Ti me : 3.

00 H r SR SANKALP
Marks : 300 SUPER GRAND-1

PHYSICS
1. A particle starts from a point P at a distance of A/2 from the mean position O &
travels towards left as shown in the figure. If the time period of SHM, executed about
O is T and amplitude A then the equation of motion of particle is

 2   2 5 
1. x  A sin  t  2. x  A sin  t 
 T 6  T 6 
 2   2 
4. x  A cos  t  3. x  A cos  t 
 T 6  T 4
2. Regarding speed of sound in gas match the following
(A) Temperature of gas is made 4 (P) speed becomes 2 2 times
times and pressure 2 times
(B) Only pressure is made 4 times (Q) speed become 2 times
without change in temperature
(C) Only temperature is changed to 4 (R) speed remains unchanged
times
(D) Molecular mass of the gas is (S) speed remains half
made 4 times
1. A – Q, B – R, C – Q, D – S 2. A – Q, B – S, C – Q, D – S
3. A – S, B –R, C – Q, D – S 4. A – Q, B – R, C – Q, D – Q
3. Water flows steadily through a horizontal pipe of variable cross-section. If the
pressure of water is P at a point where flow speed is v, the pressure at another point
where the flow speed is 2v, is (Take density of water as  )
3ρv 2 ρv 2 3ρv 2
1. P  2. P  3. P  4. P   v 2
2 2 4
4. A uniform rod of mass M and length L is hinged about a point as shown in the fig.
Initially the rod is kept horizontal by a massless string as shown. When string is cut
the angular acceleration of the rod is

6g 3g 3g g
1. 2. 3. 4.
L 2L 3L 6L
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5. A quantity measured repeatedly many times with an instrument. The readings are
shown in figure where T represent true value of the measurement. Which of the
following measurement is imprecise but accurate ?

1. 2. 3. 4.

   
6. Two vectors A and B have equal magnitudes. If magnitude of A + B is equal to n
   
times the magnitude of A - B , then the angle between A and B is
2 2
1  n  1  1  n  1  1  n  1  1  n  1 
1. cos   2. cos  2  3. sin   4. sin  2 
 n 1  n 1  n 1  n 1
7. Four spheres A, B, C and D are of same radius but made of different metals. Their
densities are in ratio 6 : 3 : 4 : 5 and specific heats are in ratio 2 : 5 : 4 : 6. These are
initially kept at the same temperature and placed in the same surroundings. The sphere
which has the slowest rate of cooling is
1. C 2. B 3. D 4. A
8. The acceleration of the 2kg block if the free end of
string is pulled with a force of 20 N as shown is

1. Zero 2. 10 m/s2 upward 3. 5m/s2 upward 4. 5 m/s2 downward

9. In the circuit shown in the figure K1 is open. The charge on capacitor C in steady state
is q1. Now key is closed and at steady state charge on C is q2. The ratio of charges
q1 / q2 is

1. 5/3 2. 3/5 3. 1 4. 2/3

10. A photon collides with a stationary hydrogen atom in ground state inelastically.
Energy of the colliding photon is 10.2 eV. After a time interval of the order
of micro second another photon collides with same hydrogen atom inelastically with
an energy of 15 eV.
What will be observed by the detector
1. 2 photon of energy 10.2 eV
2. 2 photon of energy of 1.4 eV
3. One photon of energy 10.2 eV and an electron of energy 1.4 eV
4. One photon of energy 10.2 eV and another photon of 1.4 eV
SR SANKALP SUPER GRAND-1_14-04-24 Page | 2
11. A conducting ring of radius 'r' is placed in a varying magnetic field perpendicular to
the plane of the ring, the rate at which magnetic field varies is x the electric field
intensity at any point of the ring is
rx 4r
1. rx 2. 3. 2rx 4.
2 x
12. The resistance of a galvanometer is 50 and it requires 2 A per two division
deflection. The value of the shunt required in order to convert this galvanometer into
ammeter of range 5A is (The number of divisions on the galvanometer scale on one
side is 30)
1. 0.2 2. 0.002  3. 3  10 4  4. 4  10 6 
13. The current i1and i2 through the resistors
R1   10  and R2   30  in the circuit
diagram with E1  3V , E2  3V and E3  2V are
respectively

