(0999DJM210321018) Test Pattern

DISTANCE LEARNING PROGRAMME

JEE (Main)
MAJOR
(Academic Session : 2021 - 2022) 13-03-2022

JEE(Main) : LEADER TEST SERIES / JOINT PACKAGE COURSE

ANSWER KEY
PART-1 : PHYSICS
Q. 1 2 3 4 5 6 7 8 9 10
A. A A A C A C B D A A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A D C D D A D D A D
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 60.00 5.00 9.00 2.00 5.00 10.00 15.00 150.00 0.73 200.00

PART-2 : CHEMISTRY
Q. 1 2 3 4 5 6 7 8 9 10
A. B C D D B B C C A A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. D D C B B D A A C A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 9.00 50.00 2.00 50.00 7.00 3.00 8.00 4.00 14.00 2.00

PART-3 : MATHEMATICS
Q. 1 2 3 4 5 6 7 8 9 10
A. A B D A C C D A C A
SECTION-I
Q. 11 12 13 14 15 16 17 18 19 20
A. A A C B D C D C D A
Q. 1 2 3 4 5 6 7 8 9 10
SECTION-II
A. 256.00 2.00 2.66 12.00 4.00 7.00 12.00 5.00 1997.00 10.00

HINT – SHEET
PART-1 : PHYSICS 5. Ans ( A )
20 100
SECTION-I ϕ1 = , ϕf =
ε0 ε0
3. Ans ( A ) ϕf = 5ϕ i
Frequency detected by Indian submarine Δϕ = ϕ f − ϕi = 4ϕ i
v + vsub
n′ = n [ ]
6. Ans ( C )
v − vsub
5500 + 50 VA – VB
= 1000 [ ] ≈ 1.02 kHz.
5500 − 50 = 5 × 1 – 15 + 5 × 10–3 × 103 – 11
= – 15
4. Ans ( C )
VB – VA = 15 V
power 200π
Intensity = =
2
7. Ans ( B )
area 2π × 10
−

A = πd2
= 1 Watt/m2 ⇒ d = √−−−
2Rh−

I
Now L = 10log10 = 10log10 ( 1 12 ) 8. Ans ( D )
I0 10 −

= 10log10 1012 = 120 dB

1
χ∝
T
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9. Ans ( A ) 14. Ans ( D )
2
E EαT
P = ( ) R
R+S 6.21 × 10 − 21
300
dP E
=
600
= 0 at R = 5Ω
dR E = 12.42 × 10–21 Joule
So, power is maximum at R = 5 Ω.
Therefore increases continuously till R = 5 Ω nrms α √−−
T
−−−−
484 300
10. Ans ( A ) ν
= √
600
Horizontal component of velocity
ν = 684 m/s
vx = ux = u cosθ = 30 × cos 30° = 15√–3 m/s
Vertical component of the velocity 15. Ans ( D )
vy = u sin θ – gt = 30 m
PV = RT
M
sin 30° – 10 × 1 = 5 m/s
v2 = vx2 + vy2 = 700 P α m.T
–
⇒ u = 10√7 m/s P 28 330
= ×
P /2 m 300
Hence correct answer is (A) 28 33 154
m= × =
11. Ans ( A ) 2 30 10
154 126 63
Leaked mass = 28 − = = gm
10 10 5
16. Ans ( A )
In y direction Let us first decide whether whole of the ice
v sin ϕ = e u sin45° ....(i) melts or not. The question is solved in steps as
In x direction
v cos ϕ = u cos 45° ....(ii) follows:
eq. (i) ÷ eq. (ii) (i) Heat supplied by 10 gm of water in cooling
1 from 60°C to 0°C = mS.Δt
tan ϕ = – ; ϕ = 30°
√ 3
= 10 × 1 × (60 – 0) = 600 cal
13. Ans ( C )
(ii) Heat required to raise the temperature of 10
gm ice from –5°C to 0°C
= 10 × 0.5 × (0 – (–5)) = 25 cal
(iii) Heat required to melt 10 gm ice at 0°C into
water at 0°C = mL = 10 × 80 = 800 cal
Force = ρav2 Now the heat required to melt the ice
F completely,
Acceleration =
m = (a) + (b) = 25 + 800 = 825 cal
ρav2
=
ρAH Since heat supplied by the water to lower its
−−−−
H −−
− temperature to 0°C is only 600 cal, therefore
∵ V = √2g = √ gH
2 whole of the ice does not melt. The resulting
ρ agH g
Acceleration = =
temperature of the mixture is thus 0°C.
ρ (Na)H N
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 LEADER TEST SERIES / JOINT PACKAGE COURSE/13-03-2022
17. Ans ( D ) 20. Ans ( D )
v1 2 Using Einstein photoelectric equation,
Given, =
v2 1 1 2
E−ϕ = mv
1 2 2
and mv = hυ − ϕ
1 1
2
E 1 = ϕ + (2V )2 ; E 2 = ϕ+ (V )
2
Therefore, 2 2
2 12400 E1 − ϕ
v1 − ϕ ⇒ = 4
3500
( ) = E2 − ϕ
v2 12400
− ϕ hc
450 ( − ϕ)
2 λ1
2 3.54 − ϕ ⇒ = 4
⇒( ) = hc
1 2.76 − ϕ (
λ2 − ϕ)
⇒ 4(2.76 – ϕ) = 3.54 – ϕ hc 4 1
⇒ϕ=( )( − )

