24-12-23

PHYSICS MAX.MARKS: 100

SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
1. A uniform electric field E = (8 m/e) V/m is created between two parallel plates of length
1m as shown in the figure (where m = mass of electron and e = charge of electron). An
electron enters the field symmetrically between the plates with a speed of 2 m/s. The
angle of deviation   of the path of the electron as it comes out of the field will
be_______

A) tan 1  4  B) tan 1  2  C) tan 1 1/ 3 D) tan 1  3

2. Four point charges equal to –Q are placed at four corners of a square and a point charge
q is at its centre. If the system is in equilibrium the value of q is

Q Q Q Q
A) 
4

1 2 2  B)
4

1 2 2  C) 
2
1 2 2  D)
2

1 2 2 
3. A horizontal overhead power line is at a heightof 4 m from the ground and carries a
current of 100 A from east to west. The magnetic field directly below it on the ground is
 0  4  10 7 TmA1 

A) 2.5  10 7 T northwards B) 2.5  10 7 T southwards

C) 5  106 T northwards D) 5  106 T southwards

4. A magnetic needle lying parallel to a magnetic field requiresW units of work to turn
through 600 . The torque needed to maintain the needle in this position will be

3
A) 3W B) W C) W D) 2W
2
5. A metallic rod of length l is tied to a string of length 2 l and made to rotate with angular
speed  on a horizontal table with one end of the string fixed. If there is a vertical
magnetic field ‘B’ in the region, the emf induced across the ends of the rod is

5 2 Bl 2 3 4
A) .Bl 2 B) C) .Bl 2 D) .Bl 2
2 2 2 2

6. A sinusoidal voltage of peak value 283V and angular frequency of 320rad/s is applied to
a series LCR circuit. Given that resistance R  5 , inductance L = 25 mH and
capacitance C  1000  F . The total impedance and phase difference between the voltage
across the source and the current will nearly be (respectively)

5 8
A) 10 and tan 1   B) 10 and tan 1  
3 3

5
C) 7 and tan 1   D) 7 and 450
3

7. The magnetic field of a plane electromagnetic wave is given by

B  3  10 8 sin  200  y  ct    iˆ T . Where C= 3  108 m/s is the speed of light. The

corresponding electric field is


A) E  9 sin  200  y  ct   k v / m

B) E  106 sin sin  200  y  ct   k v / m

C) E  3 108 sin  200  y  ct   k v / m

D) E  9sin  200  y  ct   k v / m

8. Two coherent sources of light interfere. The intensity ratio of two sources is 1:4. For this
I max  I min
interference pattern if the value of 
I max  I min

 I max  Maximum intensity value 

 
 I min  Minimum intensity value 

A) 1.5 B) 1.25 C) 0.5 D) 1

9. The energy required for the electron excitation in Li   from the first to the third Bohr
orbit is

A) 12.1 ev B) 36.3 ev C) 108.8 ev D) 122.4 ev

10. STATEMENT – 1: Energy is released in nuclear fission.

STATEMENT – 2: Total binding energy of the fission fragments is larger than the total
binding energy of parent nucleus.

A) Statement – 1 is True, Statement – 2 is True; Statement – 2 is a correct explanation

for Statement – 1.

B) Statement – 1 is True, Statement – 2 is True; Statement – 2 is NOT a correct

explanation for Statement – 1.

C) Statement – 1 is True, Statement – 2 is False.

D) Statement – 1 is False, Statement – 2 is True.

11. In a Vernier callipers, each cm on the main scale is divided into 20 equal parts.
10Vernier scale divisions are equivalent to 9 main scale divisions.The value of Vernier
constant will be ______  102 mm

A) 5 B) 50 C) 500 D) 200

12. A boy can throw a stone up to a maximum height of 10m. The maximum horizontal
distance that the boy can throw the same stone up to will be ________ (in m)

A) 10 B) 10 2 C) 20 D) 20 2

13. Moment of inertia of a square plate of side l about the axis passing through one of the
corners and perpendicular to the plane of square plate is given by

Ml 2 2 Ml 2
A) B) Ml 2 C) Ml 2
D)
6 3 12

14. Minimum energy required to move a satellite of mass m from an orbit of radius 2R to 3R
is, M = Mass of the planet

GMm GMm GMm GMm

A) B) C) D)
12 R 3R 8R 6R
15. The bulk modulus of a liquid is 3 1010 N / m 2 . The pressure required to reduce the volume
of liquid by 2% is
A) 3 108 N / m 2 B) 9 108 N / m 2 C) 6 108 N / m 2 D) 12 108 N / m 2
16. A sample of an ideal gas is taken through cyclic process abca as shown in the figure. The
change in internal energy of the gas along the path ca is -180J. The gas absorbs 250J of
heat along the path ab and 60J along the path bc. The work done by the gas along the
path abc is

A) 120J B) 130J C) 140J D) 100J

C 
17. The ratio of specific heats  P    in terms of degree of freedom ( f ) is
 CV 

