Chemistry PW Last 5 Years Pyq Complete Class 11

Some Basic Concepts
of Chemistry
compound 2 is PQ), then the

(c) If empirical formula of
empirical formula of the compound 1 is P.Q,.
Uncertainty in Measurement and 70 and 35, respectively,
(d) Ifatomic weight of P and Q are compound 1 is P,Q.
Laws of Chemical Combinations then the empirical formula of
1. Which of the following have same number

of significant Atomic & Molecular Masses
|8 April, 2023 (Shift-II)]
figures?
(B) 1.0003 chlorine is 35.5 g mol'. The
(A) 0.00253 6. The average molar mass of close
(C) 15.0 (D) 163 35Clto "Clin naturally occurring chlorine is
ratio of
Choose the correct answer from the options given below to: (6 Sept, 2020 (Shift-ID]
(a) A, B and C only (b) Cand Donly (a) 4: 1 (b) 3: 1
(c) A, Cand D only (d) B and C only (c) 2: 1 (a) 1:1
2. Using the rules for significant figures, the correct answer
for the expression
0.02858x 0.112 Mole Concept and Molar Masses
0.5702
|29 June, 2022 (Shift-II)] litres of O,
7. The number of molecules and moles in 2.8375
(a) 0.005613 (b) 0.00561
at STP are respectively |10 April, 2023 (Shift-I)]
(c) 0.0056 (d) 0.006
(a) 7.527 x 1022 and 0.250 mol
3. The number of significant figure in 0.00340 is (b) 1.505 x 1025 and 0.250 mol
[25 July, 2021(Shift-I)] (c) 7.527 x 1023 and 0. 125 mol
4. The number of significant figures in 50000.020 x 103 (d) 7.527 x 1022 and 0.125 mol
is |26 Feb, 2021 (Shift-I)]
5. Tocheck the principle of multiple proportions, a series of 8. Match List-I with List-II. [10 April, 2023 (Shift-II)]|
pure binary compounds (PQ) were analyzed and their List - I List - II
composition is tabulated below. The correct option(s)
is(are) [JEE Adv 2022] (A) 16g of CH,(g) (1) Weighs 28 g
Weight % of Q (B) lg of H,(g) (I) 60.2 x 102 electrons
Compound Weight % of P
1 50 50 (C) Imole of N,(g) (III) Weighs 32g
2 44.4 55.6 (D) 0.5 mol of SO,(g) (IV) Occupies 11.4 L volume
at STP
3 40 60
Choose the correct answer from the options given below:
(a) If empirical formula of compound 3 is P,Q,. then the (a) (A)-(I), B-(I), C-(l1), D-(IV)
empirical formula of compound 2 is PQ, (b) (A)-(I), B-(1I), C-(IV), D-(I)
(b) If empirical formula of compound 3 is P,Q, and (c) (A)-(I), B-(IV), C-(|1), D-(1)
atomic weight of clement P is 20, then the atomic
weight ofQ is 45. (d) (A)-(II), B-(IV),C-(), D-(|I)
17. 56.0 Lof nitrogen gas is mixed with excess of
9. When 0.01 mol of an organic compound containing 60%
carbon was bumt completely, 4.4 gof CO, was produced. gas and it is found that 20 L of ammonia ihydrogen
gas is produced
The volume of unused nitrogen gas is found to be
The molar mass of compound is g mol
(Nearest integer) |29 Jan, 2023 (Shift-I)) |25 July, 2022 (Shift-ly
10. Production of iron in blast furnace follows the following
18. Chlorophyll extracted from the crushed green
equation Fe,0,(s) +4COg)’ 3Fe() +4C0,(g) was dissolved in water to make 2 L solution of leMgavesof
When 4.640 kg of Fe,0, and 2.520 kg of CO are allowed concentration48 ppm. The number of atoms of Mg in thi
to react then the amount of iron (in g) produced is: solution is x x 1020 atoms. The value of x is
[Given: Molar Atomic mass (g mol '); Fe= 56 (Nearest Integer)
Molar Atomic mass (g mol):0= 16
(Given: Atomicmass of Mg is 24 g mol'; N, = 6.02 ,
Molar Atomic mass (g mol'); C= 12] 102 mol-') |26 July, 2022 (Shift-)I
|29 June, 2022 (Shift-)]
19. 1Laqueous solution of H,S0, contains 0.02 mmol
(a) 1400 (b) 2200 H,SO,
s0% of this solution is diluted with deionized water to give
(c) 3360 (d) 4200 ILsolution (A). In solution (A), 0.01l mmol of H,So
11. SO,Cl, on reaction with exceSs of water results into acidic are added. Total mmols of H,SO,in the final solution is
mixture x 10° m moles. |25 June, 2022 (Shift-I))
SO,C1, +2H,0 ’ H,SO, +2HCI 20. Two elements Aand B forms 0.15 moles of A,B and AR
l6 moles of NaOH is required for the complete neutralisation type compounds. If both A,B and AB, weigh equally, then
of the resultant acidic mixture. The number of moles of the atomic weight of A is times of atomic weight
SO,C1, used is: (25 July, 2022 (Shift-I)) of B. [27 June, 2022 (Shift-))
(a) 16 (b) 8 21. Number of grams of bromine that willcompletely react
(c) 4 (d) 2 with 5.0 g of pent-1-ene is x 10 g.
12. Hemoglobin contains 0.34% of iron by mass. The number (Atomic imass of Br = 80 g/mol) (Nearest Integer)
of Fe atoms in 3.3 g of hemoglobin is (Given: Atomic |25 June, 2022 (Shift-)]
mass of Fe is 56 u, N, =6.022 x 10 mol-'.)
22. The moles of methane required to produce 81 g of water
[26 July, 2022 (Shift-ID) after complete combustion is x10 mol. (nearest
(a) 1.21 x 10 (b) 12,0 x1016 integer) (26 June, 2022 (Shift-ID)
(c) 1.21 x 1020 (d) 3.4 x 1022 23. In the following reaction
13. 250 g solution of D-glucose in water contains 10.8% of
carbon by weight. The molality of the solution is nearest to SO,H OH
(Given : Atomic weights are, H,lu; C,12u;0, 16u)

Oleum NaOH (excess)
(27 July, 2022 (Shift-)) H
(a) 1.03 (b) 2.06
(c) 3.09 (d) 5.40
14. The number of Natoms in 681 gof C,H,N,0, is xx10. The % yield for reaction I is 60% and that of reaction
The value of x is II is 50%. The overall yield of the complete reaction
(N, = 6.02 x 10 mol-)(Nearest Integer) % [ Nearest integer]
|27 July, 2022 (Shift-I)
|25 June, 2022 (Shift-))
24. In the below reaction, 5g of toluene is converted into
15. A protein A' contains 0.30% of glycine ( molecular benzaldehyde with 929% yield. The amount of benzaldehyde
weight 75). The minimum molar mass of the protein 'A'
produced is x10 g.(Nearest integer)
x10°g mol[nearest integer]
(27 July,2022 (Shift-I))
(25 June, 2022 (Shift-II))
16. CNG is an important transportation fuel. When 100 g ÇH, CHO
CNG is mixed with 208 g oxygen in vehicles, it leads to
the formation of CO, and H,0 and produces large quantity
of heat during this combustion, then the amount of carbon
dioxide produced in grams is (nearest integer)
[Assume CNG to be methane] |26 June, 2022 (Shift-IDI 5g (92%)
2 JEE PYQS Chemistry

25. Areaction of 0,1 moleof Benzylamine with bromomethane 36. Aluminium reacts with sulfuric acid to form aluminium
gave 23g of Benzyl trimethyl ammonium bromide. The sulfate and hydrogen. What the volume of hydrogen
number of moles of bromomethane consumed in this
gas in liters (L) produced at 300K and 1.0 atm pressure,
reaction are n x 10, when n = (Round off to when 5.4gof aluminium and 50.0 mL of 5,0 Msulfuric
the nearest integer) (Given: Atomic masses: C: 12.0 u,
acid are combined for the reaction?
H:1.0u, N:14.0u, Br: 80.0u]| |18 March, 2021 (Shift-D))
(Use molar mass of aluminium as 27.0 g mol,R=0.082
26. 4g equimolar mixture of NaOH and Na,C0, contains x g
atm L mol K ) |JEE Adv 2020|
ofNaOH and yg of Na,C0,, The value of xis
37. The mole fraction of urea in an aqueous urea solution
(Nearest Integer) |20 July, 2021 (Shift-ID))
27. Consider the complete combustion of butane, the amount containing 900 g of water is 0.05. If the density of the
of butane utilized to produce 72.0 g of water is solution is I.2gcm,themolarity of urea solution is
x 10 g. (innearest integer) |JEE Adv 2019|
|25 July, 2021 (Shift-1)]
28. The number of atoms in 8 g of sodium is x x 1023, The (Given data: Molar masses of urea and water are 60gmol
value of x is
(Nearest integer) and 18 g mol, respectively)
[Given: N, =6.02 × 10 mol', Atomic mass of Na =23.0 u]
|1Sept, 2021 (Shift-)) Percentage Composition and
29. The NaNO, weighed out to make 50 mL of an aqueous
solution containing 70.0 mg Na per mL is g (Rounded Empirical &Molecular Formula
off to the nearest integer) |26 Feb, 2021 (Shift-II)]
[Given; Atomicweight in g mol-Na: 23; N:14;0 :16]
30. The minimum number of moles of O, required for 38. A metal chloride contains 55.0% of chlorine by weight.
complete combustion of Imole of propane and 2 moles 100mL vapours of the metal chloride at STP weigh
of butane is [5 Sept, 2020 (Shift-D)] 0.57 g. The molecular formula of the metalchloride is
31. The mass of ammonia in grams produced when 2.8 kg of (Given: Atomic mass of chlorine is 35.5 u)
dinitrogen quantitatively reacts with I kg of dihydrogen |12 April, 2023 (Shift-I)]
|4 Sept, 2020 (Shift-I))
32. Ferrous sulphate heptahydrate is used to fortify foods with (a) MCI, (b) MCI,
(c) MCI, (d) MCI
iron. The amount (in grams) of the salt required to achieve
10 ppm of iron in 100 kg of wheat is 39. An organic compound gives 0.220 g of CO, and 0.126 g
Atomic weight : Fe = 55.85; S = 32.00; O= 16.00 of H,0 on complete combustion. If the %of carbon is 24,
[8 Jan, 2020 (Shift-I)] then the %hydrogen is x 10.(Nearest integer)
33. NaCl0, is used, even in spacecraft, to produce O,. The
daily consumption of pure O, by a person is 492L at [13April, 2023 (Shift-I))
latm, 300K. How much amount of NaClO, in grams, 40. 0.5 g of an organic compound (X) with 60% carbon
is required to produce 0, for the daily consumption of a will produce x.10'g of CO, on complete
person at 1atm, 300 K?
combustion. 8 April, 2023 (Shift-I))
NaClO,(s) +Fe(s)’ O,(g) +NaCl(s) +FeO(s)
R=0.082 L atm mol K1. [8 Jan, 2020 (Shift-II)) 41. 120 g of an organic compound that contains only carbon
34. At 300 K and Iatmospheric pressure, 10 mL of and hydrogen gives 330 g of CO, and 270 g of water
a hydrocarbon required 55 mL of 0, for complete on complete combustion. The percentage of carbon and
combustion and 40 mL of CO, is formed. The formula of hydrogen, respectively are |24 June, 2022 (Shift-I))
the hydrocarbon is: [10 April, 2019 (Shift-1)] (a) 25 and 75 (b) 40 and 60
(a) C,H, (6) C,H,CI (c) 60 and 40 (d) 75 and 25
(c) C,H,, (d) CH,
42. Compound Acontains 8.7% Hydrogen, 749% Carbon and
35. 5moles of AB,weigh 125 x10 kg and 10 moles of A,B,
weigh 300 x 10 kg. The molar mass of AM) and molar 17.3% Nitrogen. The molecular formula of the compound is,
Given : Atomic masses of C, H and N are 12, I and I4
mass of BM., in kg mol are: [12 April, 2019 (Shift-)] amu respectively.The molar mass of the compound A is
(a) .M, = 50 x 10 and M, =25 x 10-3
162 g mol. |28 June, 2022 (Shift-II))
(b) M, = 25 x 103 and M, = 50 x 103
(c) M, =5 x 10and M, = 10 x103 (a) C,H,N, (b) C,H,N
(d) M, = 10x 10and M, =5 x 103 (c) C,H,N (d) CH,N,
Some Basic Concepts of Chemistry
43, T16 g of a suhstance upon disscciation reaction yields 52. AI0 mg effervewent ablet containing vdiun
75 p of hydrngen, (g of oxygen and 4%.5 yg of carhon
Given that the atonic massc of |, ) and are I,16 and
and oxalic acid releases ),25 ml of CO. at T
and p Ihar. If molar volume of CO, 525.0 L
biunderc29a%rta.15eK
condition, what is the percentaye of odium
12 g'mol respectively The data agrees with how many
formulac of the following? (27 June, 2022 (Shift-0)| in cach tablet! (Molar mass of NaHCO, - bicarbona,
|11Jan, 2019 (Shift-ty
(b) HCH)
(a) 0.84 (b) 33.6
(d) HCHO (c) 16.8 (d) 8.4
44, A2.0 gsample containing Mn0, is treated with HCI
liberat1ng 1, The C1, gas is passcd into a solution of KI
and 60,0 ml. of 0,1 M Na,S,O, is required to titrate the Stoichiometry &
liberatcd sod1nc.The percentage of Mn), in the sample Stoichiometric Calculations
(Ncarest integer)
|Atomic mases (inu )Mn 55:CI-35,5:O 16,|= 127,
53. When a hydrocarbon A undergoes combustion in the
Na 23,K 39, S 32] |28 June, 2022 (Shift-I)|
45. On complete combustion 0.30 gof an organic compound presence of air, it requires 9.5 equivalents of oxygen and
produces 3cquivalents of water. What is the moleculr
gave 0.20 gof carbon dioxide and 0.10 gof water. The formula of A? [29 Jan, 2023 (Shift-i)
percentagc of carbon in the given organiccompound is
(a) C,H, (b) C,H,
(Ncarest integer) 126 June, 2022 (Shift-1)|
(c) CH, (d) CH,
46. The complete combustion of 0.492 g of an organic 54. When a hydrocarbon Aundergoes complete combustion
comipound containing "C, 'W and '0' gives 0,793g of Co, itrequires I1 equivalents of oxygen and produces 4
and 0,442 gH,0. The pcTcentage of oxygen composition in equivalents of water. What is the molecular formula of A?
the organic compound is .(ncarest integer) [31Jan, 2023 (Shift-D|
(28 June, 2022 (Shift-I1)| (a) CH, (b) C,H,
47. In the cstimation of bromine, 0.5 gofan organic compound (c) C,H, (d) CH,
gave (0.40 gof silver bromide. The percentage of bromine in 55. Igofa carbonate (M,CO,) on treatment with excess HC]
the given compound is %(Nearest integer) produces 0.01 mol of CO,. The molar mass of MC0, is
(Relative atomic masses of Agand Br are 108 uand 80 u, gmol'. (Nearest integer)|13April, 2023 (Shift-ID)
respectively). |28 June, 2022 (Shift-1)| 56. On complete combustion, 0.492 gof an organic compound
gave 0.792 g of CO,. The % of carbon in the organic
48. Complete combustion of 1.80 gof an oxygen containing compound is (Nearest integer)
compound (C, H,0)gave 2.64 gof C0,and 1.08g of H,0. (31 Jan, 2023 (Shift-)
The percentage of oxygen in the organic compound is 57. Number of hydrogen atorns per molecule of ahydrocarbon
[25 Feb, 2021 (Shift-)) Ahaving 85.8% carbon is
(u) 53.33 (b) 50.33 (Given: Molar mass ofA = 84 g mol')
(c) 63.53 (d) 51.63 |25 Jan, 2023 (Shift-I))
49. Complete combustion of 750g of an organic compound 58. Zinc reacts with hydrochloric acid to give hydrogen and
provides 420 g of CO,and 210 gof H,0. The percentage zinc chloride. The volume of hydrogen gas produced at
composition of carbon and hydrogen in organic compound STPfrom the reaction of 11.5 g of zinc with excess HCI
is 15.3 and respectively. (Round off to the L(Nearest integer)
(Given : Molar mass of Zn is 65.4g mol' and Molar
nearest Integer). |16 March,2021 (Shift-)) volume of H, at STP = 22.7L) .31 Jan, 2023 (Shift-1)
50. Methylation of 10 g of benezene give 9.2 g of toluene. 59. Assume carbon burns according to following equation :
Calculate the percentage yíeld of toluene 2C+0l ’ 2C0(g)
(Nearest integer) |22 July, 2021 (Shift-l)] When 12 gcarbon is burnt in 48 g of oxygen, the volume
of carbon monoxide produced is x10'Lat STP
51. The pcTcentage composition of carbon by mole in methane
(8 April, 2019 (Shift-1)| [nearest integer]
(u) 80% (b) 25% |Given : Assume CO as ideal gas, Mass of Cis 12 gmol
Mass of O is 16g mol 'and molar volume of an ideal gas
(c) 75% (d) 20%
at STP is 22.7 L mol'] |31 Jan,2023 (Shift-I))
JEE PYQS Chemistry
60. If S moles of BaCl, is mixed with 2
moles of
Na,PO, the 67. In the given reaction, X +Y+ 3Z = XYZ,
maximum number of moles of Ba,(PO,), formed is
(Nearest integer) If one mole of each of X and Y with 0.05 mol of Z
[6 April, 2023 gives
61. The volume of hydrogen liberated at STP by (Shift-I)) compound XYZ,. (Given: Atomic masses of X, Yand Z
treating 2.4 gof are 10, 20 and 30 amu, respectively.) The yield of XYZ, is
magnesium with excess of hydrochloric acid is
x 10²L. g. (Nearest integer) (28 July, 2022 (Shift-)|
Given:Molar volume of gas is 22.4 Lat STP. Molar 68. 2L of 0.2 M H,SO, is reacted with 2L of 0.1I M NaOH
mass
of magnesium is 24 g mol, solution, the molarity of the resulting product Na,SO, in
the solution is
|11 April, 2023 (Shift-I1)) millimolar (Nearest integer)
62. 17 mg of ahydrocarbon (M.F. C,H,)takes up |28 July, 2022 (Shift-I)|
8.40 mLof
the H, gas measured at 0°C and 760 mm of Hg. 69. When 200 mL of 0.2 Macetic acid is shaken with 0.6 g of
Ozonolysis
of the sanme hydrocarbon yields. [29 Jan, 2023
(Shift-I)) wood charcoal, the final concentration of acetic acid after
CH, -C-CH,-, HC-H, H-C-CH, -CH, adsorption is 0.IM. The mass of acetic acid adsorbed per
-C-C-H gram of carbon is [24 June, 2022 (Shift-1D|
70. A 0.166 g sample of an organic compound was digested
The number of double bond/s present in the with conc. H,SO, and then distilled with NaOH. The
hydrocarbon
ammonia gas evolved was passed through 50.0 mL of
63. If arocket runs on a fuel(C,H,) and 0.5 N H,SO, The used acid required 30.0mL of 0.25 N
liquid Oxygen, the
weight of oxygen required and CO, released for every litre NaOH for complete neutralization. The mass percentage
of fuel respectively are: |24 June, 2022 (Shift-1)] of nitrogen in the organic compound is
(Given: density of the fuel is 0.756 g /mL) [24 June, 2022 (Shift-ID)
(a) 1188g and 1296g (b) 2376 g and 2592 g 71.
(c) 2592g and 2376g (d) 3429 g and 3142 g
64. Consider the reaction
CI
4HNO,M)+3KCI(S) -’ CL(g) +NOCIg) +2H,0g) +3KNO,(6)
The amount of HNO, required to produce l10.0 g of KNO, +C,HNHCH, >CH-CNCH),
is (Given: Atomic masses of H, 0, N and K are 1, 16, 14 0.140g 0.388g 0.210g
and 39, respectively) [29 July, 2022 (Shift-I)]
(a) 32.2g (b) 69.4g Consider the above reaction. The percentage yield of
(c) 91.5g amide product is
(d) 162.5g
65. N,(g) +3H,(g) 2NH,(g) (Round off to the nearest integer).
(Given : Atomic mass : C:12.0u, H:1.0u, N: 14.0 u, O :
20g 5g 16.0 u, CI: 35.5 u) [17 March, 2021(Shift-I)]
Consider the above reaction, the limiting reagent of
72. The formula of a gaseous hydrocarbon
the reaction and number of moles of NH3 formed which requires
6 times of its own volume of O, for complete
respectively are: [29 July, 2022 (Shift-I)) oxidation
and produces 4 times its own volume of CO, is CH. The
(a) H,, 1.42 moles (b) H,, 0.71 moles value of y is |24 Feb, 2021 (Shift-II))
(c) N,, 1.42 moles (d) N,, 0.71moles 73. grams of 3-Hydroxy propanal (MW=74)
66. The normality ofH,SO, in the solution obtained on mixing must be dehydrated to produce 7.8g of acrolein (MW= 56)
100 mL of 0.1 M H,SO, with 50 mL of 0.1 M NaOH is
(CHO) if the percentage yield is 64. (Round off to the
x 10! N. (Nearest Integer)
nearest integer). |18 Marech, 2021 (Shift-I))
|27 July, 2022 (Shift-II)| [Given: Atomic masses : C: 12.0u, H:1.0u, O:16.0u]
Some Basic Concepts of Chemistry 5

(b) Iand 2
COOH
(a) Iand I
COOH (d) Iand 0,5
(c) 2and 0.5
an cxcess of
80. 5g of zinc is treated separately with
acid and
74. +Br,
FeBr +HBr (A) dilute hydrochloric
hydroxide.
B (B) aqucous sodium
evolved in
The ratio of the volumes of H, these
19 Jan, 2020
Consider the above reaction where 6.l g of Benzoic acid is
reactions is:
(6) 1:1 (Shift
used to get 7.8g of m- bromo benzoic acid. The percentage (a) 1:4
(Round off to the nearest (d) 2:1
yield of the product is (c) 1:2
integer). 81. The ammonia(NH,) rreleased on quantitative
[Given: Atomic masses:C:120u. H:1.0u, O:16.0u, Br:80.0 u] 0.6g urea (NH,CONH,) with sodium reaction of
|18 March, 2021(Shift-I))
NO.
can be neutralized by
(a) 100 mL of 0.1 NHCI (b) 1001L.of
hydroxide(NaOH)
17Jan, 2020
(Shift-ID
0.2 NHCI
75.
(c) 200 mL of 0.2 NHCI () 200 mL of 0.4 NHCI
82. Asolution of phenol in chloroform when treated
HNO,
aqueous NaOH gives compound Pas a major product. wwith
H,so, mass percentage of carbon in P is (to the The
nearest integer) (Atomic mass: C = 12:
In the above reaction, 3.9 g of benzene on nitration H=1;0=16
|6 September, 2020 (Shift-JDi
gives 4.92 g of nitrobenzene. The percentage yield of 83. For the following reaction, the mass of water produced
nitrobenzene in the above reaction is %
from 445 gof C,,H0, 1is:
(Round off to the nearest integer). 2C,H0, (s) +1630, (g)-|14 C0, (g) +l10 H,0 ()
(Given atomic mass:C: 12.0u, H:1.0u. O:16.0u, N:14.0u) |9 Jan, 2019 (Shift-DI
|17 March, 2021 (Shift-)] (b) 445 g
(a) 490 g
76. Complete combustion of 3g of ethane gives x x 10 (c) 495 g (d) 890 g
molecules of water. The value of x is (Round
off to the nearest integer). 84. 50 mL of 0.5 Moxalic acid is needed to neutralize 25 ml
[Use : N, =6.023 x 10'3; Atomic masses in u: C:12.0, of sodium hydroxide solution. The amount of NaOH in
O:16.0; H:1.0] |17 March, 2021 (Shift-I)) 50 mL of the given sodium hydroxide solution is:
77. 100 g of propane is completely reacted with 1000 g |12 Jan, 2019 (Shift-D)
of oxygen. The mole fraction of carbon dioxide in the (a) 40g (b) 10g
resulting mixture is x x10². The value of xis (c) 20 g (d) 80 g
(Nearest integer) 85, For a reaction,
[Atomicweight : H= 1.008; C = 12.00; O= 16.00]
N,(g) +3H,(g) ’ 2NH,(g):
(27August 2021 (Shift-ID)
Identify dihydrogen (H,) as a limiting reagent in the
78. 100g of propane is completely reacted with 1000 g following reaction mixtures. |9 April, 2019 (Shift-D)]
of oxygen. The mole fraction of carbon dioxide in the (a) 14 g of N, +4g of H, (b) 28gof N, +6 g of H,
resulting mixture is x x102. The value of xis
(c) 56g ofN, + 10g of H, (d) 35 g of N, +8g ofH,
(Nearest integer) 86. The stoichiometric reaction of 516 g of dimethyldi
[Atomic weight: H= 1.008; C = 12.00; 0 = 16.00] chlorosilane with water results in a tetrameric cyclic
[27August, 2021 (Shift-I1)) product X in 75% yield. The weight (in g) of Xobtained
79. The first and second ionisation enthalpies of a metal
are 496 and 4560 kJd mol, respectively. How many
moles of HCI and H,S0,, respectively, will be needed [Use, molar mass (g mol): H= 1,C = 12, 0= 16, Si =28,
Cl = 35.5] [JEE Adv 2023]
to react completely with I mole of the metal hydroxide?
|9 Jan, 2020 (Shift-Il)]
6 JEE PYQs Chemistry

ANSWER KEY
5. (b, c) 6. (b) 1. (d) 8. (d) 9. (200] 10. (c)
1. (c) 2. (b) 3. [3] 4. (8]
16. [143] 17. [46] 18. (24] 19. [0] 20. (2]
|1. (c) 12. (c) 13. (b) 14. (5418] 15. (25]
21. [1143] 22. (225] 23. (30] 24. [530) 25. (3] 26. [1) 27. [464] 28. (2] 29. (13] 30. (18]
33. [2130] 34. (d) 35. (c) 36. (6.15] 37. (2.98 or 2.99] 38. (a) 39. (56]
31. [3400] 32. [496]
41. (d) 42. (d) 43. (2] 44. [13] 45. [18] 46. (46] 47. [34] 48. (a) 49. (3]
40. [11]
50. [78] 51. (d) 52. (d) 53. (a) 54. (a) 55. [100] 56. (44] 57. [12] 58. [4] 59. (227]
62. [3] 63. (c) 64. (c) 65. (c) 66. [1] 67. (2] 68. (25] 69. (2]
60. [1] 61. (224]
73. [16] 74. (78] 75. [80] 76. [18] 77. [19] 78. [19] 79. (d)
70. [63] 71. [77] 72. [8]
80. (6) 81. (b) 82. [69] 83. (c) 84. (*) 85. (c) 86. (222)]
EXPLANATIONS
1. (c) To determine the no. of significant figures certain 5. (b,c)

rules are followed. According to the given options (a) Compound 3 if compound is
rules are mentioned as,
3P 40 2
(A) 0.00253 P.Q, ’
4Q 60 3
Zeros to the left of first non-zero digits are not
significant. P 8
Significant figures = 3(2, 5, 3)
(B) L.0003
Zeros between non-zero digit are significant. Compound 2
Thus, 1.0003 has 5 significant figures.
3P 44.8
(C) 15.0 PQ, ’
Ifa number ends in zeros and if these zeros are to the 5Q 55.6
right of a decimal point, then it will be significant.
Significant figures = 3
(D) 163
All non zero digits are significant.
4
Significant figures = 3
3 6
Hence, number given in A, Cand D have same
significant figures. Option 'a' is wrong
2. (b) The given expression using the rules for significant (b) Compound 3
figures can be solved as:
0.02858x0.112 40
=0.00561 P= =2 1.5 3
0.5702 20
3. (3] In 0.00340, number of significant figure is 3. formula =P,Q,

60 4
4. [8] The no of significant figure in the given number is 8. Q= 45
2

P 444 4.4
-=0.8 moles of Co, from combustion
(c) Compound 2 0 S5.6 carbon 44 moles of
SP 1
Compound l= 40 -=-4 Q
0.01M 60 4.4
12 100 44
(d Compound I 4,4 100 12
50 M= -=200gm / mol
P==1 44 60 0,01
70
10. (c) Molar mass of Fe,0, =232 g/mol
50 Molar mass of CO = 28 g/mol
Q==
35
Given weight
Moles
6. (b) CI "CI Molar mass
Molar ratio be |-x
4.64x10
n, M, +n,M. Moles of Fe,0, = 232
-= 20
Average molar mass =
n, +n. 2.52x 10
Moles of CO: 90
M 35 xx +37(| - x)=35.5 28
35x - 37- 37x = 35.5 According to the reaction:
2x = 1.5 4 moles of CO reacts with I mol of Fe,0,
x=0.75; | -x = 0.25 90 moles of CO reacts with 22.5 mole of Fe,0.
0.75
Thus, limiting reagent =Fe,0,
So. ratio ofC1:Cl = =3:1 Thus, moles of Fe formed = 60
0.25
Weight of Fe = 60 x 56 = 3360g
7. (d) 22,4 L ofO. at STP ’ 1 mole 11. (c) SO,CI, +2H,0 ’ H,S0, +2HCI
2.8375 (Given: Moles of NaOH required for complete
2.8375 L of 0, at STP = =0.125 moles
22.4 neutralisation = 16)
= Number of molecules =0.125 N, =7.525 x 102 Let a moles of SO,C1, is taken
Weight Then no. of moles of H,SO, = a moles
8. (d) n=
Molar mass No. of moles of HCI = 2a moles
l6g CH, = 1mole CH, No. of moles of NaOHrequired = 2a +2a =4a = 16
a=4 moles
Imole CH,’ 10 ×6.02 x 10 electrons
= 60.2 x 10 electrons 12. (c) Number of iron atoms in 3.3 g of hemoglobin
lg H=0.5 mole H. 0.34 3.3
X x6.022 x10
Imole H, at STP ’ 22.4 L 100 56
= 1.206 x 1020
0.5 mole H, at STP ’ 12 L& ||4 L
Imole of N, =28 g 13. (b) C,H,,0,’ Glucose
(: M-28 g/mol) Mass of C
% of C= 10,8 = -x100
0.5 mole of SO, =32 g mass of solution
(: Moo,= 64 g/mol) 10.8× 250

Mass of C: = 27g
9. (200]Let Mis the molar mass of the compound (g/mol) 100
mass of compound = 0001 Mgm
.:. Mass of glucose =67.5 gm
mass of carbon =0.0IM x
60 :. Moles of glucose =0.375 moles
100 Mass of solvent = 250 67.5 = 182.5 gm
0.01M 60 0.375
moles of carbon .:. Molality = = 2.06 m
12 100 0.1825
JEE PYQs Chemistry

14. (5418] Molar mass of Hence. atomic weight of A is two times of atomic
weight of B.
CHNO,= (12 x7) +(1 5) +(14 3) +(16 x6)
= 84 + 5 + 42 +96 =227g/mol 21. [1143]
Br
given wt 681
Number of moles = =3 mol
molar mass 227 + Br,’
Number of N-atoms:
(C,H,) Br
=3 x 6.02 x 102x 3 =9-6.02 x 1023
=54.18x J023 (C,H, Br,)
= 5418 x 1021
Moles ofBr, = moles of C.H,,
X x 10² = 5418 x 102!
X = 5418 W 5
(Molar mass of C,H,,= 70 g/mol)
160 70
15. (25] It is given that 0.30 gm glycine is present in 100 gm protein
100 5x160 80
So, 75. gm glycine is present in -x 75 W= =
0.30 70 78
= 25 x 10° g/mol = |1.428g
16. [143] CH,+20,c0, +2H,0 = 1142.8 x 10 l143 x 10 g
100 208
22. (225] CH, + 20, ’C0, +2H,0
Mass
Mole Moles = According to the reaction, 2 mol H,0 = Imol CH,
16 32 Molar mass
or 36 gm of water =Imol CH,
6.25 6.5 (Here, O, is the limiting reagent) l×81
81 gm of H,0 = 2.25 mol
6.5 36
Mole of CO, formed 2
Moles of CH, = 225 x 10² mol
Mass of CO, in gm
6.5
x 44 = 143 g SO,H
2
17. (46] N,(g) + 3H,(g) ’ 2NH, (g) 23. [30] ()| Oleum
t=0 56L Excess 0

-10L +20L % yield = 60%
Final 46L 20L
Vol. of N, (g) remained unreacted = 46L Let initial moles of reactant be = n. Total moles of
Vol. of N, used = 10L benzene sulphonic acid = 0.6 n
18. (24] Mass of solute =48 x 2 x10 gram SO,H OH
mass of solute
ppm= x10° (I) NaOH (excess)
mass of solution H
Atoms of Mg = 24.08 x1020 % yield = 50%

19. (0] 50% of 0.02mmol and IL of H,SO, =0.01 mmol Moles of benzene sulphonic acid before reaction l
Total moles of H,SO, after adding 0.01 mol ofH,SO, =0.6n.
=0.01 + 0.01 = 0.02 mmol Moles of phenol(with %yield 50%) = 0.6 x 0.5 n
=0.00002 x 10° mmol =0.3n
20. [2] According to question, molecular weight of A,B = 0.3n

So, overall % age yield = x100 = 30%
Molecular weight of AB,
Thus, 2A+3 =A +3B 24. (530] According to the given condition,
’A=2B 5 92
No. of moles of toluene reacted = =5x10
92 100

3S00mp
Mass of henraldchvde obainad 29.|13] NMass of Na' in $0 ml70 xS0 -
=n mlar mass = 0 106-S3g 23000 mg of Na 85000 mg of NaNO(| mole
NaNO, oontains l mole Na')
S30 10 85000
25. (3] Step 1: ..3500 mg Na' will be present in 23000 x3500
CH.
-12934.78 mg
CHNH. - 12.93478 gm
CH 13
- H.CB 30. [18] The combustion reactions of propane and butane
3 moles of bromomethane is reouired to form l mole
CH +50,’3C0, +4H,0
of benzvl trimethvi ammonium bromide CH,+0,’c0, +SH0
Step 2: To calculate no of moles ofbenzyl trimethyl
ammonium bromide present in 23 g 2mol C,H,, is given
13 mol 0, is needed for combustion of Buto
Mut of (CHNB:)
=12x 10- |× 16 -1 × 14-| xS0 = 230 u Total moles of 0, =5 + 13 = 18
23
-0.l mole 31. (3400] N + 3H, 2NH,
No. of moles in 23 g= 230
2.8x10° lx10°
For Imole product ’ 3 mole (CH Br) required
2
So for 0.1l mole product ’ 0.3 mole CH,Br is 28
required 0.1 x 10° mol 0.5 x 10° mol
n=3>10 mole N, is a limiting reagent.
n=3 Now, mass of NH, produced =moles x molar mass
26. [1] Total w =4gm = W Wco 0.2 x 10° x17 = 3.4 kg = 3400 g
Let m be the moles for each. 32. (496]
4 = 40 m - 106 m (Here. 40 and 106 are molar Ferrous sulphate heptahydrate is FeSO,7H,0.
masses of NaOH and NaC0, respectively) Mass of Iron
PPM -x10
4 Mass of Wheat
m = mole of NaOH and Na, C0, each.
146
4
x 40=1.095 = 1.0 10 =
Mass of lron10
Mass of NaOH (x gm)= 100x10°
146
27. [464]The combustion reaction of butane is: Mass of Fe =1 gm
C H0,4c0,- SH,0 Mole of Fe =

56
Imole CaH =5 mole H-0 FeSO, 7H,0 contain =Imole of Fe atom
.5 mole H0= 5x18 =90 gm .. 56 g in l mole
:90 g H:0 obtained from 58 g CHo
58 lgin mole
.. 72g H,0 obtained from 56
90
72g
.. Mass = x277.85 = 496
:212g =46.4 =464x10'g 56
90
Mass 8 33.(2130] Acc. to reaction, moles of NaCiO, = moles of 0,
28. [2] Moles of sodium
Molar Mass 23moj PV
Ix 492
8 Moles of O, 0.082 x 300
20 mole (" n=pT
Number of atoms x6:02 × 102
23
Mass of NaClO, - 20 x 106.5 =2130 g.
=2.09 x 10 2 x 109

chloride
38. (a) Molecular weight of metal
Given: mass of metal chloride - 0572
0.57 22 700 = 129 39
100
10 10x
weight of C1 = 1299 055 = 71 1645
71.1645
By given data, .i) .. Mole of Cl = 2
35.5
10x = 40 ...(ii) Hence, metal chloride is MCI,
X=4, y=6 ’ C,H, 0.22
39. (56] Moles of CO, = 44 200
35. (c) 5[M, + 2M,] = 125
M, + 2M, - 25 (molar mass = of CO, = 44g moi)
Moles of carbon = ((Moles of CO, ) x number of
2M, + 2M,- 30 ...(1) Catoms in it
from eq.(i) &(ii) 1
200 200
M, =5
M, = 10 ..% wt. of C= -x12 = 0.06
200
36. [6.15]
0.06
2Al+3H,SO, ’ A,(SO),+3H, % of C= x100 =24
W
5.4 0.126
Moles of Al takes = =0.2 =0.007
27 Moles of H,0 = 18
50×5.0 (Molar mass of H,0= 18g mol)

Moles ofH,SO, taken -=0.25
1000 ..Moles of Hatom = (moles of H,0) x 2
=2 x 0.007 = 0.014
0.2 0.25
S,H,SO,
As- 2 3
is limiting reagent 0.014x1
Thus, % of H = -x 100 = 5.6 = 56 x 10!
3 W
Now, moles of H, formed =x0.25 = 0.25
3 40. [11] Percentage of Carbon
nRT
Volume of H, gas formed = 12 mass of CO, formed
P -x100
44 mass of compound taken
0.25x 0.082 x 300
=6.15L mass of CO, formed
12
60 = -x100
44 0.5
37. [2.98 or 2.99]
60x 44x 0.5
Mass of CO, formed
Xurea = 0,05 = 12 x100
n+50
19n =50 1.lgram
n=2.6315 = || x l0 gram
41. (d) Number of moles of C - Number of moles of CO, =
(2.6315x 60 + 900) Given weight 330 moles
sol
= 881.5789 ml
1.2 Molar nmass 44
2.6315x I000 Number of moles ofH=2 x no. of moles of H,0 =

Molarity = =2.9849
681.5789 270
-x 2 moles
Molarity = 2.98M
Some BasicConcepts of Chemistry 11

330
Mass of C=
44
x 12 gm =90 gm Mass Moles =
Sinplest Ratig
270 C4L8g 41.8 3.48
Mass of H x2 lgm = 30 gm --3.48
12 3.23
% ofC =
90 H6.5g 6.5 6.5
x 100% = 75% =6.5
120 3.23-2
%ofH =
30
100% =25°% o 51.7g S1.7
=3.23
3.23
120 16 3.23
42. (d) The empirical formula for the compound Acan be Given the ratio of moles of C, Hand O is 1-).1
calculated as:
A CH_COOH ’C: H:0= 2: 4:2 =1:2:1
B HCHO ’ C: H: 0=l:2: 1
Moles
Simplest C CH,00CH, »C:H:0=2: 6: 2=1: 3:1
Mass Weight Ratio D. CH,CHO ’ C: H:0=2:4:1
Molar Mass
So, onlytwo compounds CH;COOHIand HCHOagrees
74 6.17 =4.9 5 with given data.
C 74g =6.17
12 1.24 44. [13] MnO, +HCI’ MnCl, +Cl,+2H,0
I
Cl,+ 2KI’ 2KCl + L,
8.7 8.7
8.7g -=8.7 1.24
=7 1,+ 2Na,S,0,’2Nal+Na,S,0,
Now, meq of MnO,= meq of Na,S,0,
17.3 1.24
-=l W-x1000 = M Xn-factor x V
N 17.3g -=1.24 L.24
14 E
Hence, empirical formula is CH_N and empirical mass W

-x 1000 =0.1 x1 x 60 =0.261g
is 8lg/mol 87/2
Given: Molecular mass = 162 g/mol Mass of MnO, in sample =0.26lg
Molecular Mass 162 Given, Mn0,-2g
-2
EmpiricalMass 81 0.261
%of MnO, in sample = 2
-x100 =13.05%
Molecular formula =n xEmpirical fomula =CH,N,
43. (2] The empirical formula of the given compound can Hence, 13% MnO, is present in the sample.
be calculated as:
45. [18] Calculate wt of carbon in 0.2 gm CO, as:
% of element =
Amount of element
Amount of substance
-x 100
120.2|gm
44
Therefore %of carbon in compound is:

48.5 wt of carbon x100 12x0.2x100
Hence, % of C=. x]00 = 41.8%
|16 44× 0.3
wt of compound
7.5 2400
% of H =. -x100 = 6.5% = 18.18 x 18%
|16 44x3
60
46. [46] Moles of C=moles of CO,
% of O = -x100 = S1.7%
116 Weight of CO, 0.793
mol
Molar mass of CO, 44

Mass ofC =Molcs of CO, x Molar mass of Moles of hydrogen in compound =moles of hydrogen
0.793 in H,0
44
x12g =0.216g 210
0.442 Thus, n,, =nH,0 =2 -moles
Moles of H-2x mol 18
18
210
0.442 Mass of hydrogen = 2% -g=23.33y
Mass of H=2x xlg =0.049g 18
18
23.33
Given: Total mass of compound = 0.492g Thus. % of H: -x100 = 3. 11%=3.
750
So, mass of O-(0.492 -0.216-0,049)g
0.227g CH,
Mass of Oxygen x 100

% of O = Anhyd. AICL,
Total mass of compound 50. (78] + H,C CI
0.227
x100 = 46.14% 46%
0.492
Theoretically; I mol benzene of I mol will give 1
47. (34] Given:- Mass of organic compound -0.5g mol of toluene.
0.40 10
Moles ofAgBr = 188
moles Moles of benzene= mol
78
Now, moles of Br in organiccompound = Moles of 10
Br in AgBr = Moles of AgBr Moles of toluence (Theoretical) = mol
78
0.4
-mol 9.2
188 Mole of toluene (observed) = =0.l mol
92
Mass of Br in organic compound = Moles of Br x Observed moles
0.4 % yield = x 100
Atomic weight of Br= 188-x80g Theoretical moles
0.4x80 0.1
Hence, % of Br = x100 =34% % yield -x 100 = 78%
188x 0.5 10
78
48. (a) First calculate the percentage of C and Has:
% of C
51. (d) In CH,
Wt of CO, 12 -x100 : 2.64 12 Imole for 'C and 4 mole for 'H'
-x 100 = 40%
Wt of comp. 44 1.8 44 Total 5 mole atom
% of H
Wt of H,0 % by mole of carbon Imolatom x100 = 20%
-xx100 = 08 2 -x 100 = 6.67%
X S molatom
Wt of comp. 18 L.8 18
Now, % of O = 100 - (40 + 6.67) = 53.33% 52. (d) 2NaHCO, + H,C,0, ’ Na,C,0, + 2C0, + 2H,0
Let mass of NaHCO, be x mg
49. [3] Moles of carbon in organic compound= Moles of
carbon in CO, 0.25 10-5
nco, 25000
=
Given weight of C0, 420

nc = nc0) -moles
Molar mass of CO, 44
WNaHCO, = 84x10g
Mass of carbon in organic compound = Moles of Cx
420 84x105
Atomic weight of C= -x12 =114.54g %=
102
-x 100 = 8.4%
44

molecular mass 84
Now. n= =6
Empirical formula 14
n=6
.. Molecular formula CH,,
x+=95
4
Hence, 12 hydrogen atoms are present in pe
molecule ofa hydrocarbon, A.
(: given 3equivalents of water)
2
58. (4] The reaction takes place as follows:
x=8,y = 6 Zn + 2HCl’ ZnCl, +H,
54. (a) The general fom of combustion reaction is: 11.5
Moles of Zn = -moles
65.4
According to the reaction,

Imole of Zn produces 1mole of H, as
=4:y=8
2
(11.5\
Thus, |moles of Zn produce I1.5
x+°=11 65.4, 65.4 moles
..x=9
of H, gas.
Hydrocarbon formula will be =C,H, At STP
1mol of H, produces 22.7 Lof volume.
55. [100] The chemical reaction for treatment of carbonate
with excees HCl is given as,
M,CO, +2HCI’ 2MCI + H,0+ C0,
Excess 0.02 mole
Hence, for Pmoles
65.4) of H, Volume
0.01mole
From principle of atomic conservation of carbon atom,
11.5.
Mole of M,CO, ×| = Mole of CO, x1 = 22.7 x =3.99L = 4L
65.4
Igm = 0,01 x1
molar mass of M,CO, 59. (227] 2C(s) +0,(g) -’ 2C0(g)
Imol 1.5 mol
:. Molar mass of M,CO, =100gm /mole
Here, C acts a limiting reagent.
56. (44] Weight of Cin 0.792 gm CO, Imol C= | mol CO
12-x0.792 =0.216 Hence, volume at STP is 227 x 10 litre
44
0.216
60. [1] 3BaCl, +2Na,PO,’ Ba, (PO), +6NaCI
-x100 5 2
%of C in compound 0.492 number of moles
= 43.90% less are the limiting reagent.
stiochiometric coeffs
Hence, 44% carbon is present in the organic compound.
57. [12] Na,PO, is limiting reagent.
2mole Na, PO, gives I mole of Ba, (POJ),
Element Percentage mole = weight Mole ratio 61. (224] Mg +2HC] ’ MgCl, +H,‘
molar mass
w =2.4g
85.8 7.15 m 2.4
85.8 =7.15 =1
12 7.15
n=
M.M. 24
=0.Imole
14.2 14.2 Imole of gas at STP+22.4 litre

H 14.2 -= |4.2 2
7.15 ..0.1 mole of gas = 0.1 x 22.4
Hence, Empirical formula =CH, - 22.4 litre =224 x10 litre

17x10 65. (c) N,(g) +3H,(g) =2NH, (g)
62. [3] Moles of hydrocarbon = =L25z10
136 20
At t= 0
Mole of H, gas 28 2
8.40 According to the reaction

=nx0.0821× 273
1000 3 moles of H, require ’ Imole of N,
’n=3.75 x 104 5 moles of H, require ’5 mole of N,
2
Hydrogen molecule used for 1 molecule of
hydrocarbon is 3. Hence, N, is the limiting reagent in the given reaction
3.75x 10+
and number of moles of NH, =2 x number of moles
3
1.25x10 20 40
= 1.42 moles
of N, reacted = 2x
28 28
63. (c) Mass of C,H,, = volume x Density
= 1000mL x 0.756 gm / mL= 756gram 66. [1] No. of equivalents of 0.1 MHSO, = 100 x 0.J x2 =20
C,,H,, +22.5 O, ’ 15C0,+ 15H,0 No. of equivalents of 0.1 M NaOH = 50 x 0.1 = 5
756 No. equivalents of H,SO, left = 20 - 5 = 15
No. of moles of C,H, needed = moles 150 × x= 15
210
1
756 X = =0.IN =| x10! N
No. of moles of O, needed |22.5x 210 moles 10
67. (2] X + Y + 3Z = XYZ

756
Mass of 0, needed= 22.5 x x 32 =2592 gm mole lmole 0.05 mole
210
.. n, =1
756 n =1
No. of moles of CO, liberated = 15 x 210 moles
0.05
756 3
=0.0167 (Here, Z acts asalimiting reagent).
Mass of CO, liberated = 15 x x 44 = 2376 gm
210
0.05
64. (c) 4HNO,() + 3KCI(s)’ mole Z gives I mole XYZ,
Cl,(g) +NOCI(g) +2H,O(g) + 3KN0, () .:. Mass of XYZ, =nx molecular mass
According to the reaction
0.05
4 moles of HNO, gives 3 mol of KNO, x 120 = 0.05 x 40 = 2g
110
Here, mole of produced KNO,
101 68. (25] HSo, + 2NaOHNa,SO, + 2H0
No. of
(::MaNo, -101g/mol)
If 3 mol of KNO; produced by 4 moles of HNO,
mole = 0.2 x 2 2x 0.1
=0.4 =0.2
4
Imole of KNO; produced by moles of HNO, No. of moles
3
after reaction = 0.4 -0.1 0.2 -0.2 0.1
110 4x110
and =0.3 =0
101
-mole of KNO, produced by moles
3x101
Moles 0.1
of HNO, = 1.45 mole of HNO, :. Molarity of Na,S0, =
V(L) 4
Hence, the mass of HNO, = mole x molecular weight
= 1.45 x 63 =91.48 ~91.5 g = 0.025 = 25 mM
Some BasicConcepts of Chemistry 15

69. (2] Mass of charval =0.6g Weight of amide product produced
M,V, - M, V, 0.140
Mass of acetic acid adsorbed = x273 =0.272g
1000 140.5
0.2x 200-200 x 0.1 0.210

x60 =1.2 g x 100 = 77.20%
T000 % Yield
0.272
Mass of acetic acid adsorbed per gram = 0.6 reaction is:
72. [8] The general combustion
70. [63) M of NH, = Mof used H.SO, - M of NaOH
-NxV= 0.25 x 30=7.5
Millmoles ofN =millimoles of NH, =7.5 CHe)(x0,8)04)+Hg
V 6V
Mass of nitrogen = moles xmolar mass
4V
=7.5 x 14 x 10 x3 =0.105 gm
According to question,
0.105
% of Nitrogen = x100% =63.25% 63% Volume of C0, =4 xVCH,
0.166
Vx = 4V
71. [77] The reaction is X=4
Volume of 0, =6 xVCH,
+CHNHC, H,’CH,-C-NHCH),
=2;
4
y=8
0.140 g 0.388 g 0.210 g
Molecular weight of compounds are:
73. [16] HC- CH, -C -H C,H,0 +HO
OH Acrolein
140.5 g/mol
7.8
Number of moles of acrolein = moles
56
According to the reaction, I mol of acrolein is
C,H,NHC,H, 169 g/mol dehydrated by I molof 3-hydroxy propanal.
Hence, number of moles of 3-hydroxy propanol
273 g/mol 7.8
CH-C-NCH), required for moles of acrolein dehydration
56
7.8
moles
56
+CH,NHC,H, 7.8x 74 100

Thus, Weight =
0.388 56 64
mole
0.140 169
mole = 16.10 g 16
140.5
74. [78] Moles of benzoic acid
C-N(CH), +HCI Weight 6.1
=0.05 moles
Molar mass 122
Theoretical moles of m-bromobenzoic acid = 0.0S

7.8 6.81 0.1902 =19.02 102
Observed moles of m-bromobenzoic acid 19.9+6.81 +9.08
202
=0.039 moles
Observed moles 0.039 Hence. x = 19.
%yicld = -x100 = 78%
Theoreticalmoles 0,05
100 = 2.27 mol
78. [19] neH, 44
75. [80] NO, 1000 = 31.25 mol
32
HNO,+
C,H,(g) +50,g)’ 3C0.(g) +4H,0)
H,So, Att =0: 2.27 mol 31.25 mol 0
At t= o; 0 19.9mol 6.8lmol 9.08 mol
According to above reaction,
6.81 0.1902 =19.02 x 10
3.9 3.9
mole of nitrobenzene
Xco, 19.9+6.81+9.08
mole ofbenzene 78
78
z 19x 102
in 100% conversion.
Hence, x= 19.
Produced mole of nitrobenzene

4.92
mole. 79. (d) First ionization enthalpy of metal = 496 kJ/mole
123 Second ionization enthalpy of metal = 4560 kJ/mol
According to the given information of ionization
4.92
x100
4.92 x 100x 78
enthalpy metal belong to Ist group i.e. in the form
123 monovalent cation.
% yield = = 80%
3.9 123 ×3.9
MOH + HCI’ MCI + HO
78
Imole Imole
76.[18] The combustion reaction is 2MOH + H,SO,’ M,SO, + H,0
C,H, + 7/20, ’ 2C0,+ 3H,0 l mole /2 mole
Weight 3 80. (b) The reaction between Zn and dil. HCl is,
Mole of C,H,= Molar mass = 0.1 mol
30 Zn + 2 dil.HCI ZnCl, + H,
The reaction between Zn and aq. NaOH is,
(: Molar mass of C,H, 30g/mol)
According to reaction, Zn + 2NaOH ’ Na,Zn0, + H,
I mol of C,H,’3 mol of H,0 Mole of dil. HCI Mole of NaOH
Mole of Zn =
0.lmol of C,H,’0.3mol of H,0 2
Hence, nunmber of H,0 molecules =0.3 x6.023 x 10
= 18.06 x 1022 volume of HCI
So, x = 18 (Nearest Integer) volume of NaOH
100
77. [19] nc,H 44
= 2.27 mol 81. (b) NH,CONH,+2NaOH ’ 2NH, + Na, C0, 1 moles
urea gives 2 moles of NH,.
1000
=31.25 mol
no, 32 NH, +HCI’ NH,CI
0.6
C,H,(g) + 50,(g) ’3C0,(g) +4H,0(/) "Urea = 0.01 mole
Att=0; 2.27 mol 31.25 mol 0 60
6.8lmol 9.08 mol
At t=0; 0 19.9mol
"NH, =2 x 0.01 = 0.02 mole
82. [69] Reimer-Tiemann formylation reaction is: 28 6
(b)
OH OH OH 28
() CHC, NaOH/A, CHO Imole 3mole

+
(2) H No L.R.
(Major) CHO 56 10
(Minor) (c)
28 2
Molecular formula of product is C,H,0, 2 mol 5 mole
84 So, H, is L.R.
The mass percentage of carbon = 122 86. [222]
The reaction that occurs is:
=68.85% =69%
83. () 2CH,0, (6) +l630, (g) ’ 114 CO, (g) +110H,0 () 4(CH),SiCI, +4H,0
75%
’ (CH),Si,0, + 8HCI
Moles of Cs,HoO6_ Moles of H,0 (X)
2 110 w=516g
mass of H,0
445 516
18 n= =4 moles
890 110 129
2
Mass of H,0= 495g H,Ç CH,

84. () Eq. of (COOH), Eq. of NaOH
50 x 0.5 x 2= 25 x Mx 1 CH,
50x 2
H,C,
Mass of NaOH in 50 mL= -x 40=4g
1000 CH,
None of the given options is correct.
H,C
85. (c) N,(g) + 3H, 2NH, H,C CH,
Imole N, required 3 moles of H,.
14 Weight - 296 g
(a)
28 % yield =75
0.5 mole 2 mole
75
N, is L.R. The weight of X(in g) = 296 x = 222g
100

