MATERIAL SAFETY DATA SHEET

1. IDENTIFICATION OF THE SUBSTANCE AND COMPANY

DESCRIPTION : Salt Flux

PRODUCT NAME : Flux 4380
MANUFACTURER : PT. REFRATECH MANDALAPERKASA
ADDRESS : Jln. Mayor Oking, Kampung Kamurang No 7 A,Rt002/006
Puspanegara Citeureup, Bogor – Indonesia. 16810
TELP : (62)21 87941455
FAX : (62) 21 8752624
CONTACT PERSON : AJI (TECHNICAL PRODUCT)

2. INFORMATION ON INGREDIENTS

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CHEMICAL NAME CAS NO NIOSH OSHA PEL ACGIH TLV WEIGHT%

Sodium Chloride 77647-14-5 n/I1 15*,5** 10 > 50

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Sodium Fluorosilicate 16893-85-9 none 2.5 (F-) 2.5 (F-) > 20

Sodium Carbonate 5968-11-6 n/I1 15*,5** 10 < 10

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*,** Values expressed in mg/m3 * Total dust, ** Respirable dust
1 Classed as particulates, not otherwise classified

3. HAZARD IDENTIFICATION
IRRITANT
Causes eye, skin and inhalation irritation. Toxic – harmful by inhalation
Use proper engineering controls, work practices, and personal protective equipment to
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prevent exposure to wet or dry product.

EMERGENCY OVERVIEW
Slag is a solid, grey/black or brown/ tan, odorless powder. It is not combustible or
explosive. A single, short-term exposure to the dry powder presents little or no hazard.
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POTENTIAL HEALTH EFFECTS

- Eye contact
Airborne dust may cause immediate or delayed irritation or inflammation. Eye contact
with large amounts of dry powder or with wet slag can cause moderate eye irritation.
Eye exposures require immediate first aid to prevent significant damage to the eye.
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- Skin contact
Slag may cause dry skin, discomfort, irritation, and dermatitis
Dermatitis :
Slag is capable of causing dermatitis by irritation and allergy. Skin affected by dermatitis
may include symptoms such as, redness, itching, rash, scaling, and cracking. Irritant
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dermatitis is caused by the physical properties of slag including moisture and abrasion.
Allergic contact dermatitis is caused by sensitization to hexavalent chromium (chromate)
present in slag. The reaction can range from a mild rash to severe skin ulcers. Persons
already sensitized may react to the first contact with slag. Others may develop allergic
dermatitis after years of repeated contact with slag.
- Inhalation (acute)
Breathing dust may cause nose, throat or lung irritation, including choking, depending
onthe degree of exposure.
- Inhalation (chronic)
Risk of injury depends on duration and level of exposure
Silicosis :
This product contains crystalline silica. Prolonged or repeated inhalation of respirable
crystalline silica from this product can cause silicosis, a seriously disabling and fatal lung
disease.

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 Carcinogenicity :
Slag is not listed as a carcinogen by IARC or NTP, however slag caontains trace amounts of
crystalline silica and hexavalent chromium which are classified by IARC and NTP as known
human carcinogens.
Autoimmune disease :
Some studies show that exposure to respirable crystalline silica (without silicosis) or that the
disease silicosis may be associated with the increased incidence of several autoimmune
disorders such as scleroderma (thickening of the skin), systemic lupus erythematosus,
rheumatoid arthritis and diseases affecting the kidneys
Tuberculosis :
Silicosis increases the risk of tuberculosis
Renal diseases :
Some studies show an increased incidence of chronic kidney disease and end-stage renal
disease in workers exposed to respirable crystalline silica
- Ingestion
Do not ingest slag. Ingestion of small quantities of slag is not known to be harmful, large
quantities can cause distress to the digestive tract
- Medical conditions aggravated by exposure
Individuals with lung disease (e.g. bronchitis, emphysema, COPD, pulmonary disease) or
sensitivity to hexavalent chromium can be aggravated by exposure.

