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Assignment(C)

FIITJEE IUPAC NOMENCLATURE

I. Give IUPAC name for each of the following:

I
2 COOH
C
|
O
|| 3 Chloro
N  CCH z one
1. 2 2. CH3  CH C CH3
z Batan
2 Tano Ethanol'carid
y
Br
|
3.
3
CH
2 I
 CH CH C 4. CH3 CH2  C HCOOH
3 2
|
2 07 2
OH
1 ChloroPropan 43 Butanoic
OCH3
| 3 metazoan 2 132030 acid
5. CH3  CH  CH2  CHO 6. CH3  CH  CH  CH  CH2
4 3 2 5 4 3
O
||
Boomopopan 2 one8. CH4 3 a
pinta 113
7. CH3  C CH2  Br i 2 OHCH2 CH2 CH2 OH diene
9. 3 2
HOCH2CH2CH2COOH 10. CH3 CHCH Butane
COOCH in diol
2 3
|
Br32
i
43 2
4 hydroxyguntnoic y
3CHBromometry
11. 56
32 2COOH
HOOCCH2 CHCH
|
12.  CCH CN 2
Butanoate
OH y 32
O
3 hydntioicanid But imitate
14. 3 2
pentane
 CH  CHCCH COOCH
||
2 3 15. Fyne
CH2  CHCH2CH2 CCH3
||
5 43 3 0 0
metyemeth z one
O
ex s ene
16. CH3 CH  CH2CH2 CHCH2CH3
|
NHo tu
|
OHsa
Pentanoate 17. CH3 CH  CHCHO
z
2
amino Heptan 2 01 y
CHG
CHO 2 But z ene t al
r|
18. CH3  C  C 19. CH2  CHCOOH
|
3 chloro 3 metal
3ps b l oic
CH3

Butanol a ene
C
| acid
20. C  Cr COOH 21. CH2  CH  CH  CH  CH  CH2
|
C 2 2,2 toi chloro o 5 4 3 2 I
Ethanoicacid sizes tiene
CH3
| Hera
22. CH3  C  C  N 23. I  C2  CH CH
CH 2 2 3
| |
3 HCCH3
Ethy
CH3
2
3
|
2,2 dimethyl propane nitrile
CH3
3 metry
C OH But i CH3 em
| | |
24. C  C i C i OH 25. CH2  CHCH2  CHOH
| |
us a
C H s
21212 triathlon Ethane i i de'd CH2CH3
|
Pent Ipe
26. CH2  CH  C  C  CH2OH 28. CH3 Cz CH2OH
|
3 2
5 no
CH3

pent e ere
OH
|
z une 2 2 dimethyl
CH
|
Item 3

29. CH3 OCH2CH2 CHCH2C 30. CH3 CHOHCH2  C  OH


| z
4 3 21 s y y CH3
e calorggaramethox Baton 2
31. CH3  CH CH2  CH  CHO 32. CH3metal
2 pentane'd
CH  OH CH2 CH2 COOH
| |
5 OH CH3
5 4 32 1
FIITJEE (Hyderabad Classes) Limited.
2 intense 4 hydroxy
a hydroxy
l an pentanoicaid
Assignment(C)
FIITJEE IUPAC NOMENCLATURE

O
||
33. CH3  CH  CH  CH  CH2  C OH 34. CH3 CH2CH  CHCOOH
|
CH3

O
NH2
|
35. CH3 CH  CHCH2 CH CH2COOH 38. Br
O
CHO COOH

39. Br 40. COOH

CH 2COOH
41. 42. CH3 CHCH2 CH CH3
| |
CN C
CH 2COOH

C(OH)COOH
CH3
|
43. CH3 CH C  C O  CH3 45. CH 2COOH
| | ||
Br OH O
46. CH2  C C  C  CH COOH 47. C CH2  CH CH CH3
| | | |
H CH3 OH OH
Br CH3
O