( CP = Specific heat capacity at constant Pressure

CV = Specific heat capacity at constant Volume)

f 2 f 1
A) 1  B) 1  C) 1  D) 1 
3 f 2 f

18. A simple harmonic motion is represented by y  5 sin  3 t   3 cos  3 t  cm

The amplitude and time period of the motion are

3 2 2 3
A) 5cm, S B) 10cm, S C) 5cm, S D) 10cm, S
2 3 3 2
19. Two identical blocks A and B each of mass m resting on the smooth horizontal floor are
connected by a light spring of natural length L and spring constant k. A third block c of
mass m moving with a speed v along the line joining A and B collides elastically with A.
The maximum compression in the spring is

m mv m mv
A) v B) C) D)
2k 2k 2k k
20. A large number of water drops each of radius r combine to form a drop of radius R. If
the surface tension is T and mechanical equivalent of heat is J, the rise in heat energy per
unit volume will be

3T 2T 3T 1 1  2T 1 1 
A) B) C)    D)   
J rJ J r R J r R

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
21. The coefficient of static friction between two blocks is 0.5 and table is smooth. The
maximum horizontal force that can be applied to move the block together is ________N.

22. The centre of mass of a solid hemisphere of radius 8cm is x cm from the centre of the
flat surface. Then value of x is ________.

23. The centre of a wheel pure rolling on a plane surface moves with a speed of v0 . A particle

on the rim of the wheel at the same level as the centre will be moving with xv0 .The
value of x is ________.

24. An ideal gas is expending such that PT 2  C . If gas expands from 0K, the co-efficient of
x
volume expansion of the gas is . The value of x is _____________.
T

x
25. A transverse wave is described by the equation y  y0 .sin 2  ft   . The maximum
 
 y0
particle velocity is equal to four time the wave velocity if   . The integer part of
2
 is __________.(to the nearest integer )
26. In the given circuit diagram, a wire is joining point B and D. The current in this wire is
__________ A.

27. A prism of refractive index  and angle of prism A is placed in position of minimum
angle of deviation. If minimum angle of deviation is also A, then in terms of refractive

index the value of A is  cos 1   . The value of    is__________.
 

28. An  - particle and a proton are accelerated from rest by a potential difference of 100 v.

P
After this their de Broglie’s wavelength are  and P . The ratio to nearest integer is _.


29. Consider the situation shown in figure. The plates of the capacitor have plate area A and
are clamped in the laboratory. A dielectric slab is released from rest with length a inside
the capacitor. Neglecting any effect of friction or gravity the time period of periodic

motion of slab will be   x 

  l  a  lmd  , Then x =___________.(K is dielectric

  0 AE 2  K  1 

constant of the slab.)

30. A particle is moving in a circular path of radius a under the action of an attractive
K
potential U   . Its total energy is ____________.
2r 2
CHEMISTRY MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
31. Which of the following statement is incorrect ?
A) The order of the ionic character of the following chlorides is
BeCl2  MgCl2  CaCl2  SrCl2  BaCl2

B) The reducing nature of alkaline earth metals in aqueous medium follows the
increasing order as Be  Mg  Ba  Ca  Sr
C) Berylium is not readily attacked by acid because of the presence of an oxide film on
the surface of Be.
D) Sodium hydroxide is produced on a large scale by the electrolysis of aqueous
solution of NaCl using Hg as cathode
32. Which of the following product in a hydrogen atom, dependent of the principal quantum
number ‘n’ ? [Given : En  Total energy of electron; rn  Radius of Bohr orbit ; vn 
velocity of electron]
 1  1
A) vn2 . rn B) En . rn C)   . vn2 D) vn .  
 En   rn 

33. At a given temperature the dissociation equilibrium of PCl5 ( g )  PCl3 ( g )  Cl2 ( g ) , the
variation of (1   ) against (D/d) is represented on :
(Given :   dod of PCl5 , D = initial vapour density, d = vapour density at equilibrium)

A) B)

C) D)
34. Find the  pH (initial pH – final pH) when 100 mL of 0.01M HCl is added in a solution
containing 0.1 m moles of NaHCO3 solution of negligible volume

 ka 1  107 , ka2  1011 for H 2CO3 

A) 6  2 log 3 B) 6  log 3 C) 6  2 log 2 D) 6  2 log 3

35. For an ideal gas having molar mass M, specific heat at constant pressure can be given as:

 RM R RM R
A) B) C) D)
(  1) M (  1) (  1) M (  1)

36. For the reaction 2 H 2  2 NO  N 2  2 H 2O the following mechanism has been suggested :

[equilibrium constant  K1 (fast)]

K2
N 2O2  H 2   N2O  H 2O (slow)

K3
N 2O  H 2   N 2  H 2O (fast)

According to following mechanism is correctly matched.