1. 0.2 A, 0.1 A 2. 0.4 A, 0.2 A 3. 0.1 A, 0.2 A 4. 0.2 A, 0.4 A

14. A current i ampere flows along an infinitely long straight thin walled tube, then the
magnetic induction at any point inside the tube is
 2i 2i
1.  2. Zero 3. 0 . Tesla 4. Tesla
4 r r
15. A series LCR circuit containing a resistance of 120 has resonance frequency
4  105 rad s -1 . The voltages, at resonance, across resistance and inductance are 60V
and 40V respectively. The values of L and C respectively are
1. 0.3 mH, 0.0195  F 2. 0.1 mH, 0.4525  F
3. 0.2 mH, 0.03125  F 4. 0.4 mH, 0.5125  F
16. Figure shows three resistor configurations R1R2 and R3 connected to 3V battery. If the
power dissipated by the configuration R1 , R2 and R3 is P1 , P2 and P3 respectively,
then

1. P1  P2  P3 2. P1  P3  P2 3. P2  P1  P3 4. P3  P2  P1
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17. Find the equivalent capacitance of the circuit between point A and B.

C C C
1. 2. 3. C 4.
3 8 32
18. The B-H curves S1 and S2 in the adjoining figure are associated with

1. Diamagnetic and paramagnetic substances respectively

2. Paramagnetic and ferromagnetic substances respectively
3. Soft iron and steel respectively
4. Steel and soft iron respectively
19. Find the time constant of following circuit

3L 3R 2L 2 R
1. 2. 3. 4.
2R 2L 3R 3 L
20. A spherical portion has been removed from a solid sphere having a charge distributed
uniformly in its volume as shown in the figure. The electric field inside the emptied
space is :

1) zero everywhere 2) nonzero and uniform

3) nonuniform 4) zero only at its center
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 SECTION-II
21. Two ice skaters A and B approach each other at right angles. Skater A has a mass 30
kg and velocity 1 m/s and skater B has a mass 20 kg and velocity 2 m/s. They meet
and cling together. Their final velocity (in m/s) of the couple is
22. Frequency of tuning fork A is 256 Hz. It produces four beats/sec. with tuning fork B.
When wax is applied at tuning fork B then 6 beats/sec. are heard. By reducing little
amount of wax 4 beats/sec. are heard. Frequency (in Hz) of B is:
23. A ball is dropped from a height of 80 m on a surface which is at rest. Find the height
(in m) attainded by ball after 2nd collision if coefficient of restitution e = 0.5
24. A shown in the figure, the amount of heat absorbed along
the path ABC is 90J and the amount of work done by the
system is 30 J. If the amount of work done along the path
ADC is 20 J, the amount of heat (in J) absorbed will be

25. What is the maximum value of the force F (in N) such that the block shown in the
arrangement does not move (g=10 m/sec2)

26. According to Joule's law of heating, heat produced H = I2 Rt, where I is current, R is
resistance and t is time. If the errors in the measurement of I, R and t are 3%, 4% and
6% respectively then error in the measurement of H is
27. 10 gm of ice at 00C is mixed with ' m ' gm of water at 500 C . What is minimum value
of m (in gm) so that ice melts completely.  L f =80 cal/gm and SW =1 cal/gm-0C 
28. A ray of light strikes a plane mirror M at an angle of
450 as shown in the figure. After reflection, the ray
passes through a prism of refractive index 1.5 whose
apex angle is 40. The total angle through which the ray
is deviated is

29. Find VAB (in V)

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30. A 9V stabilized voltage supply is required to run a car stereo system from the car’s
12V battery. A zener diode with Vz  9V and Pmax = 0.27 W is to be used as the
voltage regulator. The load resistance is 450  . The value of series resistor (in ) is

CHEMISTRY
31. What is the position of an element in the periodic table whose atomic number is 33?
1. Group 1 2. Group 3 3. Group 15 4. Group 14
32. When 1 mol CrCl3. 6H2O is treated with excess of AgNO3, 3 mol of AgCl are
obtained. The formula of the complex is :
1. CrCl3  H 2O 3  .3H 2O 2. CrCl2  H 2O 4  Cl.2 H 2O
3. CrCl  H 2O 5  Cl2 .H 2 O 4. Cr  H 2O 6  Cl3

33.