⇒ 11.04 – 4ϕ = 3.54 – ϕ
3 λ2 λ1
1240 4 1
⇒ 11.04 – 3.54 = 4ϕ – ϕ ⇒ϕ=( )( − )
3 540 350
⇒ 3ϕ = 7.5 ≈ 1.8eV
⇒ ϕ = 2.5 eV
PART-1 : PHYSICS
⇒ 2.50 × 1.6 × 10–19 J
SECTION-II
= 4 × 10–19 J
4. Ans ( 2.00 )
18. Ans ( D )
Ip = 4A, Np = 140, Ns = 280
From the formula
Ki + Ui = Kb + Ub Ip Ns
=
K (2e)e Is Np
0+ = Kα + Kp + 0
4 280
r =
2 Ke2 Is 140
Kα = Is = 2A
5 r
2 1 e2 5. Ans ( 5.00 )
= ×
5 4πε 0 r
e 2 Elastic potential energy
Kα = 1
10πε 0 r = × Y × (strain)
2
× volume
2
19. Ans ( A ) 2
1 11 10 3 −
6
× 2 × 10 ) × 8 × 2 × 10
−
= ×(
2 8
For substance A : 16 1
= × 10 = 0.025 J
−

64
= 25 × 10–3 Joule
6. Ans ( 10.00 )
dv
For substance B : aT = = 4t + 1
dt
v2
ac =
r
−−−−−−
a = √a 2c + a 2T
a = 10 m/s2
NA : NB = 1 : 1 It is the centripetal acceleration of a moving ball.
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7. Ans ( 15.00 ) 3. Ans ( D )
ℓ 3ℓ
12 × ℓ = m + 3 × K1 = K2 (given)
2 2
2000 1000
⇒ m = 15 kg
1015 e 1014 × e
− ( ) − ( )
T = T

8. Ans ( 150.00 ) (
1000
)

1000 × 3 × 9 × 10–6 × Δθ or 10 = e T

= V × 1.8 × 10–4 × Δθ on taking log of both side

1000 × 27 × 10 − 6
V e1000 /T }
=
4
loge10 = loge {

1.8 × 10 −

100 × 27 1000
V = = 150 C.C. loge 10 = × loge e
18 T
1000
9. Ans ( 0.73 ) 2.303 × log1010 = × 1
1N 1P 0
T
0 → 1 +
− 1e + Q 1000
T= = 434.2 kelvin
Q = (MReactant – MProduct) C2 2.303
= [1.6747 × 10 – (1.6725 × 10–27 + 9 × 10–31)]C2
–27
4. Ans ( D )
= [0.0022 × 10–27 – 9 × 10–31]C2 N3– —→ N2+ + 5e ∴ E = M/5
= (22 × 10–31 – 9 × 10–31)C2 6e + 2N3– —→ (N0)2 ∴ E = M/3
= 13 × 10–31 × 9 × 1016J
13 × 9 × 10 15
− 12. Ans ( D )
Q= N2O is a neutral oxide
1.6 × 10 13 −

