Vedantu - JEE Main Simulator: Questions

1/24/24, 11:25 AM Vedantu - JEE Main Simulator
Vedantu - JEE Main Simulator
Questions
1. 81
A rubber ball is released from a height of 5 m above the floor. It bounces back repeatedly, always rising to 100 of the height
(
through which it falls. Find the average speed of the ball. Take g = 10 m/s 2 )
(a) 3.0m / s
(b) 3.50m / s
(c) 2.0m / s
(d) 2.50m / s
2. If one mole of the polyatomic gas is having two vibrational modes and β is the ratio of molar specific heats for polyatomic
(a)
( )
v
1.02
Cp
gas β = C , then the value of β is:
(b) 1.20
(c) 1.25
(d) 1.35
3. Which one of the following will be the output of the given circuit?
(a) NOR Gate

(b) NAND Gate
(c) AND Gate
(d) XOR Gate
4. ΔV
An object is located at 2 km beneath the surface of the water. If the fractional compression V is 1.36%, the ratio of
hydraulic stress to the corresponding hydraulic strain will be ___________.
[Given : density of water is 1000 kg / m 3 and g = 9.8m / s 2]
(a) 1.96 × 10 7N / m 2
(b) 1.44 × 10 7N / m 2
(c) 2.26 × 10 9N / m 2
(d) 1.44 × 10 9N / m 2
5. A geostationary satellite is orbiting around an arbitrary planet 'P' at a height of 11R above the surface of 'P', R being the
radius of 'P'. The time period of another satellite in hours at a height of 2R from the surface of 'P' is_________. 'P' has the
time period of 24 hours.
(a) 6√2
6
(b)
√2
(c) 3
(d) 5
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6. A sound wave of frequency 245 Hz travels with the speed of 300m / s along the positive x – axis. Each point of the wave
moves to and fro through a total distance of 6 cm. What will be the mathematical expression of this travelling wave?
[ ( )]
(a) Y(x, t) = 0.03 sin5.1x − 0.2 × 10 3 t
(b) Y(x, t) = 0.06 [sin5.1x − (1.5 × 10 )t ]

3
(c) Y(x, t) = 0.06 [sin0.8x − (0.5 × 10 )t ]

3
(d) Y(x, t) = 0.03 [sin5.1x − (1.5 × 10 )t ]

3
7. Which one is the correct option for the two different thermodynamic processes ?
(a)
(b)
(c)
(d)
(a) (c) and (a)

(b) (c) and (d)
(c) (a) only
(d) (b) and (c)
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8. The velocity of a particle is v = v + gt + Ft 2. Its position is x = 0 at t = 0; then its displacement after time (t = 1 s) is:
0
(a) v 0 + g + F
g F
(b) v 0 + +
2 3
g
(c) v 0 + + F
2
(d) v 0 + 2g + 3F
9. Two cells of emf 2E and E with internal resistance r 1 and r 2 respectively are connected in series to an external resistor R
(see figure). The value of R, at which the potential difference across the terminals of the 2E cell becomes zero is:
(a) r 1 + r 2
r1
(b) − r2
2
r1
(c) + r2
2
(d) r 1 − r 2
10. A hairpin like shape as shown in figure is made by bending a long current carrying wire. What is the magnitude of a
magnetic field at point P which lies on the centre of the semicircle?
μ 0I
(a) (2 − π)
4πr
μ 0I
(b) (2 + π)
4πr
μ 0I
(c) (2 + π)
2πr
μ 0I
(d) (2 − π)
2πr
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11. The four arms of a Wheatstone bridge have resistances as shown in the figure. A galvanometer of 15 Ω resistance is
connected across BD. Calculate the current through the galvanometer when a potential difference of 10 V is maintained
across AC.
(a) 2.44μA
(b) 2.44mA
(c) 4.87mA
(d) 4.87μA
12. Two particles A and B of equal masses are suspended from two massless springs of spring constants K 1 and K 2
respectively. If the maximum velocities during oscillations are equal, the ratio of the amplitude of A and B is:
K2
(a)
K1
K1
(b)
K2
K1
(c)
√ K2
K2
(d)
√ K1
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13. Match List-I with List-II
List – I List – II
(a) Phase difference between current π

and voltage in a purely resistive AC (i) 2 current leads voltage
circuit
(b) Phase difference between current (ii) Zero

and voltage in a pure inductive AC
circuit
(c) Phase difference between current π

and voltage in a pure capacitive AC (iii) 2 ; Current lags voltage
circuit
(d) Phase difference between current

and voltage in an LCR
(iv) tan − 1
( )
XC − XL
R
Choose the most appropriate answer from the options given below :
(a) (a)–(i),(b)–(iii),(c)–(iv),(d)–(ii)
(b) (a)–(ii),(b)–(iv),(c)–(iii),(d)–(i)
(c) (a)–(ii),(b)–(iii),(c)–(iv),(d)–(i)
(d) (a)–(ii),(b)–(iii),(c)–(i),(d)–(iv)
14. Two identical blocks A and B each of mass m resting on the smooth horizontal floor are connected by a light spring of
natural length L and spring constant K. A third block C of mass m moving with a speed v along the line joining A and B
collides elastically with A. The maximum compression in the spring is:
m
(a) v
√ 2K
mv
(b)
√2K
mv
(c)
√K
m
(d)
√2K
15. The atomic hydrogen emits a line spectrum consisting of various series. Which series of hydrogen atomic spectra is lying
in the visible region?
(a) Brackett series
(b) Paschen series
(c) Lyman series
(d) Balmer series
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16. Two identical photocathodes receive the light of frequencies f 1 and f 2 respectively. If the velocities of the photo electrons
coming out are v 1 and v 2 respectively, then
2h
(a) v 21 − v 22 = [ ]
m 1
f − f2
2h
(b) v 21 + v 22 = [f 1 + f 2 ]
m
1
(c) v 1 + v 2 =
[ 2h
m (f1 + f2 ) ] 2
(d) v − v =
1 2 [ 2h
m (f 1 − f 2 ) ] 2
17. What happens to the inductive reactance and the current in a purely inductive circuit if the frequency is halved ?
(a) Both, inductive reactance and current will be halved
(b) Inductive reactance will be halved and current will be doubled.
(c) Inductive reactance will be doubled and current will be halved.
(d) Both, inducting reactance and current will be doubled
18. A sphere of mass 2 kg and radius 0.5 m is rolling with an initial speed of 1m / s goes up an inclined plane which makes an
angle of 30 0 with the horizontal plane, without slipping. How long will the sphere take to return to the starting point A?
(Take g = 10 ms − 2)
(a) 0.60 s
(b) 0.52 s
(c) 0.56 s
(d) 0.80 s
19. In Young’s double slit experiment, the two slits act as coherent sources of equal amplitude A and wavelength λ. In another
experiment with the same set up the two slits are sources of equal amplitude A and wavelengthλbut are incoherent. The
ratio of the intensity of light at the mid-point of the screen in the first case to that in the second case is
(a) 4: 1
(b) 1: 1
(c) 2: 1
(d) 1: 4
20. A 2 kg block is attached to a spring for which K = 200 N / m. The block is held at an elongation of 5 cm in the spring and
then released at t = 0.
Find the speed of block when its displacement is half of the amplitude
(a) 0.25 m / s
(b) 0.43 m / s
(c) 0.33 m / s
(d) 0.5 m / s
21. The electric field intensity produced by the radiation coming from a 100 W bulb at a distance of 3 m is E. The electric
x
field intensity produced by the radiation coming from 60 W at the same distance is
√ 5
E. Where the value of x
=__________.
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22. 1
A body of mass 1 kg rests on a horizontal floor with which it has a coefficient of static friction . It is desired to make
√3
the body move by applying the minimum possible force F N. The value of F will be __________. (Round off to the
Nearest Integer)
[Take g = 10m / s 2]
23. A boy of mass 4 kg is standing just below the pulley on a piece of wood having mass 5 kg. If the coefficient of friction
between the wood and the floor is 0.5, the maximum force that the boy can exert on the rope, so that the piece of wood
does not move from its place is ________N.
(Round off to the Nearest Integer)
[Take g = 10 m / s 2]
24. Suppose you have taken a dilute solution of oleic acid in such a way that its concentration becomes 0.01cm 3 of oleic acid
per cm 3 of the solution. Then you make a film of this solution (monomolecular thickness) of area 4 cm 2 by considering
1
( )
100 spherical drops of radius 40π
3 3
× 10 − 3 cm. The thickness of oleic acid layer will be x × 10 − 14m.
Where x is_______________.
25. A particle of mass m moves in a circular orbit in a central potential field U(r) = U r 4. If Bohr’s quantization conditions
0
are applied, radii of possible orbitals r n vary with n 1 / α, where α is _________.
26. → 2 3 N
The electric field in a region is given by E = 5 E 0î + 5 E 0ĵ with E 0 = 4.0 × 10 3 C . The flux of this field through a
rectangular surface area 0.4 m 2 parallel to the Y – Z plane is _________Nm 2C − 1.
27. The disc of mass M with uniform surface mass density σ is shown in the figure. The centre of mass of the quarter disc (the
xa xa
shaded area) is at the position 3 π , 3 π ; where x is ______.
[a is radius of disc as shown in the figure]
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28. The image of an object placed in air formed by a convex refracting surface is at a distance of 10 m behind the surface.
2 2
The image is real and is at 3 of the distance of the object from the surface. The wavelength of light inside the surface is 3
x
times the wavelength in air. The radius of the curved surface is 13 m. The value of ‘x’ is ________
29. A 2μF capacitor C 1 is first charged to a potential difference of 10 V using a battery. Then the battery is removed, and the
capacitor is connected to an uncharged capacitor C 2 of 8μF. The charge in C 2 on equilibrium condition is ______μC.
30. Seawater at a frequency f = 9 × 10 2Hz, has permittivity ε = 80ε and resistivity ρ = 0.25Ωm.Imagine a parallel plate
0
capacitor is immersed in seawater and is driven by an alternating voltage source V(t) = V 0sin(2πft). Then the conduction
1
current density becomes 10 x times the displacement current density after time t = 800 s. The value of x is ______
( 1
Given : 4πε = 9 × 10 9Nm 2C − 2
0 )
31. tan ( π cos 2θ )
The value of the limit lim 2 is equal to :
θ → 0 sin ( 2π sin θ )
1
(a) −
2
1
(b) −
4
1
(c)
4
(d) 0
32. [ r ] + [ 2r ] + . . . . . . + [ nr ]
The value of lim , where r is a non-zero real number and [r] denotes the greatest integer
n→ ∞ n2
less than or equal to r, is equal to :
(a) r
r
(b)
2
(c) 0
(d) 2r
33. Let a computer program generate only the digits 0 and 1 to form a string of binary numbers with probability of occurrence
1 1
of 0 at even places be 2 and probability of occurrence of 0 at the odd place be 3 . Then the probability that ‘10’ is
followed by ‘01’ is equal to :
1
(a)
3
1
(b)
9
1
(c)
18
1
(d)
6
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34. Consider the function f : R → R defined by
{( ( ))
1
2 − sin x
|x|, x ≠ 0
f (x) = . Then f is :
0 , x = 0
(a) monotonic on ( − ∞, 0) ∪ (0, ∞)
(b) not monotonic on ( − ∞, 0) and (0, ∞)
(c) monotonic on ( − ∞, 0) only
(d) monotonic on (0, ∞) only
35. P and Q are two distinct points on the parabola, y 2 = 4x , with parameters t and t 1 respectively. If the normal at P passes
2
through Q, then the minimum value of t 1 is
(a) 4
(b) 6
(c) 8
(d) 2
36. Let y = y(x) be the solution of the differential equation