1 d  H2 
A)   K [ NO]  H 2  where K  K 2  K3
2 dt

1 d [ NO]
B)   K [ NO][ H 2 ] where K  K 2  K1
2 dt

d[ N2 ]
C)  K [ NO ] [ H 2 ] where K  K 2  K1
dt

1 d [ NO]
D)   K [ NO]2 [ H 2 ] where K  K 2  K1
2 dt

37. Resistance of 0.2 M solution of an electrolyte is 50  the specific conductance of the

solution is 1.4 Sm1 the resistance of 0.5 M solution of the same electrolyte is 280  the
molar conductivity of 0.5 M solution of the electrolyte in Sm2 mol 1 is

A) 5  103 B) 5  103 C) 5  102 D) 5  104

38. Which of the following order of leaving group is incorrect ?

A) F   Cl   Br   I 

B)

C) CH 3  OH  CH 3  O 

D) Cl   H 

39. Statement-1: The 5th period of periodic table contains 18 elements not 32.

Statement-2: The order in which the energy of available orbitals 4d, 5s and 5p increases
is 5s < 4d < 5p and the total number of orbitals available are 9 and thus 18 electrons can
be accommodated.

A) Statement-1 is true, statement-2 is true, statement-2 is a correct explanation for

statement-1.

B) Statement-1 is true, statement-2 is true, statement-2 is not a correct explanation for

statement-1.

C) Statement-1 is true, statement-2 is false

D) Statement-1 is false, statement-2 is true

40. Which of the following compound used maximum number of non-axial d-orbitals in
hybridization of central atom ?

A) XeF4 B) XeO3 F2 C) XeF5 D) XeO3

41. Which of the following option is CORRECT ?

A) 3 p  3 p  3 p  3d  3d  3d (  bond strength)

B) Ethanol < Glycerol < ethylene glycol (Viscosity)

C) XeO3 F2  XeF4  XeF2 (Dipole moment)

D) In 13th group Al has least S.R.P

42. Assertion (A) : 1 mole of FeC2O4 is oxidised by 0.6 mole of MnO4 in acidic medium

Reason (R) : MnO4 oxidises both Fe 2 as well as C2O42

A) Both A and R are true and R is the correct explanation of A

B) Both A and R are true but R is not the correct explanation of A

C) A is true but R is false

D) A is false but R is true

43. Which one amongst the following are good oxidizing agents ?

a) Sm2 b) Ce 2 c) Ce 4 d) Tb 4

Choose the most appropriate answer from the options given below:

A) c only B) d only C) a and b only D) c and d only

44. The IUPAC name dichloride bis ( ethane 1,2-di amine) cobalt (III) chloride referred for

A) Co  dien 2 C 2  C B) Co  dien  C  2  C

C) Co  en 2 C 2  C D) Co  en 2 C   C  2

45. In Dumas method for estimation of nitrogen, 0.3 g of an organic compound gave 50 mL
of nitrogen collected at 300k temperature and 715 mm pressure. Calculate the
percentage composition of nitrogen in the compound. (Aqueous tension at 300k =
15mm)

A) 40% B) 70% C) 17.5% D) 6%

46. The correct reactivity order of following C  C / C  C bonds towards H  is

A) 4 > 3 > 2 > 1 B) 3 > 2 > 1 > 4 C) 1 > 3 > 4 > 2 D) 1 > 3 > 2 > 4
47. Test Reagent
1) Lucas test a) C6 H 5 SO2Cl
2) Hinsberg test b) Alc KOH  CHCl3
3) Iso cynide test c) An hyd ZnCl2  Conc.HCl
4) Molisch test d) Alc  -naphthol+Conc. H 2SO 4
A. 1-c, 2-a ,3-b, 4-d B) 1-a, 2-c, 3-b, 4-d
C. 1-c, 2-a, 3-d, 4-b D) 1-c, 2-b, 3-a, 4-d
48. P-Cresol reacts with chloroform in alkaline medium to give the compound A which adds
HCN to form, the compound B. The latter on acidic hydrolysis gives chiral carboxylic
acid. The structure of carboxylic acid is

A) B)

C) D)

49.

Me H KSH
A , then A is ?
Et D (major)

H
 A) B)

C) D)

50.

A) B)

C) D)

SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
51. 500 mL of 2M impure H 2 SO4 sample can completely react with 1.5 L of 1 M NaOH
solution. Then find ‘  ’ ?

Weight of H 2 SO4
Where   .
25
52. 1 gram of arsenic dissolved in 86 gm of benzene brings down the freezing point to
-1
5.310 C from 5.500 C . If k f of benzene is 4.9 k. molality , then atomicity of molecule is ?

[Given atomic weight of As = 75 amu]

53. How many of the compound will evolve methane gas on treatment with CH 3 MgBr

(A) H 2O (B) CH 3  OH (C) CH 3COCH 3 (D) CH3COOH

(E) CH 3CONH 2 (F) CH 3COCl (G) CH 3COOCH 3 (H) CH 3Cl

(I) Ph  OH

54. Br2
C6 H12 
CCl4
 C6 H12 Br2

X (Optically inactive single product with 2 chiral center)

How many structures of “X” can satisfy above reaction condition ?