The structure of P is

1. 2. 3. 4.

34. By which of the following reagents can the following conversion be effected?

1. 2CH3MgBr and the H 3 O 

2. i) HOCH 2 –CH2OH / H 
ii) LiAlH4 iii) 2CH3MgBr /ether iv) H3O +
3. i) HOCH 2 –CH2OH/ H 
ii) 2CH 3MgBr/ether iii) H 3 O 
4. i) HOCH 2 –CH2 –OH / H 
ii) H2/Pt iii) CH3OH/ H 
35. Which of the following has the highest mass?
1. 1 g – atom of phosphorous
2. 2 moles of water
3. 22.4L of CO 2 gas at STP
4. 6.02  1023 atoms of sulphur
36. The correct electron affinity order is(EA = –ΔHEG ) :-
1. N   O   NO  2. O   N   NO  3. N   NO   O  4. NO   N   O 
SR SANKALP SUPER GRAND-1_14-04-24 Page | 6
37. What will be the maximum value of (n  l  m) for all unpaired electrons of
chlorine in its second excited state
1. 25 2. 20 3. 28 4. 27
38. Which of the following gives 2°-alcohol as a major product with CH3MgBr followed
by H2 O

1. CH 3 CH 2 – OH 2. 3. 4.

H 2O
39. PhN 2Cl 

 product of the following reaction is?

1. 2. 3. 4.

40. Which of the following vitamin is water soluble?

1. Vitamin-C 2. Vitamin-D 3. Vitamin-K 4. Vitamin-E
41. Which of the following statement is incorrect?
1. Lu(OH)3 is more basic compared to La(OH)3 .
2. Lanthanide carbide (LnC2 ) produces acetylene on hydrolysis
3. CeS is used to make Crucible
4. Misch-metal is used for making Cigarette lighter
42. Which of the following compound does not give Tollen’s test?

1. 2. 3. 4.

43.

1. 2. 3. 4.

44.

Relation between products A and B is ?

1. Functional isomer 2. Metamers
3. Position isomer 4. Geometrical isomer
SR SANKALP SUPER GRAND-1_14-04-24 Page | 7
45. The major product formed in the following reaction is:

1. 2.

3. 4.

46. The complex that has highest crystal field splitting energy (  ) is
1. [Co(NH3)5 (H2O)]Cl3 2. K2[CoCl4] 3.[Co(NH 3)5Cl]Cl2 4. K 3[Co(CN)6]
47. The correct sequence of amino acids present in the tripeptide given below is

1. Val – Ser – Thr 2. Thr – Ser – Val

3. Leu – Ser – Thr 4. Thr – Ser – Leu
48. In which of the following processes, the bond order has increased and paramagnetic
character has changed to diamagnetic?
1. NO  NO  2. N 2  N 2 3. O2  O2 4. O2  O22
49. The transition element that has lowest enthalpy of atomization is
1. Fe 2. Cu 3. V 4. Zn
50. Homoleptic octahedral complexes of a metal ion ‘M+3’ with three monodentate ligands
L1, L2 and L3 absorb wavelengths in the region of green, blue and red respectively.
The increasing order of the ligand strength is
1. L3 < L1 < L2 2. L3 < L2 < L1 3. L1 < L2 < L3 4. L2 < L1 < L3
SECTION-II
51. The formation of phosgene is represented as,
CO + Cl2  COCl2
The reaction is carried out in 500 mL flask. At equilibrium 0.3 mole of phosgene, 0.1
mole of CO and 0.1 mole of Cl2 are present. The equilibrium constant of the reaction
is:
52. The total number of compounds amongst the following, that can be classified as
vicinal dihalides will be