π
cos x (3sinx + cosx + 3) dy = (1 + y sinx (3sinx + cosx + 3)) dx, 0 ⩽ x ⩽ 2 , y (0) = 0.
Then, y
() π
3
is equal to :
( )
3√ 3 − 8
(a) 2 log
e 4
( )
2√3 + 10
(b) 2 log
e 11
(c) 2 log e
( √3 + 7
2 )
( )
2√ 3 + 9
(d) 2 log e
6
37. Let f : R → R be defined as f (x) = e − x sinx. If F : [0, 1] → R is a differentiable function such that F (x) = ∫ x f (t) dt,
0
1 ′ x
then the value of ∫ 0(F (x) + f (x)) e dx lies in the interval
(a)
[ 330
360
331
, 360 ]
(b)
[ 327
360
329
, 360
]
(c)
[ 331
,
360 360
334
]
(d)
[ 335
360
336
, 360 ]
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38. A circle touches both the y-axis and the line x + y = 0. Then the locus of its centre is
(a) y = √2x
(b) x = √2y
(c) y2
− x 2 = 2xy
(d) x 2 − y 2 = 2xy
39.
The coefficient of x − 5 in the binomial expansion of
(a) -1
( 2
x+1
1
x3 −x3 +1
−
x−1
1
x−x2 ) 10
where x ≠ 0, 1 is:
(b) 4
(c) 1
(d) -4
40. If the curve y = y(x) is the solution of the differential equation
(
2 (x 2 + x 5 / 4) dy − y (x + x 1 / 4) dx = 2x 9 / 4 dx, x > 0 which passes through the point 1, 1 − 3 log e2 , then the
4
)
value of y(16) is equal to :
(a) 4
( 31
3
8
− 3 log e3 )
(b)
( 31
3
8
+ 3 log e3 )
(c)
( 31
3
8
− 3 log e3
)
(d) 4
( 31
3
8
+ 3 log e3 )
41. If x, y, z are in arithmetic progression with common difference d, x ≠ 3d, and the determinant of the matrix
[ ]
3 4√ 2 x
4 5√ 2 y is zero, then the value of k 2 is :
5 k z
(a) 36
(b) 12
(c) 6
(d) 72
42. Let S 1, S 2 and S 3 be three sets defined as

S 1 = {z ∈ C : | z − 1 | ⩽ √2}
S 2 = {z ∈ C : Re ((1 − i) z) ⩾ 1}
S 3 = {z ∈ C : Im (z) ⩽ 1}
Then the set S 1 ∩ S 2 ∩ S 3
(a) is a singleton
(b) has exactly two elements
(c) has infinitely many elements
(d) has exactly three elements
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43. Let C be a circle passing through the points A(2, –1) and B (3, 4). The line segment AB is not a diameter of C. If r is the
13
radius of C and its centre lies on the circle(x − 5) 2 + (y − 1) 2 = 2 , then r 2 is equal to:
(a) 32
65
(b)
2
61
(c)
2
(d) 30
44.
Let aˉ = 2î + ĵ − 2k̂ and bˉ = î + ĵ. Let cˉ be a vector such that |cˉ − aˉ | = 3, |(aˉ × bˉ ) × cˉ | = 3 and the angle between
cˉ and aˉ × bˉ be 30 ∘ . Then aˉ . cˉ is equal to:
(a) 2
(b) 5
1
(c)
8
25
(d)
8
45. [ sin 2πx ] 1

If the integral ∫ 10
0 dx = αe − 1 + βe − 2 + γ, where α, β, γ are integers and [x] denotes the greatest integer less
ex − [ x ]
than or equal to x, then the value of α + β + γ is equal to :
(a) 0
(b) 20
(c) 10
(d) 25
46.
[ ] [ ]
1 2 0 2 −1 5
Let A + 2B = 6 −3 3 and 2A − B = 2 − 1 6 . If T r(A) denotes the sum of all diagonal elements of the
−5 3 1 0 1 2
matrix A, then T r(A) − T r(B) has value equal to :
(a) 3
(b) 1
(c) 2
(d) 0
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47. The angle between the straight lines, whose direction cosines are given by the equation 2l + 2m − n = 0 and
mn + nl + lm = 0, is :
π
(a)
3
(b) π − cos − 1
9 () 4
(c) cos − 1
π
9 () 8
(d)
2
48. If the sides AB, BC and CA of a triangle ABC have 3, 5 and 6 interior points respectively, then the total number of
triangles that can be constructed using these points as vertices, is equal to :
(a) 360
(b) 364
(c) 240
(d) 333
49.
The number of solutions of the equation sin − 1 x 2 + 3
[ 1
] [ ]
+ cos − 1 x 2 − 3
2
= x 2, for x ∈ [ − 1, 1], and [x] denotes
the greatest integer less than or equal to x, is :

(a) 4
(b) 0
(c) Infinite
(d) 2
50. π
The number of solutions of the equation x + 2 tanx = 2 in the interval [0, 2π] is :
(a) 4
(b) 5
(c) 3
(d) 2
51. Let f : [ − 1, 1] → R be defined as f (x) = ax 2 + bx + c for all x ∈ [ − 1, 1], where a, b, c ∈ R such that
1
f ( − 1) = 2, f ′ ( − 1) = 1 and for x ∈ ( − 1, 1) the maximum value of f ″ (x) is 2 . If f (x) ⩽ α, x ∈ [ − 1, 1], then
the least value of α is equal to ................ .
52.
Let the coefficients of third, fourth and fifth terms in the expansion of x +
( ) a
x2
n
, x ≠ 0, be in the ratio 12 : 8 : 3. Then
the term independent of x in the expansion, is equal to ............ .