55. How many of the following ions gives precipitate with H 2S+NH 4 OH

Pb 2 , Cu 2 , Al .3 , Ca 2 Mn 2 , Zn 2 , Cd 2 , Cr 3 , Mg 2

56. How many isomers obtained by the halogenation of ethane?

57. The number of monobromo products (including stereoisomers) obtained during heating
of methylcyclobutane with Br2 .

58. The condensation of two amino acids, glycine and () alanine yields total products x.
Find value of x. Assume that only dipeptides are formed.

59. How many of the following compounds contains carboxylic acid group ? Ascorbic acid,
Phthalic acid, Cinnamic acid, acrylic acid, aspirin, formic acid, picric acid, adipic acid.

60. Total number of  -keto monocarboxylic acids (including stereoisomers) which on

heating give .
MATHEMATICS MAX.MARKS: 100
SECTION – I
(SINGLE CORRECT ANSWER TYPE)
This section contains 20 multiple choice questions. Each question has 4 options (1), (2), (3) and (4) for its answer,
out of which ONLY ONE option can be correct.
Marking scheme: +4 for correct answer, 0 if not attempted and -1 if not correct.
61. The set of values of a for which all extremum of

 
function f ( x)  x3  3ax 2  3 a 2  1 x  1 lie in the interval  2,4 is

A)  3,4  B)  1,3 C)  3, 1 D)  2, 1

 sin 101x   sin

99
62. x  dx equals

sin 100x  sin x  cos 100x  sin x 

100 100

A) C B) C
100 100

cos 100x  cos x  sin 100x  sin x 

100 101

C) C D) C
100 101

 tan 4 x

  4  tan 3 x 
; 0 x
 3  2

 
63. The function f ( x )  b  2 ; x then the sum  a  b  if f is
 2
 a
|tan x| 
 (1 | cos x |) b
;  x 
 2


continuous at x  is
2

A) –1 B) 1 C) 2 D) –2

64.    
Let f ( x)  [a]2  5[a]  4 x3  6{a}2  5{a}  1 x  (tan x)sgn x, be an even function for


all x  R   2n  1 , n  Z then sum of all possible values of a is (where [.] and {.}
2
denote the greatest integer function and fractional part functions respectively)

70 35 35 70
A) B) C) D)
3 6 3 6
65. Let y  y  x  be the solution of the differential equation

dy
dx

 1  xe yx ,  2  x  2, y  0   0 then the minimum value of y  x  , x   2, 2 is 
equal to

 
A) 2  3  log e 2  
B) 1  3  log e  3 1 
 
C) 1  3  log e  3 1   
D) 2  3  log e 2

 3 1 
 
66. If P   2 2  , A   1 1  and Q  PAPT then the inverse of PT Q2023 P is
 0 1
 1 3  
 
 2 2 

 1 2023   2023 0  1 0   1 2023 

A)  B)  C)  D) 
0 1   1 1  
 1 2023  0 1 

67. The number of numbers between 2000 and 5000 that can be formed with the digits
0,1,2,3,4 (repetition of digits is not allowed) and are multiple of 3 is :

A) 24 B) 30 C) 36 D) 48

  1  x2 
68. The range of the function f ( x )  cos 1  
log 4 x 
2
 sin 1 
 4 x
 is equal to


           
A)  0,   B)  ,   C)  ,  D)  
 2 2  2 2 2 6 2 6

 e x  k, x0
 x
69. If f  x    e  1, 0  x  1 is one-one and monotonically increasing for all
 ex 2   , x 1

x  R, then difference of maximum value of k and minimum value of  is

A) 0 B) 1 C) 2 D) 3
70. f ( x ) is differentiable function which satisfies the equation

x x   
f ( x)    f (t ) tan tdt   tan(t  x) dt where x    ,  , passes through  0,0 , then
0 0
 2 2
the maximum value of f ( x ) is

A) 1 B) –1 C) 0 D) 2

71. Four digit numbers are formed using the digits from the set 0,1, 2,3, 4,5 repetition of
digits is allowed then

Statement- S1 The number of such numbers formed that are odd is 480

Statement- S 2 The number of such numbers formed such that it contains exactly three
different digits is 360

A) S1 , S 2 are true B) S1 , S 2 are false

C) S1 is true and S 2 is false D) S1 is false and S 2 is true

x  3 y  2 z 1 x3 y 6 z 5
72. The shortest distance between the lines   and   is
2 3 1 2 1 3

18 22 46
A) B) C) D) 6 3
5 3 5 3 5

73. Two loaded dice each have the property that 2 or 4 is three times as likely to appear as

1 or 3 or 5 or 6 on each roll. When two such dice are rolled, the probability of obtaining
a total of 7 is

1 1 7
A) B) C) D) none of these
8 7 50

74. Circles of radii 36 and 9 touch externally. The radius of the circle which touches the two
circles externally and also their common tangent can be

A) 4 B) 5 C) 17 D) 18
75. Consider a branch of the hyperbola x 2  2 y 2  2 2 x  4 2 y  6  0 with vertex at the
point A. Let B be one of the end points of its latus rectum and C be the focus of the
hyperbola nearest to the point A, the area of the triangle ABC is :

3 3 3 2
A) B) 1 C) 1 D)
2 2 2 3

76. The vector r , which is normal to both a  4iˆ  5 ˆj  kˆ and b  iˆ  4 ˆj  5kˆ and r  c  21

Where c  3iˆ  ˆj  kˆ is_____

A) 7(iˆ  ˆj  kˆ) B) 7(iˆ  ˆj  kˆ) C) 7(iˆ  ˆj  kˆ) D) 7(2iˆ  ˆj  2kˆ)

1 1
77. Let A and B be two independent events such that P  A   and P  B  . Then, which
3 6
of the following is TRUE?

