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Journal of Electronic Materials (2024) 53:571–595

https://doi.org/10.1007/s11664-023-10809-9

REVIEW ARTICLE

A Review of Metamaterial‑Based Microwave Absorbers and Sensors


Shashi Kumar Ranjan1 · Swagatadeb Sahoo1

Received: 3 June 2023 / Accepted: 31 October 2023 / Published online: 19 December 2023
© The Minerals, Metals & Materials Society 2023

Abstract
Metamaterial-based microwave absorbers and sensors are challenging and promising topics for scientists and engineers.
In this work, we categorically review microwave absorption mechanisms, different simulation techniques, various types of
metamaterial-based microwave absorber and sensor structures, and factors affecting the microwave absorption. This review
provides an overall summary of the state-of-the-art progress on various promising and interesting metamaterial absorbers
(MTMA) and sensors. Finally, some new prospects are highlighted on advanced MTMA and sensors from theoretical and
experimental results.

Keywords Metamaterial · wideband absorber · bandwidth · electromagnetic wave · simulation · sensor

Introduction Metamaterials (MTMs) have been specifically devel-


oped to display characteristics that are not seen in natural
In order to limit the transmission and electromagnetic materials, including reverse clocking, backward propa-
wave reflection for a specific range of frequencies, absorb- gation, negative refraction index, and Doppler effect.18
ers are widely utilized in wireless technology for numer- The composite materials with distinctive properties have
ous applications, including antenna reduction for radar been described by the Greek word "meta" which signi-
cross sections,1,2,3,4,5,6 electromagnetic interference(EMI)/ fies qualities beyond those that are found in nature.19 In
electromagnetic compatibility (EMC) applications,7,8,9,10 recent years, metamaterial-based applications have grown
antenna side lobe reduction,11 and sensing.12,13,14,15,16 Elec- exponentially. Antennas and other communication-related
tromagnetic radiation-absorbing materials, and in particular electrical technologies have benefited greatly from the
microwave-absorbing materials, have been of great research metamaterial design, including artificial magnetic con-
interest because of the increasingly stringent government ductor (AMC), 20,21,22,23,24 frequency-selective surface
standards during the 1990s to monitor and control electro- (FSS), electromagnetic band gap (EBG),25,26,27,28 radio fre-
magnetic radiation. For a material to act as an absorber, it quency identification (RFID),29,30,31,32,33,34,35 and absorber
must meet two basic requirements.17 applications.35,36,37,38,39,40
A metamaterial absorber is an artificially built surface
• Relies on the electrical conductivity, as well as the per- composed of several periodic unit cells with a low profile,
mittivity and permeability, of the material utilized light weight, and a range of absorption capabilities. Con-
• Low reflection from the air-absorber contact sequently, metamaterial absorbers have been the subject
of in-depth research in the last few decades. The operating
guidelines are primarily determined by the impedance match
between metamaterial absorber and free space. We can
characterize the electromagnetic properties of metamaterial
* Swagatadeb Sahoo absorbers based on effective permittivity (𝜖eff ) and perme-
swagatadebsahoo@gmail.com
ability (𝜇eff ). For effective impedance matching,
√ the imped-
Shashi Kumar Ranjan ance value of a metamaterial must be Z = 𝜇0 𝜇eff ∕𝜀0 𝜀eff
2021rsec013@nitjsr.ac.in
which is equal√to the free-space impedance derived by the
1
Department of Electronics and Communication Engineering, formula Z0 = 𝜇0 ∕𝜀0 . Calculations are typically done on
National institute of Technology Jamshedpur, Jamshedpur, the S-parameters of metamaterial absorbers to determine
Jharkhand 831014, India

13
Vol.:(0123456789)
572 S. K. Ranjan, S. Sahoo

their effective permittivity and permeability.41 A significant absorber (MTMA), the effective permittivity and permeabil-
development is observed in MTM structures which allow for ity of a metamaterial can be adjusted to achieve the imped-
the utilization of ultrathin structures consisting of periodic ance matching with free space.65 In this case, the interface
unit cells in the subwavelength regime to achieve almost does not allow reflection by giving the full incoming wave
unity absorption through ohmic and dielectric loss.42 MTM an opportunity to be absorbed by MTMA. Interference the-
absorbers of various designs have been developed, includ- ory assumes that many inner reflections with the dielectric
ing single-band,43,44 dual-band,45,46,47 triple-band48,49,50 substrate cause destructive interference of multiple-order
bandwidth-enhanced,51,52 and even broadband.53,54,55 Each reflection.
design contributes different characteristics.
Sensor research is one of the most captivating areas
of metamaterial development. Metamaterial sensors, as a Impedance Matching Theory
potential form of sensing mechanism, may break the resolu-
tion limit of conventional sensors and provide the advantage An MTMA is generally a sandwiched structure consisting
of quick response, high sensitivity and simple measurement. of an array of certain metallic patterns on one side while
By optimizing the microstructure (single split-ring, double the other side is backed with a highly conductive metallic
split-ring, nested split-ring, asymmetric split-ring, three- ground plane of substrate as illustrated in Fig. 1. The elec-
dimensional split-ring, etc.), remarkable advancements in tric permittivity and magnetic permeability of the material
the sensing properties of metamaterial sensors have been is given by
realized. Metamaterial sensors are further validated by 𝜀 = 𝜀0 𝜀r (𝜔) and 𝜇 = 𝜇0 𝜇r (𝜔)
the utilization of ultrathin substrate or low-index substrate where 𝜀0 and 𝜇0 are the free-space permittivity and perme-
material and integrating microfluidics to predict material ability, and 𝜀r (𝜔) and 𝜇r (𝜔) are the frequency-dependent
characteristics across a wide range of frequencies. The meta- permittivity and permeability of the medium.
material is suitable for understanding and predicting mate- Due to the existence of a ground plane, there can be no
rial properties under various frequency regions.56,57 Also, transmission on the other side of the metamaterial. As a
sensing metamaterials can be utilized in various types of result, we turn our attention to the reflection. According
substances, both s­ olids58,59 and liquids.60,61 A chiral meta- to the Fresnel formula of reflection, the reflectivity R of
material sensor is used to determine humidity, thickness, MTMA ­is66
and permittivity values.62 Microfluid-sensing applications √
are developed for adulteration detection of fuels and oils.63 � �2
� 𝜇r cos 𝜃 − n2 − sin 𝜃 �
There are still many problems related to microwave sensors RTE = ��rTE �� = �� √ �
� (1)
� 𝜇 cos 𝜃 + n2 − sin 𝜃 �
that need to be addressed, such as accuracy, cost, size, and � r �
real-time measurements.
� √ �2
� 𝜀r cos𝜃 − n2 − sin 𝜃 �
RTM � � �
= �rTM � = � √ �
� (2)
Physics Mechanism for Microwave � 𝜀 cos𝜃 + n2 − sin 𝜃 �
� r �
Absorption
TE: transverse electric polarized wave
The mechanism of absorption in a metamaterial can be eas- TM: transverse magnetic polarized wave

ily understood by impedance matching and interference n = 𝜀r 𝜇 r → effective refractive index
theory.64 In impedance matching theory, due to the develop-
ment of electric and magnetic resonance in the metamaterial

