QUESTION BANK ANALYSIS Lag SAQ S.NO ‘TOPIC NAME ysag | TOTAL 1 SOLID STATE. - - 3 5 3 11 22 2 | soLutions -|2 6}4a]o} a9 45 3 | ELECTRO CHEMISTRY -|- 3/7/15 22 37 4 | CHEMICAL KINETICS a} 3|6|12| 28 51 5 SURFACE CHEMISTRY - - 6 3 3 19 no ‘GENERAL PRINCIPLES OF 6 | METALLURGY “|: 4]2]6 | 10 22 7 | p-BLOCK ELEMENTS 4] 2 s]}9]5 34 58 8 | d &£- BLOCK ELEMENTS 2/3 4)5/5 27 46 9 POLYMERS - - - - - 21 21 10 | BIOMOLECULES -/- 4}4a]3] 24 35 ‘CHEMISTRY IN EVERY DAY MU ire “| - =]. [3] 18 21 HALOALKANES AND 12 | HALOARENES 4] 5 3]-,2] u 25 ‘ORGANIC COMPOUNDS 13 | CONTAINING c,H&O 5 2 3 5 1 12 29 ORGANIC COMPOUNDS 7 CONTAINING NITROGEN, 3 2 3 1 2 6 18 SUB TOTAL 19| 17 |7] 52] 51] 59 262 | 462 TOTAL 43 156 © scaned thon SeamerSR CHEMISTRY QUESTION BANK LONG ANSWER QUESTIONS (8 Marks) LUTI "1. 100g of liquid a (molar mass 140gmot") was dissolved in 100g of liquid B (molar mass 180gmot’). ‘The vapour pressure of pure liquid B was found to be 500torr. Calculate the vapour pressure of pur liquid A and is vapour pressure in the solution ifthe total vapour pressure of the solution is 475 torr #2, Benzene and Toluence form ideal solution over the entire range of compositon. The vapour pressure of pure benzene and toluene at 300K are 50.71 mm of Hg amd 32.06mm of Hg respectively. Calculate the mole fraction of benzene in vapour phase if 80g. of benzene is mixed with 100g of toluene. “3. Heptane and Octane forman deal solution. At 373K’ the vapour pressure of the two liquid components are 105.2kp, and 46.8kp, respectively. What will be the vapour pressure ofa mixture of 26.0g heptane and 35g of octane? “4. ‘Two elements A and B from compounds having formula AB, and AB, . when dissolved in 20g of Benzene (C,H). 1g of AB, lowers the freezing point by 2.3K where as 1.0g of AB, lowersit by 1.3K . The molar depression constant ofr benezene is 5.1K kg mol”. Calculate atomic masses of Aand B. *5, Determine the osmotic pressure of solution prepared by dissolving 25mg of KO, intwo lire of water at 95° assuming that itis completely dissociated %6. — Anaqueous solution of 29% non volatile solute exerts a pressure of 1,004 bar at the normal boiling point ofthe solvent. What is the molecular mass of the solute? “7, 195g of CH,FCOOH isdissolved in 500g of water. The depression in freezing point of water observed is 1,0°C. calculate the van't Hoff factor and dissociation constant of fluoroacetic acid. CHEMICAL KINETICS "#8, Give a detailed account of the collsion theory of reaction rates of bimolecular gaseous reactions. **9, Explain the following terms with suitable examples, (a) average rate of areaction (b) slow and fast reactions _(c) order of a reaction (@) motecularity ofareaction —(e) activationenergy of a reaction, - BLOCK ELEMENTS GROUP 16 ELEMENTS #10, Explain in detail the manufacture of sulphuric acid by contact process, °° LL. How is ozone prepared from oxygen ? Explain its reaction with (Mareh-2014) a) CH, b)KI ong @)PbS ©)S0, SnCl, GROUP 17 ELEMENTS 12. How is chlorine prepared in the laboratory ? How does it react with the following ? a) Iron b)Hot.conNaOH —_c) Acidified FeSO, d) Iodine) H,S f) Na$,0, "#13, How ischlorine prepared by electrolytic method ? Explain it’s reaction with (a) NaOH (b) NH, under different conditions #14, Write the names and formulae of the oxo acids of chlorine explain their structures and relative acidic nature “#15, How is CIF, prepared ? How does it react with water ? Explain it’s structure ? \Nishith Multimedia India Pvt. Ltd. Page.No. 59 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK d - and f-Block Elements & Coordination Compounds *** 16, Explain different types of isomerism exhibited by coordination compounds, giving suitable examples, 17. Discuss the nature of bonding and magnetic behavior in the following coordination entities on the basis of valence bond theory. @[Fe(cn), J” [Fer] ii) [Co(C,0,), ]” and Civ) [CoF,]” **18, Explain IUPAC nomenclature of coordination compounds with suitable examples, 19. Whats spectrochemical series? Explain the difference between a weak field ligand and a strong field ligand. *20, Explain the applications of coordination compounds in different fields. HALO ALKANES AND HALO ARENES ‘#21, Write the reactions showing the major and minor products when chlorobenzene is reacted with CHCl and CH,COCI inpresence of AICI, ***22. Explain the mechanism of Nucleophilic bimolecular substitution sjy* reaction with one example, ~**23. Explain the mechanism of Nucleophilic unimolecular substitution $y! reaction with one exampk. ***24. Define the following j)Racemicmixture i)Retentionofconfiguration i) Enantiomers. **25. Write the mechanism of dehydro halogenation of 2-bromobutane? **26, Account for the following statements: 1) Aryihalides are extremely less reactive towards Nuckeophilic substitution reactions. 2) p-Nitrochlorobenzene and o, p-dinitrochlorobenzene undergo Nucleophilic substitution readily compared to chlorobenzene. 