13 × 9 13.
= Ans ( C )
160
117 Carbonates of Na+, K+, Rb+ and Cs+ do not
= ≃ 0.73 MeV
160
decompose on heating.
10. Ans ( 200.00 )
14. Ans ( B )
dN
At t = 0, A0 = = 1600
dt
Principal Fn. group = (ester)
at t = 8 s, A = 100
A 1 Side chain = OCH3 (methoxy)
= in 8 sec
A0 16
Therefore half life is t 1 2 /
= 2 sec
3
1 Ethyl-4-methoxy butanoate
∴ Activity at t = 6 will be 1600( ) = 200
2
PART-2 : CHEMISTRY 15. Ans ( B )
SECTION-I
1. Ans ( B )
a, c, d are correct
2. Ans ( C ) 16. Ans ( D )
1 7 1
A→7× = B→6× =3 are positional isomers.
8 8 2
A7/8 B3 ⇒ A7B24
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 LEADER TEST SERIES / JOINT PACKAGE COURSE/13-03-2022
17. Ans ( A ) 2. Ans ( 50.00 )
iCRT)1 = iCRT)2
17.4 4 × 10
Para tautomerism i× × 10 = 2×
174 40
−−−−−−−−−− →
i = 2 for K2SO4
i = 1 + α (3 – 1)
18. Ans ( A ) a = 0.5
Cl2 /hν
or 50%
−−−− →
3. Ans ( 2.00 )
n
p= . RT

+ + v
n
ℓn p = ℓn + ℓn RT
v
log n = −0.3010
+ + v
v
log = 0.3010
n
v
+ = anti log 0.3010
n
v
= 2
No. of monochloro product = 6 n
19. Ans ( C ) v = 2L

−
4. Ans ( 50.00 )
O H /Δ Degree of hydrolysis of salt of weak acid and
−−−− →
weak base is independent from concentration.
5. Ans ( 7.00 )
20. Ans ( A ) XeF2, I3– —→ linear (planar)
BCl3 —→ Plane triangle (planar)
XeF4 —→ Square planar (planar)
[XeF5]– —→ Pentagonal planar (planar)
ClF3 —→ Bent 'T' - shape (planar)
PART-2 : CHEMISTRY H2O —→ 'V' - shape (planar)
SECTION-II 6. Ans ( 3.00 )
1. Ans ( 9.00 ) Sodium zeolite, Na2Al2Si2O8. xH2O
HX ⇌ H+ + X– Bauxite, Al2O3. 2H2O
0.1(1–α) 0.1α 0.1α Cryolite, Na3AlF6
1000 1000 7. Ans ( 8.00 )
^m = k × ⇒ 5 × 106 ×
C 0.1 4 4
Δ0 = Δt = × 1800 = 800 unit
= 0.05 Ω–1cm2-mol–1 9 9
Λm 0.05 1
8. Ans ( 4.00 )
a= = Ω −
− cm 2 mol 1
−
= 10
− 4
Λm 50
Ka = Ca2 = 0.1 × (10–4)2 = 10–9
pKa = 9

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9. Ans ( 14.00 ) 5. Ans ( C )
D.B.E. = No. of ring + no of p bond (3-in each 50
α= (a 1 + a 50 )
ring & 1 in –COOH) 2
50
= 4 + 10 = 14 and β = (a 51 + a 100 )
2
PART-3 : MATHEMATICS β – α = 25 (a 51 − a 50 + a 100 − a 1 )

SECTION-I = 25(d + 99d)

⇒ β – α = 2500 d
1. Ans ( A ) β−α
⇒ d=
As A2 = O, Ak = O∀ k ≥ 2 2500

Thus, (A + I)50 = I + 50A 6. Ans ( C )

⇒ (A + I)50 = I + 50A
⇒ a = 1, b = 0, c = 0, d = 1

2. Ans ( B ) = 336
2 4 6 8 8. Ans ( A )
Sum = + + + +. . .
x ([x] + |x|) sin[x]
10 10 3
10 5
107 lim
2 2 3 2 x→0 −
|x|
= (1 + + +. . . .) = S1
10 102 104 10 x→0 −