Fig. 1  Layout of a metamaterial absorber.53

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 573

�√ √ �2 2jk d
− cos2𝛼
� Z − Z0 �2 � 𝜇r − 𝜀r � t12 t21 e t
R = �� � =�√
� � √ �� (3) = r12 − 2jk d (6)
� Z + Z0 � � 𝜇 + 𝜀r � 1 + r21 e
− cos2𝛼
� r � t


Z = 𝜇𝜀 ∶ impedance of the metamaterial where r = |r|ej𝜙 , t = |t|ej𝜃
√𝜇 𝛼 ∶ incident angle
Z0 = 𝜀 0 : impedance of free space 𝛼t ∶ refraction angle
0 √
Because no transmission occurs, the absorption profile k2 =
2𝜋 𝜀2
𝜆0
becomes
The highly conductive lower surface region provides a
� √𝜇 − √𝜀 � 2 phase shift of 180◦ to the EM wave reflecting on it, so that
� Z − Z0 � 2 � r � r23 = −1
A = 1 − R = 1 − �� � =1−�√ r
� � √ �� (4)
� Z + Z0 � � 𝜇 + 𝜀r �
� r � Φ21 + 2𝛽 → 𝜋 + 2n𝜋, N = 0, ±1, ±2, ±3, … which can be
explained by the theory of electromagnetic wave tunneling
Equation 4 suggests that impedance matching Z = Z0 or 𝜇r = effect.
𝜀r is the condition for obtaining perfect absorption. It should
be noted that simultaneous electric and magnetic resonance Absorption Phenomenon
is necessary for impedance matching in MTMA.
The mathematical expression for the absorption phenomena
of a metamaterial is denoted by the equation given below:
Interference Theory
2 2
A(𝜔) = 1 − ||S11 (𝜔)|| − ||S21 (𝜔)|| (7)
Magnetic resonance induced due to antiparallel current
exists between the front and back metallic layers. This In Eq. 7, S11 represents reflected power while S21 is transmit-
magnetic response is insufficient for providing imped- ted power
ance matching or absorption, 67 and hence to explain the The bottom layer of a metamaterial absorber (MMA) con-
absorption mechanism, interference theory is used.68 A sists of copper material, which prevents the transmission of
certain metallic pattern on the front layer is considered as EM waves through this layer. Hence, S21 becomes zero and
a partial reflection surface that may be used to alter the absorption depends upon theS11 parameter. Now the absorp-
complex reflection and transmission coefficient. Figure 2 tivity can be defined as:
shows that the multilayer reflection occurs from the dif- 2
A(𝜔) = 1 − ||S11 (𝜔)|| (8)
ferent layers, so that overall reflection can be calculated
by the superposition principle from classical electromag- A lower value for S11 indicates that the absorption value
netic (EM) theory.69 of the metamaterial absorber is close to unity, which sug-
RTotal = R1 + R2 + R3 + … gests that an increasing number of waves are being absorbed.
2jK d 4jk d (5) It is possible to provide an explanation for the absorption
− cos 2𝛼 − cos2𝛼
= r12 + t12 r23 t21 e t + t12 r223 r21 t21 e t +…

Fig. 2  A classical model for interference theory.67

13
574 S. K. Ranjan, S. Sahoo

mechanism by carrying out an evaluation of the effective the unit cell are crucial for the performance of the
electromagnetic parameters (𝜖eff and 𝜇eff ) using the equa- absorber. Split rings (MHz to GHZ), patches (THz),
tions as follows: fishnets (optical range), and Jerusalem crosses are
√ examples of common unit cell forms. The dimensions
√( )
√ 1 + S 2 − S2
√ will be determined by the selection of the frequency
Z=
11 21
(9) range of interest and the material employed.
2 2
( 1 − S11 ) − S21
4. Simulation and optimization: Utilize electromagnetic
⌈ ⌉ simulation software to simulate and examine the meta-
1 1 ( ) material absorber’s behavior. This process aids in unit
cos−1 (10)
2 2
𝜂= 1 − S21 − S11
kd 2S21 cell parameter optimization to provide the appropriate
absorption properties.
where 𝜂 = refractive index, Z = impedance, d = thickness of 5. Tunning and adjustment: In order to obtain maximal
the MMA, k = wave number. absorption at the specified frequency, fine-tuning of the
It is possible to determine the effective electromagnetic metamaterial structure is required. This could involve
parameters by using the relation described in Eqs. 11 and adjusting the unit cell sizes, spacing, and orientation.
12, and the normalized impedance can be determined by 6. Broadband versus narrowband absorption: A nar-
Eq. 13. rowband MTMA provides very sharp resonance and
𝜂 acquires limited bandwidth, whereas a broadband
𝜀eff =
z
and 𝜇eff = 𝜂z (11) MTMA provides a wider frequency range. It is up to
the researcher to determine whether they need a nar-

𝜇0 𝜇eff

𝜇eff rowband or broadband absorber.
Z(𝜔) = = 𝜂0 (12) 7. Polarization and incident angle sensitivity: Practical
𝜀0 𝜀eff 𝜀eff
applications require an absorber whose performance
√ remains constant regardless of incidence or polari-
𝜂 Re(𝜇eff ) − jIm(𝜇eff ) zation angle. As a result, microwave absorbers with
Normalized Impedance = 0 = incidence and polarization angle stability are a key
z Re(𝜀eff ) − jIm(𝜀eff )
development objective within the research community.
(13)
The physics behind polarization- and incident-angle-
insensitive MTMA includes special design strategies
and principles such as symmetry in unit cell design,
phase matching, bi-anisotropic or chiral metamaterial,
Design and Simulation of MTMA Structure engaging multiple resonance, magnetic and electric
coupling, and multilayer or graded structures.
Design 8. Thickness and compactness: Determine the absorber’s
thickness and total size, as they are essential for practi-
Designing a metamaterial absorber requires careful con- cal applications where space is restricted.
sideration of several aspects in order to obtain the desired 9. Fabrication consideration: Feasibility and practicality
absorption qualities for specified wavelengths or frequency should be considered for MTMA fabrication. Details
ranges. Some crucial factors and considerations for devel- of the fabrication process are described in section (7).
oping a metamaterial structure are as follows: 10. Material losses: The overall absorption of the MTMA
can be affected by inherent absorption loss of some
1. Selection of frequency/wavelength range: Determine material, which should be taken into account regarding
the frequency or wavelength range of interest for which the selection of material for MTMA.
the absorber can perform. The complete design process 11. Environmental factor: The chosen material should
will be guided by this selection. resist the environmental variation if the absorber will
2. Material selection: Select the best material for the be used in different climate scenarios (such as high
metamaterial construction. Metamaterials are man- humidity or high temperatures).
made composites with non-natural qualities and are 12. Validation and testing: Validate the metamaterial
often composed of periodic subwavelength unit cells absorber performance with the use of a testing mecha-
that interact with electromagnetic radiation in certain nism when the fabrication is complete. The setup for
ways. the testing or measurement is shown in Fig. 3.
3. Unit cell design: The unit cell is the metamaterial’s
primary repeating structure. The shape and size of