27. Whatis the criteria for optical activity? give two examples of chiral molecules? #28. Explain how the following conversions are carried out : 1)Propeneto propanol 2)Ethanolto but-I-yne 3) 1-Bromopropane to 2-Bromopropane #29. Name the following halides according to TUPAC system and classify them as primary.secondary, tertiary, vinyl or aryl halides. i) CH,CH(CH, )CH(Br)CH, ii) CH,C(CI)(C,H,)CH,CH, iii) m-CICH,C,H,CH.C(CH,), iv) O-Br-C,H,CH(CH,)CH,CH, ORGANIC COMPOUNDS CONTAINING C,H & O ALCOHOLS, PHENOLS AND ETHERS ***#30. Explain why (i) Ortho nitrophenol is more acidic than ortho methoxyphenol. ii) OH group attached to benzene ring activates it towards elecrtophilic substitution, %**3]. With asuitable example write equations for the following: (i) Kolbe’s reaction _(ii) Reimer-Tiemann reaction. (ii) Williamsons ether synthesis. ***32, Write equations of the below given reactions : i) Alkylation of anisole (ii) Nitration of anisole (iii) Fridel-Crafts accetylation of anisole 33, Illustrate hydroboration-oxidation reaction witha suitable example, *=34, Write the equations for the preparation of phenol using benzene, cone. H SO, and NaOH - (Mareh-2014) Nishith Multimedia India Pvt. Ltd. Page.No. 60 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK ALDEHYDES, KETONES & CARBOXYLIC ACID ***35. Describe the following 1)Acetylation 2)Cannizaro reaction 3) Crossed aldol condensation 4) Decarboxylation **36. Explain the following terms. Give an example of the reactionin each case. 1) Cyanohydrin 2)Acetal 3)Semicarbazone. 4) Aldol 5) Hemiacetal 6) Oxime "37. Howare the following conversions carried in not more than two steps. 1) Ethanol to 3-hydroxybutanal 2) Bromobenzene to |-Phenylethanol 3) Benzaldehyde to + Hydroxyphenylacetic acid 4) Benzaldehyde to benzophenone IRGANIC COMPOUNDS CONTAINING NITROGEN "38, Complete the following conversions i) CHNC+Hg0>? ii) 2+2H,0 > CH,NH, + HCOOH iii) CH,CN + C,H,MgBr > 2252 iv) CH,CH,NH, +CHCI, +KOH ">? is Cpe Br, ———> ? "39, Complete the following conversions: Anilineto i) Fluorobenzene ii) Cyanobenzene _—_ii) Benzene and 40, Explain the following named reactions: i) Sandmeyer reaction i) Gatterman reaction. °”'41, Write the equation involved in the reaction of Nitrous acid with Ethylamine and aniline. °»'42, Explain with equations how methylamine, N,N-dimethylamine and N,N,N-trimethylamine react with benzenesulphonyl chloride and how this reaction is useful to separate these amines. **43. Write the steps involved in the coupling of benzene diazonium chloride with aniline and phenol. SHORT ANSWER QUESTIONS (4 Marks: SOLID STATE %**1, Derive Bragg’s equation, (March-2014) ***2, Describe the two main types of semiconductors and contrast their conduction mechanism, ***3, Classify each of the following aseither a p-type ora n-type semiconductor. ( Gedoped with In Gi) Sidoped with B. **4, Explain why ionic solids are hard and brittle, "*5. cubic solid is made of two elements P and Q. Atoms of Q are at the comers of the cube and P atthe body-centre, What isthe formula of the compound? What are the coordination numbers of P and Q? 6. Ifthe radius of the octahedral void is ‘r’ and radius of the atoms in close packing is ‘R’ derive relation between and R. **7, _Interms of band theory, what is the difference between a conductor and an insulator? **8, _Interms of band theory, what is the difference between a conductor and a semiconductor? "9. Calculate the efficiency of packing in case of a metal of body-centered cubic crystal? “10. Niobium crystallizes in body-centered cubic structure. If density is 8.55g em”? . Calculate atomic radius of niobium using its atomic mass 93U?. Nishith Multimedia India Pvt. Ltd. Page.No. 61 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK aT ‘Aluminum crystallizes ina cubic close packed structure. Its metallic radius is 125pm. () what is the length of the side of the unit cell, [Ans: 354 pm] Gi) How many unit cells are there in 1 ¢m° of aluminum? SOLUTIONS ***12, Define mole fraction, A solution of sucrose in waters labelled as 20% w/w. What would be the mole fraction ofeach component inthe solution? (Mareh-2014) ***13, What is meant by positive deviations from Raoult’s law and how is the sign of ,,,.H/ related to positive deviation from Raoult’s law? ***14, What is meant by negative deviation from Raoult’s law and how is the sign of A, related to negative deviation from Raoult’ law? °©*15, What is relative lowering of vapour pressure? How isit useful to determine the molar mass of solute? +#*16, State Raoult’s law. Vapour pressure of water at 203K is 17.535mm.Hg Calculate the vapour pressure of the solution at 293K when 25g of gulcose is dissolved in 450g of water. °***17, What is an ideal solution? Give sutable exmaples. "#18. How ismolar mass-related to the elevation in boiling point ofa solution. #19, How ismolar mass related to the depression in freezing point ofa solution? #20. How many types of solutions are formed ?Give an example for each type of solution. #21. A solution of glucose in water is labeled as 10% W / W - What would be the molarity of the solution? "22. Define mass percentage, volume percentage and mass to volume percentage solutions. "23. Concentrated nitric acid used inthe laboratory work is 68% nitric acid by mass in aqueous solution. ‘What should be the molarity of such a sample ofthe acid if the density ofthe solution is 1.504gmL.! 24, How many mL, of 0.1M HCL istequired to react completely with 1.0¢ mixture of Na,CO, and NaHCO, containing equi-molar amounts of both? 25. A solution is obtained by mixing 300g of 25% solution and 400g of 40% solution by mass. Calculate the mass percentage of the resulting solution. 