A 2  A  1 A 1  A  1
A) P    B) P    C) P    D) P  
B 3  B  3  B  3 A B 4

Let  ,  be two roots of the equation x2  (20)1/4 x  (5)1/2  0 . Then    is equal to

8 8
78.

A) 10 B) 50 C) 5 D) 30

79. Let A  1,a1 ,a 2 ,.......a18 ,77 be a set of integers with 1  a 1  a 2  ......  a 18  77 . Let the

set A  A  x  y : y  A contain exactly 39 elements. Then, the value of

a 1  a 2  .....  a 18 is equal to_____.

A) 600 B) 702 C) 800 D) 200

80. Normals of parabola y2  4x at P and Q meets at R  x 2 ,0 and tangents at P and Q meets

at T  x1 ,0  . If x 2  3, then the area of quadrilateral PTQR is____

A) 4 B) 8 C) 12 D) 6
 SECTION-II
(NUMERICAL VALUE ANSWER TYPE)
This section contains 10 questions. The answer to each question is a Numerical value. If the Answer in the
decimals , Mark nearest Integer only. Have to Answer any 5 only out of 10 questions and question will be
evaluated according to the following marking scheme:
Marking scheme: +4 for correct answer, -1 in all other cases.
81. Let p,q,r  R  and 27pqr  (p  q  r)3 and 3p  4q  5r  12 then the value of
8p  4q  7r is equal to_______.

sin  3x 2  4x  1  x 2  1
82. If lim  2, then the value of  a  b  is equal to______
x 1 2x 3  7x 2  ax  b

83. Let f : R  R be a differentiable function such that

f  x   x 3  x 2 f  1  xf   2   f   3 , x  R . Then f  2  is equal to

84. Suppose a class has 7 students. The average marks of these students in the mathematics
examination is 62, and their variance is 20. A student fails in the examination if he/she
gets less than 50 marks, then in worst case, the number of students that can fail is_____

85. Consider the set of all triangles OPQ where O is the origin and P and Q are distinct
points in the plane with non-negative integral coordinates  x, y  such that 5 x  y  99 .

Number of such distinct triangles whose area is a positive integer is______

log x K
86. If the area of the region bounded by the curves y  ex log x and y  is , find the
ex 4e
value of [K] (Where  represents greatest integer function) _____

87. Using all of 0,0,0,1,1,1,-1,-1,-1, a set ‘S’ of all 3  3 matrices formed.If number of
symmetric matrices in S is K and number of matrices having trace zero in S is P, then the
P
value of  K is
10

x  2 y 1 z  3
88. The foot of perpendicular of the point (0,2,7) on the line   is
1 3 2
4
( ,  ,  ) then the value of is

89. A spherical iron ball of radius 10cm is coated with a layer of ice of uniform thickness
that melts at a rate of 50 cm3/min. When the thickness of the ice is 5cm, the rate at which
1
the thickness (in cm/min) of the ice decreases is , find the value of k.
k

90. If the equation z 4  a1 z 3  a 2 z 2  a3 z  a 4  0 where a1 , a2 , a3 , a4 are real coefficient

different from zero has purely imaginary roots then find the value of the expression
a3 aa
 1 4.
a1a2 a2 a3
 Date: 24-02-23
Time: 3 HRS Max. Marks: 300
KEY SHEET
PHYSICS
1 B 2 B 3 D 4 A 5 A
6 D 7 D 8 B 9 C 10 A
11 A 12 C 13 B 14 A 15 C
16 B 17 B 18 B 19 A 20 C
21 15 22 3 23 2 24 3 25 3
26 2 27 4 28 3 29 8 30 0

CHEMISTRY
31 B 32 D 33 A 34 A 35 D
36 D 37 D 38 D 39 A 40 C
41 D 42 A 43 D 44 C 45 C
46 D 47 A 48 B 49 D 50 A
51 3 52 4 53 5 54 1 55 5
56 9 57 8 58 9 59 6 60 6

MATHEMATICS
61 B 62 A 63 A 64 C 65 B
66 B 67 B 68 D 69 C 70 C
71 B 72 A 73 C 74 A 75 B
76 C 77 C 78 B 79 B 80 B
81 5 82 11 83 2 84 0 85 90
86 2 87 540 88 3 89 18 90 1
 SOLUTIONS
PHYSICS
1. Given velocity in x-direction
vx  2 m / s
Acceleration
E   e  8m   e  
a     . j  8 jm / s 2
m e m
d 1
 time, t   s
vx 2
1
Now y  .a y t 2
2
vy  u y  ayt
1
v y  0  8   4m / s
2
v 4m / s
Now tan   y  2
vx 2 m / s
  tan 1  2
2. In the diagram balance all the forces

3.

