paut of calt and 3 partr of solid Na, CO,.

2 Add 15- 20 mL 0f atex to it.
Boilit
3BoilI and filtex it.
he fi ltta te obtained is K Na,có, extiact.
FOR ANIQN

0BSERVATION INFERENCE
SNo ExPERIMENT

A qas
qas is evolyed with qas evalved is ca
1 o salt, add dil. A
bxisk effrvesente andand c0, ion is
H,soy moist blue litmu suspeuked.
changes
3d.

for co,

dime water tuYns C0 on is

1: Pass the evolved Confivmed.
milky.
lime
9as thr0u9hwater.
leccher's Signcture
 Expt. No.
Dale01|01 |24
Page No. 23

FOR CAT ION

PRE PA RATION 0F
ORIGINAL SOLU Tl0 N

Original Soln. LS
prcpared in dis tilled water.
EXPERiMENT 0BSERVATION INFERENCE

Salt t Na0H t A
No. obsex vation. qIGup 1o absent.
2: To 0-s add dil. HCL No obser vatin. q10up I absent.
Pass H, qas thTuzh No absex vatian 4Iaup I abs ent.
the filthate of
I.

o bser vatign. II absnt.

4 Boil off H,s qas fsom No.
the filhate of qrup
I and add a fcw
diopr of Amc. HNO, ta.
Cool it and add a
pinch of solid NH,CL
t excess 0f NH, 0H soln.
T iis
Dirty white pt. isG1cup puent.
S. Pass H,S gas to the obtained.
filtsate of qroup L.

leacher's Signature
 Dote
Expt. No.

Page No. 24

fox GROUP T
Diss olve the ppt.
HCl, Boil Ppt. in min. quantity of
off H,s qas and
soln, into divide the
part.
SNe ExPERIMENT 0BSERvATION INFER ENCE

t Io fiSt part, add Abluish white ppt. n ion is

Ku lfe CN)s1 son. to, it. is obtained. Con fium d.
2J0 second pait, add|A white ppt. ic obtaine Kn ion is
Na Ot fi1st in little & -d which dissaver in crn fitmed.
then In excess. excess f NH0H.

RESUL T

he given salt contains: CATION : n

ANioN : C0,*

leccher's Signarure
Expt. No. Date 0101 4
Page No. 25

ExPERI MENT - 9
AIM: To
salt.
detect theanin and catian in the
given
PREPARATIDN 0F Na,CU3 ExTRACI

Add 1 part of sa and 3 parts of salid Na, cas.

Add 15-20 mL af distilled wateY,
Bail it and filter it.
he filtxa te obtained
FOR ANION

OBSERvAtION INFERENCE
ExPERIMENT

lo salt, add Conc. Colaurlers ,pungent smlling HCL qas /S

evolve d and
H,soy and heat. qas is evolvcd which tuins
moist blue litmus ied c is suspected.
and produces dence white
fumes with a qlas xod
dipped an bkn NHOH is
brought near
ne it.

cccher s Sicncture
 Date
Expt. No.
Pape No. 26

Neutxalise Na, c0, Curdy hite ppt. is obtai! Cl in is

extxact by addinq dil|-ned which is soluble in confi1med.
HNO, and add AgNo, excess of NH4 oH soln.
soln. to it.

FoR CATION

PREPARATIO N 0F ORIGiNAL SoLUTION

Original solution is þreparcd in distilled watex.

ExPERIMENT 0BSERVATION INFERENCE

Saltt NaoH t No cbscrVatian qaup KIO absent.

No obseI Vation. GrOup I absent.

Io 0-s, add.dil. HCL.
G10up I absent.
No black ppt. s
|Pass H, s qas to the obtaincd.
|filtate of q1oup I.
TIL abstnt.
off H,s qas from No obser vation,
Boil
|the filtta te of qroup"
and add a few drops|
Conc. HN0, t A, Cool it
land adde pinch af lcachcr's Sioncturc
Expt. No.

21

NHyClt excess of NO
NH4 H soln, white Ppt. i:

Pass H,s qas o the fNo

|lhate of Greuplil observation.
Boil off H,s gas fr eTn White ppt. is
the filrate af giop obtainrdl Girp Y ore:ent.
TL and add pinch af|
NH,Cl t excess o0f NH,0H
follow ed by conc.
ammonium sabanate
|soln.

C1 foY Bat

Disso lye the white ppt. YellGuw ppt. is

in hot dil, acetic acid obtained. Canfimd.
and add k,60 soln.