26. Why do gases always tend to be less soluble in liquids as the tempeature is raised? *27. Calculate the mass of non-volatile solute (molar mass 40g mol~') which should be dissolved in 114g Octane to reduce its vapour pressure to 80% 28. 45g ofethylene glycol (C,H,O,) ismixed with 600 g of water. Calculate (a) the freezing point depression and (b) the freezing point of the solution, 29. 1,00g of anon-electrolyte solute dissolved in 50 g of benzene lowered the freezing point of benzene by 0.40 K. The freezing point depression constant of benzene is 5.12 K kg mol. Find the molar ‘mass ofthe solute. *30, 200 cm of an aqueous solution of a protein contains 1.26 g of the protein, The osmotic pressure of such a solution at 300 K is found to be 2.57 x 10° bar. Calculate the molar mass of the protein. ELECTRO CHEMISTRY "#31, Give the applications of koblrausch’s law of independent migration of ions. #32, Give the construction and working of a standard hydrogen electrode with a neat diagram. °***33, What is electrolysis and State Faraday’s laws of electrolysis. (Mareh-2014) 34, Whatare galvanic cell” Explanthe working ofa galhanic cll with aneat sketch taking daniel cella exam. *35, What are primary and secondary batteries? Give examples. "36, State and explain Nemst equation with the help of a metallic electrode and non metallic electrode. **37, What is Metallic corrosion ? Explain it with respect to iron corrosion, "38 Whatarefuelcells? How they are different from galvanic cells? Give the construction of H, ~O, fuelcell. Nishith Multimedia India Pvt. Ltd. Page.No. 62 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK 39, What are the products obtained at the cathode and the anode during the electrolysis of the following when platinum electrodes are used in the electrolysis. (@) Molten KCI (b) Ag.Cuso, (©) Ag-K,SO, Solution NUMERICAL PROBLEMS #40. Calculate the emfof cell at 25°C Cr /Cr¥(0.1M)// Fe"(0.01M)/ Fe "41. Calculate the equilibrium constant ofthe reaction Cu) +2Ag (oe) > Cus +2Ag (5) given Ey) =0.46V %#42, The standard emt of Daniell cell is 1.1V, Calculate the standard Gibbs energy for the cell reaction Zn) + Cr 3 Zn) + Cus) 43. Calculate AL for CaCl, and MgSO, (given ing = 106,5,,.. = 160) 44, AS for NaCl, HCland CH,COONa are 126.4,425.9 and 91.0 cm?mol respectively calculate Af for CH,COOH *45. A solution of CuSO, iselectrolysed for 10 minutes with a current of 1.5 amperes. What is the mass of copper deposited at the cathode? (March-2014) CHEMICAL KINETICS #46, Define and explain the order of a reaction. How isit obtained experimentally? +47, What is “molecularity” of a reaction? How ist different from the ‘order’ of a reaction? Name one bimolecular and one trimolecular gaseous reactions, (March-2014) #48, Whatis half-life (1, ) ofa reaction? Derive the equations for the ‘half-life’ value of zero and first order reactions 49. What is Arthenius equation? Derive an equation which describes the effect of rise of temperature (T) onthe rate constant (k) of areaction. **50. Discuss the effect of catalyst on the kinetics of a chemical reaction with suitable diagram, “51 the integrated rate equation for afirst order reaction. 52. Explain the terms (a) Activationenergy (Ea) _(b) Collisionfrequency (Z)_() Probability factor P) with respect to Arrhenius equation, NUMERICAL DATA BASED AND CONCEPT ORIENTED QUESTIONS #53. A reaction is 50 % completed in 2hours and 75% completed in 4 hours. What is the order of the reaction? °"*54. A reaction has a half life of 10 minutes. Calculate the rate constant for the first order reaction, "#55, Ina first order reaction, the concentration of the reactant is reduced from0.6 moV/L to 0.2moVL in Smin, Calculate the rate constant. #56. Show that in the case of first order reaction, the time required for 99.9 % completion of the reaction is 10 times that required for 50% completion. (log? = 0.3010). *57. The rate constant for a reaction of zero order in A is 0,00amolL'S~' . How long will it take for the initial concentration of A to fall from0.1M to 0.075M? "58. The thermal decomposition of HCOOH is afirst order reaction, The rate constant is 2.410757! at certain temperature, Calculate how long willittake for 3 /4 ifinitial quantity if COOH to decompose. \Nishith Multimedia India Pvt. Ltd. Page.No. 63 Orman oS (© scaned thon SeamerSR CHEMISTRY QUESTION BANK *59, *60, *61 62, *63, *64, *65, *66, For the reaction R —> P , the concentration of a reactant changes from 0.03M to 0.02M in 25 minutes. Calculate the average rate of reaction using units in seconds, The conversion of molecules X to Y follows second order kinetics. If concentration of X is increased to three times how will it affect the rate of formation of Y? AA first order reaction has a rate constant of 1,15 107's~! - How long will5.0 g of this reactant take to reduce to 3.0 g? From the rate expression for the following reactions determine their order of reaction and the dimensions ofthe rate constants: (® 3NO(g)—N,0(g) + NO, (g) Rate = k[NO (i) H,0, (aq) +31" (aq) + 2H" (ag) —>2H,0(I) +1; ,Rate = k[H,0,][17] (ii) CH,CHO(g)—+ CH, (g) + CO(g), Rate = k[CH CHO] (iC, ,Cl(g) —¢, (, (g) + HCI(g), Rate = k[C,H,Cl] ‘A reaction is second order with respect to a reactant. How is the rate of reaction affected if the concentration of the reactant is () doubled (ji) reduced to half? ‘Areactionis first order in A and second order in B. (D Write the differentia rate equation. (i) How isthe rate affected on increasing