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EXCERSICE-1
CHEMISTRY_ANSWERS & SOLUTIONS

1. A 2. B 3. C 4. B 5. C 6. D 7. A 8. C 9. C 10. A
11. D 12. C 13. D 14. C 15. D 16. B 17. D 18. B 19. A 20. A
21. B 22. A 23. D 24. A 25. 04.96 26. 14.00 27. 10.00 28. B 29. C 30. A
31. D 32. A 33. BONUS 34. D 35. A 36. B 37. A 38. D 39. C 40. C
41. B 42. A 43. C 44. 02.13 45. D 46. B 47. A 48. B 49. A 50. A
51. A 52. A 53. -85.00 54. D 55. A 56. B 57. C 58. B 59. D 60. A
61. A 62. B 63. C 64. A 65. A 66. D 67. 10.60 68. 5.22 69. A 70. A
71. A 72. B 73. C 74. C 75. B 76. B 77. B 78. D 79. C 80. D
81. A 82. B 83. A 84. B 85. A 86. -02.70 87. 48 88. 06.25 89. A 90. A
91. 2.176 92. A 93. D 94. C 95. D 96. C 97. A 98. D 99. C 100. B
101. A 102. C 103. C 104. C 105. B 106. C 107. A 108. A 109. A 110. C
111. A 112. D 113. B 114. C 115. A 116. B 117. D 118. B 119. D 120. A
121. B 122. D 123. A 124. B 125. A 126. A 127. C 128. C 129. 20.00 130. C
131. C 132. A 133. D 134. D 135. A 136. B 137. C 138. A 139. B 140. C
141. B 142. B 143. C 144. C 145. C 146. C 147. A 148. D 149. D 150. D
151. C 152. D 153. B 154. C 155. D 156. D 157. A 158. B 159. 160.

1.Conceptual 8
2.Conceptual
3.

9
5

6
10

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13 17

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21

16
22

23
2
n
rn  0 .5 2 9 
0
Sol: A
z
2
2
r  0 .5 2 9   0 .5 2 9  4  2 .1 2 A
0

1
24

25

31

26

27

28
32

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34 38

35

39
5
C 2 H 4O  O2  
 2C O 2  2 H 2O
2
40
36 The weight of 1 H = 7 .5 k g  1 0 % o f 7 5 k g 
The weight of 2 H = 1 5 k g
 net increase in weight = 7.5 kg
41
M 2C O 3 + 2 H C l  
 C O 2 + M C l2 + H 2O

1 gm
1 m o le  1 m o l  0 .0 1 1 8 6 m o le
M .wt
1
M .wt = = 8 4 .3 m o le
0 .0 1 1 8 6

42

43
37
At a particular temperature as intermolecular force of
attraction increases vapour pressure decreases.
44

45

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46 50

47
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54

49 55

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56 60
Conceptual
57

58

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64

69

65

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66
 dH
d  ln K 
RT
As T increases, K decreases for an exothermic
reaction
1
As increase, K value increases
T
Form the graph A & B supports
71
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72 76

77

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78

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80 84
10
K sp
of BaSO4  1 10
2 
Ba  N a2SO4  
 BaSO4  2 N a

N a2SO4 : BaSO4 :

M 1
 1M M 2
 x

V1  5 0 m l V2  500
50  1  500  x

x  0 .1
2 1
The conc. Of SO4  10
10 2 1
1 10  Ba   10
2 2  
K sp   B a   SO4 
   2 9
Ba   1 10
 
2 9
In 1 L the conc. Of B a ions is 1 0 then in 450
81 450  x  500  1 10
9

 
C H 3C O O  H 2 O  C H 3C O O  O H
5 9
5 ml is x   10
K a  10 4 .5
14 9
K 10 9  1 .1  1 0
Kh    10
N
5
Ka 10

d) A l  O H  3 a n d H C N both are weak 85

82 P
Ka Kb
of H A < P o f B O H
The pH of methyl orange indicator is 3.5 which is
K of H A > K Strength of HA > Strength
of BO H
suitable for titration of weak base vs strong acid.The a b

colour change observed is yellow to pinkish red. of BOH

83 Reactivity of A < reactivity of B +
Given that +
B hydrolyse to produce acidic solution
Conc. Of H2S=0.10M 86
Conc. Of HCl = 0.20 M
K a1 1  1 0 
  7
H 2 S H  HS

