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Determinationofcellconstant 191023045558
Determinationofcellconstant 191023045558
Theory: Conductivity (mho or ohm -1) of any solution depends on the nature of ions present in it.
The specific conductance is measure of conductance of solution with electrodes of unit area that
are place 1 cm apart. The specific conductance (K) is given by
K = C (l/a)
Cell constant = Specific conductance (ohm -1cm -1) / measured conductance (ohm -1)
Thus, the unit of cell constant is cm -1.
Procedure:
i) Calibrate the conductivity cell
Refer the instrument manual.
Observations:
Room temperature =____ ◦C.
Conductance of distilled water ‘A’=______ ohm -1.
Table 1
Concentration of Specific Measured Observed Cell constant
KCl conductance conductance conductance (cm -1)
(mohm -1 cm -1) (ohm -1) (ohm -1)
‘B’ =B-A
0.1 12.88
0.01 1.413
Result: Cell constant =______ cm -1.
Further Reading
Experiments in Applied Chemistry, S. Rattan, S. K Kataria and Sons.