Clearly, S1 is an arithmetic-geometric series x

[ ] = − 1 ⇒
x (−x − 1) sin(−1)
= − sin 1
lim
x→0 −
−x
with a = 1,
x
| | = − x
1
d = 1 and r =
102 9. Ans ( C )
a dr Let t = sin2 x; t ∈ [0, 1]
∴ S1 = +
1−r ( 1 − r) 2 f(x) = g(x) = t . e–2t
100 100 g'(t) = e–2t – 2te–2t
⇒ +
99 99 × 99 g'(t) = (1 – 2t) . e–2t = 0
2 10000 2000
⇒ ( ) = 1
10 9801 9801 t = ∈ (0, 1) (∵ e–2t → +ve)
2
3. Ans ( D ) g(0) = 0 (min.)
Required probability 1 1 1 1
g( ) = e −
= e (max.)
1 1 2 2 2
3
×
5 42
⇒P= = g(1) = 1.e–2 = 1/e2
1 1 1 1 1 1 107
3
×
5
+
3
×
6
+
3
+
7 1 1
max. f(x) – min. f(x) = –0= .
4. Ans ( A ) 2e 2e

α + α2 = 1α3 = – k 10. Ans ( A )

α3 + α6 + 3α3(α + α2) = 1 f'(x) = cos x + sec2 x – 2
– k + k2 – 3k = 1 π
as cos x > cos2 x; x ∈ (0, )
2
k2 – 4k – 1 = 0
⇒ f'(x) > cos2 x + sec2 x – 2
4 ± √− −
20
k= π
2 > (cos x – sec x)2 > 0; (0, )
– 2
4 ± 2√5 – π
= 2 ± √5
2 Hence f(x) is increasing in (0, .
)
2

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11. Ans ( A ) 14. Ans ( B )
π Let P(h, k) be the point from which two
α ⃗ . β ⃗ = |α ⃗ ||β |⃗ cos
4 tangents are drawn to y2 = 4x. Any tangent to
– – 1
√ 2a + 3√2b + 4c = I.6. – 1
2 the parabola y2 = 4x is y = mx + .
√
m
a + b + 2√–2C = I.3 If it passes through P(h, k), then
1
⇒ LHS is integer if c = 0 k = mh +
m
then α ⃗ = a^i + b^j which lies in xy plane ⇒ m2 h – mk + 1 =0
Let m1, m2 be the roots of this equation.
12. Ans ( A ) Then,
k 1
Locus of variable point 'P' is a parabola with m1 + m2 = and m1m2 =
h h
k 1
⇒ 3m2 = and 2m22 =
given line as directrix and given point as focus. h h
[ ∵ m1 = 2m2(given)]
Vertex is the mid point of S and foot of k
2
1
⇒ 2( ) = ⇒ 2k 2 = 9h
3h h
perpendicular 'N'. Hence, P(h, k) lies on 2y2 = 9x
15. Ans ( D )
−−−−−−−−−−−−−−−−−
r 2
AB|
| = √( P Q) 2 − r
( + )
2
−−−−−−−−−
9 2
= √ 9r 2 − r
Let N be (–1 + 3λ,2 + 4λ, 7 + 2λ) 4
− −−− –
27r 2 3√3 r
−
− → = √ =

SN = ( 5 − 3λ)^i + (3 − 4λ)^j + (1 − 2λ)k^ 4 2

16. Ans ( C )
−
− →
SN . (3 i ^
+ 4j ^
+ 2k) = 0 ⇒ λ = 1
^
Σx 2i 2
Σx i
σ2 = −( )
n n
N ≡ (2,6,9) 100 20
2
4= = ( )
n n
11 17
⇒ V ≡ (3, , )
2 2 ⇒ n2 – 25n + 100 = 0

13. Ans ( C ) ⇒ n = 5 or 20

2x+3y−5 2 − 3x+2y+1 2 17. Ans ( D )

( ) ( )
√ 13
+
√ 13
= 1 p = T, q = F
4 1 (i) p ⇔ q = T ⇔ F = F
x2 y2 (ii) ~ p ⇔ q = F ⇔ F = T
which is equivalent to + = 1 with a = 2, b = 1
a2 b2
(iii) ~ q ⇔ p = T ⇔ T = T
∴ Area of ellipse = π.2.1 = 2π. (iv) ~ p ⇔ ~ q = F ⇔ T = F