the concentration of B three times? (ii) How is the rate affected when the concentration of both A and B are doubled? for a first order reaction, show that time required for 99% completion is twice the time required for the completion of 90% of reaction. [Identify the reaction order from each of the following rate constants. @ k=23x10°L mor st Gi) k=3x104s* SURFACE CHEMISTRY ***67. What are different types of adsorption? Give any four differences between characteristics of the different types. (March 07 & May 07, Mar 2011) 68, What isan emulsion ? Explain the classification of emulsions with examples? (March 05, 06,08 & May08) #69. What iscatalysis? How is catalysis classified? Give two examples for each. (March 05, 06,10,2014, May 06) +#*70, Name the dispersed phase and dispersion medium in the following colloidal systems 927] (fog ii) smoke_-—(iii)milk_— (iv) cloud ~—(v) blood -—_(vi) gold sol, ‘What are micelles? Discuss the mechanism of micelle formation and cleaning action of soap. ***72, How are colloids classified on the basis of interaction between dispresed phase and dispesion medium? #73. What is coagulation? Explain with suitable examples. 74, What are colloidal solutions? How are they classified? Give examples. "75, i) Name the enzymes obtained from soyabeen and yeast. ii) Name the enzymes used in (a) Decomposition of urea into ammonia. (b) Conversion of proteins into peptides in stomach, Nishith Multimedia India Pvt. Ltd. Page.No. 64 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK 76. __ i) Alumis used to purify water obtainded from natural sources. Explain. ii) Bleading from fresh cut can be stopped by applying alum. Give reasons. *77. _ Whatisan adsoprtion isotherm? Discuss the phenomenon of adsorption of gases on solids with the help of Freundlich adsorption isotherm. “78. Name the four positively charged sols and negative charged sols. GENERAL PRINCIPLES OF METALLURGY 79***. Giving examples to differentiate roasting and calcination. (March - 09, 12, 2014) '80***, Write down the chemical reactions taking place in different zones inthe blast furnace during the extraction of iron. (March-2011) 81**#, Outline the principles of refining of metals by the following methods. a) Zone refining b) Electrolytic refining ) Poling ) Vapour phase refining '82***, Explain the purification of sulphide ore by froth floatation method. 83**, Give two uses each of the following metals a) Zine b) Copper ¢) Iron 4) Aluminium '84**, How is copper extracted from copper pyrites? 85*. Write down the chemical reactions taking place in the extraction of zinc from zinc blende. 86*. Explain Zone refining. 87%. Explainelectrometallury with an example. 88°. What isthe role of graphite rod inthe electrometallurgy of aluminium? 89°, Explain briefly the extraction of aluminium from bauxite. 90*. Explain the process of leaching of alumina from bauxite. p-BLOCK ELEMENTS GROUP 15 ELEMENTS. ***91. How is ammonia manufactured by Haber’s process ? ***92. How is nitric acid manufactured by Ostwalds process ? 93, Discuss the trends is chemical reactivity of group 15 elements? *94, Complete the following reactions a) Ca,P, + H,0 > b) P.+KOH > ) CuSO, + NH, > 4) Mg+N, > e) (WH,), CrO, > ) Decomposition of nitrous acid GROUP 16 EL! TS #95. How is ozone prepared ? How does it react with the following ? a) PbS b) KI co) Hg dAg *96. — How does SO, react with the following ? a) Na,SO,,.b) Cl, c)Fe**ions d) KMn0, *97. — Compket the following a) KC1+H,80, (cone) > by Sucrose _cneissa ©) Cu+ H,S0, (conc) > 4) C+H,S0,(conc) > *98. Describe the structures of $0;7 and SO, Nishith Multimedia India Pvt. Ltd. Page.No. 65 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK GROUP 17 ELEMENTS #99, How can you prepare Cl, from HCl and HCl from Cl, ? Write the reactions ? 100, Explain the structures of (a) BrF, (b) IF, ? 101. Write balanced equations for the following ? (a) NaClis heated with conc H,SO, in the presence of MnO, (b) Chlorine is passed into a solution of Nal in water °** 102. What are inter halogen compounds ? Give some examples to illustrate the definition how are they classified ? #103. Write the names and formulae of the oxo acids of chlorine explain their structures and relative acidic nature 104, How is CIF, prepared ? How does it react with water ? Explain it’s structure ? GROUP 18 ELEMENTS 105. How are XeF, and XeF, are prepared Give their structures. (March-2014) ind XeOF, prepared? 107. Give the formulae and describe the structure of a noble gas species, iso elecrtronic with a) ICI, b) Br; ©) BrOy **108. Explain the structure of a) XeF, _b) XeOF, 109. Complete the following a) XeF,+H,0> b) XeF, + PF, > ©) XeF, + SbF, > d) XeF, + AsF, > ©) XeF,+0,F, > f) NaF + XeF, d - and f-Block Elements & Coordination Compounds +**110. Explain Werner's theory of coordination compounds with suitable examples. (Mar-11,2014 Jun-10) *** 111, Using IUPAC names write the formulae for the following: (May-2012) (i) Tetrahydroxozincate(II) (i) Hexaamminecobal(II]) sulphate (iii) Potassium tetrachloropalladate(II) and (iv) Potassium tri(oxalato) chromate (IIT) **112. What is lanthanoid contraction? What are the consequences of lanthanoid contraction? "#113, Using TUPAC names write the systematic namesof the following: (Jun- 2011,2009) @ [Co(wH,), Jo, Go [Pe(WH,), C1(NH, CH,) Ct Gi) [71(4,0), ” (wy) [Nic J” 114, Explain geometrical isomerism in coordination compounds giving suitable examples. °"*115. Explain the terms (i) Ligand (ii) Coordination number (ii) Coordination entity (iv) Central metal atom/ ion °**116. What is meant by chelate effect? Give example, “*117. Write the characteristic properties of transition elements (TUN - 2009) "#118. Why do the transition metal ions exhibit characteristic colours in aqueous solutions explain giving examples "119. Predict which of the ions Cu’, Se", Mn”, Fe** are coloured in aqueous solution? Give reasons. 