Saraswati Vidhya Mandir, Gandhinagar

Chapters : 1,2 Std 12 : Chemistry Date : 11/02/24

Total Marks : 48 Unit Test Time : 03 Hour
Section A
//X
• Write the answer of the following questions. [Each carries 2 Marks] [10]
1. Draw structures of geometrical isomers of [Fe(NH3)2(CN)4]–.
2. Write any four limitations of valence bond theory of complex compound.
3. Draw the isomers of [Co(NH3)3(NO2)3] complex.
4. Explain the nature of bonding in metal carbonyls.
5. Draw the geometrical isomers of [CoCl2(en)2].

Section B
//X
• Write the answer of the following questions. [Each carries 3 Marks] [6]
6. Give postulates of Werner's theory.
7. Discuss the nature of bonding in K4[Fe(CN)6] on the basis of valence bond theory.

Section C
//X
• Write the answer of the following questions. [Each carries 4 Marks] [32]

8. [Ni(CN)4]2– is square planar while [NiCl4]2– is tetrahedral. Explain.

9. (i) Explain that complex [Ti(H2O)6]3+ is voilet in colour, on the basis of crystal field theory.
(ii) Discuss the nature of bonding in metal carbonyls.
10. Explain hybridization, geometrical shape and magnetic property in [Ni(NH3)2Cl2] and also draw
isomers.
11. On the basis of valence bond theory state electronic configuration, hybridization. Magnetic property
with calculation of magnetic dipole value and state type of spin present in [Fe(CN)6]–3 complex.
12. (a) Draw optical and geometrical isomers of [CoCl2(en)2]+.
(b) Give evidence that [Co(NH3)5Cl]SO4 and [Co(NH3)5(SO)4]Cl are ionisation isomers.
13. Write down the IUPAC name of the following complexes and calculate their magnetic moment.
(i) K3[Co(C2O4)3] (ii) Cs[FeCl4]

14. Explain on the basis of valence bond theory that [Fe(H2O)6]3+ is paramagnetic where as [Fe(CN)6]4–
is diamagnetic.

15. Explain on the basis of valence bond theory that [Ni(CN)4]2– ion with square planar structure is
diamagnetic and the [NiCl4]2– ion with tetrahedral geometry is paramagnetic.

Wish You - All The Best

 Saraswati Vidhya Mandir, Gandhinagar
Chapters : 1,2 Std 12 : Chemistry Date : 11/02/24
Total Marks : 48 Unit Test Time : 03 Hour
Section A
//X
• Write the answer of the following questions. [Each carries 2 Marks] [10]
1.

2.

3.

4.

5.

Section B
//X
• Write the answer of the following questions. [Each carries 3 Marks] [6]
6.

7.

Section C
//X
• Write the answer of the following questions. [Each carries 4 Marks] [32]

8.

9.

10.

11.

12.

Welcome To Future - Quantum Paper

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14.

15.

Welcome To Future - Quantum Paper