FINAL JEE–MAIN EXAMINATION – JANUARY, 2024

(Held On Thursday 01st February, 2024) TIME : 9 : 00 AM to 12 : 00 NOON

NOON
CHEMISTRY TEST PAPER WITH SOLUTION
SECTION-A 63. In acidic medium, K2Cr2O7 shows oxidising action
61. If one strand of a DNA has the sequence as represented in the half reaction
ATGCTTCA, sequence of the bases in Cr2 O27  XH  Ye   2A  ZH2 O
complementary strand is: X, Y, Z and A are respectively are:
(1) CATTAGCT (2) TACGAAGT (1) 8, 6, 4 and Cr2O3 (2) 14, 7, 6 and Cr3+
(3) GTACTTAC (4) ATGCGACT (3) 8, 4, 6 and Cr2O3 (4) 14, 6, 7 and Cr3+
Ans. (2) Ans. (4)
Sol. Adenine base pairs with thymine with 2 hydrogen Sol. The balanced reaction is,
bonds and cytosine base pairs with guanine with 3 Cr2 O27  14H   6e   2Cr 3  7H 2 O

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hydrogen bonds. X = 14
A T G C T T C A DNA strand Y=6
Hydrogen bonds A=7
T A C G A A G T Complementary strand
64. Which of the following reactions are
62. Given below are two statements : one is labelled as disproportionation reactions?
Assertion (A) and the other is labelled as Reason (A) Cu+  Cu2+ + Cu
(R). (B) 3MnO24  4H  2MnO4  MnO2  2H2O
Assertion (A) : Haloalkanes react with KCN to (C) 2KMnO4  K2MnO4 + MnO2 + O2
form alkyl cyanides as a main product while with (D) 2MnO4  3Mn 2  2H2 O  5MnO2  4H
AgCN form isocyanide as the main product. Choose the correct answer from the options given
Reason (R) : KCN and AgCN both are highly below:
ionic compounds. (1) (A), (B) (2) (B), (C), (D)
In the light of the above statement, choose the most (3) (A), (B), (C) (4) (A), (D)
appropriate answer from the options given below: Ans. (1)
(1) (A) is correct but (R) is not correct Sol. When a particular oxidation state becomes less
(2) Both (A) and (R) are correct but (R) is not the stable relative to other oxidation state, one lower,
one higher, it is said to undergo disproportionation.
correct explanation of (A)
Cu+  Cu2+ + Cu
(3) (A) is not correct but (R) is correct
3MnO24  4H  2MnO4  MnO2  2H2O
(4) Both (A) and (R) are correct and (R) is the 65. In case of isoelectronic species the size of F–, Ne
correct explanation of (A) and Na+ is affected by:
Ans. (1) (1) Principal quantum number (n)
(2) None of the factors because their size is the
(i) KCN + R — X R—CN same
(Ionic) (Ma jor product) (3) Electron-electron interaction in the outer
Sol. .. orbitals
(ii) AgCN + R — X R—NC
(Covalent) (Ma jor product) (4) Nuclear charge (z)
AgCN is mainly covalent in nature and nitrogen is Ans. (4)
Sol. In F–, Ne, Na+ all have 1s2, 2s2, 2p6 configuration.
available for attack, so alkyl isocyanide is formed They have different size due to the difference in
as main product. nuclear charge.

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66. According to the wave-particle duality of matter by Sol. [Ni(H2O)6]+2  Green colour solution due to d-d
de-Broglie, which of the following graph plot transition.
presents most appropriate relationship between [Ni(CN)4]–2  is diamagnetic and it is colourless.
68. Given below are two statements: one is labelled
wavelength of electron () and momentum of
as Assertion (A) and the other is labelled as
electron (p)? Reason (R).
Assertion (A) : PH3 has lower boiling point than NH3.
Reason (R) : In liquid state NH3 molecules are
 p associated through vander waal’s forces, but PH3
(1) (2) molecules are associated through hydrogen bonding.
In the light of the above statements, choose the
p most appropriate answer from the options given

below:
(1) Both (A) and (R) are correct and (R) is not the
correct explanation of (A)
  (2) (A) is not correct but (R) is correct
(3) (4)