120. Account for the zero oxidation state of yj and Fe in [Ni(CO), ] and [Fe(CO), ] respectively Nishith Multimedia India Pvt. Ltd. PageNo. 66 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK “121, Use Hund’srule to derive the electronic configuration of Ce™ ion and calculate its magnetic ‘moment on the basis of ‘spin-only’ formula. Describe the preparation of potassium permanganate. How does the acidified permanganate solution react with (iron) ions (ii) SO, (ii) oxalic acid Write the ionic equations "123. Write a short note on metal carbonyls *122. BIO-MOLECULES 6124, Give the sources of the following vitamins and name the diseases caused by their deficiency. (March-2011, 12) aA b)D ©)E and OK #125, What are hormones ? Give one example for each. (March-2014) 4) Steroid hormones ii) Poly peptide hormones and ii) Amino acid derivatives, +126. Write notes on vitamins, (June-2011) #127. Write notes on the functions of different hormones in the body. (Sune-2010,May-2012) #128, What are enzymes ? Give examples. +129, Explain the classification of carbohydrates. °** 130, What are hormones? Give one example for each. °"* 131. Write the importance of carbohydrates. 132. Discuss the structure of glucose on the basis ofits chemical properties. °*133. What isthe DNA finger printing, mention its applications. *134, Explain the denaturation with suitable examples, CHEMISTRY IN EVERY DAY LIFE *135. Explain the drug - enzyme interaction, *136, What are broad spectrum and narrow spectrum antibiotics ? give one example for each. 137. Explain the following terms with suitable examples §) Cationic detergents (ii) Anionic detergents (ii) Non-ionic detergents, HALO ALKANES AND HALO ARENES ¥**138, Predict the alkenes that would be formed in the following reactions and identify the major alkene Bro CH, NaOEt a E1OH ii) 2-Chloro -2- methyl butane —S0#> 2 ***139, How will you carry out the following conversions ? 1) Ethane to bromoethene 2) Toluene to benzylalcohol \Nishith Multimedia India Pvt. Ltd. Page.No. 67 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK 555740, Write the mechanism of the following reaction n—Butylbromide + KCN "#25 n— butyleyanide “141. Ahydro carbon C,H,, does not react with chlorine in dark but gives a single monochloro compund C,#,C1 in bright sunlight identify the hydrocarbon 142. Explain why the dipolemoment of chlorobenzene is lower than that of cyclohexylchloride. ORGANIC COMPOUNDS CONTAINING C, H & O ALCOHOLS, PHENOLS AND ETHERS +143. Write the mechanism of hydration of ethene to yield ethanol. 144. Explain the acidic nature of phenols and compare with that of alcohols. °”*145. Write the products formed by the reduction and oxidation of phenol "+146. Ethanol with HO, at 443K forms ethane while at 413 K it forms ethoxy ethane, Explain the ‘mechanism. 147. While separating a mixture of ortho and para nitorphenols by steam distillation, name the isomer which willbe steam volatile. Give reason. CARBOXYLIC ACIDS +148. Explain the role of electron with drawing and electron releasing groups on the acidity of carboxylic acids 149. Arrange the following in the increasing order of their acidic strength: Benzoic acid, 4-Methoxybenzoic acid, 4-Nitrobenzoic acid and 4-Methylbenzoic acid. #150, Write the equations of any aldehyde with Fehlings reagent. #151. What is Tollens reagent? Explain its reaction with Aldehydes, ORGANIC COMPOUNDS CONTA! »+* 152. Write the IUPAC names of the following compounds ITROG: ) CH,CH,NHCH,CH,CH, ii) phCH,CN CH,NC NH, * ii) iv) Br Br #153. How do you prepare the following? i) N,N Dimethyl propanamine from Ammonia, ii) Propanamine from Chloroethane: e154, How do you carryout the following conversions? i) N-ethylamine to N,N diethyl propanamine, ii) Anilineto Benzene Sulphonamide "155. How do you prepare ehtyl cyanide and Ethyl isocyanide froma common alkylhalide? * 156. Account forthe following: ’) pK, of aniline is more than that of methylamine. ii) Reduction of alkyleyanide forms primary amine whereas alkyl isocyanide forms secondary amine. * 157. Compare the basicity of the following in gaseous and in aqueous state and arrange themin increasing order of basicity. CH,NH,, (CH,), NH, (CH,), N and NH, \Nishith Multimedia India Pvt. Ltd. Page.No. 68 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK VERY SHORT ANSWER QUESTIONS (2 Marks SOLID STATE 1. How do youdistinguish between crystal lattice and unit cell? 2. Whatiis Schottky defect 3. Whatis Frenkel defect? 4, Stability of a crystal is reflected in the magnitude of its melting point. Comment 5. What makesa glass different from quartz? 6. Howmany lattice points are there in one unit cell of face-centered cubic lattice? 7. How many lattice points are there in one unit cell of face-centered tetragonal lattice? 8 How many lattice points are there in one unit cell of body centered cubic lattice? 