(Round off the answer to nearest integer)
53.
Let A =
[ ]
a
c
b
d
and B = [] []
α
β
≠
0
0
such that AB = B and a + d = 2021, then the value of ad − bc is equal to
................ .
54. A line ‘l’ passing through origin is perpendicular to the lines

→
l 1 : r = (3 + t)î + (− 1 + 2t)ĵ + (4 + 2t)k̂
l 2 : →r = (3 + 2s)î + (3 + 2s)ĵ + (2 + s)k̂

If the co-ordinates of the point in the first octant on ‘l 2’ at a distance of √17 from the point of intersection of ‘l’ and ‘l 1’
are (a, b, c), then 18(a + b + c) is equal to:
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55. Let I = ∫ e x 19 (log | x | ) n dx, where n ∈ N. If (20) I = αI + βI , for natural numbers α and β, then α − β equals to
n 1 10 9 8
.............. .
56. Consider a set of 3n numbers having variance 4. In this set, the mean of first 2n numbers is 6 and the mean of the
remaining n numbers is 3. A new set is constructed by adding 1 into each of first 2n numbers, and subtracting 1 from each
of the remaining n numbers. If the variance of the new set is k, then 9k is equal to .................. .
57.
If 1, log 10 (4 x − 2) and log 10 4 x + 5 ( 18
) are in arithmetic progression for a real number x, then the value of the
| ( )
|
1
2 x− 2 x−1 x2
determinant is equal to :
1 0 x
x 1 0
58. ( 2n − 1 ) π
Let tanα, tanβ and tanγ ; α, β, γ ≠ 2
, n ∈ N be the slopes of three line segments OA, OB and OC,
respectively, where O is origin. If circumcentre of ΔABC coincides with origin and its orthocentre lies on y-axis, then the
value of
( cos 3α + cos 3β + cos 3γ 2
cos α cos β cos γ ) is equal to .................... .
59. Let f : [ − 3, 1] → R be given as
f (x) =
{ min {(x + 6), x 2},
max {√x, x 2} ,
−3 ⩽ x ⩽ 0
0 ⩽ x ⩽ 1.
If the area bounded by y = f(x) and x-axis is A, then the value of 6A is equal to ............ .
60. → → →
Let a, b, c be three mutually perpendicular vectors of the same magnitude and equally inclined at an angle θ, with the
→
vector a + b + c. Then 36cos 22θ is equal to ____
→ →
61. For 1 molal aqueous solution of the following compounds, which one will show the highest freezing point?
(a) [Co (H2O)3Cl3].3H2O
(b) [Co (H2O)6] Cl3
(c) [Co (H2O)5Cl] Cl2.H2O
(d) [Co (H2O)4Cl2] Cl.2H2O
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62. Which of the following compounds will be suitable for Kjeldahl's method of nitrogen estimation?
(a)
(b)
(c)
(d)
63. Given below are two statements:

Statement I: 2-methylbutane on oxidation with KMnO4 gives 2-methylbutan-2-ol.
Statement II: n-alkanes can be easily oxidised to corresponding alcohols with KMnO4.
Choose the correct option:
(a) Both statement I and statement II are incorrect
(b) Both statement I and statement II are correct
(c) Statement I is incorrect but statement II is correct
(d) Statement I is correct but statement II is incorrect
64. The common positive oxidation states for an element with atomic number 24, are:
(a) + 2 to + 6
(b) + 1 and + 3
(c) + 1 to + 6
(d) + 1 and + 3 and + 6
65. Choose the correct statement regarding the formation of carbocations A and B given.
(a) Carbocation B is more stable and formed relatively at faster rate

(b) Carbocation A is more stable and formed relatively at faster rate
(c) Carbocation B is more stable and formed relatively at slow a rate
(d) Carbocation A is more stable and formed relatively at slow rate
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66. The correct pair(s) of the ambident nucleophiles is (are) :

(A) AgCN/KCN
(B) RCOOAg/RCOOK
(C) AgNO2/KNO2
(D) AgI/KI
(a) (B) only
(b) (A) and (C) only
(c) (B) and (C) only
(d) (A) only
67. Primary, secondary and tertiary amines can be separated using :

(a) Benzene sulphonic acid
(b) Acetyl amide
(c) Chloroform and KOH
(d) para-Toluene sulphonyl chloride
68. Glucose on prolonged heating with HI gives

(a) 6-iodohexanal
(b) n-Hexane
(c) 1-Hexene
(d) Hexanoic acid
69.
In the above reaction, the structural formula of (A), “X” and “Y” respectively are :
(a)
(b)
(c)
(d)
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70. Amongst the following, the linear species is :

(a) Cl 2O
(b) NO 2
−
(c) N 3
(d) O 3
71. The increasing order of basicity of the following compounds is:
(A) (B) (C) (D)

(a) (D) < (B) < (A) < (C)
(b) (A) < (B) < (C) < (D)
(c) (B) < (A) < (C) < (D)
(d) (B) < (A) < (D) < (C)
72. Arrange the following labelled hydrogens in decreasing order of acidity :
(a) b>a>c>d
(b) b>c>d>a
(c) c>b>d>a
(d) c>b>a>d
73. Consider the following reaction and statements:

[Co (NH3)4Br2] + + Br– → [Co (NH3)3 Br3] + NH3
(I) Two isomers are produced if the reactant complex ion is a cis- isomer.
(II) Two isomers are produced if the reactant complex ion is a trans-isomer.
(III) Only one isomer is produced if the reactant complex ion is a trans-isomer.
(IV) Only one isomer is produced if the reactant complex ion is a cis isomer.
The correct statements are
(a) (II) and (IV)
(b) (I) and (II)
(c) (I) and (III)
(d) (III) and (IV)
74. Enzyme A
C 12H 22O 11 + H 2O → C 6H 12O 6 + C 6H 12O 6
Sucrose Glucose Fructose
Enzyme B
C 6H 12O 6 → 2C 2H 5OH + 2CO 2
Glucose
In the above reactions, the enzyme A and enzyme B respectively are :
(a) Invertase and Amylase
(b) Invertase and Zymase
(c) Amylase and Invertase
(d) Zymase and Invertase
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75. Nitrogen can be estimated by Kjeldahl’s method for which of the following compound ?
(a)
(b)
(c)
(d)
76. During which of the following processes, does entropy decrease?