4f S is present, then :
: Dissolve the hwhite ppt. n hot dil. cH, CatH
and divide it (nto 2 parts.
INFERENCE
ExrERIMENT 0BSERVATION

absent.
lo GTe part, ad d No ppt.
Lpatassium chramat salnd
 Expt.No. Dote

l'age No 28

part, add
conc. s0ln. of (NH, ), so, White ppt formud.
and warm.
prcsent.
1f Ca
CT foY Cat present, then:
Dissolve the white ppt. in hot dil. CH,cO0H
and divide it in parts.
ExPERIMENT
0BSERVATION INFEREN CE

Jo on e part, add No ppt. obtained Ba

2+
is absent

70 second part, add

conc. soln. of (NH, ),o No Ppt abtained. S is absent
and arm.

o third part, add |ahite ppt.cbtained which Ca im is

ammanium oxalate is insolube in CH, cooH. confim«d.
soln.

RESULT

|: Ba/
CATION: Sy*/ (a'
.he given salt con tains:
ANION: Cl

Teocher's Signaturk
 Expt. No. Date 01o124
Page No. 29

ExPERIMENT - 10
Aim: Jo de tect anim And kation in thc qiven salt.
PREPARA TION OF Na, C0
ExTRACI
Jake 1 pat of salt and 33 partr of
solid Na, (Oz.
2 Add 15-20 ml of dis tilled waterto lt.

3 Boil it and filtey it.

4. he fitrate obtaincd is Na, cOz extract

FOR ANION

ExPERIMENT 0BSERVATION I NFERENCE

Gas evolved is c0,

Io salt, add dilA qas is evolved with 2
lbyisk effeivesence which
turns moist blue litmus suspectd.
|paper 1cd.

water turm milk Co icn is

Poss the (volved Gasl Lime Cnfirmod.
qas
fhrcu gh lime wattr.
Teccher's Signcture
Expt. No. Date

Page No. 30

FoR CATION
PREPA RATION
0RIGINAL SoLUTION
O1iginal Soln. is prepare d dis ti lled watY.
ExPERIMENT
0BSERVATION INFERFNCE

Salt t NalH t A No obser Vatin. 4rup AtY0 absent

Jo 0xiginal soln, No abser vatim. Graup I abstnt.
add dil. HcL.

J0 filttate of gieup No bseIVa tign. G1Mp I absent.

I parr 4,s gas.
Boil 0f{ H, s qas frm No obser va tin lhrGup TT absent.
filtrate 0f qrcup I
and addfew duops
0f Conc HNO,t A +Cool
t pinch of solid NH, (U
t Cxcess 0fNH, 0H soln.
absent.
No obsrVation.
Pass H,s qas thtugh
|the filtratt of qroup
H,s qas frorn No obstuva tion.
|Bil off
Lfiltat af leacher's Signature
Expt. No.
Dote

Page No. 31

and add pinch of

NH, 0H and (NH), co,
soln.

Roil the soln. to

teduc White cIys talline
the bulk. To thi,
add excess of Na, HPa obscrved.
and add fcw drops M' isn is
of NH Hsoln. Shake cm fimed.
well and scra tch thd
wallk ot it with a
glasrrod.

ResULT

qiven salt cntains: (ATIUN: M,

ANION: C0,

Teccher's Signatur
 Expt.No.
Date 10o124
Page No. 32

ExpERIMENT -11
You are
provided with:
1 Soln. C-15 which
dil. H,sO, 0f Concentration 9.450 qL
Soln.(-16 which
2 Is of Tmpure sodium car bonate (Na, Co,)o4
Cancentration 10. 520 ql'.
fexfom titratim by taking C-1(-15 in burette and (- 16 in
pipz tte using methyl orange as an indicatox and cCalculate
the following:
ú Malazity of c:15 in dil. H,so, soln.
i Molarity of (-16 ie. Ampure Na, (0, soln.
[iiiL Stiength of Na, co, soln.
iv Pescenfage purity of Na, Co, in the sample used to make
solutions
[w Streng th of An the solutin of -16 in gl'.

chemical equationnepresent he chemical

he following
butween the Solutign s.
actigr
Na, SO4 t H,0 t0,
Na, c03 t H,So4
(dil.)
H:1, S: 32.
(: 12,016
Given:
pipette, titra tin flask, whit
ipparatus iequid: Bure tte , Teacher's Sionature
 Expt. No.
Dote 10 |o1424
Page No. 33

qlazcd tile and mcthyl osange.