2 Structure of Atom
4. If the Thompson model of the atom was correct, then the

Sub-Atomic Particles and result of Rutherford's gold foil experiment would have
been: [27 July, 2021 (Shift-11))
Atomic Models
(a) All a- particles get bounced back by 180°
(b) a-particles are deflected over a wide range of angles
1. Given below are two statements: one is labelled as assertion
and the other is labelled as reason.
(c) All of u-particlespass through the gold foil without
decrease in speed
Assertion (A): Loss of electron from hydrogen atom (d) a- particlespass through the gold foil deflected by
results in nucles of ~1.5 x 10 pm size. small angles and with reduced speed
Reason (R): Proton (H)always exists in combined form 5. Amongst the following statements, that which was not
In the light of the above statements, choose the most proposed by Dalton was [7 Jan, 2020 (Shift-)|
appropriate answer from the options given below: (a) Matter consists of invisible atoms
[6 April, 2023 (Shift-I) (b) When gases combine or reproduced in a chemical
(a) Both (A) and (R) are correct and (R) is the correct reaction they do so in a simple ratio by volume provided
explanation of (A) all gases are at the same temperature & pressure
(b) (A) is correct but (R) is not correct (c) Chemical reactions involve reorganisation of atoms.
(c) (A)is not correct but (R) is correct These are neither created nor destroyed in a chemical
(d) Both (A) and (R) are corect but (R) is NOT the reaction
correct explanation of (A). (d) All the atoms of a given element have identical
2. Electrons in a cathode ray tube have been emitted with a properties including identical mass Atoms of
velocity of 1000 ms'. The number of following statements different elements differ in mass
which is/are true about the emitted radiation is
Given : h =6x 104 Js, m=9x 1031 kg.
[1 Feb, 2023 (Shift-ID)) Developments Leading to the
(a) The deBroglie wavelength of the electron emitted is Bohr's Model of Atom
666.67nm
(b) The characteristic of electrons emitted depend upon
6. Given below are two statements : one is labelled as
the material of the electrodes of the cathode ray tube
(c) The cathode rays start from cathode and move Assertion (A) and the other is labelled as Reason (R):
towards anode Assertion (A): In the photoelectric effect, the electrons
(d) The nature of the emitted electrons depends on the are ejected from the metal surface as soon as the beam of
nature of the gas present in cathode ray tube light of frequency greater than threshold frequency strikes
the surface.
3. Consider an imaginary ion X.The nucleus contains 'a'%
more neutrons than the number of electrons in the ion. Reason (R): When the photon of any energy strikes an
The value of 'a' is [nearest integer] electron in the atorn, Iranster of energy from the photon
|26 July, 2022 (Shift-ID))
to the electron takes place. ||lApril, 2023 (Shift-)|
In the light of the above statements, choose the most 10. The number of following statement/s which islare
appropriate answer from the options given below:
incorrect is (8 April, 2023 (Shift-1)1
(a) Both (A) and (R) are correct but (R) is NOT the (a) Line emission spectra are used to study the electroni
structure
correct explanation of (A)
(b) (A)is correct but (R) is not corect (b) The emission spectra of atoms in the gas phase shou
acontinuous spreadof wavelength from red to violet
(c) Both (A)and (R) are correct and (R) is the correct
explanation of (A) (c) An absorption spectrum is like the photographi
negative of an emission spectrum
(d) (A) is not correct but (R) iscorrect (d The element helium was discovered in the sun h
7. The wavelength of an electron of kinetic energy 4.50 × spectroscopic method
10Jis x 10m. (Nearest integer)
1. Values of work function (W,)for a few metals are given
Given: mass of electron is 9x 1031 kg. h=6.6 x 10* Js below:
(6 April, 2023 (Shift-))
Metal Li Na K Mg Cu
8. The number of incorrect statement/s about the black body Ag
from the following is 10 April, 2023 (Shift-I)) W,jeV 2.42 2.3 2.25 3.7 4.8 43
(a) Emit or absorb energy in the form of electromagnetic The number of metals which will show photoelectric effert
radiation
when light of wavelength 400 nm falls on it is
(6) Frequency distribution of the emitted radiation Given: h=6.6 x 1034 Js
depends on temperature c=3x 10° ms; e= 1.6 × 10-19 C
(c) At a given temperature, intensity vs frequency curve |12 April, 2023 (Shift-1)|
passes through a maximum value
12. The energy of one mole of photons of radiation of
(d The maximum of the intensity vs frequency curve is frequency 2 x 102 Hz in Jmol-! is
at a higher frequency at higher temperature compared
to that at lower temperature (Nearest integer)
(Given: h=6.626 x 104 Js
9. Following figure shows spectrum of an ideal black body
at four different temperatures. The number of correct N, =6.022 x 102 mol-!) [30 Jan, 2023 (Shift-I)I
statement/s from the following is 13. The energy of one mole of photons of radiation of
[24 Jan, 2023 (Shift-ID) wavelength 300 nm is
(Given:h = 6.63 ×1034 Js, N, = 6.02 × 102 mol:.
1
c=3× 10 ms) [24 June, 2022 (Shift-ID|
distribution
Encrgy
(a) 235 kJ mol-! (b) 325 kJ mol-!
(c) 399 kJ mol! (d) 435 kJ mo-!
14. If the work function of ametal is 6.63 x 1019J, the maximum
wavelength of the photon required to remove aphotoelectro
from the metal is nm. (Nearest integer)
[Given h =6.63 x 10*Js, and c =3 x 10'ms]
|28 June, 2022 (Shift-D)
15. The minimum energy that must be possessed by photons I
Wavelength order to produce the photoelectric effect with platinum metal s
[Given: The threshold frequency of platinumis 1.3 x10"S
(a) T,>T,>T,>T, and h = 6.6 × 104 Js.] |25 June, 2022 (Shift-11)
(6) The black body consists of particles performing (a) 3.21x 10-14 J (b) 6.24 x 10-l6J
simple harmonic motion (c) 8.58 x 10 J (d) 9.76 x 10 J
(c) The peak of the spectrum shifts to shorter wavelength 16. The wavelength of electrons accelerated from rest throu
as temperature increases apotential difference of 40 kV is x x10'm. The value o1
(d) T,T, T, constant . (Nearest Integer) |20 July, 2021 (Shift
V, V, V, Given: Mass of electron = 9.1 x 10-" kg
(e) The given spectrum could be explained using Charge on an electron = 1.6x 10-1C
quantisation of energy Planck's constant = 6.63 x 10" Js
17. Ametal surface is exposed to 500 nm radiation. The
threshold frequency of the metal for photoelectric 25. The region in the electromagnetic spectrum where the
is 4.3 x 104 Hz. The current Balmer series lines appear is: (4 Sept, 2020 (Shift-I)]
velocity ejected electron is
of (a) Ultraviolet (b) Visible
x 10°ms. (Nearest
integer) (c) Infrared (d) Microwave
[Use: h =6.63 ×10 4 Js, m =9.0 x 10 kg] 26. If Pis the momentum of the fastest electron ejected
|26 Aug, 2021 from a metal surface after the irradiation of light
18, A50 watt bulb emits monochromatic red light of (Shift-I)] having wavelenght ., then for (A)5 momentum of the
of 795 nm. The number of photons wavelength
emitted per second by photoclectron, the wavelength of the light should be:
the bulb is x x 1020, The value ofx is (Assume kinetic energy of cjected photoelectron to be
IGiven:h=6.63 x 10 4 Js and c = 3.0 x 10 ms] very high in comparison to work function).
|1 Sept, 2021 (Shift-I)] [8 April, 2019 (Shift-I))
19. A proton and a Li" nucleus are accelerated by the same (a) (b)
4
potential. If , and , denote the de Broglie wavelengths
4
of Li' and proton respectively, then the value of (c)
3 9
Xx 10. The value of x is 27. Which of the graphs shown below does not represent
(Rounded off to the
nearest integer) Mass of Li" =8.3 mass of proton] the relationship between incident light and the electron
ejected from metal surface? |10 Jan, 2019 (Shift-IDJ
|24 Feb, 2021 (Shift-I)] K.E. of
20. Electromagnetic radiation of wavelength 663 nm is just es
sufficient to ionise the atom of metal A. The ionization (a)
energy of metal A in kJ mol! is (Rounded-off to
the nearest integer) Energy of
[h=6.63 x104 Js, c= 3.00 x 10° ms, N, =6.02x 10 mol] Light
Number
|25 Feb, 2021 (Shift-II)] ofc s
21. A source of monochromatic radiation of wavelength (b)

400 nm provides 1000 J of energy in 10 seconds. When
Frequency of
this radiation falls on the surface of sodium, x x 10 Light
electrons are ejected per second. Assume that wavelength K.E. of
es
400 nm is sufficient for cjectionof electron from the surface
of sodium metal. The value of x is (Nearest (c)
integer) (h =6.626 x10"Js) |25 July, 2021 (Shift-I)]
22. The number of photons emitted by a monochromatic + Frequency of
Light
(single frequency) infrared range finder of power I mW K.E.of
and wavelength of 1000 nm, in 0.1second is x x103. The es
value ofx is (Nearest integer)
(d)
(h=6.63 x 1034 Js, c = 3.00 x 108 ms)
|27 July, 2021 (Shift-I)) + Intensity of
Light
23. When light of wavelength 248 nm falls on a metal of 28. What is the work function of the metal if the light of
threshold energy 3.0eV, the de-Broglie wavelength of emitted wavelength 4000 Agenerates photoelectrons of velocity
electrons is Å. (Round off to the nearest Integer). 6x 10° ms from it? |12 Jan, 2019 (Shift-1))
[Use: 3 =1.73, h=6.63 x 10 "Js (Mass of electron =9x 103 kg
m=9.1 x 103 kg:c=3.0 x 10 ms; leV= 1.6 x 10 1 J] Velocity of light = 3 x 10 ms
Planck's constant =6.626 x 10 Js
|16March, 2021(Shift-I)| Charge of electron =1.6 x 10" JeV ')
24. The work function of sodium metal is 4.4| x 10 J. (a) 0.9 eV (b) 3.l eV
If photons of wavelength 300 nm are incident on the (c) 2.I eV (d) 4.0 eV
metal, the kinetics energy of the ejected electrons will be 29. Consider a Helium (He) atom that absorbs a photon of
(h =6.63 x 10 4J s; c=3 x 10 m/s) x1021 J.
wavelength 330 nm. The change in the velocity (in cm s')
|2Sept, 2021 (Shift-I1)) of He atom after the photon absorption is
Structure of Atom 21
35. If wavelength of the first line of the Paschen
wavelengthserieofs theof
(Assume: Momentum is conserved when photon is
hydrogen atom is 720 nm, then the
absorbed). second line of this series is
Use: Planck constant 6.6 x10 4 Js, Avogadro number
integer)
nm. (Nearest
124 Jan, 2023 (Shift
=6 10' mol ', molar mass of He - 4g mol
JJEE Adv 2021| 36. Assume that the radius of the first Bohr orbit of
atom is 0.6 A. The radius of the third Bohr of orbit hydrogeN
He'i
Bohr's Modelfor Hydrogen Atom picometer. (Nearest Integer)
129 Jan, 2023
30. The shortest wavelength of hydrogen atom in Lymanseries 37. The electron in the nth orbit of Li?: is
(Shift-ID
is . The longest wavelength in Balmer series of He' is (n +) orbit using the radiation of energy 147 x 10
excited
|29 Jan, 2023 (Shift-)] (as shown in the diagram). The value of n is
5 92. Given R,, =2.18 x 10 J |10April, 2023 (Shift-I)
(a)
92.
(b) 5 -n+|
362. 52 1.47 x I0 17 J
(c) (d) 9
31. The radius of the 2nd orbit of Li?' is x. The expected radius n
of the 3rd orbit of Be is |25 Jan, 2023 (Shift-I)|
9 4 38. If the radius of the 3rd Bohr's orbit of hydrogenatom ist
(a) X (b) x9 andthe radius of 4h Bohr's orbit is r,. Then:
27 16 |26 June, 2022 (Shift-)]
(c) X (d) 9 16
16 27
32. Given below are two statements: (a) I,S (b) ,=G5
Statement-I: According to Bohr's model of hydrogen 3 4
atom, the angular momentum of an electron in a given
stationary state quantised.
Statement-I1: The concept of electron in Bohr's orbit, 39. When the excited electron of aHatom from n=5 drops to
violates the Heisenberg uncertainty principle. In the light the ground state, the maximum number of emission lines
of the above statements, choose the most appropriate observed are [25 July, 2022 (Shift-)
answer from the options given below: 40. !fthe wavelength for an electron emitted from H-atom is
|15April, 2023 (Shift-1)) 3.3 x 10 Om, then energy absorbed bythe electron in is
(a) Both Statement-Iand Statement-II are correct ground state compared to minimum energy required for
(b) Statement-I is correct but Statement-I| is incorrect its escape from the atom, is times. (Nearest
(c) Statement-I is incorrect but Statement-|is correct integer)
(d) Both Statement-I and Statement-IIare incorrect [Given:h=6.626 x 10 34 Js
33. The energy of an electron in the first Bohr orbit of Mass of electron =9.1 x 103 kg]
hydrogen atom is -2.18 × 10 J. Its energy in the third |28 July, 2022 (Shift-ID))
Bohr orbit is |13April, 2023 (Shift-I)| 41. The longest wavelength of light that can be used to
of this value
the ionization of lithium atom (Li) in its ground state
(a) (Nearest Integer)
27 Xx 10% m. The value of xis
(b) One third of this value [25 June, 2022 (Shift-D)
(c) Three times of this value 42. Given below are two statenments:
(d) of this value Statement-1: Bohr's theory accounts for the stab1lity
9 line spectrum of Li' ion.
34. If the radius of the first orbit ofhydrogen atom a, thende Statement-ll: Bohr's theory was unable to explan
Broglie's wavelength of electron in 3rd orbit is splitting of spectral lines in the presence of a magne
|6 April, 2023 (Shift-ID)| field.
choose the mos!
In the light of the above statements,
(a) (b) below:
6 3 appropriate answer from the options given (Shift-1)
(c) 6ta, (d) 3na, |18March, 2021

(a) Both statement-I and statement-II are true (a) Statement-Iis true but Statement-IIis false
(b) Statement-I is true but statement-II is false (b) Both Statement-I and Statement-II are false
(c) Both statement-I and statement-II are false (c) Both Statement-Iand Statement-II are true
(d) Statement-I is false but statement-Il is true (d) Statement-I is false but Statement-Il is true
43. Given below are two statements. 47. For the Balmer series in the spectrum of H atom,
Statement-I: According to Bohr's model of an atom,
qualitatively the magnitude of velocity of electron
v=Ru the correct statenments among () to
increases with decrease in positive charges on the nucleus (IV)are: [8 Jan, 2020 (Shift-I)|
as there is no strong hold on the electron by the nucleus. () As wavelength decreases, the lines in the series
Statement-II: According to Bohr's model of an atom, converge
qualitatively the magnitude of velocity of electron (lI) The integer n, is equal to n,
increases with decrease in principal quantum number. (III) The lines of longest wavelength corresponds to n, =3
[26 Aug, 2021 (Shift-I)) (IV) The ionization energy of hydrogen can be calculated
from wave number of these lines
In the light of the above statements, choose the most
appropriate answer from the options given below: (a) (l), (III), (IV) (b) (1), (II), (IV)
(a) Statement-Iis false but Statement-II is true (c) (),(I), (11) (a) (), (I),(1V)
(b) Statement-I is true but Statement-II is false 48. The radius of the second Bohr orbit, in terms of the Bohr
radius, a,, in Li is [8 Jan, 2020 (Shift-IID)
(c) Both Statement-Iand Statement-IIare true
(6) 2a0
(d) Both Statement-I and Statement-Ilare false 4a,
(a)
44. According to Bohr's atomic theory: 3
(24 Feb, 2021(Shift-I)] 2a, 4a,

(c) (d)
3 9
(A) Kineticenergy of electron is 49. The shortest wavelength of H
atom in the Lyman series
is ,. The longest wavelength in the Balmer Series of He
(B) The product of velocity (v) of electron and principal is: 14 Sept, 2020 (Shift-II)]
quantum number (n) 'vn' Z?
362.,
(C) Frequency of revolution of electron in an orbit is (a) (6)
z³ 92,
(c) (d) 272,
n' 5 5
(D) Coulombic force of attraction on the electron is 50. The ground state energy of hydrogen atom is -13.6 eV.
The energy of second excited state of He' ion eV is:
|10Jan, 2019 (Shift-ID)]
(a) -54.4 (b) -3.4
Choose the most appropriate answer from the options (c) -6.04 (d) -27.2
given below:
51. The ratio of the shortest wavelength of two spectral series
(a) (A) and (D) only (b) (A)only of hydrogen spectrum is found to be about 9. The spectral
(c) (A), (C) and (D) only (d) (C) only series are: [10 April, 2019 (Shift-II)|
45. The kinetic energy of an electron in the second Bohr orbit
(a) Paschen and Pfund (b) Lyman and Pasehen
h The value of 10x (c) Brackett and Pfund (d) Balmer and Brackett
of a hydrogen atom is equal to
xma, 52. Which one of the following about an electron occupying
is (a is radius of Bohr's orbit) (Nearest the sorbital in a hydrogen atom is incorrect? (The Bohr
integer) [Given : = 3.14] |27 Aug,2021 (Shift-I)| radius is represented by a) |9 April, 2019 (Shift-II)
46. Given below are two statements: (a) The electroncan be found at a distance 2a from the
nucleus
Statement-I: Rutherford's gold foil experiment cannot
explain the line spectrum of hydrogen atom. (b) The probability density of finding the electron is
maximum at the nucleus
Statement-II: Bohr's model of hydrogen atom contradicts (c) The magnitude of potentialenergy is double that of
Heisenberg'suncertainty principle. its kinetic energy onan average
In the light of the above statements, choose the most (d) The totalenergy of the electron is maximum when it
is at a distance a, from the nucleus
|27 July, 2021 (Shift-I))
Structure of Atom
53. For emission line of atomic hydrogen from n, =8 ton, 1, Comprehension (Q. 59to 60): Aswer the lollowi.
ive.
appropriately matching the lists based on the inloration
theplot of wave number (v) against willbe (The the paragrnph
Consider the Bohr's model of a one-clectron atom whete
Rydberg constant, R,, is in wave number unit): clectron moves around the nucleus. In the lollowing Listcontu.
|9 Jan, 2019 (Shift-1)] sOme quantities lor the nh orbit of the atomn and IList-1| contai
(a) Linear with intercept - R,(b) Non linear options showing how they depend on n. |JEE Adv201
(c) Linear with slope R, (d) Linear with slope - R, List-1 List-1|
54. For any given series of spectral lines of atomic hydrogen, () Radiusof the nh orbit. (P) n
let Av = V -V.min be the difference in maximumand
max
() Angular momentum of the (0) n!
minimum frequencies in cm, The ratio Av, Lyman |AVbalnver clectroninthe nh orbit.
is: 9 April, 2019 (Shift-1)| (||I) Kinctic energy of the clectron (R) n"
(a) 27:5 (6) 4: I in the nh orbit.
(c) 5:4 (d) 9:4 (IV) Potential energy of the (S) n'
clectron in the nh orbit. (T) n'
55. Heat treatment of muscular pain involves radiation of
wavelength of about 900 nm. Which spectral line of H (U) n2
atom is suitable for this purpose? 59. Which of the following options has the correct combinati
[R, =1 x 10° cm!, h =6.6 x 1034 Js, c = 3 x 10 ms-!] considering List-I and List-I1?
|11Jan, 2019 (Shift-I)) (a) (1), (R) (b) (), (P)
(a) Paschen, o’3 (b) Paschen, 5’3
(c) (), (T) (d) (I), (0)
(c) Balmer, oo’2 (d) Lyman, o ’1
60. Which of the following options has the correct combinatio
56. If the de-Brogile wavelength of the electron in nh Bohr orbit
considering List-I and List-I1?
in a hydrogenic atom is equal to 1.5ra, (a, is Bohr radius),
then the value of n/z is: [12 Jan, 2019 (Shift-II)] (a) (||I), (S) (b) (IV), (Q)
(a) 0.40 (b) 1.50 (c) (IV), (U) (d) (),(P)
(c) 1.0 (d) 0.75
57. For He, a transition takes place from the orbit of radius Towards Quantum Mechanical
105.8 pm to the orbit of radius26.45 pm. The wavelength
(in nm)of the emitted photon during the transition is Model of the Atom
[Use:
Bohr radius, a =52.9 pm
Rydberg constant, R, =2.2 x 10-18 J 61. The wave function () of 2s is given by
Planck's constant, h = 6.6 x 10-34 Js
Speed of light, c =3 x 10 ms] (JEE Adv 2023|
58. The figure below the plot of potential energy' versus
internuclear distance (d) of H, molecule in the electronic Atr=, radial node is formed. Thus,r, in terms of a,
|30 Jan, 2023 (Shift-1)
ground state.What is the value of the net potential energy
E, (as indicated in the figure) in kJ mol", for d-d, at (a) r, = 2 (b) r, =4a,
which the electron-electron repulsion and the nucleus
nucleus repulsion energies are absent? As reference, (c) , = (d) r, =2a,
2
the potential energy of H atom is taken as zero when its
electron and the nucleus are infinitely far apart. 62. Ifthe uncertainty in velocity and position ofa minute particl
Use Avogadro constant as 6.023 x 1025 mol-. in space are: 2.4 x l0 2(ms )and 10 (m) respectively. 1h
mass of the particle in g is (nearest integer
|JEE Adv 2020]
(Given:h = 6.626 xl0 "Js) |27 June, 2022 (Shift-[)
Potential
Energy
63. The wavelength of an electron and a neutron will becon
mol)
kJ HH equal when the velocity of the clectron is x times th
E velocity of neutron. The value ofx is
(Nearest Integer)
do+ (Mass ol electron is 9.| x 10 "kg and mass of neutron
(Shift-)
Internuclear distance (d)> 1.6x10 2" kg) |26 July, 2022

64. The minimum uncertainty in the speed of an electron in 72. The number of correct statements from the following
an one dimensional region of length 2ao (Where ao = Bohr
radius 52.9 pm)is kms |11April, 2023 (Shift-ID|
(Given: Mass of electron =9.1x10" kg, Planck's constant, (a) For isorbital, the probability density is maximum at
the nucleus.
h=6.63x10"Js) [29 July, 2022 (Shift-1))
65. An accelerated electron has speed of 5 x 10° ms with (b) For 2s orbital, the probability density first increases
to maximum and then decreases sharply to zero.
an uncertainty of 0.02%. The uncertainty in finding its
location while in motion is xx 10m. The value ofx is (c) Boundary surface diagrams of the orbitals encloses
(Nearest integer) aregion of 100% probability of finding the electron.
[Use mass of electron =9.1 x10 kg, h=6.63 x 10-4 Js, (d) pand d-orbitals have I and 2angular nodes respectively.
n=3.14 [25 July, 2021 (Shift-I)) (e) Probability density of p-orbital is zero at the nucleus.
66. The de Broglie wavelength of an electron in the 4h Bohr 73. The orbital angular momentum of an electron in 3s orbital
orbit is: [9 Jan, 2020 (Shift-I)) xh
is The value of .x is [13 April, 2023 (Shift-I)]
(a) 6na, (b) 4na, 2T
(c) 2a, (d) 8na, 74. The number of radial and angular nodes in 4d orbital are,
67. The de-Broglie wavelength () associated with a respectively [26 June, 2022 (Shift-II)]
photoelectron varies with the frequency (v) of the incident (a) land 2 (b) 3 and 2
radiation as [v, is threshold frequency]: (c) 1and 0 (d) 2 and 1
[11Jan, 2019 (Shift-ID)) 75. The correct decreasing order of energy for the orbitals
1
having, following set of quantum numbers:
1
(a) c (27 July, 2022 (Shift-II))
(v-vo) (v-v,)i (A) n=3, l=0, m =0 (B) n=4, l=0, m = 0
(C) n=3, l= 1, m =0 (D) n=3, l = 2, m =1
1 1
(c) (a) (a) (D) > (B) > (C) > (A) (b) (B) > (D) > (C) > (A)
(v-v,)? (v-v,): (c) (C)> (B) > (D) > (A) (d) (B) > (C) > (D) > (A)
76. Identify the incorrect statement from the following.
[28 July, 2022 (Shift-)]
Quantum Mechanical (a) A circular path around the nucleus in which an
Model of the Atom electron moves is proposed as Bohr's orbit.
(b) Anorbital is the one electron wave function (w) in
an atom.
68. Maximum number of electrons that can be accommodated (c) The existence of Bohr's orbits is supported by
in shell with n = 4 are: |30 Jan, 2023 (Shift-II)] hydrogen spectrum
(a) 16 (b) 32 (d) Atomic orbital is characterised by the quantum
(c) 50 (d) 72 numbersn and l only.
69. Arrange the following orbitals in decreasing order of 77. Given below are two statements : One is labelled as
energy? |31 Jan, 2023 (Shift-II)] Assertion (A) and the other is labelled as Reason (R):
(A) n=3, 1 = 0, m =0 (B) n =4, 1=0, m=0 Assertion (A): Zero orbital overlap is an out of phase
(C) n=3, I = 1, m=0 (D) n= 3, I=2, m=1 overlap.
The correct option for the order is: Reason (R): It results due to different orientation/ direction
(a) B>D>C>A (b) D> B>C>A of approach of orbitals. |28 July,2022 (Shift-))
(c) A>C>B> D (d) D>B>A> C In the light of the above statements, choose the correct
answer from the options given below
70. The number of given orbitals which have electron density
along the axis is (a) Both Aand Rare true and R is the corect explanation
ofA
P, Py P, d, d,, d,,dz. d2 |25 Jan,2023 (Shift-ID (b) Both Aare R are true but R is NOT the correct
71. The number of atomic orbitals from the following having explanation of A
5 radial nodes is
(c) A is true but R is false
7s, 7p, 6s, 8p, 8d 8April, 2023 (Shift-I)) (d) A is false butRis true
78. Consider the following pairs of electrons 81. Which of the following sets of quantum numbers
|24 June, 2022 (Shift-1))
allowed? 125 July, 2022 (Shift
(a) n=3, I =2, m, =0, s = +
(A) (a) n=3,/= l, m/=1, m =
(b) n=3, |= 2, m, =-2, s= t
2
(b) n = 3, I= 2, ml =1, m,
(c) n=3, | =3, m, =-3, s = -
2
(B) (a)n=3, 7=2, m/ =-2, m=
(d) n=3, | = 0, m, =0, s= 2
(b) n =3, 7=2, ml =-1, m,
2 82. Given below are the quantum numbers for 4 electrons
[29 July, 2022 (Shift
(C) (a)n=4,7=2, ml=2, m=+,
2 (A) n=3, =2, m, =1, m, = +1/2
(B) n=4, l =1, m, =0, m, = +1/2
(b) n=3, /=2, ml=-2, m, = 2 (C) n=4, l=2, m, =-2, m, =-1/2
(D) n=3, = 1, m, =-1, m, = +1/2
The pairs of electrons present in degenerate orbitals is/are:
The correct order of increasing energy is
(a) Only (A) (b) Only (B)
(a) (D) <(B) < (A)<(C)
(c) Only (C) (d) (B) and (C)
79. Consider the following statements :
(6) (D) <(A) < (B) < (C)
(c) (B) < (D) < (A)<(C)
(28 June, 2022 (Shift-II)]
(a) (B) < (D) <(C) < (A)
(A) The principal quantum number 'n' is a positive 83. Given below are two statements. One is labelled a
integer with values of 'n'= 1, 2, 3, ...
Assertion (A) and the other is labelled as Reason (R).
(B) The azimuthal quantum number P for a given 'n'
(principal quantum number) can have values as Assertion (A): Energy of 2s orbital of hydrogen atomi
greater than that of 2s orbital of lithium.
T= 0, 1, 2, ... n
(C) Magnetic orbital quantum number 'm/ 'for a Reason (R): Energies of the orbitals in the same subshel
decrease with increase in the atomic number.
particular T (azimuthal quantum number) has (2/ +
l)values. |27 July, 2022 (Shift-)
(D) +1/2 are the two possible orientations of electron spin. In the light of the above statements, choose the corred
(E) For /=5,there willbe a totalof9 orbital answer from the options given below:
Which of the above statements are correct ? (a) BothAand Rare true and R is the correct explanatd
ofA.
(a) (A), (B) and (C) (b) (A),(C), (D) and (E) (b) Both A and are true and R is NOT the core
(c) (A), (C) and (D) (a) (A), (B), (C) and (D) explanation of A.
80. Which of the foHowing is the correct plot for the probability (c) A is true but R is false
density yr) as afunction of distance 'r' of the electron from (d) A js false but R is true.
the nucleus for 2s orbital? |29 June, 2022 (Shift-I))
84. Consider the follow ing set of quantum numbers.
|27 July, 2022(Shift-l)
(a) (b) w'r)) n
m,
A. 3 3 -3
B. 3 -2
(r)’ (r) ’
C. 2 +|
D. 2 2 +2
The number of correct sets of quantum numbers 1S
(c) v') (d) v'
va
85. The Plots of radial distribution functions forbelow:
given
orbitals of hydrogen atom against 'r are (Shift-l)
()’ |25 Feb, 2021

91. Consider the hypothetical situation where the azimuthal
AR0)
8 quantum number, /, takes values 0, 1, 2,. . +1, where
n is the principalquantum number. Then, the element with
[3 Sept, 2020 (Shift-ID)
A
(A) atomic number:
(a) 9 is the first alkali metal
0 10 (b) 8 is the first noble gas
r(A) (c) 13 has a half-filled valence subshellI
(d) 6 has a 2p-valence subshell
3 92. The correct statement about probability density (except
at infinite distance from nucleus) is:
(B) |5 Sept, 2020 (Shift-ID)
10 (a) Itcan be zero for 3p orbital
r() (b) It can be zero for ls orbital
(c) Itcan be zero for 2p orbital
4rR) 3
(d) It can be zero for 2s orbital
quantum number
93. The number of orbitals associated with
(C) n=5,m=+% is [7Jan, 2020 (Shift-)]
10 (a) 15 (b) 11
r(A) (c) 50 (d) 25
quantum
94. The figure that is not a direct manifestation of the
4rR)
2.0
nature of atoms is: [2 Sept, 2020 (Shift-)]
(a) ’Increasing wavelength
1.5
(D) 1.0
10 Absorptionspectrum
r(A)
Rb K Na
The correct plot for 3s orbital is: (b)
Kinetic
(a) (D) (b) (B) energy of
(c) (A) (a) (C) photoelectrons
angular nodes and two radial
86. A certain orbital has no Frequency of incident
nodes. The orbital is: [18 March, 2021(Shift-D)] radiation
(a) 3s (b) 3p T,
(c)
(c) 2s (d) 2p
as well as two angular nodes Intensity of
87. The orbital having two radial (26 Feb, 2021 (Shift-I)] black body
radiation T
is:
(a) 4d (b) 5d
Wavelength
(c) 4f (d) 3p
of
n=4 and m, =-3. The number (d)
88. Acertain orbital has (Round off to Internal
is
radial nodes in this orbital Energy
the nearest integer). (17 March,2021(Shift-I)) of
AI 300 400 500 600
with n = 5, m, = +2 is
89. The number of orbitals Temperature (K)
(Round off to the nearest integer). the orbitals that are filled
are:
|16 March, 2021 (Shift-II)) 95. In the sixth period, (Shift-I))
with n =4 and m=-2 (5 Sept, 2020
subshells associated
90. The number of
quantum numbers is: [2Sept, 2020 (Shift-I)) (a) 6s, 5f, 6d, 6p
(b) 6s, 6p, 6d, 6f
(d) 6s, 5d, 5f, 6p
(a) 2 (b) 16 (c) 6s,4f, 5d, óp
(d) 4 Structure of Atom 27
(c) 8
101. Which of the following combination off statements is tn
96. The size of the isoelectronic species C1-, Ar and Ca'* is
affected by: [8 April, 2019 (Shift-I)) regarding the interpretation of the atomic orbitale?
(A) An electron in an orbital of high angular
(a) Principal quantum number of valence shell.
(6) Nuclear charge.
stays away from the nucleus
than an momentu
electron in the
orbitalof lower angular momentum.
(c) Azimuthal quantum number of valence shell.
(B) For a given value of the principal quantum
(d) Electron-electron interaction in the outer orbitals. the size of the orbit is inversely proportionalnumbe
to
97. The 71" electron of an element Xwith an atomic number azimuthal quantum number.
of 71 enters in to the orbital: |10 Jan, 2019 (Shift-II)] (C) According to wave mechanics, the ground st
(a) 6p (b) 4f h
angular momentum is equal to
(c) Sd (d) 6s 2
98. The graph between w and r (radial distance) is shown (D) The plot of (y) Vs (r) for various azimuthal quante
below. This represents: [10April, 2019 (Shift-1)] numbers, shows peak shifting towards higher r val
19 Jan, 2019 (Shift-In
(a) (A), (D) (b) (A), (B)
(c) (A),(C) (a) (B), (C)
102. The quantum number of four electrons are given below
(8 April, 2019 (Shift-)
1
(I) n=4, I= 2, m,=-2, m, =
1
(a) 3s orbital (b) 1sorbital (II) n=3, I= 2, m,= 1, m = t
2
(c) 2p orbital (d) 2s orbital
99. The electrons are more likely to be found: 1
(II) n=4,l= 1, m,=0, m= 2,
[12 April, 2019 (Shift-)]
(IV) n= 3, l=1, m,= 1, m, =

+ (x)
B The Correct order of their increasing energies willbe:
(a) IV < III <I <I (b) IV < || <II| <I
(c) I< II < II < IV (d) I< II <II <IV
103. The ground state energy of hydrogen atom is -13.6 e
Consider an electronic state y of He* whose energ
azimuthal quantum number and magnetic quantut
(a) In the region (A) and (B) number are -3.4 eV, 2 and0 respectively. Which of th
(b) In the region (A) and (C) following statement(s) is(are) true for the state ñ?
(c) Only in the region (C) JJEE Ady 2019
(d) Only in the region (A) (a) It has 2 angular nodes
(b) It has 3 radial nodes
100. Among the following the energy of 2s orbital is lowest in:
(c) It is a 4d state
|12 April, 2019 (Shift-II))
(a) K (a) The nuclear charge experienced by the electron I
(b) Na
this state is less than 2e, where e is the magnitude o
(c) H (d) Li the electronic charge

ANSWER KEY
1. (d) 2. [2] 3. [4] 4. (d) 5. (b) 6. (b) 7. [7] 8. [0] 9. (2] 10. [1]
11. (3] 12. [798] 13. (c) 14. [300] 15. (c) 16. [6] 17. (5] 18. (2] 19. [2] 20. [181]
21. [2] 22. [50] 23. [9] 24. [222] 25. (b) 26. (d) 27. (c) 28. (c) 29. [30] 30. (b)
31. (c) 32. (a) 33. (d) 34. (c) 35. [492] 36. [270] 37. [1] 38. (b) 39. [10] 40. (2]
41. (*] 42. (d) 43. (a) 44. (a) 45. [3155] 46. (c) 47. (c) 48. (a) 49. (c) 50. (c)
51. (b) 52. (d) 53. (d) 54. (d) 55. (a) 56. (d) 57. [30] 58. (-5246.49] 59. (c)
60. (d) 61. (d) 62. [22] 63. [1758] 64. [548] 65. (58] 66. (d) 67. (d) 68. (b) 69. (b)
70. [S.00] 71. [3] 72. [3] 73. [0] 74. (a) 75. (a) 76. (d) 77. (a) 78. (b) 79. (c)
80. (b) 81. (c) 82. (b) 83. (a) 84. (2] 85. (a) 86. (a) 87. (b) 88. [(0] 89. (3]
90. (a) 91. (c) 92. (a) 93. (d) 94. (c) 95. (c) 96. (b) 97. (c) 98. (d) 99. (b)
100. (a) 101. (c) 102. (b) 103. (a,c)
EXPLANATIONS
1. (d) Loss of electron from hydrogen atom results in H+ 6. (b) Photoelectric effect is the ejection of electron from
ion. Due to extremely small in size it does not exist the metal surface when beam of suitable frequency
freely. Hence, both Aand R are correct but R is not strike on it. There will be minimum frequency v,
the correct explanation of A. (Threshold frequency) below which photoelectric
2. [2] (a) V, =1000 m/s ; h=6x 104 Js; effect is not observed.
m=9 x 10-3 kg The ejected electrons leave with a specific amount of
6x]0-34 kinetic energy at a frequency v >V, with an increase in
= 666.67x10m light frequency ofthese electron kinetic energies also rise.
my 9x10x1000
7. [7] Acc. to De- Broglie
= 666.67 nm
h h 6.6x 10-4
(b) The characteristic of electrons emitted is
independent of the material of the electrodes of mv V2mKE N2x9x10-x4.5x10
the cathode ray tube. 6.6x 10-34
(c) The cathode rays start from cathode and move V9² x10-0
towards anode.
6.6x1034 6.6 x104
(d) The nature ofthe emitted electrons is independent 0.733 x 10+
9x10-30
on the nature of the gas present in cathode ray
tube. =7.3 x 105 m
3. [4] In the imaginary ion, 8. [0] Ablackbody can emit and absorb all the wavelengths
X Number of neutrons=48- 22 = 26 inelectromagnetic spectrum > (A) is correct
Number of electrons = 22+3=25
26-25 T,
% of extra electrons = x100 = 4% T,>T,
25
4. (d) On passing alpha particles through the gold foil, they Intensity
get deflected because according to Thompson model,
T
positive charge is dispersed throughout the atom. Also,
due to repulsion from protons, their speed decreases. Frequency
5. (b) Statement givenin optionb is not proposed by Dalton. > (B), (C), (D) correct
9. |2] The spectrum of Black body radiation is explained 2=0.614 x 10! m
by the phenomenon quantization of energy. With 2=6.14 x 1012 m
increase in temperature, pcak of spectrum get shifted 17. [5] In photoelectric effect;
[Nearest integer
to shorter wavelength or higher frequency. For above hc 1
graph; the correct order is -> T, >T, >T, >T, = hv +my
2
10. [1) The cmission spectra of' atoms in the gas phase, on h =6.63 x 10-34 Js,
Given:
the other hand, do not shows a continuous as all of
m =9.0 x 10 kg
wavelengths of the visible light. 2= 500 x 10° m
Statement (B) is incorrect. = 4.3 x 10!4 Hz
1240
11. (3] E(eV) =- -3.leV 6.63x1034 x3x108
400 = (6.63 x 10" x 4.3 x 104
500x 10-9
Mg,Cu, Ag
12. [798] For one photon E = hv x 9.0 x 10-1 x
2
For one mole photon, 3.978 x 10-19 =2.85 x 10-19+4.5 x 10- x y²
E=6.023 x 102 x 6.626 x 1034 x 2 x 10!2
(3.978x 10 -19 -2.85x 10-)
=798.16J 798J V=
4.5x10-3I -25x1o9
ho
13. (c) The formula to calculate energy for I photon = =5 x 10 m/s
ho 18. (2] Power = 50 watt = 50 J/sec
Energy of lmole of photon = N, Energy emitted per second = 50J
6.022 x10 x6.63 x104 x3x1O Wavelength ; . = 795nm
300x109
The formula to calculate energy (E) is:
hc
= 0.399 x 10 J = 399 kJ Energy of one photon =
14.[300]Given: Work function, w,=6.63 x10-9 J 6.63x 10x3x10
Threshold wavelength, A,=? 795x 109
hc =0.025 x 10-7 J
Using;W= nNo n 50
hc Number of photons emitted per second =
or, 0 = 0.025x10
Wo =2 x 1020
on substituting values, 19. [2] The formula to calcular 2 is:
6.63 x103 x3x10° m d=
6.63 x10-19 V2qVm
-3 x 10'm For Li,
=300 x 10 m= 300nm
Mi
15. (c) The minimum energy possessed by the photons will W2x3exVx8.3m
beequal to the work function of the metal. For p,
, =hv,
= 6.6 x 1034 x 1.3 x 10'5J W2xexVxm
= 8.58 x 10-19 J Ratio is:
16. [6] The formula to calculate in terms of potential
difference is: 2eVm
h V2x24.9eVm
=
J2xmxqx V =0.2 = 2 x10-!

6.63 x 1o34
20. [181]The formula tocalculate energy (E) is:
m hc 6.63 x10x3x10
E=
2x9.1x 10"xL.6x 10"x 40000 663x10

=0,03 x 10-7 =3.0 x 10-19 J/atom
= (3.0 x 10-19 x 6.02 x 1023 x (K.E.) = E- E,
103) kJ/mol hc
= 18.06 x10' kJ/mole = 180.6 ~
21. (2] .:. E=E, +K.E
181 kJ/mole .-E
2=400 nm is sufficient to eject electron 6.63 x10" Js x3x 10 ms
- 4.41 x 10 J
Energy can be calculated as: 300 x10m
hc 6.626x1034 x3x108 = 2.22 x 10-19J
E= E, =
400 x109 = 222 x 102"J
6.626x3 x10-34+1S) 25. (b) According to the electromagnetic
4
spectrum, balmer
series appears in the visible region.
= 4.965 x10-19J 26. (d) hv-= KE
100
Number of e ejected = =20.14x 10!9 hc
= KE +
4.965 x 10-19
incident
=2.01 x 1020
hc
22. (50] Energy of emitted photon in 0.1sec = 0. 1sx 10³ Js! KE
=104 Js! incident
Given: = 1000 nm =10³ x 10- m= 106 m p' hc hc

KE =
hc 2m ...i)
nx = 10 Aincident
p'x(1.3) hc
.(ii)
nx6.63x104x3x108 = 104 2m
10
divide (i) and (ii)
n=5.02 x10!4 =50.2 x 1013 50 x 1015
42
23. [91 We know that, (1.5)? =
9
K.E.- ¢- , 27. (c) K.E= hy-hv,, so (c) is not correct.
Given, 28. (c) hv = +hv,
, =3eV=3 x1.6 x10-19J =4,8 x 10-19J
(:: lev = 1.6 x 10-19)
Lmv'
2
=
=248nm = 248 x 10m 1
Also, hv = + 2 mv²
hc 6.63x10-34 x3x108 6.626x 10- x3x10 1
248 x109
-J=0.08 x 10-!7J=8 x 10-19J =
4000 ×10-10 2
x9x10 x(6x10')
(::h=6.63 x10-34Js
c=3x 10 ms-) =3.35x10"J ’ = 2.1 eV
Thus, K.E =8 x 10-19 4.8 x 10-19 =3.2 x 10-19J h
29. [30] =
m(Av)
Using,
6.6x1034
2= 330×10=
V2K.Em 4x10-3
XAy
On substituting values, 6x1023
6.63 x10 34 6.63x10-34 6.6x6x103 x10 34
m = Ay 30 cm/s
V2x3.2x10-1 x9.1x1031 7.63x10-25 4x10x330×10-9
= 0.87 x 10m =8.7 Å =9 Å 30. (b) The formula used for the determination of is
24. (222]E, =4.41 x 1019J
2=300 x 10 m n
Ihere, n is initialortit n, is tinal orbit
.()
(2),
1
RZ5 16.
..(i) (a,)
7
(a,) 16x9 25x7
16 16x16
(2)
25×9
25x7
-x 720
16x16
(^,), = 492 nm
31. () Bet n'
36. [270] rc Z
,-y=kx
4 Given: r, =0.6 A
n=3 (For 3rdorbit)
27
4 4
=
l6
y= 16
z=2
32. («) Aconding to Bohr's model the angular momentum n

7
nh
is quantised and equal to
nh
2T Ve 0.6x3) -=2.7Å
2
Het270 pm
Heisenberg uncertainty principle explains orbital
1 1
concept, and itexplain we can't determine the position 37. [1] AE = RyZ'|
and momentum of the electron simultaneously while
acc to Bohr's model the electrons are assumed to
move in a welldefined orbits with quantised angular For Li, Z=3, n, = n, n, =nt1
momentum. Given: AE: 1.47 x 10-" J,R,, =2.18 x 10-18 J
33. () The energy of an electron in the Bohr orbit of
1.47 x10-17 = 2.18 x 10-18 x 9
hydrogen atom is calculated using the formula, n (n +1)
-2.18x10lSz2 1.47 3 1
E, = 1.96 4
n' n' (n+1)
For n=1 On solving, n = 1
38. (b) Radius of Bohr's orbit for hydrogen, R =0.529A xI
E, =-2.18 x 108 (Given)
for n = 3 Forthird orbit (R,) =0.529Å x9=r,
-2.18x10-I8 Fourth orbit (R,) = 0.529A x 16 =r,
E, = 0.529Å x9 l6r,
34. (c) From formula of Bohr's radius 0529Åx 16 t, 9
a,n' 39. [10] For single H- atom, maximum number of spectL
(6),= = a,, x3 x =9a,
lines n(n -l) 5(5-1) =10, n = orbit number
By De-Broglie Principle 2 2
2r = n excited electron.
= 32
40. (2] A= Here, E = Kinetic Energy
’)=6ta,
35. [492] For first line of paschen series n = 4 and for
V2mE
the
second line n = 5 E=
2ma
(6.626x 104)? 46. (c) Hydrogen spectrum is explained by Bohr's atomic
model and from Bohr's atomic model, uncertainity
2x9.1x10x(3.3x1010)?
= 2.215 x 10-18 principle can't be explained.
Eahsorhd = Ereguired + K.E 47. (c) The wave length/wave number of light emitted/
E 'absorbed K.E absorbed is calculated by Rydberg's formula. It is
=1+ expressed as,
Erequired
2.215x10-18
Erequired V== Rz
=1+ 10-l92.016 2
13.6x1,602 y
41. [*] Bohr's model is only applicable for H-like species. For H atom z = 1
Hence, the value of x can't be determined.
42. (d) Bohr's theory is applicable only for the line spectrum v=R
of single electron species, but Li' has two electrons.
Bohr's theory fails to explain splitting of spectral For Balmer series: n, =2
lines in presence of magnetic field i.e. Zeeman effect.
43. (a) According to Bohr's model,velocity of an electron Ifn, =3 - R4
increases with atomic number (z) and decreases 9
with number of shell (n) that is, V, «(z=

Z
Atomic =R
36
number and n = number of shell/ principal quantum
1 36
number)
5R
44. (a) According to Bohr's theory, max
z? n
K.E. = 13.6
n2 48. (a) As, r= a,x
Z
V=2.18 x 106
For IInd Bohr orbit of Li? (n =2,Z =3)
kqj42 kZe n2 a, x4 4a,

F= 3
Z
49. (c) For H-atom;
So according to the above expression,
For Lyman series: n, = 1&n, =0
1
F«
n*
Hence, (A) and (D) are correct.
---
For He ion;
So, =
RH
45. (3155]
For Balmer series:n,=2&n, =3
n'h?
K.E = (Bohr's kinetic energy)
8mr
for n=2, we have
5
4h =R, x4x
K.E = ((.:r=4a,) 36
8r'm(4a,)'
4 h?
8 x16) ma,2
--R
1 h
KE =
32T ma, (:r=4a,)
h
On comparing with (given) 50. (c) E--13.6-eV
Xma,
x=32r=315.50
Ej =-13.6 -6.04 eV
’10x = 3155 9
1
= R,
1
AV almer
R
4
5R1
36
4R
36
R
n
51. (b) n
1
AVyman
Av, R9
9
mí Balmer
as for shortest wavelengths both n, and m, are o 55. (a) [i]Given: 900 nm =9000A
9 m; It is in far infra red region, therefore Paschen
1 n 56. (d) 2r=nà.
Now if m, = 3& n, = l it will justify the statement =
2Tr 2rn'a, n
hence Lyman and Paschen (b) is corrcct. n nxZ

52. (d) v' =1.5 Ta,
n
Z,2, =1.5ra,
s|N n 1.5
-=0.75
2
57. [30] As we know that, for a singleelectron system.we ha
r= 52,9x 2 Pm
n'
Given Z=2 for He

r, = 105.8 ppm
+r
Thus, 105.8 =
2
2a, n, =2
53. (d) For emission line r, = 26.45
n,<n,
So 26.45= 52.9x"
2
..v= RZ? n, =1
Hence, transition is from 2 to 1.
or, v = R R Rå hc
64 n As
2
= R,Z?
V=-R, R 64
On solving,
58. [-5246.49]
=30 × 10 m=30 nm
y= mX tc
Slope =-R At d= d,, nucleus-nucleus & electron-electro
54. (d) For Lyman repulsion is absent.
Hence potential energy will be calculated for 2
max atoms. (P.E. due to attraction of proton & electron
Av,Lyman R
4
For Balmer
P.E, = -Kq4: (ox10)(1.6x10
0.529 x100
") =-4.355x10"KJ
(Bohr radius)
For I mol =-4.355 x 102 x 6.023 x 10

=-2623.249 kJ/mol
For 2H atoms =-5246.49 kJ/mol
n Av= 5x10 x-0.02 = 5x 2x 10 = 1000m /s
59. (c) r=0.529 x ’rcn' ’ ()(T) 100
nh 6.63 x 1034
m
myr (mrv) «n ’(II) (S) 4x3.14x9.1x 10-5 x 1000
2T
KE = + 13.6 x
z = 5.8 x 108 m = 58 x 10 m
n
> KE «n² >(III)(P)
n
z? 66. (d) As, n = 4&r=a,,
PE = - 2 x 13.6 x ’ PE n? ’ (IV) (P)
n2
n?
60. (d) Conceptual :. 2ra, = nâ (: 2r = n2.)
7
61. (d) At node Y, =0
4° a, = 4h =8ta,.
2 =0 2r
..I, = 2a,
67. (d) =
Hence, option (d) is the correct answer. mv
62. [22] AV= 2.4x 1026 m /sec According to Einstein's theory of photoelectriceffect:
And Ax= 10 m hy = hv, + KE
1
According to Heisenberg's uncertainty principle, hy =hv,2-mv²
h
Ax Ap 2h(v - v,)=my²
4T
Ax - mAv =
h 2h(v- Vo=v
4n
6.626x 10-34 6.626 x 10-!
vc (v- v,)le
. m
4X Avx Ax 4x3.14x2,4x10-2 x10-7 30.144 h
m =22 m(v- v,y2
63. [1758] X,-X, 1
’MV =M,V, n n
(v-V,)2
M, 1.6x10-27
9.1x10-T1758.24
V. M, 68. (b) The maximum number of electrons that can be
accommodated in shell with n = 4 can be calculated
64. [548]According to Heisenberg's uncertainty principle, we using the formula 2n'
have Thus, Number of electrons = 2(4) =32
Ax x Ap =4T 69. (b) (A) n=3; 1= 0; m=0;3s orbital
(B) n=4;1=0; m=0;4s orbital
h
Or Ax x Av = (C) n=3; I=1; m=0;3p orbital
4TX m (D) n=3; 1=2; m=0;3d orbital
Given: h=6.63 x 10-34 J/s, m =9.1 x 103l kg Higher the value of (n + 1), higher will be the energy.
6.63 x10-34 For the same values of (n + I), higher value of n will
. .Av = be higher inenergy.
4x3.14x 2x52.9x10-12 x9, 1lx103!
= 548273 m/s
70. (5.00lp,, P,, P, d, & d:2 are axial orbitals.
71. [31 Radial node is calculated by the formula n -l-1.
Or Av = 548 km sec For 7s =R.N=7-0-1 =6
65. [58] By using Heisenberg uncertainty principle: For 7p = R.N=7- 1-|=5
h For 6s R.N=6 0-1 =5
Ax " Ap = R.N =8-1-1 =6
4 For 8p
For &d R.N =8-2-l=5
Ax Av= For 7p, 6s and 8d the value of radial node is same i.e. 5.
4Tm
72. [3] A, Dand E statements are The azimuthal quantum number / can
correct have Val
).1, 2....., nI
The magnctic quantum number can have valueg =)1,
The values of spinquantum number, m, are
2
The number of orbitals for particular value of
2/+1,thus for /=5,n0, of orbitals =2(5+l) = ||
For 2s orbital, the probability density first decreases
and then increases. Angular nodes for p and d-orbitals
80. (b) For 2s, the number of radial nodes =n -l-14
is 1and 2.
-0-| = 1, and y(r) will always be positive. Hen
At any distance fronm nucleus the probability density option (6) is correct,since it hasone radial node and
is +ve.
of finding electron is never zero and it always have
some finite value 81. (c) Value of n&I can'tbe same. Iis always less than
82. (b) Rule of (n+ ) determines the sequence of sub enen
73. [0] Orbital angular momentum level. The one with more (n +) value has mo
energy.And in case if (n + ) value is same, then t
On comparing the formula of orbital angular one with more 'n' value has more energy.
momentum given above with the value given in 83. (a) Energy of orbitals in same subshell decrease witha
question, weget x=Ji(+) increase in the atomic number.
The value of /for s =0 84. [2] Conditions: For a valid set of quantum numben
Therefore, the value of x will be zero. following conditions needs to be satisfied.
74. (a) In 4d orbital , n = 4 and = 2 |=0to n- 1, m, = to +1
Radial nodes =n-l-1,42-1=1 A.. n=3 |=3 m, =-3 is incorrect as I can noth
And angular nodes ,l=2 equalton.
75. (a) For (A) n+l=3 B. n=3 |=2 m, =-2 is correct set.
(B) n + =4 C. n=2 l=1 m, =+1 is correct set
(C)n+ =4 D. n=2 1=2 m,=+2 is incorrect set asl can o
(D) n +=5 be equal to n.
Energyof the orbitals is directly proportional to the So, B and Care the correct set of
(n+) value. Higher (n +) valued orbital will have quantum numbers
85. (a) Number of radial nodes of 3s
higher energy. If n+l is same, then higher the value orbital are:
of n, higher is the energy. (.:.
D>B>C>A) =n-l-|=3-0-|=2
76. (d) An atomic orbital is 86. (a) Total Node =n-1
numberS: n, / and m.
characterised by three quantum
Radial Node = n-l-1
Angular Node :
77. (a) Here, is Azimuthal Quantum number
Here, Angular node =0
P ’l=0ie sorbital
Zero overlapping is present due to improper Radial nodes = 2
orientation
’n-l-1 =2
Zero overlapping n-0-| =2’n=3
Hence, orbital is 3s
78. (b) Degenerate orbitals must have same energy. 87. (b) Radial node
=n-(-1 for 5d, 5-2-1 =2
Orbitals with same values of n and /are degenerate Angular node = for d-orbital, =2
orbitals.
88. [0] For n =4, l=0, 1,2, 3
79. (c) The principal quantum number, ncan
have values For =3 and m =-3
=1,2,3, ......
Radial nodes = (n - |- 1)=
36 JEE PYQSs Chemistry (4-3-1)=0
89. (3] When n =5and m, =+2, also l can have values from n=5 m ’ - lto +/
0to (n - 1) and m, = -to +l |=n-1 ’0 ’ 0
l=0, m, =0 = 4 ’1’-1, 0, 1
l=1 m, =-1, 0, +1 ’2 ’-2,-1, 0, 1, 2
(=2 m, =-2, -1,0, +1, (+2) (0, 1, 2, 3) ’3’-3, -2, -1, 0, 1,2
l=3 m, =-3,-2, -1,0, +1, (+2), +3 ’4-4, -3, -2,1, 0, 1,2, 3,4
l=4 m, =4,-3, -2, -1, 0, +1, (+2), +3, +4 Total 25 orbitals are possible.
Thus, the number of orbital with n=5 and m, = +2 94. (c) Figures A, Band Dare according toquantum theory
are 3. but figure C belongs kinetic theory of gases.
90. (a) For aprincipal quantum number n=4, possible value 95. (c) A
ccording toAufbau's principal, the electrons are
of /= 0, 1,2, 3. Because for anyn value, l =0 to n- 1, filled in increasing energy of atomic orbitals. For
only / = 2 & l= 3 can have m =- 2. So, possible sixth period element,the correct order is:
6s < 4f < 5d < 6p
subshells are 2. Because for any value of I, m will
have values from - to + 1. 96. (b) For isoelectronic species, the size is compared by
nuclear charge.
91. (c) For n= 1, 7= 0, 1,2
For n = 2, I will be 0, 1, 2,3
97. (c) The electron configuration is [Xe]4f4 5d' 6s?
98. (d) Graph of lu? v/s r touches r axis at I point so it has
Electronic configuration of element is: one radial node and since at r = 0, has somne value
ls lp ld 2s 2p 2d 2f so it should be for s' orbital.
For atomic number 13: ..n-/-l =l where /= 0 =n-1=1
ls² Ip° ld (half-filled) .. n=2 ’ 2s' orbital
92. (a) Probability density plots for Is, 2s,2p and 3p orbitals are: 99, (b) P(x) = 4 x? x [v]'
2s 2p Probability willbe maximum at A and C.
100. (a) K,2s feels more attraction from nucleus so It has less
2 energy.
node
4 nh
101. (c) (A) mvr
2T
As nincreases, angular momentum increases.
nh
(C) Angular momentum 2T
Y3p 102. (b) According to (n + ) rule: 3p < 3d<4p < 4d