(A) Freezing of water to ice at 0ºC
(B) Freezing of water to ice at – 10ºC
(C) N 2(g) + 3H 2 (g) → 2NH 3 (g)
(D) Adsorption of CO(g) on lead surface.
(E) NaCl(s) → Na + (aq) + Cl − (aq)
Choose the correct answer from the options given below:
(a) (A), (C) and (E) only
(b) (A), (B), (C) and (D) only
(c) (A) and (E) only
(d) (B) and (C) only
77. The set that represents the pair of neutral oxides of nitrogen is :
(a) N 2O and NO 2
(b) NO and N 2O
(c) N 2O and N 2O 3
(d) NO and N 2O 3
78. The trans-alkenes are formed by the reduction of alkynes with

(a) Sn − HCl
(b) H 2 − Pd / C, BaSO 4
(c) NaBH 4
(d) Na / liq. NH 3
79. Fructose is an example of :

(a) Aldohexose
(b) Heptose
(c) Pyranose
(d) Ketohexose
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80.
Match List-I with List-II :
List-I List-II
(A) [Co (NH 3) 6] [Cr (CN) 6] (i) Linkage isomerism
(B) [Co (NH 3) 3 (NO 2) 3] (ii) Solvate isomerism
(C) [Cr (H 2O) 6] Cl 3 (iii) Co-ordination isomerism
(D) cis − [CrCl 2 (ox) 2] 3−
(iv) Optical isomerism
Choose the correct answer from the options given below :
(a) (A) – (i), (iii), (B) – (i), (C) – (ii), (D) – (iv)
(b) (A) – (ii), (B) – (i), (C) – (iii), (D) – (iv)
(c) (A) – (iii), (i), (B) – (ii), (C) – (iii), (D) – (iv)
(d) (A) – (iv), (B) – (ii), (C) – (iii), (D) – (i)
81. A 1 molal K 4Fe(CN) 6 solution has a degree of dissociation of 0.4. Its boiling point is equal to that of another solution
A
which contains 18.1 weight percent of a non electrolytic solute A. The molar mass of 9 is ............... u. (Round off to the
Nearest Integer).
[Density of water = 1.0 g cm–3]
82. In the ground state of atomic Fe (Z = 26), the spin-only magnetic moment is .................... BM. (Round off to the Nearest
Integer).
[Given : √3 = 1.73, √2 = 1.41]
83. One complete reaction of FeCl3 with oxalic acid in aqueous solution containing KOH, resulted in the formation of
product A. The secondary valency of Fe in the product A is .......................... (Round off to the Nearest Integer).
84. The number of chlorine atoms in 20 mL of chlorine gas at STP is .............. 1021. (Round off to the Nearest Integer).
[Assume chlorine is an ideal gas at STP
R = 0.083 L bar mol–1 K–1, NA = 6.023 × 1023]
85. T
Consider the reaction N 2O 4(g) ⇌ 2NO 2(g). The temperature 60 at which K C = 20.4 and K P = 600.1, is ............. K.
(Round off to the Nearest Integer).
[Assume all gases are ideal and R = 0.0831 L bar K–1 mol–1]
86. The reaction 2A + B 2 → 2AB is an elementary reaction.

For a certain quantity of reactants, if the volume of the reaction vessel is reduced by a factor of 3, the rate of the reaction
increases by a factor of .................. (Round off to the Nearest Integer).
87. A KCl solution of conductivity 0.14 S m–1 shows a resistance of 4.19 Ω in a conductivity cell. If the same cell is filled
with and HCl solution, the resistance drops to 1.03 Ω. The conductivity of the HCl solution is ............... × 10–1 S m–1.
(Round off to the Nearest Integer).
88. The total number of C–C sigma bond/s in mesityl oxide (C 6H 10O)is ............... (Round off to the Nearest Integer).
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89. For the disproportionation reaction 2Cu + (aq) ⇌ Cu(s) + Cu 2 + (aq)at 298 K, In K (where K is the equilibrium constant)
0 0 RT
is ………… × 10–1. Given (E Cu 2 + / Cu + = 0.16 V E Cu + / Cu = 0.52 V F = 0.025)
90.
Consider the above reaction. The percentage yield of amide product is ................ . (Round off to the Nearest Integer).
(Given: Atomic mass : C : 12.0 u, H : 1.0 u, N : 14.0 u, O : 16.0 u, Cl : 35.5 u)
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Answer Key
1. D 2. B 3. D 4. D 5. C 6. D
7. B 8. B 9. B 10. B 11. C 12. D
13. D 14. A 15. D 16. A 17. B 18. C
19. C 20. B 21. 3.00 22. 5.00 23. 30.00 24. 25.00
25. 3.00 26. 640.00 27. 4.00 28. 30.00 29. 16.00 30. 6.00
31. A 32. B 33. B 34. B 35. C 36. B
37. A 38. D 39. C 40. A 41. D 42. C
43. B 44. A 45. A 46. C 47. D 48. D
49. B 50. C 51. 5.00 52. 4.00 53. 2020.00 54. 44.00
55. 1.00 56. 68.00 57. 2.00 58. 144.00 59. 41.00 60. 4.00
61. A 62. C 63. D 64. A 65. A 66. B
67. D 68. B 69. C 70. C 71. D 72. B
73. C 74. B 75. C 76. B 77. B 78. D
79. D 80. A 81. 9.00 82. 5.00 83. 6.00 84. 1.00
85. 6.00 86. 27.00 87. 4.00 88. 5.00 89. 144.00 90. 77.00
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Solutions
1. (D)
h = h 0e 2
81
⇒ = e 2 ⇒ e = 0.9
100
S total = h 0 + 2h 1 + 2h 2 + 2h 3 + . . .
[ (
= h0 1 + 2 e2 + e4 + e6 + . . . )]
[
= h0 1 + 2 × e2
1 − e2 ( ) ( )]1
= h0
1 + e2
1 − e2
2h 0
T total =
√ g [1 + 2 × e + 2e 2
+.... ]
√ [ ( ) ( )]
2×5 1 1+e
= 10
1 + 2e 1 − e =1× 1−e
( )
( )
5 × 1 + 0.9 2 1 − 0.9
∴ V av = × 1 + 0.9
= 2.50 m / s
( 1 − 0.9 2 )
2. (B)
f = 4 + 3 + 3 = 10
Assuming non linear molecule:
Cp 2 12
β = C = 1 + f = 10 = 1.2
v
3. (D)
ˉ D Y
A B C C
0 0 0 1 0 0
0 1 0 1 1 1
1 0 0 1 1 1
1 1 1 0 1 0
Hence it is a XOR gate
4. (D)
P = hρg
p 2 × 10 3 × 10 3 × 9.8
β = ΔV =
1.36 × 10 − 2
V
= 1.44 × 10 9N / m 2
5. (C)
T ∝ R3 / 2
24
T
= ( ) 12R 3 / 2
3R
⇒ T = 3hr
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6. (D)
ω = 2πf
= (1.5 × 10 3)rad / s
6
A= = 3cm = 0.03m
2
7. (B)
Option (a) is wrong; since in adiabatic process V ≠ constant.
Option (b) is wrong, since in isothermal process T = constant
Option (c) & (d) matches isotherms & adiabatic formula:
Tγ
TV γ − 1 = constant & = constant
Pγ − 1
8. (B)
v = v 0 + gt + Ft 2
ds
dt
= v 0 + gt + Ft 2
1
(
∫ ds = ∫ v 0 + gt + Ft 2 dt
0
)
[ ]
1
gt 2 Ft 3
s = v 0t + 2 + 3
0
g F
s = v0 + 2 + 3
9. (B)
3E
i=
R + r1 + r2
TPD = 2E − ir 1 = 0
2E = ir 1
3E × r 1
2E = R + r + r
1 2
2R + 2r 1 + 2r 2 = 3r 1
r1
R = 2 − r2
10. (B)
B = 2 × B st.wire + B loop
()
μ 0i μ 0i π
B = 2 × 4πr + 2r 2π
μ 0i
B = 4πr (2 + π)
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11. (C)
x − 10 x−y x−0
100
+ 15 + 10 = 0
53x − 20y = 30 ……(1)
y − 10 y−x y−0
60
+ 15 + 5 = 0
17y − 4x = 10 …….(2)
On solving (1) & (2)
x = 0.865 V
y = 0.792 V
ΔV = 0.073V&R = 15Ω
i = 4.87mA
12. (D)
A 1ω 1 = A 2ω 2
√ √
K1 K2
A1 = A2
m m
A1 K2
A2
=
√ K1
13. (D)
VC − VL XC − XL
(d) tanϕ = VR
= R
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14. (A)
V
C comes to rest and V cm of A & B = 2
Maximum compression occurs when velocities of A and B are equal.
By using energy conservation:
1 1 1
2
mv 2 − 4 mv 2 = 2 Kx 2
m
v
√ 2K
=x
15. (D)
Balmer series lies in visible region.
16. (A)
1 2
2
mv 1 = hf 1 − ϕ
1 2
2
mv 2 = hf 2 − ϕ
2h
2 2
v1 − v2 = m f1 − f2 ( )
17. (B)
X L = ωL
V0
i = ωL
So, inductive reactance will be halved and current will be doubled.
18. (C)
gsin θ 5 10 25
a= I = 7 × 2 = 7 m / s2
1+
mR 2
2v 0 2×1×7
t= a = 25
= 0.56s
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19. (C)
Resultant Intensity
I= (√I1 + √I2 )2
⇒I= I+I+2( √ (I1I2 ))
⇒ I = 2I + 2I
⇒ I = 4I. . . (1)
For calculating the intensity of the Young's double slit experiment with the incoherent sources, another formula is used
I = I1 + I2
⇒I=I+I
⇒ I = 2I. . . (2)
The ratio of the intensity,
4I : 2I = 2 : 1
20. (B)
(
x = 0.05 sin 10 t + 2
π
)
A = 0.05 m,x = 0.025 m
v = ω A2 − x2
√
= 10√(0.05) 2 − (0.025) 2
= 10√0.001875 = 0.43 m / s
21. (3.00)
100
⇒ c ∈ 0E 2 =
4π × 3 2
⇒ c ∈0
(√ ) x
5
E
2
=
60
4π × 3 2
x 3
⇒ 5 = 5
⇒x=3
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22. (5.00)
Fcosθ = μN
Fsinθ + N = mg
μmg
⇒ F=
cosθ + μsinθ
1
× 10
μmg √3
F min = = 2
=5
√ 1 + μ2
√3
23. (30.00)
N + T = 90
T = μN = 0.5(90 − T)
1.5T = 45
T = 30N
24. (25.00)
4 1
Volume of oleic acid = 100 × 3 πr 3 × 100
4
3
πr 3 = A × t
t = 25 × 10 − 14m
x = 25
25. (3.00)
− dU mv 2
F = dr = − 4U 0r 3 = r
-ve sign indicate that force is attractive in nature.
mv 2 = 4U 0r 4
v ∝ r2
nh
mvr =
2π
r3 ∝n
1
r ∝ n3
⇒α=3
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26. (640.00)
2
ϕ = E xA ⇒ 5 × 4 × 10 3 × 0.4 = 640
27. (4.00)
4a 4a
C.O.M of quarter disc is at 3π , 3π
=4
28. (30.00)
λa 3
λm = μ → μ = 2
μ 1 μ−1
v
−u = R
3
3 1 2
−1
2 × 10
+ 15 = R
30
R = 13 m
= 30
29. (16.00)
(
20 = C 1 + C 2 V ⇒ V = 2volt )
Q 2 = C 2V = 16μC
= 16
30. (6.00)
E V
J c = ρ = ρd
1 dq
J d = A dt
C dV c
= A dt
∈ dV c
= d dt
V 0sin 2πft 80ε 0
⇒ ρd
= 10 x × d V 0(2πf)cos2πft
(
tan 2π × 800
900
) = 10 x ×
10
9 × 10 9
× 900
=x=6
31. (A)
( πcos θ )
tan tan ( π − πsin θ )
2 2
lim = lim ( ∵ cos 2θ = 1 − sin 2 )

