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AITS-FT-II-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

Chemistry PART – II
SECTION – A

1. D
It is a chain silicate.

2. C
Total  H    CH  due to HCl  OH   .

3. C
(A) Both carbonates give oxides and CO2 gas.
(B) Both bicarbonates give carbonates, CO2 and H2O
(C) MgCl .6H O  
 MgCl .H O  5H O
2 2 2 2 2

Mg  OH Cl  HCl

Na2 SO4 .10 H 2 O 
 Na2 SO4  10 H 2 O
(D) Both the sulphates give oxides and SO3

4. C
A  3B
a 0
a  x 3x
V0  a  and Vt   a  5x 
2.303 5V0
 equation is K  log
t 6V0  Vt
Substituting Vt  2V0 at t  971sec
2.303 5 2.303
K  log   .0971  2.303  10 4
971 4 971
.693
 t1/ 2   3010 sec
2.303  10 4

5. D
Ortho can be easily reduced than para isomer, more rings can also be reduced easily

6. D
O O O O
CH3 CH3 CH2-
CH- CH2

O- O O
7. C
1 3

NH 3   N2   H 2 
2 2
n 0 0
n 3n
n 1   
2 2

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AITS-FT-II-(Paper-1)-PCM(Sol)-JEE(Advanced)/16

 1   3  
Partial pressure at equation   P; P;  P
 1    2 1    2 1  
1/2 3/ 2

Kp 
P  P 
N2 H2

3 3P   2 
 
PNH 3 4 1   2 
1/ 2
 3 3 P 
   1  
 4 K p 

8. B, C
Polar forms are more stable in polar solvents.

9. A
Volume of H2SO4 used at equivalence point is 15mL.
15  0.2  2  20  conc.
Conc. = 0.3

SECTION – B

2. (A)  q, (B)  r, (C)  p, t, (D)  s, t

(p) 2 H   2e   H 2
0.0591 1
E log 2
 0.414 V
2 107 
(q) H 2   2H   2e 
[It will be oxidation potential]
(r) 2 Hg  Cl2   Hg 22   2Cl 
(s) Ag   e 
 Ag

 Ag  

1016  108 M

SECTION – C

4. The coordination compound is Pd  PdF6  . The coordination number of Pd  IV  is six:

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