-13.6x 4
103. (a,c)-3.6 =
n
n=4
l=2
m =0
From the given graph answer is (1)
Angular nodes = l=2
93. (d) For aprincipal quantum number n, there will be (n-1)
values of/ therefore, ifn = 5, I= 5-1 =4 values Radial nodes =(n -l- 1)=1
For any value of I, there will be -/ to +/"m values". n =4d state
3 Classification of Elements and
Periodicity in Properties
3. TheIUPAC nomenclature of an element with electroni

Modern Periodic Law & configuration [Rn] Sr"6d' 7' is: (25 July, 2022 (Shif-iy
(a) Unnílbíum (b) Unnilunium
Nomenclature of Elements (c) Unnilquandíum (d) Unniltrium
4. Which one of the following statements for D.I. Mendclevs
is incorrect? (22 July, 2021 (Shift-II
1. It is observed that characteristic X-ray spectra of clements (a) At the tíme, he proposed períodíc table of elements
show regularity. When frequency to the power 'n' ie. v structure of atom was known
of X-rays cmitted is plotted against atomíc number Z, (b) Element with atomícnumber 101is named after him
following graph is obtaincd. |24 Jan, 2023 (Shift-1)| (c) He invented accurate barometer
) He authored the textbook - Prínciples of Chemistry
5. The atomícnumber of Unniluníum is
[6 Sept, 2020 (Shift-II))
6. The atomíc number of the element unnilenníum is
(03 Sept, 2020 Shift-)|
(a) 102 (b) 108
(c) 119 (d) 109
The value of 'n' is 7. The IUPAC symbol for the element with atomic number
(a) 1 (b) 2 119 would be: [8 April, 2019 (Shift-11)|
(a) unh (b) uun
(); (d) 3
2. Henry Moseley studied characteristic X-ray spectra of
(c) une (d) uue
clements, The graph whích represcnts his observation

correctly is : (Given v= frequency of X-ray emitted; Electronic Configurations and Types
Z= atomic number) [8 April, 2023 (Shift-)) of Elements: s-, p, d-, f- blocks
(a) (b)
8, The number of 6-clectrons present in an íon with 5>
protons in its unipositive state is [24 Jan, 2023 (Shift-11)
(a) 8 (b) 9
(c) 12 (d) 10
9, Match List- Iwith List- II, 130 Jan, 2023 (Shift-I))
List-I List-II
(Atomie number) (Block ofperiodic table)
(c) y² (d) v (A) 37 (I) p-block
(B) 78 (I1) d-block
(C) 52 (III) -block
(D) 65 (IV) s-block
Choose the correc answer from the options given below: 17. Given below are two statements: one is labelled as
(a) (A)-(1). (B)-(IV), (C-), (D)-(I) LS Assertion (A) and the other is labelled as Reason (R).
(b) (A)-),(B»-(), (CO-(IV),(D)-(U1) Assertion (A): The energy required to form Mg* from
(c) (AIV), (B)-(||),(C)-(1), (D)-()lo Mg is much higher than that required to produce Mg*.
d) (A-IV), (B)}-(I), (C)-(), (D-(11) Reason (R): Mg? is small ion and carry more charge than
10. The total number of isoelectronic species from the given Mg'. [10April, 2023 (Shift-II)]
set is
In the light of the above statements, choose the correct
O,F,Al, Mg'", Na', 0', Mg, AP", F answer from the options given below:
|15 April, 2023 (Shift-)| (a) Both(A) and (R) are true but (R) is NOT the correct
11, Which one of the following sets of ions represents a explanation of (A).
collection of isoclectronic species? (b) (A) is true but (R) is false.
(Given: Atomic Number: F:9, CI: 17, Na =11, Mg =12, (c) (A)is false but (R) is true.
Al 13, K- 19, Ca - 20, Sc-21) (d) Both (A) and (R) are true and (R) is the correct
| |Feb, 2023 (Shift-I)| Texplanation of (A).
(a) Li', Na', Mg?, Ca? (b) Ba', Sr, K, Ca? 18. Which of the following represents the correct order of
(c) N', 0, F,S (d) K', CI,Ca, Sc metallic character of the given elements?
[25 Jan, 2023 (Shift-II))
12. The pair, in which ions are isoclectronic with AlP" is: (b) Be < Si< Mg <K
|25 June, 2022 (Shift-I)] (a) Si<Be < Mg<K
(a) Br and Be? oo (b) CI and Li 6(c) K< Mg< Be < Si (d) Be<Si<K<Mg
19. The difference between electron gain enthalpies will be
L-O (c) S and K' (d) 0 and Mg? maximum b e t w e e n : 6
April, 2023 (Shift-I))
13. Theclement with 2= 120 (not yet discovered) willbe an/a bol (a Ne and F (b) Ne and CI
|12 Jan, 2019 (Shift-I)| (c) Ar and Cl (d) Ar and F
h (a) Inner transition metal (b) Alkaline earth metal 20. For elements B, C, N, Li, Be, O and F the correct order
0-(c) Alkalimetal (d) Transition metal of first ionization enthalpy is [11 April, 2023 (Shift-D]
14. The group number, number of valence electrons, and valency (a) Li< Be <B<C<N<0<F
of an clement with atomic number 15, respectively, are O (6) B> Li> Be> C>N>0>F
otit to|12 April, 2019 (Shift-)] -1 Li<B< Be <C<0<N<F
i(-(a) 16, 5 and2 (b) 16,6 and 3 (d) Li< Be <B<C<0<N<F
(c) 15,5 and 3 (d) 15,6and2oe 21. Inert gases have positive electron gain enthalpy. Its correct
15. The isoclectronicset of ions is [10 April, 2019 (Shift-)] order is [25 Jan, 2023 (Shift-I)]
0oT1O (a) Xe < Kr< Ne< He (b) He < Ne< Kr< Xe
(a) N, Li", Mg? and O2 (b) Li', Na', O and F (d) He <Kr< Xe<Ne
(c) He < Xe < Kr< Ne
(c) F, Li', Na' and Mg? (d) N,0, Fand Na'
22. The correct increasing order of the ionic radii is
|31 Jan, 2023 (Shift-I))
Periodic Trends in Properties (a) C <Ca?t < K*<S? (b) K* <S < Ca<Ct
of Elements 02(c) S²-<CI<Ca²*<K* (d) Ca <K*<Ct<S
23. The correct order of electronegativity for given elements
0is: |8 April, 2023 (Shift-I))
16. Given below are two statements: (a) C>P> At>Br (6) Br > P> At >C
enthalpy
Statement-1: The decrease in first ionization (c) P>Br > C> At (d) Br>C>At>P
from Al to Ga.
from B to Al is much larger than that 24. For electron gain enthalpies of the elements denoted as
iStantement-|: The dorbitals in Ga are completely fille. AH, the incorrect option is: |1Feb, 2023 (Shift-l))
|29 Jan, 2023 (Shift-I)) (6) AH(Se) <A_H(S)
statements, choose the most (a) A,H(CI) <A H(F)
In the light of the above i-(c) A H()<A H(A) () AH(Te) <A_H(Po)
the options given below
80 appropriate answer from Statement-ll iscorrect 25. The correct order of metallic character is:
l (a) Statement-Iisincorrect butII are correct |10 April, 2023 (Shift-Il)]
(6) Both the Statements-I and (a) Be> Ca > K (b) Ca>K>Be
Statement-l is incorrect
(c) Statement-Iis correct but (c) K>Ca >Be () K> Be >Ca
II are incorrect
() Both the Statements-I and
Classification of Elements and Periodicity in Properties
39
31. The absolute value of the
electron gain
26. Thc coTrect dccrcasingorder for metallic character is
|28 July, 2022 (Shift-I1))
117March, 2021
halogens satisfies :
(a) F>C|> Br>Ihh (b) CI>F> Br>]
(Shif enthalpy
(a) Na> Mg> Be> Si> P(b) P>Si> Be > Mg> Na (c) 1> Br> C|>F ) Ci > Br> F>I
(c) Si>P> Be> Na >Mg (d) Be> Na > Mg> Si >P 32. The set of elements that differ in mutual relationship
27. Match List-I with List-11. (26 Feb, 2021 (Shift-1)] froa
those of the other sets is: [17 March, 2021 (Shif
List -I List - II (a) Be -AI (b) B-Si
Electronic A,H in kJ mot! (c) Li- Na (d) Li-Mg
configuration 33. The ionic radiíof K, Na, Al and Mg are in the orde
of elements [25 July, 2021 (Shift
(A) 1s 2s? a () 801 (a) K*< AP < Mg?< Na(b) A<Mg<K<
(B) Is' 2s? 2p Sma (I) 899 (c) AP <Mg?< Na <K(d) Na <K*< Mg<AP
(C) is2s?2pebi (III) 1314 34. The correct order of ionic radii for the ions, P, S.c
(D) 1s2s2p' (IV) 1402 K,CH is: [27 Aug, 2021 (Shift-In
Choose the most appropríate answer from the options (a) K*> Ca?> p> S> CH
given below: (6) P²>>Ct> Ca²>K
(a) (AHII), (B}{III), (CIV), DI) c) CH>s>p> Ca*>K*
(b) (A-I),(B)-(III), (CIV), (D-(II) () p>s> Ct>K> Ca?
(c) (A){),(B-IV), (C-(I1), (D-(II) 35. The correct order of electron gain enthalpy is:
(d) (A-IV),(B}-(I), (C-(I1), (D-(III) [26 Feb, 2021 (Shift
28. Given below are two statements : one is labelled as (a) S> Se> Te > 0 (b) O>S> Se>Te
Assertion (A) and the other is labelled as Reason (R). (c) Te >Se>S>0 (d) S>0>Se>Te
Assertion (A): Metallic character decreases and non-metallic 36. The ionic radius of Na ion is 1.02 Å. The ionic rad (in A
character increases on moving from left to right in a períod. of Mg and AP,", respectively are: (8March, 2021 (Shif
Reason (R): It is due to increase in íonisation enthalpy (a) 0.85 and 0.99 (b) 0.68 and 0.72
and decrease in electron gain enthalpy, when one moves c) 0.72 and 0.54 (d) 1.05 and 0.99
from left to right ín a period. [31 Aug, 2021 (Shift-1)] 37. The CORRECT order of first ionisation enthalpy is:
In the light of the above statements, choose the most [27 July, 2021 (Shift-I
appropríaté answer from the options given below: (a) Mg <Al<S<P (b) Al< Mg <S<P
(a) (A) ís false but (R) ís true (c) Mg <S<Al<P (d) Mg <Al<P<S
(b) Both (A)and (R) are correct and (R) is the correct 38. The first ionization energy of magnesium is smaller
explanation of (A) compared to that of elements X andY, but higher tha
(c) Both (A) and (R) are correct but (R) is not the correct that of Z. The elements X, Y and Z, respectively are:
explanation of(A) [18 March, 2021 (Shift-I)
(d) (A)is true but (R) Ís false (a) Argon, chlorine and sodium
29. Consider the elements Mg, Al, S, P and Si, the correct (b) Chlorine, lithium and sodium
biocks
increasing order of their first ionization enthalpy is: (c) Neon, sodium and chlorine
[24 Feb, 2021 (Shift-I)) (a) Argon, lithium and sodium
(a) Al < Mg <S<Si <P () Al< Mg< Si<S<P 39. In general, the property (magnitudes only) that shows a
(c) Mg<Al <Si<P<S (a) Mg <Al <Si<S<P opposite trend in comparison to other properties across
30. The ioníc radií of Fand 0 respectively are 1.33 Aand period is : alsidab 12 Sept, 2020 (Shif-!
O14A, while the covalent radius of N is 0,74 A.
t (a) lonization enthalpy(b) Electron gain enthap
The correct statement for the ionic radíus of N from the (c) Atomic radius (d) Electronegativity.
following is: (25 July, 2021(Shift-II)) follow
40. The increasing order of the atomic radii of the (Shift-1)
(a) It is smaller than O and F, but bigger than of N elements is: d Sutooai 18 Jan, 2020
(b) It is bigger than F and N, but smaller than of O (A) C e e l bes (B) O to id)
(c) It is smaller than F andN (C)
F u d a (D) Cl
(d) It is bigger than 0 andF (E) Br s bas lainatost2 ars io&

bn (a) (A) <(B) <(C)<(D) <(E) 48. Bhas a smaller first ionization enthalpy than Be. Consider
(6) (D) <(C) <(B) < (A)< (E)la uc 1 the following statements: (9 Jan, 2020 (Shift-))
(c) (C) < (B) < (A) < (D) < (E) (1) it is easier to remove 2p clectron than 2s clectron.
j020- (a) (B) <(C) <(D) <(D) <(E) noi ( ) 2p clectron of B is more shielded from the nucleus by
41. Within each pair of elements F & CI, S & Se and Li & Na, the inner core of clectrons than the 2s electrons of Be.
respectively, the elements that release more energy upon
an electron gain are |7 Jan, 2020 (Shift-I1)] on0 (I) 2s electron has more penetration power than 2p electron
(a) F, Se and Na (B) C1, Se and Na (IV) atomic radius of B is more than Be (atomic number
(c) F,Sand Li toitssinot B=5, Be =4)
(D) CI, S and Li
The correct statements are:
42. The five successive ionization enthalpies of an element are
(a) (1), (III) and (1V) (b) (), (I) and (II)
800, 2427, 3658, 25024 and 32824 kJ mol",The number
of valence electrons in the element is: (c). (),(I) and (1V) (d) (I), (III) and (IV)
[3 Sept, 2020(Shift-I)) 49. The first ionization energy (in kJ/mol) of Na, Mg, Aland
(a) 4 (6) 2
Si respectively, are: [8 Jan, 2020(Shift-I))
(c) S (a) 3 (a) 496, 577, 786, 737 (b) 786, 737, 577, 496
43. The process that is NOT endothermic in nature is: (c) 496, 577, 737,786 (d) 496, 737, 577,786
[4 Sept, 2020 (Shift-II)] 50. The correct order of the first ionization enthalpies is:
(a) Hte ’ H (b) Oro te’Og [10 April, 2019 (Shift-I)]
(c) Na,g ’ Napte (d) Arte’Arp (a) Mn <Ti< Zn<Ni (b) Ti< Mn < Ni < Zn
44. The correct order of the ionic radii of O, N, F, Mg?:, (c) Zn <Ni< Mn<Ti (d) Ti< Mn <Zn <Ni
Nat and Al is: [5 Sept, 2020 (Shift-II)] 51. In general, the properties that decreases and increase down
(a) N<0<F< Na<Mg2* <AP+ a group in the periodic table respectively are
(b) AP* < Mg? < Na<F<02 < N [9 Jan, 2019 (Shift-I))
(c) A1* < Na' <Mg2* < 0 <F<N (a) Atomic radius and electrongegativity
(d) N<F<0<Mg? < Na <AP* (6) Electron gain enthalpy and electronegativity
45. Three elements X, Y and Z are in the 3rd period of the (c) Electronegativity and atomic radius
periodic table. The oxides of X, Y and Z, respectively, are
basic, amphoteric and acidic. The correct order of the atomic (a) Electronegativity and electron gain enthalpy
numbers of X, Y and Z is: [2 Sept, 2020 (Shift-II)) 52. The correct option with resepect to the Pauling electronegativity
(b) Z<Y<X values of the elements is: [11 Jan, 2019 (Shift-II)]
(a) X<Z<Y
(c) X<Y<Z (a) Y<X<Z (a) Te > Se (6) Ga < Ge
46. The ionic radiiof O-,F, Nat and Mg? are in the order: (c) Si<AI (a) P> S
14 Sept, 2020 (Shift-)] 53. The pair that has similar atomic radii is
(a) -0->F> Mgt> Na (b) Mg² > Na>F>02 |12 April, 2019 (Shift-Il)
(c) F>0-> Nat> Mg? (d) 0-> >Na> Mg2 ) Sc and Ni (b) Ti and HF
47. Among the statements (1-IV), the correct ones are: (c) Mo and W () Mn and Re
13 Sept, 2020 54. When the first electron gain enthalpy (A, H) of oxygen is
( S
(I) Be has smaller atomic radius compared to Mg. h i l its second electron gain enthalpy S
(II) Be has higher ionization enthalpy than Al. |9 Jan, 2019 (Shift-I))
(I) Charge/radius ratio of Be is greater than that of Al. (a) Amore negative value than the first
(IV) Both Be and Al form mainly covalent compounds. ()2 (b) Almost the same as that of the first
) (a) (T), (III) and (IV) (b) (II), (II) and (IV) (c) Negative, but less negative than the first
(c) (1), (II) and (II) (a) (I), (II) and (IV) t) (a) A positive value
Classification of Elements and Periodicity in Properties 41
55. In comparison to boron, berylium has: 57. The 1", 2nd and the 3rd jonization enthalpies I,, L, and I
(12 April, 2019 (Shift-II)] of four atoms with atomic numbers n, n + 1,n+2 and n +
(a) Lesser nuclear charge and greater first ionisation where n < 10, are tabulated below. What is the value ofn
enthalpy IJEE Adv 20201
(6) Lesser nuclear charge and lesser first ionisation Atomic lonization Enthalpy (kJ/mol)
enthalpy number
(c) Greater nuclear charge and greater first ionisation I
enthalpy
1681 3374 6050
(a) Greater nuclear charge and lesser first ionisation n
enthalpy n+1 2081 3952 6122

56. The correct order of the atomic radii of C, Cs, Al and S is:
[11 Jan, 2019 (Shift-I)] a d n + 2 4 9 6 n 4562 6910
(a) C<S<Al<Cs (b) S<C< Cs<AI
n+3 738 1451 7733
(c) S<C<Al<Cs. (d) C<S<Cs<AI
ANSWER KEY
7. (d) 8. (a) 9, () 10. [5]
1. (c) 2. (b) 3. (a) 4. (a) 5. [101] 6. (d)
17. (d) 18. (a) 19. (b) 20. (c)
11: (d) 12. (d) 13. (b) 14, (c) 15. (d) 16. (*)
30. (d)
21. (c) 22. (d). 23. (d) 24. (b) 25. (c) 26. (a) 27. (a) 28. (d) 29. (b)
34, (d) 40. (C)
31. (6) 32. (c) 33. (c) 35. (a) 36. (c) 37. (6) 38. (a)h 39. (c)
50. (b)
41. (d) 42. (d) 43. (a) 44. (b) 45. (c) 46. (d) 47. (a) 48. (6) 49. (d)
S1. (c) 52. (b) 53. (c) 54. (d) 55. (a) 56. (a) 57. [9]

EXPLANATIONS
CI ’ number of electrons =17+1= 18
1. () According to Henry Moseley vvcz-b Lit ’ number of electrons = 3-1 =2
1
So, n=2 S²number ofelectrons =16+2 = 18
K* ’ number of electrons = 19-l= 18
2. (6) v «Z t O-2. ’ number of electrons = 8+2 = 10
The correct graphical representation of Moseley Mg2. ’ number of electrons = 12-2= 10
observation is graph b' Hence, O & Mg*2 will be isoelectronic with Al,
3. (d) IUPAC nomenclature of element with atomic 13. (b) [Og.J 8s' is the configuration for Z=120, where Og
no. 103 is uniltrium having electronic configuration awla i nis oganesson.
[Rn] Sfl4 6d' 7S2,
14. (c) Atomic number (Z) 15 »P’ Ne] 3s 3p'
4. (a) Wehn Mendeleev's proposed periodic table of elements, Phosphorous belongs to 15h group.
structure of atom was not known at that time. no. of valence e = 5 o b oi
5. [101]To find atomic number, following are the rules: and valency =3 in (G.S.)
0-nil
15. (d) N’ ls 2s² 2p
anotnc n 1-un Li ’ ls?
bes oinO 2-bi Mg*’ 1s² 2s? 2p
3-tri O²’ l? 2s? 2p
and so on... F’ls? 2s² 2p61icalo
6. (d) un stands for 1, nil for 0 and enn for9 l e 2 e Na ’ 1s² 2s? 2p
S lian So, atomic number = 1 0 9 z N,02,Fand Nat are isoelectronic
7. (d) 119 symbol is : Ununennium (uue)
16. (*) Size c
8. (d) Z=55 [Cs] IE.
Cs :[Xe<6s' As we move down the group, size increases, So in
Cst: [Xe] case of group 13 element size of Gashould be greater
i.e.,oSbr than size Al. This is due to the presence of d-electron
Cst:1s² 2s? 2p 3s? 3p 3d'° 4s² 4p° 4d° 5s Sp in Ga which do not shield the nucleus effectively. As
[Cs"] > Xe] i.e. upto 5s count e of s-subshell i.e. result, Ga experience greater force of attraction form
Is, 2s, 3s, 4s, 5s 10electrons the Al. Hence size of Ga is less than size of Al. and
9. (d) The electronic configuration with respect to given To6 LE.of Ga is quite higher than Al.
atomic numbers are as follow, NTA ans key ’ (b)
37-[kr]5s! belongs to s-block PW ans key ’ (a)
78 - [Xe] 4f, 5d, 6s'belongs to d-block 17. (a) Since Mg? is a small ion and carry more charge
52 - [kr] 4d°, 5s², 5p ga belongs to p-block than Mg, therefore, more energy is required in its
65 [Xe] 4f, 6s? belongs tof-block formation.
10. [5] Isoelectronic speices have same no. of in valence shell. 18. (a) On going from top to bottom, metallic character
Isoelectronic species O, F, Mg, Na", Al3 d Increases and along the period, it decreases.
11. (d) Isoclectronic species are those which haye same b19. (b) Cl has the most negative AH, among all the elements
number of electrons in it.
Ca2t Sç3+
and Ne has the most positive AH due to full illed
K* CI
18 18 18 18
deuto t electronic configuration.M
20. (c) F>N>O> C> Be> B> Libs
12. (d) Isoelectronic species contain same number of electrons.
Al3 ’ number of electrons = 13 -10 =3 As we move down the group I.E. decreases, while
Br ’ number of electrons =35 +|=36 o we moving along period 1.E. increases.
Be*2’ number of electrons = 4- 2=2
Classification of Elements and Periodicity in Properties

21. (c) 29. (b) Al< Mg <Si<S<P
RONAlong the period, I*1. Eincreases with an excen.
on moving from group 2to group 13 and
Element A H[kJ/mol] from gro
15 to group 16.
He +48 30. () Higher the negative charge on ion, higher will h
Ne +116 ionic radius. Also, size of neutral autom is largera
cation and smaller than anion.
Kr +96 31. (b) Since, Clatom has large size, therefore, addition o8
Xeene +77
in outer most orbit produce less electronic repulsi
with respect to F-atom. Thus, the correct order:
As we move down the group size increase and tsokA Cl>F>Br >I. to
electron gain enthlpy decreases. 32. (c) The diagonal relationship in period (2) and period (a
So, order is Ne < Kr< Xe <He otmcts is shown below:rstaliargon DA9U
aoilei LËn Be B CN 0L.
22. (d) For isoelectronic species, the size of anion is always NaMg Al Si
greater than cation. Also, for anion, size increases
with the increase in more negative charge. And for oHence, Li-Na does not show diagonal relationshi
cation, it decreases with more positive charge. 33. (c) For isoelectronic species, ionic radii decreases wid
23.- (d) Atom E.N. an increase in positive charge. bat ol[i02
Br 2.96
Al3 < Mg*2< Nat<K*
C 2.55 34. (d) Ionic radii of cations isalways smaller than anions
Also, more the +ve charge less will be the ionic radi
At
2.2S
2.19
and more the -ve charge more will be the ionic radi
P Hence, the correct order of ionic radii is,
Correct order of electronegativity is p> S> Cr>K*> Ca2+
Br >C At> P 35. (a) Down the group,electron gain enthalpy décreases bu
O
shows anomalous behavior due to its small size.
24. (6) (a) AH(C) <A HF) S> Se> Te >O
(345) (328) Correct iotmce eti
36. (c) The number of electrons in the given species are:
(6) A_H(Se) < A H(S) electrons
osoni 195) (-200) Incorrect Na 10
( ) A H) <A_H(A) Mg?t 10 isoelectronic (same electrons)
i0gaa -295)) (-270) Correct totk
() A H(Te) <A H(Po) AI+ 10
(-190) (-183) Correct valúe: AlPt> Mg²t > Na
25. (c) On moving from top to bottom, metallic character Ionic Radius: Na> Mg* > AI" s o
increases while on moving from left to right metallic
decreases. 0.72 0.54
Hence, the correct order is: K> Ca > Be. 37. (6) Along the period, ionization energy increases bu
26. (a) Down the group metallic character increases and species having fully filled or half-filled configuratio
decreases along the period. have more I.E.
Correct order is :- Na>Mg> Be> Si> P Order of 1"L.E. is Al < Mg<S<P

27. (a) N>0> Be >B 9 , 38. (a) Mg has first I.E. smaller than Ar and Cl but greaie
Due to half filled configuration of N, it has more than Na.
atomic radius
IE as compared to oxygen and due to fully filled 39. (c) On moving left to right along aperiod,
decreases
tolli uconfiguration Be has more ILE than that of B.
genera
28. (d) " Metallic character decreases from left to right 40. (c) Left to right in a period, the atomic radius
bottom,
atomi
and non metallic character increases as one move decreases and in a group, top to
from left toright. radius increases.
Both I.E. and electron gain enthalpy increases as Hence, the order would be:
one move from left to right. Br > Cl>C>0>Fie.. E>D>A> B> C.
44 JEE PYQsChemistry
41. (d) The electron gain enthalpy order in the given pair of 50. (b) Ti ’ [Ar] 3d² 4s?
elements is as follows, Mn ’ [Ar]3d 4s?
CI>F (exception) Ni’ [Ar] 3d 4s?
S> Se(size effect) Zn ’ [Ar] 3d1° 4s²
Li> Na(size effect) 51. (c) On moving down a group, Electronegativity decreases
42. (d) Due to large difference in 3rd and 4th ionisation and atomic radius increases for representative elements.
energies, the number of valence electrons is 3. 52. (b) Electronegativity increases from left to right ín a
43. (a) The process given in option (a) is exothermic in period and decreases down the group.
nature due to release of heat. 53. (c) Mo and Whave nearly similar, atomic radius due to
44. (6) As compared to neutral atom, size of anion is larger lanthanoid contraction.
and that of cation is smaller. Also, 54. (d) 2nd electron gain enthalpy of oxygen is positive.
charge of anion < size 55. (a) In case of "Be" electron remove from "2s" orbital
1 while in case of "B" electron remove from 2p"
o n charge of cation oc orbital. 2s' orbital have greater peretration effect
Sizeoo e then 2p' orbitals. So, 'Be' have more LE. than B'.
-is2 Hence, the correct order is:
AP* < Mg?t < Nat <F<0<N 56. (a).On moving down, size increases:
45. (c) On moving left to right in a period, atomic number
order : C<S<Al< Cs.
s as well as acidic character of oxides increase. 57. [9]
buee i3rd period element is oxides are given as, bbo cint Atomic Ionization Enthalpy (kJ/mol)
C5luo Number I:
Na,0 MgO Al0, Sio, P,0, Cl,0,
biloe Basic 1681 3374 6050
AmphotericAcidic
n+1 2081 3952 6122
Hence, the correct order of atomic number is X<Y<Z n+2 496 4562 6910
46. (d) As compared to neutral atom, size of anion is large n+3 738 1451 7733
while for cation, size is smal.
0->F> Na>Mg?+ By observing the values of I,, I and I, for atomic
47. (a) The ratio of charge / radius of Be and Al is same number (n+2), it is observed that L, >> I,.
because of diagonal relationship.taau This indicates that number of valence shell electrons is
land atomic number (n + 2) should be an alkali metal.
48. (b) Atomic radius of boron is smaller than that of
beryllium. Hence IV statement is false. Rest are true CAlsofor atomic number (n+3), I, >>L. This indicates
statements. that it willbe an alkaline earth metal which suggests
49. (d) The increasing order of inonisation energy: that atomic number (n+1) should be a noble gas and
atomicnumber (n) should belong to halogen family.
Na < Al< Mg < S i e 1-3 Since n<10: Hence n=9(F atom)
Note: n=1 (Hatom) cannot be the answer because
496 577 737 786 it does not have I, and I, values.
Classification of Elements and Periodicity in Properties 45

States of Matter
Intermolecular Forces and

The Gas Laws (c)
P(atm)
1. A 300ml bottle of soft drink has 0.2 M CO2 dissolved in

X
it Assuming CO2 behaves as an ideal gas, the volume of
the dissolved CO2 at STP is mL. (Nearest integer)
Given: At STP, molar volume of an ideal gas is 22. 7 L mo1- 1
(30 Jan, 2023 (Shift-I)]
2. At constant temperature,. a gas is at a pressure of 940.3
mm Hg. The pressure at which its volume -decreases by
(d) t-
. P(atrn )
40% is · mm Hg. (Nearest Integer)
(10 April, 2023 (Shift-I)] X
3. Which amongst the given plots is the correct plot for d(gcm-3 )
pressure (p) vs density ( d) for an ideal gas?
4. The pressure of a moist gas at 27°C is 4 atm. The volume
· of the container is doubled at the same temperature. The
y T 3>T 2>T1
new pressure of the moist gas is _ _ _ __ x 10- 1atm.
(Nearest integer) [25 July, 2022 (Shift-I)]
~ · (Given: The vapour pressure of water at 27°C is 0.4 atrn)
(a) f T, 5. Given below are two statements : one is labelled as

Assertion (A) and the _other is labelled as Reason (R).
P(atm) T2
Assertion (A): Dipole-dipole interactions are the only non-
T1
X
covalent interactions, resulting in hydrogen bond formation.
d(gcm -3 ) Reason (R): Fluorine is the most electronegative element
y and hydrogen bonds in HF are symmetrical.
y T1>T2>T1 (26 Feb, 2021 (Shift-I))
In 'the light of the above statements, choose the most
appropriate answer from the opti?ns given below :
T, (a) (A) is true but (R) is false
(b)
(b) (A) is false but (R) is true
P(atm)
(c) Both (A) and (R)' nre true and (R) is the correct
X
explanation of A
d(gcm -3) (d) Both (A) and (R) are true but (R) is NOT the correct
y T1>T2>T1 explanation of (A)
ldea1Ga; Eq~~tl~n --~
1
6. An LPO cylinder contains gas at a pressure of 300 kPa at
27°C. The cylinder can withstand the pressure of 1.2 x I()'I
PL The room in which the cylinder is kept catches
fire. The minimum temperature at which the bursting
I12. -~
of cylinder will take place is _ _ _ _ °C. (Nearest
integer) (25 July, 2021 (Shift-I DI
7. A car~ is filled ·with nitrogen gas at 35 psi at 27°C. It
will burst if pressure exceeds 40 psi. The temperature in
°Cat.which the car tyre will burst is __. (Rounded - off
to the nearest integer) (25 Feb, 2021 (Shift-1)1
Three bulbs are fill ed wi th Cl f4, CO2 and Ne a11 Hh,
8. The relative strength Qf interionic/intermolecular forces
the picture. The bulbs are connected through pipcH,~
in decreasing order is (7 Jan, 2020 (Shift-I))
volume.
(a) ion-dipole> dipole-dipole> ion-ion When the stopcocks are opened and the temperature i,~
(b) dipole-dipole> ion-dipole> ion-ion constant throughout, the pressure of the ~ystem is r~
(c) ion-ion ion-dipole> dipole-dipole to be atm . (Nearest integer) (8 April, 2023 (Shir~
· (d) ion-dipole> ion-ion> dipole-dipole 13. An evacuated glass vessel weighs 40.0g when em,
135.0 g when fill ed wi th a I/q uid of density 0.95 g~
9. Match the type of interaction in column A with the distance and 40.5 g when fi lled with an ideal gas at 0.82 atm atl
dependence of their interaction energy in column B : K. The molar mass of the gas in g mot-1 is:
[2 Sept, 2020 (Shift-II)) (Given: R = 0.082 L atm K- 1 mol 1)
A B (26 June, 2Q22 (Shih~
(a) 35 (b) 50
(A) Ion-ion (D .!.- (c) 75 (d) 125
r 1
14. At 300 K, a sample of 3.0 g of gas A occupies the sa
(B) Dipole-dipole (II) 1 volume as 0.2 g of hydrogen at 200 Kat the same pressa
r2 The molar mass of gas A is _ _ _ _ _ g mot
(nearest integer) Assume that the behaviour of gases as i<k
(C) London dispersion {III) 1 (Given: The molar mass of hydrogen (1-1 2) gas is 2.0 g mot
_rJ
(24 June, 2022 (Shift.fl
(IV) 1 '.' 15. 100g of an ideal gas is kept in a cylinder of 41 6 L vol111
r6 at 27°C under 1.5 bar pressure. The molar mass of the t
(a) (A)-{I); (B)-(III); (C)-(IV) is _ _ _ g mol- 1.(Nearest integer)
(b) (A)-(Il); (B)-(IV); (C)-(111) (Given : R = 0.083 L bar K- 1 mol· 1)
(28 June, 2022 (Shift-0
(c) (A)-(Q; (B)-(IJ); {C)-(111)
16. Geraniol, a volatile organi c compo·und, is a compano
(d) (A)-(Q; (B)-(fD; {C)-(IV) of rose oil. The density of the vapour is 0.46 gL-1 at 251
I
10. The predominant intermolecular forces present in ethyl and 100 mm Hg. The molar mass of geraniol is----
acetate, a liquid, are: (8 Jan, 2020 (Shift-I)) g mo1- 1 (Nearest Integer).
(a) Hydrogen.bonding and London dispersion [Given R = 0.082 L atm K- 1 mot- 1) •
(29 June, 2022 (Shin·1
(b) Dipole-dipole and hydrogen bonding
17. A box contains 0.90 g ofliquid water in equilibrium wi
(c) London dispersion, dipole-dipole and hydrogen
water vapour at 27°C. The equilibrium vapour pressu~'.
bonding water at 27°C is 32.0 Torr. When the volume of the bO
(d) London dispersion and dipol~dipole increased, some of the liquid water evaporates to mainll
11. A spherical balloon of radius 3 cm containing helium gas the equilibrium pressure. If all the liquid water evaporate
then the volume of the box must be _ _ _ litre. [ neaie
has a pressure of 48 x 10-3 bar. At the same temperature, the
integer]
pressure, of a spherical balloon of radius 12 cm containing
(Given : R - 0.082 L atm K .1 molt, 1) -
_the same amount of gas will be _ ___'_ _ __
(Ignore the volume of the liquid water and assume;.~~
x Jo-6 bar. (6 Sept, 2020 (Shift-I)) vapours behave as an idcul gas.)(29 June, 2022 (Shi
--
18. A 10 g mixture of hydrogen and heliwn is contained in a 27. Two flasks I and TI shown below are connected by a valve
3
vessel of capacity 0.0125 m at 6 bar and 27°C. The mass of negligible volume.
of heliwn in the mixture is _ _ _ g, [nearest integer] When the valve is opened, the final pressure of the system
1 1
Given: R= 8.3 JK- mol - • in bar is xx 10-2 • The value of xis _ _ _. (Integer answer)
(Atomic masses of Hand He are 1 u and 4u, respectively)
(26 July, 2022 (Shift-II)]
. 19. 2.0 g ofH 2 gas is adsorbed on 2.5 g of platinum powder at 2.8 gN 2 0.2 g N 2
300 Kand 1 bar pressure. The volume of the gas adsorbed 300K 60K
per gram of the adsorbent is _ _ ml. lL 2L
1
(Gi~ R =0.083 Lbar K- mot- 1) [26 June, 2022 (Shift-I)]
20. 'x' g of molecular oxygen(O 2) is mixed with 200 g of
If
neon (Ne). The total pressure of the non- reactive mixture
ofO 2 and Ne in the cylinder is 25 bar. The partial pressure of [Assume- Ideal gas; 1 bar = 105 Pa; Molar mass ofN2 =
Ne is 20 bar at the same temperature and volume. The value 28.0 g mol- 1 ; R = 8.31 Jmol- 1K- 1]
of'x' i s _ _ _ (29 July, 2022 (Shift-II)] ·
[27 Aug, 2021 (Shift-II))
[Given: Molar mass of 0 2 = 32 g mol- 1• Molar mass of Ne
=20gmor ]
1
. 28. Which one of the following is the correct PV vs P plot at
21. A rigid nitrogen tank stored inside a laboratory has a pressure constant temperature for an ideal gas? (P and V stand for
of 30 atrn at 06:00 am when the temperature is 27°C. pressure and volume of the gas respectively)
At 03:00 pm, when the temperature is 45°C, the pressure [31 Aug, 2021 (Shift-I)]
in the .tank will be_ _ _ _ _ atm. [nearest integer] ·.
22. A sealed flask with a capacity of 2 dm 3 contains 11 g of . (a) PV
propane gas. The flask is so weak that it will burst if the
pressure becomes 2 MPa. The minimum temperature at
which the flask will burst is _ _ _ _ _ °C. [Nearest p p
integer]
(Given: R = 8.3 J K - 1 mol- 1• Atomic masses of C and H
are 12u and 1u, respectively) (c) PV · (d) PV
(Assume that propane behaves as an ideal gas.)
[25 July, 2022 (Shift-II)) p . p
23. A mixture of hydrogen and oxygen contains 40% hydrogen
29. The pressure -exerted by a non- reacti\ e gaseous mixture
by mass when the pressure is 2.2 bar. The partial pressure
of 6.4 g of methane and 8.8 g of carbon dioxide in a IO L
of hydrogen is _ _ _ _ _ bar. (Nearest Integer)
vess(!l at 27°C •is· - kPa.
[26 July, 2022 (Shift-I))
24. An empty LPG cylinder weighs 14.8 kg. When full, it (Round off to the nearest integer).
weighs 29.0 kg and shows a pressure of3.47 atrn. In the / [Assume gases are ideal, R = 8.314-J mol- 1 K- 1
·course of use at ambient temperature, the mass of the . Atomic masses: C: 12.0\u, H: 1.0 u, 0: 16.0 u]
cylinder is reduced to 23 .0 kg. The final pressure inside
[17 March, 2021 (Shift-I))
of the cylinder is _ _ _atm. (Nearest integer)
(Assume LPG to be an ideal gas)[l Sept, 2021 (Shift-Il)] 30. The number of chlorine atoms in 20 mL of chlorine oas
25. 3.12 g of oxygen is adsorbed on 1.2 g of platinum metal. at STP is_·_10 21 (Round off to the nearest integer).~
The volume oxygen adsorbed per gram of the adsorbent [Assume chlorine is ;m ideal gas at STP
at 1 atm and 300 K in L is _ _ __ I • R =0.083 L bar mor 1 K- 1, NA = 6.023 X 1023]
[R = 0.0821 L atm K- 1 mole- 1] [26 Feb, 2021 (Shift-I)]
. l17 March, 2021 (Shift-11))
26. A home owner uses 4.00 x 103 m 3 of methane (CH 4 ) gas,
31. The volume occupied by 4.75 g of acetylene gas at 50°c
(assume CH4 is an ideal gas) in a year to heat his home.
Under the pressure of 1.0 atm and 300 K, mass of gas used and 740 mm Hg pressure is _ _ _ L. (Rounded off to
is xx105g. The value of xis---,--· (Nearest integer) the nearest integer)
1 1
r (Given R = 0.083 L atrn K- mol- )
. [25 July, 2021 (Shift-I)]
[Given R = 0.0826L atm K- 1 mol- 1]
[24 Feb, 2021 (Shift-II))
r
--
,, ;'
i I
I
!
I
I
'
32. Which one of the following graphs is not correct for ideal 36. An ope!" vessel at ~7°C is he~te~ until two fifth
i
I
gas? I2 Sep~ 2020 (Shifl-1)1 air (assum ed as an ideal gas) m 1t has escaped fi 0f \
vessel. Assum ing that the volum e of the vessel r°lll \
f f
_consta ~t, the tempe rature at which the vessel h~a~
I
heated 1s:
d d
(a} 500°C
(12 Jan, 2019 (Sh· " ,,,.,,
(b) 500 K (c) 750°C (d) 750 I( '
Kin etic Mol ecu lar The ory of

T--. T-
I U
Gases and Mol ecu lar Speeds
f
/
37. At 600K, the root_mean squar e (rms) speed of
gas
d (mola r mass = 40) 1s equal to the most probable SJ)eed ~
gas Y at 90K. The molar mass of the gas Y is ~
g mol- 1• (Near est intege r) (12 April , 2023 ~
38. If the distri butio n of molec ular speed s of a gas
is•
1rr - P- per the_figure shown below, then the ratio of the mOl
III N proba ble, the avera ge and the roots mean square sJ)ee(k_
-d = Dens i~, P = Pressure, T = Temp eratur e respec tively, is (JEE Adv 202~
(a) I (b) N (c) II (d) III
33. A cylind er contai ning an ideal gas (0.1 mol of 1.0 dm3
) is
in therm al equili brium with a large volum e of 0.5 molal
aqueo us solution of ethyle ne glyco l _a t its freezi ng point.
· ff the stopp ers S and S (as show n in .the figure ) are Ii\
1 2
sudde nly withd rawn, the volum e of the gas in litres after
equili brium is achiev ed will be _ _ I \
(Give n,~ (wate r)= 2.0 K kg mol-:1, R = 0.08 dm3 atm
mot 1)
K-i
(9 Jan, 2020 (Shift-II)]
7 \
j
Frictionaless J \-
piston
I/ \ speed
(a) 1:1:1
••
•• •• ••
jdeaJ gas •
•• (c) 1:1.12 8:1.22 4
(b) 1:1:1. 224
(d) 1:1.128:1
aq. ethylene glyco
34. A mixtu re of one mole each of H , He and O each are

2
Deviation From Ideal
enclo sed in a cylind er of volum e V at tempe r!ture T.
If
the partia l pressu re of H is 2 atm, the total pressu re of
· Gas Behaviour
2 the
gases in the cylind er is: (3 Sept, 2020 (Shift-II))
(a) 14 atm (b) 6 atm (c) 22 atm (d) 38 atm 39. For 1 mol of gas, the plot ofpV vs pis shown below
. Pis
35. 0.5 moles of gas A and x moles of gas B exert a pressu re the pressu re and Vis the volum e of the gas.
of 200 Pa in a conta iner of volume IO m 3 at I OOOK. Given
:
R is the gas const ant in JK- 1 mo1- 1, xis
2R
(9 Jan, 2019 (Shift-I)) t
pV
2R
(a) 4+R (b) 4-R
P-+-
4+R (d) 4-R What is the value of comp ressib ility factor at point A?
(c) 2R 2R · (29 Jan, 2023 (Shift-01
68 . •
a b 46. The volume of gas A is twice that of gas B . The
(a) 1 - - - (b) 1+-
RTV V compre ssibility factor of gas A is thrice that of gas B at
same tempera ture. The pressure of gases for equal moles
b
(c) 1 - - (d) 1+ - a - are 112 Jan, 2019 (Shift-I ))
V RTV . . (a) 3P" = 2P8 (b) 2PA= 3P 9
40. Arrange the following gases in increasi ng order of vander
(c) PA= 3P8 (d) PA= 2P 9
Waal's constan t 'a'. (8 April, 2023 (Shift-I I))
47. Points I, II and Ill in the follo~i ng plot respect ively
~)~ ~) c~ corresp ond to
(C) H20 (D) C6H6 (V : most probabl e velocity )l10 April, 2019 (Shift-I I))
Choose the correct option from the followin g : mp
(a) B, C, D and A (b) C, D, Band A t

(c) A, B, C and D (d) D, C, B and A
41. A certain quantity 9freal gas occupie s a volume of 0.15
dm 3 at .100 atm and 500 K when its compre ssibility
factor is· 1.07. Its volume at 300 atm and 300K (When
its compre ssibility factor _is 1.4) is _ __ x 10- 4 dm 3
(Nearest Integer) [13 April, 2023 (Shift-I)) Speed v-
42. For a real gas at 25°C tempera ture and high pressure (99
(a) Vmp ofN2 (300K); V mp of f-Ii 300K); V mp of02{400K)
bar) the val ue of compre ssibility factor is 2, so the value
of Vander Waal 's constan t ' b' should be_ _ _ x 10-2 (b) Vmp of1°½ (300K); V mp ofNi 300K); V mp ofOJ 400K)
L mo1- 1• (Neares t Integer) . (c) V mp ofO2 (400K); V mp ofNi30 0K); Vmp of1°½(300K)
(Given R = 0.083 L bar_K- 1 mol- 1) (d) Vmp ofNi (300K); V mp ofO2(40~K); V mp ofl-I/30 0K)
43. The unit of the van der Waals gas equation parameter 'a' in
Liqu ifact ion of Gase s and
~:_-}v·-
( P +. nb) = nRT is: (27 Aug, 2021 (Shift-I ))
Liqu id State
(a) atm dm 6 mol~2 (b) dm 3 mol- 1
· (c) kg m s- 1 (d) kg m s-2 48. Four gases A, B, C and D have critical tempera tures 5.3,
44. A certain gas obe;s P(V m- b) = RT. The value of (

is xb . The value of x is_ _ _ _ . ·
:!l 33 .2, 126.0 and 154.3K respecti vely.
For their _adsorpt ion on fixed amount of charcoa l, the
correct order is : [12 April, 2023 (Shift-I ))
RT
(Integer answer) (Z : compre ssibility factor) (a) C > B > D > A
(b) C > D > B > A
. (26 Feb, 2021 (Shift-I)]
45. Identify the correct .labels of_A , Band C in the following (c) D > C > A > B
graph from the options given below (d) D > C > B > A
A 49. Given below are two stateme nts : One is labelle d as
Asserti on (A) and the other is labelled as Reason (R).
·no. of ·
molecu les Asserti on {A): Among st He, Ne, Ar and Kr; l g of
activated charcoa l adsorbs more of Kr.
Speed Reason (R): The critical volume V (cm·' mot- 1) and

0
critical pressure Pc (atm) is •highest for Krypton but the
Root mean square speed(Vrm,); mosf probable speed(V mp);
compre ssibility factor at critical point Z is lowest for
Average speed(V.J [7 Jan, 2020 (Shift-I I)) '
C
Krypton . ( l Feb, 2023 (Shift-I ))
(a) A-V 8-V C-V (b) A-V,m,' 8-Vmp' C-V.v
av' nns' . mp In the light of the above stateme nts, choose the correct
(c) A-V 8-V C-V · (d) A-V~P' B-V•v' C-Vrm• answer from the options given below.
mp' n.na' av
States of Matter
(a) (A) is true but (R) is false Gas Critical temperature (I<)
(b) (A) is false but (R) is true He 5.2
(c-) Both (A) and (R) are true but (R) is NOT the correct CH 190.0
! . explanation of(A) co 304.2
· (d) Both (A) and (R) are'true and (R) is the correct NH 405.5
explanatio n (A) The gas showing least adsorption on a definite arnount
SO. The number of statement's, which are correct with_respect charcoal is ~
to the compression of carbon dioxide from point (a) in the (a) He (b) CH4
Andrews isotherm from the following is·_ __ (c) CO2 (d) NH 3
53. Given below are two statements. One is labelled
(24 Jan, 2023 (Shift-II)) Assertion (A) and the other is labelled as Reason (R)~
Assertion (A): Sharp_glass_ edge becomes smooth°'
heating it upto its meltmg pomt.
l -Reason (R): The viscosity of glass decreases on meltin&

. Choose the most appropriate answer from the optio'-
given below. . [20 July, 2022 (Shift-~
(a) (A) is false but (R) is true.
· (b) Both (A) and (R) are true but (R) is NOT the correa
explanation of (A). , ·
a _
(c) · (A) is true but (R) is false
Volmn e---- . (d) Both (A) and (R) are true .and (R) is the correct
(a) Carbon dioxide remains as a gas upto point (b) explanation of (A).
(b) Liquid carbon dioxide appears at point (c) 54. Given:
(c) Liquid and gaseous carbon dioxide coexist between Gas H2 CH 4 _ CO2 so2
points (b) and (c)
Critical Temperatu re/K -33 190 304 630
(d) As the volume decreases from (b}to.(c), the amount
On the basis of data given above, predict which of Iii
of liqui~ dec,eases . .
following gases show least adsorption on a definite amowi
St. Based on the given figure, the number of correct of charcoal? · [12 Jan, 2019 (Shift-ijl
statement/s is/~ [25 Jan, 2023 (Shift-II)) · (a) ·s02 · · . (b) . CO
2
. (c) CH4 , (d) 8i
55. Consider ·the· van d!!r Waals constants, a and b, for the
following gases:
.----::~~- -- - Liquid molecule on
E:=.,- - ~ - - -=-:?. the surface Gas Ar · Ne Kr Xe
6 2
a/(atm dm ~ol- ) 1.3 0.2 5.1 4.1
-
b/(10-2 dm3 mol- 1)
3.2 1.7 5.0
1.0
Which gas is expected to have the highest critical
-
\ Liquid molecule in temperature ? · · [9 April, 2019 (Shift-1)1
the bulk (~)" Ki lb) Ne

(A) Surface tension is the outcome of equal attractive and (c) Ar · (d) Xe
repulsion fore.es acting on the liquid mol~ule in bulk. 56. Consider the following table· _.
(8) Surface tension is due to uneven forces acting on the 1
Gas a/(k dm6 mol-1) b/(dm mol-
--
3
)
Pa
molecules present on the surface.
(C) The molecule in the bulk can never come to the liquid A 642.32 0.05196
--
surface.
(D} The molecules on the surface are responsible for
vapour pressure if the system is a closed system.
B
C
155.21
431.91
0.04136
0.05196
---
D 155.21 0.4382
S2. Given below are the critical temperature of some of the a and b are vander waals cons~ant. The correct sta t: ment
l)I
gases: (29 July, 2022 (Shift-II)) about the gases is: · (10 AprU, 2019 (Shift-
(a) Gas C will occupy lesser volume than gas A; gas B S8. Which of the following statement(s) is (are) correct regarding
will be lesser compressible than gas D. the root mean square speed (U nns) and average translational
(b) Gas C will occupy more volume than gas A; gas B kinetic energy (e1 . ) of a molecule in a gas at equilibrium?
will be lesser compressible than gas D. (JEE Adv 2019)
(c) Gas C will occupy more volume than gas A; gas B
will be more compressible than gas D. (a) Urms is doubled when its temperature is increased four
(d) Gas C will occupy lesser volume than gas A; gas B times.
will be more compressible than gas D. (b) eav at a given temperature does not depend on its
S7. A gas has a compressibility factor of 0.5 and a molar molecular mass.· ·
volume of 0.4 dm 3 mot-• at a temperature of 800 K and
pressure x atm. If it shows ideal gas behaviour at the same (c) Unns is inversely
.
proportional to the square
.
root of its
temperature and pressure, the molar volume will bey dm3 molecular mass,
mo1- 1• The value of x/y is . (d) e•• is doubled when its temperature is increased four
[Use: Gas constant, R = 8 x 10-2 L atm K- 1 mol- 1] times.
[JEE Adv 2023)
. ' .
~
• \ ANSWER KEY '\ •
1. [1362] 2. [1567] 3. (b) 4. [22] 5. (b) 6. [927] 7. [70] ~- (c) 9. (a) 10. (d)
11. [750] 12. [3] 13. (d) 14. (45] 15. [4] 16. [152] 17. [29] 18. [8] , 19. [9%0] 20. [80]
21. [32] · 22. [1655] 23. [2] 24. [2] 2S. [2] 26. [26] 27. [84] 28. . (a) 29. [150] 30. [ l]
31. [5] 32. (c) 33. [0.217 to 2.23] 34._(b) 3S. (d) 36. (b) 37. [4] 38. (b) 39. (a)
40. (c) 41. (392] 42. (0.25] 43. (a) 44. [I]
-
4S. (d) 46. (b) 47. (d) 48. (d) 49. (a)
so. [2] 51. [2.00] S2. (a) S3. (b) S4. (d) 55. (a) S6. (c) · S7. (100] 58. (a,b,c)
EXPLANATIONS
1. [1362] The calculation moved here is given as, 300x 103 l.2x 106 = 1200 K
Mole of CO2 = 0.2 M x (300 x ·10-1)L = 0.06 Mole 300 T2
Volume of0.06 mole CO2 at S.T.P = 0.06 x 22.7 :. T in °C = 1200 - 273 = 927 °C
= 1.362 L 7. [70] Apply Gay - Lussac's law as:
2. [ 1567] According to Boyles's low
p P2 35 40
P1V 1 =P 1V2 ...!..=- ⇒ -=-
P,= 940.3 mm Hg Tl T2 300 T2
v, = 100 . = 40 X 300 =342.85 K
V 2 =60 .. T2 35
P.2 =? In celsius,
. 940.3 X l 00 = p 2 X 60 T2( 0 C)·= 69.707 ~ 70°C .
P2 = 1567 _mm of Hg 8. (c) Inter-ionic force ex: charge on the species
.3. (b)
Therefore, ion-ion strength is highest and diPol
dipole strength is lowest.
9. (a) The correct order of interactions are given as,
(A) ion-ion interaction energy is inversely proponi
p
(attn) . to the distance between ions ( ; ) .
(B) dipole-dipole interaction energy is inverse!