θ→0
( 2πsin θ ) θ → 0 sin ( 2πsin θ )
2 2
− tan θ ( πsin θ ) 2
= lim ( ∴ tan(π − θ) = − tanθ)

(
θ → 0 sin 2πsin θ
) 2
− tan ( πsin θ )
2
= lim
θ→0 sin
πsin 2θ
( 2πsin θ ) 2
×2
( As θ → 0
sin 2θ → 0 )
2πsin 2θ
= −2
1
( ∵ lim
θ→0
sin θ
θ
= 1 and lim
θ→0
tan θ
θ
=1
)
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32. (B)
(r − 1) < [r] ⩽ r
(2r − 1) < [2r] ⩽ 2r
.
.
.
(nr − 1) < [nr] ⩽ nr
Adding
n(n+1) n(n+1)
2
r − n < [r] + [2r] + . . . + [nr] ⩽ 2
r
n(n+1)
2
r−n [ r ] + [ 2r ] + . . . . . . + [ nr ] n(n+1)
lim ⩽ lim ⩽ lim r
n→∞ n2 n→ ∞ n2 n→∞ 2n 2
r [ r ] + [ 2r ] + . . . . . . + [ nr ] r
⇒ 2 ⩽ lim ⩽ 2
n→ ∞ n2
[ r ] + [ 2r ] + . . . . . . + [ nr ] r
⇒ lim = 2
n→ ∞ n2
33. (B)
1 1
P(0 at even place) = 2 , P(0 at odd place) = 3
1 2
P(1 at even place) = 2 , P(1 at odd place) = 3
P(1001) = P(OEOE) + P(EOEO)
=
(
1
2
3
×2×3×2
1
1
1 1
) ( +
1
2
1
×3×2×3
1 2
)
= 18 + 18
1
= 9
34. (B)
{ ( )
1
− 2 − sin x x, x<0
f(x) = 0, x=0
( )
2 − sin x x,
1
x>0
( )(
) )
{ (
1 1 1
− x − cos x − − 2 − sin x , x<0
x2
f ′ (x) =
( )( ) ( )
x − cos x
1
−
x2
1
+ 2 − sin x ,
1
x>0
{
1 1 1
− x cos x + sin x − 2, x<0
= 1 1 1
x
cos x − sin x + 2, x>0
f ′ (x) changes its sign on (0, 1)

Also f ′ (x) changes its sign on (− 1, 0)
Hence, f(x) is not monotonic on (− ∞, 0) and (0, ∞)
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35. (C)
2
t1 = − t −
t
2 4
t1 = t2 + 2 + 4
t
A.M. ≥ G.M.
4
t2 +
t2
2
⩾ √4
4
t2 + ⩾4
t2
4
t2 + +4⩾8
t2
2
t1 ⩾ 8
2
Minimum value of t 1 = 8
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36. (B)
cosx(3sinx + cosx + 3)dy = (1 + ysinx(3sinx + cosx + 3))dx . . . (1)
(3sinx + cosx + 3)(cosx dy − ysinx dx) = dx
dx
∫ d(y. cosx) = ∫ 3sin x + cos x + 3
dx
ycosx = ∫
( )( )
x x
2tan 2 1 − tan 2 2
3 x + x +3
1 + tan 2 2 1 + tan 2 2
x
sec 2 2 dx
ycosx = ∫ x x x
6tan 2
+ 1 − tan 2 2 + 3 + 3tan 2 2
x 1 x
sec 2 2 dx 2
sec 2 2 dx
ycosx = ∫ x x =∫ x x
2tan 2 2 + 6tan 2
+4 tan 2 2 + 3tan 2
+2
x 1 x
Put tan 2 = t in the integral ⇒ 2 sec 2 2 dx = dt
dt
ycosx = ∫
t 2 + 3t + 2
dt
ycosx = ∫
( ) ()
t+ 2
3 2
−
1
2
2
| | t+1
ycosx = ln t + 2 + C
| |
x
tan 2
+1
ycosx = ln x +C
tan 2
+2
At x = 0, y = 0
⇒ C = − ln 2
() 1
= ln(2)
() | |
π 1 + √3
y 3 = 2ln + ln2
1 + 2√ 3
| |
5 + √3
= 2ln 11
+ ln2
| |
2√3 + 10
= 2ln 11
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37. (A)
F ′ (x) = f(x) by Leibnitz theorem
1 1
( )
Let I = ∫ F ′ (x) + f(x) e xdx = ∫ 2f(x)e xdx
0 0
1
1
I = ∫ 2sinx dx = 2[− cosx] 0
0
I = 2(1 − cos1)
{ ( 12 14
= 2 1 − 1 − 2! + 4! − 6! + . . .
1
)}
{ (
⇒ 2 1 − 1 − 2 + 24
330
1 1
331
)} { ( 1 1 1
< 2(1 − cos1) < 2 1 − 1 − 2 + 24 − 720
)}
360
< 2(1 − cos1) < 360
330 331
360
< I < 360
38. (D)
Let (h, k) is centre of circle
| |
h−k
√2
= |h|
k 2 − h 2 + 2hk = 0
∴ Equation of locus is y 2 − x 2 + 2xy = 0
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39. (C)
( ( ) ( )
)
1 3 1 2
x3 + 13 x2 − (1) 2 10
2 1 −
x3 −x3 +1
( )
1 1
x2 x2 −1
( )( ) ( )( )
1 2 1 1 1
( ( ) ( ))
x3 + 1 x3 − x3 + 1 x2 + 1 x2 − 1 10
⇒ −
2 1 1 1
x3 − x3 + 1 x2 x2 − 1
( ) 1
(( ) )
x2 + 1 10
1
⇒ x3 + 1 − 1
x2
⇒
( 1
x3 + 1 − 1 − x− 2
1
) 10
(
= x3 − x− 2
1 1
) 10
Thus General term for the expansion is
= 10C r x 3
() ( )
1 10 − r
10 − r
−x − 2
−r
1 r
= 10C r(− 1) rx 3 x 2
10 − r r
= 10C r(− 1) rx 3
−2
Now,
10 − r r
3
− 2 = −5
20 − 2r − 3r
⇒ 6
= −5
⇒ 20 − 5r = − 30
⇒ − 5r = − 50
r = 10
Co-efficient of x − 5 = 10C 10(− 1) 10
=1
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40. (A)
9
dy y x4
dx
− 2x =
( )
5 3
x4 x4 +1
1 1 1
IF = e − ∫ 2x dx = e − 2 ln x = 1
x2
9 1
1 x4 .x− 2
y. x − 2 = ∫ dx
( )
5 3
x4 x4 +1
1
1 x2
y. x − 2 = ∫ dx
( )
3
x4 +1
In the integral, put x = t 4 ⇒ dx = 4t 3dt