0i
B
2 d


 4 107   100 
2  3.14  4
B  5  106 T (Southwards)
4.   MB  cos2  cos 1 
MB
  MB  cos 600  cos 00  
2
Torque  MB sin 60  2.sin 600
0

 3
5.

3L
   B xdx
2L

5
  .Bl 2
2
6.  0  283v,   320 s 1
z  R2   X L  X C 
2

 7
 X L  XC 
  tan 1    45
0

 R 
7. Conceptual
 
2
I max  I1  I 2
8.
 
2
I min I1  I 2
Simplifying the required answer will be 2
9. Using
z2
En  13.6 2 ev
n
 3
2

E1  13.6 2 ev  122.4 ev
1
 3
2

E3  13.6 2 ev  13.6 ev
 3
E  108.8 ev
10. Conceptual
11. Vernier constant = Least count
1 MSD
= ,  10

1cm
1 MSD 
20
u2
12. H max   10m....... 1
2g
u2
Rmax   20m,   450  angle of projection 
g
13. I  I com  md 2
2
mL2  L 
  m 
6  2
2
I  ml 2
3
14. Energy   TE 3R   TE 2 R
GmM  GmM 
  
3R  2R 
GmM
Energy 
6R
DV
15. P   B.
V
 6  108 N / m2
16. Alongbc w  0
Q  V  60 J
Along ab u  180  60  120 J
also Q  250 J
So
w  250  120  130 J
Hence wab  wbc  130  0  130 J
fR
17. CV 
2
CP  CV  R
fR  f 
CP  R  CV  R   R 1  
2  2
CP

CV
18.

2
T ,   3 

19.

1 mm 1
  v  0   kx 2
2
.
2 2m 2
20. Energy lost = Energy utilised for rise in temperature.
21.

F
ac 
z
F
FBD of 1Kg f  1
3
 f
 110    f  15 N
z
3R
22. x
8
23.

24. PT 2  C
 RT 2
.T  C
V
T 3V 1  C
Differentiating
1 dV 3
. 
V dT 1
y  y 
25. find &    2 fy0
t  t max
wave velocity  f 
26. Find equivalent resistance then distribute current.
 Am 
sin  
27. Use m   2 
sin  A / 2 
m  4
h
28. 
2mav
P m q
  82 2 3
 mP q P
29.

1 2 F
S at , a 
2 m
T  4t
K dv K
30. U  2 ,F    3
2r dr r
2
mv K K
 3  mv 2  2
r r r
Total energy = KE + PE = 0
 CHEMISTRY
31. Conceptual
Z
32. Vn 
n
n2
rn 
Z
Z2
En 
n2
33. PCl5  PCl3  Cl2
1 0 0
(1   )  
Law of conservation of mass
WPCl5  Weq m
M PCl5  (1   ) M eq
M PCl5 D
(1   )  
M eq d
pKa1  pKa2
34. ( pH )i  9
2
( pH ) f  3  2 log 3
 pH  6  2 log 3
CP , m
35. CP 
M
R
 CP , m 
(  1)
R
CP 
M (1)
36. According to slow step
r (t )  K 2  N 2O2  H 2 

Where K1 
 N 2O2 
 NO 
2

 N 2O2   K1  NO 
2

So, r (t )  K 2 K1  NO   H 2 
2

So, r (t )  K 2 K1  NO   H 2  K
2

1 d H2  1 d [ NO] d[ N 2 ]
    K [ NO]2 [ H 2 ]
2 dt 2 dt dt
Where K  K1 K 2
37. K GC*
C*  70
2 70
m    5  104
280 1000  0.5
38. Leaving group ability  its stability
Weak base are good leaving group
39. Conceptual
40. d xy , d yz , d zx are also known as non-axial d-orbitals
41. (A) 3 p  3 p  3 p  3d  3d  3d (  bond strength)
(B) Ethanol  C2 H 5OH  < ethylene glycol
 CH 2  CH 2 
 
 | |   Glycerol
 OH OH 

 CH 2  CH  CH 2 
 
 | | |  (Viscosity)
 OH OH OH 

(C) XeO3 F2  XeF4  XeF2 (All have zero dipole moment)
(D) more electro positive element in 13th group is Al
42. Conceptual
43. Conceptual
44. dien is tridentate
w
45. 0.05  0.92   0.0821  300
28
w  0.0522
w%  17.46
46. ror  stability of C 
47. Conceptual
48. Conceptual
49. SN 2
50. Cannizaro followed by esterification
moles of NaOH
51. 
2
moles of NaOH
WH 2 SO4   98
2
(0.75  98)
 3
25
1 1000 4.9
52. 0.19   
75 86 x
x4
53. Conceptual
54.

55. Both 2nd and 4th group cations are precipitated in the presence of H 2 S  NH 4OH
56. Mono halo product =1
Di halo products =2
Tri halo products=2
Tetra halo products=2
Penta and hexa are each one  total =9
57.