-
We know that; PM = dRT proportional to the third power ofr ( ~ J
(C) The interaction energy of London force ·
P=(:)d
inversely proportional to sixth power of distan1
On comparing with, y = mx + C, we get between two interaction particles ( r: J
. RT
Slope, m = -
M 10. (d) The structure of Eihyl acetate is [ CH 3 - ~- OC, H;]
⇒ Slope cx:T, that is higher the slope, higher the T.
Hence, T 3 > T2 > T,. It is a polar molecule, so dipole-dipole and Londoc
4. [22] Pressure of gas = Pressure of moist gas - Vapour forces will be present b_etween them.
pressure of water
11. [750] Apply Boyle's law: .
= 4 atm -0.4 atm = 3.6 atm
PIVI = P2V2
On doubling the volume, pressure of gas i's halved:
48 X } 0· 3 X 33 = p 2 X ) 23
P,VJ = P2 V 2 .
3.6 V 1 = P2 (2V 1) 48x 10· 3

p 2 = - - - = 0.75 X )0· 3 = 750 X }0--6
3.6 4x4x4
-=P
2 2 12. [3] PTVT = nTRT
P2 = 1.8 atm For Cl-1 4
Total pressure= (1.8 + 0.4) = 2.2 atm or 22 x I 0- 1 atm 2 x 2 = n 1RT
s. (b) Assertion is wrong because not all dipole- dipole 4
interactions are responsible for hydrogen bonding. ⇒ n1 =-
RT
6. [927] Apply Gay Lussac's law: For CO2
P1 P2 12
-=-
⇒ n2=-
T1 · T2 RT
72 . 1
For Ne
17. (29] The expression for ideal gas in terms of volume, V is
12 1 . 28
⇒ n 3 = - ⇒ nT =-[4+12+ 12]=- nRT 0.90x0.0821x 300 ·
RT . RT RT V = - - ------x7 60=29.2 1:29
P 18x32
PT= 28 RT 18. [8] Ideal gas equation, PV = n . RT
mix
RT VT
n .= 6xl2.5 =3
PT=~ 28 = 28 =3.11 mUI 0.083 X 300
VT 2+3+4 9 Let moles ofHe is x
13. (d) Wt ofliquid = wight of glass ves_sel filled with liquid Moles ofH 2 = 3 - x
- weight of empty glass vessel = 135 - 40 = 95 gm Total moles of mixture,
Volume of liquid
wt. 95 4x + 2 (3 - x) = 10
. = - - = 100 mL
dess1ty 0.95 x = 2 mo!
Hence, volume of vessel = 100 mL = 0.1 tit · Hence, Mass of He 2 x 4 = 8 gm
19. (9960]
An ideal equation in terms of molar mass (M) is.
PV = nRT PV= nRT
V 1x 0.082 x 300 =
0.82 X] 00 0.5 24900 mL
lOOO =Mx0.082x2 50 1
· 24900
:.M = 125 g/ mol Volume of8i adsorbed perl g Pt = - - = 9960 mL
14. (45] Apply ideal gas equation as: . 20. [80] p 0 =PTotal - P Ne 2.5 .
2
PV = nRT Given: P Total = 25 bar, P Ne = 20 bar.
Now, according to given questio·n, Hence, P O = 25 - 20 = 5 bar
2
(PV)H 2 = (PV) 0 as noz
Po 2 = X0 2 x PToial ------"-xP
n + Total
(nRT)H2·= (nRT\,as oz ., nNe
0.2 3 · /32 ]
-x200=--- X 300 5= X
200
X 25 ⇒ X = 80gm
2 (MM)oas [ x / 32+ -
20 .
(MM)0 35 = 45 gm/mole
15. [4] Using PV = nRT (Ideal gas equation) ·: n =~ 0 == 200) ·
.( oz 32 ' Ne 20. -
Given: P = 1.5 bar, T = 27°C = 300K, V = 416L and
R = 0.083Lbar mot- 1K- 1 · 21. [32] An ideal gas equation is:
1.5 X 416 = n X 0.083 X 300 PV=nRT
On solving, P oc T [n, V, R are constants]
. P 1 = 30 atm, T 1 = 300K
n=25 mo!= W
M Pz = ?, T2 = 318K
Here, M is the molecular weight . P1 P2
25 = 100
.. Ti= T2
. .
M 30 _ P2 . l .
Hence, molar mass, M = 4g/ mo! 300-: 31~ .. P2 =10x318 = 31.8atm::::i32atm
16.(152] Using p = dRT 22. (1655]

. ' M V = 2/ , n = 0.25 Moles, P = 2 x 106 Pa,
Given: P ~ 100 atm, T = 257°C, d = 0.46g/L R = 8.3141 /mol.k
100 From ideal gas law
⇒ P = -atm , T = 257 + 273 = 530 K
760 PV = nRT
M 0.46 xO.OS 2 x 53 0 x760 = 151.93 =152 g/mole 2 x 106 x 2. x 10-3 = 0.25 x 8.314 x T
100 · ._ . . ⇒ T = 1654.7 ::::i 1655K
States of Matter
I
I'
I
:i t4 x J00 + 60 K
I
23. (2) Given, total pressure (P,) • 2.2 bar T = - 15
Ii I
"" (40/2 ) s: 0.914

X11 , =n + n =(40/ 2)+(6 0/ J2) f "" 284K
I
11, o, . 3
I,
'I p • x ic p • 0.914 x 2.2 • 2bar (·: "112.,. o.9 t 4)
147 1
(n, + "2),.,,., -- -28 mol
24. [2] Mus of gas in cylinder when filled; w, • 29 - I4·R
,.,
II
3
' • 14.2 kg _!_,v, +½> = 2"
Mass of gas in cylinder after using, w2 ., 23 - I4.R RT 0
., 8.2 kg p = _3 ) x 8.31 x 284- J Y. IO ., bar = 0}S42,i7 ·

( 28 3xl0 ~
Use ideal gas equation as:
p = 84.28, 10- bar
2
PV =~ RT * 84 x 10 -2 bar
M
28. (a) According to ideal gas equation,
P,V z~ RT ·... (i)
PV = nRT
M
PV =- constant (at constant TJ (Boyle', law)
P2 V =~ RT ... (ii)
P, w,
M
t
pyi ..-- --
Now
• p- = -2 W2
3.47 14.2
--=- P-+
P2 8.2 Hence , PV remairis constant at constant T.
P2 = 2 atm
. . Weight of CH 4 6.4
lS. [2] PV = nRT 29. [150] Mole of CH4 = MI -16 =0.4
oar mass
V = 3. 12 ,c 0.0821 x300 = i.40L
32 · I Weight of CO 2 8.8
and mole of CO2 = M
Vol. of oxygen gas adsorbed per g on Pt metal oar
1 mass 44 =0.2
Total mole = (0.4 + 0.2) = 0.6 mole of non-reac:i
= 2.40 =2 mixture of gas
1.2
nRT
26. (26] Volume ofCH gas = 4 x 103 m3 = 4 x 106 lit
4 Using ; P = - - (Ideal gas equati.on)
An ideal gas equation is: . V
Given: R = 8.314 JK- 1 moJ- 1
:.PV =nRT =~R T V = I0L
M
T.= 27°C = 300 K
PVM J x4x 106 x 16
. p = 0.6 X 8.3] 4 X 300 =
"'=R T= o.os3x 3oo 8 149 _65 ::: ]50 lJ'l
10
= 4xl6x l04 = 257.02x]04 30. · [1] .According to Ideal gas equatio~
0.083x3 g g Given : PV = nRT
= 25. 70 x IO' g • 26 x JO' g P = 1 bar
27. (84] Applying: (n, ... nl)1m111I ::: (n, + nl)final V = 20 ml = 0.020 L
Assuming the iystem attains a final temperature of R = 0.083 L bar mot-1 K-1
T ( Such that 300 < T_< 60) NA= 6.023 )( 1021
(Heat lost by N2 of container I) • (If cat gained by N 1 x 0.020 "" n x 0.083 1 x 273
. 1
of container II)
On solving,
'
,I n,Cm (300 - T) '"' nl c;n<T -60) n • R.8 x 10 4 moles
2·k)(30 0 - T)
= o.i (T - 60) Now,
( 28 2k
N
14(300 - T) "" (T - 60) n :g-
NA
74 . •
N = 8.8 X IO""" X 6.022 X 1023 As n, V and T are constants, SQ,
= 5.3 x 1020 molecules ot' c1 2 · PH, =P02 =PHe = 2atrn
Numbe~ of Cl atom =5.3 x 1020 x 2
= }.Q6 X }021 ~} X }Q21 Hence, PT011I = PHl +Pol + PHe = 6atm
35. (d) PY. = nRT
31. [5] w = 4.75 g
200 x 10 = (0.5 + x)R x JO00
Mass . 4- R
Moes=
I ----
Molar mass On solving x = - -
2R
4.75
n=-- 36. (b) As, the vol. of vessel remains constant
26
740
nl, = n2T2
P=-atm 2
760 Gas left in the volume = n2= ( n - n)
5
( 52n) Tz
An ideal gas equation in tenns of V is:
n x 300 = n - .
y = nRT = 4.75x0.0826x323 SL
3
300 = -5 T2 ⇒ T2 = 500K
P 26(740)
760
32. (c) For ideal gas 37. [4] Urms ~J3~T .
PM=dRT
Given: (Unns)X,600 = (Um)Y,90
d ~ [PM]_!_ ⇒ d ex:_!_ .
R T T_ 3,xRx600 = J2xRx90
40 . . M
. Therefore, graph betwen d Vs T is not str~ight line.
M=4
33.[0.217 to 2.23]
r----- - ---- -- ---, 38. (b) Graph represents symmetrical distribution of speed
. Ideal gas s2 and hence, the most probable and the average speed
:::::::::: s, . - ---
should be same. But the root mean square speed must
be greater than the average speed.
39. (a) For 1 mole ofreal gas
PY ;= ZRT .- (Z = Compressibility factor)
From graph we can see that PV for real gas is less
.~han PV for ideal gas at point.A -
V.=
I
ldm3 . 0.5 m ethylene Z< 1.
glycol in water
· _a_
Z=l--
Kr =2.0 . VmRT
m=0.5 40. (c) vander Waal's constant - 'a'
~Tr= Kpi = 0.5 x.2 (A) Ar= 1.34
Tinilial =_273 K (B) CH 4 =2.25
n=0.J mol I • (C) Hp .= 5.:.46_ ·
V= 1 dm 3 - ., - (D) C H =.18.57
6 6
. Here, 'a' represents the force of attraction and it is

p ·= nRT = 0.lx0.08x273 2_184 atm ·, .
gas .Y 1 directly proportional to the surface area. For all the
After releasing piston, P1V1 =P 2V2 given species, the increasing order value of 'a' is
2.184 X 1 =} X V2 given as, Ar < CH 4 < Hp < C6H6
V 2 = 2:18 dm 3 41. [392] Given,
34. (b) An ideal gas equation in terms of moles (n) and Z1 :: 1.07, P1 = lOOatm, V1 = 0.15L, T1 = SOOK
volume (V) is: 2 2 = 1.4, P2 = 30011tm, T2 = 300 K, V, "" ?
p = ngasRT ~ = P2V2 = n
su V Z1RT1 · Z2RT7
States of Matter
______ _____ ______ ______ _____
r.rrr:;
I,
I I
=Z A >< Vu =(IJ x (.!.J = I
'!
• : I I On suhstituting value, we get, PA
'I I I Pu zH VA 1 2 2
,,I I 00 >< 0.15 ., 300 >< V2
j. 1.07 >< 500 1.4 >< 300 2PA = 3PB
.,I ⇒ V a ~x.03 • 392>< IO~dm

2
1.07
1
47, (d) Vm, = ~ => Vm, oc ~
42. [0.25] For I mole of real gas under high pressure.
ti For N2, 0 2, H2
I
P(V _- b) • RT
PV - Pb • RT
PV Pb ·
[W jW J3~o < <
- - - a: I
RT RT . V ofNi300K) < V ofO2(400K) < V ofH(J
mp • mp • • mp l (JA
48. (d) Extent of adsorption ex: ·critical temp. More will be
z• I + Pb . 2 • I + Pb . Pb = I
RT' RT' RT critical temp. more will be the extent of adsorpti~'
49. (a) Adsorption ex: Vanderwaal attraction forces
⇒ b = RT = 0.83x298
P 99 .
Z = -83 for all real gases
•
s 0.25 >< 10-..2 L mot- 1 C
43. (a) As we know that,

50. [2] Pt "'-.. ,,,,.-critical
. an 2 /~ Isotherm
umt of - 2 = atm
V 2 I
I '
'
. f
atmxunitofV
Th us, umt o a= .
umt of n 2
atmx(dm 3 )2 At
= mol 2
CO2 exist as gas at point a.
= atm dm 6 mol-2 liquefaction of CO2 starts at b.
44. (1] P(Vm-b)=RT liquefaction ends at c.
PVm-Pb = RT CO 2 exist as liquid at d.
Divide whole equation by RT: · Between (b) & (c) ➔ liquid and gaseous CO2 CC>-ffl
PVm _ Pb =l As volume changes from (b) to (c) gas decreases ai
RT RT liquid increases. ·
Pb · A and C both are corr~ct.
Z=l+-
RT St [2.00] Surface tension arises due to uneven forces that s
(!!t = :T on the molecules which are present on the surfac
These molecules one also responsible for the vapcc
pressure, if the system is a closed system.
So comparing with xb
x will be equal to 1 RT Hence; both b and d options are correct. ·
' ' 52. (a) · Higher is t~e Tc, greater is the ease of liquificaJ·)
45. (d) The ratio of speeds are Vfflll : VIV : Vmp = 1' 22 '· I ' 12 ·' 1
and greater 1s the adsorption.
:. Vfflll >VIV >Vmp
53. (b) During the process of heating of glass, constitu
Therefore, Vrm, is greatest Le. point C and· V is .
lowest i.e. point mp. unit of glass body gets ruptured and gives theed~
mp
smoothness.
46. (b) Z = PV/nRT
54, (d) Amount of gas adsorbed oc T
C
P=~
V 55. (u) T =- ~
At constant T and mot: g 27Rb
Greater value of .!. ⇒ higher is T ,
p oc.-
z b C
v Gas%
76 · •
T = 800 K, P = X atm.
Ar .!_2 = 0.406
3.2 AsZ = PVm
02 RT
Ne · = 0.118 Substituting values
1.7
X(0.4) .
Kr ~ = 5.l ⇒ 0.08 X 800 = O.S
l
On solving,
Xe -~ = 0.82 ⇒ X = 80
5
· According to ideal gas, PYm = RT
:. T has order: Kr> Xe> Ar> Ne
C
56. (c) Gas A and C have same value of'b' but differentv
~lue ⇒ V = RT 0.08x800 = 0. 8 L~oJ- '=y
,
'a' have more m P 80
of 'a' so gas having higher value of
force of attraction so molecules will be more doser X 80
hence occupy less volume. Then , y~ 0_8 =:= I00.
Gas B and D have same value of 'a' but different
value of ' b' so gas having lesser value of 'b' will be ·
58. (a,b,c) Urrns, = -M -
)3RT
more compressible.
57. [100] . ·=, Ikr
: Eavg 2
.
Given: Z = 0.5, Vm = 0.4 L/mol : •'
I I
~I
i / •
States of Matter
•
Thermodynamics
I. Whal happens when methane undergoe

s combustion 'in
sysll·ms A nnd B rcspcctivcly'? I13 April,
2023 (Shif'l"-11)1
(a) P
~ y
I
(b) P
~kJ: T
I
Diothermic container
Atliahal ic syslt'lll
System A
-- --Sys1--em--
A
-. -- -- --
(a) 1- -.. ..: _- --- -l~
Temperature rises
System B
-- -- -- i
System 8 --- --- i
--. :.. :-- -:-
Temperature remains same
I
(e) H ~Ill
s
II
(d)
s
T
l" Ill
rgoes two revenJ)

B --,
5. One mol e of an idea l gas at 900 K, unde
em~
Syst- w. If the wo
(h)
System A -.:i--- - ~
1--_____:,;::.___ _ prqcesses, I follo wed by II, as shown belo
Tcmpernture falls Temperature rises e, the value
done by the gas in the two process are sam 1
Syst em 8 V3 [JEE Adv 20!

System A ----- In - is:
(c} 1--- ~ - - --1--- - ~ -remains sam e V2
Tcmpcraturefoils Temperature
sure, V: vollJ/1
(U: internal energy, S: entropy, P: pres
System A System B
__ ;-- -- ,
(cl) I--- - . ! - . . - - ---+-_ perature rises
R: gas constant)
Temperature remains same Tem volume, C,~'
(Given: molar heat capacity at constant
from the followin g 5
2. The lotal number of intensive properties the gas is R )
is_ _ __ 2
0 cell, Gibb s free
Volume, Molar heat capacity, Molarity, E
energy change, Molar mass, Mole
111 April, 2023 (Shift-II))
of state variable is
u
R (K)
225 0 - ---r··:·)
I .
3. Among the following the number II
128 July, 2022 (Shift-II)) 450 · ····
(P2,V2) (p3,V3>
Internal energy (U) Volume (V)
S(J K·1 moI·1)
Heat (q) Enthalpy (H)
rsible isothermal 6. Among.the following the set of para
meters that represtl
4. An ideal gas undergoes a reve [9 April, 2019 (Shill·
1
by a reversible path function is:
expansion from state I to state II followed
Ill. The correct (A) q + w (C) q
adiabatic expansion from state II to state
I to state III is (D) H - TS
plot(s) representing the changes from state (8) w
(b) (B), (C) and (D)
e, H:enthalpy, (a) (B) and (C)
(are)(p:pressure, V:volume, T:temperatur
fJEEAdv 2021 1 (c) (A), (B) and (C) (d) (A) and (D)
S:entropy
7. The combination of plots which do not represent isothermal 12. Wh e n 5 m o les o f He g as ex pa nd iso th e rm a ll y a nd
:~~:cz:deal is;B)I:,~O (Shin-Il)J

gM 19
reversibly at 300 K from IO litre to 20 li tre, the magni tude
o f th e max imum wo rk ob ta ined is _ _ _ J. ( nearest
integer) [G iven: R= 8.3 JK I mol an d log2 = 0 .30 I OJ
I
f27 Jun e, 2022 (Shift-11) 1

O Vm 13. 4.0 L o f an idea l gas is a ll owed to expand isotherma lly
/
INm
ulL_
0
(C) PVL 0 p
(D)
into vacuum until the tota l vo lume is 20L. The amount of
heat absorbed in th is expansion is_ _ _ _ L atm .
128 June, 2022 (S hift-1)1
14. , Five moles of an ideal gas at 293 K is expanded isothermally
0 vm
from an initial pressure of 2.1 MPa to 1.3 MPa against at
(a) (B) and (D) (b) (A) and (C) constant external pressure 4.3, MPa. The heat transferred in
(c) (B) and (C) (d) (A) and (D) this process is__· _kJ moJ- 1• (Rounded -off to the nearest
in teger). ·
[Use R = 8.314 J mo1- 1 K- 1J (25 Feb, 2021 (Shift-JI)]
First Law of Thermodynamics 15. A system does 200 J of work and at the same time
and Applic ations of Work ·oone absorbs 150 J of heat. The magnitude of the change in
internal energy ·is_ _ _ _ J. (Nearest integer)
8. 1 mole of ideal gas is allowed to expand reversibly and
adiabatica lly from a temperatu re·of27°C . The work done 16. At 25°C, 50 g of iron reacts with HCI to form FeCli- The
1
is 3 kJ mol- • The final temperatu re of the gas is - - - evolved hydrogen gas expands against a constant pressure
K (Nearest integer). Given C v. = 20 J mol- 1K - 1• of 1 bar. The work done by the gas during this expansion
[30 Jan, 2023 (Shift-II)] is _ _ _ _ J. (Round off to the nearest integer).
9. When 2 litre of ideal gas expands isotherma lly into [Given: R= 8.314 J mol- 1 K- 1• Assume hydrogen is an ideal gas]
vacuum to a total volume of 6 litre, the change in internal [Atomic mass of Fe is 55.85u]
energy is J. (Nearest integer) [30Jan, 2023 (Shift-I)] [16 March, 2021 (Shift-II))
10. One mole of an ideal monoatom ic gas is subjected to 17. Five moles of an ideal gas at 1 bar and 298 K is expanded
changes as shown in the graph. The magnitude of the into vacuum to double the volume. The work done is:
work done (by the system or on the system) is _ _ _ J
(4 Sept, 2020 (Shift-II))
(nearest integer).
(a) Cy(T2 - T,) (b) -RT ln V2N
1
(c) zero (d) -RT V 2N 1
rOl----li~: :
18. The magnitude of work d9ne by a gas that undergoes a
reversible ·e xpansion along the path ABC shown in ·the
I!) 0.5 figure i s - - ~ ' - - (8 Jan, 2020 (Shift-I)]
3
Pressure
"'"'
I!)
~ (Pa) 1O
A
-8 T"------- ..
B
20 40
Volume (L) 6
4
Given: log 2= 0.3, ln 10 = 2.3 [24 Jan, 2023 (Shift-II)]
11. 2.2 g of nitrous oxide (N20) gas is cooled at a constant (2, 2) 10 12 Volume
4 6 8
pressure of I atm from 310 K to 270 K causing the (m' )
compression of the gas from 217.1 mL to 167.75 mL. The · 19. In thermodyn amics the P-V work done is given by
change in internal energy of the process, ~U is '-x' J. The
value of 'x' is-~-· [nearest integer]
w = -JdV P
0, 1 •
(Given: atomic mass of N = _14 g moJ- and of O = 16 g For a system undergoin g a partic ular process, the work
1
1
moJ- • done is,
Molar heat capacity of NP is I 00 J K- 1 mot- )
1

w =-Jdv(~-~) V- b Y2
lJEE Adv 2020)
9
This ~uatif•n is arrlkaMc tl, a:
IWI 1
20.
(a) S~"'S1t.,u lh."lt 5.lti:-6'.-s d11: van '1,.,- Waals 1.-qu.1ti,,n ,,rstatc.
(b\ Pn,~ that is reven-iMc and is,,thcnnal.
(d Pnx'\.--ss that is re,"·n.ihlc and lhtiahalk.
(.i) Pr\,~~ that is im:-,'--n.ihk an1.t at '-"-'nstant is,,thcnnal.
0 1.----:l-n -:-:V
(d)
J;l,
o----
During '-'-"1lJ'l\."SSi1.,n ,,fa spring. the work ,tone is IO k.l
In V
and ~ U ~"3('00 ''-' th(- sumll11·11.fot~~ as heat. The change in 25. An ideal gus is allowed to expand from I L to Io L
internal e~~Y- ~L' (in kJ) is: (9 April, 2019 (Shift-II)(
a constant externul pressure of I bar. The work d ag-4'
(d) 8 (/'>) 11 onei,,
(d -I~ is ll2April,2019(SL• 1
(d) -8 . ,,,r,i
21. f<-'r (a) - 9.0 (b) + I 0.0
a diatl,mic ideal gas in a dosed system. which
<-'f the t,,nowing plots d1.x-s not correctly describe the (c) -0.9 (cf) - 2.0
relation t>etween various thennodynamic quantities? 26. One mole of ari ideal monoatomic gas undergo
(12 Jan, 2019 (Shift-I)] es ~
reversible processes (A ➔ B and B ➔ C) as shown .
In (
given figure: [JEE Adv 2()~
(b)U ~
T
(~½L
22. 5 moles of an ideal gas at 100 K are allowed to undergo
T
reversible compression till its temperature becomes 200 10

K.. If C,.. = 28 J K- 1 moI- 1, calculate ~U and ~p V for this Volume (m3)
process. (R = 8.0 J K- 1 moI- 1] (8 April, 2019 (Shift-II)] A--+ B is an adiabatic process. If the total heat absorbc
(a) .:11_; = 14 kl; ~(pV) = 4 kJ in the entire process (A--+ Band B--+ C) is RT ln 10,lh
2
(b) ~U = 14 kJ; ~(pV) = 18 kJ value of 2 log Y 3 is _ _ __
(c) ~l: = 2.8 kJ; ~(pV) = 0.8 kJ
[Use, molar heat capacity of the gas at constant pressUit
(d) ~u = 14 kJ; ~(pV) = o.8 kJ
Cp,m = 5/2R]
23. \Vb.icb one of the following equations does not correctly
represent the first law of thermodynamics for the given
processes involving an ideal gas? (Assume non-expansion Enthalpy Change, ~H of a
work is zero) [8 April, 2019 (Shift-DJ
Reaction & Enthalpies for
(a) Cyclic process: q = -w
( b) Isothermal process : q = - w
fc) Adiabatic process : ~U= - w
(d) Isochoric process : ~U= q
24. Consider the reversible isothermal expansion of an ideal
-----...
Different Types of Reactions
27. Given
---- ------
[10 April, 2023 (Shift-Ill
(A) 2CO(g) + O/g) ➔ 2CO/g) ~H ~ = -x kJ mol-
1
gas in a closed system at two different temperature T &T

(T 1<T2 ) The graphical depiction of the dependence of
1 2 (B) C(graphite) + O/g) ➔ CO (g)
2
~H~ =-y kJ mol
8
work done (w) on the final volume (V) is The ~H for the reaction
(9 Jan, 2019 (Shift-I)]
C(graphite) + ..!_ O/g) ➔ CO(g) is
IWI
1w1YT2 T, (a)
x-2y
2
x+2y-
(a) (b) . 2
(b) 2
0
o..______ (c) 2x -y
lnV (d) 2y - x
In V 2
28. 0.3 g of ethane undergoes combustion at 27"C in a bomb
35. A 2 + B 2 ➔ 2AB-~H7 = - 200kJrnol - 1 AB, A 2 and 8 2 are
calorimeter. The temperature of calorimeter sys te m
(including the water) is found to rise by 0 .5°C. The heat diatom ic molecule. If the bond enthalpies of A2 , 8 2 and
evolved during combustion of ethane at constant pressure AB arc in the ratio I :0.5: I, then the bond entha lpy of A 2
is _ _ _ _ _ _ kJ mot-•. (Nearest integer) is _ _ _ _ kJrno l 1 (Nearest integer)
[Given: The heat capacity of the calorimeter system is I 13 April, 2023 (Shift-1)1
20kJ K- 1, R = 8.3 JK- 1 mot-•.
36. Solid fuel used in rocket is a mixture of Fe/) 1 and Al (in
Assume ideal gas behaviour. ratio I : 2). The heat evolved (kJ) per gram of the mixture
Atomic mass ofC and Hare 12 and I g mol 1 rcspcdivcly] is _ _ (Neatest integer)
( 1 Feb, 2023 (Shifl-11)) Given : ~H~ (A lp 3
) ::: - 1700 kJ mol 1
p
29. An athlete is given 100 g of glucose (C6H 1 6) for energy. M-1~(Fep3) = - 840 kJ rnol 1
This is equi,·alent to 1800 kJ of energy. The 50% of this

Molar mass of Fe, Al and O are 56, 27 and J 6 g mol 1
energy gained is utilized by the athlete for spmts activities.at
respective ly. f t3 April, 2023 (Shift-I JI
the event In order to avoid storage of energy, the weight of
extra water he would need to perspire is g (Nearest integer) 37. Consider the fol lowing date
Assume that there is no other way of consuming stored Heat of combustion of H2(g)= - 241 .8 kJ moJ· 1
energy. Heat of combustion ofC(s) = - 393.5 kJ mol_,
Given: The enthalpy of evaporation of water is 45 kJ mo1- 1 Heat of combustion of C 2HpH(I) = - 1234. 7 kJ mol-'
Molar mass ofC, H & 0 are 12.1 and 16 g m6t- 1• Th~ heat of formation ofC2HpH(I) is(- ) _ _ k:J moJ-'
[25 Jan, 2023 (Shift-I)] (Nearest integer) [6 April, 2023 (Shift-lJJJ
38. Enthalpies of formation of CClig, Hp(g), CO/ g) and
30. The enthalpy change for the conversion _!_Cl 2 ( g) to
2 HCJ (g) are-105, -242, - 394 and-92 kJ moJ- 1 respectively.
CJ-(aq.) is(-) _ _ _ _ kJ moI- 1(Nearest integer) The magnitude of enthalpy of the reaction given below is
kJ mo1- 1
Given, AdisH~1:?(g) = 240kJmol- 1 ---
(nearest integer)
Ae2H~1
- g)
= -350kJmol-1 CClig)+2Hp (g) ➔ COiCg) + 4HCl(g)
0 1 (31 Jan, 2023 (Shift-II)]
AbvdH ci-
- (&)
= -380kJmol- [31 Jan, 2023 (Shift-I)]
39. At 25°C, the enthalpy of the following processes are given:
31. When a 60W electric heater is immersed in a gas for 100s
in a constant volume container with adiabatic walls, the H/g) + O 2(g) - 2OH(g); AH 0 = 78 kJ mot- 1
temperature of the gas rises by 5°C. The heat capacity of H/g) + ½ O 2 (g) ➔ Hp(g); AH 0 = -212 kJ moI- 1
the given gas is ___J K- 1 (Nearest integer) · H/g) - 2H(g); LlH = 436 kJ moJ- 1
0
[8 April, 2023 (Shift-I)] ½ O 2(g) ➔ O(g); .llH 0 = 249 kJ mo1- 1

32. The number of endothermic process/es from the following What would be the value ofX for the following reaction'?
is__ _ _ [10 April, 2023 (Shift-II)] _ _ (Nearest integer)
(a) l 2(g) ➔ 21(g) (b) HCl(g) ➔ H(g) + Cl(g) Hp(g) ➔ H(g) + OH(g); AH 0 = X kJ mo1- 1
(c) Hp(l) ➔ 8iO(g) (d) C(s) + O/g) ➔ CO2(g)
[l Feb, 2023 (Shift-I)]
(e) Dissolution of ammonium chloride in water
40. At 25°C and 1 atm pressure, the enthalpy of combustion
33. 28.0 L of CO2 is produced on complete combustion of 16.8 of benzene (1) and acetylene (g) are - 3268 kJ mot- 1 and
L gaseous mixture of ethene and methane at 25°C and I - 1300 kJ mol- 1, respectively._The change in ~nthulpy for
atm. Heat evolved during the combustion process is kJ.
the reaction 3C 2 H/g) ➔ C 6 H0 (1), is
Given: AHc(CH 4) = -900 kJ mol- I
(25 June, 2022 (Shift-11)1
AHc(C 2HJ = -1400 kJ moJ- 1 {25 Jan, 2023 (Shift-11)1
(a) +324 kJ mol 1 (b) +632 kJ mol 1
34. For complete combustion of ethene. 1
(c) - 632 kJ mol (d) - 732 kJ mot 1
C 2 H◄<g) + 3OiCg) ➔ 2CO 2(g) + 2H 2O(I) ~he am? unt of
heat produced as measured in bomb calonmeter 1s 1406 41. Which of the fo llowing rdation is not l'OITl!l't'?
kJ mo1- 1 at 300K. The minimum value ofTAS needed to (28 July, 2022 (Shift-I)!
reach equilibrium is(- ) _ _ _ _ kJ. (Nearest integer) (a) AH ;= LlU - P.ll V (b) LlU =q + W
Given : R = 8.3 JK-1 mo1- 1 [8 April, 2023 (Shift-II)) (c) LlS,y~ + AS""" ~ 0 (d) AG ;, M-1- TAS
•U, ( ·, !io) 1 ( I.(~ I • ( 't I,(~ I t ·11111 ~.I /\ JJ.ll li ( M11l111 llllli1H - 7-HIJ jJ, ,,,,,, J) WIii\ ""'"' i,
i
, 1:ti:r 1111, I d1iri ., .'~x,~.·li\,
cuI1 111111
, . I I11 111•01111111111 I \'II 111111: 11 ,., (;1 ,,,,1 .
$ "') t I 00 ~ I
..
( t "'I I , t \ ,( I.$ • C 'I
11111 IC'lllfll'l'llllll ll "' '11f,,,i11 wl1:r 11,cri:a,":" fr<1111 2, ' %,
?. 1Jlt,'I'\ K, lf'tli1~ fw111 rnpw lty o l' c11 f1Jri1111;f1:r ;.1 2,;,'~·'1~1
1
\\'h,·11 ,·,,1111111111111,· hll",, ,,. 11ll11w1•1I 111 h11111111 p11•111·1w11

,,r 111,111111"11·11111,,.,,•11, r,11 11
11 111r111h11111,. ,,.,11v, 11h'tl 111111
,. ' ' ,. . I k
l' III I 111 IPYII C:11111 III HIIIIII ,, /J.IIH IH ) ., ,,,,,, ' II,
,.J r.'\,
lt/J lt/
'( ., l' "'"' ''"' l\'llll;llll11v, I" n1m·,·1h',I 111111 '( '( ,, ' , 'I Ill' 111'111 111' 1~1111 h11ml iH v,. (N1;;1rc;1,1 ; 111,,,,
.,._.:,, ,,,,_
>''''"'' ,,11,,t "h,•11 0.h ~l,l of ,•11111 I" h11111I I" 127 ,July, 2022 (''t
•1 1lfLfl
I Z\J ,lul~•• lOU (Shift-II )I ~o. The ,.,1111d111'd e11tmpy cluu,v,c li,r tl1c rc:11;ti,m I
\,1) I hOll Id (/t) ,\:1110 ti
tlf 1c:(tt) I J ()l (p,) ~ 2l'e/)/HJ hi 55<JJK 'al2'J%J<
kl -l•ll\11 Id (di r,11110 ~.I
IC flvc11: 'l'l1e Hl11111lurd 1.:11 tliufpy dw11v,e fi,r the rc:i ..
◄.\, :\1 ~ ~•·, ' nnil I 111m p,,·~~111,•, th,• 1•111hnlpl,•" ot\•1111il111r11l1111
I <,1 k.1 111of ' J . '/'fie lct11pem l1,rc in K al which Uic ~'.''111 •
111,• "" i,:,wn lwl11w : 124 ,lttlll', 2022 (Shll'l-11)1 l 'J'f . , rc'11,t~
111111 II H cq111 1 >r111111 '"· _ • . __ (Nc:Jrc,it inv:,,,.'
S11h~tnn,·,• '-''I
12~ ,Jun~, 2022 (St,irt
.\ II A li1d1 HW in11ning in wuter hody when taken ,,ut f 1
rcirr1~
JC),1 ,(1 1~,,o.o
\
:' Sh.0 w11ter hody iHcovered with a lifm of water of weigh,
Id 111111 I 1
When it iHHul~jecLcd to cooking at I{)(J'•C, then the in .lf1
c,wrgy ,.or vaponzat,on
, . ,n . kJ mo , I tH
• (N
k.77.
Th,· 1.·111hnl11y 111' formnt i1111 of clh11111: iH
.1nlegurJ , - -· ea,~
(11) 1 ~.to Id mot 1 (/,) • <iH ,O kJ n1ol 1
(c') 1'6.0 k.lmnl 1 (ti) ·I "7.0 kJ nwl 1 IAHtHl me Htcam lo be an ideal gas, Given .6••pH' forw-alt 1
4~. F11r 1.·ompk11.• 1.·omh11st ion of' 111ctlrn11ol al 373 K and I har iH4.1 kJ mol 1
, R-=: 8.3 I JK- 'mof 'I
J 126 ,June, 2022 (Shift-Hi
Cit ,OI I( f') +- -2 O ,(g)- ('() (g) ·t 211 0(/1)
. J 2 52. Whil e perl'orrni ng a thermodynamics expcrimeni
,I
The llllHHllll of hcul produced 1111 111cus11rcd hy bomh Hludenl made the following observation.
1·11lori1m:tcr is 726 k.111101 I Lil 27°C. I ICI ➔ NaOl I ➔ NaCl + I 1/) .61I = - 57.3 kJ moJ-1
Th1.· enthalpy of com bust ion 1hr the rcucl ion iH x kJ mol 1, Cl l 1COOI I I NaOl l ➔ CI l 1C<X)Na+HptiH =-55J klmt
where x ii._ _ _ _ . (Ncurest i11tcgur)
The enthalpy of' ionization of'CH 3 COOH as calculated ~,
(Given : R "' 8.3 J K 1 mol 1) 12<, June, 2022 (Shlff,.1)1 the student is _ _ _ _ kJ mol 1• (Nearest integer)
4~. For combustion of one mole or mugnesi um in on open
125 July, 2022 (Shift-HJ
c(lntuiner at 300 K und I bur pressure, t\ .11~1 ::, - 60 I.70kJ
. 53. 2.4 g eo<1 I is burnt in a bomb calorimeter in excess a ·
mot·1• the magnitude of\:hnnge in inlernnl energy fhr thu
reaction is _ _ _ _kJ. (Nearest integer) oxygen al 298 K <111d I atm pressure. The temperatured
the calorimeter ri ses from 298 K to 300 K. The enthal~
(Given: R = 8.3 J K·1 mot· 1) 128 June, 2022 (Shlfl-11)1
ch<1nge during the combustion of coal is - x kJ mo1· 1. Th
46. 17.0 g of NU.I" completely vupouriseli ut - 33.42°C and I
value of x is _____ . (Nearest Integer)
bar pressure and the enthalpy chunge l'or the process is
23.4 kJ mot 1. The chunge for the vupourisulion of' 85 g (Given: I Icat cap<1city of bomb calorimeter 20.0 kJ K-1.
of NH J under the same conditions is ___ kJ . Assume coal to be pure carbon) 126 July, 2022 (Shift-ij
129 June, 2022 (Shlft-1)1 54. The molar heat capacity for an ideal gas at constao
47. The enthalpy of' coJ11bustion of' propane, graphite und pressure is 20. 785 J K 1mol 1. The change in intern~
di hydrogen at 298 K arc - 2220.0 kJ mol 1, - 393.5kJ mol 1 energy is 5000 J upon heating it from 300 K to 500 K
and - 285.8kJ mol 1 respectively. The magnitude of' the The numbur of moles of the gas at constant volume ~
enthalpy of formution of propane C) IKis _______ kJ _ _ _ _ . (Nearest integer)
mol 1 (Nearest integer) 125 July, 2022 (Shift-1)1 (Given: R= 8.3 14 JK 1mof- 1) . (27 July, 2022 (Shift-IM
48. For the reudion 55. When 600 mL of 0.2 M HN03 is mixed with 400 mL d
11 1 1~, (g) ➔ l l1 (g) + t·;(g) 0. 1 M NaOl I solution in u flask, the rise in temperatUJ!
6U = - 59.<ikJ mol al 27"C or the llusk is - - - - X I0- 2 "C.
I
The enthalpy change for the above reaction is ( - ) •- • kJ (Enthalpy of'nculralization = 57 kJ mo1· 1 and Specific he;
of' water = 4.2 J K · 1 g· 1) (Neglect heal capac ity of flask)
1 1
11101 1, l nearest inlcgerJ Uiven: R "' 8.314 JK 11101 •
126 July, 2022 (Shlt'l-11)1 129 July, 2022 (Shift-Ill
82 · •
2.4 g coal is burnt in a bomb calorimeter in excess of 64. The reaction of cyanamidc, NH ,C N(s) with oxygen
oxygen at 298 K and 1 atm pressure. The temperature of was run in a bomb ca lorime ter and [I..U was found to be
the calorimeter rises from 298 K to 300 K. The enthalpy - 742 .24 kJ mol 1• T he magnitude of l\l Im for the reaction
change during the combustion of coal is -x kJ mol- 1• The
value ofx is _ _ _ _ _ . (Nearest Integer)
NI·\ CN(S) +I Oig) ➔ Nig) +OiCg) + Hp(l) is _ _ kJ .
2
(Given: Heat capacity of bomb calorimeter 20.0 kJ K 1• 125 Feb, 2021 (Shift-I)!
Assume coal to be pure carbon)l26 July, 2022 (Shift-l)l 65. According to the following figure, the magnitude of the
57. At 298.2 K the relationship between enthalpy of bond enthalpy change or the reaction
1
dissociation ( in kJ mol - ) for hydrogen (Ell) and its A + B ➔ M + N in kJ mol I is equal to ____ .
isotope, deuteriwn (En), is best descdbed by: (Integer unswer) 131 Au~, 2021 (Shift- f)f
[25 July, 2021 (Shift-1)1 x = 20 kJ mol 1
I A+ B y= 45 kJ mol 1
(b) EH =- Eo
.2 .
l. y
z = 15 kJ mot ·'
j ·--+-
(c) EH = 2E0 (d) EH .:::: E0 - 7.5
58. The average S - F bond energy in kJ mo1- 1 of SF 6 is M +N
(Rounded off to the nearest integer)
[Given : The values of standard enthalpy of formation Reaction Coordinate
of SF6(g), S(g) and F(g) are - 1100, 275 ;:md 80 kJ mo1- 1 66. Asswning ideal behaviour, the magnitude of log K for the
1
respectively.] [26 Feb, 2021 (Shift-II)] following reaction at 25°C is x x I 0- •
59. The Born-Haber cycle for KCl is evaluated with the The value ofx is _ _ _ _ (integer answer)
following data: 3HC = CH(g) ~ C 6 H/l)
[Given: [l..p 0 (HC = CH) =-2.04 x 105 J moJ- 1; [l,,p (C6 HJ
0
dfle for KCl =-436.7 kJrnoI- ; d subH for K = 89.2 kJrnol-
1 9 1
;
d .. . H 9 for K = 419.0kJrnoI- 1; [1.. e1ectronga .mH 9 for Cl(g) = - 1.24 x I 0 5 J moJ- 1: R = 8.314 JK- 1moJ- 1]
1omza11 on
= -348.6kJmoI- 1; (24 Feb, 2021 (Shift-II)]
~ondw~ forCl2 = 243 .0kJmol-

1 67. The ionization enthalpy of Na+ formation from Na(g)
The magnitude of lattice enthalpy of KC! in kJ rno1- 1 is is 495.8 kJ mol- 1, while the electron gain enthalpy of Br
[26 Aug, 2021 (Shift-I)] is - 325.0 kJ moJ- 1• Given the lattice enthalpy of Na Br is
_ _ _ (Nearest integer)
-728. 4 kJ mol- 1• The energy for the formation of NaBr
60. For·water [I,,\'ap H = 41 kJ mol- 1 at 3 73 K and 1 bar pressure.
ionic solid is(-) _ _ x 10- 1kJ moJ- 1•
Assuming that water vapour is an ideal gas that occupies a
[25 Feb, 2021 (Shift-I))
much larger volume than liquid water, the internal energy
change during evaporation of water is _ _ _ _ kJ mo1- •
1 68. When 400 mL of0.2 M H 2SO4 solution is mixed with 600
[Use: R = 8.3 J rnoI- 1 K- 1] (26 Aug, 2021 (Shift-II)] mL of 0.1 M NaOH solution the. ihcrease in temperature
of the final solution is _ _ _ _ x 10- 2 K.
61. For the reaction C2H 6 ~ C2H 4 + 8i, the reaction enthalpy
[l..,H = _ _ _ _ _ kJ mo1- 1• (Round off to the nearest (Round off to the Nearest Integer)_.
integer). [Use: H+(aq) + OH- (aq) ➔ Hp : [l..rH = -57. l kJmol - 1]
1
[Given: Bond enthalpies in .kJ rnol- : C - C: 347 , Specific heat of H,O = 4. 18 JK- 1g- 1
C = C: 611; C-H: 414, H - H: 436] Density of H 2O = 1.0 gcnr3
[18 March, 2021 (Shift-I)] [Assume no change in volume of solution on mixing]
62. At 298 K, the enthalpy of fusion of a solid (X) is 2.8kJ 127 July, 2021 (Shift-ll)I
mo1- 1 and the enthalpy of vaporization of the liquid (X) 69. 200 mL of 0.2 M HCI is mixed with 300 mL of 0.1 t\l
is 98.2 kJ rno1- 1• The enthalpy of sublimation of the NaOH. The molar heat of neutralization of this reaction is
substance (X) in kJ mo1- 1 is _ _ _ _ _ . (in nearest - 57.1 kJ . The increase in tcmpemtut~ in °(' of the system
I
2
integer) [25 July, 2021 (Shift-I)] on mixing is x x I0 - • The vuluc of x is · ·
63. If the standard molar enthalpy change for combustion of · (Nearest integer)
of water = 4. l ~ J g ~ Dt'nsitv
1 1 1
graphite powder is -2.48 x I 0 2 kJ mol- , the amount of [Given: Specific hcnt l,f
I I •
heat generated on combustion of I g of graphite powder water = ~.00 g cm · 1
is _ _ _ _ kl. (Nearest integer) (Assume no vo l11111c change on mixing)
!' 122 July, 2021 (Shift-11)1 127 Aug, 202 I (Shin-1)1
l
70. The standard enthalpies of fonnation of Alp, and CoO 79. Tin is obtained from cnssiterite by reduction With
are -1675 kJ mo1-1 and -635 kJ mo1-1 respectively. Use the data given below lo determine the . _co~,
• . I . 111 1n1ni
temperature (in K) at which I 1e reduction of ca .. ~~
For the reaction ssucr·
by coke would take place. 1~
3CaO + 2Al ➔ 3Ca +A~O
• 3
the standard reaction enthalpy
l\H' = _ _ _ kJ. At 298 K: ~,H"(SnOz(s)) =-581.0 kJ mol 1, 1\H"(Co
= - 394.0 kJ n10l -1 i!ijJ1
(Round off to the nearest integer).
S0(SnO (s))=56.0 J K-1 mol -1, S"(Sn(s))52.0 J K I rn
117 l\tarch, 2021 (Shift-I)! 2 OI I
S"(C(s)) = 0.6 J K-1mol· 1, S"(CO/g)) = 210.0 J KI n, '
71. For water at l00°C and I bar 01 1
..,, ·~
· A,...,H - .6. U =
-- x 102 .I mo\-1
Assume that the enthalpies and the entropies ·
temperature independent. [JEE Adv 20;~
80. The difference between ~H and ~U (6H - 6U), when ~
(Round off to the Nearest integer)
[Use: R = 8.3 l J mo1· 1 K·'] combustion of one mole of heptane(/) is carried out ~
[Assume volume of H,O(/) is much smaller than volume temperature T, is equal to [10 April,. 2019 (Shirt.::,
ofHp(g). Assume H2O(g) can be treated as an ideal gas] (a) 3RT (b) - 3RT ij
[27 July, 2021 (Shift-I)) (c) - 4RT (d) 4RT
72. An average person needs about I0000 kJ energy per day. 81. An ideal gas undergoes isothermal compression fro
The amount of glucose (molar mass= 180.0 g mol-1) 5 m3 to l m3 against a constant external pressure or~
needed to meet this energy requirement is_ _ _ g, Nm-2• Heat released in this process is used to increase~
(Nearest integer) . temperature of I mole of Al. If molar heat capacity of Ai
(Use: .6.cH (glucose)= -2700kJ mo\- 1) is 24 J mol-1 K- 1, the temperature of Al is increased by:
(20 July 2021 (Shift-I)) [10 Jan, 2019 (Shift-lQI
73. Lattice enthalpy and enthalpy of solution of NaCl are . 3
(a) -K (b) 2 K
788 kJ moJ-1 and 4 kJ mo1-1, respectively. The hydration 2
enthalpy of NaCl is: (5 Sept, 2020 (Shift-II)]
2
(a) 784 kJ moJ- 1
(b) -784 kJ mol- 1 (c) -K (d) I K
3
(c) 780 kJ moI-1 (d) -780 kJ mo1-1
82. For silver, Cp(JK-1mol-1) = 23 + 0.01 T. If the temperature
74. If enthalpy of atomisation for BriCJ) is x kJ/mol and bond (T) of3 moles of silver is raised from 300K to I000K ai
enthalpy for Br2 is y kJ/mol, the relation between them: I atm pressure, the value of 6 H will be close to:
(9 Jan, 2020 (Shift-I)) (8 April, 2019 (Shift-DI
(a) is x = y (b) is x > y (a) 21 kJ (b) 16kJ
(c) does not exist (d) is X < y (c) 13 kJ (d) 62 kJ
75. The standard h'eat of formation(~fl~ 98 ) of ethane . 83. Enthalpy of sublimation of iodine is 24 cal g-1 at 200° C.
(in kJ/mol), if the heat of combustion of ethane, hydrogen If specific heat of 1i(s) and 1/vap) are 0.055 and 0.031
and graphite are -1560, -~93.5 and -286 kJ/mol cal g-1 K- 1 respectively, then enthalpy of sublimation of
respectively is _ _. [7 Jan, 2020 (Shift-II)) iodine at 250°C in cal g-1 is: [12 April, 2019 (Shift-DI
76. At constant yolume, 4 mo) of an ideal gas when heated (a) 2.85 (b) 11.4
from 300 Kto 500 Kchanges its intema_lenergy by 50001. (c) 5.7 (d) 22.8
The molar heat capacity at constant volume is _ _ 84. Given: (12 Jan, 2019 (Shift-11)1
[8 Jan, 2020 (Shift-II)) (i) C(graphite) + O/g) ➔ CO 2(g); ~,H° = x kJ mol·
1
77. The heat of combustion of ethanol into carbon dioxide and

water is -327 kcal at constant pressure. The heat evolved (ii) C(graphite) + ¾O (g) ➔ CO(g); 6,H° = y kJ mol·
2
1
(in cal)- at constant volume at 27°C (if all gases behave

ideally) is (R = 2 cal mol· ' K-1) [2 Sept, 2020 (Shift-II)) (iii) CO(g) + ¾O (g) ➔ CO (g); ~,H
2 2
0
= z kJ mol·
1
1
78. The internal energy change (in J) when 90 g of water Based on the above thermochemical equations, find 0~
undergoes complete evaporation at I 00°C is _ _. which one of the following algebraic relationships 15
[To the nearest integer] correct?
(Given: ~H vap for water at 373 K = 41 kJ/mol, R = 8.314 (a) x=y+z (b) z=x+y
J K- 1 mol· 1) [2 Sept, 2020 (Shift-I)) (c) y = 2z-x (d) X = y - z
I
85. Choose the reaction(s) from the following options, for
91. Match the List-I with List-II (27 June, 2022 (Shift-I))
which the standard enthalpy of reaction is equal to the
List-I List-II
standard enthalpy of fonnation. [JEE Adv 2019)
(A) Spontaneous process (I) AH < 0
(a) i2 o; (g) ➔ 03 (g) (8) Process with ~p· = _0 , (II) AGT,P < 0
AT =0
1 (C) AH rcncllon
(b) Sg(s) + O 2(g) ➔ SO2(g) (llf) Isothermal and Isobaric
8 process
(c) 2H2(g) + O/g) ➔ 2Hp(l) (D) Exothermic Process (IV) [Bond energies of -
(d) 2C(g) + 3Hi(g) ➔ C H (g) molecul es in reactants]
2 6
-[Bond energfos of
product mol ecules]
Spontaneity, Entropy, Gibbs Choo~e the correct an swer from the option g iven below:
. (a) (A)-(lll), (B)-(11), (C)-(IV), (O)-(I)
Energy_Change and Equilibrium (b) (A)-(ll), (B)-(lll), (C)-(IV), (D)-(J)
(c) (A)-(Il), (B)-(III), (C)-(1), (D)-(IV)
86. Which of the following relations are correct? (d) (A)-(II), (B)-(1), (C)-(IIl), (O)-(IV)
92. Given below are two statements : One is labelled as
(A) AU = q + pAV (B) AG = AH - TAS
Assertion A and the other is labelled as Reason R
(C) AS= q ,..,v (D) AH = AU - AnRT (28 July, 2022 (Shift-II)]
T Assertion (A): The reduction of a metal oxide is eas ier if
Choose the most appropriate answer from the options the metal formed is in liquid state than solid state.
given below: [29 Jan, 2023 (Shift-II)] Reason (R): The value of AG 0 becomes more on negative
(a) (C) and (D) only (b) (B) and (C) only side as entropy is higher in liquid state than solid state.
(c) (A) and (B) only In the light of the above statements, choose the most
(d) (B) and (D) only
appropriate answer from the options given· below
87. One mole of an ideal gas at 350K is in a 2.0 L vessel of
(a) Both A and R are correct and R is the correct
thermally conducting walls, _w hich are in contact with explanation· of A
the surrounding s. It undergoes isothermal reversible . (b) Both A are Rare correct but R is NOT the correct
expansion from 2.0L to 3.0L against a constant pressure explanation of A
of 4 atrn. The change in entropy of the surrounding s (AS) (c) A is correct but R is not correct
is _ _ _ J K- 1 (Nearest integer) (d) A is not correct but R is correct
Given: R = 8.314 J K- 1 Mol- 1• [12 Ap.ril, 2023 (Shift-I)] 93. The incorrect expression among the following is:
88. For independent process at 300 K. [31 Aug, 2021 (Shift-II)]
0
Process AH/kJ mo1- 1 AH - TAS 0
AS/J K- 1 (a) lnK = - - - -

A - 25 -80 RT
B - 22 40 ( b) For isothermal process, W Yr
bl = - nRTln-
C 25 -50
revers1 e vi
D 22 20 AG system
(c) --'--- = - T (at constant P)
The number of non-spontan eous process from the following ASTotal
is____ [24 Jan, 2023 (Shift-I)] ( d) K = e - e.G 1RT
0
89. 30.4 kJ of heat is required to melt one mole of sodium 94. During which of the follo•.ving processes, does entropy
chloride and the entropy change at the melting point is decrease? (17 March, 2021 (Shift-II)]
28.4 JK- 1 mol- 1 at 1 atm. The melting point of sodium (A) Freezing of water to ice at 0°C
~hloride is K (Nearest integer)[l5 April, 2023 (Shift-I)] (B) _Freezing of water to ice at - 10°C
(C) N 2(g) + 3H 2(g) ➔ 2NH (g)
90. The value of log K for the reaction A ;= 13 at 298 K is 3
(D) Adsorption of CO(g) on lead surface
_ _ _ _ (Nearest integer) _ [6 April, 2023 (Shift-I)]
(E) Dissolution of NaCl in water
Given: AH 0 = - 54.07 kJ moI- 1 Choose the correct answer from the options given below :
AS 0 = - 10 JK- 1 moI- 1 (a) (A) and (E) only (b) (A), (8), (C) and.(D) only
(Take 2.303 x 8.314 x 298 = 5705 (c) (A), (C) and (E) only · (d) (B) and (C) only
Thermodynamics
95• For a given chemical reaction A ➔ B l\l 300 K th11.• th.-e
energy change is - -N.4 Id m,,l ' nnd the cnthnlpy l'f
I03. f\,r on'-' nmk of un ilkul gus. which of these stnt,
must he true'/ · 14 s~pt, 2020 (S~~~Q~
',_
reaction is 5 l .4 Id mol '· The cntn,py durn~e of the (A) U und 11 eul'h depends only on tcmpcrnture ·l)j
reaction is _ _ J K_-1 n\\.,l '• (lll Jul~·. 2021 \Shlll-11)( (B) (.\lmprcssihility ful·tor z is not equnl to I
96. Data giwn tt,r the foll,"' ing. rea'-·ti,,n is as t"i.,11,,ws: (C) ('r_,., - C\ 111
,. R
FeO(_s) + c~,--+ F\.'\_S) + C()(_g.) . (D) dU • C'_ dT fnr uny process
Substance 1 ~s• \J mol 'K- 1 (11) (A). (C') uml (D) (h) (0), (C') and (D)
. ~\kJ mot- ) )
(c) (A) um! (C') (c/) (C) nnd (D)

FeO,,, -~M.3 57.•N
104. The entropy chungc associated with the conversion of ·
Cl,.._\ 0 5.74 1
of ice ut 273 K to wutcr vapours nt 383 K is: (Specific hka
Fe", 0 27.28 of wutcr liquid nnd water vnpours nre 4.2 kJ K-•kg I a dcai
kJ K- 1 kg-1, he.it ofliquid fusion and vapourisation of:al.o
co 18
, -110.5 197.6
are 334 kJ kg-1 and 2491 kJ kg- 1, respectively) (log tr
1
27
The minimum temperature in K at which the reaction = 2.436, log 3 73 = 2.572, log 383 = 2.583) l
becomes spontaneous i s _
19 Jan, 20 I 9 (Shift-lIJJ
(Integer answer) - [27 Aug, 2021 (Shift-II)) 1 1
(a) 7.90 kJ K- kg- (b) 2.64 kJ K- 1 kg-•
97. For the reaction 2NO:tg) ~ N~O..(g). when ~S =-176.0
(c) 8.49 kJ K-1 kg-• (d) 9.26 kJ K- 1 kg-'
JK-1 and~ =-57.8 kJ mol-', the·magnitude of ~G at 298
K for the reaction is_ _- kJ mot-•. (Neares·t integer) 105. The reaction
[l Sept, 2021 (Shift-II)] MgO(s) + C(s) - Mg(s) + CO (g), for which
~rH 0_ = +491.1 kJ moI- 1 and fl rS = l 98 •0 JK- 1 1·s not
0
98. For a chemic.al reaction A+ B .==:= C+D
feasible at 298 K. Temperature above which re~ction will
(.,\H"" = 80kJ moI-1) the entropy change fl,S 8 dep~nds on
be feasible is: (11 Jan, 2019 (Shift-lijJ
the temperature T (in K) as fl, s e = 2T (JK- 1 moI - 1) •
(a) 2040.5 K (b) 1890.0 K
Minimwn temperature at which it will become spontaneous
is _ _ _ _I<.. (Integer). [26 Feb, 2021 (Shift-I)] (c) 2480 K (d) 2380 K
99. Consider the following cell reaction: 106. A process that has !lH = 200 J mol~1 and flS = 40 J K-1.
9 9 . Out of the values given below, ·choose the minimum
Cd(s)+ H~SOis)+ ~O(l)~CdS04 • ~O(s)+2Hg(I) temperature above which the process will be spontaneous:
5 5 (10 Jan, 2019 (Shift-ijJ
The value of E~ is 4.315 Vat 25°C. If MI°= - 825.2 kJ
(a) 20 K (b) 12 K
mot--1, the standard entropy change, flS 0 in J K - 1 is
(c) 5 K (d) 4 K
(Nearest integer)
107. The standard reaction Gibbs energy for a chemical
[Given: Faraday constant= 96487 C moI- 1]
reaction at an absolute temperature T is given by:
[31 Aug, 2021 (Shift-II)] 0
flGr
=A-BT
100. The true statement amongst the following is :
Where A and B are non· - zero constant. Which of the
(9 Jan, 2020 (Shift-II)] following is TRUE about this reaction?
(a) Sis a function _oftemperature but flS is not a function [11 Jan, 2019 (Shift-tnl
of temperature.
(a) Endothermic if A > 0
(b) Both AS and Sare functions of temperature.
(b) ExothermicifA > 0andB < 0
(c) Sis not a function of temperature but flS is a function
of temperature.· (c) Endothermic if A < 0 and B > 0
(d) Both Sand flS are not functions of temperature (d) Exothermic if B < 0
101. For a dimerization reaction, 2A(g) ~ _A,(g), at 298 K, · 108. The process with negative entropy change is:
8
flu8 = -20kJ moI- 1, flS = -30 JK- 1 mo1- 1, then the flG
8 . [10 Jan, 2019 (Shift-IOI
will be _ _ _ _ J. (5 Sept, 2020 (Shift-II)] (a) Dissociation ofCaSO~ (s) to CaO (s) and S03 (g).
102. For the reaction A({) ➔ 2B(g) (b) Sublimation of dry ice.
~U = 2.1 kcal, flS = 20 cal K- 1 at 300 K (c) Dissolution of iodine in water.
Hence, flG in kcal is · (7 Jan, 2020 (Shift-I)) (d) Synthesis of ammonia from N2 and H2 •
109. For the equilibrium I11 Jan, 2019 (Shift-II)) (a) YifT =300K
2HP ~ H 30 + +OH-, the value of AG 0 at 298 K is (b) YifT ::,280K
approximately (c) X if T = 350 K
(a) 100 kJ mo1-• (b) - 80 kJ mol-1 (d) X ifT = 315 K
(c) 80 kJ mol- 1 (d) -lOO kJ mol-1 "PARAGRAPH"
110. A process will be spontaneous at all temperatures if: The entropy versus temperature plot for phases fl and Pat
I bar pressure is given. ·
[10 April, 2019 (Shift-I))
S and S are entropies of the phases at temperatures T
(a) Lili > 0 and AS < 0 T 0
and 0 K, respectively.
(b) Lili< 0 and ~S > 0
(c) Lili> 0 and ~S > 0
(d) Aft< 0 and AS < 0 I,-._ 6 ••••••·•••••••••••• a.
~ I
11 l. Two blocks of the same metal having same mass and at "i 5 -·-----····-- ······ :
temperature T, and T2 respectively, are brought in contact 0 :
8 :
"ith each other and allowed to attain thennal equilibrium t!,
0
:
I
at constant pressure. The change in entropy, AS, for this r:/) :

