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DDT AND DETONATION

PREDICTIONS WITH CFD - TIME TO


BE CONSIDERED IN EXPLOSION
RISK ASSESSMENTS?

Olav Roald Hansen


Llyod’s Register Consulting

E: olav.hansen@lr.org
T: +47 91 17 17 87

Technical meeting proceedings - JUNE 2014 www.fabig.com 101


DDT and Detonation Predictions with CFD
- Time to be Considered in Explosion Risk Assessments?

FABIG technical meeting, Aberdeen & London June 25-26, 2014


Olav Roald Hansen Lloyd’s Register Consulting, Bergen, Norway

Working together
for a safer world

FLACS validation and new application areas - Focus for 20 years:


Good results for explosion and dispersion- hydrocarbons, hydrogen, LNG, dust, explosives etc.
Sometimes hard to understand reasons for deviation

FLACS validation against full scale tests1997-98, HSE Phase 3A test 4, 19 and 22
©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 102


HSE Phase 3A Test 4 - blast pressures severely underpredicted
3.7 barg

17 barg

2.0 barg

TEST

Pressure at end of test rig Pressure 12m, 24m and 48m outside

FLACS

1.0 barg
0.6 barg
2.4 barg

©Lloyd’s Register Consulting

Deflagrations

Strong deflagrations require turbulence


(obstructions– e.g. pipes/equipment or trees)
1 to 10+ barg pressure & ~1000 m/s flame speed
Flames slow down outside congestion

DNV GL video from 1980s


Most (near all) explosion studies consider deflagrations to be worst-case
(sometimes only 5-10% of energy contributes)
Deflagration -
only congested
units contribute Unit 1 Unit 2

Blast energy
Unit 3 Unit 4

Safe design not stimulated


Gas cloud
=> Focus on sufficient distance to congestion
©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 103


Deflagration

DNV GL video

©Lloyd’s Register Consulting

Detonation

Detonations propagate by ignition of unburnt gas ahead of flame due to shock waves
16-20 barg pressure & 1600-2000 m/s (detonation limits similar to flammability limits - LFL:UFL)
From OECD hydrogen safety report and other sources

~1 cm ~3 cm ~ 5-10 cm ~ 30 cm

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 104


Fast deflagrations may transit to detonations (DDT)

Detonations propagate by shockwave interaction


16-20 barg pressure & 1600-2000 m/s
Both within congestion and gas cloud outside

DDT is deflagration-to-detonation-transition DNV GL video from1980s

At
Flame speed > 600 m/s DDT BLASTENERGY Unit 1 Unit 2

Pressure > 2 barg Unit 5

and sufficient scale Unit 3 Unit 4

DDT has been observed in experiments Gas Cloud

ALL energy in flammable cloud may contribute to blast waves


©Lloyd’s Register Consulting

Detonation

DNV GL video

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 105


DDT observed in several recent major accidents

Buncefield 2005 (DDT)


Jaipur
Puerto Rico 2009 (likely DDT)
Jaipur 2009 (DDT)
Sunrise Toronto 2008 (concluded DDT)

Buncefield
There are likely more …

Sunrise

Puerto Rico???

©Lloyd’s Register Consulting

DDT also observed in several large scale experiments

 45m BG test (cyclohexane)


 BEX tests (ethylene/propane)
 MERGE tests (propane, ethylene)
 HSE Phase 3A full-scale rig (natural gas)
 Buncefield explosions in trees (propane) 28m x 12m x 8m rig HSE Phase 3A
 Various hydrogen tests (FLAME facility, KOPER tests, pipe-tests, BakerRisk, Fh-ICT)
 BakerRisk congestion rig tests (ethylene)
 Shell tests congestion block (e.g. ethane)
 NIOSH 73m 1.05m diameter pipe tests (natural gas)

Car and drum placed inside detonation test


GL Spadeadam April 2013
©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 106


DDT predictions using FLACS (Middha & Hansen) 2006=>

DDT predicted using normalised spatial pressure gradient DPDX (-)


[Simple explanation: Max pressure change (bar) per grid cell inside flame front]

Max DPDX < 0.5 DDT unlikely


0.5 < Max DPDX < 5 DDT possible  criterion to be fulfilled,
5 < Max DPDX DDT likely DPDX-region > 7-10 across

Validated against numerous tests:


 Hydrogen tests (FLAME, KOPER, BakerRisk, Fh-ICT, …) Buncefield tre simulering DPDX

 Ethylene tests (MERGE & BakerRisk)


 Propane tests (Buncefield trees)
 Natural gas (fullscale rig, 73m pipe)

From Hansen & Johnson (2013)