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(3) Both (A) and (R) are correct but (R) is the
correct explanation of (A)
1/p p (4) (A) is correct but (R) is not correct
Ans. (1) Ans. (4)
Sol. Unlike NH3, PH3 molecules are not associated
h 1 through hydrogen bonding in liquid state. That is
Sol.    
p p why the boiling point of PH3 is lower than NH3.
 p = h (constant) 69. Identify A and B in the following sequence of
reaction
So, the plot is a rectangular hyperbola. CH3


Cl2 / h
 A 
H2 O
373K
B

COCl CHO
(1) (A) = (B) =
p
67. Given below are two statements: CHCl2 CHO
Statement (I): A solution of [Ni(H2O)6]2+ is green (2) (A) = (B) =
in colour.
Statement (II): A solution of [Ni(CN)4]2– is CH2 Cl CHO
colourless.
(3) (A) = (B) =
In the light of the above statements, choose the
most appropriate answer from the options given CHCl2 COOH
below: (4) (A) = (B) =
(1) Both Statement I and Statement II are incorrect
(2) Both Statement I and Statement II are correct Ans. (2)
(3) Statement I is incorrect but Statement II is Sol.
CH3 CHCl2 CHO
correct
Cl 2 /h


H2 O
(4) Statement I is correct but Statement II is 373 K

incorrect Toluene Benzal chloride Benzaldehyde

Ans. (2)

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70. Given below are two statements: 73. Ionic reactions with organic compounds proceed
Statement (I) : Aminobenzene and aniline are through:
same organic compounds. (A) Homolytic bond cleavage
Statement (II) : Aminobenzene and aniline are (B) Heterolytic bond cleavage

different organic compounds. (C) Free radical formation

(D) Primary free radical
In the light of the above statements, choose the
(E) Secondary free radical
most appropriate answer from the options given
Choose the correct answer from the options given
below:
below:
(1) Both Statement I and Statement II are correct
(1) (A) only
(2) Statement I is correct but Statement II is incorrect
(2) (C) only
(3) Statement I is incorrect but Statement II is correct (3) (B) only
(4) Both Statement I and Statement II are incorrect (4) (D) and (E) only

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Ans. (2) Ans. (3)
Sol. Aniline is also known as amino benzene. Sol. Heterolytic cleavage of Bond lead to formation of
71. Which of the following complex is homoleptic? ions.
(1) [Ni(CN)4]2– 74. Arrange the bonds in order of increasing ionic
(2) [Ni(NH3)2Cl2] character in the molecules. LiF, K2O, N2, SO2 and
(3) [Fe(NH3)4Cl2]+ CIF3.

(4) [Co(NH3)4Cl2]+ (1) CIF3 < N2 < SO2 < K2O < LiF
(2) LiF < K2O < CIF3 < SO2 < N2
Ans. (1)
(3) N2 < SO2 < CIF3 < K2O < LiF
Sol. In Homoleptic complex all the ligand attached with
(4) N2 < CIF3 < SO2 < K2O < LiF
the central atom should be the same. Hence
Ans. (3)
[Ni(CN)4]2– is a homoleptic complex.
Sol. Increasing order of ionic character
72. Which of the following compound will most easily
N2 < SO2 < ClF3 < K2O < LiF
be attacked by an electrophile? Ionic character depends upon difference of
CH3 electronegativity (bond polarity).
(1) (2) 75. We have three aqueous solutions of NaCl labelled
as ‘A’, ‘B’ and ‘C’ with concentration 0.1 M,
Cl OH 0.01M & 0.001 M, respectively. The value of van
(3) (4) t’ Haft factor (i) for these solutions will be in the
order.
Ans. (4) (1) iA < iB < iC
Sol. Higher the electron density in the benzene ring (2) iA < iC < iB
more easily it will be attacked by an electrophile. (3) iA = iB = iC
(4) iA > iB > iC
Phenol has the highest electron density amongst all
Ans. (1)
the given compound.