1 t 2.4t 3dt
⇒ y. x − 2 = ∫
(t +1 ) 3
1 t2 (t +1−1 )
3
y. x − 2 = 4∫ dt
( )
t + 1 3
1 t2
y. x − 2 = 4∫ t 2dt − 4∫ dt
t3 + 1
1 4t 3
( )
4
y. x − 2 = 3 − 3 ln t 3 + 1 + C
( )
3
1 4x 4 4 3
−2
y. x = 3 − 3 ln x 4 + 1 + C
It passes through the point 1, 1 − 3 log e2 ( 4

)
4 4 4
1 − 3 log e2 = 3 − 3 log e2 + C
1
⇒ C= −3
So, equation of the curve is
4 5
4
4
y = 3 x 4 − 3 √xln x 4 + 1 − 3
( )
4
3 √x
4
y(16) = 3 × 32 − 3 × 4ln9 − 3
124 32
= 3 − 3 ln3 = 4 3 − 3 ln3 ( 31 8
)
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41. (D)
| |
3 4√2 x
4 5√2 y =0
5 k z
R 1 → R 1 + R 3 − 2R 2
| |
0 4√2 + k − 10√2 0
4 5√2 y = 0 { ∵ 2y = x + z}
5 k z
⇒ (k − 6√2 )(4z − 5y) = 0
k = 6√2 or 4z = 5y
Now, 4z = 5y ⇒ x = 3d which is not possible.
So, k = 6√2
k 2 = 72
42. (C)
Let, z = x + iy
S 1 ≡ (x − 1) 2 + y 2 ⩽ 2 . . . (1)
S2 ≡ x + y ⩾ 1 . . . (2)
S3 ≡ y ⩽ 1 . . . (3)
⇒ S 1 ∩ S 2 ∩ S 3 has infinitely many elements.
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43. (B)
AB = √26
r 2 = CM 2 + AM 2
( √ ) (√ )
= 2×
13 2
2
+
13 2
2
65
r2 = 2
44. (A)
| |
î ĵ k̂
ˉ
aˉ × b = 2 1 −2
1 1 0
aˉ × bˉ = 2î − 2ĵ + k̂
|aˉ × bˉ | = 3
Given, |(aˉ × bˉ ) × cˉ | = 3
|aˉ × bˉ | |cˉ |sin30 ∘ = 3

1
⇒ 3 |cˉ |. =3
2
⇒ |cˉ | = 2
Now, |cˉ − aˉ | = 3
|cˉ | 2 + |aˉ | 2 − 2aˉ . cˉ = 9
⇒ 4 + 9 − 2ˉa. cˉ = 9
⇒ aˉ . cˉ = 2
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45. (A)
Given integral
10 [ sin 2πx ] 1 [ sin 2πx ]
∫ dx = 10∫ dx (using property of definite integration)
0 ex − [ x ] 0 e {x}
[ ]
1
2 1 −1
[ ]
1
= 10 ∫ 0.dx + ∫ dx = 10 e − x 1
0 1 ex
2
2
[ ]
1 1
= 10 e − 1 − e − 2 = 10e − 1 − 10e − 2
Comparing with the given relation,

α = 10, β = − 10, γ = 0
α+β+γ=0
46. (C)
( )
1 2 0
A + 2B = 6 −3 3 . . . (1)
−5 3 1
( )
2 −1 5
2A − B = 2 −1 6
0 1 2
( )
4 −2 10
⇒ 4A − 2B = 4 −2 12 . . . . (2)
0 2 4
( )
5 0 10
(1) + (2) ⇒ 5A = 10 −5 15
−5 5 5
( ) ( )
1 0 2 2 0 4
A= 2 −1 3 and 2A = 4 −2 6
−1 1 1 −2 2 2
( )( )
2 0 4 2 −1 5
∴ B= 4 −2 6 − 2 −1 6
−2 2 2 0 1 2
( )
0 1 −1
B= 2 −1 0
−2 1 0
tr(A) = 1 − 1 + 1 = 1
tr(B) = − 1
tr(A) = 1 and tr(B) = − 1
∴ tr(A) − tr(B) = 2
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47. (D)
We have
2l + 2m − n = 0
n = 2(l + m) and
mn + nl + lm = 0,
lm + n(l + m) = 0
lm + 2(l + m) 2 = 0
2l 2 + 2m 2 + 5ml = 0
()
2 m
l 2
+2+5 m ()
l
=0
l
Let m = t
2t 2 + 5t + 2 = 0
(t + 2)(2t + 1) = 0
1
⇒ t = − 2 or t = − 2
(i) t = − 2
l n
⇒ m = − 2 and m = − 2
∴ (− 2m, m, − 2m)
⇒ (− 2, 1, − 2)
1
(ii) t = − 2
l 1
⇒ m = − 2 and n = − 2l
∴ (l, − 2l, − 2l)
⇒ (1, − 2, − 2)
−2−2+4 π
cosθ = =0⇒θ= 2
√ 9√ 9
48. (D)
Total number of triangles = 14C 3 − 3C 3 − 5C 3 − 6C 3 = 364 − 1 − 10 − 20 = 333
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49. (B)
x ∈ [− 1, 1] ⇒ 0 ⩽ x 2 ⩽ 1
1 2 2
Possible integral value of x 2 + 3 is 1 and possible integral value of x 2 − 3 is 0 which occur at x 2 = 3
Let us consider two cases :
2
Case I: 0 ⩽ x 2 < 3
⇒ [ ] [ ]
x2 + 3
1
=0,
2
x2 − 3 = −1
∴ sin − 1(0) + cos − 1(− 1) = x 2

⇒ 0 + π = x2
⇒ x = ± √π → (Reject)
2
Case II: 3 ⩽ x 2 ⩽ 1
⇒
[ ] [ ]
x2 + 3
1
=1,
2
x2 − 3 =0
∴ sin − 1(1) + cos − 1(0) = x 2