48. HOOC  CH  CH  COOH 49.

50. H5 C2 O C CH2 CH2 C OC2H5


|| ||
O O

Answers
1. 2-Cyanoethanoic acid
2. 3-chloro-butan-2-one (or) 3-chloro-2-butanone
3. 1-chloropropan-2-ol (or) 1-chloro-2-propanol
4. 2-Bromobutanoic acid
5. 3-methoxybutanal
6. penta-1,3-diene (or) 1,3-pentadiene
7. 1-Bromopropanone
8. Butane-1, 4-diol (or) 1,4-Butanediol
9. 4-Hydroxybutanoic acid
10. Methyl-3-bromobutanoate
11. 3-Hydroxypentane-1, 5-dioic acid (or) 3-hydroxypentanedioic acid
12. But-3-yne-1-nitrile (or) 3-Butyne nitrile
14. Methyl-4-methyl-3-oxopentanoate
15. Hex-5-en-2-one (or) 5-Hexen-2-one
16. 6-Aminoheptan-3-ol (or) 6-Amino-3-heptanol

FIITJEE (Hyderabad Classes) Limited.


Assignment(C)
FIITJEE IUPAC NOMENCLATURE

17. But-2-en-1-al (or) 2-Butenal


18. 3-Chloro-3-methylbutanal
19. Prop-2-enoicacid (or) 2-propenoic acid
20. 2,2,2-Trichloroethanoic acid
21. Hexa-1,3,5-triene (or) 1,3,5-hexatriene
22. 2,2-Dimethylpropane nitrile
23. 2-Ethyl-3-methyl but-1-ene
24. 2,2,2-Trichloroethane-1,1-diol
25. pent-4-en-2-ol
26. pent-4-en-2-yn-1-ol
28. 2,2-dimethyl butan-1-ol
29. 1-chloro-4-methoxy butan-2-ol
30. 2-methylpentane-2,4-diol
31. 4-Hydroxy-2-methyl pentanal
32. 4-Hydroxy pentanoic acid
33. 5-methylhex-3-enoic acid (or) 5-methyl-3-hexenoic acid
34. Pent-2-en-1-oic acid (or) 2-pentenoic acid
35. 3-Aminohept-5-en-1-oic acid (or) 3-Amino-5-heptenoic acid
38. 4-Bromo-2-ethylcyclopentanone
39. 3-Bromo-2-formylcyclohexanone.
40. Cyclohex-3-ene-1, 2-dicarboxylic acid
41. 2-cyclobutylethanoic acid (or) cyclobutyl ethanoic acid
42. 4-chloro-2-methyl pentane nitrile
43. Methyl-3-bromo-2-hydroxy-2-methylbutanoate
45. 3-Carboxy-3-hydroxypentane dicarboxylic acid
46. 2-Methyl hex-5-en-3-ynoic acid
47. 1-chlorobutane-2,3-diol
48. But-2-ene-1,4-dicarboxylic acid
49. 2-Bromo-2-methyl cyclopent-3-enone (or) 2-Bromo-2-methyl-3-cyclopentenone
50. Diethylbutanedioate.

FIITJEE (Hyderabad Classes) Limited.


Assignment(C)
FIITJEE IUPAC NOMENCLATURE

Write down structure of the following compounds:


