PAPER - 2

One or More Correct Type

1. O
-
OH
H3C CH3
O

O O O
CH3
Which of the following is/are involved in the mechanism of above conversion?
(A).Acid base reaction (B) Nucleophilic addition
(C) E1CB (D) dehydration
Ans: ABCD

2. O
-

H3C O

O
Br
Which of the statements regarding the product formed in the above reaction is correct?
(A) If Br is replaced with NO2 rate of reaction increases
(B) Inversion of configuration takes place.
(C) Nucleophilic acyl substitution takes place.
(D) Configuration at chiral carbon does not change
Ans: ACD
3. Identify the incorrect statement

(A) If Pure water is heated to 700C, pH will increase but solution will be neutral

(B) Na2HPO3 is an amphiprotic species

(C) When a solution of a weak monoprotoc acid is titrated against a strong base, at half-
Pk a
neutralization point pH 
2

(D) H3BO3 is a monobasic acid

Ans: ABC
4. Choose the correct statement(s) from among the following
2
 an 
(A) The corrected pressure  P  in vander waals’ equation (symbols have their usual
 v2 
meanings) is the pressure which the gas would exert if it was ideal.
(B) Above their respective Boyle’s temperature, N2 shows throughout positive deviation
while O 2 shows negative deviation followed by positive deviation in Z vs P graph
(C) At inversion temperature, real gas behaves as ideal gas
(D) The intercept of PV vs. P isotherm of any gas at 27°C is approx. equal to 24.6 L atm.
Ans: AC
5. Which is /are correct
(A) Cr(VI) is more stable than Mo(VI) and W(VI)
(B) Sc (I) is more stable than Sc(II) and Sc(III)
(C) The transition metal ions containing empty d-orbital’s [e.g Sc3+ and Ti+4ions] or completely
filled d-orbital’s [e.g Cu + ,Ag + ,Zn 2+ ,Cd 2+ ,Hg 2+etc] in dry state are colourless
(D) Eo Cu2+ /Cu o
is +ve among E M2+ /M of 3d series elements as energy required to transform

Cu(s)  Cu 2 ( g ) is more than hydration enthalpy of Cu+2.

Ans: CD
6. In which of the following cases will a violet/purple colouration be observed
(A) An alkaline solution of sodium nitroprusside is treated with a solution of Na2S
(B) A solution of sodium cobaltinitrite is treated with KCl
(C) A solution of Mn(NO3)2 is treated with sodium bismuthate or red lead in the presence of
concentrated HNO 3
(D) A solution of sodium nitroprusside in aqueous, NaOH is heated with Na SO3
2
Ans: AC

Solution: A solution of Mn(NO3)2 is treated with sodium bismuthate or red lead in the presence of
concentrated HNO 3 forms permanganate ion
Numerical Type
Br2 (1 mole)
7. Reaction X: Acetone →
OH -
(1 mole)

Br2 (1 mole)
Reaction Y: Acetone 
CH COOH
→
(1 mole) 3

Number of moles of unreacted acetone left after the reaction in Reaction X and Reaction Y are 'a' and 'b' respectively.
The value of (a+b) is.....
Ans: 0.67

8. In the below reactions X number of reactions give aromatic species Whereas Y number of reactions give gaseous
product. The value of (X/Y) is....

NaNH2
(I)

NaNH2
(IV)

(II) + 2K

NaNH2
(III)

Ans: 1.50

9 . In the below compounds, number of compounds which show geometrical isomerism are X and number of
compounds which exhibit optical isomerism are Y. The value of (Y/X) is:

(i) (ii) (iii)

F Br

(iv) Ph – N = N – Ph (v) (vi) Cyclooctene

Cl I

(vii) MeCH = N – NH 2 (viii) PhCH = N – OH

(ix)

Ans: 0.50
10. Pure oxygen is manufactured by the following sequential reactions, where MnO 2 is acting as a
catalyst. The yield in each step of reaction is 50%.
(i) MnO2  s  2KClO3  s    K 2MnO4  s  Cl2  g   2O2  g  ;
(ii) K 2MnO 4  s   Cl2  g   2KCl  s   MnO 2 s   O 2  g  ;
How much mass of KClO3 in gms is required to liberate 60 g of O2 gas at STP?
(Atomic mass : K = 39, Cl = 35.5, O = 16)
Ans: 367.50

11. In the given graph, the area of circle A

and B are 40 unit and 36 unit respectively,
total work done ‘P’ unit.
A B
P

V
When a system is taken from state A to B C B
along path ACB, as shown in the figure, 5
unit of heat flows into the system and the
system does 3 unit of work. If ‘ Q’ unit heat
flows into the system along the path ADB,
and the work done by the system is 2 unit. A D

Then the value of (P x Q) is

Ans: 16.00

Solution: P = 4 and Q = 4
.
12 X number of below metals can be refined by vapour phase refining
Zr, Zn, Cd, Hg, Ni, Co, Pt, Fe, Ti