⇒ x 2 = π ⇒ x = ± √π (Reject)
50. (C)
π
x + 2tanx = 2 in [0, 2π]
π
2tanx = 2 − x
π x
tanx = 4 − 2
−x π
Consider graphs of y = tanx and y = 2 + 4
3 intersection points
∴ 3 solutions
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51. (5.00)
f(x) = ax 2 + bx + c
f ′ (x) = 2ax + b
f ″ (x) = 2a
1 1 1
Given, maximum value of f ″ (x) = 2 ⇒ 2a = 2 ⇒ a = 4
3
f ′ (− 1) = 1 ⇒ b − 2a = 1 ⇒ b = 2
13
f(− 1) = a − b + c = 2 ⇒ c = 4
( )
1
So, f(x) = 4 x 2 + 6x + 13 , x ∈ [− 1, 1]
1
f ′ (x) = 2 (x + 3) = 0 ⇒ x = − 3 ∉ [− 1, 1]
f(1) = 5, f(− 1) = 2
f(x) ⩽ 5
So α minimum = 5
52. (4.00)
T r + 1 = n C r x n − r. 2
x () a r
= nC r a rx n − 3r
T 3 = nC 2a 2x n − 6, T 4 = nC 3a 3x n − 9, T 5 = nC 4a 4x n − 12
coefficient of T 3 nC 2
2.a 3 3
Now, coefficient of T = n = a(n−2) = 2
4 C3 . a3
⇒ a(n − 2) = 2 . . . (i)
coefficient of T 4 nC 3
3.a 4 8
And coefficient of T = n = a(n−3) = 3
5 C4 . a4
3
⇒ a(n − 3) = 2 . . . (ii)
1
By (i) and (ii) n = 6, a = 2
For term independent of ′ x ′
n 6
n − 3r = 0 ⇒ r = 3 ⇒ r = 3 = 2
T 3 = 6C 2 2
() 1 2 15
x 0 = 4 = 3.75 ≈ 4
53. (2020.00)
A=
[ ] []
a
c
b
d
, B=
α
β
AB = B
[ ][ ] [ ]
a
c
b
d
α
β
=
α
β
[ ] []
aα + bβ
cα + dβ
=
α
β
⇒
aα + bβ = α
and cα + dβ = β
. . . (1)
. . . (2)
α(a − 1) = − bβ and cα = β(1 − d)
α −b α 1−d
β
= a − 1 and β = c
−b 1−d
∴ a−1 = c
− bc = a − ad − 1 + d
ad − bc = a + d − 1 = 2021 − 1 = 2020
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54. (44.00)
→
l 1 : r = (3 + t)î + (− 1 + 2t)ĵ + (4 + 2t)k̂
→
l 2 : r = (3 + 2s)î + (3 + 2s)ĵ + (4 + s)k̂
DR of l 1 ≡ (1, 2, 2)
DR of l 2 ≡ (2, 2, 1)
(
DR of l line ⊥ to l 1 and l 2 )
= (− 2, 3, − 2)
→
∴ l : r = − 2μî + 3μĵ − 2μk̂
For intersection of l and l 1
3 + t = − 2μ
− 1 + 2t = 3μ
4 + 2t = − 2μ
⇒ t = − 1 and μ = − 1
∴ Point of intersection P ≡ (2, − 3, 2)
Let point on l 2 be Q(3 + 2s, 3 + 2s, 2 + s)
Given PQ = √17 ⇒ (PQ) 2 = 17
⇒ (2s + 1) 2 + (6 + 2s) 2 + (s) 2 = 17
⇒ 9s 2 + 28s + 20 = 0
10
⇒ s = − 2, − 9
s ≠ − 2 as point lies on 1st octant.
∴ a=3+2 − 9 ( ) 10 7
= 9
b=3+2 − ( ) 10
9
=
7
9
c=2+ − ( ) 10
9
=
8
9
∴ 18(a + b + c) = 18 9 ()
22
= 44
55. (1.00)
e
I n = 2∫ x 19(lnx) ndx
1
|
e e ( ln x ) n − 1 x 20
x 20
= (lnx) n. 20
− ∫n x 20
dx
1 1
e 20 n
I n = 20 − 20 I n − 1 ( )
20I n = e 20 − n I n − 1
(
20I 10 = e 20 − 10I 9 ) . . . (1)
20I 9 = e 20 − 9I 8 . . . (2)
eq n(1) − eq n(2)
20I 10 = 10I 9 + 9I 8
α = 10, β = 9
⇒ α−β=1
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56. (68.00)
Let first 2n observations are x 1, x 2. . . . , x 2n
And last n observations are y 1, y 2. . . , y n
∑ xi ∑ yi
Now, 2n = 6, n
=3
∑ xi + ∑ yi 15n
⇒ ∑ x i = 12n, ∑ y i = 3n ∴ 3n
= 3n = 5
2 2
∑ xi + ∑ yi
Now, 3n
− 52 = 4
2 2
⇒ ∑ x i + ∑ y i = 29 × 3n = 87n
∑ ( xi + 1 ) + ∑ ( yi − 1 ) 15n + 2n − n 16
New mean is 3n
= 3n
= 3
( xi + 1 ) 2 + ∑ ( yi − 1 ) 2
()
∑ 16 2
New variance is 3n
− 3
2 2
( ∑ xi − ∑ yi ) + 3n
()
∑ xi + ∑ yi + 2 16 2
= 3n
− 3
=
87n + 2 ( 9n ) + 3n
3n () −
16 2
3
= 29 + 6 + 1 −
324 − 256 68
() 16 2
3
= 9
= 9 =k
⇒ 9k = 68
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57. (2.00)
(
1, log 10 4 x − 2 , log 10 4 x + 5 ) ( 18
) are in AP.
(
2. log 10 4 x − 2 = 1 + log 10 4 x + 5 ) ( ) 18
(
log 10 4 x − 2 ) 2
( ( ))
= log 10 10. 4 x + 5
18
(4 − 2 ) = 10. 4 +
x 2
( ) x
18
5
(4 ) + 4 − 4.4 = 10.4 + 36
x 2 x x
(4 ) − 14.4 − 32 = 0
x 2 x
(4 ) + 2.4 − 16.4 − 32 = 0
x 2 x x
4 (4 + 2 ) − 16. (4 + 2 ) = 0
x x x
(4 + 2 )(4 − 16 ) = 0
x x
4 x = 16
x=2
| ( )
|
1
2 x− 2 x−1 x2
Therefore
1 0 x
x 1 0
| |
3 1 4
= 1 0 2
2 1 0
= 3(− 2) − 1(0 − 4) + 4(1 − 0)
= −6+4+4
=2
58. (144.00)
Orthocenter and circumcentre both lie on y − axis
⇒ Centroid also lies on y − axis
⇒ ∑ cosα = 0
cosα + cosβ + cosγ = 0
⇒ cos 3α + cos 3β + cos 3γ = 3cosαcosβcosγ
cos 3α + cos 3β + cos 3γ
∴ cos αcos βcos γ
( )
4 cos 3α + cos 3β + cos 3γ − 3 ( cos α + cos β + cos γ )
= cos αcos βcos γ
= 12
Then, ( cos 3α + cos 3β + cos 3γ 2

