SAFETY DATA SHEET Issue date: 01/04/2022

Version: 8
Product: PARA TERTIARY BUTYL CYCLOHEXANOL
1000000074

Section 1. Identification of the substance or the mixture and of the supplier

1.1 Product Identifier

Product trade name: PARA TERTIARY BUTYL CYCLOHEXANOL (PTBCH) ; CAS: 98-52-2
Product number: 1000000074
Other means of
identification: p-tert-Butyle Cyclohexanol OR Cyclohexanol, 4-(1,1-dimethyl ethyl) OR 4-(1,1-dimethyl ethyl)
Cyclohexanol OR Patchone OR Patchouli hexanol OR Patchona Cruda

1.2 Relevant identified uses of the substance of mixture and uses advised against

Product uses: Ingredient for fragrances

1.3 Details of the supplier

Company name: Eternis Fine Chemicals Ltd.

Company address: 1004, Peninsula Towers, 10 th Floor, Peninsula
Corporate Park, G.K. Marg, Lower Parel, Mumbai-
400013, India
Contact: Salomi Samuel
E-Mail address: sales@eternis.com/regulatory@eternis.com
Company phone: 91-22-66513400

1.4 Emergency telephone number

Emergency phone:
Emergency Telephone Region/ Emergency Telephone Region/ Emergency Telephone
Region/ Countries Languages Provided Languages Provided Languages Provided
Number Countries Number Countries Number
English, Bahasa
English, Dutch,
*East/South East Malaysia, Hindi, English, Spanish,
+65 3158 1412 *Americas +1 215 207 0061 *Europe French, German, +44 1273 289451
Asia Japanese, Korean, French, Portuguese
Italian, Spanish
Mandarin, Tagalog
400 120 6011 (toll-
+1 866 928 0789 (Toll
free, access from English, French,
China English, Mandarin United States free) ' France English, French +303 1 72 11 00 03
China only) Spanish
' +1 202 464 2554'
**0532 8388 9090
0800 000 7801 (toll-
0120 015 230 (toll- +1 800 579 7421 (Toll
free, access from
Japan English, Japanese free, access from Canada English, French Free) ' Germany English, German
Germany only)
Japan only) '+1 202 464 2554'
+49 89 220 61012
Malaysia English, Malaysian +60 3 6207 4347 Mexico English, Spanish +52 55 5004 8763 Spain English, Spanish +34 91 114 2520

000 800 100 7479 (toll

Portuguese, Spanish, 800 699 792 (toll-free,
India English, Hindi –free number, access Brazil +55 11 3197 5891 Italy English, Italian
English access from Italy only)
from India only)

Philippines English, Tagalog +63 2 8231 2149 Chile English, Spanish +56 2 2582 9336 Netherlands English, Dutch +31 10 713 8195

South Korea English, Korean +82 2 3479 8401 Colombia English, Spanish +57 601 508 7337 *Middle East English, Arabic +44 1273 289454

Europe, Middle
Singapore English +65 3165 2217 Argentina English, Spanish +54 11 5984 3690 English +44 1865 407333
East & Africa

18000 74234 (toll

–free number, access
Australia English
from Australia only)
+61 2 8014 4558
0800 446 881 (toll
–free number, access
New Zealand English from New Zealand
only)
+64 9 929 1483

Section 2. Hazards identification

2.1 Classification of the substance or mixture

Classification accordance with UN-GHS:
Acute Toxicity Oral 5, H303
Environment Hazard Acute 2,H401
Eye irritation 2A, H319

Classification accordance with 29 CFR 1910.1200(d)/US-GHS/OSHA:

Eye irritation 2A, H319

Classification according with Regulation (EC) No 1272/2008

None

2.2 Label elements

Eternis Fine Chemicals Ltd ; Tel : 91-22-66513400 1/5

 SAFETY DATA SHEET Issue date: 01/04/2022
Version: 8
Product: PARA TERTIARY BUTYL CYCLOHEXANOL
1000000074

Classification accordance with UN-GHS:

Hazard pictogram(s):
Signal word:
Hazard statements:
Precautionary statements:
Warning
H303, May be harmful if swallowed
H319, Causes serious eye irritation.
H401, Toxic to aquatic life
P261, Avoid breathing vapour or dust.
P312 Call a POISON CENTER or doctor if you feel unwell.
P264 Wash contaminated body parts thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses
if present and easy to do - continue rinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance to local regulations

Classification accordance with 29 CFR 1910.1200(d)/US-GHS/OSHA:

Hazard pictogram(s):
Signal word:
Hazard statements:
Precautionary statements:
Warning
H319, Causes serious eye irritation.
P312 Call a POISON CENTER or doctor if you feel unwell.
P264 Wash contaminated body parts thoroughly after handling.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses
if present and easy to do - continue rinsing.
P337+P313 IF eye irritation persists: Get medical advice/attention.
P273 Avoid release to the environment.
P501 Dispose of contents/container in accordance to local regulations

Classification according with Regulation (EC) No 1272/2008

Signal word: Warning
Hazard statements: None
M factor: None
Supplemental Information: None
Precautionary statements:
P280, Wear protective gloves/eye protection/face protection.
P302/352, IF ON SKIN: Wash with plenty of soap and water.
P333/313, If skin irritation or rash occurs: Get medical advice/attention.
P501, Dispose of contents/container to approved disposal site, in accordance with local regulations.