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 575

Fig. 3  Free-space measurement setup for (a) normal incidence,54 (b) oblique incidence.54

Simulation the periodic boundaries, a certain polarized plane wave is


incident on the structure. The complex scattering param-
Because of the fast growth of the contemporary antenna sec- eters are the output of all simulation setting listed above.
tor, computational technologies for modeling the interaction This parameters include the transmission coefficient ( S21)
between electromagnetic waves and materials with complex and reflection coefficient (S11). Simulation also characterizes
structures are quite advanced and may thus enable accurate the phase of S11 and S21 at different angles of incidence for
prediction of the MTMA performance. Many metamate- different types of polarization. Figure 4a shows the values
rial experts are using commercial software to predict the of R(𝜔), T(𝜔) and A(𝜔) obtained from the MTMA.73 The
behavior of their devices before the start of manufacturing. MTMA is also characterized by the extracted permittivity,
One advantage of MTMA simulation is that it allows for permeability, and refractive index as an efficient homogene-
the design of an optimized structure and the prediction of ous material as illustrated in Fig. 4b.74 Simulation can be
behavior without the need for extra fabrication iterations. used to investigate specific properties of MTMA which can-
Furthermore, if the material characteristics are well estab- not be determined experimentally, such as electric (E) and
lished, there is often a good match between simulated and magnetic (H) field distribution and surface current distribu-
experimental results due to the precision of the simula- tion inside and outside the MTMA. This distribution may
tion approaches. CST Microwave Studio,70 Ansys HFSS,71 also reveal the main absorption mechanisms in the MTMA.
and ­COMSOL72 are a few of the most popular simulation Most simulation programs can retrieve these parameters
programs. The most essential measurement for MTMAs by inserting corresponding field monitors at the frequency
is undoubtedly absorptivity, and as discussed earlier, the of interest. Figure 4c, d e and f depict several examples of
absorption is calculated using Eq. 7. Reflectivity and trans- monitoring the electric field, magnetic field, surface current
missivity are obtained by setting proper boundary condi- distribution,75 and power loss density.76
tions and excitation in the simulation. Here, a plane wave
either with periodic boundary conditions or with the pres-
ence of waveguide port perfect electric (PE) or perfect mag- Classification of MTMA
netic (PM) boundary conditions can be applied. Using the
finite difference time domain (FDTD) mathematical tool, Initially, it was expected that metamaterial absorbers
one can simulate the interaction between the periodic struc- would have a restricted bandwidth and function at certain
ture and EM waves. A transverse electromagnetic (TEM) frequencies. Depending on absorptivity, various MMA have
wave is excited on the designed structure in the presence been designed and formulated including single-, double-,
of waveguide ports on either side of the structure, while for triple-, quad-, penta- and multi-band absorbers.

13
576 S. K. Ranjan, S. Sahoo

Fig. 4  (a) Absorption (green), reflection (blue), and transmission with permission from Ref. 75. (e) Surface current distribution on the
(red) for MTMA backed by a metallic plane.73 (b) Real and imaginary front side. Figure reprinted with permission from Ref. 75. (f) Power
value of 𝜖 , 𝜇, and n.74 (c) E-field distribution. Figure reprinted with loss density of MTMA (Color figure online).76
permission from Ref. 75. (d) H-field distribution. Figure reprinted

Single‑Band Metamaterial Absorber procedure on an FR-4 dielectric substrate. The proposed


configuration and the absorptivity curve are shown in Fig. 5.
Soheilifar et al.77 presented a single-band MTMA which Singh et al.78 proposed a single absorber band MMA
belongs to the class of electric field-driven LC (ELC) reso- operating at a frequency of 77 GHz. The structure consists of
nators. Its first resonance is excited by an electric field com- a C-shaped split-ring resonator. They demonstrated a meta-
ponent parallel to one of its crossed wires. Unit cell dimen- material absorber capable of working at millimetre wave
sions are 10 mm × 10 mm × 1 mm using the conventional frequency of 77 GHz on the polyimide substrate of thickness

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 577

Fig. 5  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 77.

dimensions of G = 0.6, t = 0.6, H = 11.8,a1 =4.2, a2 = 12,


W = 4, L = 1.7 (in mm). Each component of the absorber
was built on an FR-4 substrate of 0.2 mm thickness. They
validated the proposed structure by conducting a study on
complex S-parameters of a broad planar array of pixel loca-
tions (outer dimensions of 15 ×15 cm). The MMA structure
and absorptivity curve are shown in Fig. 7.
Cheng et al.80 designed and simulated a metamaterial
absorber with dimensions (in mm) of d = 0.2, g = 0.6,
t = 0.6, w = 0.3, a = 12, b = 4.2, along with single copper
wire of dimensions h = 11.8 mm and l = 1.6 mm. An FR-4
lossy substrate of 0.3 mm thickness was used to manufacture
each metallization. Measurement of the fabricated structure
provides an absorptivity of around 98% at 10.4 GHz. The
final configuration and the absorptivity curve are illustrated
in Fig. 8.

Dual‑Band Metamaterial Absorber

Wen et al.81 developed a dual-band metamaterial absorber


Fig. 6  Proposed absorber design and absorptivity curve. Figure and studied the characteristics at two different absorptions
reprinted with permission from Ref. 78. of 80.8% and 63.4% near the frequencies of 0.45 THz and
0.9 THz. The whole structure is built on a 500 𝜇m SI-GaAs
substrate, as illustrated in Fig. 9. The proposed resonator
125 𝜇m which was introduced for the first time as flexible dimensions (in mm) are as follows:
substrate. The proposed configuration and the absorptivity t4 = 13, t3 = 14, t2 = 4, t1 = 6, l = 28.6, h = 55, b = 120,
curve are shown in Fig. 6. a = 60 . Sputtering and spin coating with 10 mm polyim-
Landy et al. 79 proposed an MTM absorber for high ide was used to create the device. Reactive ion etching was
absorbance at 11.5 GHz. This narrowband absorber was used to form it into the desired electric split-ring resona-
designed with two common split-ring resonators which are tor (ESRR) shape. Au film of 200 nm is deposited on the
connected by an inductive ring parallel to the split-wire top of the polyimide film. The overall dimensions of the

13
578 S. K. Ranjan, S. Sahoo

Fig. 7  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 79.