cos αcos βcos γ ) = 144
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59. (41.00)
−2 0 1
Area = A = ∫ (x + 6)dx + ∫ x 2dx + ∫ √xdx
−3 −2 0
[ ] [] [ ]
−2 0 1
(x+6) 2 x3 2 3
= 2
+ 3
+ 3x2
−3 −2 0
7 8 2 41
= 2+3+3 = 6
So, 6A = 41
60. (4.00)
||
→
Let | a | = b = | c | = k
→ →
We have
|a + b + c | 2 = |a |2 + | b |2 + | c | 2 + 2 ( a. b + a. c + b. c )
→ → → → → → → → → → → →
⇒ | a + b + c | = 3k 2
→ →2 →
⇒ | a + b + c | = √3k
→ → →
a. (a + b + c ) = |a | |a + b + c |cosθ
→ → → → → → → →
⇒k= √3kcosθ
1
⇒ cosθ =
√3
1
⇒ cos2θ = − 3
∴ 36cos 22θ = 36 9
() 1
=4
61. (A)
For highest freezing point, ΔTf must be minimum & hence i should be minimum
(a) i = 1
(b) i = 4
(c) i = 3
(d) i = 2
62. (C)
Kjeldahl’s is suitable for Aniline. This method is used for quantitative analysis of N compound in organic substance
(NH3/NH4+)
about:blank 43/50
63. (D)
KMnO 4
n-Alkanes → No reaction
64. (A)
Chromium has 24 atomic number and it shows oxidation state from +2 to +6
65. (A)
B carbocation is more stable due to more hyperconjugation & it form relatively faster rate compared to A.
66. (B)
Ambident nucleophile
(A) KCN and AgCN
(C) AgNO2 and KNO2
67. (D)
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68. (B)
69. (C)
70. (C)
+
ˉ =N=N
(1) N ˉ
sp (linear)
(2)
sp 3 (bent)
(3)
sp 2 (bent)
(4)
sp 2 (bent)
about:blank 45/50
71. (D)
Basicity α availability of lone pair.
(B) < (A) < (D) < (C)
72. (B)
So, the answer is b > c > d > a
Hence, option (b) is correct
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73. (C)
74. (B)
Invertase
C 12H 22O 11 + H 2O → C 6H 12O 6 + C 6H 12O 6
Glucos e Fructose
Zymase
C 6H 12O 6 → 2C 2H 5OH + 2CO 2
75. (C)
For this compound, nitrogen can be estimated by Kjeldahl’s method.
76. (B)
A, B → Freezing of water will decrease entropy as particles will move closer and forces of attraction will increase. This leads
to decrease in randomness. So entropy decrease.
C → No. of molecules decreasing
D → Adsorption will lead to decrease in randomness of gaseous particles.
E → NaCl(s) → Na + (aq) + Cl − (aq)ΔS > 0
So, (A,B,C,D) decreases entropy
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77. (B)
NO and N2O are neutral oxides and N2O3, NO2 and N2O5 are acidic oxides.
78. (D)
Birch reduction
79. (D)
Fructose is an example of Ketohexose.
80. (A)
List-I List-II
(A) [Co (NH 3) 6] [Cr (CN) 6] (i) Co-ordination isomerism, linkage isomerism
(B) [Co (NH 3) 3 (NO 2) 3] (ii) Linkage isomerism
(C) [Cr (H 2O) 6] Cl 3 (iii) Solvate isomerism
(D) cis − [CrCl 2 (ox) 2] 3 − (iv) Optical isomerism
81. (9.00)
Since boiling point is same,
⇒ elevation in boiling point is also same for both solution.
(ΔTB )k [ Fe ( CN )
4 6 ] = (ΔT B ) A
( )
⇒ ik bm
k 4 [ Fe ( CN ) 6 ]
= ik bm ( )
A
18.1
1 × M × 1000
(1 + 4α) × 1 =
100 − 18.1
18.1 1000
⇒ 2.6 = ×
M 81.9
⇒ M = 85
M 85
9
= 9 = 9.44
∴ Nearest integer is 9
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82. (5.00)
Fe : 1s 22s 22p 63s 23p 63d 64s 2
In 3d 6, no. of unpaired e − = 4
Spin only magnetic moment = √n(n + 2)
= √4(4 + 2)
= √24
= 4.9
Nearest integer is 5
83. (6.00)
FeCl 3 + 3H 2C 2O 4 + 6KOH → K 3 Fe C 2O 4
3[ ( )]
+ 3KCl + 6H 2
(A)
CN = 6
S.V. = C.N
84. (1.00)
PV
n=
RT
1 × 20 × 10 − 3
=
0.083 × 273
1 × 20 × 10 − 3
No. of atoms = 0.083 × 273 × 2 × 6.023 × 10 23
= 1.06 × 10 21
85. (6.00)
K P = K C(RT) Δn g, Δn g = 1(For given reaction)
600.1 = 20.4(RT) 1
⇒ T ≈ 354K
T 354
60
= 60 ≃ 6
86. (27.00)
For elementary reaction,
Rate of reaction = K[A] 2 B 2 [ ]
Initial rate = K V
0( )( )
nA 2 nB
V0
( ) ( ) ( )( )
Final rate = K V / 3
0
nA 2 nB
V0 / 3
= 27K V
0
nA nB
V0
⇒ Final rate = 27 × Initial rate
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87. (4.00)
For KCl solution, conductivity = G G* = (1/R) G*
⇒ G* = k × R = 0.14 × 4.19 = 0.5866 m–1
Now when same cell is filled with HCl, conductance will be additive,
GHCl + GKCl = (1/R2)
1 1
⇒ GHCl = 1.03 – 4.19 = 0.7322 S
Thus, conductivity of HCl = G G* = 0.7322 × 0.5866 = 0.4295 = 4.295 × 10–1 S m–1
Nearest integer is 4
88. (5.00)
89. (144.00)
2Cu + ⇌ Cu(s) + Cu + 2
E o = 0.52 – 0.16
= 0.36
RT
E o = nF ln (k eq)
0.36 1
ln (k eq) = 0.025 × 1
360
= 25 = 14.4
= 144 × 10 − 1
Ans. 144
90. (77.00)
0.14 0.388
mol mol
140.5 1600
10 − 3 mol 2.29 × 10 − 3
L.R.
Stoichiometric moles of amide = 10 − 3 mol
Actual moles of amide = 7.69 × 10 − 4 mol
7.69 × 10 − 4
% yield = × 100
10 − 3
= 76.9%
= 77%
about:blank 50/50

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1/24/24, 11:25 AM Vedantu - JEE Main Simulator

Vedantu - JEE Main Simulator

(a) NOR Gate

(b) Y(x, t) = 0.06 [sin5.1x − (1.5 × 10 )t ]

(c) Y(x, t) = 0.06 [sin0.8x − (0.5 × 10 )t ]

(d) Y(x, t) = 0.03 [sin5.1x − (1.5 × 10 )t ]

(a) (c) and (a)

13. Match List-I with List-II

(a) Phase difference between current π

(b) Phase difference between current (ii) Zero

(c) Phase difference between current π

(d) Phase difference between current

34. Consider the function f : R → R defined by

36. Let y = y(x) be the solution of the differential equation

The coefficient of x − 5 in the binomial expansion of

40. If the curve y = y(x) is the solution of the differential equation

4 5√ 2 y is zero, then the value of k 2 is :

42. Let S 1, S 2 and S 3 be three sets defined as

45. [ sin 2πx ] 1

the greatest integer less than or equal to x, is :

the term independent of x in the expansion, is equal to ............ .

54. A line ‘l’ passing through origin is perpendicular to the lines

l 2 : →r = (3 + 2s)î + (3 + 2s)ĵ + (2 + s)k̂

59. Let f : [ − 3, 1] → R be given as

63. Given below are two statements:

(a) Carbocation B is more stable and formed relatively at faster rate

66. The correct pair(s) of the ambident nucleophiles is (are) :

67. Primary, secondary and tertiary amines can be separated using :

68. Glucose on prolonged heating with HI gives

70. Amongst the following, the linear species is :

71. The increasing order of basicity of the following compounds is:

(A) (B) (C) (D)

72. Arrange the following labelled hydrogens in decreasing order of acidity :

73. Consider the following reaction and statements:

76. During which of the following processes, does entropy decrease?

78. The trans-alkenes are formed by the reduction of alkynes with

79. Fructose is an example of :

Choose the correct answer from the options given below :

(b) (A) – (ii), (B) – (i), (C) – (iii), (D) – (iv)

(d) (A) – (iv), (B) – (ii), (C) – (iii), (D) – (i)

86. The reaction 2A + B 2 → 2AB is an elementary reaction.

Hence it is a XOR gate

The ratio of the intensity,

lim = lim ( ∵ cos 2θ = 1 − sin 2 )

= lim ( ∴ tan(π − θ) = − tanθ)

f ′ (x) changes its sign on (0, 1)

Thus General term for the expansion is

In the integral, put x = t 4 ⇒ dx = 4t 3dt

It passes through the point 1, 1 − 3 log e2 ( 4

|aˉ × bˉ | |cˉ |sin30 ∘ = 3

Comparing with the given relation,

Total number of triangles = 14C 3 − 3C 3 − 5C 3 − 6C 3 = 364 − 1 − 10 − 20 = 333

∴ sin − 1(0) + cos − 1(− 1) = x 2

∴ sin − 1(1) + cos − 1(0) = x 2

Then, ( cos 3α + cos 3β + cos 3γ 2

Chromium has 24 atomic number and it shows oxidation state from +2 to +6

(A) KCN and AgCN

(C) AgNO2 and KNO2

(B) < (A) < (D) < (C)

So, the answer is b > c > d > a

Hence, option (b) is correct

For this compound, nitrogen can be estimated by Kjeldahl’s method.