58. Conceptual
59.
OH

HO O
O

OH OH
Ascorbic acid
60. Conceptual

MATHS
61. f ( x)  x  3ax  3  a  1 x  1
3 2 2

f  ( x)  3x 2  6ax  3  a 2  1
 3( x - (a  1))( x - (a -1))
So f  ( x)  0  x  a  1 or a  1
 a  1 (2,4) if a  (3,3)
And a  1 (2,4) if a  (1,5)
 a  (1,3)
62. Apply by parts
 tan 4 x
4
 
tan 3 x 
;0  x 
 3  2

 
63. f ( x )  b  2; x 
 2
 a
|tan x| 
(1 | cos x |)
b
;  x 
 2
 tan 4 x tan 4 h

 4  tan 3 x 4 (  cos 3 h )
lim f ( x)  lim f    lim  
x

x
 3 h 0 3
 
2 2
So, =1=b+2
B=-1
a
|tan x|
lim f ( x)  lim (1 | cos x |) b
 
x x
2 2
a
 |tan x|
lim (1  cos x) b

x
2
a
 cot h
lim(1  sinh) b
h 0
a a
cosh
 lim(1  sinh) b
e b
h0 sinh
a
1 e  b  2
b

a=0, b  1
a+b  1
64. f ( x)   x3   x  (tan x)sgn x
f (- x)  f ( x)
   x3   x  tan x sgn x
  x3   x  (tan x)(sgn x)
 2  x 2    x  0x  R
   0 and   0
 [a]2  5[a]  4  0
and 6{a}2  5{a}  1  0
 (3{a}  1)(2{a}  1)  0
 [a ]  1,4 and {a}  1 / 3,1 / 2
1 1 1 1
 a  1  ,1  ,4  ,4 
3 2 3 2
35
Sum of value a 
3
dy
65.  1  xe yx
dx
dy
 e y  e y  xe x
dx
dy dt
Let e y  t  e y 
dx dx
dt
  t  xe x
dx
 dt
 t  xe x
dx
 Integrating function  e 
1dx
 ex
 Solution is t  e x    xe x  e x dx
x x2
te    C
2
x2
exy    C
2
 y 0  0  C  1
x2  x2 
 exy  1   y  x   x  ln 1  
2  2 
‘P’ is orthogonal matrix. i.e., P.P  P .P  I
 
66.
 
And Q 2023  PAPT PAPT     PAPT   
 PT Q 2023 P  PT  PA2023 P P
T

1 1  1 11 1  1 2 
Similarly A     A2     
 0 1  0 1 0 1  0 1 
1 3 
A3   
0 1
 1 2023 
A2023  
0 1 
 1 2023 
 PT Q 2023 P  
0 1 
 1 2023 
The inverse of PT Q 2023 P is 
0 1 
67. For multiple of 3, the sum of all digits should be divisible by 3.
So, number can be formed 0,1,2,3 (sum is 6 which is divisible by 3) or 0,2,3,4 (sum is 9which is
divisible by 3). 0 and 1 cannot be on highest digit in the number. Therefore, number of 4 digit
numbers
 2  3! 3  3!  30
 1  x2 
68. We have f ( x )   sin
1
 
log 4 x  sin  1

 4x 

Clearly domain of f ( x) is x  1 only, so f (1) 
2 
0  sin 1   
4 6
 
Hence range of f ( x)   
6
69. Draw the graph of f  x  .
 x x
70. f ( x)    f (t ) tan tdt   tan(t  x) dt
0 0
x x
f ( x)    f (t ) tan tdt   tan(t )dt
0 0
(Use f (a  x)  f ( x))
x x
f ( x)    f (t ) tan tdt   tan(t )dt
0 0
Differentiating w.r.t x, we have
f  ( x)   f ( x ) tan x  tan x
dy
 (tan x) y  tan x
dx
dy
 (tan x) y   tan x
dx
IF  e 
tan xdx
 elog sec x  sec x

Therefore, solution is y. sec x   secx tan xdx  c
Or y sec x   sec x  c
Or y  c cos x  1
Curve passes through (0,0)
 0  c  1 or c  1
 y  cos x  1
Therefore, the maximum value of y is 0.

71. We have
In S1 units place can have 1 or 3 or 5
4!
In S 2 it is 5C3  3   5C2  9  2  6   600
2!

72. Line passes through the points a1  (3, 2,1) a
 
a2  (3,6,5), b1  2iˆ  3 ˆj  kˆ
  
b1  2iˆ  ˆj  3kˆ, a2  a1  6iˆ  4 ˆj  4kˆ
   
SHORTEST DISTANCE 

 a2  a1  b1  b2 
 

b1  b2 
iˆ ˆj kˆ
 
b1  b2 2 3 1  10iˆ  8 ˆj  4kˆ
2 1 3
   
 
 a  b  
 2 1  1  b2  60  32  16  108
a
b1  b1  100  64  16  180
108 108 18
S .D   
180 6 5 5
73. Let the probability of the faces 1,3,5 or 6 p for each face.
Hence the probability of the faces 2 or 4 is 3p. therefore
1
4 p  6 p 1 p 
10
1
P(1)  P(3)  P(5)  P(6) 
10
3
P(2)  P(4) 
10
P( total of 7 with a draw of dice )  P(16,61,25,52,43,34)
1 1  3 1  3 1
 2    2    2  
 10 10   10 10   10 10 
2  6  6 14 7
  