Pictograms:
Other hazards None

Classification and hazards statements are listed according to the United Nations Globally Harmonized System of Classification and Labelling
of Chemicals (GHS).

Section 3. Composition / information on ingredients

3.1 Substances

CAS No. EC No. (EINECS) Chemical Name % UN GHS-Hazard

98-52-2 202-676-4 4-tert-butylcyclohexanol 100 ATO 5(4200),EH A2,EDI 2A

CAS No. EC No. (EINECS) Chemical Name % OSHA-Hazard

98-52-2 202-676-4 4-tert-butylcyclohexanol 100 EDI 2A

CAS No. EC No. (EINECS) Chemical Name % CLP-Hazard

98-52-2 202-676-4 4-tert-butylcyclohexanol 100 None

Section 4. First-aid measures

4.1 Description of first aid measures
Inhalation: Remove from exposure site to fresh air, keep at rest, and obtain medical attention.

Eternis Fine Chemicals Ltd ; Tel : 91-22-66513400 2/5

 SAFETY DATA SHEET Issue date: 01/04/2022
Version: 8
Product: PARA TERTIARY BUTYL CYCLOHEXANOL
1000000074

Eye exposure: Flush immediately with water for at least 15 minutes. Contact physician if symptoms persist
Skin exposure: Remove contaminated clothes. Wash thoroughly with soap and water. Contact physician
if irritation persists.
Ingestion: Rinse mouth with water and obtain medical attention.
4.2 Most important symptoms and effects, both acute and delayed
Symptoms/injuries: Not expected to present a significant hazard under anticipated conditions of normal use

4.3 Indication of any immediate medical attention and special treatment needed
No additional information available

SECTION 5: Firefighting measures

5.1 Extinguishing media
Suitable media: Carbon dioxide, Dry chemical, Foam.
5.2 Special hazards arising from the substance or mixture
In case of fire, may be liberated: Carbon monoxide, Unidentified organic compounds.
5.3 Advice for fire fighters:
In case of insufficient ventilation, wear suitable respiratory equipment
Section 6. Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Avoid inhalation. Avoid contact with skin and eyes. See protective measures under Section 7 and 8.
6.2 Environmental precautions:
Keep away from drains, surface and ground water, and soil.
6.3 Methods and material for containment and cleaning up:
Remove ignition sources. Provide adequate ventilation. Avoid excessive inhalation of vapours.
Contain spillage immediately by use of sand or inert powder. Dispose of according to local regulations.
Section 7. Handling and storage
7.1 Precautions for safe handling:
Keep away from heat, sparks, open flames and hot surfaces. - No smoking. Use personal protective equipment as
required. Use in accordance with good manufacturing and industrial hygiene practices. Use in areas with adequate
ventilation Do not eat, drink or smoke when using this product.
7.2 Conditions for safe storage, including any incompatibilities:
Store in a well-ventilated place. Keep container tightly closed. Keep cool. Ground/bond container and receiving
equipment. Use explosion-proof electrical, ventilating and lighting equipment. Use only non-sparking tools.
Take precautionary measures against static discharge.
7.3 Specific end use(s):
Ingredient for flavours and fragrances: Use in accordance with good manufacturing and industrial
hygiene practices.
Section 8. Exposure controls/personal protection
8.1 Control parameters
Workplace exposure limits: Not Applicable
8.2 Exposure Controls
Eye / Skin Protection
Wear protective gloves/eye protection/face protection
Respiratory Protection

Under normal conditions of use and where adequate ventilation is available to prevent build up of excessive vapour, this material should not require
special engineering controls. However, in conditions of high or prolonged use, or high temperature or other conditions which increase exposure, the
following engineering controls can be used to minimise exposure to personnel: a) Increase ventilation of the area with local exhaust ventilation.
b) Personnel can use an approved, appropriately fitted respirator with organic vapour cartridge or canisters and particulate filters. c) Use closed
systems for transferring and processing this material.