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53. How many stereoisomers can be drawn for the following molecule?
H3CCH2CH = CHCH2 CH (Cl) CH 3
54. How many of the following will have negative standard reduction potentials?
K, Na, Ag, Zn, Li, Cu, Hg
55. 30 ml NaOH solution is required for complete neutralisation of 0.98 gm
orthophosphoric acid. The concentration of NaOH solution is :
56. For the reaction :
CH4 (g) + 2O2 (g) → CO2 (g) + 2H 2 O(l); Δr H 300 = –212.2 Kcal / mol. The absolute
0
value of  r U 300 (in Kcal/mol) for this reaction is : (R = 2 cal/mol-K)
57. For the Galvanic cell :
Ag  s  Ag 2C2O4  S  C2O42  0.02 M  Ag   0.5M  Ag  s 
EMF of cell is 0.264 V at 250C.If the K sp of Ag2C2O 4(s)
X 1012 , give x
2.303  8.314  298 2.303RT
[Given :   0.06, log 2  0.3]
96500 F
58. The boiling point (in °C) of 0.2m- aq. Urea solution is (Kb of water = 0.50 K.kg.mol–1 )
59. Consider the following reversible chemical reactions:
K1

A2  g   B2  g    2 AB  g  ........... 1
K2

6 AB  g    3 A2  g   3B2  g  .........  2 
x y yx
If the relation between K1 and K 2 is K1  K 2 (y > x) then the value of is
2
60. The products formed in the reaction of cumene with O2 followed by treatment with
dil. HCl are A and B respectively. If A is aromatic and acidic in nature, B is aprotic
polar compound then the number of carbon atoms present in B is
MATHEMATICS
x  2 y 1 z 1
61. Image of line   in the plane x  y  z  7 is
3 1 4
x  4 y 3 z 3 x3 y 4 z 3
1.   2.  
1 1 1 1 1 1
x 3 y 4 z3
3. x  4  y  3  z  3 4.  
3 1 4 3 1 4
1
62. The range of is
3sin   4cos  2
 1 1  1 1   1 1   1 1 
1.  ,  2.  ,  3. ,    ,  4. ,    ,
 3 7 3 7  3  7   2  5 

63. A non-zero vector a is parallel to the line of intersection of the plane determined by
the vectors iˆ, iˆ  ˆj and the plane determined by the vectors iˆ  ˆj , iˆ  kˆ .The angle

between a and iˆ  2 ˆj  2kˆ is
   
1. 2. 3. 4.
4 3 6 2
2 2
64. Equation of the curve satisfying xdy  ydx  x  y dx; y 1  0 is
1. y  x 2 sin  log x  2. y 2  x  x  12
3. y 2  x 2  x  1 4. y  x sin  log x 
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65. If ax  y  16  0 and x  ay  6  0 represented two adjacent sides of a rhombus
whose diagonals intersect at  3,5  then sum of possible value of a is
9
1. 4 2. 2 3. -2 4. 
4
d  3 d2y 
66. If y 2  p  x  is a polynomial of degree 3, then 2  y 
dx  dx 2  is equal to

1. p '''  x   p '  x  2. p ''  x   p '''  x 

3. p  x  p '''  x  4. p ''  x  p '''  x 

67. If x, y, z  R  such that x  y  z  4 ,then maximum possible value of xyz 2 is

1. 3 2. 4 3. 5 4. 6
 2 x  5 dx
68.   x  1 x  2  x  3 x  4   1 is equal to (where C is constant of integration)
1 1 1 1
1. 2
C 2. 2
C 3. 2
C 4. 2
C
x  5x  5 x  4x  1 x  5x  1 x  5x  1
 