Ii--, 11.--_ _ _ ___._'-
process is: (11 Jan, 2019 (Shift-I)) (/) 600
Temperature (K)
(a) c, 1n [er~;,? ] . (b) 2c, 1nl (T,;:,) ] The transition temperature for fl to Pphase change is 600
K and cP, p - GP, a = 1 J moJ-I K-1• Assume (CP, p - cP,)
is independent·of temperature in the range of 200 to 700
K. CP, a and CP, P are heat capacities of a. and p phases,
respectively.
113._ The value of entropy change, SP - S.a (in J moJ-1 K-1), at
112. For the chemical reaction X ~ Y, the standard reaction
300 K is___ [JEE Adv 2023]
Gibbs energy depends on temperature T (in K) as
[Use: In 2 = 0.69
A G0 ( in kJ mol-1) = 120 - iT Given : SP - S0 = 0 at OK]
The major component of the8reaction mixture at Tis: 114. The value of enthalpy change, HP - H (in J mol- 1), at 300
0
[11 Jan, 2019 (Shift-I)] K is___ [JEE Adv.2023)
• i\ ANSWER KEY \ •
s
1. (a) 2. [4] 3. [3] 4. 5. [IO]
(a,b,d) 6._(a) . 7. (a) 8. [150] 9. [O] 10. [620]
11. [195] 12. [8630] 13. [O] 14.
[15] 15. [50] 16. [2218] 17. (c) 18: [48.00] 19. (a,b,c) 20~ (a)
21. (a) . 22. (a) 23. (c) 24.
(b) 25. (c) 26. [7] 27. (a) 28. [ 1006] 29. [360] 30. [610]
31. [1200] 32. [4] 33. [847] [1411] 35. [400]
34. 36. [4] 37. [278] 38. [173] 39. [499] 40. (c)
41. (a) 42. (d) 43. (c) [727] 45. [600]
44. 46. [117] 47. [104] 48. [57] 49. [35] 50. [300]
_51. [38] 52. [2] 53. [200] [2]
54. 55. [54] 56. [200] 57. (d) _58. [309] 59. [718] 60. [38]
61. [128] 62. [101] 63. [21] [741] 65. [45]
64. 66. [855] 67. [5576] 68. [82] · 69. [82] 70. [230]
71. [3 l] 72. (667] 73. (b) 74.
(b) 75. [192.5] 76. [6.25] 77. [-326400] 78. [ 189494]
79. (935.00] 80. (c) 81. (c) 82.
(d) 83. (d) . 84. (a) 85. (a,b) . 86. (b) 87. [3] 88. (2]
89. [1070] 90. [ l 0] 91. (b) 92.
(a) 93. (a) 94. (b) 95. [336] 96. [964] 97. [5] 98. [200]
99. [25] 100. (b) 101. [-13538] 102. (-2.70] 103. (a) 104. (d) 105. (c) 106. (c) 107. (a)
108. (d) 109. (c) 110. (b} 111. (a) 112. (d) 113. (0.31] 114. [300]
• \'-__EI_P_LA_N_AT_IO_N_S__~~s-------:_........_,_
1. (a) Adiabatic containers do not pennit heat exchange, 7. (a) As PV = nRT, where n & Tare constant
hence heat generated in container can't escape out PV m = k = nRT
and therefore increasing the temperature. isothermal ex_pansion PVm = k (graph ➔ c)
On the other hand. in case of diathennic container, heat k .
flow can Ol.-cur to maintain the constant temperature. P =- ➔ (Graph A)
2. [4] Extensive properties arc depends upon the mass/
vm
amount of matter p~scnt in a system while the intensive 8. ( 150] For an adiabatic process, q = 0
properties doesn't depends on the amount of mauer. L\U =w
Extensive ⇒ Mole, Volume, Gibbs free energy. Given : w =3kJ/mol = 3000 J/mol
Intensive ⇒ Molar mass, Molar heal capacity, Molarity, Also L\U = nCvL\t
E11 cell. I x 20 x [T2 - 300] = - 3000
3. [3] State variables internal energy, volume and enthalpy. T2 - 300 = - 150
4. (a.b.d)
T2 = 150K
9. [OJ For isothermal expansion
T
~U = 0
10. [620]From I ➔ 2 ⇒ Isobaric process
From 2 ➔ 3 ⇒ Isochoric process
(I) -,,--_R_•"....:.'CTS;.c.;i.:..;.ble.::....__➔(II) Rev . Adia_batic (Ill) From 3 ➔ I ⇒ Isothermal process
lsothcnnal expansion Expansion
Isothermal process is isoenthalpic while reversible w = w. ➔2 + w2..;3 + wJ➔•

adiabatic process is isoentropic
5. [IO] 1st process is adiabatic since entropy is constant.
= (-P(V, - v, )+o[-P,V,ln( i )]J
W = dU .
I .
dU = 450R ~ 2250R = -1800R ...(i) = [-lx(40-20)+0+[-1x201nG~)]]
In 2nd process
=-20 + 20 ln 2
V3
W 2 = -2.303 nRT log - ... (ii) = - 20 + 20 X 2.3 X 0.3
V2
=-6.2 bar L
=-nRTin-
V3
IWI = 6.2 bar I =-620 J .
v2 22
U = nCvT for process II 11. [195] Moles ofN2 O = · = -1
44 20
450R = lx~RT . 1
2 ~H = nC ~T = -20 x 100 (-4) =-2001
. P
T 450x 2 = 180k According to 151 law of thermodynamics,

5 dU=q p +w
w 1 =w2 W =-P dV 0
...
-1 SO0R = -1 x Rx IOOJn.2. W = - 1 (167.75 - 217.1) x I01.3J =+5J

V2 • l000
AU = - 200 + 5 = - 1951
In .2. = I 800 = l 0
v2 )80 12. (8630] Given: Number of moles, n= 5m~l
6. (a) Path function are those which depends on the intial Temperature, T = 300K
and final state of the system. Initial volume, V1 = l0L
Final volume. V 2 = 20L
I
As we know that, =- X }6 X 6
2
V2 = 48J
Work done. w =-2.303nRTlog 10 -
V1 19. (a,b,c) For I mole Vander Waal's gas
Substituting the values, we get, RT a
P=----
20 V-b V 2
= -2.303 x 5 x 8.3 x 300 log 10 - J = -86301
10 lf P = P means process is reversible. For Vanderwaal
~xl '
Hence, the magnitude of work done = 8630 J. gas, expression is correct for all reversible process.
J3. (OJ Workdone, w = 0, for expansion in vaccumn. 20. (a) AU=q+w
AU = 0, In an isothermal process, q = -2kJ, w = IO kJ
According to first law of thermodynamics, AU= 8kJ
AU=q+w 21. (a) CP does not changes with change in pressure
On substituting value, we get, n = 5; T; = 100 K; Tr= 200 K;
22. (a)
q=O
Cv = 28 J/mol K; Ideal gas
J4. (15] If AU= 0, then,
AU= nCv6T
q = -w (first law of thermodynamics)
= 5 mol x 28 J/mol K x (200 - 100) K
w = -P=(AV)= -4.3 nRT[- 1
P2
_ __!_]
P1 ⇒
= 14,000 J = 14 kJ
cp = CV+ R = (28 + 8) J/mol K
1 1 = 36 J/mol K
= -4.3 x 5 x 8.314 x 293 [ - - --]
l.3 2.1 ⇒ AfI = nC p AT= 5 mol x 36 J/ mol K x 100 K
=-15347.70 J/mol = -1 5.3 kJ/mol = 18000 J = 18 kJ
q = 15 kJ/moL AfI = AU+ A(PV)
15. (50] q=+l50J ⇒ A(PV) = 68- AU = (18-14) kJ = 4 kJ .
w = -200 J (As work done by the system sign is 23. (c) For cyclic process: AU= 0 ⇒ q =-w
negative) · For isothermal process: AU= 0 ⇒ q = -w
First law of thermodynamics is: For adiabatic process: q = 0 ⇒ AU= W
:. AU=q+w For·isochoric process: w = 0 ⇒ AU= q
= I 50 - 200 = -50 J
24. (b) w =-nRTln~
· So, magnjtude of AU is 50J. V1
16.[2218] The reaction taking place is:
Fe + 2HCI--4 FeC½ + 1½(g) w =-nRTln~
V;
Weight of Fe 50
Mole of Fe=_--=:..._ __
Molar mass 55.85 lwl=nRTln~
V ·I
Mole of Fe= _2Q_ = 0.89 mole lwl ~ nRT(ln vb - 1n v)

55.85 y=mx-c
Moles of Fe= moles of H2 Slope of c~e 2 is more than curve I and intercept
Now, Work done = -An x R x T of curve 2 ts more negative than curve.
= -0.89 x 8.31 x 298 = -22 I 8.05 J 25. (c) W = -Pext (V2-V,)
Hence, Work done by the gas= 2218 J (Nearest integer) =- I bar x (10- l)lit
17. {c) Pat is zero. w =-Pal AV, w = 0 = - 9 bar lit = -900 J
18. [48.00] Work done= Area covered by the diagram =-0.9 kJ
26. [7] For the reaction, A -.a
= .!csum of p~allel sides) X height 1
2 60ovi1 - =60VJ- 1 (y=S/3)
l For Reversible adiabatic process,
!WI= (6+10)x6
2 i'
600 (V 1 = 60 (V ) 213
~j
;, IJll(I jjll /l I '11
,
'.' III
l \\'jl I I
11,, ,, -
,
IJ( ,, I
'1 i
- 2111111,k
,·~1:1 W - 211 1 1Ii - V,(J ~

l II I
:- \ ·,- 11~1\l\ 1 ' - Ill''
,IO, l<dlll ~,
""'
·1)/11 / ,, ·1111.1 '"'l~J ,Cli,,,,,
\il\\'11, ,1,.,, - It ,,I '"
Ill - OIi It hi IO ~ ll i\11 I 11111 t\1l" -- All"101 f All"•It t All''l,y4
',' ,, \II • (\ , )11 1ml1ttllt11l l11µ, v1d11cH, w,~1,1,ct
V
:- "'" - (\\I H 111 '\I - no It 111 _I All " "" ~, 2'10 I ( -31()) I ( 3~<J) • f)J<J.
VJ
l~hw,1, ll •(' I~111v1 Hillil.1 IN11tl11 1rn111II
1
;'l l , 11 2011 I Pow,:r 111' hc11 tcr ...., r,o W
:- NI K 111 I11 - Ml It 111 ( VI J ) ,,o ,I/Hee
Ill" '11111d c11crgy crnHt.cd
. {,() I J(J() - (,(J/J() J
I lc11t cup11cHy I( t.cmp dilforcncc "- 6000

7 ' ()()()()
:- h11,l VI - " ' ), ~ h11,l VI - 7 l J1,11t c11rmclty '-' - ~ .,. I 200JK 1
•
27. (11\ Th,• l111w•1,•,1111111\11111'1 ;\2, llf I ll11dot l1crmic J)roceHHCH are thoHe which the hear
11h1mrhc:,I. On Lhc othcr hand, in exothcmic pr~~
('(~111pl111,,) I ~ ()J(p.) >( '( l( p.) ' ..( /) l1c;111 iHc;volvcd .
• A ~► l!ndothcrmic (Atomisation)
N,,w. ( '(wuphih•) t ( IJ(p.) , ► ( '( )J(I!) , ",( //)
,\I I I - • y k.l/11101,, ll -➔ f\ndo thcrmic (At.omisation)
I C ➔ l1ndn1hermic (Vapourirmtion)
(.'( l ~(t,:.) - ► ('()(p.) I " , ()J(j-t) , .. (Ill)
X
- D -► f(xothermic (Combustion)
l 1➔ l!ndotl wrmic (Dissolution)
,\II •, - :_ k.l/111olt.1
'I Thus, I here urc 4 endothermic processes.
l-''11111111,11 (I) 1,.•1111 ht' uh1111lwd hy 1uldl11l-\ t1q1111tlon (//) 33. I8'17 I J.ut thu vo lume of C) 14 is x litre
11ml (Ill), Thu rc11clion for combustion process is
X X - 2V
"" ~ - - 'I ... -- - - '··
c2114 + 30 2 ➔ 2~02 + 21-1p
2 2 lnili11I X
:H. I IOO<,J (lh1111h c11lorh,1111l1,. r • ► c1111st voh11110
1
Jlin11I 2x
t 'ukulnt~ h,•111 l'l.ll,•11:-1,·d Cl f4 + 20 2 ➔ CO2 + 2Hp
by 1,.•,,111h11stiu11 or I 111011.l ns: lnil ial ( 16.8 - x)
<: 11 (t\ll) .... ~ 20 )( o.~ )( :rn ._ ~ 1000 k.l Final ( 16.8 - x)
J ~ OJ
Tol11 I vo lume of CO2 = 2x + 16.8 - x
C,11~(~) +- 7/2 O}p.) ->2COil-() t< \11/)( I)
⇒ 28 "" 16.8 + X
t\n• ,... 2 - (:! ~ 7/2 ) ... (7/2
x • 11' .2 L .
I 000 - 7/2 )( HJ )( 300 kJ
-
According to idcul gas equation. PV = nRT
= 1000 - 6.2::?~ ... · I 006 kJ
, PV l x 5.6
So. hl·nt rcknscd ... I 006 kJ 11ml 1 I lun<.:c, n,.,, =- - - - - - = 0.229 mole
0.082 x 298
• RT
2~.l.'<,OJt',,ll ,;<),,<s) 1 t,<>, ~•<1( '0 1(1() 1 <,11/)(1)
( '11k11l11h.• tlll' l'X lrn 11111011111 of' cllcl'HY w;cd lo co11vcrl I x I 1.2
n" 11 = - - - - = 0.458 mole
11 ,.c >(I) i11io 11} >(lt) us: I I 0,082 )( 298
~ !~m,~ , 900 kJ :. 1lcu l cvo lvull =- 0.229 x (- 900) + 0.458 x 14oo

.., • - (206. I + 641. 2) .., - 847.3 kJ
. [1411] For the given reaction, C 2 Hig) + 3Oi(g) __. 40. (c·) The c han ge in c nthulpy i~ ca lc ulated as :
34
2CO/g) + 21\0(/') /\II ~ I:/\11,. (rcactnnt s) - !:/\ I 1,. (prod11<.:ls)
Heat produced, i:\U =-1406 kJ mol 1
, T = 300 K t\11 "' 3(/\ l fcnnih)C',ll,c~I (t\l fc11n1l)c ,, 11,,( 11
i:\ng = 2 - 4 = -2 = - I JOO x 3 ( 3268 )k.1/mo lc
i:\H = i:\U + i:\ntiRT =( 3900 i.- 3268)k.l/mo lc
i:\H = - 1406 + (- 2) x 8.3 x 300 = - 1406 - 4 .98 .,,, - 6)2kJ/molc
=-1410.98 KJ mot - 1 ~ - 1411 41. (a) /\ II =- L\U + t\(l'V)
l\G = i:\H - T i:\S = L\U + P~ V + V t\P
At equilibrium, i:\G = 0, At conslnnl pressu re,
:. £\H = Ti:\S =-1411 k.ln101- 1 = i:\U + P.1V
(,(} - 360
35. [400] A 2 + B2 ➔ 2AB · i:\Hi = -200kJmol- t 42. (cl) Massofpurc Cincoal = 0.6 x f(J(J0g/ IOO - g
l\H ~ (B·E)A-A+ (B·E)B---B -2(B·E)A-B
. 60
Mass of C. converted mlo CO = - x 360 =216 g
IfB·E of A- A = x then, B ·E of B- B = 22 and
.
JOO .
that of A-B =x ⇒ Mol = 2 16

= 18 mole of C
l\H 1{A-B) = - 200 kJ 12
Mass ofC converted into CO2 = 360 - 216 = 144 g
X X
⇒ Mole = 144 = 12mole of C
-200= x+--2x =- -
2 2
22
⇒ x = 400 kJ/mol
36. [4] Fep3 + 2Al ➔ Alp 3 + 2Fe C(s) + 0 2 (g) - CO 2 (g) + 400kJ
Mole = 12 for CO production, Hence the total
Molar mass 160 g 27 g 2
energy produced = 400 x 12 = 4800kJ
( Lili~ teaction = [ (Lili~) Al 0 2 3
+ 2 ( Lill~ );e ]- 1
C(s)+- O 2 (g)--➔ C O (g) + l00kJ
2 . .
[ ( Lill~ )Fe 0 + 2 ( i:\H~) Al]
2 3
Mole = 18 for CO production, Hence, the energy
= [-1700 + O] - [-840 + 0] = -860 kJ/mol produced = 100 x 18 = l 800kJ
· Total mass of mixture= Fe 0 + Al (1 : 2 molar ratio) Thus, total heat = 4800 + 1800 = 6600kJ
3 2
= 160 + 2 x 27 = 214 g/mol
7
43. (c) (I) C 2H/ g) +
860
2 O 2(g) ---t 2COiCg) + 3~0(/)
Heat evolved per gram= - = 4 kJ /g Lili= -1560 kJ
214
(11) C(s) + O 2 (g) ~ CO2 (g) Lili= - 394 kJ
1
2 O (s) ➔ C
37. [278] 2C(•l +3H 2 (s) + 2 2 H 5 0H(l) 1
(III) H/g) + Lili = -286 kJ
( £\Hf )c H , OH(I) = L (i:\Hcomb ),~ctant - L (i:\Hcomb )product
2 O (g)---t Hp(!)
2
2 2C(s) + 3H 2( g ) ~ C/l 6(g), i:\H = Llli/C: Hb)

=2 X (-393.5) + 3° (- 241.8) - (- 1234.7) f1H!C2H6) = [2 X (- 394)] + [3 X (- 286)]
=. -277.7 kJ I mol - [ I x (- 1560)] kJ mole
.
38. [173] i:\rH = LHp - LHR = (- 788 - 858 + 1560) kJ/mole = - 86kJ/ mole
= (- 394 + 4 X - 92) - (- 105 +(2 X -242)) 3
2 Oz(g) ➔ CO/g) + 2 HlO(f)
44. [727]CHpH (e)+
=-l 73kJ I mol
39. [499] Multiply by (2) 2Hp(g) ➔ 2H/g) + O 2 (g) + i:\ H = i:\U + i:\n RT = - 726 - ( 0 ·5 x 8 ·3 x 300)
{242 x 2) kJ moJ- 1 s 1000
Hz(g) + 0 (g) ➔ 2OH + 78 kJ moJ- 1 = - 726 - 1.24 = - 727.24 ::::i - 727kJ/mol
2
Hz(g) ➔ 2H + 436 kJ mot- 1 45. [600] T he co mbustion reaction of Mg is:-
2Hp ➔ 2H + 2OH + 998 kJ mot- 1
1
Mg( s ) + O 2 ( g) ➔ MgO(s)
Hp ➔ H + OH 998 x 1/2 = + 499 kJ moI- 1 2
I
H;<-,n ~ H2()(g)
Ht'n\ ·''\ "" n,_...,. ..,. n,_..-- = - 2
11 - 1-.SJl ·d 7J
=4 1.1 - - - -
..\~ .\H ""-' _\l' ._ ~n, RT 1000
(ii,\,r .\t~ "" Nll ."'' ti nl\,I = JS kJ 1mol
~,1. .. = _,r •l-1}sJ, w·\doo S2. (~] Enthalrhy of ionisation is given as:
6H_ ofCHFOOH = - 55.3 -(-57.3)
· = 2kJ/molc
,~ U " ~XlkJ
.\l' = - N-._,_
Ht""'-'t. the ma~ituJe of .mis til"XlkJ. SJ. [~00) ((s) + Oz(g) - CO2(g)
._ [ l l '" J~ ~ \H~= 5 1n1.,1t~ ,,n,H; AT= (300-298)K= 2K
( ·: n = weight'molar mass) Given. AH = -x kJ / mole
Enthalr~ '-~'t l\'£ I nl\ll = ~14 kJ (Given) 24

No. of moles of C = · = 0.2 moles
Thus. mthalry d11~-e for 5 mt,I = ~3.4 x 5 = 117 U 12
AH for 01 mole
4".". [l ll4J C,}\~)--- 50l ➔ 3('(): +48:(Xl)..llil =-2220kJ/mol
=0.2 X (-X) kJ =-0.2 XkJ
cl~ire\ •O:ti)-CO:(g). ~ =-393.5 U/mol,
As,q=CAT
l.lli; = -:SS.S U tool)
0Jx=20 X 2
3CtGraphire) + 4H (g)-+ Ci$g)
40 .
.lli:{C}$ = (3 X Afl.-t,(C)] + [4 X Aflcomb{~ )] x = - = 200kJ/moJe-•
-[.lli,,..,itlC)\l]
02
=-l03.7U mole
54. [2] Cp.a = CT.m + R
48. [5 ..] The enthalpy change for the given reactions, CUii =C(lJll -R =20.785-8.314= 12.471nc-:IiAt
AU=nC1:JIIAT
.lH=..lU+~T
AT= (500- 300)K =200K
.lH = -59.6 + (l X 8.314 X 300 xl0-3)
5000 25
= -57.lOU / mol n=--- .::::2
l2.47lx200 12.471
49. [35) let X g·gas is burnt
Moles of gas =x.1280 55. [54] The reaction that occur is:
Hear released by x_!280 mol = 2.5 x 0.45 kJ HN03 + NaOH ~ Na.~0. .,. E.:
Att=0 (600x02) (400x0.l) _ , ·
1-r~~by I m
Hearre~ Io2.5x0.45x280
=----
x 120 m moles 40 m moles
Enthalpy change for combustion of gas is, t =oo 80 m moles 40 m moles 40 mm.-c
Mi=AU+6ngRT Hence, the total heat produced during neutraliz:l::il
Mi=AU 40
=- x 57 x l OOOJ = 22801 = m.s8
2.5x280x0.45 1000
9
X 2280 = 1000 X 4.2 x 8
x=35 g :. e= 2280 I 4200 = 54.28 X l o-10c
SO. [300] AG =AH - TAS 56. [200]C(s) + 0 1(g)-+ CO2(g) 6flg== 0
At equilibrium; 6G =0, So, AT= (300 - 298)K = 2K
TAS=AH-6G Given, AH = -x kJ / mole
TAS=AH
No. of moles ofC =
2
A
12
= 0.2 moles
T MI -165 x 1000 K
AS -550 6H for 0.2 mole
=Jx IOOK = 0.2 X (-X) kJ = --0.2 XkJ
=JOOK As, q = CAT
36 0.2x = 20 x2 (·:q ==-JII
51. [38] Mole of Hp= =2 mol
18 40
x = - =200kJ/mole-1
6U=AH-6n RT 0.2
'
57. (d) Bond dissociation enthalpy of D2 > Bond dissociation
enthalpy of H 2 ·
I H H H H
I I I I
B.D.EH-H = 435.9 kJ / mole H- C- C- H ~ H- C = C - H + H- H
B.D.Eo-o = 443.4 kJ / mole
·1 I
H H
EH::::: ED -7.5 M-1, "" [Al le-<:+ 6AHc_11 ] - AHc-c - 4AHC-H- AH 11 _H
58. [309] S(g) + 6F(g) ~SF/g) · = £\He- c + 2~Hc. H - AHc~c - M·f11 ·H
0 0
AH R = I:AH ~Products) - 1:AH r (Reacta;,ts) 0
Given : Al-lc-e: = '3 47 kJ/mol
0 0
. AH R,,;, Afl ~SF6) - AH 0 r (S) - 6xAH 0f (F) Ml('· c = 611 kJ/mol
= (-1100) - (275) - 6(80) = - 1855 Allc-H= 414 kJ/mol
0 1855 M·fII fl = 436 kJ/mol
AH s-F = - - = 309. 16 KJ/mol ~ 309
6 = 347 + 2 X 414 - 611 - 436
59. [718]The Born-Haber cycle for KCl can be drawn as: · = 128 kJ/mol
1 62. [l0l]The formula to calculate enthalpy of sublimation is:
Cli(g) - - - + KCl(s) ; AHr°
l
. K(s) +
2 ' + AH vaporisa
AH subll mot Ion == AH,us1on '
' tion
l½
I
= 2.8 + 98 .2 = 101 kJ/mol

+ m:, sub + 1.IH;o,
63. [21] 1 mole 'graphite = 12g C
. K(g) Cl(g)
Beat generated on combustion of lg graphite can be
+ m:, l-e AH,'.. }e calculated as:

2
= 2.48 X }0 k.J
K +(g) + 12
HmioE)
= 20.67,kJ::::: 21 kJ
AH:- (+~.J + (+m:,l + 64. [741] AU = 742.24 kl/mole
3 '
NHFN(s) + -O/g) ➔ N/g) + O/g) + H 2O(l)
+ (Afl~A) + (-AH~J 2 .
On substituting values given in question,.we have, The relation between AfI and AU is:
-436.7 =(892)+(419)+ ( ½x 243) +(-34R6)+(-M-t) AH = AU+ An RT· An = 2-I = _!.

g ' g 2 2
On solving,
= - 742.24 + _!.X 8314 X298
AH~E= 89:2 + 419 + 121.5 - 348.6 + 436.7 kJmol- 1
. 2 1000
Lattice energy= 717.8 ::::: 718 kJ/mol =-742.24 + 1.238::::: -741.001::::: -741 kJ/mol
60. [38] Given: Aff. vap = 41 KJmol- 1 . Hence, magnitude is 741 kJ/mole.
R = 8.3 JK- 1 mot- 1

65. [45] Magnitude of enthalpy change, Aff = Ear- E¾
T=373 K . r =x
Ea
E¾ '= X + y
As, Aff = AE + An g RT
⇒X- (X + y) = - y
For the reaction
Hence, AH = 45 kJ/mol
H 7O(£ ) ~ H 2O(vap), .1.ng = 1 . 66. [855] The reaction is: ·
Thus, AE (Change of internal energy) = AH - AnsRT 3CH = CH(g) ~ C6H/£)
On substituting values, AG 0 =-RTfoK ...(i)
AE -~ 41- lx8.3x373kJmol- l = 41 - 3.09kJmoI-' AG 0 = LAGp
0
LAG 0 R
-
... (ii)
1000 From equations (i) and (ii),
= 37.91 kJmo1- 1 ::::: 38 kJ/mol. - 2.303 RTlogK = 4.88 x 10 5
61. [I28]C2H6 ~ C 2H 4 + H 2
logK -4.88 x 10s -488000 = - 85.52 = - 855 x 10- 1
When bond is formed , Energy is ~eleased · 2.303 x R x T 5705.848
When bond is broken, Energy is consumed Hence, magnitude of logK = 855 X l 0- 1
I. 6 7. [5576] The representation of conversion of species to ions is: = [(-1675 + 0)-(-635
,
)( 3-I-
+
2rg)
1
71. [31] H 0(/)--+ Hp(g)
= -1675 + 1905 = 23o kJ O
0
The relation between L\H and L\U 0 is:
j
6H 0 = L\U 0 + L\ngRT
Na(g) 6H - 6U 0 = L\n I! RT
0
Br(g)
NalJr(s)
= I x 8.31 x 373
!495.8!1/mole ! - 325kJ/mole = 3099.63 J / mol
= 30.9963 x 102 J/ mo! ::i:: 3 I x 102 ·
Na+(g) Br-(g) 72. [667]2700 kJ energy wilf be re le a sed fron,
18
J:i ~
(I mole) of glucose ,
Now, &H...t, of Na mel'al
. = 495 .8 kJ/mole
&H, = 495.8 + (-325 - 728.4) =-55.76 kJ/mole 180
I kJ energy released from - gn, of gl
=-5576 x 10- 1 kJ/mole . 2 700 u~
H 2S04 + 2Na0H ~ N3iS04 +2Hp
Hence, 1·0000 kJ energy r~leased from ( ~
68. [82]
Milli mole 80 60 (limiting reagent ) gm of glucose 2700 .
H+ + OH- ~ Hp
18000
Milli mole 160 60 Amount of glucose = ~ = 666.66 ::::: 667 gm
·7
Milli mole 160-60 0 60
73. (b) Born-Haber cycle can be represented as:
Total heat liberated = Heat gained
60 3
. ·L'. H Hydration
IOOO x57.lxl0 = (1000 x I) x 4 .18 x &T Na+(g) + Cl-(g)
On solving,
&T=0.8196 K L'.HLatticel
= 81.96 X 10-2 K . b.Hsolution .
. NaCl(s) . Na+(aq) + Cl-(aq)
⇒ 82 X 10- 2 K
Use Hess's law as :
69. [82] Millimoles ofHCl = volume x molarity
&Hsolution = L\Hlanice + &Hhydration
=200 X 0.2=40
4 = 788 + L\Hhydration
Millimoles of NaOH = volume x molarity
L\Hhydration = - 784 kJ moJ-1
= 300 X 0.} = 30
74. (b) Given, .18atom 1.satton
. (Br2) =. xkJ/mol and B.E. •
30 (Br2) = y kJ/rriol.
Heat released = - - x 57 .1 ?< 1000 J = 1713 J
1000 . Br (.e) t-.Hatomisation - 2 Br
[ m] p=-
m=;v
.1:~ ~gy ,~
Br2(g) .
Mass of solution= 500 x _lg= 500 g . . = L\H vap + Bond Energy

L\HatomLSatton
Specific heat of water= 4 .18 Jg- 1 K- 1 Therefore, x > y .
75. [ 192.5] Formation of ethane from hydrogen and graphite,
As &T=~ 2C(gr) + 3H 2(g)--+ C 2H/g) . C
me
L\H f= 2 X .18comb(C) + 3 X .18· comb ( H2) - L\Hcomb ( !~
On substituting values, we get,
L\Hr= 2 (- 286) + 3(- 393.5)- (- 1560) = 192.5 .
1713
°C = 0.8196 °C ·76. [6.25] L\U = nCvl\T
500x4.18
5000 = 4 X Cv(500 - 300) ( ',' L\U ~ 5000 J)
= 81.96 x10-2 0 c :::: 82 x 10-2 0 c :. C = 6.25 J K- 1 moJ- 1. f)
70. [230]Given: &H~<Ai,o1 > =-1675 kJ/mol 77. [- 326400] VC2HSOH(f) + 302(g) ➔ 2CO/g) + 3HP ( '
L\H = - 327 cal = - 327 x 103 cal
= -635 kJ/mol
&H~,ca0J
L\n g = 2 - I = 1
&H =L&Hf;P) - L&Hf(R) L\H = L\U + ~n g RT
94 ' •
-327 X-103 ="L\U + 1 x 2 x 300
(A) Acc. to first law of thermo dynam ics
L\U = - 32640 0 cal
L\U =Q+ W
There fore, heat evolv ed at consta nt volum e is Jf we apply consta nt P and revers ible work.
· -3264 00 cal. .
L\U = Q - P.1V
78. ·[189494]
(C) Acc. to 2nd law of thermo dynam ics.
90g
No. of moles of Hp = / dS = dq,"
. 18 g mot T
= 5 mol At consta nt T
=
L\H L\U + L\n gRT
L\S = qrn
41000 x 5 = L\U + 5 x 8.3 I4 x 3 73 T
20500 0 = L\U + 15505.61 . (D) H = U + PV
For ideal gas
L\U = l 89494 .39 J = 18949 4 J
H = U + nRT
79. [935.00] SnO2<5/ C<s> ➔ Sn<5/ CO 2<g) At consta nt T
L\H°rxn = [~394] - [- 581] = 187 kJ/mo le
L\H = L\U + L\nRT
0
L\S rxn = [52 + 210] - _[56 6] +
· = 200 J/K-m ole 87. [3] Entrop y chang e in isothe rmal proces s .
T = L\H0 /L\S0 ,1s = nRen ( vV12 )
= (187 x 1000)/ 200 = 935 K System
80. (c) C 1H,i1!) + 11O/g ) ➔ 7CO/ g) + 8Hp (e)

L\n g =nP -n r =7-1 1=-4
= 1 x 8.314 fn )
(%
L\H = L\U + L\ngRT L\Ssystem = 3.37
:. L\H - L\U = - 4 RT L\SSurr. = 3.37
81. (c) q = PL\V 88. [2] L\O = Lili - T L\S
q = 16 A : L\O (J mol- 1) = - 25 x 103 + 80 x 300: -ve
B : L\O (J mol- ) = -22 x 10 - 40 x 300 : -ve
1 3
Cr=2 4
C : L\O (J mot- 1) = 25 x 103 + 300 x 50: +ve
C = ~ ⇒ L\T=~K.=3,K. D ~ L\O (J moI- ) = 22 x 103 - 20 x 300 : +ve
1
L\T 24 3
P~oces·s es C and D are non-sp ontane ous as value of
P
T2 1000 L\O is positiv e.

82. (d) L\H = n fCp,mdT =3 f (23 + 0.0lT)dT
x .
89. [1070] L\S _=-
L\H
T1 300
T mp
0.01 000 2 -
= 3[ 23(10 00-30 0) +-(1 3002)] 30.4x iooo
2 28.4
61950 J::::: 62 kJ
83. (d) i/s) ➔ IiCg) · :L\H 1 = 24cal/gat200°C Tmp
. 30.4><1000
L\H2 = L\H I + L\Cr rxn(T2- T. 1) 28.4

= 24 + (0.031 - 0.055) X 50 = 24 - 1.2 T mp = 1070.4 22 K.
= 22.8 cal/g 90. [10] L\O° = L\H 0 - TL\S
⇒ L\O° = (- 54070 - 10 X 298)
84. (a) (ii)+ (iii)= (i)
Also, L\O° = (- 2.303 RT log K)
y+z= x ·
⇒ (- 54070 - 10 X 298) = - 57050
85. (a,b) Enthal py of forma tion is define d as enthal py chan~ e
= (- 2.303 x 8.134 x 298 logK) = (-5705 .8 logK)
for forma tion of 1 mole of substa nce from its 10 = logK
· t h eir
eleme nts, presen t m . stable form.
· na tural m·ost s.
91. (b) L\O < 0, (negat ive) for the sponta neous proces
86. (b) Only (B) and (C) are correc t. L\P = 0, for isobar ic proces s
(B) G= H-TS L\T = 0, for isothe rmal proces s
At consta nt T L\H reactio n = IB.E(Rl"- IB.E.(P>'
L\O = L\H-T L\S For exothe rmic proces s, L\H < 0 (negat ive)
92. (a) AG=Mi-TAS · 98. [200]For a spontaneous reaction:
When~ increases then (-Ve) value oft\G will increase A so> ArHO
and reduction becomes easy. Entropy ofliquid is greater r T
as compared to solid. On melting, entropy increases
LirHo
· due to which AG becomes more negative. T >--
93. (a) The given expressions can be expressed as: Lirso
. (A) AG = AG 0 + RTCnQ 3
0 0
T > 80x 10
t\G = t\H - Tt\S 0
. •
... (')
I 2T
At equilibrium t\G = 0, Q = K 2
cq T > 40000K
:. AG 0 =-RTCnKcq (")
... "
T> 200K
:. t\H0 -Tt\S0 = - RTfnK
cq
0 0 So, 200K is the minimum T at which reaction .
t\H-- -
CnK =- ( - T t\S
-
)
. eci RT be spontaneous. w
99. [25] LiG 0 = -nFE 0
(B) W= = ·- nRTCn(~) . LiG 0 = LiH 0 -TliS0
LiSo = litto + nFEo

(C) AG=-Tt\SToiai(atconstantP) :. liG = - T T
, LiSTotal
:._ (-825.2xl03 )+(2 x 96487x4.315)
(D) AG = -RTfnK
0
:. K = e<--6G 1RTl 0
94. ( b) Water ooc > ice eq LiS = -ve eq

298
Hp(/} -iooc > ice LiS = -ve = 7.483 xlOJ =25.l!JK-I ~25JK-I
298
N 2(g) + 3~(g) ➔ 2NHig) LiS = - ve _
100. (b) In the given statements, true statement is given .
For adsorption, t\S = -ve
option (b).
95. [336] The relation ·between LiS and AH is:
S= Ii . 1
Mi= AG+ TLiS . : . . AS= AH -LiG
- T
51.4-(-49.4)] LiS = ncf Ti dT
AS= [ - - - - - x 1000 JK- 1 mo1- 1 T1
300
Both LiS and S are function of temperature.
= 336 iK-1 moI- 1 101. [- 13538] 2A(g) ➔ ~(g)
96. [964] The minimum temperature at which reaction becomes Ling = 1 - 2
spontaneous can be calculated using below formula:• Ling =-1
AHO
T = -· The relation between MI and AU is:
min . ASO
Litt = AU + LingRT .
AH::U., = [AH';(Fe)+ LiW;(CO)] - [AH1FeO) + MiiC)] ·MI = - 20 x 103 +(- 1)8.31 x 298 = - 22477.572 J/mol
= [0 - 110.5] - [- 266.3 + O] = 155.8KJ/mol Now, AG = MI - TLi$
AS 0 = [AS 0 (Fe) + t\S 0 (CO)] - [LiS 0 (FeO) + LiS 0 (C)] AG= - 22477.572 - (- 30)298 = - 22477.572 + 894-0
= (27.28 + 197.6)- (57_.4?_+ 5.74) J/molK = - 13537.57 J mo1- 1
= 161.651/molK 102. [- 2.70] For the given reaction, enthalpy change is,
Substituting the values in above formula, we get, · Litt = AU + LingRT
·.
155.8xl03 . = 2.1 x 103 +·2 x 2 x 300
T . = - - - K = 963.8K ::= 964K
ffllD • 161.65 = 3300 cal.
· .,,. . · AG = MI - TLiS
97. [5] 2NOig) ~ NzO,. (g)
The relation between AG and AH is: . . = 3300 - 300 X 20 ,.
AG = AH - TAS . = - 2700 cal.
= - 57.8 - (298 x ~.176) kJmol- 1 =-2.7 kcal.
= - 57.8 + 52.5 kJmol- 1 103. (a) AU = nC VdT; LiH .= nCpdT
= -5.3 kJmol- 1 Both U and H are temperature dependent
Hence, magnitude of AG in kJmol- 1 is 5. cP,m- cV,m= R (for 1 mole of ideal gas) .
96 . •
J04. (d) Hp(s) ➔ "20(/) ➔ "20(/) ➔ Hp(g) ➔ Hp(g)
1kg . 1kg 1kg
at 273 K at 273 K at 373 K at 373 K at 383 K
/ls= /ls 1 + As2 +As 3 + As4
334 373 2491 383
4
= 273 + .Un 273 + 373 + 2Cn 373 = 9·267 kJKg-'K-' = Cr In
105. (c) In order to be spontaneous AG should be - ve
0
AG0 = AH 0 - TA S0
O=491.l x 103 - T x 198 3
112. (d) As AG 0 = r20 - - T
491100 . 8
T= = 2480
198 . 3 .
(a) AG 0= 120 -- x 300 = 7.5 :. Ynotmax1mum
Iftemp is above 2480 K, the reaction will be spontaneous. 8
106. (c) AG = AH - TAS < O . 3
AH 200 . (b) AG0= 120 -- x 280 = 15 :. Y not maximum
T=-=-=5 K 8
AH 40
(c) AG0= 120-i x 350 = 11.25 :. Xis minimum
107. (a) AG0 = AH0 - TAS0 8 .
AG0 = A- BT
In endothennic reaction MI = +ve. Hence, A= +ve (d) AG0= 120-I x 315 = l.875 :. Xis maximum
8
108. (d) Four moles of gas
113. [0.31] At 1 bar
(N 2 + 3H2) ➔ 2~ reacts to give only tw~ moles of
gas the he~ce entropy decreases. a~~
109. (c) LiG0 = - 2.3O3RT log Keq o + CP(a)Rn 600
so = s a(JOO)
a(600)
= - 2.303 x 8.314 ~ 298 log l 0- 14 300
=-2.303 X 8.314 X 298 X - 14 .
So = Soa(JOO) + CP(a).en 600
= 79,881.87 a(600) 300
80 KJ mol-1
s:(600) = s:(600) + s:(300) + s:(300) + (CP(ll) + CP(a))fn2
110. (b) AG=AH - TAS
6 - s = s;cJoo) - s;cJoo> + 1 x .en2
For spontaneous process at all temperature, LiG <
0, and it is only possible when Lili < 0 and LiS > O. 1 = s;cJoo>·_ s;cJooi + o.69
111. (a) At the thennal equilibrium, So s;cJooJ = s;(JooJ = 0.31
T +T 114. [300] Since, the temperature at which the phase transition
final temperature Tr = - 1- -2 occurs is 600 K
2
T Thus, at 600 K LiG 0 rxn = O
⇒ for the 1st block, LiS, = CPIn _f__
T, MI 0rxn = TLiS 0rxn
T So MI 0 reaction
..
(600)
= TLiS 0 reaccion (600)
⇒ for the 2nd block, LiSII = cp In /
2 MI 0 c600l = 600 x I = 600 Joule/mole
When brought in contact with each other, Thus, MI 600 - MI300 = LiCP (T2 - T1)
MI600 - MIJOO = l X 300
LiS = LiS + LiS = Cp In Tr + C In Tr
I II T
I
p T
2
MI300 = Af:1 600 - 3OQ = 600 - 300 = 300 Joule/mole.
8 Redox Reactions
and oxalic acid in acidic

9. In the titration of KMnO, number of carbonat the
medium, the change in oxidation
Oxidation Number and Its [27 July, 2022 (Shift-I)
end points
Application oxidation states for an element with
10. The common positive
atomic number 24, are: [17 March, 2021 (Shift-II)
(b) +1and +3
1. In Chromyl chloride, the oxidation state of chromium is (a) +1 and +3 to +6
(+). |15 April, 2023 (Shift-I)] (c) +2 to +6 (d) +1 to + 6
2. Asample of a metal oxide has formula M,..0, m.The change in the oxidation state
11. Identify the process in which
).83
metal M can exist in two Oxidation states +2 and +3. In the [25 July, 2021 (Shift-II)
is five:
sample of Mas:O, o0 the percentage of metal ions existing
in +2 oxidation state is % (nearest integer) (a) CrO? ’Cr* (b) Mn0, ’ Mn
|31 Jan, 2023 (Shift-I)] (c) Cr,O?’ 2Cr+ (d) C,o;’ 2C0,
3. In ammonium-phosphomolybdate, the oxidation state of 12. Oxidation number of potassium
in K0, K,0, and KO,
Mo is + ( [6 April, 2023 (Shift-I)] |7 Jan, 2020 (Shift-I)
respectively is
4. In neutral or faintly alkaline medium, KMnO, being (a) +1, +2 and +4 (b) +1, +1 and+
a powerful oxidant can oxidize, thiosulphate almost
quantitatively, to sulphate. In this reaction, overall change (c) +1, +1 and +1 (d) +1, t4 and +2
in oxidation state of manganese will be:
[29 July, 2022 (Shift-I)] 13. The compound that cannot act both as oxidising and
reducing agent is: [9 Jan, 2020 (Shift-I)
(a) 5 (b) 1
(c) 0 (d) 3 (a) HNO, (6) HPO,
5. The difference in oxidation state of chromium in chromate (c) H,SO, (d) H,0,
and dichromate salts is 14. Consider the following molecules : Br,O, F,0, H,S,O,
|24 June, 2022 (Shift-I)]
H,S,O,, and C,0,. Count the number of atoms existing
6. Manganese (VI) has ability to disproportionate in acidic in their zero oxidation state in each molecule. Their sum
solution. The difference in oxidation states of two ions it |JEE Adv 2023|
forms in acidic solution is
|24 June, 2022 (Shift-II))
Types of Redox Reactions and
7. Theoxidation state of manganese in the product obtained
in areaction of potassium permanganate and hydrogen Balancing of Redox Reactions
peroxide in basic medium is
|27 July, 2022 (Shift-II))
15. 210;txt + 12H’ 61, + 6H,0. What is the value of x?
8. On reaction with stronger oxidizing agent like klO, |8April, 2023 (Shift-I)]
hydrogen peroxide oxidizes with the evolution ofO,.
The
(a) 12 (b) 2
Oxidation number of Iin KIO,, changes to
|28 July, 2022 (Shift-II) (c) 6 (d) 10
16. Which of thefollowing options are corect for the reaction (c) Clo,, Mn0,, CI0, and F,
2|Au(CN),JtZn(s)’ 2Au(s) +(Zn(CN),J (d) Cr,0; , MnO,, CIO, and Cl,
|6 April, 2023 (Shift-1)) 22. 2MnO, +bC,0', t cH'’XMn +yC0, +zH 0
A. Redox rcaction B. Displacement reaction Ifthe above equation is balanced with integer
C. Decomposition reaction D. Combination reaction the value of c is coefficients
|16 March, 2021 (Shift
Choose the corect answer from the options given below: (Round off to the nearest Integer).
(a) Aand Bonly (b) Aonly 23. The reaction of sulphur in alkaline medium is given belo,
(c) CandD only (d) Aand Donly S,(s) +aOH (aq) ’ bS (aq) + cS,0, (aq) +dH.O
17. Which one of the following is an example of The values of 'a' is (Integer answer)
disproportionation reaction? (26 June,2022 (Shift-1I)) |24 Feb, 2021 (Shif-i
(a) 3Mn0;+ 4H ’ 2MnO, +MnO, +2H,0 24. The redox reaction amongthe following is:
(b) MnO, +4H +4e ’ Mn0, +2H,0 |7 Jan, 2020 (Shift
(c) 101 +2Mn0; + 16H" ’ 2Mn' + 8H,0+ 51,
(a) 8Mn0, +3S,0} + H,0 8MnO, +6s0} +2OH (a) Reaction of [Co(H,0),]Cl, with AgNO,
(b) Formation of ozone from atmospheric oxygen in th.
18. Whichof the given reactions is not an example of presence of sunlight
disproportionation reaction? [26 July, 2022 (Shift-))
(a) 2H,0, ’ 2H,0 + O, (c) Combination of dinitrogen with dioxygen at 20 K
(d) Reaction of H,S0, with NaOH
(b) 2NO, + H,0’ HNO, + HNO,
(c) Mn0, +4H + 3e ’ MnO, +2H,O 25. Consider the following equations:
(d) 3MnO, + 4H ’ 2MnO, +MnO, +2H,0 2Fe +H,0, ’ xA+ y B(in basic medium)
(in acidic medium)
19. Match the List-I with List-II. |1Sept, 2021 (Shift-II)] 2MnO, + 6H +SH,0, ’ xC +y'D +ZE
List-I List-II
(in acidic medium) |4 Sept, 2020 (Shift-ID)
(Colloid Preparation (Chemical Reaction) The sum of the stoichiometric coefficients X, y, x', y' and
Method) z' for products A, B, C, Dand E, respectively, is
(A) Hydrolysis () 2AuCl, + 3HCHO + 26. An example of a disproportionation reaction is:
3H,0 ’ 2Au(sol) + [12 April, 2019 (Shift-)|
3HCOOH + 6HCI
(B) Reduction (II) As,0, + 3H,S ’
(a) 2KMn0, ’ K,MnO, +MnO,+ 0,
(b) 2MnO, + 101 +16H*’ 2Mn? + 5L, + 8 H0
As,S,(sol) +3H,0
(c) 2CuBr ’ CuBr,+ Cu
(C) Oxidation () SO, + 2H,S ’ 3S(sol)
(d) 2NaBr+Cl, ’ 2NaCl + Br,
+2H,0
(D) Double (IV) FeCl, +3H,0 -’>
Fe(OH),(sol) +3HCI
Redox Reactions, Electrode
Decomposition
Choose the most appropriate answer from the options Processes and Titrations
given below.
(a) (A)-(IV), (B)-(), (C)-(III), (D)-() 27. Given below are two statements:
(b) (A)-M),(B-(), (C)-(IV), (D)-() Statement-1: In redox titration, the indicators used arc
(c) (A)-(M),(B)-(|I1), (C)-(I), (D)-(IV) sensitive to change in pH of the solution.
(d) (A)-(IV), (B)-(1), (C)-(I), (D)-(II) Statement-II: In acid-base titration, the indicators usel
20. The species given below that does NOT show are sensitive to change in oxidation potential.
disproportionation reaction is: [20 July, 2021 (Shift-I)) (8 April, 2023 (Shift-1D)
(a) BrO (b) BrO, In the light of the above statements, choose the mos
(c) BrO, (d) BrO, appropriate answer from the options given below
21. In which one of the following sets all species show (a) Both Statement-I and Statement-IIl are correct.
disproportionation reaction? (31 Aug, 2021 (Shift-II)) (b) Statement-I is incorrect but Statement-II is correcl.
(a) MnO, Clo,, C1, and Mn' (c) Statemnent-I is correct but Statement-ll is incoret
(b) Clo,, F, Mn0, and Cr,0; (d) Both Statement-I and Statement-II are incorrect.

18 20 mL of calcium hydroxide was consumed when it was neutralization of NaOH with CH,COOH. Compound 'X*
compound
The
reacted with 10 mL of unknown solution of H,SO,. Also exists in ionized form in basic medium.
20 mL standard solution of 0.5MHCl containing 2drops 'X' is |29 July, 2022 (Shift-I)|
of phenolphthalein was titrated with calcium hydroxide. (a) Methyl orange (b) Methyl red
the mixture showed pink colour when burette displayed (d) Erichrome Black T
the value of 35.5 mL whereas the burette showed 25.5 ml. (c) Phenolphthalein
the titration of
initially. The concentration of H,SO, is M 33. 20 mL of 0.02 Mhypo solution is used for
(Nearest integer) |13 April, 2023 (Shift-) 10mL of copper sulphate solution, in the presence of
molarity of
excess ofKIusing starch as an indicator. The
90 Given below are two statements : One is labelled as Cu²' is found to be x10 M. [ncarest integer
Assertion (A)and the other is labelled as Reason (R).
Given: 2Cu+41 Cu,l, + 1,
|28 July, 2022 (Shift-I))
1, +2S,0’21 +S,0
Assertion (A): Permanganate titrations are not performed [26 July, 2022 (Shift-I))
inpresence of hydrochloric acid.
of 0.05 M
Reason (R): Chlorine is formed as a consequence of 34. 0.01 M KMnO, solution was added to 20.0mL
Oxidation of hydrochloric acid. Mohr's salt solution through a burette. The initial reading
In the light of the above statements, choose the correct of 50 mL burette is zero. The volume of KMnO, solution
left in the burette after the end point is mL. (nearest
answer from theoptions given below |28 June 2022 (Shift-I))
integer)
(a) Both (A) and (R) are true and (R) is the correct
explanation of (A) 35. 20mL of0.02 MK,Cr,0, solution is used for the titration
The
of 10 mL of Fe? solution in the acidic medium.
(b) Both (A) are (R)are true but (R) is NOT the correct molarity of Fe* solution is x102 M. (Nearest
explanation of (A) Integer) [27 July 2022 (Shift-)]
(c) (A)is true but (R) is false 36. Given below are two statements. [26 Aug,2021 (Shift-)]
(d) (A) is false but (R) is true Statement-I: In the titration between strong acid and weak
30. In base vs acid titration, at the end point methyl orange is base, methyl orange is suitable as an indicator.
present as |25 July, 2022 (Shift-II)| Statement-II: For titration of acetic acid with NaOH,
(a) Quinonoid form (b) Heterocyclic form phenolphthalein is not a suitable indicator.
(c) Phenolic form (d) Benzenoid form In the light of the above statements, choose the most
31. Given below are two statements one is labelled as
Assertion (A)and the other is labelled as Reason (R). (a) Both Statement-I and Statement-II are false
[26 July, 2022 (Shift-I)) (b) Both Statement-I and Statement-II are true
Assertion (A): Phenolphthalein is a pH dependent (c) Statement-I is true but Statement-II is false
indicator, remains colourless in acidic solution and gives (d) Statement-I is false but Statement-Ilis true
pink colour in basic medium.
37. In basic medium Cr0, oxidises S,0 to form S0 and
Reason (R): Phenolphthalein is a weak acid. It doesn't itself changes into Cr(OH),. The volume of0.154 M CrO
dissociate in basic medium. required to react with 40mL of 0.25 M S,0, is mL.

