Elfante, Erika Naelle L.

2ABC
1 .
Write an
expression for the coefficient of thermal expansion of a Berthelot gas .

R -
p =

a and b)
*
b are constants (V >

↓(E)p
a
coefficient of thermal expansion
=
:

(P 2) IV - b)
+
=

RT

ivPU-pb G E RT)
+

=
-

PTV -

PbTV + aV-ab RTV

I
=

-[30bTV() Pbv2] 9(2)

ov ERVT
(3) 3RTV(E)
PT +

+
+

Simplify ·

PbU2-CRVT=(2RTV+2PbTV
PVS a
3vpT/()
-
- -

/25V +
2PbTV a 3vpT/ - -

/ERTV+ 2PbTV -

a-3VpT/

Pr-PbV-CRVT
(E)
=

p 2RTV+ 2PbTV -

9-3V2pT

PTVS -

PDTV =
RTV2-aV+ ab

(RTV2-aV+ab) -

3RVT)
=I IRTV+ 2PbTV -

a
-
3V PT

ERVT
=(RTV2 aV
)-
-

F
+

IRTV+ 2PbTV -

a
-
3V PT

qV +
-
RTV -

IRTV+ 2PbTV -

a
-
3V PT

=I (ypta-RTV grept
C

ab- aU-RTV2
(2) I
a
:

+ -

2RTU+ 2PbTV -

aT- 3 V2p+2
2 . Write an expression for the variation of temperature as a function of enthalpy and pressure .

Assign values to corresponding

partial derivatives then evaluate the total differential

variables 1, H P
:

T =

+(H P) ,

di
1 (paT (E) P
=

As a function of enthalpy

*+
I =

)p(+ 1)
1(p 1) (4)
0 =

(- 1)
-

-1- ( 1) (p
de
tr

UsT

1
8p()+
- =
M
+
Us Cv

Us Cp

itp " ( )+
As function of pressure

+ 1)p()+ 1) / --
step()

-
= +

Cont
i
-

op
0 =

/(p() +
+

((r p
uscp
1) general
=
-

(*) H ()pll
-

1 =

((p)+ 1)
11 =
p

I I

s
I
M
-