K a 2  1 .2  1 0 
  2 13
HS H  S

K eq  K a1  K a 2
7 13
 1 10  1 .2  1 0 87
20
 1 .2  1 0
 2
H 2 S 2 H  S
2
 2
H  S  88
   
K  K a1 .K a 2 
H 2S 
 0 .2 
2 2
20
S
1 .2  1 0 
0 .1
20 1
2 1 .2  1 0  10 20
89
S    3  10
  2
4  10

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90 93

91

94

92

95

96

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96 100

101

97
102
H  U  nRT

15
C6H 6
  6C O 2  3 H 2O  l 
O2  
2
Given:
 U   3 2 6 3 .9 K J / m o l

15 3
n  6   
2 2
3 3
 H   3 2 6 3 .9   8 .3 1 4  2 9 8  1 0
2
  3 2 6 3 .9  3 .7 1 6

  3 2 6 7 .6 K J / m o l
98 103
From 1 Law of thermodynamics
U  w  q
In adiabatic process, q = 0
U  W
104
C  s   O2  g   
 C O 2  g  ;  H 1   3 9 3 .7 K J m o l
1

2 H 2  g   O2  g   
 2 H 2 O  g  ;  H 2   5 7 1 .6 K J m o l
1

C O 2  g   2 H 2O  l   


 g   2O 2  g  ;
1
CH 4
H 3  8903 K J m ol

99 Eliminating oxygen, C O 2 & H 2 O on both sides in all the three

equations we get
C s  2H 2  g   
 CH 4  g ;  rH
1
  7 4 .9 K J m o l
o

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105.

106.

107.

108.

109.

110.

111.

112.

113.

114.

115.

116.

117.

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118.

119.

120.

121.

122.

123. Should have same no of electrons

124.

125.

126.

127.

128.

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129.

130.

131.

132.

133.

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134.

135.

136.

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137.

138.

139. 
I3 ion has Trigonal Bipyramidal geometry
The geometry is distorted to linear due to the presence of lone of electrons on central iodine
atom.
The total no of lone pair of electrons is 9
140. Bond order  1 / 2  b o n d in g e  = a n tib o n d in g e  
If bond order (B.O), is zero. The species does not exist
Viable = Exist
a) H e 2 B .O  1 / 2  2  1   1 / 2  0 .5
b) H 2 B .O  1 / 2  2  1   1 / 2  0 .5
c) H 22  B .O  1 / 2  2  2   0  d o es n o t ex ist
d) H e 22  B .O  1 / 2  2  1   1

141. KCl  
 Io n ic c r y s ta llin e s o lid

H 2S O 4  
 C o v a le n t

B 2H 6

 C o v a le n t

PH 3

 C o v a le n t
142. NO, O 2, B2 are paramagnetics
CO  
 D ia m a g n e tic

O 2   1s  1s   2s  2 p  2 p   2 p  2 p   2 p  p a ra m a g n e tic
2 2 2 2 2 2 1 *2 *1
2s x z z y z

B 2   1s  1s   2 s  2 p   2 p  2 p  2 p   2 p  p a ra m a g n e tic
2 2 2 2 2 1 *2 *1
2s y z x y z

N O   1s  1s   2 s  2 p   2 p  2 p  2 p   2 p  p a ra m a g n e tic
2 2 2 2 2 1 *2 *1
2s x z x y z

C O   1s  1s   2 s  2 p   2 p  2 p  2 p   2 p  d ia m a g n e tic
2 2 2 2 2 1 *2 *1
2s y z x y z

143.

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144.

145.

146.

147.

148.

149.

150.

151.

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152.

153.

154.

155.

156.

157.

158. 2K 4 Fe CN  6    2K 3 Fe CN

H 2 S O 4  H 2O 2    6   K 2 S O 4  2 H 2O
 
2K 3 Fe CN  6    2K 4  Fe CN
2 K O H  H 2O 2    6   2 H 2O  O 2
 

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