(Rounded- off to the nearest integer)
4ppropriate answer from the options given below. |25 Feb, 2021 (Shift-I))
(a) Both (A) and (R) are true and (R) is the correct 38. 0.4g mixture of NaOH, Na,C0, and some inert impurities
explanation of (A). was first titrated with HCl using phenolphthalein as
correct 10
(b) Both (A) and (R) are true but (R)is NOT the
explanation of (A). an indicator, 17.5 mL of HCI was required at the end
point. After this methyl orange was added and titrated.
(c) (A)is true but (R) is false
1,5 mL of same HClwas required for the next end point.
(d) (A)is false but (R) is true. The weight percentage of Na,C0, in the mixture is
exhibits colour (Rounded -off to the ncarest integer)
. A compound X' is a weak acid and it
change at pH close to the equivalence point during |25 Feb, 2021 (Shift-l)]
Redox Reactions 127

39. 10.0mL of Na.CO, solution is titrated against 0.2 MHCI 46. The exact volumes of | MNaOH solutionandrequired
solution. The following titre values were oblained in 5 neutralize 50 mL. of IM H,PO, solution 100
2M H,PO, solution respectively, are: ml.
readings: |18 March, 2021 (Shift-11))
4.8 mL, 4,9 mL 5.0 mL S.0 mL and 5.0 mL |16 March, 2021
(a) 100 mL and 50 mL
(Shift-Ji
(b) 100 mL and 200 mi
Based on these readings, and convention of titrimetric
estimation, the concentration of Na,CO, solution is (c) 50 mL and 50 mL (d) 100mL and 100 ml
mM. (Round off to the nearest integer). 47. While titration dilute HClsolution with aqueous NaOt
40. When i0 ml of an aqueous solution of Fe ions was titrated which of the following will not be required?
in the presence of dil H,SO, using diphenylamine indicator,
|2 Sept, 2020 (Shift
15 mL of 0.02 Msolution of K,Cr,0, was required to get (a) Burette and porcelain tile
the end point. The molarity of the solution containing (b) Clamp and phenolphthalein
Fe' ions is x x102 M. The value of x is. (Nearest (c) Pipette and distilled water
integer) |25 July, 2021 (Shift-I)] (d) Bunsen burner and measuring cylinder
41. Consider titration of NaOHsolution versus 1.25 Moxalic 48. The strength of an aqueous NaOH solution is mocs
acid solution. At the end point following burette readings accurately determined by titrating: (Note :consider that
were obtained. [25 Feb, 2021(Shift-II)) an appropriate indicator is used) [8 Jan, 2020 (Shift-)u
() 4.5mL (iü) 4.5 mL (a) Aa. NaOH in a burette and aqueous oxalic acid in a
(iii) 4.4 mL conical flask
(iv) 4.4 mL
(v) 4.4 mL (b) Aq. NaOH in a pipette and aqueous oxalic acid in a
burette
If the volume of oxalic acid taken was 10.0 mL then the
molarity of the NaOH solution is.......M. (c) Aq. NaOH in a volumetric flask and concentrated
H,SO, in a conical flask
(Rounded-off to the nearest integer). (d) Ag. NaOH in a burette and concentrated H,SO, ina
42. When 10 mL of an aqueous solution of KMnO4 was titrated conical flask
in acidic medium, equal volume of 0.1 Mof an aqueous 49. 25 mL of the given HCI solution requires 20 mL of 0.1
solution of ferrous sulphate was required for complete Msodium carbonate solution. What is the volume of this
discharge of colour. The strength of KMnO, in grams per HCl solution required to titrate 30 mL of0.1 Maqueous
NaOH solution? [11Jan, 2019 (Shift-D)
litre is x10. (Nearest integer)
[Atomic mass of K 39, Mn = 55, O= 16] (a) 25 mL (b) 75 mL
(c) 50 mL (d) 12.5 mL
[27 Aug, 2021 (Shift-I)
50. Given : [12 April, 2019 (Shift-)
43. 10.0 ml of 0.05 M KMnO, solution was consumed in
Co' +eCo»; E° =1.81V
a titration with 10.0 mL of given oxalic acid dehydrate
Pb + 2e ’ Pb*; E, = +1.67V
solution. The strength of given Oxalic acid solution is
x 10 g/L [27 July, 2021 (Shift-IID) Cet +eCe E° +1.61V
Bi + 3 e ’ Bi: E° = +0.20V
(Round off to the Nearest Integer).
Oxidizing power of the species willincrease in the order
44. When 35 mL of 0.15Mlead nitrate solution is mixed with
20mL of 0.12 Mchromic sulphate solution, (a) Cet < Pbt<Bi* < Co*
10 moles of lead sulphate precipitate out. (b) Co' < Pbt < Cet < Bi
(Round off to the nearest integer). (c) Bi < Cet< Pb < Co'
[16 March 2021 (Shift-I)] (d) Co' <Cet< Bi<Pb"
51. Inorder to oxidise a mixture one mole of each of FeC,O,
45. 15 mL of aqueous solution of Fe' in acidic medium
completely reacted with 20 ml. of 0.03 Maqueous Cr,0:. Fe,(C,O), FeS0,and Fe, (SO), in acidic medium, the
The molarityof the Fe' solution is x 102 M
number of moles of KMnO, required is:
[8 April, 2019 (Shift-1)
(Round off to the nearest integer). (a) 3
|17 March 2021 (Shift-I) (b) 2
(c) I (d) 1.5
52. In an acid base titration, 0.1 M
|HCI solution was added
n the NaOH solution of unknown strength. Which of the
(C)pH
following corectly shows the change of pH of the titration
nixture in this experiment? 9 April, 2019 (Shift-I))
V(mL)
V(mL)
( 4 PH
)
(B) PH
(a) B (b) A
V(mL) (c) C (d) D

V(mL)
ANSWER KEY
1. (6] 2. [59] 3. [6] 4. (d) 5. [0] 6. [3] 7. [4] 8. (5] 9. [1] 10. (c)
11. (b) 12. (c) 13. (b) 14. [6] 15. (d) 16. (a) 17. (a) 18. (c) 19. (d) 20. (d)
21. (*) 22. [16] 23. [12] 24. (c) 25. [19] 26. (c) 27. (d) 28. [1] 29. (a) 30. (a)
31. (c) 32. (c) 33. [4] 34. [30] 35. (24] 36. (c) 37. [173] 38. [4) 39. (50] 40. [18]
41. (6] 42. (316) 43. [1575] 44. (525] 45. (24) 46. (b) 47. (d) 48. (a) 49. (a) 50. (b)
51. (6) 52. (a)
Redox Reactions 129
EXPLANATIONS
1. (6] CrO,C1, 10. (c) The electronicconfiguration of
Let the oxidation state of chromium is X.
Cr(24) [Ar]4s'3d'
X4-2=0
Hence, chromiumcan show common
Oxidation State = +6 from +2 to +6.
oxidation
2. (59] Let for + 2 oxidation state, x be the
percentage, +6
Cr,Change in oxidation numberst
While (0.83-x) bethe percentage of+ 3oxidation state. 1. (b) Cro7
2r +3(0.83 -x) =2 7
I=0.49
MnO, Mn,Change in oxIdation numberst
% M= 0.49 x 100 =59% Cro ’2Cr3
Change in oxidation number s
0.83 +3 +4
3. [6] Formula of ammonium

phosphomolybdate C02C0,, Change in oxidation number=
(NH,),PO,12Mo0, 12. (c) Ox. no. of Kin K,0, [oxide]
Let X = oxidation state of Mo in MoO, 2x-2 =0
X+(-2) x3 =0 X=+1
X=+6 Ox. no. of Kin K,0, [peroxide]
4. (d) The reaction of KMnO4 with 2x-2 =0
thiosulphate anion in
basic medium is: X=+1
+7
8MnO, +3S,0 +H,0

+4
Ox. no. of Kin KO, [superoxide]
’8MnO, +6S0 +2OH
X-l=0
Hence, Change =7-4=3 x=+1
+6 +6
13. (b) As in H,PO, phosphorus is present in i's maximum
s. [0) Cro;.Cr0} Oxidation state hence it cannot act as reducing agent.
Therefore, difference in oxidation state =0
6. [3] In acidic solution, Mn0? disproportionates to MnO; 14. [6] In Br,0, the number of atoms with zero oxidation
and MnO,. state are zero as shown below:
+6 +4
3MnO? +4H’ 2Mn0, +Mn0, +2H,0
Difference in oxidation state of Mn in product t6 +4 +6
RrBrBr (-2)
=7-4=3
-2)
7. [4] The reaction of polassium permangate and hydrogen
peroxide in basic medium is given as, In F,0,the number of atom with oxidation state zero
basic medium
2KMn0, +3H,0, ’ 2MnO, + 30, are zero and is shown below:
+2H,0 +2KOH
MnO, = t4
)
8. (5] I0, +H,0, ’ I0, +0,

Oxidation number of lin,l0, In H,s,O,, the number of atom with oxidation stale
’ X-8 =-1, x = +7 zero are 2 and is shown below:
2)
Oxidation number of I in,l0,
’ X-6 =-1, x = +5
(-2)
(+0
+3
9. (1) 2KMnO, +SH,C, 0, +3H,S0,(dil)’

+4
K,SO, + 2MnSO,+10C0, +8H,0 In H,S,O, the number of atoms with zero oxidatio
.. Change in O.S = I (+4 to +3) state are3and is shown below:

There the change in oxidation state ofN from zero
reduction of
or native state of +2 oxidation state and
OXygen from 0 to -2 state.
H-O
25. [19] In basic medium:
In C,O,, the number of atoms with zero oxidation 2Fe' + H,0,’ 2Fe' + 20H
state are one and is shown below: In acidic medium:
(0)
2MnO, +5H,0, + 6H" ’ 2Mn + 50, 8H,0
0=C=C=C-0
So, sum of (x + y + x'+y'+ z')= 2 + 2+2 +5 +
15. (d) 210; +10> +12H'’61, +6H,0 8= 19
No. of lodine in product = 12 26. (c) 2CuBr’CuBr, + Cu is adisproportionation reaction
So. No. of lodine should be 12 in reactant then x oxidation state of Cu is changing from +1l to +2 or o.
should be 10 0.02 × 100x5 2x
lE 2x=y
X= 10 0.05x 100× 2 y y
0 0 27. (d) Both statement I and statement I are incorrect because,
16. (a) ’2Au+ in redox titration, indicators are sensitive to oxidation
potential and in acid base titration, indicators are
It isa redox reaction in which Zn displaced Au sensitive to change in pH of the solution.
Reduction and Oxidation both are taking place. 28. [1] Reaction of Ca(OH), with HCl is
Ca(OH), +2HCI’ CaCI, +2H,0
17. (a) Disproportionation reaction is given in option (a).
+4 Volume of Ca(OH), = 10ml
3MnO? +4H’2MnO, + MnO, +2H,0 Volume of HCI = 20 ml
Concentration of HCl =0.5 M.
18. (c) MnO4 + 4H +3e’ MnO, +2H,0 is reduction
No. of milli moles of HCI= 10
process, while rest others are examples of
disproportionation reaction. No. of milli moles of Ca(OH), 5.
no. of milli moles 5
19. (d) FeCI, +3H,0 -’ Fe(OH), + 3HCI (Hydrolysis)
2AuCl, ’ 2Au (Reduction)
Mca(OH)2 V(ml) 10
As,0, +3H,S ’ As,S, +3H,0 Reaction of Ca(OH), with H,S0, is

(Double Decomposition) Ca(OH), +H,S0, ’ +CaSO, +2H,0.
SO, +2H,S ’ 3S +2H,0 (Oxidation) No. of millimoles of Ca(OH), = 20 x 0.5 =10
20. (d) Br has +7 0.S in BrO,, therefore it only acts as a i.e. no. of millimoles of H,SO, = 10
Oxidizing reagent and as a result, does not undergo no. of millimoles 10
=1M
disproportionation reaction. Myso4 v(ml) 10
21. (*) CIO,, CI, Mn can show disproportionation reaction Hence, concentration of H,SO, =1M
while MnO, cannot show disproportionation reaction
29. (a) 2KMnO, + 16HCI’ 2MnCl, +2KCl+ 8H,0 +CI,
as Mn is in +7 oxidation state.
KMnO, oxidizes HClto CI,, as a result, HClcannot
None of the given options is corect. be used in permanganate titration.
22. [16] The given equation can be balanced as: 30. (a) Athe end point methyl orange is exist as quinonnoid
2MnO, + 5C,0, + 16H* ’ 2Mn + 10CO, + form in an acid-base titration.
8H,0
Hence, value of c= 16
23. (12] The complete balanced equation is:
sorO=O
Benzoid form
4S (aq) + 28,0,(aq) + (Yellow colour)
S,(s) + 120H (aq)
6H,0() CCH
According to the above reaction, a = 12 so, -NH-N= CH,
2000 K
24. (c) Combination of dinitrogen with dioxygen at Quinonoid form
(Pinkish red)
N,(g) +0,(g) ’ 2NO(g)
Redox Reactions 131
31. () Phenolphtalein is a weak acid which is colourless in 38. 14] NaOH +Na,CO,
acidic medium but in basic medium gives pink colour.
Iis pH depcndent indicator. The pink colour is due () On addition of Hph,
to its conjugate form. Phenolphthalein dissociates in
basic medium. m.e. NaOH +m.e
2
Na,CO, =m.e
HPh(aq.) H' Ph
HC| = 17.5x=1.75
(Colourless) (Pink) 10
32. (c) An indicator of weak acid which in basic medium (m.e. = milli equivalents
produces pink colour is phenolphthalein. (2) On adding MeOH after Hph;
33. (4) According to given condition, m.e Na,C0, =m.e HCIl= 1,5x10 -=0.15
2
meq of 1, = meq of Na,S,0,
.. m.e. NaOH = 1.75 0.15 = 1.6
=20 x 0.002 x 12 x mmol of I, = 04
m.e Na,C0, =0.15 x 2=0.3
mmol of 1, = 0.2 mmol
mmol of Cu' = 0.2 x 2 x10 WNs,cO, -x1000 = 0.3
0.4x103
Molarity of (Cu]= 10x103 =0.04= 4 x 10 M
Ea,CO, 0.3x53
34. (30] n-factor of KMnO, in acidic medium =5 Wn,co, 1000 Eaco, =53
n-factor of Mohr's salt = 1 Weight %of Na,CO,
0.3x53
of KMnO, = m of Mohr's salt
1000 0.3x53 1S.9
=M Xnmohr's salt x100 =3.975 x4%
Mohr's salt 0.4 10×04
0.01 x5 =V=0.05 x] =20
Thus, volume of KMnO, used, V= 20 mL 39. (50] V,Nayco, =10mL (Given)
Total volume of burette = 50ml
Volume of HCI used will be 5 mL (average of titre
So; volume of KMnO, left in burette = 50- 20mL
values)
= 30 mL
Mof HCl= mof Na,C0,
35. (24] Meq of K,Cr,0, =Meq of Fe? (M × n-factor x V),u(MXn-factor XV)NCO,
(Mx Volume xn) ofK,Cr,0,-(M× Volume x n) ofFe 0.2 x 1 x5= Mx 2 x 10
0.02 x 20 x6= Mx 10 x 1 M=0.05 M
Molarity =24 x 10² M M=50 mM
36. (c) The Methyl orange indicator has 3.2 to 4.2 as pH
40. (18] Cr,0 +Fe*? ’Fe*+Cr*3
range which is suitable for buffer made by weak base
m.eCH0; =M.e,Fet2
and strong acid. Hence, I is true.
Statement Il is false since, phenolphthalein has pH Vx Mxn,=VxMxn,
range (8.4 to 10.2) and only suitable for equivalence 15 x 0.02 x 6= 10 x M x1
point greater than 7. In this case, pH gets increased
by the addition of NaOH on acetic acid, CH,COOH. ..M= 15x0.02 x6 =0.18=18×10*M
Hence, it is suitable indicato. 10
37. [173](+6) (+2) (+3) (+6) 41. [6] Meq of NaOH - Meqof H,C,0,
CrO; + S,o;? ’ Cr(OH), + So M,x V, x n, =M, xV,x n,
4,44 x N= 1.25 x 2 x 10
n factor ofS,0, =8 (2 x4)
nfactor of CrO =3 (3 x 1) 1.25x2x10 =5,63
Now, m.e., Cro,?=m.e S,0: 4.44
Vx Mx n,= VxM x n, .:N=M=5.63 6.
80 42. (3 16]Let the molarity of KMn0, be x
Vx (0.154 x 3) =40 x (0.25 x 8)
0.462
= 173.16 mL 173 mL
KMnO, +FeSO, ’ Fe, (SO,), + Mn?
n,=5 n,=1 Ferric sulphate

We know that
Meq Cr,0; = MeqFe'
equivalent of KMnO, =equivalent of FeSO, = M XYe
DgkMO,) XKmo,) XMaM0,)=Mso) x rso, MrsO,)
20 x 0.03 x 6= 15 x M x I
5xx x10 = 1x 0.1x10
20x 0.03 x 6 = 0.24 =24 x 102
On solving M,=
X=0.02M
Strength =Molarity xMolecular weight 46. (b) According to question,
=(0.02 x158) =3.16g /L
Meg of Base = M_ ofAcid
100mL of NaOH
=316 x10g/L For H,PO,; 1xV=50x | x2.:. V=
NaOH
43,[1575] For H,PO,; 1xV= 100x2 x1.. V= 200mL ofBunsen
H 47. (d) In thisacid base titration, there is no use of
MnO, + H,C,0,2H,0 ’ Mn?' + C0, burner and measuring cylinder. For getting the end
n,=(5) n,- (2) poinof titration other laboratory equipment will be
Milli equivalent of C,0; - mili equivalent of MnO, required.
n, xMx V=n, xMxV 48. (a) The strength of an aqueous NaOH solution is most
2 x Mx 10 =5 x 0.05 x 10 accurately determined by treating Aq. NaOH in a
M=0.125M
burette and aqueous oxalic acid in a conical flask.
49. (a) Apply law of equivalence:
M:
Strength
M.M of H,C,0,.2H,0 m of HCl = m of NaOH
25 x N = 30 x 0.1 x 2
Strength = 0.125 x 126 g/L 30× 0.2 6 1.2
=15.75g /L= 1575 x 10 g/L 25 5 x0.2=
44. [5251The reaction occurs as: For the 2nd titration
of HCI= m, of NaOH
3Pb(NO,), +Cr,(S0,),’ 3PbS0, +2Cr(NO,),
Att=0 35 x 0.15 20 x 0.12 1.2
x Vu=
HCI
30 x 0.2
= 5.25 mmole = 2.4 mmole
2 6x5 30
Att= 0 0 (2.4-1.75) 5.25 x 2.25 VHCI = 1.2 -=25mL
3 1.2
mmole mmole mmole 50. (b) Lower the standard reduction potential, more the
ability to get reduced higher the oxidizing power Bi
Hence, the total moles of PbS0, precipitated out has the higher oxidising power.
= 5.25 x 10= 525 x 10 moles.
S1. (b) , KMn0, -n, (FeC;0, +Fe(C,0),+ FeSo]
45. (24] The reaction is: or nx5=|x3+ l x 6+1x 1
.:. n=2
Cr,0% + Fe?" H, Cr + Fe'*
52. (a) The pH of NaOH is more than 7 and during the
n,=6 n, = 1 titration it decreases.
Redox Reactions 133

Hydrogen
In tbe light of the above statements, choose the m

' fr h ' ' OSI
l
appropnate answer om t e options given below:
Preparation, Properties of (a) Both (A) and (R) are correct but (R) is NOT th
Dihydrogen & Hydrides correct explanation of (A) e
(b) Both (A) and (R) are correct and (R) is the correct
1. Match List-I with List-II. 125 Jan, 2023 (Shift-II)) explanation of (A)
List-U (c) (A) is not correct but (R) is correct
List-I
(I) (H2 + Clz) production (d) (A) is correct but (R) is not correct
(A) Cobalt catalyst
(II) Water gas production 5. Given below are two reactions, involved in the commercial
(B) Syngas
production of dihydrogen (H2).
(C) Nickel catalyst (lll) Coal gasification
The two reactions are carried out at temperature "T1"and
(D) Brine solution (IV) Methanol production
"T/ respectively
Choose the correct answer from the options given below: T
(a) (A)-(IV), (B)-(l), (C)-(II), (D)-(IU) C(s) + Hp(g) ~ CO(g) + H/g)
T
(b) (A)-(IV), (B)-(III), (C)-(l), (D)-(11) CO(g) + Hp(g) ~ CO (g) + H2(g)
(c) (A)-(Il), (B)-(111), (C)-(fV), (D)-(1)
The temperature T1 and T2 are correctly related as
(d) (A)-(IV), (B)-(Ilf), (C)-(Il), (D)-(1) 110 April, 2023 (Shift-1)1
2. Which of the given compounds can enhance the efficiency (a) T1 > T2
of hydrogen storage tank? 129 Jan, 2023 (Shift-I))
(b) Tl =T2
(a) Li/P4 (c) T1 = 100 K, T2 = 1270 K
(b) SiH 4 (d) Tl < T2
(c) NaNi 5 6. Given below are two statements: one is labelled as
(d) diisobutylaluminium hydride Assertion (A) and the other is labelled as Reason (R).
3. The water gas on reacting with cobalt as a catalyst forms Assertion (A): Physical properties of isotopes of hydrogen
[8 April, 2023 (Shift-nl are different.
(b) Methanoic acid Reason (R): Mass difference between isotopes of
(a) Ethanol
hydrogen is very large. 110 April, 2023 (Shift-11)1
(c) Methanal (d) Methanol
In the light of the above statements chose the correct
4. Given below are two statements, one is labelled as answer from the options given below;
(a) (A) is false but (R) is true. ·
Assertion A: Isotopes of hydrogen have almost same (b) Both (A) and (R) are true and (R) is the NOT th(
chemical properties, but difference in their rates of correct explanation of (A).
reaction. (c) (A) is true but (R) is false.
Reason R: Isotopes of hydrogen have different enthalpy (c~ Both (A) and (R) are true and (R) is the correct
of bond dissociation. I13 April, 2023 (Shift-11)1 explanation of (A).
r Given below are two statements: one is labelled as
Assertion (A) and the other ts labelled as Reason (R).
Assertion A: Hydrogen is an environment friendly fuel.
(a) Reaction of zinc aqueous alkali .
(b) Electro lysi s of ac idifi ed water using platinum
electrodes.
Reason R: Atomic number of hydrogen is I and it is a .
(c) Electro lys is of warm aq ueous ba rium hydroxi de
very light element. I1 Feb, 2023 (Shift-I)! solution between nickel electrodes.
answer from the options given below (d) Reaction of zinc with dilute acid.
(a) (A) is true but (R) is fa lse 13. Which of the fo llowing form s of hydroge n emi_t; ~~~
(b) Both (A) and (R) are true but (R) is NOT the correct energy ~ - particles? 126 Feb, 2021 (Shi t-
explanation of (A) (a) Proton 1-f+ (b) Tritium :H
(c) (A) is false· but (R) is true (c) Oeuterium ~H (d) Protium :H
(d) Both (Ar and (R) are true and (R) is the correct
14. lsotope(s) of hydrogen which emits low energy~- p~rticles
explanation of (A) .
with t value > 12 years is are :(22 July, 2021 (Shift-11)1
8. Match List-I with List-II . 112 April, 2023 (Shift-I) I 1/2
(a) Protium (b) Tritium
List-I List-II
(c) Deuterium (d) Deuterium and Tritium
Type of Hydride Example
(A) Electron deficient (I) MgH 2 15. Given below are two statements :
hydride Statement-I: The process of producing syn-gas is called
(B) Electron rich hydride (II) HF gasification of coal.
(C) Electron precise (III) B2H6 Statement-II: The composition of syn-gas is CO + CO 2
hydride + H (I : I : 1) (31 Aug, 2021 (Shift-I))
2
(D) Saline hydride (TV) CH 4 In the light of the above statements, choose the most
Choose the correct answer from the options given below: appropriate answer from the options given below:
(a) (A)-(Ill), (B)-(11), (C)-(IV), (O)-(I) (a) Statement-I is true but Statement-II is false
(b) (A)-(II), (B)-(III), (C)-(IV), (O)-(I) (b) Both Statement-] and Statement-II are true
(c) (A)-(lJ), (B)-(III), (C)-(1), (O)-(IV) (c) Statement-I is false but Staiement-II is true
(d) (A)-(III), (B)-(II), (C)-(I), (O)-(fV) (d) Both Statement-I and Statement-II are false
9. Dihydrogen reacts with CuO to give 16. Given below are two statements : one is labelled as
[28 June, 2022 (Shift-I)) Assertion (A) and the other is labelled as Reason (R).
(a) CuH 2 (b) Cu [24 Feb, 2021 (Shift-Il)J
(c) Cup (d) Cu(OH\ Assertion (A): Hydrogen is the most abundant element
in the Universe, but it is not the most abundant gas in the
I0. The highest industrial consumption of molecular hydrogen
troposphere.
is to produce compounds of element:
Reason (R): Hydrogen is the lightest element
124 June, 2022 (Shift-DJ
(a) Carbon (b) Nitrogen
answer from the options given below:
(c) Oxygen (d) Chlorine
(a) Both A and R are true but R is NOT the correct
11. Hydrogen has three isotopes: protium (1H), deuterium explanation of A
(2H or D) and tritium (3H or T). (b) A is false but R is true
(28 June, 2022 (Shift-IijJ (c) Both A and Rare true and R is the correct explanation
They have nearly same chemical properties but different of A
physical properties. They differ in · (d) A is true but R is false
(a) number of protons. 17. Deuterium resembles hydrogen in properties but:

(b) atomic number. 127 Aug, 2021 (Shift-I)!
(c) electronic configuration (a) reacts vigorously than hydrogen
(d) atomic mass (b) emits rt particles
12. High purity(> 99.95%) dihydrogen is obtained by (c) reacts just as hydrogen
125 July, 2022 (Shift-II)) (d) reacts slower than hydrogen
18. Which one of the fo llowing metals fonn s interstitial (a) 4 (b) 3
hydride easil y? 125 July, 2021 (Shift-11)1 (c) 2 M l
(a) Fe (b) Cr
26 • The total number of isotopes of hydrogen and nunib'er
(c) Mn (d) Co radioacti·ve isotopes
· among th em, respecti·ve ly are· or
19 • The number of neutrons and electrons respectively, present 110 Jan, 2019 (Sh1·r
in the radioactive isotope of hydrogen is: (a) 3 and I (b) 3 and 2 '·l)I
127 July, 2021 (Shift-11)1 (c) 2 and I (d) 2 and 0
(a ) 2 and I (b) I and I
27. Among the follo~ ing reactions ~f.hydrogen with halogens
(c) 3 and I (d) 2 and 2 the one that requires a catalyst ts. ·
20. The single largest industrial application of dihydrogen is : 110 Jan, 2019 (Shift.II
120 July, 2021 (Shift-11)1 (a) H + ½➔ 2HJ (b) H1 + F1 ➔ 2HF )I
1
(a) Rocket fuel in space research
(c) H1 + Cl1 ➔ 2HC1 (d) H1 + Br1 ➔ 2HBr
(b) In the synthesis of nitric acid 28. The correct statements among (i) to (iv) are:
(c) In the synthesis of ammonia
110 April, 2019 (Shift.fl)!
(d) Manufacture of metal hydrides (i) saline hydrides produce H1 gas wnen reacted with
21. Which one of the following statements is incorrect? HlO.
131 Aug, 2021 (Shift-II)) (ii) reaction of LiAIH 4 with BF3 leads to B1H6.
(a) Atomic hydrogen is produced when 8i molecules at
a high temperature are irradiated with UV radiation. (iii) PH 3 and CH4 are electron - rich and electron-precise
hydrides, respectively.
(b) Bond dissociation enthalpy of H1 is highest among
(iv) HF and CH4 are called as molecular hydrides.
diatomic gaseous molecules which contain a single
bond. (a) (iii) and (iv) only (b) (i), (ii) and (iii) only
(c) Dihydrogen is produced on reacting zinc with HCI as (c) (i), (ii), (iii) and (iv) (d) (i), (iii) and (iv) only
well asNaOH(aq). 29. The hydride that is NOT electron defi cient is:
(d) At around 2000 K, the dissociation of dihydrogen [11 Jan, 2019 (Shift-II)!
into its atoms is nearly 8.1 %. (a) SiH 4 (b) B1H6
(c) GaH3 (d) AlH 3
22. Water does not produce CO on reacting with:
125 Feb, 2021 (Shift-II)) 30. NaH is an example of: 111 Jan, 2019 (Shift-01
(a) CJH8 (b) col (a) electron rich hydride (b) metallic hydride
·(c) CH 4 (d) C (c) saline hydride (d) molecular hydride
23. Deuterium resembles hydrogen in properties but: 31. The metal that gives hydrogen gas upon treatment with
127 Jul 202 I (Shift-I)) both acid as well as base is: 112 April, 2019 (Shift-01
(a) reacts vigorously than hydrogen (a) zinc (b) iron
(b) emits W particles (c) magnesium (d) mercury
(c) reacts just as hydrogen
32. The correct statements among (a) to (d) regarding H2 as
(d) reacts slower than hydrogen a fuel are: 111 Jan, 2019 (Shift-1)1
24. Dihydrogen of high purity (>99.95%) is obtained through: (A) it produces less pollutants than petrol
. 16 Sept, 2020 (Shift-II)) (8) A cylinder of compressed dihydrogen weighs -30
(a) the reaction of Zn with dilute HCI. times more than a petrol tank producing the same
(b) the electrolysis of acidified water using Pt electrodes amount of energy.
(c) the electrolysis of brine solution. (C) Di hydrogen is stored in tanks of metal alloys like
(d) the electrolysis of warm Ba(OH\ solution using Ni NaNi5
electrodes. (D) On combustion, val ues of energy released per granl
of liquid dihydrogen and LPG are 50 and 142 kJ,
25. Hydrogen has three isotopes (a), (b) and (c). I_fthe number
respectively.
of neutron(s) in (a), (b) and (c) respectively, are (x), (y)
(a) (B) and (D) only (b) (A) and (D) only
and (z), the sum of (x), (y) and (z) is:
18 Jan, 2020 (Shift-11)1 (c) (B), (C) and (D) only (d) (A), (B) and (C) only
fl JEE PYQs Chemistry
~
33. The isotopes or hydrogen :ire: 19 .Ian, 2019 (Shlrt-1)1 40. The metal sails formed during softening of' hard watcr
(a) Tritium and protium only using Clark 's method arc: 128 .July, 2022 (Shift-1)1
(b) Protium and deuterium only
(a) Ca(011)2 and Mg(OH)2 (h) CaC'O 1 and Mg(Oll )2
(c) Protium, deuterium and trit ium
(c) Ca(OH)2 and MgC0 1 (J) CaC0 3 and MgCOJ
(d) Deuterium and tritium only
4 I. The runctional groups that are responsible for the ion-
exchange property of cation and anion exchange resins,
Preparation, Properties of H2O &J respectively, a1'e:
(a) - SO/I and - NH2
117 March, 2021 (Shift-11)1
(b) - S03H and -COOH
Heavy Water
(c) - N!-1 2 and - COOH (d) - NH 2 and - S0 1H
42. Which one of the fo llowing methods is most suitable for
34. Given below are two statements: preparing deionized water? 126 Aug, 2021 (Shift-I)]
Statement-I: Pem1utite process is more efficient compared
(a) Permutil method (b) Synthetic resi n method
to the synthetic resin method for the softening of water.
Statement-0: Syntl1etic resin metl1od results in tl1e formation (c) Calgon's method (d) Clark's method
of soluble sodium salts. 113 April, 2023 (Shift-11)1 43. Given below are two statements : One is label led as
In the light of the above statements, choose the most Assertion (A) and the other is labelled as Reason (R).
appropriate answer from the options given below: [18 March, 2021 (Shift-I)]
(a) Both the Statement-I and Statement-II are correct Assertion (A): During the boi ling of water having
(b) Statement-I is correct but Statement-II is incorrect temporary hardness, Mg(HC0) 2 is converted to MgC03 .
(c) StatemenFI is incorrect but Statement-II is correct Reason (R): The solubility product of Mg(OH)2 is greater
(d) Both the Statement-I and Statement-11 are incorrect than that of MgCOr
35. The starting mater.ial for convenient preparation of In the light of the above statements, choose the most
deuterated hydrogen peroxide (Dp2) in laboratory is: appropriate answer from the options given below:
11 Feb, 2023 (Shift-II)] (a) Both (A) and (R) are true and (R) is the correct
(a) ~SPs (b) 2-ethylanthraquinol explanation of (A)
(c) Ba02 (d) BaO (b) (A) is false but (R) is true
36. During water-gas shift reaction [15 April, 2023 (Shift-DJ (c) (A) is true but (R) is fa lse
(a) carbon monoxide is oxidized to carbon dioxide. (d) Both (A) and (R) are true but (R) is NOT the correct
(b) carbon is oxidized to carbon monoxide. explanation of (A)
(c) carbon dioxide is reduced to carbon monoxide. 44. Calgon is used for water treatment. Which of the following
(d) water is evaporated in presence of catalyst. statement is NOT true about Calgon?
37. Decreasing order of the hydrogen bonding in following 126 Feb, 2021 (Shift-Inl
forms of water is correctly represented by
(a) It is also known as Graham 's salt.
124 Jan, 2023 (Shift-I)]
(A) Liquid water (b) It is polymeric compound and is water soluble.
(8) Ice
(C) Impure water (c) It doesn't remove Ca2+ ion by precipitation.
(a) (A) = (8) > (C) (b) (B) > (A) > (C) (d) Calgon contains the 2nd most abundant element by
(c) (C) > (B) > (A) (d) (A) >.(B) > (C) weight in the Earth 's crust.
38. The products obtained during treatment of hard water 45. The INCORRECT statement(s) about heavy water is
using Clark's method are: 128 July, 2022 (Shift-II)] (are) 11 7 March, 2021 (Shift-1)1
(a) CaC03 and MgC0 3 (b) Ca(OH\ and Mg(OH) 2 (A) used as a moderator in nuclear reactor
(c) CaC03 and Mg(OH\ (d) Ca(OH) 2 and MgC03 (8) obtained as by-product in fertilizer industry
39. Boiling of hard water is helpful in removing the temporary (C) used for the study of reaction mechanism
hardness by converting calcium hydrogen carbonate and
(D) has a higher dielectric constant than water
magnesium hydrogen carbonate to
126 June, 2022 (Shift-II)] Choose the correct answer from the options given below:
(a) CaC03 and Mg(OH)2 (b) CaC03 and MgC0 3 (a) (D) only (b) (C) only
(c) Ca(OH)2 and MgC0 3 (d) Ca(OH)2 and Mg(OH\ (c) (8) only (cl) (B) and (D) only
4
b. Given bcl0w :lt\' two statements: one is l:ibelled as (a) Calgon's method
AssN·tion (A) and the other is labelled as Reason (R).
(b) Clark 's method
126 Aug, 202 t (Shift-11)1 (c) Treatment with sodium carbonate
Assertion (A): Heavy waler is used for the study of
reaction mechanism. (d) Ion-exchange method
Ruson (R): The rate ofreaction for the cleavage ofO- H SI. The synonym for waler gas when used in the producr
bond is slower than that of 0- 0 bond. of methanol is: 110 April, 2019 (Shift~~~
Choose the most appropriate answer from the options (a) natural gas · (b) laughing gas
given below: (c) syn gas (d) fuel gas
(a) (A) is true but (R) is false. 52. I 00 mL of a waler sample contains 0.8 1 g of calci
. Ul)t
(b) (A) is false but (R) is true. bicarbonate and 0: 73 g of maines1um bicarbonate.
(c) Both (A) and (R) are true but (R) is the true The hardness of this water sample expressed in term
explanation of (A). of equivalents of CaCO3 is: (molar mass of calciu s
bicarboriate is 162 g mol· 1and magnesium bicarbonate:
(d) Both (A) and (R) are true and (R) is not the true 1
explanation of(A). 146 g mol- ) 18 April, 2019 (Shift-I)!
(a) l,000 ppm (b) 10,000ppm
47. Statements about heavy water are given below:
(c) I00 ppm (d) 5,000 ppm
126 Feb, 2021 (Shift-DI 53. The hardness of a water sample (in terms of equivalents
(A) Heavy water is used in exchange reactions for the of CaCO) containing I0-3 M CaSO4 is: (molar mass of
study of reaction mechanisms. CaSO4 = 136 g mol· 1) 112 Jan, 2019 (Shift-OJ
(B) Heavy water is prepared by exhaustive electrolysis (a) I00ppm (b) 50ppm
of water (c) IO ppm (d) 90 ppm
(C) Heavy water has higher boiling point than ordinary 54. The temporary hardness of water is due to
water.
19 Jan, 2019 (Shift-D)J
(D) Viscosity ofHp is greater than op.
(a) Na2SO4 (b) NaCl
Choose the most appropriate answer from the options (c) Ca(HCOJ2 (d) CaCl2
given below:
(a) (A) and (D) only 55. The temporary hardness of a water sample is due to
(b) (A), (8) and (C) only
compound X. Boiling this sample converts X to compound
(c) (A) and (B) only (d) (A) and (C) only
Y. X and Y, respectively, are 112 April, 2019 (Shift-U)J
48. In comparison to the zeolite process for the removal of (a) Ca(HCO)l and Cao
permanent hardness, the synthetic resins method is
(b) Mg(HCO3) 2 al)d MgCO3
17 Jan, 2020 (Shift-DI
(c) Mg(HCO 3) 2 and Mg(OH),
(a) less efficient as it exchanges only anions
(d) Ca(HCO3\ and Ca(OH)z
(b) more efficient as it can exchange only cations
(c) less efficient as the resin cannot be regenerated
(d) more efficient as it can exchange both cation as well
as anions
49. The equation that represents the water-gas shift reaction
I Preparation!'~ro~erties of H,ol
56. In which of the following reactions the hydrogen peroxide
1s 15 Sept, 2020 (Shift-I)! acts as a reducing agent? 124 Jan, 2023 (Shift-IOI
(a) CO(g) + Hp(g) 673
K CO 2(g) + H2(g) (a) · PbS + 4Hp2 ➔ PbSO4 + 4H O
Catalyst 2
(b) 2Fe2' + Hlo l ➔ 2Fe3+ + 2OH·
1270K
(b) C(s) + Hp(g) (c) HOC! + H,O, ➔ HJO' + Cl· + 0 ,•
• •
(c) 2C(s) +Oz(g) + 4N 1 1273 K 2CO(g) + 4Nz(g) (c~ Mn ' + Hp2 ➔ Mn4' + 2OH
2
1270K
57. Which of the following can reduce decomposition ofHP
(d) CH 4(g) + Hp(g) CO(g) + 3Hz(g) on exposure to light JS April, 2023 (Shift-Illl
Ni
50. The one that is NOT suitable for the removal of permanent (a) Alkali (b) Urea
hardness of water is: 15 Sept, 2020 (Shift-11)1 (c) Dust (d) Glass containers
JEE PYQs Chemistry - - - - - - - - - - - - - - - - - - - - - - - - - - -
,!a,~
> (h) Mn 1 ' , Il l) onl y
. H,O acts as a reducing agent in 131 .Inn, 202:\ (Shlft-1)1 (a) Mn 1' , II }) only
58 2 (d) Mnl', ll / J, O2onl y
(;) 2NaOCI + H20 2 ➔ 2NnCI -l 1\ 0 1 0 2 (c) Mn4 ' , I lp , (\ only
1
(b) 2Fe 2' + 2H' + Hp 2 ➔ 2Fc '-1 21110 66. Uivc n below arc two ~latcmcnl s.
[27 .July, 2022 (S~i~t~l)I
(c) Mn2' + 2Hp 1 ➔ MnO1 -l 21Ip
(d} Na 2S + 41-1 20 2 ➔ Na 2SO4 + 41lp Sflll cment -1: Hydrogen peroxide can act as an ox 1d1z111g
agent in both ac idic and basic cond itions. .
li9. Given below arc two stalemcnls: peroxide at
298 K '"
St11l cment-ll : Density of hydrogen
· Statement-I: HP i is used in the synthesis ofCephalosporin
lower than that of' Dp .
Statement-II : Hp 2is used for the restoration of aerobic th
In the light of the above statements, choose e correct
conditions lo sewage wastes. 131 Jan , 2023 (Shift:-11)1 answer from the options given below.
ln the light of the above statement s, choose the most (a) Both Statement -I and Statement -II are true.
appropriat e answer fro m the opti ons g·iven below:
(b) Both Statement -I and Statement -II are fa lse.
(a) Both·Statement -I and Statement II are correct
(c) Statement-I is true but Statement- II is fa lse.
(b) Statement-I is incorrect but Statement -II is correct
(d) Statement-I is fa lse but Sta tement-II is true.
(c) Statement -I is correct but Stalem~nt -11 is incorrect
(d) Both Statement -I and Statement-II are incorrect
67. Given below are two statement s : One is labell ed as
60. '25 volume' hydrogen peroxide means
120 July, 2021 (Shift-1)1
125 Jan, 2023 (Shift-1)1
(a) 1 L marketed solution contains 250 g of Hp 2. Assertion (A): The dihedral angles in Hp 2 in gaseous
(b) 1 L marketed solution contains 75 g of Hp 2. phase is 90.2° and in solid phase is 111 .5°.
(c) 100 mL marketed solution contains 25 g of Hp 2. Reason (R): The change in dihedral angle in solid and
(d) 1 L marketed solution contains 25 g ofHp 2. gaseous phase is due to the di fference in the intermolec ular
61. The strength of 50 volume solution of hydrogen peroxide forces.
ts _ _ _ _ g/L (Nearest integer). Choose the most appropriate answer from the options
Given: given below fo r (A) and (R).
Molar mass of Hp 2is 34 g moJ-1 (a) (A) is correct but (R) is not correct.
Molar volume of gas at STP = 22.7 L. (b) Both (A) and (R) are correct but (R) is not the correct
[30 Jan, 2023 (Shift-ID I explanatio n of (A).
(c) Both (A) and (R) are correct and (R) is the correct
62. Which of the fo llow i.ng can be used to pre vent the
126 July, 2022 (Shift-1)1 explanation of (A)
decompos ition of Hp /
(d) (A) is not correct but (R) is correct.
(a) Urea (b) Formaldehyde
(d) Ethanol
68. In basic medium, Hp 2 exhibits which of the following
(c) Formic acid [18 March, 2021 (Shift-Il)J
reactions?
63. Which one of the fo llowing reacti ons indi cates the
(A) Mn 2• ~ Mn4• (B) 12 ~ 1-
reducing abil ity of hydrogen peroxide in basic medium?
(C) PbS ~ PbSO4
[29 July, 2022 (Shift-1)1
Choose the most app ropriate answer fro m the options
(a) HOCI + HP 2~ H)o ++ c 1- + 0 2 given below:
(b) PbS + 4Hp 2~ PbSO 4 + 4H,O (a) (A), (C) only (b) (B) only
(c) 2MnO4-+ 3Hp 2 ~ 2MnO2 + 302 + 2Hp + 2OH· (c) (A), (8) only (d) (A) onl y
(d) Mn2• + H2O2 ~ Mn4• + 2OH-
69. (A) HOCI + H2O2 ~ HJ0 + + c 1- + O2
64. The reaction of Hp 2 with potassium permanganate in
(B) 12+ HlOl + 2OH- ~ 21- + 2H,O + 0 ,
acidic medium leads to the formation of mainly.
Choose the correct option. 124 F; b, 2oi 1 (S hift-1)1
[25 July, 2022 (Shift-1)1
(b) Mn 4• (a) Hp 2 acts as ox idizing agent in equations (A) and (B)
(a) Mn 2•
(c) Mn 6• (b) Hp 2 act_as oxidizing and reducing agent respective ly
(c) Mn 3•
111 equati ons (A) and (B)
65. The products obtai ned from a reaction of hydroge n (c) ~P i acl~as reducing and ox idizing agent respectively
peroxide and acidi fied potassium permanganate are 111 equations (A) and (B)
126 July, 2022 (Shift-11)1 (d) 1-tp 2acts as reducing agent in equati ons (A) and (B)
70. Hydrogen pero:-.ide reacts \\'ith iodine in basic medium to (a) non-planar and almost colorless
give : 11 Sept, 2021 (Shift-11)1 (/J) planar and blue in color
(a) 10 (h) I (c) linear and blue in color
(c) 10 , (d) 10 , (cl) linear and almost colorless
71. Which of the fo llowi ng equation depicts the oxidizing
nature of 1\0/ 125 Feb, 2021 (Shift-1)1 77. Among statements (A) - (D), the correct ones are
(a) 21 + H,O, + 2H' ➔ 1 + 2H 0 17 Jan, 2020 (Shift-lJ)
• • 2 1
(h) Cl:+ Hp, ➔ 2HCI + 0 (A) Decomposition of hydrogen peroxide gives dioxy I
2
(c) KIO,+ H2O, ➔ KIO_,+ Hp + 0 gen
2 (B) Like hydrogen peroxide , compounds such ·
(d) 1, + H,O, + 2OH- ➔ 21- +2H O + 0 a1
• • • ,2 2 KCIO 3, Pb(NO 3) 2 and NaNO 3 when heated liberat
' e(j
72. Given below are two statements: d1oxygen.
116 Mardi, 2021 (Shift-I)] (C) 2-Ethylanthraquinone is useful for the industrial
Statement-I: ~0 2 can act as both oxidizing-and reducing preparation of hydrogen peroxide
agent in basic medium. (D) Hydrogen peroxide is used for the manufacture of
Statement-II: In the hydrogen economy, the energy is sodium perborate
transmitted in the form of dihydrogen . (a) (A), (B), (C) and (D) (b) (A) and (C) only
In the light of the above statements, choose the correct (c) (A), (8) and (C) only (d) (A), (C) and (D) only
78. The volume strength of8.9 MHp 2 solution calcidatedai
(a) Both statement-I and statement-II are false 273 Kand I aim is (R = 0.0821 L atm K·1 mol·1) (rounded
(b) Statement-I is false but statement-II is true off to the nearest integer) [3 Sept, 2020 (Shift-DI
(c) Both statement-I and statement-II are true 79. At 20.0 mL solution containing 0.2 g impure Hp reacts
1
(d) Statement-I is true but statement-II is false completely with 0.316 g of KMnO 4 in acid solution. The
purity ofHp 1 (in %) is _ _ __ _
73. The product obtained from the electrolytic oxidation of
acidified sulphate solutions, is: (27 July, 2021 (Shift-I)] [4 Sept, 2020 (Shift-DI
(a) HSO 4 · (b) HO3SOOSO3H (mo!. wt. ofHp2 = 34; mol. wt. ofK.MnO 4 = 158)
(c) HO 2SOSO2H (d) HO 3SOSO 3H 80. The chemical nature of hydrogen peroxide is
74. The correct statement about Hp 2 are: [10 Jan, 2019 (Shift-DI
(A) Used in the treatment of effluents. (a) Oxidising agent in acidic medium, but not in basic
(B) Used as both oxidizing and reducing agents medium
(C) The two hydroxyl groups lie in the same plane. (b) Reducing agent in basic mediutn, but not in acidic
medium
(D) Miscible with water.
(c) Oxidising and reducing agent in acidic medium, but
not in basic medium
116 March, 2021 (Shift-II)]
(cl) Oxidising and reducing agent in both acidic medium,
(a) (B), (C) and (D) only (b) (A), (C) and (D) only
and basic medium
(c) (A), (B) and (D) only (d) (A), (B), (C) and (D)
81. The percentage strength of 11 .2 volumes solution ofH,O, is:
75. The strengths of 5.6 volume hydrogen peroxide [Given that molar mass ofH = 1g mo1-1 and O= 16 g-mol-']
(of density I g/mL) in -terms of mass percentage and
molarity (M), respecti vely, are: 18 April, 2019 (Shift-II)!
(a) 13.6% (b) 3.4%
13 Sept, 2020 (Shift-II)]
(Take molar mass of hydrogen peroxide as 34 g/mol) (c) 34% (cl) 1.7%
(a) 0.85 and 0.25 (b) 0.85 and 0.5 82. The volume strength of I M Hp is (Molar mass of HP 2
2
· (c) 1.7 and 0.5 (d) 1.7 and 0.25 = 34 g mol-1) jl2 Jan, 2019 (Shift-II)!
76. Hydrogen peroxide, in the pure state, is: _ (a) 5.6 (b) 16.8
15 Sept, 2020 (Shift-II)] (c) 11 .35 (d) 22.4
~ JEE PYQs Chemistry

\ \
\ ANSWER KEY s •
t. (d) 2. (c) 3. (d) 4. (b) 5. (a) 6. (d) 7. (/J) 8. (a) 9. (h) 10. (h)
1\. (d) 12. (c) 13. (b) 14. (h) 15. (a) 16. (c) 17. (cl) 18. (h) 19. (a) 20. (c)
21. (d) 22. (b) 23 . (cf) 24. (d) 25. (b) 26. (a) 27. (a) 28. (c) 29. (a) 30. (c)
31. (a) 32. (d) 33. (c) 34. (d) 35. (a) 36. (a) 37. (b) 38. (c) 39. (a) 40. (h)
4\. (a) 42. (b) 43 . (b) 44. (d) 45. (d) 46. (a) 47. (b) 48. (b) 49. (a) 50. (h )
5\. (c) 52. (b) 53. (a) 54. (c) 55. (c) 56. (c) 57. (b) 58. (a) 59. (a) 60. (b)
61. [ISO] 62. (a) 63. (c) 64. (a) 65. (cf) 66. (c) 67. (d) 68. (c) 69. (d) 70. (b)
71. (a) 72. (c) 73. (b) 74. (c) 75. (c) 76. (a) 77. (a) 78. [ I00) 79. (85) 80. (cl)
St. (b) 82. (c)
• s\ EXPLANATIONS \
•
l
1. (d) Cobalt catalyst ➔ Methanol producti on as ionic hydrides or pseudohalides. .
Syn gas ➔ Coal gasifica tion Bl H6 ⇒ e- defi cient hydride
(C(Re<lhotcokc) + Hp(g) ➔ CO + ti) HF ⇒ e- rich hydride
Nickel catalyst ➔ Water gas producti on CH4 ⇒ e- Precise hydride
Brine solution is a mixture of sodium chloride and water MgH2 ⇒ Saline hydride
H2 ➔ Cathode
9. (b) When di hydroge n reacts with CuO, then Cu is fanned
C\1 ➔ Anode
CuO + H ,➔ Cu + Hp
2. (c) NaN i5, Mg-MgH2 are compounds that can enhance
the efficiency of hydroge n storage tanks. 10. (b) During Haber's process, production of ammo nia
3. (d) CO + 2H2 Catalyst CH3OH takes place. It has been observed that around 55%
of hydrogen has been consumed during this process .
Water gas on reaction with catalyst to form Methanol.
4. (b) Due to difference in the atomic weight of isotopes of 11. (cf) Isotopes are the atoms of same element with different
hydroge n they differ in their rate of reaction. Again atomic mass. Hence, three isotopes of hydroge n differ
due to this difference in mass, they have different bond in their atomic mass.
dissociation enthalpy. The stronger bond in deuterium 12. (c) Hi gh purity (> 99.95%) dihydrogen gas can be
compared to protium leads to higher bond dissociation obtained by electrol ysis of warm aqueous Ba(O H),
enthalpy. This in turns influence rate of reaction. solution using Ni electrode. -
5. (a) In the given reaction, T = 1270 K T2 = 673 K
1
13. (b) Tritium is an radioactive isotope of hydroge n which
Hence,T > T 1.
1
decays into He4 during emission of ~- radiatio n
6. (d) Physical properties of isotopes differ considerably due
to large mass differences between isotopes of hydroge n. I
T3 ~ l
He4 + - 1e0
7. (b) Due to low density of hydroge n, it create no pollution 11
on combustion. p ratio of tri tium is high, So it emit ~-particle.
8. (~) Electro n defic ient hydri des are th ose hav in g
incompl ete octet and When there are more electrons 14. (b) Triti um is the onl y isotope of hydroge n whic h
present than are needed to form an octet, the hydride is radioactive in natu re and emits low energy ~-
• .I
is referred to as a "electron rich hydride." part1c es because its
. 11
- ratio lies above stabi li ty belt.
Electron precise hydrides are those that have precisely p
the right number of electrons for forming a covalent bond.
15. (a) Syn-gas is also called water gas which is a mi xture
Saline hydrides are compounds formed when hydroge n
of' (CO + H2) . It is produced as:
is combined with the most acti ve metals, also known
C + H 20 ~ co + 1-1 2 H
(Red hot) (steam) (I : I mixture)
I
16. (c) In universe, Hydrogen is th e most abundant element C
and the lightest e lement. In troposphere, the mosl
abundant gas in Nitrogen .
H/l""H
H
it is e lectro precise hydrict
e.
17. (d) The bond dissociation energy ofD- D is greater than (i v) HF & C H4 are mol ec ular hydride due to the
1-1- H. hence D 2 reacts slower than Hr are covalent molecul es . Y
18. (b) Metals belong to group 7, 8, & 9 dose not form 29. (a) S iH has a complete octet hen ce, it is not ele t
4 c~
interstitial hydride, this is known as hydride gap. deficient.
Mn ➔ group- 7 30. (c) NaH is an example of ionic hydride which is 1
known as saline hy d n'de. a so
Fe ➔ group :-- 8
Co ➔ group-9 31. (a) Zn+ 2HCI ➔ ZnCl 2 + H 2
So, Cr will fonn interstitial hydride easily. Zn + 2NaOH ➔ Na 2Z nO 2 + H 2
19. (a) Tritium is the radioactive isotope of hydrogen. Its 32. (d) (A) H 2 produces less pollution because it doesn'
1
representation is ~H . produce carbon monoxide.
Number of neutron = 3 - I = 2 (B) Because it has high calorific value.
Number of electron = I (C) Dihydrogen is stored in tanks of metal alloys.
(D) LPG produces less energy than liquid dihydrogen.
20. (c) With respect to industrial consumption of H 2 ,
manufacturing· of NH 3 is one of the largest 33. (c) The isotopes are:
applications. : H , ~Hand :H = P,_D, T
21. (d) At around 2000K, the dissociation ofH2 into its ~toms 34. (d) Today, synthetic ion exchangers are used to soften
is nearly 0.081%. hard water. This approach is more effective than the
zeolite or Permutite processes.
Hence, (D) is the incorrect statement.
35. (a) ~Spg(s) + 2D 2 O(1) ➔ 2KDSO/aq.) + op2
22. (b) Water forms carbonic acid with CO 2 gas.
36. (a) In water gas shift reaction , carbon monoxide is
H 2O + CO 2 ➔ H 2CO 3 oxidised to carbon dioxide.
23. (d) The bond dissociation energy ofD-D is greater than CO(g)+ H2 + H 2 O
Iron Chromate
Catalyst
H-H, hence D 2 reacts slower than H 2 . water gas S team
24. (d) Dihydrogen with high degree of purity (>99.95%) 37. (b) Ice > Liquid water > Impure water
can be obtained by the electrolysis of warm Ba(OH\ As the impurity decreases H-Bonding decreases.
solution by using Ni electrodes. 38. (c) Ca(HCO) 2 + 2Ca(OH) 2 ~ 2CaCO 3 + 2Hp
25. (b) Number of neutrons in protium (a), deuterium (b) Mg(HCO 3 \ + 2Ca(OH) 2 ~ 2CaCO 3 + Mg(OH)i
and tritium (c) are 0, 1 and 2 respectively. +2Hp
Therefore, x + y + z = 0 + I + 2 = 3 39. (a) Mg(HCOJ 2
_ B_oi_l~ Mg(OH) 2 + 2CO 2 t
26. (a) 3 and 1 Ca(HCO 3 ) 2 Boil CaCO 3 + H 2 O + CO 2 t
27. (a) Reaction given in option (a) requires a catalyst.
40. (b) ln clark's method Ca(OH), is used for softening hard
28. (c) water. -
el 0
(i) M H+ HOH----'- MOH+ H 2 Ca(HCO 3 ) 2 + Ca(OH) 2 ~ 2CaCO 3 + 2Hp
Ionic hydride/saline hydride Mg(H CO) 2 + 2Ca(OH\ ~ 2CaCO 3 + Mg(OHl2
(ii) 4BF 3 + 3LiAIH 4 ➔ 28 2 H6 + 3LiF + 3AIF 3 + 2Hp
Q
p
41. (a) - NH, is anion exchanger and -SO H is cation exchanger.
-
42. (b) De ioni ~e d water is obtained by passing wate~

3
successively through a cation exchange and an an!O

(iii) H/ HI ""H - phosphorous is electron rich exc hange.
- of
43. (b) The temporary hardness is removed by bot-1ing
hydride due to presence of lone pair
water and the reaction occurs as:
= 0. lg of CaCO1
Mg(HCO3) 2 ~ Mg(OH)2 t +2co 2
Hardness of water (i n terms of CaCO1)
(white ppl)
The compound MgCO 3 is more solu ble th an = WcnCOi x I06ppm
Mg(OH \, that is why ppt of Mg(OH)2 is fonned. WH 20
Also. K"' of Mg(OH)2 is higher than MgCO 1.