Fig. 8  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 80.

absorber are 140 × 124 𝜇m2 . Both the design configuration are presented in Fig. 10. These spectra are determined using
and absorptivity curve are shown in Fig. 9. an equivalent circuit model and are compared with those
Liu et al.82 employed a straightforward MTMA configura- obtained through FDTD simulation. The comparison reveals
tion which consists of a periodic arrangement of graphene a high level of agreement between the two sets of results,
patches placed on top of a dielectric spacer, and this setup is confirming the accuracy and effectiveness of the equivalent
capped with a metallic back reflector to create a dual-band circuit model.
terahertz absorber. Based on the outcomes of both simula- Li et al.83 proposed a microwave-based dual-band meta-
tion and an analytical circuit model, the proposed absorber material absorber. They performed both experimental and
is able to achieve complete absorption at frequencies of 0.5 simulation analysis and confirmed that almost complete
THz and 0.15 THz. The absorption spectra of the structure absorption is attained at near 11.15 GHz and 16.01 GHz.
The structure contains a single split-ring resonator whose

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 579

Fig. 9  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 81.

Fig. 10  Proposed absorber design and absorptivity curve.82

inner (r2 ) and outer radius (r1 ) are 2.3 mm and 2.7 mm, planar sheets for dual- and triple-band absorbers by adjust-
respectively. The same width of 0.2 mm is maintained for ing the scale factor of the ELC unit cell. The ultimate opti-
both wire thickness and the capacitor gap. The length of mized geometry of a single ELC is a = 5 mm, d = 3.6 mm, l
a capacitor positioned at the center of a unit cell (dimen- = 5.5 mm, w =0.4 mm, g = 0.2 mm, and the thickness of the
sions 25 × 25 mm) is 1.6 mm. The proposed configuration copper film is 0. 035 mm. The fabricated structure acquires
and absorptivity curve are displayed in Fig. 11. three absorption peaks at 7.44 GHz with 97.8% absorption,
10.37 GHz with 95.9% absorption, and 12.27 GHz with
Multiple‑Band Metamaterial Absorber 98.6% absorption, respectively. The proposed configuration
and absorptivity curve are shown in Fig. 12.
Li et al.84 proposed a multiple-band metamaterial absorber Shen et al. 85 proposed a triple-band metamaterial
based on an ELC resonator fabricated on two 240 × 240 mm2 absorber consisting of three concentric square rings of

13
580 S. K. Ranjan, S. Sahoo

Fig. 11  Proposed absorber design and absorptivity curve. From Ref. 83, reproduced courtesy of the Electromagnetics Academy.

Fig. 12  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 84.

different sized unit cells. The ring dimensions are optimized the unit cell are a = 18 mm, d1 = 8.37 mm , d2 = 6.4 mm ,
at w1 = 84 𝜇m , w2 = 56 𝜇m and w3 = 36 𝜇m . The absorp- d3 = 4.7 mm , w = 0.25 mm, W1 = 0.35 mm , and
tion spectrum of simulated and experimental response shows W2 = 0.42 mm , while the copper film is 0.035 mm thick. To
absorption rates of 96.4%, 96.3%, and 96.7% at frequencies validate the simulation result, the structure was constructed,
f1 = 0.50 , f2 = 1.03 and f3=1.71 THz, respectively, with and experimental studies were conducted. The experimental
nearly unity absorption peak. The performance of the pro- measurement depicts absorptions peak values of 94.98 GHz
posed absorber is quantitatively assessed using the multi- at 5.25 GHz, 87.1 GHz at 7.158 GHz, 94.06 GHz at 10.02
ple reflections interference theory. The MMA structure and GHz, and 87.1 GHz at 10.5 GHz. The proposed configura-
absorptivity curve are illustrated in Fig. 13. tion and absorptivity curve are shown in Fig. 14.
Bhattacharyya et al.86 proposed a square-shaped closed- In conclusion, all the abovementioned and some existing
ring resonator-based triple-band polarization-independent multi-band metamaterial absorbers possess their own indi-
metamaterial absorber with a broad angle of incidence, vidual set of characteristics, advantages and applications as
operated in airborne and surveillance radar applications, shown in Table I.
particularly under C-band and X-band. The dimensions of

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 581

Fig. 13  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 85.

Fig. 14  Proposed absorber design and absorptivity curve. Figure reprinted with permission from Ref. 86.

Wideband Metamaterial Absorber or broadband structures as a means of breaking the narrow-


band constraint. This has been accomplished in a variety of
The narrowband absorption of the MMA is a great disad- ways, such as by developing multi-resonant structures or unit
vantage. To broaden the absorption bandwidth, researchers cells with proper impedance matching at many frequencies.
have employed several methods including multilayer, multi- Ultimately, the final absorption spectrum, which displays
resonant, and single-layer structures. Similar to Jaumann several resonance peaks, may be roughly thought of as the
absorbers, they utilize numerous dielectric layers with metal- linear superposition of the various resonance peaks. Differ-
lic patterns and a continuous metallic ground in the multilayer ent structures have been reported using this mechanism. Ding
technique. The multiple dielectric layers create total destruc- et al.96 proposed an absorber composed of multilayer metal-
tive interference, and the metamaterial absorber completely lic-dielectric quadrangular frustum pyramids. The absorber
absorbs all incident waves. This technique allows for broad illustrated in Fig. 15a has a unit cell consisting of 20 metal
absorption, but the primary issue is the dielectric thickness. A patches, each with a width that tapers linearly from top to bot-
large volume of research has been devoted to multi-resonance tom; between every pair of metal patches is a dielectric patch.

13
582 S. K. Ranjan, S. Sahoo

Table I  Comparison among existing multi-resonant MTMA structures


References Year Substrate Unit cell Resonant frequency (GHz) Absorption (%) Operating band/ Polarization
dimensions application sensitivity
(mm)

84 2011 FR-4 240 × 240 7.46,10.43, 12.23 99.1,94.8,92.5 RCS reduction Up to 60°
and in aircraft
and stealth
technology
86 2013 FR-4 252 × 252 5.258,7.518, 10.02,10.49 94.98,87.1, 94.06,87.1 Radar stealth/C- Up to 60°
and X-bands
87 2020 FR-4 5×5 17.32,21.87,29.43,35.3 99,97.11, 94.71,97.71 5 G application, Insensitive
MIMO antenna
isolation
enhancements
88 2020 FR-4 10 × 10 3.35,5.1,9.5,11.55,16.6 99.59,95.49, 97.5,99.25, 93.89 RCS reduction Up to 60°
and airborne
application
89 2020 FR-4 128 × 128 4.1,6.86,11.3,13.45 97.9,99.1, 99.5,99.95 C-, X-, Ku-bands Insensitive
90 2014 FR-4 252 × 252 4.828,5.556, 8.058 99.3,94.1, 99.5 Airborne and Up to 60°
surveillance
radar/C-band
91 2014 FR-4 230 × 230 3.91,5.16, 7.10,9.16 99.35,98.04, 99.85,99.78 Radar, IR Up to 45°
camouflage,
Imaging/S, C-
and X-bands
92 2015 FR-4 256 × 256 3.4,8.34,9.46,14.44,16.62 98.6,96.6,90.1,97.8,93.1 Airborne radar, Up to 45°
stealth tech-
nology, and
radome/S-, X-,
and Ku-bands
93 2013 FR-4 25 × 25 6.45,7.4,9.1,11.0 97,98,98,98 Not reported Up to 45°
94 2017 FR-4 10 × 10 5.28,7.36,9.52,12.64,16.32 92.03,90.46,95.10,91.65,91.10 Stealth technol- Insensitive
ogy, elec-
tromagnetic
interference
and airborne
radar systems
95 2019 FR-4 12 × 12 3.1,5.5,7.6,10.98 90 EM wave Insensitive
protection
and military
purpose/S-, C-
and X-bands