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18. 20. Ans ( A )
Ans ( C )
Let the curve y = f (x). The equation of tangent at
dx sec6 x any point (x, y) is given by Y – y = f' (x) (X – x).
Let I = ∫ =∫ dx
cos6 x + sin 6 x 1 + tan 6 x So the portion of the axis of X which is cut off
( 1 +
2
tan 2 x) sec2 xd x between the origin and the tangent at any point is
=∫ obtained by putting Y = 0.
1 + tan 6 x
Therefore
If tan x = p, then sec2 x dx = dp y
x− ′ = ky
f (x)
2
( 1 + p2 ) dp ( 1 + p2 ) dx
= =∫ dp ⇒x−y = ky
1 + p6 p4 − p2 + 1 dy
1 dx x
p2 (1 + ) ⇒ − = −k
p2 dy y
=∫ dp
p2 ( p2 + 1
− 1) which is a linear equation in x, so its integrating
p2
factor is e 1 ydy = y–1.
−∫ /

dk 1
∴ I = ∫ = tan −
k
( )+ c Therefore, multiplying by y–1
k2 + 1
d
1 1 we have (xy–1) = – ky–1
If p − = k, then (1 + ) d p = dk dy
p p2
⇒ xy–1 = – k log y + c
1 1 x = y (c – k log y).
= tan −
( p− )+ c
p
Hence (A) is the correct answer.
= tan − 1
( tan x − cot x) + c PART-3 : MATHEMATICS
SECTION-II
1
= tan −
(− 2 cot 2 x) + c
1. Ans ( 256.00 )
adjA| = |A| n
|
− 1
Hence (C) is the correct answers n 1 3
| adj (adj (adjA))| = |A| ( − )

3
3 1
19. Ans ( D ) = | A| ( − )
= | A| 8
⇒ 28 = 256
2. Ans ( 2.00 )
Applying C1 → C1 + C2 + C3
a2 + b2 + c2 + 2 = 0
∣ 1 ( 1 + b2 )x ( 1 + c2 )x ∣
∣ ∣
– [x] = {x} ∣ ∣
∴ f (x) = ∣ 1 2 2
1+b x ( 1 + c )x ∣
∣ ∣
∣ ∣
x – [x +1] ={x} x – 1 ∣ 1 (
2
1 + b )x 1+c x 2 ∣

4 R1 → R1 – R2
1
∫ f (x) dx = 6. (1 . 1) = 3 R2 → R2 – R3
2
2
−

= (x – 1)2
Hence (D) is the correct answer. = Hence degree is 2

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 LEADER TEST SERIES / JOINT PACKAGE COURSE/13-03-2022
3. Ans ( 2.66 ) 9. Ans ( 1997.00 )
π
x4 − 1 x 3 − k3
lim = lim I =∫ x f (cos2x + tan4x) dx
x→1 x − 1 x→k x 2 − k 2
0
k2 + k2 + k2 π
⇒ lim(x + 1) (x 2 + 1) =
x→1 2k =∫ π − x)
( f (cos2x + tan4x) dx
⇒ k = 8/3 0
π
4. Ans ( 12.00 ) ⇒ 2I = ∫ π f (cos2x + tan4x) dx
Since f(x) is decreasing in the interval (–2, –1), 0
π
therefore, π
I= ∫ f (cos2x + tan4x) dx
f'(x) < 0 ⇒ 6x2 + 18x + λ < 0 2
0
The value of l should be such that the equation π /2
π
6x2 + 18x + λ = 0 has roots –2 & –1. = ×2∫ f (cos2x + tan4x) dx
2
0
λ
Therefore, (–2) (–1) = ⇒ λ = 12
6 10. Ans ( 10.00 )
6. Ans ( 7.00 )
∣( c1 − c2 ) (d1 − d2 ) ∣
Use formula ∣ ∣
∣ m1 − m2 ∣

7. Ans ( 12.00 )

A1 ⇒ area included between the line and circle

in first quadrant =
πa 2 1 2 ( π − 2) a 2
− a =
AE = AB – BE = AB – CD 4 2 4
A2 = area included between the line and
[∵ BC DE is a ||gm] −− −−
√| | x + √|y| = √a
−

So BE = CD a
1 − 2
= a2 – ∫ (√
− −
−√ ) a x dx
= 20 – 14 = 6m 2 0
a2
In right angled ΔAED = (9p – 2)
12
A2 1 9π − 2
∠ADE = 30° Now = ( ) ,
A1 3 π−2
AD
∴ cosec 30° = A = 9, B = 1
AE
⇒ 12 m A + B = 10

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