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Sol. Sol. DIBAL  H, H2 O
CH3 (CH 2 )5 COOC 2 H 5  CH 3 (CH 2 ) 5 CHO
Salt Values of i (for different conc. of a Salt)
0.1 M 0.01 M 0.001 M C6 H5COC6 H5 
Zn(Hg) & conc. HCl
 C6 H5CH2 C6 H5
NaCl 1.87 1.94 1.94
C6 H5CHO 
CH3MgBr
C6 H5CH  OH  CH3
i approach 2 as the solution become very dilute. H2 O

76. In Kjeldahl’s method for estimation of nitrogen, CH3COCH2COOC2 H5 

NaBH4 , H 
CH3CH(OH)CH2COOC2H5
CuSO4 acts as :
(1) Reducing agent (2) Catalytic agent 79. Choose the correct option for free expansion of an
(3) Hydrolysis agent (4) Oxidising agent ideal gas under adiabatic condition from the
Ans. (2) following :
Sol. Kjeldahl’s method is used for estimation of
Nitrogen where CuSO4 acts as a catalyst. (1) q = 0, T  0, w = 0
77. Given below are two statements : (2) q = 0, T < 0, w 0
Statement (I) : Potassium hydrogen phthalate is a
(3) q  0, T = 0, w =0
primary standard for standardisation of sodium

hydroxide solution.
Statement (II) : In this titration phenolphthalein
can be used as indicator.
In the light of the above statements, choose the most
appropriate answer from the options given below:
(1) Both Statement I and Statement II are correct
(2) Statement I is correct but Statement II is incorrect
(3) Statement I is incorrect but Statement II is correct
(4) Both Statement I and Statement II are incorrect
Ans. (1)
Sol. Statement (I) : Potassium hydrogen phthalate is a
primary standard for standardisation of sodium
hydroxide solution as it is economical and its
concentration does not changes with time.
Phenophthalin can acts as indicator in acid base
titration as it shows colour in pH range 8.3 to 10.1
78. Match List – I with List –II.
List – I (Reactions) List – II (Reagents)
(A) CH3(CH2)5–C–OC2H5CH3(CH2)5CHO (I) CH3MgBr, H2O
O
(B) C6H5COC6H5C6H5CH2C6H5 (II) Zn(Hg) and conc. HCl
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(4) q = 0, T = 0, w =0
Ans. (4)
Sol. During free expansion of an ideal gas under
adiabatic condition q = 0, T = 0, w =0.
80. Given below are two statements:
Statement (I) : The NH2 group in Aniline is ortho
and para directing and a powerful activating group.
Statement (II) : Aniline does not undergo Friedel-
Craft’s reaction (alkylation and acylation).
In the light of the above statements, choose the
most appropriate answer from the options given
below :
(1) Both Statement I and Statement II are correct
(2) Both Statement I and Statement II are incorrect
(3) Statement I is incorrect but Statement II is correct
(4) Statement I is correct but Statement II is incorrect

(C) C6H5CHOC6H5CH(OH)CH3 (III) NaBH4 , H+

Ans. (1)
(D) CH COCH COOC H CH C(OH)CH COOC H (IV) DIBAL-H, H2O Sol. The NH2 group in Aniline is ortho and para
3 2 2 5 3 2 2 5

H directing and a powerful activating group as NH2

Choose the correct answer from options given
has strong +M effect.
below:
(1) A-(III), (B)-(IV), (C)-(I), (D)-(II) Aniline does not undergo Friedel-Craft’s reaction
(2) A-(IV), (B)-(II), (C)-(I), (D)-(III) (alkylation and acylation) as Aniline will form
(3) A-(IV), (B)-(II), (C)-(III), (D)-(I)
complex with AlCl3 which will deactivate the
(4) A-(III), (B)-(IV), (C)-(II), (D)-(I)
Ans. (2) benzene ring.