Figure 15b depicts the distributions of E-field and H-fields at layer, a metallic ground, and metallic patterns. The metal-
various frequencies to understand the physics behind the pro- lic designs were refined to achieve polarization-insensitive
posed ultra-broadband MA system. It is clear that at a specific wideband absorption. In this context, Barde et al.97 pro-
frequency, a particular area of the pyramid experiences reso- posed a wideband metamaterial absorber (WBMMA) for
nant localization and electromagnetic field absorption. The Ku (12–18 GHz) and K (18–27 GHz) bands with average
electromagnetic field is confined at the base of the pyramids absorptivity of 98% at frequencies of 16.54 GHz, 20.54
at lower frequencies, and due to the increase in frequency, it GHz, and 25.81 GHz. The observed and computed absorp-
progressively climbs to the top side. The absorptivity curves tion measurements show almost identical results, with little
clarify that the absorption occurs from 8 GHz to 14 GHz over variation in manufacturing tolerance. Investigation of the
a wide band range, as depicted in Fig. 15c. unit cell is performed for both different oblique (up to 45°)
The single-layer structures are another technique for wide and normal incidence, confirming absorption up to 80% as
bandwidth formation. Compared to the preceding construc- depicted in Fig. 16.
tion types, these single-layer structures are thinner and To achieve wideband absorption, researchers have typ-
more compact. The structure is characterized by a dielectric ically employed lumped components such as resistors,

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 583

Fig. 15  (a) Proposed metamaterial absorber design.96 (b) Generated Absorption capacity of the proposed absorber. Figure reprinted with
electric and magnetic amplitude distributions at frequencies of 8.3 permission from Ref. 96.
GHz, 10 GHz, and 12 GHz on a unit cell’s center cross section.96 (c)

Fig. 16  Design of the proposed metamaterial absorber and absorptivity curve. Figure reprinted with permission from Ref. 97.

capacitors, and diodes, and single resonant structures of GHz and 90.48% at 12.50 GHz, respectively, as illustrated
higher order. Ranjan et al.98 designed a unit cell compris- in Fig. 17b, which confirms the utility of the proposed
ing four resistors in a square shape, and the whole struc- MMA as a wideband MMA.
ture is formed using copper as the conducting material In summary, all the abovementioned along with other
and FR-4 as the dielectric material. The dimensions of existing wideband absorbers, each having a unique set
the unit cell are 14 × 14 mm , with thickness of 3.5 mm, of traits, benefits, and applications, are illustrated in
as shown in Fig. 17a. Simulated and fabricated proto- Table II.
types are investigated and the results are almost iden-
tical, showing two absorption peaks of 91.56% at 5.25

13
584 S. K. Ranjan, S. Sahoo

Fig. 17  (a) Front view of the proposed MTMA.98 (b) Simulated absorptivity of the proposed structure.98

Table II  Detailed comparison of existing wideband metamaterial absorbers


References Size of unit cell FWHM Band- Frequency range Absorption (%) Use of lumped Application
(mm) bandwidth width (GHz) element
(GHz) (GHz)

96 11 × 11 NA 6 8–14 > 90 No Not reported


97 5 × 1.41 16.39 13.43 14.44–27.87 > 98 No K- and Ku-bands
98 14 × 14 9.44 8.32 4.68–13 90 Yes EMI, stealth technol-
ogy
99 300 × 300 10 11.1 3.1–14.2 > 90 Yes Not reported
100 9×9 7.55 5.98 5.94–11.92 > 98 No X-band
101 10 × 10 11.32 8.76 11.39–20.15 > 80 No Ku-band
102 9×9 NA 10.2 7.92–18.12 > 95 No X- and Ku-bands
103 20 × 20 NA 1.74 1–2.74 > 95 Yes UHF-RFID systems
and 4 G communi-
cations
104 190.4 × 190.4 8.25 5.9 5.3–11.2 > 70 Yes C- and X-bands
105 13 × 13 NA NA 4.96–18.22 > 96 Yes C- ,X- and Ku-bands
106 462 × 343 NA NA 9.05–11.4 > 80 No X-band
110 22 × 22 NA 4 8–12 90 No RADAR applications
111 15 × 15 NA 9.3 8–18 > 90 Conductive ink RCS reduction
112 0.085 × 0.085 NA NA 500–2500 > 80 No X-band
113 18 × 18 NA 6.4 5.6–11.29 > 80 No Radar application
114 9×9 NA 10.78 4.15–14.93 > 80 No Radar

Radar‑Absorbing Material bandwidth, the need to develop stealth technologies for


dodging radar detection has increased. In the military sec-
Since the advent of microwave radar during the Second tor, stealth technology plays a key role due to rapid advance-
World War, these devices have posed the greatest threat ment of material science and electronics. Stealth technol-
to aircraft due to their ability to identify distant airborne ogy’s radio frequency (RF) and microwave components
objects regardless of the time of day or weather. Addition- in this respect are primarily concentrated on lowering the
ally, since radar technology has advanced over time thanks radar cross section (RCS). Various mechanisms are applied
to the employment of powerful transmitters with a wide for RCS reduction (RCSR). Shaping is the main stealth

