Quiz-Phase Test 3 FIITIEE LIMITED LEVEL-1 Single Correct Answer Type This section contains 06 multiple choice questions. Each question has four choices (A). (B). (C) and (D) out of which ONLY ONE is correct. 1, Rank the given compounds from most acidic to least acidic based on the acidity of the encircled H: OF mY, OY aN MeO: MeO. ‘OMe ‘OMe ‘Me (3) (A) 1>2>3 (B) 1>3>2 (C) 2>3>1 (D) 2>1>3 2 Give the major product of the following reaction sequence : Ieee Rant, _Na ats, Major product (eae ‘B) WY er © rl (De 3 n below is correct ? CHy cl ae we a La Tena i Hy tee OH © 0901, 00,04 wore? Tio mo? 4, Which of the following statements incorrect ? (A) Alkynes on reaction with Tollen’s reagent gives white precipitate. (B) Hydrolysis of magnesium carbide gives propyne. (C) Pure acetylene is obtained when iodoform is heated with silver powder. (D) Acetylene when passed through an ammoniacal cuprous chloride solution gives red precipitate 5. Optically active isomer is, 4. H Cl cl (ay =o=ed EXO H Br Br ‘Br Cc oe H. g © = (D) of 8 =e H 6 Inthe reaction given below, the product C i aiHS0. yg Hath Cac, 8? > aT 9B 3c (A) CoHSOH. (B) CHCHO (C) CHO (D) CHxCOOH THMAG€ KOLKATANORTHCENTHE VP TOWER Gr Flow #0 VIP Rous Gnaghala Utadanga Kohaa-7000 4 ‘El iene eam URI are ee com @ scanned with OKEN ScannerThiy section contains 08 multiple choice questions. Each question has four chotees (A) (B). (Cs and (D) out of which ONE OR MORE "WW Multi Correct Answer Type be correct Keto-enol tautomerism is observed in: ° (a) (By why sc” CH © (D) H:C5 Hye So. Which structure(s) is/are chiral’? &. os Bt “ CO 8) HOH 0 «© 3 (D) Hs Stable C* ' °C w CO ally (lv) ij (ayi (C)-NOz 13. Grignard reagents gives alkanes with (A)phenol (B)ether (C)alcohol (D) water 14, What are the products obtained upon the ozonolysis of 2-pentene? (A)CHsCH,CHO. (B)CHsCHO (C)CHsCOCHS (D)CHsCOCH:CHs Paragraph Type This section contains 2 paragraphs. Based upon the paragraphs 2 multiple choice questions have 10 be answered. Each of these questions has 4 choices (A), (B). (C) and (D) out of which ONLY ONE is correct. Paragraph for Question Nos. 15 to 16 wr the same When CHsCH=CHp is treated with Br it forms an optically inactive product, furthe compound when treated with HBr also forms optically inactive product. CH,CH - CH, +Br, —>Product CH,CH = CH, + HBr —>Product When HCI adds to 2-methyl-L-butene in the presence of benzoyl peroxide. then product is racemic mixture, CHy | CHy—CH,— However, when HBr adds on 3-chloro-I-butene, then product is found to be optically active. CHy =CH, + HCI 28, Racemic mixture et + HBr ——+ Optically active ‘CH=CH, 15. Formation of optically inactive product by the addition of Br (A)of same type (B)of different types (C)due to formation of carbocation in I* reaction and free-radical in 2 reaction (D)due,to formation of carbocation in both reactions id HBr on CHxCH=CHb is 16. The type of intermediate formed in the above mentioned reaction of 2-methyl-1-butene is (A)Carbocation (B) free radical (C)Carbanion (D)Carbene Paragraph for Question Nos. 17 to 18 The carbon-carbon double bond in a molecule is capable of decolorizing Bry/CCls following free radical mechanism. The decolorization of Bry/water solution however shows electrophilic addition. The addition of bromine to cyclopentene provides evidence for bromonium ion immediate in bromine addition, It follows ionic mechanism. When cyclopentene reacts with bromine in presence of CCly anti addition occurs and gives trans-isomer so addition of halogen to an alkene is a stereospecific reaction, Cis-alkene on addition with halogen gives meso products and trans alkene on addition gives racemic mixture ITE KOLKATA NORTH CENTRE Ganga Apavment 36 Floor. 88, IP Roos, Galaghata,Utadanga, Kanal TEN! norokolalagtije com URL war ijesohatararh cm @ scanned with OKEN ScannerHye H " > "A Intmedate forms are Ww ‘cy (A) Hydroxonium ion (C) Hydronium ion (B)Chloronium ion (D) None of these itene on reacting with Bry -ibromobutane (C)-2.3-dibromobutane in CCA forms mainly (B)+2,3-dibromobutane (D)Mese-2,3-dibromobutane LEVEL 2 Multi Correct Answer Type This Section contains 08 multiple choice questions, Each question has four choices (4), (B), (C) and (D) out of which ONE OR MORE may be correct 1. Which of the following will give eis-diols? \_/ \ / (a) TRO (BR) Cac ORO a 2 The consequences of global warming may be (A)increase in average temperature of the earth (B) melting of Himalayan