100 100 50
74. Apply condition for externally touching circle.
2
 x  2  ( y  2) 2
75. The hyperbola    1
 4  2
3
a  2, b  2, e 
2
If D be the centre, then
DC  ae  6 and DA  a  2
b2
AC  6  2 and BC   1
a
1 3
Now area of ABC  ( AC )( BC )  1
2 2
76. Use r  a  0
r b  0
Where v  xiˆ  yjˆ  zkˆ
And x  iˆ  21
 A  P  A  B 1
77. For option (1) P     PA 
B P  B 3
 A  2
Similarly P    P  A   
 B  3
1 5
A P  
A 1  P   3  6 1
B
P    
 B  1  P  B  5 3
6
 A  P  A   A  B 
P 
 A B P  A  B
 1
PA 3
 
P  A  B 1 1
 
1
3 6 18
6 3
 
6  3 1 4
1 1

 
2
78. x  5  (20) x  x 2  5
2 2 4
 20 x 2
 x 4  5  2 5 x 2  2 5 x 2  x 4  5  x8  25
So,  8   8  50
79. If we write the elements of A + A, we can certainly find 39 distinct elements as
1  1,1  a 1 ,1  a 2 ,.......1  a 18 ,1  77,a 1  77, a 2  77,....a 18  77,77  77 .
It means all other sums are already present in these 39 values, which is only possible in case when all
numbers are in A.P.
Let the common difference be ‘d’
77  1  19d  d  4
18
18
So,  a1   2a1  17d   910  68  702
i 1 2
80. PQ is focal chord.
Quadrilateral PTQR is square

PQ  TR
Area  8
2
3
81. Given 27 pqr  ( p  q  r )
But using AM  GM
pqr
  ( pqr )1/3
3
 p  q  r (using (i) and (ii))
Also, 3 p  4q  5r  12
 sin  3x 2  4x  1 
   3x 2  4x  1  x 2  1
 3x  4x  1 
2

82. lim    2
x 1 2x  7x 2  ax  b
3

3x 2  4x  1  x 2  1
 lim  2
x 1 2x 3  7x 2  ax  1
 2  x  1
2

 lim 3  2
x 1 2x  7x 2  ax  b

So f  x   2x 3  7x 2  ax  b  0 has x  1 as repeated root, therefore f 1  0 and

f  1  0 gives a  b  5 and a  8
So, a  b  11

Let f  x   x  ax  bx  c
3 2
83.
f   x   3x 2  2ax  b  f  1  3  2a  b
f   x   6x  2a  f   2   12  2a
f   x   6  f   3  6
 f  x   x 3  f  1 x 2  f   2  x  f   3
 f  1  a  3  2a  b  a  a  b  3 .......1
 f   2   b  12  2a  b  2a  b  12 ....... 2 
From 1 and  2 
3a  15  a  5  b  2
 f  x   x 3  5x 2  2x  6
 f  2   8  20  4  6  2
84. According to given data
7

 x  62 
2
i
i 1
 20
7
7
   X i  62   140
2

i 1

So for any X i ,  Xi  62   140

2

 X i  50 i  1, 2,3,.....7
So no student is going to score less than 50.
85.

0 0 1
1
Area  x1 99  x1 1
2
x2 99  x2 1
1
  x1  99  x2   x2  99  x1  
2
 1
Area   x1  x2  99 
2
Area is an integer. Then both x1 and x2 are simultaneously either even or odd.
10
Hence, C2 10 C2  2 10 C2  90
1
log x
86. Area bounded 
1/ e
 ex

1
1   log x 
2 1
  x2 x2 
    e  log x  
e  2 1
  2 4 1
e e

 1 
1 
1 1   2 e2 
     e 2  
e  2   2e 4 

 
1 1 e 1
   
2e 2e 4 4e
e 5
 
4 4e
87. K  3! 3! 1  36
P  6! 3! 6!  6! 7  5040
88. Conceptual
4 4
Vice   10  r    10 
3 3
89.
3 3
dV 4 2 dr
  310  r 
dt 3 dt
2 dr
 4 10  r 
dt
dr
At r  5,50  4  225
dt
dr 50

dt 4  225 
1
 cm/min
18
90. Let z  iy
 y 4  a1 y 3i  a3 y 2  ia3 y  a4  0
 y 4  a2 y 2  a4  0  1 and  a1 y 3  a3 y  0

 y  0 or y 2  a3   2 
a1
From (1) and (2)
a32 a
2
 a2 3  a4  0
a1 a1
a3 aa
  1 4 1
a1a2 a 2 a3