69. Let f  x   ln x  x  1 then the value of determinant
2

  
f (sin 2 0 1 7  ) f  sin  f e x 
 6 
 2   2 0 1 7    
f  cos  f  cos  f  ta n 
 3   2   3 
is
 5 
f  e x
 f  cot  f 0 
 6 
1. 0 2. 3 3. e 3 4. 
 z2 
70. If z is a complex number such that amp    0 and z0  3  4i , then the
 2 z  3i 
value of z0 z  z0 z ( whenever defined )
1. is 6 2. is 24
3. is 12 4. Depends on the value of z
n
 1
e 1    1
71. If lim  n exists and is equal to l  l  0  , then the value of 12  l    is
n  n
1. 4 2. 3 3. 6 4. 7
20 20 1  i
72. The value of  j 1  i1 
tan  is
j

1. 200 2. 50 3. 150 4. 100

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73. Let M be a set of  2  2  non-singular matrices and R be a relation defined on set M
such that R   A, B ; A, BM; Ais inverseof B then R is
1. Reflexive, symmetric but not transitive
2. Reflexive, transitive but not symmetric
3. Neither reflexive nor transitive
4. transitive, symmetric but not reflexive
74. If roots of the quadratic equation x2  Nx  444 N  0 are integers and N is a prime
number then number of possible values of N is
1. 1 2. 2 3. 3 4. 0
2
75. Let L : y  mx  c C1 : x  4 y C 2 : y  4 ax , a  0 be three curves in xy plane. If L
2
, ,
is normal to C1 and tangent to C2 , then the possible value of a 2 can be
1. 1 2. 4 3. 6 4. 16
76. Two circles whose radii are equal to 4 and 8 intersect at right angles. The length of
their common chord is
16 8 5
1. 2. 8 3. 4 4.
5 5
 
77. Let a  2iˆ  ˆj  2kˆ and b  iˆ  ˆj . if c is a vector such that a. c  c , c  a  2 2
     

and the angle between a  b and c is 300 , then a  b  c is equal to 
2 3
1. 2. 3. 2 4. 3
3 2

78. If the 10th term of an A.P. is 1 and its 20th term is 1 , then the sum of its first 200
20 10
terms is:
1 1
1. 50 2. 50 3. 100 4. 100
4 2
79. If A3  0 then I  A  A2 equals
1 1
1. I  A 2.  I  A 3.  I  A 4. I
80. An ellipse with foci at  0, 2  and  0, 2  and minor axis of length 4, passes through

which of the following points ?

1. 1,2 2  2.  2, 2  3.  2, 2 2  4.  2,2 
SECTION-II
65
4
dx
81. If the value of definite integral  1  2 1  2  is equal to k .Then k is equal

4
cos x sin x

to
82. The number of pairs of diagonals of a regular polygon of 10 sides that are parallel, are

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83. The mean marks obtained by 300 students in mathematics are45. The mean of top
100 students was 70 and the mean of last 100 was known to be 20. The mean of
remaining 100 students is
2
84. For a certain curve y  f  x  , d y  6 x  4 as f  x  a local minimum at x=1 and
2
dx
f 1  5 . If N is the least value of f  x  for x 0,2 then 2N is equal to
85. 10 9 8
Coefficient of x in 1  x   x 1  x   x 1  x   .....  x 1  x   x is
8 2 9 10

86. A bag contains 3 red, 2 white and 2 black balls. Two balls are drawn at random and
a
none of them is found to be a white ball. The probability that both balls are red is
b
(where a , b are co prime ) then b  a is equal to

 x  a, if x  0 x 1 if x  0
87. Let f  x    and g  x    2 Where a and b
 x  1 , if x  0  x  1  b, if x  0

are non-negative real numbers. If the composite function gof  x  is continuous for
all real x , then the values of a  b is
88. 2
Consider the equation 3 32cos6 x  48cos4 x  18cos2 x  1  sin x Number of


solutions of equation in  0,  is
 2
89. The value of a  a  0  for which the area bounded by the curves

x 1
y  , y  0, x  a and x  2a has the least value , is
6 x2
90. For some positive numbers a and b, if

cos3 x sin 3 x    b
  a  sin  2 x   cos  2 x  cot  bx   x   0,  then the value of is
sin 5 x cos5 x  20  a
THE END

SR SANKALP SUPER GRAND-1_14-04-24 Page | 12