Glaciers (C) increased biochemical oxygen demand (D)eutrophication 3 Which of these gives Hoffmann product as major product 2 Br \ f \ (A) CHy ~ CH, ~CH- CH, —Stslscons_, (8) CH, —CH, ~CH-CH, —2h0N2 i ° (C) CHy—CH, ~CH- CH, —SHONe_, (0) CH, ~CH,~ CH-N(CH,), Oa, chy 4 Which ofthe following carbides can be used to prepare methane by is action with water? (A) Aluminium carbide (8) Berylium carbide (C) Calcium carbide (0) Slicon carbide 5 Which of these gives syn addition with alkenes ? (A) BroiCCle (B) Bra/HOH (C) KMnO./OH-1H20(cold) (0) BHs/THF 6 Which statements among the following are correct ? - CH HC e-CHy ODN. NO, (A) is more basie than Nop No, TAME KOLRATA NOM @ scanned with OKEN ScannerNH NM. A | (B) [OL emore ase tnan O,N- NO, No; Nie wn 7 A «© is less basic than A aL 2 on? 7 ~NOe Ow. «D) is less basic than NO, 7 Which ofthese compounds exist in eipoar form ? a) (By Pa «© O ) oI ° 6. cenderteguon eaten < < O«-@ i . ‘ (R) (P) Which of the following statements are correct for the above reaction ? (A) Number of delocalized n-electrons in (R) & (P) are same (8) (P) is aromatic in character {C) The Feaction is acid-base reaction (D) Lone pair of nitrogen in (R) takes part in delocalization Mateh List Type “Answer the following by appropriately matching the list based on the information given in the paragraph. 9. The reaction intermediates are short lived species. which are given in list-I and their characteristics are given list-II List-1 List Th | Carbocation wD (1) | Carbanion (Q 5| J (ID) | Free radical (R) | sp) - | [Vy | Singlet Carbene —____[(8)_ | zero unshared e pair | _ — (1) _| one unshared pair | CL] _ TW) [two unshared €_ pair 1 Which of the following options has the correct combination considering List-l and List-I? Opti Tamed FOUWATA NORTH CENTRE Goa patent 8 Tian #9 UP Road Gana, Wasaga KOLAG-T000 4 ‘iat netuckawarcnce om UR. men enone @ scanned with OKEN ScannerFAND.ARY all Answer the follow inj Paragraph 10. The reaction int characteristics are given list-II (By). (Sp (DIIV).(Q) Hy by appropriately matching the lists based on the information given in the termediates are short lived species. which are given in list-I and their List-t List-II (| Carbocation ) | sp (| Carbanion (Q) | sp* ! (U1) | Free radical (R)_| sp? Singlet Carbene (S)_| zero unshared e pair (T)_| one unshared e- pair | (U)_| two unshared e pair Which of the follow mbination considering List-l and List-I? (A). (P) (B) (I), (R) (C) CM), (R) Answer the followin, Paragraph u (D)AV), (P) 8 by appropriately matching the lists based on the information given in the ar @) | planar ay (Q) | (4n+2) x delocalised LM) | Cyclo-cetatetraene | (R) | dn x delocalized (IV) | Pyrrole (S) | non-planar (T) | cyclic | L(U) | open chain J (Which ofthe following options has the correct combination considering List-l and List-l1? Options (A)(ID, (P), (R), (T) (B) (I), (P), (Q), (1) (C1), P).(R). (U) (D)(1).(P).(R). (8) Answer the following by appropriately matching the lists based on the information given in the Paragraph 12, List-I List-11 (1) [Aromatic —_|@) [planar | (1) _| Anti-aromatic ___|(Q) | (4n+2) m delocalised (iy | (R) | 4n x delocalized (IV) | Pyrrole. —[(S)_| non-planar |.) [eyelie — 1) fei in = Which of the following options has the correct combination considering List-l and List-II? aa (B) (IV), (R), (8) (AJ(IV), (R), (U) .(R), (C)(U, (R),(S) (D)AUD, (P), (R) mi 378 Toor. 86 ViP Road. Golaghal,Utaaanga Kavala 7000 #8 KOLKATA NORTH GENTRE Ganga Aparment 9 oo 2s, aaa EM nontachatagiie com URL ww hesrohstanonh com @ scanned with OKEN Scanner| Integer Answer Type Miony Tie answer to cach question 1s a singlesdigit integer. ranging This section contains 06 que from 010.9 The correct de vm Oto (1 gut below she question number 1m the OMR iste he bubbled 1 What 'al's the number of chiral centres in the compound 7 HgC. Hc 1 Hy HO 2 How many of the following compounds are aromatic ? Total number of monochlorinated products of CH ~ CH2 ~ CH2 ~ CHs is In the following monobromination reaction, the number of possible chiral products is 4, CHACHCH, Bestenee ay (10 mole) (enantimeselly pure) 8. Ortho xylene — SEH, ma +B +00 ‘What is the value of 2 ifz = m+n +0? What is the number of positional isomers for an alkyne with molecular formula C3FCIB¢l TITIEE KOLKATA NORTH GENTRE Ganga Agate! id Flor 6 VIP Roaa Guagaia Ursin Kosaa-700048 Fito nantuonatetriqee com URL wor hectare com @ scanned with OKEN Scanner