2012: Method to simulate DDT and detonation with FLACS (Hansen & Johnson 2013)
©Lloyd’s Register Consulting

Simulated Buncefield Test 2 (DDT and detonation) in 2012

Proper analysis of trees


used to develop “dummy trees”

Handout from Mike Johnson’s presentation at FABIG March 2014

mm % vol/m m/m3 m2/m3 m/m3 adj m2/m3 adj Diameter model m/m3 m2/m3 Pr 3 x 3 x 4m
170 0,00 0,023 0,00 0,00 0,00 0,00
120 0,41 0,011 0,36 0,14 0,12 0,05 100 1 0,314 V 36
85 1,04 0,006 1,83 0,49 0,61 0,16
60 0,40 0,003 1,42 0,27 0,47 0,09 50 2 0,314 H 72
42 0,21 0,001 1,52 0,20 0,51 0,07
30 0,24 0,001 3,40 0,32 1,13 0,11 25 4 0,314 H+V 144
22 0,18 0,000 4,74 0,33 1,58 0,11
18 0,19 0,000 7,47 0,42 2,49 0,14 10 20 0,628 H+V 720
12 0,23 0,000 20,35 0,77 6,78 0,26
8 0,23 0,000 45,78 1,15 15,26 0,38 5 52 0,816 1872
3 0,23 0,000 325,55 3,07 108,52 1,02
7,15 2,382 Original estimate 2,386
3 x high 3 x high 2,65 Final estimate

©Lloyd’s Register Consulting Method used November 2012 to develop tree-model used by Hansen & Johnson (2013)

Technical meeting proceedings - JUNE 2014 www.fabig.com 107


Simulation of Buncefield Test 2 with trees

FLACS simulation predicted likely DDT, can we also predict consequences?


Tweaking parameters in FLACS => detonation can be simulated

Test 2 – standard FLACS simulation (video)


Test 2 – simulated with DDT and detonation settings (video)

Video frames
From Hansen & Johnson (2013) Mike Johnson FABIG presentation March 2014
©Lloyd’s Register Consulting

Good results predicting DDT and detonations

Test 2 detonation modelling: Realistic pressures and flame speeds

From Hansen & Johnson (2013) [updated to include experimental results]


©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 108


Good results predicting DDT and detonations

Test 2 detonation modelling: Observed and simulated pressures

Sensor 1-3 Sensor 4-6 Sensor 7-9

©Lloyd’s Register Consulting

HSE Phase 3A Test 4 – ”perfect results” assuming DDT

From Hansen & Johnson (2013)

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 109


LRC has made automatic DDT & detonation prediction functionality

Scripts are developed which will


 Evaluate potential for DDT in running simulation
 Define exact time and location for DDT
 If DDT, start detonation simulation in parallel
=> Efficient evaluation of DDT risk (including consequences)

©Lloyd’s Register Consulting

Automatic scripts for Safety Gap Issue + Blast Smearing also developed

FLACS will give too high pressures


after safety gap, work-around exists

Standard FLACS Improved

FLACS will smear and underpredict far-field


Improved
blast from strong explosions, work-around exist
Standard
FLACS

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 110


Summary Differences Deflagration & Detonation Flames

Parameter Deflagration: Detonation:


Flame propagation: by turbulence/congestion by shock-waves
Flame speeds: 1 m/s – 1000 m/s 1600-2000 m/s
Pressures 0.001 to ~10 barg 16-20 barg
Blast waves Often directional Strong in all directions
Strong explosion expected Inside congestion & near stoichiometry Anywhere flammable
Natural gas 8-11% Natural gas 5-15%

Deflagration

Visual look
Detonation

GL Buncefield tree test video captures (Source New Scientist Website)

©Lloyd’s Register Consulting

Implication of DDT: Onshore & offshore (FPSO/FLNG and platforms)

For onshore facilities it may be a “game changer” to consider DDT in design


 Must optimize design for individual units to prevent DDT
Must ensure deflagrations
do not undergo DDT Unit 1 Unit 2
Blast energy
Unit 3 Unit 4
Gas cloud
For FPSO and FLNG risk for DDT should be considered (more slides follow)
 Optimize design to minimize DDT potential
 Avoid gas clouds detonating at critical locations (e.g. at hull deck)
 Extreme loads may be seen locally, still it is feasible to design for far field loads onto LQ

Offshore platforms
Illustration
 Already optimized using CFD (?) Not caused by DDT
 Higher loads expected with DDT
 However, already in “trouble” at DDT
Could make automatic deluge more attractive! DDT can represent a significant potential for complete loss
©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 111


FPSO study: Geometry model and study approach
From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Process areas below yellow decks

Study approach:
1 Ventilation & dispersion study
=> frequency for ignitied clouds estimated