(1) 1,2-Dibromo-3-chloro-1-propene (2) 2-Ethoxy-1-ethanol.
(3) 2-Butenamide. (4) 2-Aminopropanoicacid.
(5) 2-Chloromethoxyethanol. (6) 3-Bromo-1 -propene.
(7) 1, 3-Dichloro-2-propanol. (8) 3-Buten-2-ol.
(9) 3-Methyl-2-butenoic acid. (10) 4-Dimethylamino-2-butanol.
(11) 4-Chloro-4-methyl-l -pentyne. (12) 2-Methyl-2-pentenal.
(13) 2-Ethyl-3-hydroxyhexanal. (14) 4-Methyl-2-pentene.
(15) 2-Methyl-2-butene. (16) 3-Ethyl-1, 3-hexanediol.
(17) 4-Methoxy-2-butenoic acid. (18) 1, 5-Hexadiene.
(19) 2-Propen-1-ol. (20) 2,2, 2-Trichloroethanoic acid.
(21) 2-Chloro-1, 3-butadiene. (22) 2-methyl-2-propene-1, 1 -dicarboxylic acid
(23) 2-methyl-2-butenoic acid (24) 3-bromo-2-methylpentan-2-ol
(25) 3-methylbut-3-en-1-ol (26) pentane-2, 4-dione
(27) 1-ethoxypropan-1-ol (28) 6-hydroxy-3, 5-dimethyloct-4-enal
(29) 5-bromopent-3-en-2-one (30) 4-cyano-4-ethylheptan-3-one
(31) 2-chlorohex-5-ynal (32) 2-Methylbutane
(33) 2, 2, 4-Trimethylpentane (34) 3-Methylpentane
(35) 4-Ethylheptane (36) 5-Ethyl-2, 2-dimethylheptane
(37) 3-Methylpentane
(38) 4-tert-Butyl-2-methylheptane or 4-( 1, 1 -Dimethylethyl)-2-methylheptane
(39) 4-Ethyl-3-methylheptane
(40) 4-Isopropylheptane or 4-( 1 -Methylethyl) heptane
(41) 2, 3-Dimethylpentane (42) 2-Ethyl-1-hexene
(43) 2-Methylpropene (44) 2-Ethyl-3-methyl-1-butene
(45) 2-Methylpropane (46) 2, 2, 4-Trimethylpentane
(47) 3,3, 5-Trimethylheptane (4.8) 3, 3-Dimethyl-1-butene
(49) 2, 4-Dimethyl-2-pentene (50) 2-Methyl-3-hexyne
(51) 1, 2, 3-Trichlorobutane (52) 1, 2-Dibromo-3-chlorobutane
(53) 1-Bromo-2, 2-dimethylpropane (54) 2-Methyl-2-propanol
(55) 1 -Phenyl-2-propanol (56) 1 -Phenyl-1 -propanol
(57) 3-Ethyl-3, 7, 7-trimethyl-2-octanol (58) 2-Phenylethanol
(59) Propanal (60) 3-Cyclopropyl-3-methylbutanal
(61) 3-Methyl-2-butanone (62) 3-Methylbutanal
(63) 3-Methylbutanoic acid (64) 4-Methyl-2-pentanone
(65) Ethyl propanoate (66) N, N-Diethylpropanamide
(67) 3-Methoxypentane (68) 1-Ethoxypropane
(69) 3-Methylpentanoic acid (70) Propanoicanhydride
(71) N-Ethylethanamide
(72) Isopropyl propanoate or 1-Methylethyl propanoate
(73) N-Methylpropanamide (74) 2-Methyl-3-phenylpentanoic acid
(75) 3-Chloro-1 -butanol (76) 4-Chloro-2-pentyne
(77) 3-( 1 -Chloroethyl)-4-methyl-4-phenyl-2-pentanone
(78) 3-Chloro-4-methyl-3-hexene (79) 3-Bromo-1 -propyne

FIITJEE (Hyderabad Classes) Limited.


Assignment(C)
FIITJEE IUPAC NOMENCLATURE

(80) 2.-Ethyl-3-oxobutanal (81) 2-Butenoic acid


(82) 3-Oxobutanoic acid (83) Methylaminoethanoic acid
(84) Bromopropanone (85) 1 -Chloro-2-propanol
(86) 1, 2-Dimethoxyethane (87) 4-Methoxy-2-methyl-2-butanol
(88) 3-Penten-1 -ol (89) 4-Methyl-3-penten-2-one
(90) 3, 5-Hexadienoic acid (91) 1, 1-Dichloro-2-methylpropene
(92) 2-Hydroxybutanoic acid (93) 1 -Chloro-5-methyl-2-hexanone
(94) 3-Bromo-1, 3, 5-hexatriene (95) 3, 3-Dimethyl-1 -penten-4-yne
(96) 1-Bromo-3-methoxypropane (97) 1, 4-Dibromo-1-butyne
(98) Methoxypropanone (99) 3-Bromo-N-ethylbutanamide
(100) 3-Methoxy-2-pentanol (101) 4-Chloro-2-ethyl-1-butene
(102) 1 -Penten-3-one (103) 4-Methyl-3-pentenal
(104) 5-Amino-3-methylhexanoic acid (105) 5-Bromo-3-hexanol
(106) Propenenitrile (107) Butenedioic acid
(108) 2-Butyne-1, 4-diol (109) 2-Methylpropanedioic acid
(110) 1-Ethyl-1 –methylcyclohexane (111) 1-lsopropyl-3-methylcyclohexane
(112) 1-Cyclobutyl-3-methylpentane (113) Methyl 3-bromo-2-hydroxy-2-methylbutanoate
(114) 5-Oxopentanoic acid (115) N, 3, 3-Trimethyl-1-butanamine
(116) 4-Chloro-2-methylpentanenitrile

FIITJEE (Hyderabad Classes) Limited.

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