PRoCE DUR E :

Wash, inse and filL the bure tte with (- 15 up to mark

Nash and inse the
of (-16 into well pipctte and use it to transfer A5 m.
washed titration flask.
Add two drops of me thyl orange to C-16 in titraicn.
flas k.
Place the flask on white qlaztd tit and sun drum
(-15 from burctte to add it to the cmtents of0f the flask.
in smalL ins tall mnt caxe fully shaking the flask and
obstivin the colour of the solutin iitill a peimancnt
light pink colous is obtained,
keptat the
the expeviment till tw0 Konordant teaclings
aTe obtained.
Titre alue 0Y fnd
Volume of acid
SNG. Bunette Reading used point
Initial final
24.9 ml 24.9 ml
1 0.0 ml
24,8 ml
24.8 m
0.0 ml 24.8m L
24.8 ml 24.8 ml
3 0.0 ml

leachers Signature
 Expt.No.
Dote
Page No. 34
PAL CULA
Ti0NS: (0 Molarity of H,so soln
Stength
Mol. ut.
9.450 3 0,0964 M
for molari hy 0t Na, Co, soln. (Na,cog)
9%
M4
M,v,cMsa,)n,
0.0964 x24.8
M, x25

M: 0.0 9565 M
jit Sticngth of Na, Co, Soln.: Molarity xx Mal. bt.
a
30.09565 x 106
3 10. 13 96 g
* 10.14 -1

(ivi for
pcicentage purity of Na, co,i 1a-520 9 of impure Sample
Contains 10.140 9 of pure salt. 1009 of impute sample
Con tans: 10 . 140 x100
l0.52

96.39/.

For Concentration 0t Co.: Mol. wt. of Na, Co, : 2*23 t |2 X23x16

: 46 +12 +48

[06 4 Nq, Co, has Conc. 0f Co : 60 9

xl0.14 : 5. 7396 q!.
will have : 60I06
10.14 Na, Co,

lcocher's Signaturc
Expt.No.
Dote

Page No. 35

Ex?ERI MENT: 12
Yo u provided with tawo solutions:
Solution C-10
can taining s.15 9 of
tian
Solu C-11 of H,so4 0f
anhydcus Ne,co, i
unkngwn concentration.
PROCEDURE: 1'
Washinseand fill the buie tte
to the mark. with (-11 up

Pipette 0ut 25 c. of C-10 in a cle an cani cal

flask
Add two
dops af mthyl 01ange to conical flask
Con taining c-10.
Place the flask white qlazcd tile and tun don
(11 fLGm buitte. Prform titration. by constant shaking
of flask till permannt light pink Lotour is ob taind
in conical flask.
Repeat the experiment ilL two toncardant Ytading.
obtaincd.
Na, so, t H,0
|Na,Co, t H,so4

Na: 23(: 12, 0: 16., H: 1

Given:
leacher's Signature
 Expt.No.
Date

Page No. 36

Calculate ti1 Molarity

Malavity of
sol ( H, (-10 soln.
Molarity of (-11 soln. (Na,0,)
ril Strength of C- 11 soln so,)
in
Conc. of Soy L
LOns (n (11 (n
(vl No. of so,
So, iions (n
(-11 soln.
(BSERVATION TABLE:

s"No Bure tte, Readings Vol. of H, So4 used

4nitial inal itre V¡lue
(Tinal - Anitial)

0-0 ml
1 25.1 mL
0.0 ml 23.6 ml 23.6 ml 13.6 m
0.0 mL 23.6 ml 23.6 ml

CAPAC1TY OF PPeTIE US ED 25 m l 01 CC.

CALCULA [i0NS : i Molarity of Na, s0, soln: M: Strenth

Mol. wt.
M, : 5.15 0.04859 M
106

ty of Sul phuric acid:

n,

0.0485 8 X 25 M, : 0. 05146 M
1
M, X23. 6

leacher's Signature
 Expt.No. Date

Page No. 31

dtStreng th of G11 An g: Concerntration 0.05146

Malarity* Mol. ut
= % 9.8 x10
S.4308
Conc. of so,
989 af Can tains 96 2

5.04308 q SO4
will cGn tain 5.04308 K96
98

ions (-11 Sol.

-1
98 qL H, so, contains 6.023x1o So,
1 23
4,94 HSO Con tains: 6.023X 0 x4.44
98
x03
4,3.153
98
23
0.30360 x10

30360 x10 igns.

Teccher's Signature