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 585

technique used to lower RCS. Shaped aircraft are stealthier, metal backing for a wideband radar absorber which covers
but they face many challenges. Even while stealth may be both X- and Ku-band. According to the measured results, a
produced by good aerodynamic design, it is frequency- 62% fraction bandwidth, or effective absorption bandwidth,
dependent, making it difficult to achieve broadband reduc- spanning from 10.4 GHz to 19.7 GHz may be achieved with
tion.107 An interesting solution for RCSR at microwave fre- only 2 mm thickness. The graph shows the simulated reflec-
quencies is radar absorbers. In the development of stealth tion coefficient (S11 ) and absorption value of the absorber
flying systems, research has been focused on wideband for various silicone thicknesses, and h = 2 mm allows for
lightweight radar absorbers. The stealth technique conceals the widest bandwidth to be attained. In this instance, the
a vehicle or building from radar detection by using radar- optimized absorber is operated under both X- and Ku-bands,
absorbing materials (RAMs). The absorbent material must yielding significant absorption (> 90%). The sustained wide-
be thin and have great absorption properties across a broad band absorption shows graphene nanoflake radar absorber’s
frequency range.108 The considerable trade-off between potential uses in delivering RCS reduction for objects of
thickness and bandwidth, however, poses a significant obsta- diverse forms. Figure 19 displays the proposed layout as well
cle to the creation of high-performance radar absorbers.109 as the absorptivity curve.
Broadband radar absorbers are continuously required for Wang et al.112 proposed a model which has four rectan-
modern military applications. Therefore, Ali et al.110 pre- gular metallic rings, a metallic ground plane, and a polariza-
sented a six-band and almost polarization-insensitive MMA tion-insensitive terahertz metamaterial absorber, separated
which is formed by a closed circular ring resonator (CCRR) by a dielectric layer. With an average absorption of almost
and metallic ground plane separated by FR-4 dielectric sub- 97%, four different absorption peaks are detected at 0.777
strate. The operation of the intended absorber, the surface THz, 1.13 THz, 1.53 THz, and 2.06 THz frequencies. The
current, and the distribution of the electric field were exam- overlapping of four resonant frequencies is thought to be the
ined and reported for analysis. The proposed metamaterial mechanism of the four-band absorber, and the distributions
absorber yields absorption of 98%, 98%, 91%, 98%, 100% of the E-field are used to examine the process of absorption.
and 100% at 11.85 GHz, 11.16 GHz, 10.66 GHz, 9.88 GHz, By altering the size of the corresponding metallic ring, each
9.2 GHz and 8.3 GHz, respectively, and can be treated as absorption peak’s frequency can be flexibly controlled. The
a strong option for military radar applications. Figure 18 high degree of symmetry of the five-square-ring structure
displays the proposed layout and the curve related to MA ensures that the polarization-insensitive absorption feature
absorptivity. still holds true for the five-band case. Applications for the
Huang et al.111 presented a model and experimentally suggested structure include stealth, imaging, and detection
evaluated a flexible, conformable wideband radar absorber technologies. Figure 20 shows the preferred layout as well
made out of a layer of nanoflakes constructed from graphene as the absorptivity curve.
with a printed patterned structure, a silicon substrate, and a

Fig. 18  Proposed metamaterial absorber design and absorptivity curve. Figure reprinted with permission from Ref. 110.

13
586 S. K. Ranjan, S. Sahoo

Fig. 19  Proposed metamaterial absorber design and absorptivity curve.111

Fig. 20  Proposed metamaterial absorber design and absorptivity curve.112

In summary, all the abovementioned along with other sensors based on metamaterials, a variety of metamaterial-
existing wideband and radar absorbers, each with unique set based components have been developed for collecting the
of traits, benefits, and application, are illustrated in Table II. details of a substance as well as the circumstance. Metama-
terials can display high field localization and enhancement,
allowing them to be utilized to increase sensor selectivity for
Metamaterial as a Sensor detecting nonlinear chemicals and detect extremely tiny con-
centrations of analytes.115 Conventionally, sensing devices
The science of metamaterials has advanced significantly in are used to analyze minor changes based on four criteria.
recent years. Novel improved characteristics of metamateri- First, the operating frequency of the sensors must be kept
als have been achieved in the submicron and nanoscale range low to restrict background absorption followed by substrate
due to advancement of design and production of metamateri- absorption. Since typical sensing instruments possess a small
als. Therefore, the interdisciplinary border between sensing surface area and are therefore more likely to be operated fre-
technology and metamaterials research has developed into a quently, this presents a substantial difficulty. As a result, it is
productive area for new scientific and technical advancement. essential that the layout of the sensor is kept compact while
Due to the significant advancements achieved in research of also minimizing its working frequency. Second, the sensors

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 587

need to generate a potent, detectable readout signal with a bioprocess was used to bind biotin and streptavidin, as shown
sharp enough resonance characteristic to precisely follow in Fig. 21b. The split-ring resonator (SRR)-based biosensor
the shift in transmission spectra. The third criterion focuses operates on variation of resonant frequency which is a useful
on the linearity of sensing, which has been shown to cor- microwave characteristic. This is due to the SRR’s basic √ LC
relate with the quality factor of sensors. Fourth on the list circuit nature, which has a resonant frequency of f0=1∕ LC .
of requirements is the sensitivity of the sensor.116 Micro- As stated in the formula, the inductance and/or capacitance
wave sensors are widely used in industrial, biological, and variations affect the resonant frequency. Lee et al.119 presented
electrical applications because of their advantages such as DNA sensing using a split-ring resonator alone in the micro-
high sensitivity, versatility, affordable production costs, and wave regime, demonstrating the viability of employing a sin-
straightforward measurement techniques. Based on the operat- gle element double split-ring resonator as a biosensing device
ing frequency of the detecting biomolecule and component, in Fig. 22a. Figure 22b displays the distributions of induced
metamaterial-based sensors are classified into three types: surface currents at the resonant frequency as well as the reso-
microwave biosensors, terahertz biosensors, and plasmonic nance of S21, which has a value of 10.2 dB at 12.35 GHz.
biosensors. Another classification of metamaterial sensor has The outer and inner ring boundaries are where the surface
been reported by Ref. 117 which is based on the physical current is concentrated because of the proximity effect and
structure. Lee et al.118 proposed a metamaterial-based micro- well-known Maxwellian distribution, as seen in the image.
wave sensor based on a split-ring resonator as illustrated in Terahertz waves, which are located between the micro-
Fig. 21a and experimentally demonstrated for a biosensing wave and infrared (IR) regions, have assumed a significant
device at microwave frequency. Streptavidin and biotin were role over the past few decades in the detection of chemical
utilized in this investigation to show the split-ring resona- and biological substances.120 Sensing a sample’s complex
tor capacity for biosensing. It is widely known that a very dielectric properties in the terahertz region can directly
high affinity coupling system is developed by noncovalent reveal the chemical or biological molecular composition by
attachment of these biomaterials. They have been frequently detecting resonant absorption of molecules or phonon reso-
employed for finding selectivity and sensitivity properties of nance for small-molecule compounds.121,122 As no conspicu-
biosensors due to their unique and strong chemical attrac- ous absorption patterns are seen for large biomolecules, the
tion. Because ss-DNA and Au have a strong chemical affinity, unmistakable detection and identification of macromolecules
single-stranded deoxyribonucleic acid (ss-DNA)-linked biotin is accomplished by the dielectric changes brought about by
was used to immobilize on the Au surface. The sample surface the interaction of biomolecules. However, a considerable
was covered with an Au layer. Following immobilization, a

Fig. 21  (a) Surface current directions and capacitances generated outer rings is denoted as ro. Figure reprinted with permission from
in the SRR: mutual and gap capacitances are denoted by Cmut and Ref. 118. (b) Resonant frequency for the detection of biotin and
Cs, respectively. Ii and Io stand for the inner and outer rings’ respec- streptavidin binding. Figure reprinted with permission from Ref. 118.
tive surface currents. The average separation between the inner and

