SECTION – I

(MULTIPLE CORRECT ANSWER TYPE)

This section contains 7 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONE OR MORE than ONE option can be correct.

1 . A photon of wavelength is 4  107 m strikes on a metal surface, the work function of the metal being
3.4  1019 J . Select the correct statements.
A) The energy of photon is 4.97  1019 J
B) The kinetic energy of the emission is 1.57  1019 J
C) The kinetic energy of the emission is 0.98ev
D) The velocity of photo electron is 5.87  105 ms 1

2 . Which of the following is/are correct?

(A) carbon-carbon bond length in CaC2 will be more than in CH 2  C  CH 2

(B) O  O bond length in KO2 will be more than in Na2O2

(C) O  O bond length in O2[PtF6] will be less than that in KO2
(D) N  O bond length in NO gaseous molecule will be smaller than in NOCl gaseous molecule
3 . Which of the following is/are correct about dicarboxylic acid
COOH

 CH 2 n
COOH where n = 0, 1, 2, 3, ..

(A) pKa1 for all the dicarboxylic acids is smaller than the pKa for monocarboxylic acids with the same

number of carbon atoms

(B) The difference between pKa1 and pKa2 for dicarboxylic acids decreases as ‘n’ increases
(C) pKa1 for all the dicarboxylic acids is higher than the pKa2
(D) Ka1 for all dicarboxylic acid is higher than the Ka2.

4 . Which of the following is/are correct ?

(a) B(OH) 3 partially reacts with water to form H 3 O + and [ B(OH) 4 ] – , and behaves like a weak

acid
(b) B(OH) 3 behaves lika a strong monobasic acid in the presence of sugars, and this acid can be

titrated against an NaOH solution using phenolphthalein as an indicator

(c) The hydration of alkenes by hydroboration and oxidation

leads to the cis hydration of the carbon-carbon double bond with apparent anti-Markovnikov addition to
give alcohols.
(d) B(OH) 3 reacts with NaOH , forming Na [ B(OH) 4 ]
5 . Borax is converted into boron by steps
I
Borax   H 3 BO3  II
B2 O3 Boron

III

Colored compound

I , II & III are

a) acid, Na, Fe 3 (b) acid , carbon, Zn 2

(c) acid , Fe, Al 3 (d) acid , Mg , Cu 2
6 . Which of the following statement/s is/are correct?
A) A sub-atomic particle has K.E of 6.626 1024 kg m2 s 2 . Then, its de Broglie frequency is 2 1010 Hz .
B) The minimum pH when B  OH  starts precipitating from a solution containing 0.1M
3

BCl3  KspB  OH 3  8  1011  is 10.3

C) The number of radial nodes of valence shell orbital of potassium  Z  19  are 3.
D) A sample of 1M solution of  S   2  bu tanol in a sample container of 10 cm length has an observed
rotation + 1.030. Then the specific rotation of S-2-butanol is 13.90.
SECTION-II
(INTEGER ANSWER TYPE)
This section contains 5 questions. The answer is a single digit integer ranging from 0 to 9 (both inclusive).

7 . A current of dry air was bubbled successively through a bulb containing 25 gm of a weak mono basic
acid (non-volatile) in 180 gm of water, pure water and a U-tube containing anhydrous CaCl2. The loss in
80
weight of water was 0.1 gm and gain in weight of U-tube was 1.1 gm. If 1 gm of acid required ml of
3
1 N alkali for complete neutralization, then the value of (  4) is? (where  = degree of dissociation
of acid)
8 . The number of isomeric compounds having a benzene ring and molecular formula C7H9N are …
9 . The no.of intermediates involved in the following conversion is

SECTION – III
(SINGLE CORRECT ANSWER TYPE)
This section contains 6 multiple choice questions. Each question has 4 options (A), (B), (C) and (D) for its answer,
out of which ONLY ONE option can be correct.

Column A Column B Column C – n factor of either

1. 20.8 gms of lead 208
2. 9.2 gms of Sodium
3. 10.8 gms of Ag - 108
4. 6.3 gms of Cu - 63
the OA or the RA or their
products
A) 0.4 moles of HNO3 (conc) P n=2
B) 0.4 moles of HCl Q n= 1
C) 0.2 moles of HNO3 (conc) R n = 0.5
D)0.1 moles of HNO3 (conc) S n=0
Column A is to be completely consumed by Column B in a reaction.
Column C gives the n factor of either the OA/its product or the RA/its product in the reaction between column
A and B.
10. Which of the following combinations is correct?
(a) 1 = C = P (b) 1 = A = R (c) 2 = D = Q (d) 2 = A = R
11. Which of the following combinations is correct?
(a) 1 = A = Q (b) 2 = A = P (c) 3 = C = P (d) 4 = D = P
12. Which of the following is incorrect?
(a) 3 = C = Q (b) 3 = A = Q (c) 4 = C = P (d)4 = A = R

Column – A - Reactant Column B - Reagent Column C – Product

1) Cis – 2 Pentene A) Conc KMnO4 and heat
B) dry Ag2O and heating followed
2) Trans – 2 Pentene by acidic medium hydrolysis
3) Trans 2 – Butene C) Bayer’s Reagent
4) Iso butene D) Cl2 in CS2
P) Racemic mixture
Q) Meso Structure or optically
inactive compound
R) ANTI ADDN product
S) CO2 Gas evolves or Single
Carboxylic acid as product

13. Which of the following combinations is correct?

(a) 1 = C = R (b) 2 = B = QR (c) 3 = D = Q (d) 4 = A = P
14. Which of the following combinations is correct?
(a) 1 = A = S (b) 2 = A = P (c) 3 = A = QS (d) 4 = D = P
15. Which of the following is incorrect?
(a) 2 = D = PR (b) 1 = A = Q (c) 3 = C = P (d)4 = A = R

Answer Key

1 ABCD 2 CD 3 ABD 4 ABCD

5 AD 6 ACD 7 2 8 5

9 3 10 B 11 B 12 C

13 C 14 C 15 D