nd = ~ x 106 = 100 ppm
44 . (d} Calgon does not contain the 2 most abw1dant element 1000
by weight in earth crust because that is Silicon.
Water solu ble 54. (c) Temporary hardness is due to solub le ~ g(HC0 ) 2
CaIgon ➔ Na2[N a4(po 3)6l .
and bicarbonates of ca lcium and magnesium .
2Na [Nai PO 3\ ] 2-~ 2Na' [Na 2Ca(PO3\]2- 55. (c) Temporary hardness is due to solu ble Mg(H COJ 2
45. (d} Dielectric constant of op and H2O are respectively and Ca(HCO) 2.
78.06 and 78.39 C2/N. m2 Mg(HCO3) 2 ~ Mg(O f-1)2t + 2CO2 t
46. (a) To study reaction mechani sm, heavy water (Dp) Ca(HCO3) 2 ~ CaCO 3 t + Hp + CO 2 t
is used . Si nce O-H bond energy is less than O-D, -I
therefore, it wil I give fast reaction than O-D. 56. (c) +I -I G> B o
HOC!+ 1-1,0, - H,O + Cl + 0,
(O.A) (R.A
47. (b) Heavy water (DP) is used in organic reaction to
Oxidation
know about the kinetics of reaction. Reduction
Heavy water o p is obtained by carried out repeated Hence H O acts as a reducing agent in this reaction.
electrolysis of Hp . ' 2 2
57. (b) Hp 2 decomposes slowl y on ex posure to light.
Heavy water has b.pt IO I .4°C while ordinary water 2H O (/) ➔ 2H 20(/) + O/ g). In the presence of
has b.pt I 00°C me:al ~urface, or traces of alkali, reaction is catalysd,
op has more molecular mass as compared Hp, Therefore, it is stored in glass / plastic vessel in dark.
hence greater degree of association and as a result Here, urea can be added as a stabilizer.
bas greater b.pt and viscosity. 58. (a) Since, Hp 2is getting oxidised to 0 2, therefore, it act
48. (b) In synthetic resin method, only cations are exchanged, as reducing agent in this reaction.
therefore, it is more efficient. Reduction
-I 0
49. (a) ln water gas shift reaction, carbon monoxide gets NaOCI + H 0--+ 2NaCI +Hp + 0 7
oxidized to carbon dioxide by reacting it with steam +] 2t2 (
in the presence of catalyst. oxidation
50. (b) Boiling and clark 's method (Ca(OH\ ) are used to 59. (a) Hp 2is used to synthesize tartaric acid, hydroquinone,
remove temporary hardness. cephalosporin. It is also used in environmental treatment
of domestic and to restore aerobic conditions to sewage
Wh ile, calgo n, sodium carbonate, ion exchange wastes.
methods are used to remove permanent hardness. 60. (b) Volume = 11 .35 x M
51. (c) The synonym for water gas is syn gas. Strength
52. (b) neq ·CaCO3 = Neq Ca(HCO3 )i +neq Mg(HCO3 )z M=~M
11.35
W 0.81 0.73
Or - x 2 = - x2 + - x2 g/L = 25 x 34/ 11 .35 = 74.889
' 100 162 146 50
: . w = 1.0 61. [150] Molari ty= - -
11.35
Hardness = ~ x I0 = I0, 000ppm : . Strength in gm/ L = ~ x 34 = 150 g/L
6
100 11 .35
53. (a ) Mass ofCaSO 4 = 10-3 x 136 62. (a) Among the given compunds, urea acts as negative
= 0.136g catalyst fo r decomposition of Hp 2.
136g ofCaSO 4 ➔ 100g ofCaCO 3 63. (c) In reducing ac ti on, H2O2 always changes to O,
because it will undergo ox idation but in option (a):
100
0 . 136gof CaSO 4 ➔ - x0.136 the reaction is in acidic medium therefo re answer
136 will be (c). ' '
64 . la) RcaL11011 ol 11.0 \\Ith KMnO, gl\ C\ Mn ' 111 ac1d11.:
75. (1) ·1he rclatron between molarity and volume \lrc:nvtf, I\
medium
2MnO 4 · 611 5110 -+2 Mn 1 · • 8 11 O ➔ 5O l·or II ,CJ2:
: "' 1 2
65. Id) Reaction bct\,een hydrogen peroxide and acidified Volume strength
5.6
Molarity = =- 0.5~
K\.1110, I\ gl\en a~ II .2 11 .2
2MnO .. 611 ' .. 511 O --, 2Mn2' + 811 O ➔ 50 Now, in terms of mass percentage:
' l l l l
66. (c) H:O1 can act as oxidizing agent in both acidic as well . %( w I w) / I OY d
as basic medium. Molarity = GMM
Dens11y of D2O = 1.1 gm/cc
%(w / w)/ l0Yd
Density of H2O2 = I.45 gm/cc 0.5 = 34
67. (d) In gas phase. dihedral angle is 111 .5° while in solid
base, i1 is 90.2°. 0.5x34
¾(w / w) = - - = 1.7
Change in angle is due 10 the change of intermolecular 10
interaction in different phases. ~---- - -,
76. (a)
68. (c) Hp 2 can behave as both reducing oxidising agent in
basic medium. so ii can reduce 12'io I and can oxidize
:
i
l,
H
Mn 2• to Mn•·. j •• / ~
'.---} }--9.-:------0 90.f angJ,
69. (d) in both the given reactions, Hp acts as reducing agent.
2 H
In reaction (A), HOCI ~ Oxidizing agent
Hp 2 ~ Reducing agent Hydrogen peroxide is colorless in free state and has
In reaction (B), 12 ~ Oxidizing agent open book type structure.
Hp 2~ Reducing agent 77. (a) All the given statements are correct.
70. (b) In a basic medium, hydrogen peroxide reduces iodine 78. [ I00] The relation between molarity and volume strength is:
to iodide ion.
Volume strength)
Hp l + 2OH + 12➔ 0 2+ 21- + 2Hp Molarity of Hp 1 solution = ( _
11 2
71. (a) I + Hp 2+ 2W ~ 12 + 2Hp
Volume strength = 8.9 x 11 .2 = 99.68 V
(- 1) oxidation (0)
79. [85] Eq. of Hp =, Eq. of KMnO4
Here, 1- is getting oxidized from - I to 0, hence, acts 1
as a reducing agent. · 0.316

:. H2O2acts as an oxidizing agent. xx2=--x 5
158
72. (c) Hp 2 in both acidic & basic medium act as both
x = 5 x I0-3 mo!
oxidizing & reducing agent.
Energy is transmitted and stored in form ofdihydrogen Mass of H2O2 = 5 x I0-3 x 34
(H2) in hydrogen economy. = 0.17 g
73. (b) Main product of electrolysis of cone. H SO is H Sp 0.17
2 4 2 8 ¾H:0 = - x l00% = 85%
i.e. HO3SO-OSO3H l 2 0.2
74. (c) In Hp 2, it looks like open book structure and contains 80. (d) Hp 1 act as oxidising and reducing agent in both
two -OH groups in different plane as shown below: acidic and basic media.
81. (b) Volume strength = 11 .2 x molarity = 11 .2
H:
,: ⇒ molarity = I M
0 ⇒ strength = 34 g/L
I
9, ⇒
34
%ww = --x l00 = 3.4%
l H 1000
82. (c) Volume strength = 11 .35 x M = 11 .35 (STP)
~ JEE PYQs Chemistry - - - -- - - - - - - - - - - - - - - -- - - - - - -

The s-Block Elements
In th e li ght of th e above statements, choose the mo'it

Group 1: Alkali Metals & Their J appropriate answer form the options given below
(a) Both (A) and (R) are correct but (R) is :--,;oT the
Properties
correct ex planation of (A).
(b) (A) is correct but (R) is not correct.
t. Which of the fo llowing reaction is correct? (c) (A) is not correct but (R) is correct
130 Jan, 2023 (Shift-11)1
(d) Both (A) and (R) are correct and (R) is the correct
(a) 2LiN0 3 ~ 2LiN0 2 + 0 2 ex planati on of (A).
(b) 4LiN0 3 ~ 2Li20 +2N20 4 + 0 2 4. The correct order of hydration enthalpies is

129 Jan , 2023 (Shift-I)!
(c) 4LiN0 3 ~ 2Li 20 + 4N0 2 + 0 2 (A) K+ (B) Rb+
(d) 2LiN0 3 ~ 2Li + 2N0 2 + 0 2 (C) Mg2+ (D) cs-
(E) Ca 2+
2. Match List-I with List-II 125 Jan , 2023 (Shift-I)J Choose the correct answer from the options gi ven below:
List-I List-II (a) (C) > {A) > (E) > (B) > (D)
Elements Colour imparted to flame (b) (E) > (C) > (A) > (B) > (D)
(A) K (I) Brick Red (c) (C) > (E) > (A) > (D) > (B)
(B) Ca (II) Violet (d) (C) > (E) > (A) > (B) > (D)
(C) Sr (111) Apple Green 5. The densi ty of alkali metals is in the order
(D) Ba (I V) Crimson Red 112 April, 2023 (Shift-1)1
(a) Na < K < Cs < Rb (b) K < Na < Rb < Cs
Choose the correct answer fro m the options given below:
(c) K < Cs < Na < Rb (d) Na < Rb < K < Cs
(a) (A)-(11), (B)-(1), (C)-(111), (D)-(IV)
6. Th e mag net ic behav iour of Li 2.0 , Na 20 2 and KO ~,
(b) (A)-(11), (B)-(I V), (C)-(1 ), (D)-(111)
respect ive ly, are 129 Jan , 2023 (S hift-I)!
(c) (A)-(11), (B)-(1), (C)-(I V), (D)-(111 )
(a) Diamagneti c, para magneti c and diamagnetic
(d) (A)-(I V), (B)-(111 ), (C)-(1 1), (D)-(1)
(b) Paramagneti c, paramagnetic and diamagnetic
3. Gi ven below are two· statements, one is labelled as (c) Para magneti c, di amagneti c and paramagneti c
(d) Di amagneti c, di amagnetic and paramagnetic
125 Jan , 2023 (Shift-11)1
Assertion (A): The alkali metals and thei r salts impart 7. Which one among the fo llow ing metals is the weakest
characteri stic colour to reducing fl ame. red ucing agent? 125 Jan , 2023 (S hift-11)1
Reason (R): Alkali metals can be detected using fl ame (a) K (b) Rb
tests. (c) Na (c0 Li
8. Given below are two statements : One is labelled as (c) NaCl < NaF < NaBr < Nal
(d) Nal < NaBr < NaF < NaC l
18 April, 2023 (Shift-11)1
13. Identify the correct statements about alkali metals.
Assertion (A): Sodium is about 30 times as abundant as
potassium in the oceans. 12~ Jan, 2023 (Shift-I~!
(A) The order of st~ndar~ reduction po~ential (M• IM
Reason (R): Potassium is bigger in size than sodium.
for alkali metal tons 1s Na > Rb > L1. l
In the light of above statements , choose the correct answer .
(B) Csl is highly soluble in water.
from the options given below.
(C) Lithium carbonate is highly stable to heat.
(a) Both -(A) and (R) are true and (R) is the correct
explanation of (A). .
(D) Potassium dissolved in concentrated liquid ammon1a
is blue in colour and paramagnetic.
(b) (A) is true but (R) is false.
(E) All the alkali metal hydrides are ionic solids.
(c) (A) is false but (R) is true.
Choose the correct answer from the options given below
(d) Both (A) and (R) are true but (R) is NOT the correct
explanation of (A). (a) (A), (B) and (D) only (b) (C) and (E) only
9. Given below are two statements : one is labelled as (c) (A) and (E) only (d) (A), (B) and (E) only
Assertion (A) and the other is labelled as Reason (R) . 14. Which one of the following elements will remain as liquid
11 Feb, 2023 (Shift-11)1 inside pure boiling water? (6 April, 2023 (Shift-lJ)J
Assertion (A): An aqueous solution of KOH when for (a) Cs (b) Ga
volumetric analysis, its concentration should be checked (d) Br
(c) Li
before the use.
15. Match List - 1with List - II 130 Jan, 2023 (Shift-DJ
Reason (R): On aging, KOH solution absorbs atmospheric
List-I List-II
CO2'
(Atomic number) (Block of periodic table)
In the Light of the above statements, choose the correct
answer from the options given below. (A) 37 (I) p-block
(a) (A) is not correct but (R) is correct (B) 78 (II) d-block
(b) Both (A) and (R) are correct but (R) is not the correct (C) 52 (lll) f-block
explanation of (A) (D) 65 (IV) s-block
(c) Both (A) and (R) are correct and (R) is the correct Choose the correct answer from the options given below:
explanation of (A)
(a) (A)-(11), (B)-(IV), (C)-(1), (D)-(lll)
(d) (A) is correct but (R) is not correct
(b) (A)-(1), (B)-(III), (C)-(fV), (D)-(11)
10. The product, which is not obtained during the electrolysis (c) (A)-(IV), (BHIII), (C)-(11), (D)-(1)
of brine solution is · 16 April, 2023 (Shift-In)
(d) (A)-(IV), (B)-(11), (C)-(I), (O)-(III)
(a) NaOH (b) Cl2
16. On heating, LiNO 3 gives how many compounds among
(c) H2 (d) HCI
the following? 129 Jan, 2023 (Shift-IOI
11. Alkali metal from the following with least melting point
Lip, Nl, 0 2, LiNOl, NOl
1s: 111 April, 2023 (Shift-11)1
17. The number of alkali metal(s), from Li, K, Cs, Rb having
(a) Rb (b) K
ionization enthalpy greater than 400 kJ mot· 1and forming
(c) Na (d) Cs stable super oxide is _ _ 131 Jan, 2023 (Shift-II)!
12. Identify the correct order of standard enthalpy of formation 18. Lithium nitrate an.d sodium nitrate, when heated separaJelY,
of sodium halides. 113 April, 2023 (Shift-11)1 respectively, g_ive: 129 Jan, 2022 (Shift-I)!
(a) Na! < NaBr < NaCl < NaF (a) LiNO2 and NaNO 2 (b) LiiO and Na2O
(b) NaF < NaCl < NaBr < Na! (c) Li 2O and NaNO2 (d) LiNO 2 and Na2Q
11). Whic h ol' lh c l\1llnwi111~s1111c111c111 is incorn.: cl'! AHHerllon (A): 1.iF is sparingly solubl e in w<1ter.
12H,lul y, 2022 (Shll'l -1)1 HenHon (R): The ionic radius of l. i' ion is small est among
(11) l.l,wsnl11hili1 y lll' LiF ill w111cr is d11 c 10 ilHsmnll its group memners, hence has least hydration enthalpy.
hydrnlinn elllhnlpy,
In the light of the abov e swtcm ents, choose the most
(h ) KO, is pnrn ll111g11c1ic .
npproprlul.e answor from the options given below.
(t) Sol111 i1111 orsodium ill liquid 11 mmoni11is rn11d11e1i11g (o) Both (A) and (R) arc tru e and (R ) is th e co rrec t
ill IHllll l'e.
cx1'>lanation of' (A).
(d) Sodiu m mcin l hns hi gher clell sily 1h:111 potnss ium (/J) Both (A) ~nd (R) arc true but (R) is NOT the correct
mc111I.
ex pl anati on of (A).
20. Which of 1he fo ll ow in g slntcments arc correcl'? (c) (A ) is true but (R) is fal se.
124 ,June, 2022 (Shlfl-1)1 (d) (A) is fa lse but (R) is true.
(A) 130111 LiCI n11d MgC l2 urc soluble in ethanol 24. As-block element (M) reacts wi th oxygen to form an oxide
(B) The oxides Lip and MgO combine wi lh excess of of the formula M0 2• The ox ide is pale yell ow in colour
oxygen 10 give superox ide. and paramagneti c. The element (M) is:
(C) LiF is less soluble in water 1han other alkali metal 120 July, 2021 (Shift-1)1
lluorides.
(a) Na (b) K
(D) Lip is more soluble in water than other alkali metal
(c) Mg (d) Ca
oxides
25. Match List-I with List-II. 125 July, 2021 (Shift-II)!
Choose lhe most appropriate an swer from th e options
given below : List-I (Elements) List-II (Properties)
(a) (/\) and (C) only (A) Li (I) Poor water solubility of
(b) (A), (C) and (D) on ly
(c) (B) and (C) only
1- salt
(d) (A) and (D) on ly
21. . Maleh Lisi-I with List-II. (8) Na (II) Most abundant element
129 June, 2022 (Shift-J)I
in cell fluid
List-I List-I I
(C) K (111) Bicarbonate salt used in
(Met:11) (Emitted light
fire extinguisher
wavelength (nm))
(D) Cs (IV) Carbonate salt
(A) Li (1) 670.8
decomposes easily on
(B) Na (11) 589.2 heating
(C) Rb (111 ) 780.0 Choose the correct answer from the options given below:
(D) Cs (IV) 455.5 (a) (A)-(IV), (B)-(11), (C)-(11 1), (D)-( 1)
Choose the most appropriate answer from the options (b) (A)-(1), (B)-( 11), (C)-(111 ), (0 )-(IV )
given below :
(c) (A)-(1), (B)-(111), (C)-(11 ), (D)-(IV)
(a) (A)-(1), (8)-(11), (C)-(11 1), (D)-(IV)
(d) (A)-(IV), (8)-(111 ), (C)-(1 I), (D)-(1)
(b) (A)-(111), (8)-(11), (C)-(1), (0)-(IV)
26. Choose the correct statement from the following :
(c) (A)-( 111 ), (8)-( 1), (C)-( 11), (D)-( IV)
(d) (A)-( IV), (B)-(11 ), (C)-(1), (D)-( 111 ) 127 Aug, 2021 (Shift-ll)J
(a) The standard enthalpy of formation for alkali metal
22. Choose the co rrec t order of' densi1y of th e alkali metals:
bromides becomes less negative on descending the
125 July, 2022 (Shift- 1)1 gro up.
(a) Li < K < Na < Rb < Cs (b) Li < Na < K < Rb < Cs (b) LiF has least negati ve standard enthalpy of formation
(c) Cs < Rb < K < Na < Li (d) Li < Na < K < Cs < Rb among alkali metal flu or ides.
23. Given below are two statement s: one is labell ed as (c) The low solubility of' Csl in water is due to its high
Assertion (A) and the other is labeled as Reason (R) . la11i ce cnlhalpy.
126 July, 2022 (Shit't-11)1 (d) Among the alkali me1al halides, LiF is least soluble
in water.
The s-Block Element: r

27 · Match List-I with List-II : 127 July, 2021 (Shift-11)1 31. Give n below are two statements : one is label! d
List - I Assertion (A) and the other is labelled as Reason (~)as
List - 11
(A) Li [31 Aug, 202 I (Shift-II)
(I) photoelectric cell
(B) Na Assertion (A): Lithium salts are hydrated. I
(II) absorbent of CO 2
(C) K Reason (R): Lithium has higher polarising power th
(Ill) coolant in fast breeder
other alkali metal group members. an
nuclear reactor
(D) Cs In the light of the above statements, choose the rn
(IV) treatment of cancer . r: h . . Ost
appropriate answer ,ram t e options given below :
(V) bearings formotorengines
(a) Both (A) and (R) are correct and (R) is the corr
Choose the con-eel answer from the options given below :
explanation of (A). eci
(a) (A)-(V), (B)-(11), (C)-(lV), (D)-(1)
(b) (A) is correct but (R) is not correct .
(b) (A)-(IV), (B)-(lll), (C)-(1), (D)-(11)
(c) (A) is not correct but (R) is correct.
(c) (A)-(V), (B)-(1), (C)-(11), (D)-(IV)
(d) Both (A) and (R) are correct but (R) is NOT th
(d) (A)-(V), (B)-(111), (C)-(11), (D)-(1) correct explanation of (A). e
28. !he con-ect set from the following in which both pairs ar~
m correct order of melting point 'is : 32. Among the following, number of metal/s which can be
used as electrodes in the photoelectric cell is .. ... (Integer
124 Feb, 2021 (Shift-II)] answer) 125 Feb, 2021 (Shift-IJ)J
(a) LiF > LiCl ; MgO > NaCl
(a) Li (b) Na
(b) LiCI > LiF; NaCl > MgO
(c) Rb (d) Cs
(c) LiF > LiCl; NaCl > MgO
(d) LiCl > LiF; MgO > NaCl 33. The correct order of conductivity of ions in water is:
29. Given below are two statements: One is labelled as [17 March, 2021 (Shift-DJ
Assertion (A) and the other is labelled as Reason (R). (a) Rb+> Na+> Kt> Li+ (b) cs+> Rb+> KT> Na-
127 July, 2021 (Shift-I)) (c) K+> Na+> CsT> Rb+ (d) Na+> K+> Rb+> cs-
Assertion (A): Lithium halides are some what covalent 34. Among the statements (A) - (D), the correct ones are:
is nature.
19 Jan, 2020 (Shlft-D)J
Reason (R): Lithium possess high polarisation capability.
(A) Lithium has the highest hydration enthalpy among
the alkali metals.
(a) (A).is true but (R) is false (8) Lithium chloride is insoluble in pyridine.
(b) Both (A) and (R) are true but (R) is NOT the correct (C) Lithium cannot form ethynide upon its reaction with
ethyne
. explanation of (A)
(c) (A) is false but (R) is true (D) Both lithium and magnesium react slowly with foO
(d) Both (A) and (R) are true and (R) is the correct (a) (A), (B) and (D) only (b) (A) and (D) only
explanation of (A) (c) (~) and (C) only (d) (A), (C) and (D) only
30. Match List-I with List-II. [24 Feb, 2021 (Shift-U)) 35. Two elements A and B have similar chemical properties.
List-I List-II T_hey don't form solid hydrogencarbonates, but react with
(Salt) (Flame colour mtrogen to fom1 nitrides. A and B, respectively, are:
wavelength)
12 Sept, 2020 (Shift-11)1
(A) LiCI (I) "455.5 nm
(a) Na and Ca (b) Na and Rb
(B) NaCl (11) 670.8 nm
(c) Cs and Ba (d) Li and Mg
(C) RbCl (Ill) 780.0 nm
(fV) 589.2 nm 36. The difference between radii of3nl and 4'h orbits of Li> is
(D) CsCI
~R 1• The difference between the radii of3nl and 4'h orbits
of He+is ~R,- Ratio ~R 1 : ~R, is:
(a) (A)-(11), (8)-(IV), C-(111), D-(1)
(b) (A)-(11), (B)-(1), C-(IV), D-(111) 15 Sept, 2020 (Shift-I)!
(c) (A)-(1), (8)-(IV), C-(11), D-(lll) (a) 8 : 3 (b) 2 : 3
(d) (A)-(IV), (8)-(11), C-(lll), D-(1) (c) 3 : 8 (d) 3 : 2
37, On combustion of Li. Nn and Kin e:-..cess nl'nir, the mnjllr
oxides lo1111cd. respectively. nre: ·
14 Sept, 2020 (Shlfl-1)1
Some Important Compounds of
Na and Biological Importa nce of
j
(a) Li 20. Nap) and Kp (b) LiiO. Nn/\ nnd K0
(c) Li 10. Nnp and Kp 2 (c/) Lip, Nap and Kl)
2 Na and K
2 2
38. The metal mainly used in devising photoelectric cel ls is: 46. Number or wu ter molecules in washing soda and soda ash
respecti vely nrc: 11 0 April, 2023 (Shift-11 )1
12 Sc1>t, 2020 (Shifl-1)1
(a) 10 und I (h) I and 10
(a) Rb (b) Cs
(c) I and0 (d) I0 and0
(c) Li (d) Na
47. Compound/\ reacts with NH,p and forms a com~ound
39. Which of the following will liberate 0 , upon hydrolysis?
B. Compound B rcucts with I1p and excess of CO2_ to
IJ EE Adv 20201 form compound C which on passing through or reaction
(a) Pbp4 with saturated NaC l soluti on form s sodium hydrogen
(c) Nap2 carbonate. Compou nd A. 8 and C, are respectively.
40. Magnesium powder bums in air to give: 125 Jan, 2023 (Shift-1)1
19 April, 20 19 (Shift-1)1 (a) CaCl , NH 3, NH 4HCO 3

2
(a) MgO only (b) MgO and Mg(NO ) (b) CaCl 2, NH;, (N H4) 2CO3
3 2
(c) MgO and Mg 3N2 (d) Mg(NO) and Mg N (c) Ca(OH) 2, Nf-1 3, NH 4 HCO3
2 3 2
41. The INCORRECT statement is: (d) Ca(Ol-1)2, NH 4' , (NH4) 2CO3
I12 April, 2019 (Shift-II) I 48. Match List-I with List-II: II I April, 2023 (Shift-I)!
(a) Lithium is least reactive with water among the alkali List-I List-II
metals. · (A) K (I) Thermonuclear reactions
(b) LiCI crystallises from ~queous solution as LiC1.2Hp . (B) KCI (11 ) Fertilizer
(c) Lithium is the strongest reducing agent among the (C) KOH (II f) Sodium potassium pump
alkali metals.
(D) Li (IV) Absorbent of CO 2
(d) LiNO3 decomposes on heating to give LiNO and 0 •
2 2 Choose the correct answer from the options given below:
42. A metal on combustion in excess air forms X, X upon
(a) (A)-(111), (B)-(1 1), (C)-(IV), (D)-(1)
hydrolysis with water yields Hp 2 and 0 along with
2 (b) (A)-( IV), (B)-(1), (C)-(111), (D)-(11)
another product. The metal is: 112 Jan, 2019 (Shift-1)1
(c) (A)-(IV), (B)-(111 ), (C)-(1), (0 )-(11)
(a) Na (b) Rb
(d) (A)-(11 1), (B)-(IV), (C)-(1 1), (D)-(1)
(c) Mg (d) Li
43. The metal that fom1s nitride by reacting directly with N of air 49. In the industrial production of which of the fo llowing,
2
1s 19 Jan, 2019 (Shift-11)1 molecular hydrogen is obtained as a by product?
(a) K (b) Li 124 June, 2022 (Shift-II)!
(c) Rb (d) Cs (a) NaOH (b) NaC l
44. Sodium metal on dissolution in liquid ammonia gives a (c) Na metal
deep blue solution due to the formation of: . SO. Which one of the fo ll owi ng compounds is used as a
11 OJan, 2019 (Shift-11)1 chemical in certain type of fire extinguishers?
(a) Sodium - ammonia complex
124 June, 2022 (Shift-11)1
(b) Sodamide (a) Baking soda (b) Soda ash
(c) Sodium ion-ammonia complex
(c) Washing soda (cf) Caustic Soda
(d) Ammoniated electrons
SI. Amongst baking soda, caustic soda and washing soda,
45. The correct order of hydration enthalpies of alkali metal ions carbonate anion is present 129 June, 2022 (Shift-II)!
1s: 18 April, 20 19 (Shift-1)1
(a) Washing soda only
(a) Li'> Na' > K' > Rb '> Cs•
(b) Li• > Na'> K• > Cs•> Rb• (b) Washing soda and caustic soda only
(c) Na•> Li' > K' > Rb•> Cs' (c) Washing soda and baking soda only
(d) Na• > Li•> K• > Cs'> Rb ' (d) Baking soda, caustic soda and washing soda
- - - - - - - - - - - - - - - - -- - - - - - - - - -- - - - The s-Block Elements

52. Which amongst the fo llow ing is not a pesticide?
128 June, 2022 (Shifl-1)1 Group 2: Alkaline Earth Metals &l
(a) DDT (h) Organophosphates Their Properties
(c) Dield rin (d) Sodium arsenite
53. Fi nd A. B and C in the fo llow ing reacti on:
58. Ion h,aving hi ghest hydration enthalpy among the giv
126 Feb, 202 I (Shift-1) 1 alkaline earth metal ions is: 16 April, 2023 (Shift-I~
NH,+ A + COl ➔ (N H4)S 0 .1 (a) Be2+ (b) Bal•
(N HJ C0 3 + H20 + B ➔N H 4 H C0 1 (c) Sr2t (d) Ca2t
NH4HC0 3 + NaCl + NH p + C 59. Structure .of BeCl2 in soli? state, vapour phase and at very
(a) A- Hp ; B - 0 2; C - NaHC0 3 high temperature respectively are :
(b) A- Hp ; B - CO2; C - NaHC0 1 16April, 2023 (Shift-fijJ
(c) A- Hp ; B - Ol; C - Nalcol (a) Dimeric, Polymeric, Monomeric
(d) A- Ol; B - col; C - Naf OJ (b) Polymeric, Dimeric, Monomeric
54. One of the by-products fonned during the recovery ofNH 1 (c) Monomeric, Dimeric, Polymeric
from solvay process is: 117 March, 2021 (Shift-Il)J. (d) Polymeric, Monomeric, Dimeri c
(a) NaHC0 3 60. Better method for preparation of BeFl' among the
(c) Ca(OH )l following is f13 April, 2023 (Shift-D)J
55. If you spill a chemical toi let cleaning liquid on your hand, (a) (NH 4 ) 2 BeF4 ~ BeF2
your first aid would be: 12 Sept, 2020 (Shift-II)! Ii
(b) BeH2 + F2 ~ BeF2
(a) aqueous NH 1 (b) vinegar
(d) aqueous NaHC0 1 (c) Be+ F2 ~ BeF2
(c) aqueous NaOH
. Ii
56. A hy drated so lid X on beatin g initia ll y gi ves a (d) BeO+C+F2 ~ BeF2
monobydrated compound Y. Y upon heating above 61. Given below are two statements, one is labelled as
373K leads to an anhydrous white powder Z. X and Z, Assertion (A) and the other is labelled as Reason (R).
respectively, are: 110 April, 2019 (Shift-11)1 124 Jan, 2023 (Shift-II)]
(a) Washing soda and soda ash. Assertion (A): Beryllium has less negative value of
reduction potential compared to the other alkaline earth
(b) Washing soda and dead burnt plaster.
metals.
(c) Baking soda and de;id burnt plaster.
Reason (R): Beryllium has large hydration energy due to
(d) Baking soda and soda asb. small size of Be2+ but relatively large value of atomization
57. Matc h the fo llowin g item s in co lumn I wit h th e enthalpy.
corresponding items in column II. In the light of the above statements, choose the most
(11 Jan, 2019 (Shift-11)1 appropriate answer from the options given below.
Column I Column II (a) A is correct but R is not correct
(A) Na2COr IO Hp (I) Portland cement (b) Both A and R are correct and R is the correct
ingredient explanation of A.
(B) Mg (HC0 ) 2 (II) Castner- Kellner process (c) A is not correct but R is correct
(C) NaOH (III) Solvay process (d) Both A and R are correct and R is NOT the correct
(D) Ca3Alp 6 (IV) Temporary hardness explanation of A.
(a) (A)-(11); (B)-(III); (C)-(1); (D)-(IV) 62. Chlorides of which metal are soluble in organic solvents:
(b) (A)-(III ); (B)-(11); (C)-(IV); (D)-(1) 130 Jan, 2023 (Shift-II}!
(c) (A)-(I Y); (B)-(1 ); (C)-(11); (0 )-(l ll) (a) Ca (b_) Mg
(d) (A)-(lll ); (B)-(IY); (C)-(11 ); (D)-(l) (c) K (d) Be
63, The alkaline earth metal sulphate(s) which are readily 68. In the given renclillll cyc le [ 12 April. Ztll J (Shift-I)!
soluble in water is/are: 130 Jan. 2023 (Shift-l)j CnC I, -i Nn,CO 1 - X
_,_
I _v1
(A) BeSOJ
(C) CaSO 4
(8) MgSO 4
(D) SrSOJ
L_, J
(E) BaSO 4 X. Y oncl Z respectively nre
X Y Z
Choose the cotTect answer fro m the options given below: (a) CnO NnC I I CO 2 KCI
(a) (A) only (b) (8) only X Y Z
(c) (A) and (B) (d) (8) and (C) (b) CnCO1 NnC I KC I
64. Given below are two statements: One is labelled as X Y Z
(c) CnCOJ NnCI KCI
Assertion (A) and the other is labelled as Reason (R) :
X Y Z
115 April, 2023 (Shift-l)l
(d) CaO NaCl + CO 2 KCI
Assertion (A) : BeCI, and MgCl2 produce characteristic
flame. · 69. Given b·clow arc two stntcmen ts:
Reason (R) : The excitation energy is high in BeCl2 and [8 April, 2023 (Shift-I)[
MgC½. Statement-I: Lithium and Magnes ium do not form
In the light of the above statements, choose the correct superoxide . .
answer from the option given below : Statement-II: The ionic radius of Li · is larger than 1on1c
(a) Both (A) and (R) are true but (R) is NOT the correct radius of Mg 2 '
In the li ::,oht of the above state ments, choose the most
ex planation of (A)
(b) (A) is false but (R) is true
(c) Both (A) and (R) are true and (R) is the correct (a) Statement-I is incorrect but Statement-II is correct
explanation of (A) (b) Statement-I is correct but Statement-II is incorrect
(d) (A) is true but (R) is false . (c) Both Statement-I and Statement-II arc cotTect
65. Reaction of BeO with ammonia and hydrogen fluoride (d) Both Statement-I and Statement-II arc incorrect
gives 'A' which on thermal decomposition gives BeF2 and 70. Mg(NO3) 2• Xl-tp and Ba(NOJ)2· YHp , represent the formula
NH/~What is 'A'? (24 Jan, 2023 (Shift-I)! of the crystalline forms of nitrate_sa lts. Sum of X and Y is
(a) (NH 4) 2BeF4 (b) H3NBeF 3 111 April, 2023 (Shift-JI)[
71. The alkaline earth metal sulphate(s) which are readily
(c) (NHJBeF 3 (d) (NH) Be/ 5
soluble in water is/are : 130 Jan, 2023 (Shift-I)[
66.· Be(OH), react with Sr(OH\ to yield an ionic salt. Choose (A) BeSO 4 (8) MgSO 4
the inc~rrect option related to this reaction from the (C) CaSO 4 (D) SrSO 4
following: [13 April, 2023 (Shift-I)] (E) BaSO4
(a) Be is tetrahedrally coordinated in the ionic salt. Choose the correct answe·r from the options given below:
(b) The reaction is an example of acid- base neutralization (a) (A) only (b) (B) onl y
reaction. (c) (A) and (8) (d) (B) and (C)
(c) Both Sr and Be elements are present in the ionic salt. 72. Arrange the followin g in increasing order or their covalent
(d) The elements Be is present in the cationic part of the character. [26 July, 2022 (Shift-II)[
ionic salt. (a) Ca l\ (b) CaC l2
67. Choose the correct statement(s): 11 Feb, 2023 (Shift-I)[ (c) Ca8r2
(A) Beryllium oxide is purely acidic in nature. 73. Given are two statements one is lnbc lled as Asse rtion (A)
(B) Beryllium carbonate is kept in the atmosphere of CO2. and other is labelled as Reason ( R).
(C) Beryllium sulphate is readily soluble in water. 128 _Junc, 2022 (Shift-I)!
(D) Beryllium shows anomalous behavior. Assertion (A): Magnesium can reduce A1,0 1 at a temperature
Choose the correct answer from the options given below: below I350"C, while above I350"C nl ui°ninium can reduce
MgO.
(a) (A), (B) and (C) only (b) (B), (C) and (D) only
r
Reason (R): The melting und boiling points or magnesium
(c) (A) and (B) only (d) (A) only are lowerlhan those or aluminium.

In light o_fthe above statements. choose most uppropriatc 81. Among the fo llowing, basic oxide is:
128 ,June, 2022 (Shift.fl)
(a) B~th A and Rare co1Tec1, and R is co1Tec1explanation (b) SiOl I
(a) SQ3
ot A.
(c) CaO
(b) Both A and R are con-eel, but R is NOT the correct
explanation of A. 82. The correct order of density is 125 July, 2022 (Shift-II)!
(c) A_is correct R is not correct. (a) Be > Mg > Ca > Sr (b) Sr > Ca > Mg > Be
(d) A is not correct, R is con·ect. (c) Sr > Be > Mg > Ca (d) Be > Sr > Mg > Ca
74, Which one of the following alkaline earth metal has the 83. BeO reacts with HF in presence of ammonia to giv
highest ionic mobility in its aqueous solution? [A] which on thermal decomposition produces [BJ an~
(a) Be2•
125 June, 2022 (Shift-1)1
(b) Mgl•
ammonium fluoride. Oxidation state ofBe in [A] is
-·
127 June, 2022 (Shift-II)!
84. N_umber _of p~ramagnetic oxides among the followi ng
(c) Ca 2• (d) sr2·
given oxides 1s _ _ _ . 11 Sept, 2021 (Shift-II)!
75. s-block element which cannot be qualitatively confirmed
by the flame test is 126 June, 2022 (Shift-11)1 Lip, CaO, Nap2, KO2, MgO and Kp
(a) Li (b) Na (a) 0 (b) I
(c) Rb (d) Be (c) 2 (d) 3

85. Match List-I with List-II : 118 March, 2021 (Shift-11)1
76. Reaction ofBeCl 2 with LiAIH4 gives:
List-I List-II
[26 July, 2022 (Shift-1)1
(A) Be (I) Treatment of cancer
(A) AICL, (B) BeH2
(8) Mg (I I) Extraction of metals
(C) LiH (D) LiCI
(C) Ca (Ill) Incendiary bombs and
(E) BeAIH4 signals
Choose the correct answer from options given below: (D) Ra (IV) Windows of X-ray tubes
(a) (A), (D) and (E) (b) (A), (8) and (D) (V) Bearings for motor
(c) (D) and (E) (d) (8), (C) and (D) engmes
77. · Addition ofH,SO4 to BaO2 produces: Choose the most appropriate answer from the option given
127 June, 2022 (Shift-1)1 · below:
(a) (A)-(Ill); (8)-(JV); (C)-(V); (D)-(11)
(a) BaO, SO2 andHp (b) BaHSO4 andO2 (b) (A)-(IV); (8)-(1 11); (C)-(1); (D)-(11)
(c) BaSO4, H2 ?nd 0 2 (d) BaSO4 and Hp2 · (c) (A)-(IH); (8)-(IV); (C)-(II); (D)-(V)
78. An element A of group I shows similarity to an element (c~ (A)-(JV); (B)-(111); (C)-(11); (D)-(1)
B belonging to group 2. If A has maximum hydration 86. Given below are two statements: one is labelled as
enthalpy in group I then B is: 127 July, 2022 (Shift-Il)I Assertion (A) and the other is labelled as Reason (R).
126 Aug, 2021 (Shift-11)1
(a) Mg (b) Be
Assertion (A): Barium carbonate is insoluble in water
(c) Ca (d) Sr
and is highly stable.
79. BeCl 2 reacts with LiAIH4 to give: Reason (R): The thermal stability of the carbonates
increases with increasing cationic size.
127 June, 2022 (Shift-1)1
Choose the most appropriate a~swer from the options
(a) Be + Li[AICl4] + H2 (b) Be+AIH 3 + LiCI +HCI given below:
(c) BeH2 + LiCI + AICl3 (d) BeH 2 + Li[AIC14] (a) (A) is false but (R) is true.
(b) (A) is true but (R) is fa lse.
80. The correct order of melting point is:
(c) Both (A) and (R) are true but (R) is not the true
126 June, 2022 (Shift-I)! explanation of (A).
(a) Be > Mg > Ca > Sr (b) Sr > Ca > Mg > Be (d) Both (A) and (R) are true and (R) is the true
(df Be > Ca > Sr > Mg explanation of (A).
(c) Be > Ca > Mg > Sr
JEE PYQs Chemistry - - - - - - - - - - - - - - - - - - - - - - - - -- --
►
87, What ore the products formed in sequence when excess (D) The sodium fusion (IV) 1lalogcn Spccifically
of CO, is passed in slaked lime?
cxtroct gi ves black
126 Aug, 2021 (Shift-1)1 precipitate with acetic
(b) CaO, CaCO acid nnd lead ncctatc.
J
The correct match is:

88. The set in which compou nds lrnve different nature is: (a) (A)-(1), (8)-(11), (C)-(IY), (D)-(1 11)
120 July, 2021 (Shift-1)1 (b) (A)-(111), (8)-(1), (C)-(IY) , (D)-(11)
(a) B(OH)3 and Al (OH) (b) B(OH) and H PO (c) (A)-(IIJ) , (8)-(1), (C)-(1 1), (D)-(IY)
3 3 3 3
(c) NuOH and Ca(OH) (d) (A)-(1), (8)-(IV), (C)-(111), (D)-(11 )
2 (d) Be(OH)2 and Al(Ol-1)
3
89. Match the List-I with List-II. }22 July, 202 I (Shift-fl)! 92. Given below are two statements:
[25 July, 2021 (Shift-I)!
List-I List-II Statement-I: None of the alkaline earth metal hydroxides
(Elements) (Properties) dissolves in alkali.
A. Ba (I) Organic solvent soluble Statement-IJ: Solubility of alkaline earth metal hydroxides
compounds in water increases down the group.
B. Ca (II) Outer electronic In the li ::,oht of the above statements, choose the most
configuration 6s 2 appropriate answer from the options given below:
C. Li (a) Statement-I and Statement-I I both are incorrect.
(Ill) Oxalate insoluble in
water (b) Statement-I is incorrect but Statement-II is correct.
D. Na (IV) Formation of very (c) Statement- I is correct but Statement-II is incorrect.
strong monoacidic base (d) Statement-I and Statement-II both are correct.
Choose the correct answer from the options given below : 93. Number of amphoteric compounds among the following
(a) A-(11), 8-(lll), C-(1) and D-(IV) is_ _ _ _ 124 Feb, 2021 (Shift-1)1
(b) A-(IV), 8-(1), C-(11) and D-(lll) (a) BeO (b) BaO
(c) A-(1), 8-(JV), C-(11) and D-(111) (c) 8e(OH)2 (d) Sr(OH)2
(d) A-(111), 8-(11), C-(IV) and 0-(1) 94. Identify the elements X and Y using the ionization energy
90. Given below are two statements: values given below: 116 March 2021 (Shift-TI)!
Ionization energy (kJ/ mol)
(16 March, 2021 (Shift-I)!
I" 2 nd
Statement-I: Both CaCl .6H O and MgCl .8Hp undergo
2 2 2
dehydration on heating. X 495 4563
Y 731 1450
Statement-II: 8eO is amphoteric whereas the oxides of
other elements in the same group are acidic. (a) X = Mg; Y = Na (b) X = F; Y = Mg
In the light of the above statements, choose the correct (c) X = Na; Y = Mg (d) X = Mg; Y = F
answer from the options given below: 95. Among the su lphates of alkaline earth metals, the
(a) Statement-I is fa lse but statement-I I is true solubilities of BeSO4 and MgSO in water, respectively,
4
(b) Statement-I is true but statement-II is false are: (6 Sept, 2020 (Shift-I)!
(c) Both statement-I and statement-II are false (a) poor and poor (b) high and poor
(d) Both statement-I and statement-II are true (c) high and high (d) poor and high
91. Match List- I with List- II [16 March, 2021 (Shift-fl)[ 96. A metal (A) on heating in nitrogen gas gives compou nd
List - I List - II
8. B on treatment with Hp gives a colourless gas which
when passed through CuSO4 solution gives a dark blue-
Test/Reagents/Observation(s) Species detected
violet coloured solution . A and B respectively, are:
(A) Lassaigne's Test (I) Carbon
18 Feb, 2020 (Shift-11 )1
(8) Cu (II) oxide (II) Sulphur (a) Mg and Mg(NO ) (b) Na and NaNO
3 2
(C) Silver nitrate (111) N, S, P, and halogen (c) Mg and Mg3N2
.l
(d) Na and Na N
3

. b I w '11·c two sta tements
. : one is labcll eda
97· An alkaline earth metal 'M' readi ly forms wntcr soluble 105. G1ve11 co ,
Assertion (A) and the other 1s labelled ns Reason (R). 1
sulphate and water insoluble hydroxide. Its ox ide MO is
11 Feb, 2023 (Sh·,r,
vel)' stable to heat and docs not have rock-salt st111ct11rc. . . ·lf)I
M is: 14 Sept, 2020 (Shift-11)1 Assertion (A): Gypsum 1s used for mak ing fireproof ...
"all
(a) Sr (b) Be bonrds.
(c) Mg (d) Ca Rcnson (R): Gypsum is unstable at high temperatures.
98· The correct sequence oftherinal stability of the follow ing 111 the light
of the above statements, choose the correq
. . b
11 2 April, 201 9 (Shift-1)1 answer from the options given eIow :
carbonates is:
(a) Both (A) and (R) are correct but (R) is not the correq
(a) BaCO3 < SrCO3 < CaCO3 < MgCO1
explanation of (A).
(b) BaCO3 < CaCO 3 < SrCO3 < MgCO1
(b) (A) is correct but (R) is not correct.
(c) MgCO. < CaCO J < SrCO J < BaCO J
J
(c) (A) is not'correct but (R) is correct.
(d) MgCO 3 < SrCO 3 < CaCO1 < BaCO 1
(d) Both (A) and (R) are correct and (R) is the correet
99. The alkaline earth metal nitrate that do~s not crystallise
explanation of (A).
with water molecules is: 19 Jan, 201 9 (Shift-.1)1
106. The setting time of Cement is increased by adding
(a) Mg(NO,) 2 (b) Sr(NO 3\
I6 April, 2023 (Shift-nl
(c) Ca(NO,) 2 (d) Ba(NO,)2
(a) Clay (b) Silica
100. The amphoteric hydroxide is: 111 Jan, 2019 (Shift-I)! (d) Gypsum
(c) Limestone
(a) Be (OH)2 (b) Ca(OH)2
107. Match List I with List II. 124 Jan, 2023 (Shift-I)!
(c) Mg(OH)2 (d) Sr(OH)i
List I List 11
IO 1. The structures of beryllium chloride in the solid state and
(A) Chlorophyll (I) Na,CO.
vapour phase respectively are: 19 April, 2019 (Shift-II)! - J
(8) Soda ash (II) CaSO4

(a) Chain and dimeric (b) Chain and chain
(c) Dimeric and dimeric (d) Dimeric and chain (C) Dentistry, (IIl) Mg2+
I 02. The element having greatest difference between its first Ornamental work
and second ionization energies, is: (D) Used in white (JV) Ca(OH)2
19 April, 2019 (Shift-[)! · washing
(a) Ca (b) K Choose the correct answer from the options given below:
(c) Ba (d) Sc (a) (A)-(111), (8)-(1), (C)-(11), (D)-(IV)
103. The metal used for making X-ray tube window is: (b) (A)-(11), (8)-(1), (C)-(111), (D)-(IV)
110 Jan, 2019 (Shift-[)! (c) (A)-(Ill), (8)-(IV), (C)-(1), (D)-(11)
(a) Mg (b) Na (d) (A)-(11), (B)-(lll), (C)-(IV), (D)-(1)
(c) Be (d) Ca 108. The element playing significant role in neuromuscular
Some Important Compounds of j

'
function and interneuronal transmission is:
131 Jan, 2023 (Shift-I])!
(b) Ca
Ca and Biological Importance of (a) Be
(c) Li (d) Mg
Mg and Ca
109. What is the purpose of adding gypsum to cement?
104. Lime reacts exothermally with water to give 'A' whi'cl1 [8 April, 2023 (Shift-Ill
has low solubility in water. Aqueous solution of ' A' is
often used for the test of CO 2, a test in which insoluble B (a) To facili tate the hydration of cement
is formed. If 8 is further reacted with CO 2 then soluble (b) To speed up the process of setting
compound is formed. 'A' is 110 April, 2023 (Shift-I)!
(c) To slow down the process of setting
(a) Quick lime (b) Slaked li me
(d) White lime (d) To give a hard mass
(c) Lime water
JEE PYQs Chemistry - - - - - - - - - - - - - - - - - - - - - - - - - - - ~

- 110. Match List-I with List-LI 118 ~larch_. 2021 (Shift-OJ
II fl-b. 2023 (Sbift-ij) 11 7. Match List-I with List-II :
List-I List-II List-l Li:st-O
(A) Slaked lime (1) NaOH (I) Antacid
(Al Ca(OCll:
(B) Dead burnt plaster (11) Ca(OH):
I
(C) Caustic soda (III) N~CO; 10~O lB) CaSO I . -2 H -~o ( II) Cemenl
(D) Washing soda (TY) CaSOJ (C) CaO ( 111 ) Bleach
Choose the correct answer form the options gi,--en below: (D) CaCO, ( JV) Plaster of Paris
(a ) (A)-(1). (B )-{T\ l . (C)-(1 1). (0 )-(IJ[) Choose the mosi appropriate answer from the options
(b) (A)-(III). (8 )-(l\"). (C)-(11). (D)-(1) gi,--en below:
(c) (A)-{ll). (B)-(TV). (C)-(1). (D}-(lll) (a) (A}-{ lll). (B}-{11). (C}-{ IV). (D}-{I}
(b) (A }-{Ul). (B}-{TI). (C}-(1). (D}-{JV)
(d) (A)-(lll). (B)-{ll). (C}-(TV). (D)-(1)
(c) (A}-(IU) . (B}-{l\ l . (C}-{ 11). (OH i)
I 11. For a good quality cement the ratio of silica to alumina
(d) ( A}-(1). (B }-{I\ l . (C}-(UI ). (D }-{TI)
is found to be 115 April. 2023 (Shift-I))
118. The major component 'ingredient of Portland Cement is:
(a) 3 (b) 4.5
(c) 1 (d) l.5 131 Aug, 2021 (Shift-ij)
(a) tricakium silicate (b) dicaJcium alumiaate
112. For a good quality cement the ratio ofl ime to the total of
(c) dicak ium silicate (d) tricaJcium alumioate
the oxides of Si. Al and Fe should be as close as to:
18 April, 2023 {Shift-II)) 119. The conn~rs:ion ofhydroxyaparite occurs due to presence
(a) 4 off- ions in water. The correcr formula ofhydroxyapatite
(b) 2
is: [26 Aug. 2021 (Shift-I))
(c) 3 (d) l
(a) [Ca,(POLt CaF::] (b) [3Ca,(POLl:c,Ca(OH):J
113. The setting time of Cement is increased b,· addino
(c) [3Ca,(POJ ::.Caf:] (d) [3Ca(O~.Caf:J
106 April, 20D (Shift-I)]
(a) Clay (b) Silica 120. The number of warer molecules in gypsum_ dead bornr
plaster and pla.srer of paris.. respectiYcly are:
(c) Limestone (d) Gypsum
[2 7 Aug. 2021 (Shift-I))
114. Statement-I: An alloy of lithium and mawesium is used
(a) 2. 0 and l (b) 5, 0 and 0.5
to make aircraft plates. ~
(c) 2- 0 and 0.5 (d} 0.5. 0 and 2
Statement-II: The magnesium ions are imporram for
cell- membrane integrity. 121. When gypsum is heared ro 393 K.. it forms:
Ln the light the above statements, choose the correcr [8 Jan, 2020 (Shift-I))
answer from the options giwn below
(a) CaSO~·0.5Hp (b) Deadbumtplaster
[28 July. 2022 (Shift-II)] d) CaSO4 - 5 Hp
(c) ..\nhydrous CaSOL (
(a) Both Statement-I and Statement-II are true

122. \ larch the follo" ing compounds (column-I) ,, i th th-:-ir
(b) Both Statement-I and Statement-II are false [6 Sept 2020 (Shift-II))
uses (column-IT)
(c) Statement-I true but Statement-II is false Column-I Column-TI
(d) Statement-I is false but Statemem-11 is aue
(A) Ca(OH): (T) casts of sratue.s
115. Portland cement contains ·x- to enhance the setting time. (B) ~aCI (11) whir-e wash
What is ·x·? 129 July. 2022 (Shift-II))
I (C) Caso•...!.Ro
2 - (lll) antacid
(a) CaSO . • -H, O (b) CaSO4 • 2~0
.. 2 -
(D ) CaCO3 (T\1) \\'ashingsod3prqmation
(c) CaSO 4 (d) CaCO;
(a) (A}-(1\f), (B)-{l). (C}-(lll). (D}-(11)
116. Which one of the foll owing elemental forms is not present
in the enamel of the teeth? 124 June. 2022 (Shift-I)! (b ) (A}-(11), (B}-(IV), (C}-(l), (D)-(1)
(a) Ca"- (b) p.3- (c) (A)-(11). (B)-(lll). (C)-(1\1), (O)-{l)
(c) r- (d) ps- (d) (A)-(111), (B)-( IV), (C}-(11), (D)-{l)

\
• \
\ ANSWER KEY J ~
t. (c) 7. (I') H. (•) 9. (1·)

2. (c) l (c) 4. (,/) 5. (h) (1. (</) Ifl, (r/)
11. (d) 17. 121 IH. (t ) 19. (o)
12. (11) 13. (c) 14. (/,) 15. (</) 16. 1.11 20, (11)
2H. (a) 29, (d)
21. (n) 22. (11) H. (c) 24. (/,) 25. (1/) 26. (</) 21. M JO, (11)
3 I. (</) 32. [1 J 33. (/,) J4. (<r, 35. (</) 36. (/J) n (h) 3H. (/1) 39. (/1) 40, k)
41. (d ) 42. (/,) 47. (r) 4H. (a) 49. (o) 50, (11)
43. (b) 44. (d) 45. (a) 46. (</)
51. (a) 57. (rl) 5H. (o) 59. (/,) 60, (a)
52. (cl) 53. (/,) 54. (/J) 55. (</) 56. (a)
61. (h) 62, (cl) 66. (</) 67. (/J) 68. (c) 69. (r) 70, [61
63. (c) 64. (h) 65. (a)
71. (c) 72. (b) 77. (c/) 78. (a) 79, (c) 80, (1~
73. (b) 74. (</) 75. (cl) 76.· (b)
81. (c) 82. (c) 86. (</) 87. (c) 88. (a) 89. (a) 90, (c)
83. [2] 84. (b) 85. (d)
91. (b) 92. (b) 93. 95, (c) 96. (c) 97. (b) 98. (c) 99. (d) 100, (a)
[2] 94. (c}
IOI. (a) 102. (b) 103. (c) 104. (b) 105. (a) 106. (rl) 107. (a) I08. (/J) I09. (c) 110. (c)
11 I. (a) 112. (b) 113. (d) 114. (b) 115. (b) 116. (b) 117. (c) 118. (a) 119. (/,) 120. (c)
12.1. (a) 122, (b)
_XP_lA_N_AT_IO_NS__\_:-s-------..
--•--------4\.__E
1. (c) The correct decomposition reaction for the lithium 6. (d) up-+ 0 2- -+ diamagnetic
nitrate is: Nap2 -+ OJ--► diamagnetic
4LiN03 ~ 2Li 2 0+4N0 2 +02 KOl -+ o;- -> paramagnetic
2. (c) 7. (c) Sodium have lowest oxidation potential in alkali metals.
Element Colour in Flame test Hence, it is wenkest reducing agent among alkali melals.
K Violet 8. (*) Potassium salts having large anions are less soluble
than the sodium salts because of higher lattice energy.
Ca Brick red
Moreover, potassium is preferentially absorbed by
Sr Crimson red plants. Due to bigger size of potassium, it forms more
Ba Apple green efficient lattices as compared to sodium with silicates
3. (c) The alkali metals and their salts impart characteristic The abundance or sodium in ocean is more due to the
colour to oxidizing flame, which can be deleted using more soluble nature of salt of sodium ns compared
flame heats. to potassium sa lts.
NTA ans. key - >(n)
4. (d) Hydration enthalpies: Smaller the size, larger will be
the hydration enthalpy. PW ans. key ➔ (d)
(i) K' > Rb'> Cs' : (A) > (B) > (D) 9. (c) KOH absorb CO2, so its concentrntion must be
(ii ) Mg' 2 > Ca' 2 : (C) > (E) checked before titration.
Option (d) IO. (d) An aqueous solution of NaCl is called brim:.
(C) > (E) > (A) > (B) > (D) NnCl(nq) ➔ Na '+ Cl
5. (b) Density increases for Group I metal.because mass Al cathode, 1-1 2 is released
often increases significantly as compared to volume 211 0 + 2e- '" 11..-,i..., H +?OH
2 2( y) -
(size) moving down the group. Due to empty 3d
subshell in K increase in size is more prominent as At anode, Cl2 is re lensed
compare to mass. 2CI <l\ldntlt>tt Cl 2
➔ 2( y) + e
Li < K < Na < Rb < Cs Therefore, IICI wi II not form during clcctroly~is.
~ JEE PYQs Chemistry - - - - -- - - - - -- - - - - - - - - - - -- - -