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 SECTION-B Sol. SrSO4 – white

81. Number of optical isomers possible for Mg(NH4)PO4 – white

2 – chlorobutane ……… BaCrO4 – yellow
Ans. (2) Mn(OH)2 – white
Cl
PbSO4 – white
Sol. *
PbCrO4 – yellow
There is one chiral centre present in given
AgBr – pale yellow
compound.
PbI2 – yellow
So, Total optical isomers = 2
Cl Cl CaC2O4 – white

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[Fe(OH)2(CH3COO)] – Brown Red
and
14
82. The potential for the given half cell at 298K is C 1
84. The ratio of 12
in a piece of wood is part that
C 8
(-)………… × 10-2 V.
of atmosphere. If half life of 14C is 5730 years, the
2H+(aq) + 2e-  H2 (g) age of wood sample is ….. years.
[H+] = 1M, PH 2 = 2 atm Ans. (17190)

(Given: 2.303 RT/F = 0.06 V, log2 = 0.3) (14 C /12 C)atmosphere

Sol. t  ln
Ans. (1) (14 C /12 C)wood sample

0.06 PH As per the question,

Sol. E = EoH /H  log 2 2
2
2 [H ]
(14 C /12 C)wood 1
14 12

0.06 2 ( C / C)atmosphere 8
E = 0.00  log 2
2 [1] So, t  ln 8
ln 2
E =  0.03  0.3  0.9 102 V t  ln8
t1/2
83. The number of white coloured salts among the t = 3 × t1/2 = 17190 years
following is ……………. 85. The number of molecules/ion/s having trigonal
bipyramidal shape is …….. .
(A) SrSO4 (B) Mg(NH4)PO4 (c) BaCrO4 PF5, BrF5, PCl5, [PtCl4]2–, BF3, Fe(CO)5
(D) Mn(OH)2 (E) PbSO4 (F) PbCrO4 Ans. (3)
Sol. PF5, PCl5, Fe(CO)5 ; Trigonal bipyramidal
(G) AgBr (H) PbI2 (I) CaC2O4
BrF5 ; square pyramidal
(J) [Fe(OH)2(CH3COO)]
[PtCl4]- 2 ; square planar
Ans. (5)
BF3 ; Trigonal planar

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86. Total number of deactivating groups in aromatic Sol. Acidic oxide: Cl2O7, SiO2, N2O5
electrophilic substitution reaction among the Neutral oxide: CO, NO, N2O
following is
Amphoteric oxide: Al2O3 , SnO2 , PbO2
O O
89. Consider the following reaction:
CH3,
OCH3, –N CH3 , –N –C  N, –OCH3
3PbCl2 + 2(NH4)3PO4  Pb3(PO4)2 + 6NH4Cl
H H
If 72 mmol of PbCl2 is mixed with 50 mmol of
Ans. (2)
Sol. (NH4)3PO4 , then amount of Pb3(PO4)2 formed is
O O …… mmol. (nearest integer)
CH3,
–C  N, –OCH3 Ans. (24)
OCH3, –N CH3 , –N
H H Sol. Limiting Reagent is PbCl2
(–M group) (+M group) (+M group) (–M group) (+M group)
mmol of Pb3(PO4)2 formed
87. Lowest Oxidation number of an atom in a

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compound A2B is -2. The number of an electron in mmol of PbCl2 reacted
=
its valence shell is 3
Ans. (6) = 24 mmol
+ –2 -2
Sol. A2B  2A + B , B has complete octet in its di- 90. Ka for CH3COOH is 1.8 × 10– 5 and Kb for NH4OH
anionic form, thus in its atomic state it has 6 is 1.8 × 10–5. The pH of ammonium acetate
electrons in its valence shell. As it has negative
solution will be
charge, it has acquired two electrons to complete
its octet. Ans. (7)
88. Among the following oxide of p - block elements, pK w  pK a  pK b
Sol. pH 
number of oxides having amphoteric nature is 2
Cl2O7, CO, PbO2, N2O, NO, Al2O3, SiO2, N2O5, pKa = pKb
SnO2 pK w
Ans. (3)  pH  7
2