2 Clouds are exploded (deflagration) evaluating DDT crieria


=> Likely DDT scenarios will be re-simulated assuming DDT

3 Risk reduction measures evaluated


=> Study repeated with 3 separation walls through process areas
©Lloyd’s Register Consulting

FPSO study: Dispersion Study (84 CFD calculations)


From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Simplified Probabilistic Approach


• Three (3) release locations/directions (R1, R2 and R3 in Figure)
• Two (2) gas compositions: Propane and NG (85% methane, 10% C2 and 5% C3)
• Seven (7) release rates (3, 6, 12, 24, 48, 96 and 192 kg/s)
• One (1) wind direction (-10 degrees)
• Two (2) wind speeds 3 m/s and 9 m/s
• 60s to ESD + 60s to stop release

Wind direction and 3 release locations indicated

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 112


FPSO study: 84 CFD dispersion calculations
From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Leak frequencies:
• Typical distribution
• Somewhat low (0.5/year)

Ignition model:
• Time dependent OGP (UKOOA)
• 55% of ignition frequency from 10s to 150s
• Not sensitive to gas cloud size, only initial release rate

Likely conservatism in leak location/direction + ignition model (compared to NORSOK OLF)

©Lloyd’s Register Consulting

FPSO study: Results from dispersion calculations


From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Cloud development
• Natural gas rises, propane/condensate fall when losing momentum
• Comparable maximum cloud sizes, longer duration for propane
• Significant clouds at hull deck for large propane releases

Natural gas
96 kg/s

Propane 96 kg/s

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 113


FPSO study: Resultats from dispersion simulations
From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Q9-cloud is used as hazard indicator


(Q9 is an ESC= equivalent stoichiometric cloud)

Observations:
• 2-3 times larger Q9 cloud during low winds
• Flammable cloud (LFL:UFL) ~ twice the size of Q9
• NG & propane have similar maximum cloud sizes
• 10-4/year ignited cloud comparable for NG & propane
 NG release frequency 50% higher
 Longer exposure for propane clouds

10-4/year clouds twice the size as normal for FPSOs

Main reasons:
 Conservative choice of free horizontal jet into domain
 Choice of transient ignition model (normally OLF used)
©Lloyd’s Register Consulting

FPSO study: Explosion calculations


From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

~45 FLACS explosion calculations performed Cloud size Base case Base case
Q9 (m3) NG Propane
• 13-15 different cloud sizes, 1-3 ignition positions 400
• propane and natural gas 700
• conservative ignition location 1000
1400
• some simulations repeated as DDT 2000
Too few scenarios for quantitative DDT evaluation 3000
4500 Near DDT
6000
Observations: 8000 Near DDT
10000 DDT DDT
• DDT seems likely for all propane clouds Q9 > 10,000m3
12000 DDT
• DDT seems likely or near for some natural gas clouds 14000 DDT
17000 DDT
20000 N/A DDT
24000 N/A DDT
The figure shows identified DDT potential.
Too few simulations for quantitative evaluation
and to conclude there is no DDT in green cells.

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 114


FPSO study: Explosion study, worst-case example
From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Ignited cloud at process deck Pressure at hull deck

Cloud at hull deck Maximum pressure at hull deck

DDT indication at process deck


Maximum pressure at process deck

©Lloyd’s Register Consulting

FPSO study: Explosion study, example worst-case


From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Maximum pressure distribution


Deflagration only DDT and detonation

Hull deck LQ LQ

Process deck
LQ LQ

Detonation more energetic, sending energy in all directions


Predicted pressure at LQ comparable (or higher) for deflagration
©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 115


FPSO study: Risk reduction with separation walls
From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Aim to reduce cloud sizes and explosion pressures


OK for ventilation:
• 45% reduction in typical flow velocities
• 20% reduction in air changes / hour
Good for dispersion:
• Clouds > 10,000m3 strongly reduced
• Minor changes for smaller clouds
Worse with explosions
• Much higher loads for same cloud sizes
• Increased DDT potential
Base case Walls

Deflagration pressures significantly higher with separation walls


©Lloyd’s Register Consulting

FPSO study: Conclusion separation walls


From GCPS 2014 paper by O. R. Hansen, R. Martini, Y. Ryu and J. Choi
Lloyd’s Register Consulting & Samsung Heavy Industries

Separation walls
• Reduce cloud sizes
• Give stronger explosions
• DDT predicted for smaller clouds
• Helps ensuring safe distance to LQ
=> Not convincing for risk reduction

Identified DDT potential, too few simulations for quantitative


PS: evaluation, DDT in green cells can not be ruled out.

More extensive study to be performed before concluding


Soft barriers may be better alternative.