Section 9. Physical and chemical properties

9.1 Information on basic physical and chemical properties

Appearance: White flakes / clear colourless liquid

Odour: Camphoraceous
Odour threshold: Not determined
pH: Not determined
Melting point/freezing point: 62 °C

Initial boiling point and boiling range: 218.6 °C

Flash point 105 °C
Evaporation rate: Not determined
Flammability (solid, gas): Not determined
Upper/lower flammability or explosive limits: Not determined
Vapour pressure: 6 Pa @ 25°C
Vapour density: Not determined
Bulk density: 0.3423
Relative density: 0.8850 @80°C

Eternis Fine Chemicals Ltd ; Tel : 91-22-66513400 3/5

 SAFETY DATA SHEET Issue date: 01/04/2022
Version: 8
Product: PARA TERTIARY BUTYL CYCLOHEXANOL
1000000074

Solubility(ies): Water Solubility 264 mg/l @ 20°C

Partition coefficient: n-octanol/water: 3.23 log POW @ 20°C
Auto-ignition temperature: Not determined
Decomposition temperature: Not determined
Viscosity: 10 cSt at 80 °C
Explosive properties: None
Oxidising properties: Not determined

9.2 Other information: None

Section 10. Stability and reactivity

10.1 Reactivity:
Presents no significant reactivity hazard, by itself or in contact with water.
10.2 Chemical stability:
Good stability under normal storage conditions.
10.3 Possibility of hazardous reactions:
Not expected under normal conditions of use.
10.4 Conditions to avoid: Avoid extreme heat.
10.5 Incompatible materials:
Avoid contact with strong acids, alkalis or oxidising agents.
10.6 Hazardous decomposition products: Not expected.

Section 11. Toxicological information

11.1 Information on toxicological effects
Acute Toxicity: Based on available data the classification criteria are not met.
Acute Toxicity Oral LD50 (rat) 4200mg/kg
Acute Toxicity Dermal LD50 (rabbit) >5000mg/kg
Acute Toxicity Inhalation LD50 (rabbit) Not available
Skin corrosion/irritation:
Based on available data the classification criteria are not met.
Skin irritation
Rabbit not irritating
Serious eye damage/irritation: Eye Irritant - Category 2A
Eye irritation Irritating
Respiratory or skin sensitisation :
Based on available data the classification criteria are not met.
Skin sensitisation Based on available data the classification criteria are not met.
Germ cell mutagenicity:
Based on available data the classification criteria are not met.
Carcinogenicity:
No data available
Reproductive toxicity:
No data available
STOT-single exposure:
Based on available data the classification criteria are not met.
STOT-repeated exposure:
Based on available data the classification criteria are not met.
Aspiration hazard:
No data available

Refer to Section 2 for additional information.

Section 12. Ecological information

12.1 Toxicity
Aquatic toxicity: Based on available data the classification criteria are not met.
LC50 (48 hrs) Fish 17 mg/l
EC50 (46 hrs) Daphnia 46 mg/l
LC50 (72 hrs) Algae 29 mg/l

12.2 Persistence and degradability

Biodegradation: OECD Guideline 301 F 28 day Readily biodegradeable

12.3 Bioaccumulative potential

Partition coefficient n-octanol /water (log Kow): Measured 3.42

12.4 Mobility in soil

Adsorption coefficient:

Eternis Fine Chemicals Ltd ; Tel : 91-22-66513400 4/5

 SAFETY DATA SHEET Issue date: 01/04/2022
Version: 8
Product: PARA TERTIARY BUTYL CYCLOHEXANOL
1000000074

Koc Measured 2.2228

Log Koc Measured 167 l/kg
12.5 Results of PBT and vPvB assessment
Not applicable

12.6 Other adverse effects Not applicable

12.7 Additional information WGK-1

Section 13. Disposal considerations

13.1 Waste treatment methods:
Dispose of in accordance with local regulations. Avoid disposing into drainage systems and into the environment. Empty containers should be taken
to an approved waste handling site for recycling or disposal.

Section 14. Transport information

IMDG
Informations U.S. DOT Canada TDG ADR/RID Code ICAO/IATA (air)
(ocean)
UN Number N/A N/A N/A N/A N/A
UN Proper Shipping Name Notclassified
Transport hazard class(es) N/A N/A N/A N/A N/A
Packing Group N/A N/A N/A N/A N/A
Environmental hazards N/A
Special precautions for user None additional
Transport in bulk according to Annex II of
Notclassified
MARPOL73/78 and the IBC

Section 15. Regulatory information

15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
International Inventories
Country(s) or region Inventory name On inventory (yes/no)*
Australia Australian Inventory of Chemical Substances (AICS) Yes
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of Existing Commercial Chemical Yes
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
New Zealand New Zealand Inventory Yes
Philippines Philippine Inventory of Chemicals and Chemical Substances Yes
US. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.
SARA 304 Emergency release notification
Not regulated.
OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050)
Not listed.

REACH Registration : ECHA 01-2119976368-20-0003

Turkey 05-0000353956-08-0000 (Pre-Registration)

Section 16. Other information

Key to revisions: Revision No.8, Last Revision changed for Emergency Contact Updation
HS Code:- 2906.19.90

Key to abbreviations: GHS- Global Harmonised System

OSHA- Accupational Safety Health administration
IFRA- International fragrance association

The information in this safety data sheet is to the best of our knowledge true and accurate but all data, instructions,
Recommendations and/or suggestions are made without guarantee.

Eternis Fine Chemicals Ltd ; Tel : 91-22-66513400 5/5