9. Explain Ferromagnetism with suitable example. 10. Explain Paramagnetism with suitable example. 11. Explain Antiferromagnetism with suitable example, SOLUTIONS 12 Define the term solution, 13. Define molarity. 14, Define molality. 15. Give an example of solid solution in which the solute is solid. 16. Define mole fraction. 17. Define mass percentage solution. 18. Whatis ppmofasolution? 19. What role do the molecular interactions play in solution of alcohol and water? 20, State Raoult’s law. (Mareh-2014) 21, State Henry's law. 22, Define osmotic pressure, 23, What areisotonic solutions? 24. Amongst the following compounds. Identify which are insolule.partally solube and highly soluble in water. (phenol Gi)toluene ii) formic acid (iv) ethylene glycol (v) chloroform. (vi) pentanol 25. Calculate the mass percentage of aspirin (C,H,0,) in acetonitrile (CH,CN) when 6.5gm of C,H,O, is dissolved in 450g of CH,CN 26. The depression in freezing point of water observed fo the same amount of acetic acid. dichloro-acetic acid and trichloro acetic acid increases in the order given above. Explain briefly. 27. Whatis Van’t Hoff's factor 'j” and how is it related to ‘' in the case of a binary electrolyte 28. Whatis relative lowering of vapour pressure? 29. Calculate the mole fracation of H,50, inasolution containing 98% H,5O, by mass? 30. What are colligative properties, Give examples. ELECTRO CHEMISTRY 31. Whats galvanic cell or a voltaic cell? Give one example. 32, What is standard hydrogen electrode ? 33. Give aneat sketch of standard hydrogen electrode. 34, — What is Nernst equation? Write the equation for an electrode with electrode reaction M™. tne = M,, 35.__ Howis Gibbs energy (G) related to the cell emf (E) mathematically? Nishith Multimedia India Pvt. Ltd. Page.No. 69 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK 36. Whatiscell constant ofa conductivity cell? 37. Define molar conductivity ,, and how is it related to conductivity (K)? 38, State Kohlrausch’s law of independent migration of ions. 39. State faraday's first law of electrolysis. 40. State faraday’s second law of electrolysis. 41, What are the products obtained at the platinum anode and the platinum cathode respectively in the electroysis of fused or molten. NaCl? 42, Give the products obtained at the platinum electrodes (cathode and anode) when aqueous solution of K,80, iselectrolysed. 43, What isa primary battery ? Give one example. 44, Whatisa fuel cell? How ist different from conventional galvanic cell? 45. Give the electrode reactions occuring at the anode and at the cathode in H, ~ O, fuelcell ? 46. Whatis metallic corrosion? give one example 47. Write the cellreaction taking place in the cell Cu. / Cue) / Ag, /A8(s) 48. Write the Nemst equation for the EMF of the cell Ni(S)/Ni°* (aq)// Ag’ (aq)/ Ag 49. Howis £°,, related mathematically to the equllibrium constant K, of the cell reaction? 50. Give one example for a secondary battery. Give the cell reaction. 51. Give the cell reaction of nickel cadmium secondary battery 52. Define conductivity of a material. Give its ST units CHEMICAL KINETICS 53. Define the speed or rate of a reaction? 54, What are the units of rate of reaction ? 55. Whatisrate law? Illustrate with an example. 56. Define order of reaction? Ilustrate your answer with an example. 57, What are elementary reactions? 58. What are complex reactions? Give one example. 59. Give the units of rate constants for Zero, first order and second order reactions? 60. Define molecularity of reaction? Mlustrate with an example. 61. Give two examples for zero order reactions? 62. Write the integrated equation fora first order reaction in terms of [R}, [R], and ‘t’? 63. Give two examples for gaseous first orderreactions? (March-2014) 64. What is half-life ofa reaction? Mustrate your answer with an example? 65. Write the equation relating the half-life (1,,) of reaction and the rate constant ‘K’ for first order reaction? 66. Write the equation useful to calculate half-life (1, ) values for zero and first order reactions? 67. What are pseudo first order reactions? Give one example? 68, Write the Arrhenius equation for the rate constant (k) of a reaction? 69. Write the equation which relates the rate constants &, and X, at temperatures T, and T, of areaction? 70. Draw the graphs between potential energy Vs reaction coordinates for catalysed and uncatalysed reactions? 71. What is the effect of temperature on the rate constant? 72. What israte determining step ina complex reaction? Nishith Multimedia India Pvt. Ltd. Page.No. 70 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK Numerical Problems 73. Forareaction, A+ B— Product , the rate law is givenby, r= k[ A] [B]° What is the order of the reaction? 74, Calculate the half life of first order reaction whose rate constant is 20057! 75. Inareaction, 2A—> Products, the concentration of A decreases from Q.SmolL-! to 0.4mol I-' in 10 minutes. Calculate the rate during this interval, 76. Time required to decompose SO,CI, to half of its initial amount is 60 minutes. Ifthe decomposition is, a first order reaction, calculate the rate constant of the reaction, 777. ‘The decomposition of NH , on plantinum surface sa zero order reaction. what are the rates of production of N, and H, if k=2.5x10“mol™ Ls"? 