©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 116


Supertankers disappeared in moments Berge Istra 228,000 tons
315m long 50m wide

“Unsinkable”, double hull designs Iron ore & oil combination carrier

Berge Vanga + 2 more sister ships

29 Dec 1975: Berge Istra disappears near the Philippines


20 days later 2 crew members found on a raft
Hearing strictly confidential (insurance/claims?)

29 Oct 1979: Sister Berge Vanga disappears in Atlantic


70 officers and crew missing from 2 ships
Company stops combination cargo business

Berge Istra sank due to strong explosions inside tanks


Was this due to
* Oil spills in double hull + welding, or
* Unreliable flue gas inerting of empty tanks?

Not important => big ships can sink in moments!


©Lloyd’s Register Consulting

Conclusion:
Must prevent this from happening on FPSOs/FLNGs

Strong explosions may lead to DDT


 Simplified FPSO study: DDT to be feared every 10-4 – 10-5/year

Detonations will give massive damage locally

Even with frequency lower than10-4/year we should:


 Ensure hull integrity to avoid sinking of ship
 Ensure that LQ can survive far field blast loads

Measures:
 Limit significant gas cloud build-up at hull deck
 Deluge activation at gas detection may limit DDT risk

DDT scenarioes should be considered when evaluating design

Tanker Shoku Maru explodes and sinks


A potential DDT offshore would not be “a black swan” May 29, 2014
©Lloyd’s Register Consulting

Technical meeting proceedings - JUNE 2014 www.fabig.com 117


… Questions or comments?

Olav Roald Hansen


Senior Principal Consultant
Bergen Norway
T +47 91 17 17 87 E olav.hansen@lr.org

Lloyd’s Register Consulting


www.lr.org/consulting

Working together
for a safer world

Lloyd’s Register and variants of it are trading names of Lloyd’s Register Group Limited, its subsidiaries and affiliates.
Copyright © Lloyd’s Register Consulting. 2013. A member of the Lloyd’s Register group.

Technical meeting proceedings - JUNE 2014 www.fabig.com 118


Questions and answers

Q: For a FPSO, you advised to design so as to prevent DDT; do you have any
suggestions on how this can be done?

A: The only way I know to prevent DDT is to be very efficient at activating the deluge
system upon gas detection. Another solution is to prevent the gas from filling large
volumes at the hull deck. A DDT high up on the process deck would be significantly
less problematic than one occurring on the hull deck. You should therefore make
sure that gas is prevented from going down to the hull deck. If a gas cloud
detonates, it should be as far as possible from the hull deck as extreme loads are
inside the detonating cloud.

Q: Accidental DDTs are very rare and only seem to occur in large clouds in calm
condition. I have never come across DDTs on offshore structures; can you comment
on this?

A: Perhaps not, but does anyone want to be the first to experience a DDT offshore? After
the Buncefield accident which was the first of its kind, many similar events occurred.
We have seen experimentally that a stoichiometric natural gas can detonate in
modules of 28x12x8m; similar conditions can be achieved for a major gas release in
an offshore structure, so I think that a DDT offshore is a possibility.

Q: I understand that in many cases DDT occurs when the pressure rises ahead of the
flame, for instance when a reflected blast wave hits the flame front. As such, do you
think the DPDX parameter is reliable for predicting DDTs as it looks at the difference
between the pressure at the flame front and ahead of it?

A: We have simulated a lot of cases and the DPDX parameter seems quite reliable. What
you mentioned regarding ignition due to reflection seems to be more related to
laboratory experiments within a channel with pressure waves hitting a corner and
detonating there. In the case of large scale experiments, the occurrence of DDT is
mainly linked to what happens at the flame front.

Technical meeting proceedings - JUNE 2014 www.fabig.com 119


Questions and answers

Q: Are you saying that if the difference between the pressure at the flame front and
ahead of it is more than one bar (for instance), then it is very likely that a DDT
will occur?

A: Not exactly. The parameter that we have developed looks at the next grid cell and a
very high flame speed is required to obtain large pressure differences within one grid
cell. More than two bar in the flame front and no pressure ahead seems to have led
to DDT in some experiments, both from the Spadeadam test site and from Hydrogen
experiments from the literature.

Q: Are you simulating everything with the same solver, or do you use one for
deflagration and another one for detonation?

A: It is the same solver, but we do a dump the results, tweak the parameters and
restart the simulation.

Q: Have you looked at DDTs in hydrogen gas clouds?

A: Yes, a lot. We actually started by considering hydrogen and then considered


other fuels.

Q: What is the effect of reduced congestion on DDT?

A: Reducing congestion will prevent DDTs as it will take longer to reach a DDT in
reduced congestion.

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