Y number of metals from the below ores can be produced by self reduction method
HgS, PbS, Cu2S, FeS, ZnS, Na2S
The value of (X/Y) is:
Ans: 1.00

Solution: X = 3(Zr,Ni,Ti); Y = 3 (HgS, PbS, Cu2S)

13. The dipole moment of a polar covalent molecule XY is 3.15468 debye. The bond length of XY is
8
1.27  10 cm. If the percentage ionic character in the molecule is expressed as X%, then the
–

value of ‘X’ will be

Ans: 51.70
14. X number of below compounds are more basic than aniline?
O  toluidine, O  anisidine, m  anisidine, P  anisidine, P  chloroaniline, m  toluidine,

, H2N C NH
N NH2
H

Y number of below compounds are more acidic than benzoic acid

COOH COOH COOH COOH

O
|| Picric acid, 2,4 dinitro phenol
H — C — OH , H 2C 2O 4 ,
,

CH3 NO2 N(CH3)2 CF3

The value of (X/Y) is....

Ans: 0.67

Solution: X = 4 and Y = 6
Numerical Type
15.
Column – I Column - II
(A) XeF4  H2O     (p) Shows disproportionation reaction
One of the product is a monobasic Lewis
P4  s   OH  aq   H2O    


(B) (q)
acid but not bronsted acid
(C) B 2H6  H2O     (r) One/two of the products is/are gas(es)
One of the product has trigonal
(D) Br2  g  k2 CO3  aq 

 (s)
pyramidal structure
One of the gaseous product is used
(t)
as Holme’s signal in sea

Which of the following combination is correct?

(A) A-prs; B-prst; C-qr; D-prs (B) A-prt; B-prst; C-qs; D-prs
(C) A-prt; B-pqst; C-qr; D-prs (D) A-prs; B-prst; C-qs; D-pr
Ans: A

XeF4  H 2O 
 XeO3 (s)  HF (aq)  O2 (g)  Xe(g)
 PH 3  g   H 2 PO2  aq 
P4  OH  
 B  OH 3  H 2
B2 H 6  H 2O 

Br2  K 2CO3   KBr  KBrO3

16. Match the following column of precipitate/mass listed in Column I with the reagent (s) listed in
Column II:
Column – I (Observations) Column – II (Reagents)
(A) Mg2+ gives pale pink mass with (p) NaOH solution
(B) Pb2+ gives yellow ppt. with (q) H2 S gas
(C) Ag+ gives black/brown ppt. with (r) K2CrO4 solution
(D) Hg22  gives black ppt. with (s) KI (not in excess) or KI in excess
(t) Cobalt nitrate in charcoal cavity test
Which of the following combination is correct?
(A) A-t; B-rs; C-pq; D-pqs (B) A-t; B-rs; C-qs; D-pqs
(C) A-q; B-rs; C-pq; D-pqt (D) A-t; B-rs; C-pq; D-pqt
Ans: A

Hg 22 
NaOH
 Hg 2O  black 
Hg 22 
H2S
 Hg  HgS  black 

Hg 22 
 Hg  black   K 2 HgI 4  soluble 
KI excess
 17. Match the reaction product(s) in List- I with corresponding test which they give positively in List -II
and choose the correct combination from the codes given below:
List-I List-II
( P) O (1) Carbylamine test

i MCPBA

 ii  dil. H SO

2 4

(where MCPBA is m-chloroperoxy

benzoic acid)
(Q) O (2) NaHCO 3 test

H
dil. OH


 

O

(R) O (3) Product with Hinsberg’s reagent is insoluble in

aq. KOH solution
+  i CH3 Cl
NK  
 ii Dil. H

(S) Na/C H OH (4) Bromine water test

CH3 NC 
2 5


(5) Gives ceric ammonium nitrate test

(6) Gives a yellow liquid with CS2 which do not
give a black colour with HgCl2.
(A) P-2,5; Q-4; R-1,2; S-3,5 (B) P-2,5; Q-4; R-1,2; S-3,6
(C) P-2; Q-4,5; R-1; S-3,6 (D) P-2; Q-4; R-1,2; S-2,6

Ans: B

18. Match the following:

List – I List – II
(P) Addition of HCl can make the buffer solution (1) CH3COONa
Addition of NaOH can make the buffer
(Q) (2) NH3
solution
Increase solubility when added to a saturated
(R) (3) NH4Cl
solution of CuCO 3
Form buffer on mixing with solution of
(S) (4) NaHCO3
appropriate conjugate acid base
(5) HCOONa

Which of the following combination is correct?

(A) P-1,2,3,4,5; Q-3,4; R-2; S-1,2,3,4,5 (B) P-1,2,5;Q-3;R-3;S-1,2,3,4,5
(C) P-1,2,4,5; Q-3,4; R-4; S-1,2,3,4,5 (D) P-1,2,4,5; Q-3,4; R-2; S-1,2,3,4,5
Ans: D