1t. (dl On 1110\'ing down the group strength of metallic bond 21. (a)
decreases. Hence, the 111.pt. decrease. Rb Cq
Metals Li Na
l2, (a) For a given metal L\H 0 always becomes less negative Colour Crimson Yellow Red Blue
from fluoride to iodide. Therefore correct order of red violet
standard enthalpy of fonnation ofNaX is Na I < NaBr Wavelength/ 670.8 589.2 780 455.5
< NaCl < NaF 11111
22. (a) Density of metal a very specific and depe~ds upon

13. (c) (I) Na > Cs > Li - true {If considered with sign} many factors."
Csl is less soluble in water due to smaller hydration Li ~ 0.53 gm/qn 3
enthalpy of it's two ions
Na~ 0.97 gm/cm 3
Li 2CO3 is not so stable to heat and gets converted K ~ 0.86 gm/cm 3
into Lip and col. . Rb~ 1.53 gm/cm 3
Potassium dissolved in liquid ammonia give deep Cs~ 1.90 gm/cm 3
blue solutions that are paramagnetic but in the 'K' has less density as compare to Na.
concentrated solution, the blue. All the alkali metal
hydrides are ionic solid (True). 23. (c) LiF is sparingly soluble in water due to high lattice
energy. Due to smallest size, ~i• has high hydration
14. (b) Among the given, alkali metals i.e., Li, Cs n;act energy among its group members.
vigorously with water.
24. (b) An alkali metal oxide having formula MO 2 is super
Br gets converted in vapour state in boiling water oxide which is formed by two metals K and Rb. The
(BP = 58°C) color ofKO2 is pale yellow and it is paramagnetic in
Gallium is the element which reacts with water above nature.
100°c = (MP = 29°c, BP= 2400°q 25. (d) Li 2CO3 decomposes easily on heating as;
15. (d) The electronic configuration with respect to given Li 2C03 ~ Li 20 + CO 2 t
atomic numbers are as follow, NaHCO 3 1:.sed in dry fire extinguishers.
37 - [Kr]5s' belongs to s-block K is most abundant element in cel l fluid.
78 - [Xe] 4fl4, 5d9, 6s' belongs to d-block Csl is least soluble due to smaller hydration energy
0
52 - [Kr] 4d' 5s2, 5p
,
4
belongs to p-block of Cs• & 1-.
65 - [Xe] 4f1, 6s 2
belongs to f-block 26. (d) ( I) The standard enthalpy of formation for alkali
metal bromides becomes ·more negati ve on
16. [3] 2LiNO3 ~ Li 2 O + 2NO2 +.!..0 2 moving down the group.
2
(2) Standard enthalpy of formation for LiF is most
On heating of LiNO3 give these products Lip, NO2
negative among alkali metal fluorides.
&02
(3) Csl has less lattice energy and due to less
17. [2) Among the given elements, three metals K, Rb and hydration energy of Cs+, it is less soluble in
Cs form stable super oxides but ionisation enthalpy water.
of Cs is less than 400 kJ. (4) Tbe solubility in water increases from Li to Cs,
for alkali metal fluorides. LiF is least soluble in
18. (c) The decomposition reaction of lithium nitrate and water.
sodium nitrate are:
27. (d) (A) Li ➔ bearings for motor engine
4LiNO3 ~ 2Lip + 4NO 2 + 0 2
(B) Na ➔ coolant in fast breader nuclear reactor
1 (C) K ➔ absorbent of CO2
NaNO 3 ~ NaNO 2 + - 0 2
6 2 (D) Cs ➔ photoelectric cell
19. (a) LiF is less soluble due to its high lattice energy. .
28• (a) Latt1ce energy ex: charge ex: - .-I
20. (a) Both LiCI and MgCl2 are covalent in nature due to size
LiF LiCI
which they are soluble in ethanol LiF is very less
~ ~
soluble ,in water due to its high value of lattice energy. Li' F- Li '. Cl
- - - - - - - - - - - - - - - - - - - - -- - - - - - - - - The s-Block Elements

As compared to LiCl, LiF has more lattice enthalpy. 80
~R2 = (16 - 9)
MgO NaCl 2
~ ~ ~RI 2
Mg2• 0 2- Na" Cl : . ~R =3
MgO has more lattice enthalpy as compared to NaCl. 2
29. (d) Due to small size of Li , it has more polarizing power 37. (b ) Li form s normal oxide, Na form s peroxide Whil
due to which its most of the compounds are covalent. form s superoxt'de. · eK
30. (a) Li ~ Crimson Red 4Li + 0 2 ~ 2Lip

2Na + 0 2 ~ Nap 2
Na ~ Yellow
Rb ~ Red violet K + O2~ KO 2
Cs ~ Blue 38. (b) Caesium metal has lowest ionisation enthalpy, due
Hence, Wavelength orqer is: which it can show photoelectric effect to the maximuto
Red violet > Crimson Red > Yellow > Blue extent. Therefore it is used in photo electric cell. Ill
,j, -!, -!, -!,
39. (b) 2KO/ s) + 2H 2O(1) ➔ 2KOH(aq) + Hp/ aq) + Oig)
780nm 670.8nm 589.2nm 455.5nm
31. (d) Due to high hydration enthalpy of Li+, Li salts are 40. (c) Mg O and Mg3N2
extensively hydrated . Mg+O 2 ➔ MgO
The correct order of polarizing power is: 3Mg + N2➔ Mg3N2

Li•> Na• > K• > Rb• > Cs• 41. (d) 2LiNO 3 ~ L i p + 2NO2(g) + .!_ O/ g)
32. [I] Among the gi ven options, only Cs is used in 2
photoelectric cell because of its very low ionisation 42. (b) Rb+ 0 2 ➔ RbO 2
energy. (excess) superox ide
X ➔ is RbO 2.
33. (b) All alkali metal cations gets converted into hydrated
form in an aqueous medium. More the +ve charge on 2RbO2+ 2Hp ➔ 2RbOH + HP2+ 0 2
cation, more it will be hydrated. 43 . . (b) Li only element in the group that react with dinitrogen
to form nitride.
It will result in the increase in size of the cation.
44. (d) It give a deep blue solution due to formation of
Therefore,.Li• cation has larger size in hydrated form
ammoniated e-.
and least conductivity.
Thus, the correct order of conductivity of alkali metal 45. (a) Li+> Na•> K• > Rb+> Cs•
ions are: Li+< Na• < K• < Rb• < Cs•. It depends upon ionic Potential
34. (d) Statements A, C and D are correct among the all four. (Charge/size) I.P. tes; H.E. tes.
Li has the highest hydration enthalpy among the 46. (d) The correct chemical formulas are:
alkali metals due to small size. Washing soda: Na2CO 3• l0Hp
LiCI is covalent in nature so it's soluble in non-polar Soda ash : Na2CO 3
solvent. Hence, IO and 0 water molecules are present in both,
Li and Mg react slowly with Hp. respectively.
35. (d) Lithium and magne sium do not form solid
bydrogencarbonate, Both Li and Mg react with N2 47. (c) Ca(OH) 2+2NH 4Cl~2NH 3 +CaC1 2 +2H20
(A ) (8)
to give nitrides. Reactions are,
NH 3 + H2O +CO 2~ NH 4 HCO 3
6Li + N2 ~ 2Li 3 N (8) (cxc) (C)
3Mg + N2 ~ Mg 3 N2 NH 4 HCO 3 + NaCl~ NaHCO 3 ,j, +NH~CI

(C )
2 48. (a) K• - Sodium - Potassium Pump

a n
36. (b) R = - 0- KCl - Fertiliser
Z
KOH - absorber of CO2
For Li , Z = 3
Li - used in thermonuclear reaction·s
a
LlR 1 =__Q_(l6 - 9) 49. (a) NaOH is obtained by electrolysis of NaCl. Following
3
For He, Z = 2 are the reactions that take place at cathode and anode:
158 ' '

►
', ( f f~~ J(I rr.r,
<,11. (11) 'I he he~t rr11.:1hud f11r the pr1;~r;i v,r, ,
Cathode: Na ' ➔ c ~ Na Amalgam , ,
given rnetlwd~ i~hcfllmv, lfl (HlfiJ,1~~ 1
Anode : 2CI ~ Cl2 + 2c
It iH given r,~
.
2Na-Amalgam + 21-1 20 ~ 2NaO1I 1- 21lg 1 11 2
(N ll4)i flcl'4 ,, ,Hcl') i 1'111,.f'
so. (a) Baking soda is also known as sod ium hydrogen-
carbonate (NaHCOJ is used in fire extinguishers. 61. (IJ) fJ eryll iu,n hm• leH'I ncg1Jt1ve v1Jlue of retJ1J1_;trr,ri
potc111ial a~c:,ornpiircd 1/11,1h1.,-r alblme e1Jrth r~h,
St. (a) The fom1ula for the compounds is:
l fowever, the reducing nature (ff f~ i~ due tt,, larie
Baking soda = NaHCOi hydration energy a~n,,dawd with the <+mall ~,r..e, of
Washing soda = Nalco)' I 01-120 Bc 2' ion iind relatively large val11e rrf the att;mr71arrJ11
Caustic soda = NaOH enthulpy of mc;tal.
Hence, carbonate ion is present in washing soda only.
62. (d) According to the principle, ..like di,w~lvc~ lik~ ,
52. (d) Pesticides are DDT, organophosphates and dieldrin. cova lent molecules will be ~oluble ,n Mg.a"'."
53. (b) Solvay process solvents. Therefore, /JcCl2 having covak-nt n~re 11
(i) 2NH3 + H2O + c o 2➔ (NH4) 2CO3 soluble in orgunic solvt--nL
· hi ' r r~ -2• ,nd'~1u1 •
(ii) (NH4) 2CO3 + Hp+ c o 2➔ NH 4 HCO3 + CO3 63. (c) The greater hydratrcm cnt a prc'4 o _.,c 11 1v c;
(iii) NH4HCO3 + NaCl ➔ NHp + NaHCO3 ions overcome the lattice enthalpy factM and
therefore, their sulphates arc soluble in water.
54. (b) CaC12is obtained as by product as shown below:
64. (b) Be and Mg have alJnormally gmall sir..e and they do
2NHp + Ca(OH\ ➔ CaCl2+ 2NH 3 + Hp not give colour to flame due to high er.citation energy,
Hence, CaC12is byproduct. and they are less volatile
55. (d) In toi let cleaning liquid the mai n consti tuent is
65. (a) BeO + 2NH3 + 4HF - > (N HJz8cF4 + H/J
hydrochloric acid, which ca n ca use skin bu rn .
Therefore, it should be treated with a base li ke (NH4 ) BcF4 -A-➔ BeF2 + Nf-f , F
2
NaHCO3 which can easi ly neutralize the acid. NaOH 66. (d) Be(OH)i is amphotcric in nature.
is highly corrosive in nature therefore it is not used
Sr(Of-1)2 is basic in nature.
to neutralise acid.
A salt is created between these two by an acid-base
56. (a) The reactions that occurs are: interaction. The reaction is shown as:
t,,
N32CO3 -l0H 2O(s) _ Na2COr H2O Be(Of-1 )2 + Sr(OH)2 -► Sr[Be(OH)""l
(salt)
(X) (Y)
(Washing soda) 67. (b) (A) Beryllium oxide is amphotcric in nature.
(8) Beryllium carbonate is thermally less stable.
So, it is kept in the atmosphere of CO2•
(C) Due to high hydration energy, BeSO4 sulphate
(soda ash) is readily soluble in water. ·
(Z) (D) Beryll ium shows anomalous behaviour due
Hence X: Washing soda and Z : Na 2CO3 (Soda Ash) to small size, high ionization energy and high
valm; of (polarising power).
57. (d) Na2CO 3• I0Hp is prepared by Solvay process
68. (c) Reacl ion of cu lcium chloride with sodium carbonate
NaOH is prepared by Castner-Kellner process
gives calcium carbonate and sodium chloride.
Ca3Al2O6 - Portland cement ingredient CaCO1 NuCI
1--
Mg(HCO;) 2 - Temporary hardness CaCll I Nalco) - X y
. Charge
58. (a) Hydration enthalpy oc - . -
Size t IICI I
As, charge in same in all cases. Down the group as size z
increases hydration enthalpy decreases 69. (c) Li & Mg form oxide and order of size Li ' ,., Mg2'
Order : Be2' > Mf 2 > Ca' 2 > Sr' 2 > Ba' 2 both arc unublc to form superox idc due to small size.
70. f6J Mg(NO 1) 2·6l l20 is u hydrated salt whereas Ha(NO )
59. (b) Beryllium Chloride (BeC12) in solid state exists as .s a anI1ytIrous suit. I l
1
polymer, in vapour state it forms chloro-bridged
.". X I y 6
dimer while above I200K it exists as monomer.

7
1. (c) The greater hydration enthalpies of Be 2' and Mg 2' (Nl-14) 2 [BeF4]~ BeF2 +2NH4F
ions overcome the lattice enthalpy factor and
therefore, their sulphates are soluble in water. A: (NH 4) 2 [BeF 4) or [BeFl
72. (b) According to Fajan 's rule, covalent character is In [BeFJ , let oxidation stale of Be be x
directly proportional to the size of the anion. ⇒ X_ 4 ,: - 2 ⇒ X ,: +2.
:. CaF 2 < CaCI 2 < Ca Br2 < Cal 2
Hence, o~idalion state of Be in A is +2.
7
3. (b) Mg can reduceAlp 3 below temperature l 350°C
(':n == 3). 84. (b) Lip, CaO, MgO and ~Oare simple oxides.
and , Al can reduce MgO above I350°C as per Metals which form peroxide is Nap 2 and supero .
X1de
Ellingham diagram. is KOr
TI,e boiling and melting point of Mg are smaller than For superoxide;
that of Aluminium. o-2 ➔ cr Is2 cri s2 cr2s 2 cr2s 2 cr2p2zrr2p2, = n2p2y 1t'2p1
74. (d) Smaller the size of ion, higher will be its hydration = rr •2 Py
I I
energy and hence, smaller will be its ionic mobility. It is paramagnetic due to presence of unpaired
Order of size of hydrated ions; Be•2 > Mg+2 > ca•2 > sr•2 electron.
Order of ionic mobility; Be'2 < Mg+ 2 < ca•i < sr•2 85. (d) In X ray tube windows, Be is used.
75. (d) Due to high ionization energy of Be, it does not In incendiary bombs·& signals, Mg is used.
respond to flame test. Calcium can be .used for the extraction of metals
76. (b) The reaction involved is: from oxides that are difficult to reduce with carbon.
In treatment of cancer in radiotherapy, Radium (Ra)
2BeCl 2 + LiAIH 4 -+ 2BeH 2 + LiCI + AICl 3
is used.
77. (d) When BaO2 reacts with 8iSO4, then BaSO4 and Hp 2
86. (d) Thermal stability of carbonates increases down the
is formed. BaO 2 + H2SO4 ~ BaSO4 + Hp 2
group in alkaline earth metals due to increase in
78. (a) Li belongs to group-I. It shows diagonal relationship cationic size down the group.
with Mg. Lithium has maximum hydration enthlpy
in group i. Therefore, B must be 'Mg'. 87. (c) The following reactions occur when excess CO, is
passed in slaked lime. -
79. (c) The reaction between BeCl2 and LiAIH 4 occurs as:
2BeCl2 + LiAIH 4 ~ 2BeH 2 + LiCI + AICl 3 Ca(OH\ +CO 2 ~ CaCO3J + 8i0
Hence, the products formed are:- Be8i, LiCI andAiq. Slaked lime Calcium carbonate
80. (d) Be shows anomalous behaviour due to small size. ( 1'1 step of reaction)
Be = 1560 K CaCO 3 +Hp+ CO 2 ~ Ca(HCO)2t
Mg == 925 K Calcium bicarbonate
Ca = 1120 K (2 nd step of reaction)
Sr = 1062 K 88. (a) B(OH)3 is orthoboric acid and it is acidic in nature,
81. (c) . CaO - Basic Oxide (Metallic oxide)
while Al(OH)_, has amphoteric nature.
SO 3 & SiO2 - Acidic oxides (Non-metallic oxide) 89. (a) Ba ➔ Outer electronic configuration 6s2•
Alp 3 - Arnphoteric oxide CaC2O4 ➔ insoiuble in water.
Compounds of Li are covalent as a result, are soluble
82. (c) Element Density (gm/cm 3) in organic solvent.
Be 1.84
Na forms strong monoacidic base.
Mg 1.74 90. (c) Hydrated halides of grotip 2nd Ca onward undergo
Ca 1.55 dehydration on heating but hydrated halide of Mg
Sr 2.63 i.e. MgC12'8Hp does not undergoes dehydration on
Ca has least density among the given elements. heating but undergoes hydrolysis. BeO is amphotenc
while other oxides of group 2nd are basic is nature.
83. [2] The following reactions takes pl11ce:
91. (b) For N,P,S and halogen detection, lassaigne's teSI
BeO + 2NH 3 + 4HF ➔ (NH 4\ [BeFJ
is used to detect of C, Cu (II) oxide is use is x-
(A) s ion precipitated as
precipitated by AgNO 3 and 2-
.I.-,"
-
PbS (Black) with sodium fu sion extract. Soda ash: Na t O,
92. (b) ~own the group. solubility of 2"d group hydroxide Denti stry, Ornamental work : CaSO4 •
mcreases.
Used in white washing: Ca(Ol-l) 2
93. [2] Both BeO & Be(OH\ react with acid and base and
108. (b) Among the gi ven options, Ca lcium plays important
hence, are amphoteric in nature
ro le in neuromuscular fun cti on and interneuronal
94. (c) For alkali metal s the difference rooge of I st ionisation
transmission . It is required to trigger the contraction
energy ~nd 2~1d ionisation energy is much higher than
of muscles.
respecttve difference range of alkaline earth meta l
hence [X = Na & Y = Mg] ' 109. (c) The purpose of addin g gypsum is onl y to slow
down the process of setting of cement so that it gets
95. (c) On going from top to bottom, solubil ity of sulphate
sufficientl y hardened.
decreases.
96 • (c) A+ N2 ~ mtn
. "de (8) ~ M0
110. (c) Slaked lime_. Ca(OH)2
NH/ colourless) +
CuSO 4 ~ Blue-violet coloured sol. Dead burnt plaster - CaSO4
3Mg+ N2 ~ Mg 3 N2 ~ Mg(OH) + NH Caustic soda _. NaOH
(A) ( O) 2 J
Washing soda _. Na 2CO3• I0Hp
Hence, (A) and (8) are Mg and Mg3N2 respectively.
111. (a) For good quality cement, the ratio of silica ( SiO 2) to
97. (b) BeO fo rms water solubl e sulphate and insoluble
Alumina (Alp 3) should be between 2.5 to 4 .
hydroxides. It does not have rock-salt st~cture.
98. (c) As we move down the group. Thermal stability of 112. (b) For a good quality cement the ratio of lime to the
gp. JI carbonate increases. total of oxides of silicon (S iO 2), aluminium (Alp 3)
and iron (Fep3) should be close to 2.
99. (d) 8a(NO 3\
Due to large size of Ba, it doesn't crystallize with 113. (d) Gypsum is used fo increase the sett ing time of
water molecule. cement.
100. (a) Be(OH)2 reacts with both acids and bases. 114. (b) An alloy of lithium and magnesium is used for
IOJ. (a) BeCl 2 exist as (8eCl 2). po"lymeric chain in solid form, manufacturing armour plates and not aircraft plates.
while BeCl 2 exist as dimer (BeCl2) 2 in vapour phase. Calcium ions play an important role in ceU membrane
integrity.
102. (b) K = 2, 8, 8, I
115. (b) Gypsum (CaSO4.2Hp) is used to enhance the setting
After removal of one electron, second electron we
have to remove from another shell, hence there is time, hence X is Gypsum.
large difference between first.and·second ionization 116. (b) Enamel has composition of calcium hydroxyl apatite
energies. [CaiPO4MOH\ ], CaCO 3, CaF 2 and Mg/ PO.J~
103. (c) Be used for making X-ray tube wi ndow. which means Ca2+, P5' and F- are present while P3'
104. (b) The fo llowing reaction·s takes place: is not present.
CaO + Hp --? Ca(OH)2 117. (c) The correct matches are:
(lime) A (less soluble) (slaked lime) (A) Ca(OCI\: (111) Bleach
Ca(OH)2 + CO 2 ---? CaCOr!, + Hp 1
(A) B (insoluble) (B) CaSO4 • - H,O: (IV) Plaster of paris
2 -
CaCO3 + Hp+ CO 2 ---? Ca(HCO 3) 2 (C) CaO: (11 ) Component of cement
(B) Soluble
(D) CaCO3: ·(t) Antacid
I05. (a) Gypsum is used fo r making fireproof wa lI boards 118. (a) The fo llowi ng components are present in Portland
because it is fire resistant. cement:-
106. (d) Gyp sum is used to increa se the settin g tim e of Dicalcium si licate = 26%
cem ent.
Tricalci um si licate =· 51%
2
107. (a) Ch lorophyll : Mg+ complex Tricalcium aluminate = 11 %
- - - - - - - - - - - - - - - - - -- - - - - - - - - - - - - The s-Block Elements

Hence, the major % is of tricalcium silicate, among all. Plaster of paris CaSO/ ½H2O o.s
11 9. (b) 3Cai PO 4) 2.Ca(OH) 2 or Ca 1/ PO 4) 6(OH) 2 is Dead burnt plaster CaSO4 o
Hydroxyapatite. During contact with water dissolved 121. (a) On beating at 393K, gypson gives CaS04 • 0.Sf\o
is F- ion, it gets converted into 3Ca/PO4)2'CaF2•
I
120. (c) Gypsum 393K ►.CaSO4 ·2H2O
Formulas Number of
water
molecule 122. (b) (A) Ca(OH)2 is used in white washing
Gypsum 2 (B) Plaster of paris is used in making of molds1ror
plaster statues.
-------
JEE PYQs Chemistry - - - - - - - - - - - - - - - - - - - -
The p-Block Elements
(a) Strong ionic bond in Boric acid

Group 13 Elements ·
The Boron Family
I. The incorrect statement from the following for borazine

15:
J
[13 April, 2023 (Shift-DJ
6.
(b) Strong van der Waal's interaction in Boric acid
(c) Strong hydrogen bond in Boric acid
(d) Strong covalent bond in BF3
Given below are two statements:
Statements-I: Boron is extremely hard indicating its high
lattice energy
(a) It bas electronic delocalization Statements-U: Boron has ·highest melting and boiling
(b) It contains banana bonds point compared to its other group members.
(c) It can react with water [12 April, 2023 (Shift-DJ
(d) It is a cyclic compound In the light of the above statements, choose the most
appropriate answer from the options g iven below:
2. Given below are two statements:
(a) Statement-I is incorrect but Statement-II is correct
Statement-I: Upon heating a borax bead dipped in cupric (b) Both Statement-I and Statement-II is correct
sulphate in a luminous flame, the colour of the bead
(c) Statement-I is correct but Statement-II is incorrect
becomes green.
(d) Both Statement-I and Statement-II is incorrect
Statement-CI: The green colour observed is due to the
7. The covalency and oxidation state respectively of boron
formation of copper(I) metaborate.
in [BFJ, are (13 April, 2023 (Shift-IT))
[31 Jan, 2023 (Shift-U)J (a) 4 and 3 (b) 4 and 4
In the light of the above statements, choose the most (c) 3 and 4 (d) 3 and 5
appropriate ar1Swer from the options given below: 8. Choose the correct stability order of group 13 elements in
(a) Both Statement-I and Statement-II are true their + I oxidation state. [26 June, 2022 {Shift-DI
(b) Statement-I is true but Statement-II is false (a) Al < Ga < 1n < TI (b) Tl < In < Ga < Al
(c) Both Statement-I and Statement-II are false (c) Al < Ga < TI < ln (d) Al < TI < Ga < In
(d) Statement-I is false but Statement-II is true 9. Given below are two statements. One is labe lled as
3. Group-1 3 elements react with 0 2 in amorphous form to Assertion (A) and the other is labelled as Reason (R)
form oxides of type M,O (M = element). Which among the Assertion (A): Boron is unable to form 3 BFt
- J
following is the most basic oxide? (6 April, 2023 (Shift-ID) Reason (R): Size ofB is very small.
(a) Alp (b) Gap3 [27 July, 2022 (Shift-II))
3
(c) TI1 0 3 (d) Bp 3
4. The Lewis acid character of boron tri halides fol lows the
(a) Both (A) and (R) are true and (R) is the correct
order : (31 Jan, 2023 (Shift-ID)
explanation of (A)
(a) BBr3 > Bl > BCl > BF (b) BCl > BF > BBr > BI
3 3 3 3 3 3 3 (b) Both (A) and( R) are true and (R) is NOT the correct
(c) BF3 > BCl > BBr3 > Bl 3 (d) BI > BBr > BCl > BF explanation of (A)
3 3 3 3 3
5. Boric acid is solid, whereas BF3 is gas at room temperature (c) (A) is true but (R) is false
because of [30 Jan, 2023 (Shift-[D) (d) (A) is false but (R) is true
10. Given below arc two statements. 14. In which one of the following molecules, stronge~tJ
donati on of an electron pair from hal ide to bOrrin~I
Statement-I: The chlorides ofBc and Al have Cl-bridged
structure. Both arc soluble in organic solvents and act as expected? 127 Aug, 2021 (Shirt./'
Lewis bases. (a) 8Br3 (b) BFJ !I
(c) BCl 3 (d) BIJ
Statement-II: Hydroxides ofBe and Al dissolve in excess
alkali to give beryllate and aluminate ions. 15 The correct statements among I to Ill regarding group
• . • 11
In the light of the above statements, choose the correct element oxides are 19 April, 2019 (Shirt.,
. . .d. IJI
answer from the options given below. (I) Boron trioxide 1s ac1 1c.
127 July, 2022 (Shift-1)1 (II) Oxides of aluminium and gallium are amphoteric
(a) Both Statement-I and Statement-II are true. (III) Oxides of indium and thallium are basic. ·
(b) Both Statement-I and Statement-II are false. (a) (I), (II) and (III) (b) (II) and (Ill) only
(c) Statement-I is true but Statement-II is false. (c) (I) and (III) only (d) (I) and (II) only
(d) Statement-I is false but Statement-II is true. 16. The relative stability of+ I oxidation state of grollp 11
11. Outermost electronic configuration of a group 13 element,
elements follows the order: Ill Jan, 2019 (Shift-DI
E, is 4s2,4p 1.The electronic configuration of an element of . (a) Al < Ga < Tl < Ln (b) Tl < ln < Ga <Ai
p-block period-five placed diagonally to element, Eis: (c) Ga <Al < Ln < Tl (d) Al < Ga < ln <TI
120 July, 2021 (Sbift-Il)I 17. The electronegativity of aluminium is similar to
(a) [Kr] 4d 10 5s2 5p2 (b) [Kr]3d 10 4s2 4p2 [10 Jan, 2019 (Sbift•DI
(c) [Xe] Sd 10 6s2 6p2 (d) [Ar] 3d 10 4s2 4p2 (a) Carbon (b) Beryllium
12. Given below are two statements : one is labelled as (c) Boron (d) Lithium
Assertion (A) and the other is labelled as Reason (R). 18. The number of2-centre-2-electron and 3-centre-2-electron
Assertion (A): In Tll 3, isomorphous to Csl 3, the metal is bonds in 8 2H6, respectively, are:
present in + I oxidation state. [10 Jan, 2019 (Sbift-Il)[
Reason (R): Tl metal has fourteen f electrons in the (a) 2and I (b) 4and2
electronic configuration. [26 Feb, 2021 (Shift-II)[ (c) 2 and 2 (d) 2 and 4
In the light of the above statements, choose the most 19. Aluminium is usually found in +3 oxidation state. In
appropriate answer from the options given below: contrast, thallium exists in + I and +3 oxidation states.
(a) (A) is correct but (R) is not correct This is due to 19 Jan, 2019 (Shift-DI
(b) Both (A) and (R) are correct but (R) is NOT _the (a) Inert pair effect
correct explanation of (A) (b) diagonal relationship
(c) (A) is not correct but (R) is correct (c) Lattice effect
(d) Both (A) and (R) are correct and (R) is the correct (d) Lanthanoid contraction
explanation of (A)
13. Match List- I with List-II:
List- I List-ll · Some Important Compounds of
(A) NaOH (I) Acidic Group-13 Elements
(B) Be(OH)2 (II) Basic
(C) Ca(OH\ (111) Amphoteric 20. During the borax bead test with CuSO4, a blue green
(D) B(OH)i colour of the bead was observed in oxidising 0anie due
to the formation of [29 Jan, 2023 (Shift-Ill
(E) Al(OH\
Choose the most appropriate answer from the options (a) Cu3B2 (b) Cu
given below: [27 July, 2021 (Shift-I)[ (c) Cu(BO1) 1 (d) CuO
(a) (A)-(11), (8 )-(1), (C)-(11), (D)-(111), (E)-(111) 21. Lithium aluminium hydride can be prepared froni ihi
(b) (A)-(11), (8)-(111), (C)-(11), (D)-(1), (E)-(111) reaction of 130 Jan, 2023 (Shift-lJI
(c) (A)-(11), (8 )-(11), (C)-(11]), (D)-(11), (E)-(111) (a) LiCI and Al2H6 (b) LiH and Aip 6
(d) (A)-(11), (8)-(11), (C)-(111), (D)-(1), (E)-(111) (c) LiCI, Al and H1 (d) LiH and Al(OH)i
164 '
' i\;,
(h) (C) only
22 . If the formula of Borax is Na 28 4O,(OH) ,- zHp , then (a) (/\) on ly
x +y + z = 113 April, 2013 (Shift-11)1 (c) (A) and (B) on ly
(rf} (C) and (D) onl y
23 . Number of electron deficient molecules among th e 30. The correct statement about B/l6 is: .
following PH 1, B2H6, CC1 4, NH 3, LiH and BCl is: 125 Feb, 2021 (Sh1ft-J)I
3
125 June, 2022 (Shift-1)1 (a) All 8 _ H _ Bangles are of l 20°.
(a) 0 (b) I (b) The two 8 - H - B bonds are not of ~ame length .
(c) 2 (d) 3
(c) Its fragment, BHJ, behaves as a Lewis base.
24. Bora zine, also known as inorganic benzene, can be (d) Terminal B - H bonds have less p - character when
prepared by the reaction of 3- equivalents. of "X" with
. 1en t s of "Y" . "X" and "Y" , respective
· 1y are:
compared to bridging bonds.
6- eqmva f
31. The reaction ofHJNJBP/ A) with LiBH4in tetrahydrofuran

[26 July, 2022 (Shift-1)1
gives inorganic benzene (8).
(a) B(OH\ and NH 3 (b) B2H6 and NH 3
Further, the reaction of (A) with (C) leads to HJNJB/ Me\.
(c) 8 2H6 and HN 3 (d) NH 3 and Bp 3
Compounds (B) and (C) respectively, are:
25. When borax is heated with CoO on a platinwn loop, blue . [9 Jan, 2020 (Shift-JI)]
coloured bead fonned is largely due to
(a) Borazine and MeBr (b) Boron nitride and MeBr
[29 July, 2022 (Shift-II)]
(c) Diborane a~d MeMgBr (d) Borazine and MeMgBr
(a) B20 3 (b) Co(BO2) 2
32. Diborane (B H ) reacts independently with 0 2 and Hp
(c) Co8 40 7 (d) Co[Bp 5(OH\]
to produce, r~s;ectively (8 April, 2019 (Shift-I)!
26. Identify the correct statement for B2H6 from those given
(a) HBO 2 and H38O 3 (b) H3BO3 and Bp 3
below: (24 June, 2022 (Shift-1)1
(A) ln B2H6, all B-H bonds are equivalent (c) Bp3 and H38O3 (d) Bp 3 and [BHJ
(B) ln B2H6, there are four 3- centre 2- electron bonds
(C) B2H6 is a Lewis acid Grou~ 14 Element~ _
(D) B2H6 can be synthesized from both BF 3 and NaBH 4
_J
(E) B2H6 is planar molecule
given below:
(a) (A) and (E) only
.
Choose the most appropriate answer from ·the options
(b) (B), (C) and (E) only

----·- The Carbon Famil~-
33. The correct order of bond enthalpy (kJmol-1) is: .

(1 Feb, 2023 (Shift-II)]
(c) (C) and (D) only (d) (C) and (E) only (a) Si - Si > C - C > Sn - Sn > Ge - Ge
27. The geometry around boron in the product 'B' formed from (b) Si-Si > C-C > Ge-Ge > Sn - Sn
the following reaction is BF3 + NaH 45 0K A+ NaF (c) C- C > Si - Si > Sn - Sn > Ge- Ge
A+ NMe 3 -----t B [25 July, 2022 (Shift-1)1 (d) C - C > Si - Si > Ge - Ge > Sn - Sn
(a) Trigonalplanar (b) Tetrahedral 34. Given below are two statements, one is labelled as
(c) Pyramidal (d) Square planar Assertion (A) and the other is labelled as Reason (R).
28. Aqueous solution of which of the following boron Assertion (A): Carbon fom1s two important oxides -CO
compounds will be strongly basic in nature? and CO 2.CO is neutral whereas CO2 is acidic in nature.
(29 June, 2022 (Shift-II)] Reason (R): CO 2 can combine with water in a limited
(a) NaBH 4 (b) LiBH 4 way to form carbonic acid, while CO is sparingly soluble
(c) B2H6 (d) Na 2Bp1 in water.
29. Given below are the statements about diborane. In the light of the above statements, choose the most
(A) Diborane is prepared by the oxidation of NaBH 4 appropriate answer from the options given below:
With 12• 125 Jan, 2023 (Shift-11)1
(B) Each boron atom is in sp 2 hybridized state. (a) Both (A) and (R) are correct but (R) is NOT the
(C) Diborane has one bridged 3 centre - 2 - electron correct explanation of (A).
bond. (b) Both (A) and (R) are correct and (R} is the correct
(D) Diborane is a planar molecule. explanation of (A).
The option with correct statement(s) is : (c) (A) is not correct but (R) is correct.
[22 July, 2021 (Shift-II)] (d) (A) is correct but (R) is not correct.
35. The compound wh ich does not exist is (b) The five- membered rings are fu sed only to .
. six.
11 0 April, 2023 (Shift-l)l membered rings
(a) Napi (b) (NH 4\ BeF4 (c) The six-membered rings are fused to both six
and
(c) BeH , five-memebered rings
(d) PbEt4
36. Gi\'en below are two statements. (d) · 11 contains 12 six-membered rings and 24 fi ve.
membered rings
Statement-I: Stannane is an example of a molecular
42. The element that does NOT show catenation is:
hydride.
112 Jan, 2019 (Shift-II)
Statement-Tl: Stannane is a planar molecule.
(a) Ge (b) Si I
In the light of the above statem'ent, choose the most
(c) Sn (d) Pb
appropriate answer from the options given below.
43. The correct statement among the following is
129 July, 2022 (Shift-1)1
(a) Both statement-I and Statement-II are true.
[12 April, 2019 (Shift-DJ
(a) (SiH ) N is pyramidal and more basic than (CH) N
(b) Both statement-I and Statement-II are false. J J JJ
(b) (SiH 3) 3 N is planar and more basic than (CHJ N
(c) Statement-I is true but Statement-II is false. 1
(c) (SiH 3\ N is pyramidal and less basic than (CH ) N
(<i} Statement-I is false but Statement-U is true. 11
(d) (SiH)3 N is planar and less basic than (CH 3) N
37. Match the List-I with List-II. 3
·44. Correct statements among (i) to (iv) regarding silicones
List-I List-II
are
(Metal) (Application) (i) They are polymers with hydrophobic character
(A) Cs (I) High temperature (ii) They are biocompatible
thermometer
(iii) In general, they have high thermal stability and low
(B) Ga (II) Water repellent sprays dielectric strength
(C) B (III) Photoelectric cells (iv) Usually they are resistant to oxidation and used as
(D) Si (IV) Bullet proof vest greases. 19 Jan, 2019 (Shift-DJ
Choose the most appropriate answer from the options (a) (i), (ii), (iii) and (iv)
given below: 129 June, 2022 (Shift-l)I (b) (i), (ii) and (iii)
(a) (A)-(IU), (B)-(I), (C)-(IV), (D)-(II) (c) (i) and (ii) only
(b) (A)-(fV), (B)-(lll), (C)-(11), (D)-(1) (d) (i), (ii) and (iv)
(c) (A)-(lf), (B)-(III), (C)-(TV), (D)-(I) 45. The element that shows greater ability to form pn - pn
(d) (A)-(1), (B)-(IV), C)-(11), (D)-(III) multiple bonds, is : 112 Jan, 2019 (Shift-tnl
38. The oxide that gives H20 2 most readily on treatment with (a) Sn (b) C
8i0 is: 127 Aug, 2021 (Shift-11)1 (c) Ge (d) Si
(a) Nap2 (b) Ba02·8Hp 46. The correct order of catenation is:
(c) Pb0 2 (d) Sn02 110 April, 2019 (Shift-I)!
39. Wruch one of the following compounds of Group-14 (a) C > Si > Ge :::: Sn
elements is not known? 125 July, 2021 (Shift-1)1 (b) C > Sn > Si~Ge
(a) [GeCJJ- (b) [Sn(OH\]2- (c) Ge > Sn > Si > C
(c) [SiFJ- (d) [Siciy - (d) Si > Sn > C > Ge
40. Ge (Z == 32) in its ground state electronic configuration 47. C60, an allotrope of carbon contains:
has x completely filled orbitals with m, == 0. The value of 19 April, 2019 (Shift-I)!
xis__ 131 Aug, 2021 (Shift-I)! (a) 20 hexagons and 12 pentagons
41. The INCORRECT statement regarding the structure of Cw (b) 12 hexagons and 20 pentagons
is: 116 March, 2021 (Shift-11)1 (c) 18 hexagons and 14 pentagons
(a) Each carbon atom forms three sigma bonds (d) 16 hexagons and 16 pentagons
1
166 ·
48_ The chloride that CANNOT get hydrolysed is:
(a) PbCl4
(c) SnCl4 (d) SiCl
4
Ill Jan, 20 19 (Shift-1)1
(b) CCl
4
Some Important Compounds
of Carbon & Silicon
j
49, Choose the conect statement(s) among ti , II .
1e 1o owing.
IJEE Adv 20201 52. Match the List-I with List-II.
(a) SnCl2.2H2O is a reducing agent
List- I List-II
(b) SnO 2r~acts with KOH to fonn ~[Sn(OH) J (Si-Compounds) (Si-polymeric/Other
(c) A solution of PbCl2in HCI contains Pb2+and Cl- ions Products)
(d) The reaction of Pb3O4 with hot di'ltit·e - . 'd (A) (Cl-l 3) 4Si (I) Chain Si licone
• • 111 1nc ac, to
give PbO21s a redox reaction (8) (CH 3)Si(OI-I\ (11) Dimeric Silicone
(C) (C1-1)2Si(OH)2 (111) Silane
( Allotropes of Carbon
_J (D) (Cl\)3Si(OI-I) (IV) 2D- Silicon
127 June, 2022 (Shift-1)1
50. The C-C bond length is maximum in (a) (A)-(111), (8)-(11), (C)-(J), (D)-(IV)
(b) (A)-(IV), (B)-(1); (C)-(LI), (D)-(111)
11 2 April, 2019 (Shift-11)1 (c) (A)-(U), (B)-(1), (C)-(IV), (D)-(111)
(a) Graphite (b) C
70 (d) (A)-(111), (8)-(IV), (C)-(1), (D)-(11)
(c) Diamond (d) C 53. The basic structural unit of feldspar, zeolites, mica and
60
51. The number of pentagons in C and trigons (triangles) in asbestos is: 127 June, 2022 (Shift-I))
60
white phosphorus, respectively are: (a) (SiOJ}2- (b) SiO2
110 April, 2019 (Shift-JD! R
(a) 12and3 (b) 20and4 (c) (SiO 4 )4"
I
(d) --fSi-Ot-
(c) 12 and 4 (d) 20 and 3
k (R=Me)
• \ ANSWE
\ R KEY \\ •
I. (*) 2. (c) 3. (c) 4. (d) 5. (c) 6. (b) 7. (a) 8. (a) 9. (b) 10. (d)
l l. (a) 12. (b) 13. (b) 14. (b) 15. (a) 16. (d) 17. (b) 18. (b) 19. (a) 20. (c)
21. (b) 22. [ I7] 23. (c) 24. (b) 25. (b) 26. (c) 27. (b) 28. (d) 29. (a) 30. (d)
31. (d) 32. (b) 33. (d) 34. (b) 35. (a) 36. (c) 37. (a) 38. (a) 39. (d) 40. [7]
41. (d) 42. (d) 43. (d) 44. (d) 45. (b) 46. (a) 47. (a) 48. (b) 49. (a,b,c) 50. (c)
51. (c) 52. (d) 53. (c)
The p- Block Elements

\ ___E_
XP_lA_NI_II_ON_S_ _
\ "--
S ------~
I. (*) The chemical fommla ofBorazine is B3NJ H6 and its S. (c) In contrast to BF3, boric acid possesses strong hydr
chemical structure is bonds. Therefore, boric acid is solid . ogen
H 6. (b) Boron is non- metallic in nature. It is extremely h
le and black coloured . so I'd s· .
1 • mce its atoms are so r
ard
H '-.. e ~B'---._ e /H boron has a high melting point of 2352 Kand foiny,
N_,,. N
J B~
lie
B
strong covalent bonds with other atoms. Due to ~s
closest packing of boron atoms in its solid state, it lak~
H/ " l / '-.. H a lot of heat to break the bonds between boron atoms
H
I
B
Element
Al
----
r--
From the structure, it can be concluded that it has Ga In TI
electronic delocalization and is a cyclic compound. ----
Tile reaction wjth water takes place as:
B3N3H6 + 9Hp ➔ 3NH3 + 3H3BO3 3H 2 +
Melting point/K
Boiling point/K
2453 933 303
3923 2740 2676 2353 1730
430
7. (a) Number of covalent bon~ formed by Boron ts 4. This

--
576
NTA ans key ➔ (c) · is shown in the following structure.

PW ans key ➔ (b)
F
2. (c) Boric anhydride forms metaborate on treatment I
with metal salt which produces different colours in B
oxidizing as well as reducing flames. F/ I ""-F
1n the case of copper sulphate (CuSO 4), the following F
reaction will take place: Oxidation number of fluorine is - 1 ,
CuSO + B O Non-luminousflame C (BO ) + SO
4. 2' 3 (Oxidising) U . 2 2 3 Oxidation number of B +4 x (-1) = -1,
Cupnc metaborate
-blue- green Thus, _Oxidation number of Boron is +3
Two reactions will occur in "the presence of reducing 8. (a) Due to inert pair effect, in boron family, lower O.S.
flame (Luminous flame) (+I) becomes more stable down the group.
I 9. (b) Both Assertion (A) and Reason (R) are true but Ris
(i) The blue-green colour due to Cu(BO2\ becomes
colourless due to cuprous melaborate as: not correct explanation of A. Expension of octet not
possible for Boron due to unavailability of d-orbital.
Luminous
flame
Therefore, BF/- is not possible.
10. (d) Chlorides of Be and Al are electron-deficient in
2CuBO2 + Na 2Bp1 + CO nature and hence act as lewis acid.
(ii) Cupric metaborate may be reduced which 11. (a) The given electron configuration is of Ga and ins~
results in the metallic copper and bead appears period, diagonally situated element will be Sn with
red opaque.The reaction is: respect to Ga. Hence, electronic configuration of Sn is:
Luminous
[Kr] 4d 10 5s 2 5p2
flame 12. (b) Both (A) and (B) are correct but R is not correct
2Cu8O2 + 2Na2Bp1 + 2CO explanation of A. Both TI J and Cs! J has + I oxidation
3. (c) As we move down the group, basic character of oxide state as well as have similar lattice structure.
13. (b) NaOH- Basic Ca(OH), - Basic
increases.
B2O3 < Al,0 3 < Gap3< Inp 3> Tlp3 Be(OH)2 -Amphoteric B(OH) l ~ Acidic
.
~ L-- ----- . Al(OH \ - Amphotenc
acidic amphoteric basic
14. (b) The type of back bonding in the following boron
4. (d) Down the group, extent of back bonding decreases halides are:-
and tendency to act as Lewis acid increases. BF3 BCl BBrl Bil
BF3 > BCl 3 > 8Br3 > 81 3 (extent of back bonding) (2pn - 2pn) (2pn - 3~n) (2pn - 4pn) (2pn - 5p71)
( 2p- 2p) (2 p- Jp) (2 p- 4p) (2 p- 5p) Therefore, the order of back bonding strength:
Bf3 < BC1 3 < BBrl <Bil (lewis acidic nature) BF3 > BC1 3> BBr3> Bil
s. (a) All the given statements regarding group -I Jore wn-c<.:1
Bl O1 ~ Acid
27. (IJ) 21H\ 6Na lf
1 1111
}
►
f,
I 6Na l·
I ic
.
II } If ,, 1 2N (Me)1 ► 211 1H ( :N( McJi
Al p 1, Ga 20 1 --> Amphoteric
Geometry of'lf 11J ' :N(McJ1 , ~ Tetrahedral :
ln 2O1, Tlp 1 --> Basic Mc
16. (d) Inert pair effect gradually increases clow n the group. Mc Mc I
Hence stabi lity oflower O.S. increases clown the group. '-:N/
17. (b) E.N. of Al is same as th::il or Be clue lo presence or
Diagonal Relati onship.
t
u
. - - - 2c-2e- 11/l '- 11
H ... II . /~H
18. (b)
"/ B,_. '
..B"
II
28. (d) The borax makes basic buffer solution ·
· man aqu eous
H '· H ··1 H medium .
3c-k bond 29. (a) Diborane can be prepared by the reaction ofNaBH4
with 12•
l9. (a) The outer most electroni c co nfigurati on or Tl is
2 1
6s 6p • 6s electrons are strongl y atlraclecl towards 2NaBH 4 + I2 - >2Na l + H2 + B2H6
the nucleus due to its more penetrating power and 30. (d) The structure of B2H6 is:
deshielding or d and r-electrons, Hence, 6s-electrons -- -Hb•••
do not participate in bonding. H, ~ -- --------- - ···· ·..•... ~ H,
20. (c) Blue green colour is produced due to formation or /a·........ -----------B----
Cu(BO) 2 1-1,/ . ····1-1b---- H,
CuSO 4 -4CuO +SO 3 Angle of Terminal 8-H bonds > Angle ofBridge bonds
CuO + Bp 3
-+ Cu(BO 2) 2 I
Also Bond angle ex.% S-Character oc fp h
21. (b) Lithium aluminum hydride can be prepared by the ' % o -c araccer
reaction of lithium hydride with aluminum hydride. 31. (d) B3N3Hp 3
+ LiBH 4 ~ 8 3N3H6
The reaction involved is given as, (B)
8LiH + Alp 6 ➔ 2LiAIH 4 + 6LiCI Inorganic Benzeru:
or Borazine
22. [17] The chemical fom1Ula of borax is Na2BpiOH\-8Hp.
Therefore, the va lue of x == 5, y == 4, z == 8 B3N3Hp + MeMgBr ~ 8 3N3H/ CH3) 3 + 3MgBr
32. (b) B2H6 + Hp ~ 2H 3BO 3 + 3H2
.". X + y + Z == 17
23. (c) Electron deficient species have less than 8 electrons

H
B2 6 + 302 ~ Bp 3 + 3Hp
33. (c~ (Bond enthalpy order C - C > Si - Si > Ge - Ge >
(or two electrons for H) in their valence (incomplete Sn - Sn)
octet) B2H6, BCl3, have incomplete octet.
As we move down the group, bond length increases
24. (b) 3B2H + 6NH hi ghlemj,cr.iiu rc 2B N H + 12H and bond enthalphy decreases.
6 3 3 3 6 2
(Diborane) (Borazine) 34. (b) The oxide which fo rms acid when dissolved in water
25. (b) A blue colour Bead is cobalt (11) meta borate. is an acidic oxide.
Na 28 4O7 · I0H 2O ~ Na 2 8 4O7 + I0H 2O 35. (a) Sodium superox ide is not stable. It exists as sodium
peroxide (NapJ
36. (c) Stannane has the tetrahedral shape and its hybridisation
is sp3.
2NaBO 2+ Bp H
3
I
~
Co(BO2)2 CoO
6
H/1'\ H
H
26 ' (c) B2H6 has two 3 centre-2-electron bonds. In B2H6,
37. (a) Cs is utilized in maki ng photoe lectric cells. Boron
bridge bonds have greater bond length as compared
to terminal bonds. Also, bridge bonds lie in one plane fibres are L1sed in producing bullet - proof vest.
Silicones are wa ter repelling in nature as they are
while terminal ones lie in perpendicular plane.
surrounded by non-polar alkyl groups.
It is an deficient species and hence, act as a Lewis acid.
Ga llium is less poisonous and has a ve ry hi gh
3NaBH 4 + 4BF 3 ~ 3NaBF 4 + 2B 2H6 temperature thermometers.
, 169
38. (a) The reactions of various oxides wi th 1\0 are: 46. (a) As wc move down the group, bond strength deer
. eaSe1
thereby decreasing the catenation tendency. ,
( I) Na,O2 + 2H p ~ 2NaOH + 1\02
(2) BaO 2-8Hp gives H10 1 after evaporation Hence, the order is as expected
(3) PbO, + 2H1O ~ Pb(OH\ C > Si > Ge:::: Sn
(4) SnO 2 + 21\0 ~ Sn(OH\ 47. (a) 60 allotropes of carbon is fu llerene which contain,
20 hexagons and 12 pentagons
Hence. only Na 1O2 given H2O2 most readi ly with ~O.
48. (b) Central atom does not have vacant orbital
39. (d) [SiCIJ 2 is not known because Si cannot accommodate
49. (a,b,c)
six large chloride ions due to its small size.
SnCl2.2Hp is a reduci ng agent si nce Sni. tends
40. [7] The electron configuration of Ge is 10
convert Sn4" .
1s1 2s2 2p6 3s 2 3p6 4s 2 3d 10 4p 2
(b) SnO 2 + 2KOH (aq) + 2Hp~ ~[Sn(OliJJ
m, = 0 (for 4s, 3s, 2s, Is) 4 orbital (Amphoteric)
m1 = 0 (one p orbital of 2p and 3p) (2 orbitals)
(c) Filterate of first group contain solution of PbCJ
m1 = 0 (one d orbital) (I orbital) in HCl which contains Pb 2+ and Cl- 2
Total orbitals = 7 However in cone. HCI it produces HJPbCIJ

41. (d) All C- atoms have identical hydrogen in C
60 (d) Pbp4 +4HNO3 ~Pb<\ t+2Pb(NOJ2 +28io
molecu les.There are three sigma bond and 20 six (2PbO.PbO) .
members and 12 five membered ring. It is not a redox reaction
42. (d) Pb does not show catenation property.
50. (c) In diamod C--C bond have only bond character while
43. (d)
in case of graphite and fullerence (C 60 and C7J C-{:
(ill bond contain double bond character. That's why
(a) N........_. . 3
hybrid and diamond having maximum C-C bond length.
/ \ CH 3mtrogen is sp
51. (c) Structure is shown below:
CH3 CH 3 p
pyramidal no back-bonding i.e. more basic
(b) H3Si == N
.;7SiH3 . .
2
. I\
P--p
...,.,_, SiH N Nitrogen sp hybnd and
3
planar due to back bonding and less basic \pI
because lone pair is not available for donation. Hence, it contains 4 trigons.
44. (d) Silicones are polymers with (-~Si-0-) linkage,
In C60 , there are 12 pentagons and 20 hexagons.
they are hydrophobic and biocompatible.
52. (d) Silane is (CH 3) 4Si. 2-D silicone is produced after the
They are also resistant to oxidation and are used in removal of water from CH 3Si(OH) 3• Chain fonn is
greases.
produced from (CH 3) 2 Si(OH\. Dimer is produced
45. (b) It is due to the smallest atomic size of carbon in the from (CHJ 3 SiOH after releasing water molecule.
given options. Small size greater pn:-pn: multiple 53. (c) The basic structural unit of fe ldspar, zeolites, mica
bonds. and asbestos is (SiO/-.
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Some Basic Concepts

compound 2 is PQ), then the

1. Which of the following have same number

(Given : Atomic weights are, H,lu; C,12u;0, 16u)

2 JEE PYQS Chemistry

Some Basic Concepts of Chemistry 5

6 JEE PYQs Chemistry

1. (c) To determine the no. of significant figures certain 5. (b,c)

3. (3] In 0.00340, number of significant figure is 3. formula =P,Q,

Some Basic Concepts of Chemistry

(: Moo,= 64 g/mol) 10.8× 250

JEE PYQs Chemistry

t=0 56L Excess 0

Atoms of Mg = 24.08 x1020 % yield = 50%

20. [2] According to question, molecular weight of A,B = 0.3n

Some Basic Concepts of Chemistry

C H0,4c0,- SH,0 Mole of Fe =

10 JEE PYQs Chemistry

50×5.0 (Molar mass of H,0= 18g mol)

2.6315x I000 Number of moles ofH=2 x no. of moles of H,0 =

Some BasicConcepts of Chemistry 11

Hence, empirical formula is CH_N and empirical mass W

Therefore %of carbon in compound is:

12 JEE PYQs Chemistry

Mass of Oxygen x 100

Given weight of C0, 420

Some Basic Concepts of Chemistry 13

According to the reaction,

14.2 14.2 Imole of gas at STP+22.4 litre

Hence, Empirical formula =CH, - 22.4 litre =224 x10 litre

14 JEE PYQs Chemistry

8.40 According to the reaction

67. (2] X + Y + 3Z = XYZ

Some BasicConcepts of Chemistry 15

0.2x 200-200 x 0.1 0.210

+CH,NHC,H, 7.8x 74 100

Theoretical moles of m-bromobenzoic acid = 0.0S

Produced mole of nitrobenzene

() CHC, NaOH/A, CHO Imole 3mole

Mass of H,0= 495g H,Ç CH,

18 JEE PYQs Chemistry

4. If the Thompson model of the atom was correct, then the

21. A source of monochromatic radiation of wavelength (b)

22 JEE PYQs Chemistry

(24 Feb, 2021(Shift-I)] 2a, 4a,

24 JEE PYQs Chemistry

26 JEE PYQs Chemistry

(IV) n= 3, l=1, m,= 1, m, =

28 JEE PYQs Chemistry

J2xmxqx V =0.2 = 2 x10-!

30 JEE PYQS Chemistry

Given: = 1000 nm =10³ x 10- m= 106 m p' hc hc

32. («) Aconding to Bohr's model the angular momentum n

with number of shell (n) that is, V, «(z=

kqj42 kZe n2 a, x4 4a,

hence Lyman and Paschen (b) is corrcct. n nxZ

Given Z=2 for He

For I mol =-4.355 x 102 x 6.023 x 10

Y3p 102. (b) According to (n + ) rule: 3p < 3d<4p < 4d

3. TheIUPAC nomenclature of an element with electroni

clements, The graph whích represcnts his observation

40 JEE PYQs Chemistry