13
588 S. K. Ranjan, S. Sahoo

number of the applications that are being considered for tera- of chemical or biological molecules, flexible and sensi-
hertz sensing systems require the detection of small amounts tive solutions are urgently needed. Recently, Wang et al.123
of chemical and biomolecular components involved in secu- proposed a model for protein concentration measurement
rity application to fundamental instrumentation research. It using a biosensor operated at terahertz frequency. The bio-
is difficult to accomplish this task with traditional terahertz sensor was constructed from stainless steel using laser drill-
spectroscopy instruments because of the large gap that exists ing. Maximum refractive index sensitivity of 294.95 GHz/
between the sensing wavelength and the minute nanometric RIU and a figure of merit of 4.03 are observed from the
scale of the analyte quantity with most applications. In order simulation results (Fig. 23). A continuous-wave terahertz
to probe the dielectric characteristics of minuscule amounts spectrometer is used to characterize the sample. According

Fig. 22  (a) Design of a double-sided split-ring resonator (DSRR) g = 0.2 mm between resonator and microstrip line. Figure reprinted
sample used for biosensing with the following dimensions: d = 0.1 with permission from Ref. 119. (b) Results of the DSRR sample sim-
mm between rings, c = 0.18 mm between rings, s = 0.2 mm between ulation with the resonance peak and surface current density distribu-
split-gaps inside rings, a = 0.68 mm between average ring radii, and tion. Figure reprinted with permission from Ref. 119.

Fig. 23  (a) The biosensor has a three-dimensional array schematic as well as a cell structure diagram. The structural parameters are
Px = 500 𝜇m,Py = 300 𝜇m , L = 294 𝜇m , H = 60 𝜇m , R = 60 𝜇m.123 (b) Simulated transmission of the biosensor.123

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 589

to the experimental findings, the detection sensitivity and substances such as polytetrafluoroethylene (PTFE) (n =
detection limit for the bovine serum albumin (BSA) analyte 1.43), royal demolition explosive (RDX) (n = 1.66), and
solution are 72.81 GHz/ng/mm2 and 0.035 mg/mL, respec- trinitrotoluene (TNT) (n = 1.76), as well as biological mol-
tively. The advantages of this biosensor are its compact size, ecules such as DNA (n = 1.4–1.6) and RNA (n = 1.6–2.0).
high detection sensitivity, low detection limits, reusability, Nowadays, metamaterial-based plasmonic biosensors
ease of fabrication, and affordability. To improve its sen- are used to boost the sensitivity of plasmonic biosensors.
sitivity and enable the detection of minute changes in the The benefits of adopting metamaterial sensors include
dielectric environment, the sensor requires a sharp edge in the ability to utilize a large array of geometric shapes and
its frequency response and a point of extreme electric field sensing principles that were previously not possible with
concentration.124 Bhati et al.125 discussed the creation of an conventional plasmonic biosensors. The characteristics of
innovative meta-surface with a negative refractive index. It surface plasmons are dependent on the refractive index
is composed of a regular decagon pattern made of silver of the dielectric medium. This unique ability has been
metal and is placed on top of a quartz substrate. The meta- employed in the creation of label-free plasmonic biosensors,
surface exhibits exceptional sensitivity, an extremely high which have emerged as a prominent contemporary
quality factor (QF), and a remarkably high figure of merit technology for detecting and investigating binding events on
(FOM). These properties are achieved for the purpose of a metal surface between the target analyte and its matching
detecting biological molecules within the terahertz (THz) receptor. Surface plasmon polaritons (SPPs) are currently
part of the electromagnetic spectrum. To investigate the used in the majority of surface plasmon resonance (SPR)
sensing capabilities of our meta-surface, they examined how biosensors. According to their structural characteristics,
changes in the refractive index of the surrounding dielectric biosensors based on metamaterials may be divided into
environment affect the resonant frequencies. Figure 24b dis- three classes: two-dimensional, three-dimensional, and two-
plays the transmission spectra for an analyte thickness (ta) dimensional metasurface-based biosensors. The effective
of 5 𝜇m. Notably, we observed a significant red shift in both detection of viruses among them has been accomplished
the first resonant frequency (1.13 THz shift) and the second using two-dimensional metasurface biosensors. Although
resonant frequency (1.08 THz shift) as the refractive index the application of metamaterial in biosensing is still in
increased from n = 1.2 to n = 1.6. This frequency shift is its infancy, it has already been noted that sensitivity has
understandable because alterations in the refractive index, increased by approximately an order of magnitude,126 and
effective permittivity, and permeability of the environment viruses such as human immunodeficiency virus (HIV), 127
surrounding the meta-surface have a pronounced impact on Zika virus,128 avian influenza virus,129 cowpea mosaic virus
its resonant frequencies. The substantial shift in resonant (CPMV),130 and protein-primed DNA1 (PRD1)131 have been
frequency with changes in the refractive index underscores detected using metamaterial sensors. The use of plasmonic
the device’s remarkable sensitivity for detecting important biosensors constructed on metamaterials has the potential

Fig. 24  (a) Schematic diagram of MM structure with analyte on its structure with different refractive indices (RIs) for analyte thickness
top surface. Figure reprinted with permission from Ref. 125. (b) of 5 μm. Figure reprinted with permission from Ref. 125.
Transmission spectra with an analyte applied on the top of the MM

13
590 S. K. Ranjan, S. Sahoo

to revolutionize the field of label-free point-of-care virus the resonator is mainly on the order of tens of microns.
detection. For the fabrication of a resonator of this size, the most
effective technique is photolithography, as illustrated in
Fig. 25b. 133 Fabrication in the higher-frequency range
Fabrication exceeds the capability of the photolithography process,
and hence a higher-resolution technique is required. It has
MTMAs that operate in the microwave range are mostly been shown that focused ion beam (FIB, Fig. 25c)134 and
fabricated using the printed circuit board (PCB) technique. E-beam lithography (Fig. 25d)135 are the best processes
In this process, a certain thickness of copper is deposited for fabricating MTMA that operate in the infrared and
on both sides of photosynthesized board. FR-4 is the most visible range. This technique fabricates a structure with
commonly used material for this kind of board. In this dimensions on the order of tens of nanometers. As photo-
frequency range, the resonator size lies within a maximum lithography is a flood-exposing parallel process, it exposes
of mm to minimum of 100 μ m, due to which a photo mask the sample point by point, and therefore it is a much slower
can be easily printed on the substrate with the help of serial process. Hence, this technique is used for small-area
a high-resolution printer (Fig. 25a).132 Researchers have sample fabrication. Fabrication of MTMA with compara-
attempted to increase the working range of the MTMA tively large dimensions allows for flexibility in the design.
towards higher frequencies since the initial demonstra- As a result, many researchers have introduced the lumped
tion. As the resonance of the absorber is scaled with the element-like resistor, diode and capacitor to improve the
operational wavelength, the resonator size decreases in performance. After the fabrication has been completed,
the terahertz region, so a high-precision fabrication tech- the lumped element can be soldered onto the structure as
nique is needed. In the terahertz range, many interest- shown in Fig. 25e. 136 A large-area MTMA is preferred
ing and possible applications are studied, and the size of for various applications at higher infrared frequencies.