78. Calculate the overall order of a reaction which has the rate expression 79, Identify the reaction onder from each of the following rate constants. (i) k =2.3%10"L mol s* Gi) k= 3x10" 80. A first order reaction is found to have a rate constant. = 5.5x10"'s"!, Find the half-life of the reaction. SURFACE CHEMISTRY 81, Whatisemubsifying agent? Giveone example. (May 06, Mar 13) 82, What isGold number? 83. Whatisthe general difference between soap and detergent chemically? (March 2014) 84. What is autocatalysis? Give one example. 85. What is Tyndal effect 86, Whatis Brownian movement’? 87. Whatis protective colloid? 88, Wh atis Hardy-Schulze’s law? 89, Whatis adsorption ? Give two applications. 90. Whyisadsorption always exothermic? 91. Define “promoters” and “poisons ” in the phenamenon of catalysis 92. Easily iquifiable gases are readily adsorbed on solids. Why? 93. Why zeolites are treated as shape selective catalysts? 94, Whatis critical mecelle concentration (CMC) and Kraft temperature (T,)? 95, Whats peptization and dialysis? 96. What is electrokinetic potential or zeta potential? 97. Sky appears blue in colour. Explain. 98, What is electro osmosis and electrophoresis? 99, Define flocculation value. GENERAL PRINCIPLES OF METALLURGY 100. What isthe role of depressant in froth floatation? 101, Name the common elements present in the anode mud in the eletrolytic refining of copper. 102, What is the difference between a mineral and an ore? 103, Give the composition of the following alloys. (Mareh-2014) a) Brass b) Bronze ) German silver \Nishith Multimedia India Pvt. Ltd. Page.No. 71 Orman oS (© scaned thon SeamerSR CHEMISTRY QUESTION BANK 140, Explain the structure of XeO,? 141. Write the name & formula of the first noble gas compound prepared by Bertlet? 142, Whydo noble gases form compounds with fluorine and oxygen only? 143. Noble gasesare inert explain’? d_& f£-Block Elements &Coordination Compounds 144, How many moles of AgClis precipitated when | mole of CoCI,.5NH, is treated with AgNO, solution? 145, Write the electronic configuration of chromium (Cr) and copper (Cu) 146. Calculate the ‘spin only’ magnetic moment of Fe*,,.) ion. 147. Whatis analloy ? Give example. 148. What are coordination compounds? Give two examples. 149, What i the difference between a double salt and a complex compound? 150, Whatis a ligand? 151, Whats an ambidentate ligand? Give example. 152, CuSO,.5H,0 is blue incolour where as anhydrous CuSO, is colourless, Why? (Mareh-2014) 153. [Cr(H,),]” isparamagnetic while ['Ni(CN), |” isdiamagnetic. Why? 154, [Fe(CN),]” and [ Fe(#,0), |” areof different coloursindilute solutions Why? 155. Whats the oxidation state of cobalt ini) K[Co(CO), ] and [Co(WH,), ]” ? 156. What are complex compounds ? Give examples. 157. Why do transition elements exhibits characteristic properties. 158. Silver atom has completely filled d orbitals (4a) inits ground state. How can you say that itis a transition element? 159, Among the frst transition series (3d series) Chromium has highest meng point. Why ? 160, _Inits fluoride (or) oxide, in which a transition metal exhibits highest oxidation state and why ? 161. Why Zn’ is diamagnetic where as Mn* is paramagnetic ? 162, Aqueous Cu? ions are blue in colour where as aqueous Zn" ions are colourless. Why ? 163. How do transition metals exhibit catalytic activity ? 164, Give two reactions in which transition metals or) their compounds acts as catalysts 165. Whydo the transition metals readily form alloys 166. Whatis misch-metal give its composition and uses 167. Why do transition elements exhibt more than one oxidation state (variable oxidation states) 168. Give one example each for ionic and neutral ligands 169. Whatis a chelate ligand ? give example. 170. What is anthanoid contraction? POLYMERS 171, Mention thetype of polymerization involved inthe formation ofthe following polymers (Mar 07, 09,2014) a) Bakelite bypvc ©) Polythene 6) Tetlon 172, Whats polymerisation? Give an example of a polymerization reaction. (Mar-2014) 173. What is PHBV? How isit useful to man? (Mar 2011) 174. Define an elastomer. 175, Mention the structures and names of the monomers used for preparing the following polymers. Nishith Multimedia India Pvt. Ltd. PageNo. 73 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK a) Bakelite By Polystyrene Teflon — d) Poly vinyl chioride ©) Nylon- 6,6 (March, 2010) 176, Whatis vulcanization. (May 07 & March 08) 177. What do you mean by polydispersity index” 178, What is Bio-degradable polymer? Give two examples. 179. Write the names and structures of the monomers of the following polymers @Buna-S Gi) Buna-N ii) Dacron Civ) Neoprene. 180, Give anexample of an addition polymer. 181. What iscross linking agent used in vulcanization 182, Is fHN.CHR-CO}, ahomopolymer or a copolymer ? 183. Give two examples for Semi-synthetic polymers ? 184, What isziegler-natta catalyst 185. Give the structure of Nylon-2-Nylon-6 186, What are the monomer repeating units of Nylon - 6 and Nylon - 6,6. 187. Name the different types of molecular masses of polymers. 188, What is the difference between Buna-N and Buna-S? 189, What are fibers? Give example 190. What are thermoplastic polymers? Give example, 191, What are thermosetting polymers? Give example, BIO-MOLECULES 192, Name the vitamin responsible for the coagulation of blood. (Mareh-2009) 193. Why are vitamin A and vitamin C essential to us ? Give their important sources.