Fig. 25  (a) Fabricated prototype of MTMA by using PCB fabrication. tron microscopy (SEM) image of single unit frequency-selective ther-
Figure reprinted with permission from Ref. 132. (b) Optical micros- mal emitter (FTSE) fabricated by e-beam lithography.135 (e) Image of
copy image of fabricated absorber structure with photolithography fabricated prototype by using lumped element.136 (f) SEM image of
process.133 (c) Focused ion beam (FIB) photograph of Si wafer taken a fabricated prototype of a microscale dot array on the doctor-blade
at 52◦ tilt to show the three-dimensional nature of the funnel shape. SSQ (silsesquioxane) by R2R (roll-to-roll) NIL (nano-imprint lithog-
Figure reprinted with permission from Ref. 134. (d) Scanning elec- raphy).137

13
A Review of Metamaterial‑Based Microwave Absorbers and Sensors 591

Despite having high resolution, both E-beam and focused promising dielectric materials. (2) From microfabrication
ion beam lithography are time-consuming fabrication pro- and nanofabrication technology, the precise preparation
cesses. Extreme ultraviolet (EUV) lithography is suitable of different metamaterial sensors is essential. (3) In addi-
process at a wavelength of 193nm. This is quite similar tion to the realization of metamaterial sensors based on
to conventional photolithography but it uses shorter- resonant frequency shift, the combination of the ampli-
wavelength deep ultraviolet (UV) light, therefore ena- tude and phase changes of electromagnetic waves with the
bling higher resolution. Nano-imprint lithography (NIL, characteristics of metamaterials can generate new types of
Fig. 25f)137 is another technique for large-area fabrication, metamaterial sensors. (4) Continued exploration is needed
based on a reusable mold as displayed in Fig. 11. The mold in several fields of metamaterial sensing, such as pressure,
creates patterns by mechanically pressing on the substrate temperature, density, thickness, strain, and position. (5) As
(resist) followed by a subsequent process. metamaterial sensors are able to detect only one substance
at a time, multichannel metamaterial sensors should be
developed.
Future Scope

Depending upon several existing capabilities as mentioned


in the study, various goals can be targeted for future study. Conclusion
Extension of the tuning mechanism at the respective unit
cell or small number of unit cells to explore large regions Metamaterials possess extraordinary electromagnetic
is essential for the validation of many metamaterials or characteristics to guide electromagnetic waves in specific
conversion of electromagnetic/optical devices such as ways. In addition, metamaterials can develop powerful
lenses. Limited investigations have been performed regard- localization and refinement of an electromagnetic field to
ing spatial tuning of metamaterial for the development of formulate an ideal sensing platform with the advantages of
gradient index lenses. Ultimately, expansion of the tunable high sensitivity, higher resolution, fast response, and simple
range and application feasibility of reconfigurable meta- measurement. The review gives a comprehensive overview of
material components will ensure the validity of the design the literature on metamaterial microwave absorbers and their
strategy for solving real-life problems. Another important application in different areas. Various types of absorbers are
field of future advancement is the increase in accessible discussed, operating in several frequency regions. It is well
tunable materials. Phase change materials are being con- established from the literature that the absorption properties
tinuously developed in the area of new material genera- of the MMA are dependent on the unit cell structure, which
tion and refinement of tuning as well as switching circuits. plays an important role in defining whether the absorber
With the help of these materials, high-speed switchable is sensitive or insensitive to polarization. Several excellent
metamaterials offer an interesting field of future research choices of substrate possessing perfect absorption for a
in a commercial context. Various interesting smart materi- particular frequency band are discussed in detail. Various
als which respond to environmental stimuli can also be an diverse strategies are also explained for computation and
important area for future development of metamaterial. fabrication of many such absorbers to be operated in a
Some conducting polymers can alter their characteristics multiple-band and broadband frequency range. Numerous
under the influence of chemical analytes. Extensive studies resonating structures in each unit cell resonate at various
are essential for both electromagnetic fields and materials frequencies. The printed circuit board (PCB) approach is
science to identify sensing materials and develop meta- typically used to create MMA operating in the microwave
material platforms by connecting various smart devices frequency range. FR-4 is a common photosensitized
in practice. Metamaterial-based sensors can extend the board that is used in this process, and coating of copper
resolution limit of conventional sensors and must possess of suitable thickness is performed on either side of it. In
greater sensitivity and higher resolution than conventional addition, FR-4 dielectric substrate-based absorbers which
sensors. Further development is essential for advancing have near-perfect absorption can be explored as an antenna
the sensing properties of metamaterial sensors in order to and filtenna. Various important features of metamaterial
promote the development of improved sensors. Recently, sensors including the sensing mechanism and characteristic
metamaterial-based sensing technology has become rela- parameters and their improvement are also discussed in
tively mature, but for real-world applications such as bio- this survey. The uniqueness and versatility of metamaterial
sensing, material detection, and food security, metamate- sensors are widely accepted. These materials generally
rial sensors meet several challenging issues: (1) Sensors demonstrate excellent properties and the ability to overcome
still require advancements in sensitivity and resolution the limitations of traditional sensing devices.
with proper design of metamaterial structures or using

13
592 S. K. Ranjan, S. Sahoo

Author Contribution SKR—wrote manuscript, prepared all the figures; 15. Y.I. Abdulkarim, L. Deng, M. Karaaslan, Ş Dalgaç, R.H. Mah-
Dr. SS—reviewed the manuscript. mud, F.F. Ozkan Alkurt, F.F. Muhammadshari, H.N. Awl, S.
Huang, and H. Luo, The detection of chemical materials with a
Funding The authors did not receive support from any organization metamaterial-based sensor incorporating oval wing resonators.
for the submitted work. Electronics 9(5): 825 (2020)
16. M.R. Islam, M.T. Islam, B. Bais, S. HAlmalki, H. Alsaif, and
Data Availability Not applicable M.S. Islam, Metamaterial sensor based on rectangular enclosed
adjacent triple circle split ring resonator with good quality factor
Conflict of interest On behalf of all the authors, the corresponding au- for microwave sensing application. Sci. Rep. 12(1): 6792 (2022)
thor states that there is no conflict of interest. 17. G.Verma and K.P. Ray, Design, fabrication and characteristics
of eco-friendly microwave absorbing materials: a review. IETE
Ethical Approval Not applicable. Tech. Rev. 39(4): 756 (2022)
18. G. Tiwari and A. Yadav, A review article on design and tech-
niques of metamaterial absorber. Int. J. Eng. Sci. Res. Technol.
7(9): 942 (2018)
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127. R. Ahmed, M.O. Ozen, M.G. Karaaslan, C.A. Prator, C. Thanh, exclusive rights to this article under a publishing agreement with the
S. Kumar, and U. Demirci, Tunable fano-resonant metasurfaces author(s) or other rightsholder(s); author self-archiving of the accepted
on a disposable plastictemplate for multimodal and multiplex manuscript version of this article is solely governed by the terms of
biosensing. Adv. Mater. 32(19): 1907160 (2020) such publishing agreement and applicable law.

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