(Mar,Jun-09, Mar-10) 194, Define Carbohydrates ? 195, What are anomers ? 196, What is Zwitter ion ? Give an example 197, What are essential and non-essential amino acids ? Give one example for each, 198, Why cannot vitamin C be stored in our body ? 199, What is the difference between nucleoside and nucleotide? 200. Name the different types of carbohydrates on the basis of their hydrolysis. Give one example for each, 201. What do you understand from the names (a) aldo pentose and (b) Keto heptose ? 202. Why are sugars classified as reducing and non reducing sugars? 203. What do you understand by invert sugars ? 204. What type of bonding helps in stabilizing the c -helix structure of proteins ? 205. Temperature and pH effect the native proteins. Explain. 206. What are amino acids? Give two examples 207. What are proteins? Give an examples. 208. What are fibrous proteins? Give examples. 209. What are globular proteins? Give examples. 210. Write the names of three types of RNA. 211. Write the biological functions of nuckiic acids. 212. What is glycogen? How is it different from starch, 213. What are the hydrolysis produets of (i) sucrose and (ii) lactose \Nishith Multimedia India Pvt. Ltd. Page.No. 74 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK ‘214, What is the basic structural differece between starch and cellulose. 215. What is denaturation? Give an example, (CHEMISTRY IN EVERY DAY LIFE 216. What are antibiotics ? Give example. 217. What are antiseptics ? Give example. 218, What are anitifertility drugs ? Give example 219. What are artificial sweetining agents ? Give example. 220, What are analgesics ? Give example 221. What are non - Narcotic analgesics ? Give example 222, What are antacids ? Give example. (March-2014) 223, What are antihistamines ? Give example. 224, What are tranquilizers? Give example, 225, What are narcotic analgesics ? Give example. 226, What are antimicrobials? 227. What are disinfectants ? Give example. 228, What are the main constituents of dettot? 229, Whatis tincture of iodine ? What is its use ? 230. What are food preservatives ? Give example. 231. Name two most familiar antioxidants used as food additives. 232. What isthe difference between a soap and a synthetic detergent ? (March-2014) 233. Name the macromolecules that are choosen as drug targets? HALO ALKANES AND HALO ARENES 234. What are the ambident nucloep! 235. What is the stereochemical result of $}, and $3 reactions? 236. What type of isomerism is exhibited by 0, m, and p-chlorobenzenes ? 237. Write the isomers of the compound having molecular formula C,H.,Br 238, What are Enantiomers ? 239, Write the structures of the following compounds. §)2-chloro-3-methylpentane iip1-Bromo-4-sec-butyl-2-methylbenzene 240. Which one of the following has highest dipole moment? CH,Cl, iNCHCI, ii)CCI, 241. Which Compound in each of the following pairs will react faster in sy reaction with OH? i) CH,Br or CHI ii) (CH,), CCI or CH,CI 242. Explain why the alkyl halides though polar are immiscible with water? 243. Out of C,H,CH,Cl and C,H.CHCIC,H, Which is more easily hydrolysed by aqueous KOH? 244, Treatment of alkylhalides with ag. KOH leads to the formation of alcohols, while in presence of ale. KOH what products are formed ? ORGANIC COMPOUNDS CONTAINING C, H & O ALCOHOLS, PHENOLS AND ETHERS 245. Compare the acidic strength of acetic acid, chloroacetic acid, benzoic acid and phenol. (Mar-14) 246. _ Explain why propanol has higher boiling point than that of the hydrocarbon-butane. 247. Alocohols are comparatively more solube in water than hydrocarbons of comparable molecular ‘masses. Explain this fact. 248. Give the reagents used for the prepartion of phenol from chlorobenzene. 249, _ Name the reagents used in the following reactions. Nishith Multimedia India Pvt. Ltd. Page.No. 75 © enim (© scaned thon SeamerSR CHEMISTRY QUESTION BANK (@ Oxidation of primary alcohol to carboxylic acid (i) Oxidation of primary aleoholto aldehyde 250. Write the equations for the following reactions. (i) Bromination of phenol to 2,4,6-tribromophenol (i) Benzyl alcohol to benzoic acid. ALDEHYDES & KETONES 251. Arrange the following compounds in increasing order of their property indicated. 1) Acetaldehyde, Acetone, Methylt, butyl ketone reactivity towards HCN 2) Floroacetic acid, monochloroacetic acid, Acetic acid and Dichloroacetic acid (Acid strength) 252. Write the reaction showing cr -halogenation of carboxylic acid and give its name, 253. How do you distinguish acetophenone and benzophenone? 254, Explain the position of electrophilic substitution in benzoic acid 255. Write equations showing the conversion of - 1) Acetic acid to Acetyl chloride 2) Benzoic acid to Benzamide 256. Write the mechanism of esterification. ORGANIC COMPOUNDS CONTAINING NITROGI 257. Write equations for carbylamine reaction of any one aliphatic amine. (March-2014) 258, Explain Diazotization, (March-2014) 259. Explain why ethylamine is more soluble in water whereas aniline is not soluble. 260. Gabriel phthalimide synthesis exclusively forms primary amines only. Explain, 261. Give structures of A, B and C inthe following reaction C,H.N,CI-S25 A B24 BMA 5 C 262. Accomplish the following conversions: i) Benzoic acid to Benzamide, i) Aniline to p-bromo aniline (March-2014) eee \Nishith Multimedia India Pvt. Ltd. Page.No. 76 © enim (© scaned thon Seamer