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4. FIRST AID MEASURES
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EYE CONTACT
- Rinse eyes thoroughly with water for at least 15 minutes, including under lids, to remove

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all particles. Seek medical attention for abbrasions.
SKIN CONTACT
- Wash with cool water and a pH neutral soap or a mild skin detergent. Seek medical

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attention for rash, irritation, dermatitis, and prolonged unprotected exposures to wet slag,
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cement, cement mixtures or liquids from wet cement
INHALATION
• Move person to fresh air. Seek medical attention for discomfort or if coughing or other
symptoms do not subside
INGESTION
- Do not induce vomiting. If conscious, have person drink plenty of water. Seek medical
attention or contact poison control center immediately
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NOTE TO PHYSICIAN - The three types of silicosis include :

* Simple chronic silicosis – which results from long-term exposure (more than 20 years) to
low amounts of respirable crystalline silica. Nodules of chronic inflammation and
scarring provoked by the respirable crystalline silica from in the lungs and chest lymph
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nodes. This disease may feature breathlessness and may resemble chronic obstructive
pulmonary disease (COPD)
* Accelerated silicosis – occurs after exposure to larger amounts of respirable crystalline
silica over a shorter period of time ( 5-15 years). Inflammation, scarring, and symptoms
progress faster in accelerated silicosis than in simple silicosis.
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* Acute silicosis – results from short-term exposure to very large amounts of respirable
crystalline silica. The lungs become very inflamed and may fill with fluid, causing severe
shortness of breath and low blood oxygen levels.
Progressive massive fibrosis may occur in simple or accelerated silicosis, but is more
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common in the accelerated form. Progressive massive fibrosis results from severe scarring
and leads to the destruction of normal lung structures.

5. FIREFIGHTING MEASURES

Flammability : Non Flammbale

Flashpoint and method : Non- combustible
General hazard : Avoid breathing dust
Extinguishing media : Use extinguishing media appropriate for surrounding fire
Firefighting equipment : Slag poses no fire-related hazard. A SCBA is recommended to limit
exposures to combustion products when fighting any fire
Combustion products : None

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6. ACCIDENTAL RELEASE MEASURES
GENERAL
- Place spilled material into a container. Avoid actions that cause the slag to become
airborne. Avoid inhalation of slag and contact with skin. Wear appropriate protective
equipment as described in section 9. scrape wet slag and place in container. Allow material
to dry or solidify before disposal. Do not wash slag down sewage and drainage systems or
into bodies of water (e.g. streams).
WASTE DISPOSAL METHOD
- Disposal of slag according to Federal, State, Provincial and Local regulations

7. HANDLING AND STORAGE

GENERAL
- Handle with care and use appropriate control measures. Keep bulk slag and cement dry
until used. When slag is kept wet for long periods of time, the leachate may be discolored
and have a sulfurous odor. When this liquid is exposed to oxygen elemental sulfur may
precipitate out leaving a solution of calcium thiosulfate.
Engulfment hazard. To prevent burial or suffocation, do not enter a confined space, such
as a silo, bin, bulk truck, or other storage container or vessel that stores or contains slag
or cement. Slag and cement can buildup or adhere to the walls of a confined space. The

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slag or cement can release, collapse or fall unexpectedly
Properly ground all pneumatic conveyance systems. The potential exist for static build-up
and static discharge when moving powders through a plastic, non-conductive, or non-
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grounded pneumatic conveyance system. The static discharge may result in damage to
equipment and injury to workers.

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USAGE
- Cutting, crushing or grinding hardened cement, concrete or other crystalline silica-
bearing materials will release respirable crystalline silica. Use all appropriate

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measures of dust control or supperssions, and Personal Protective Equipment (PPE) .
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HOUSEKEEPING
- Avoid actions that cause the slag to become airborne during clean-up such as dry sweeping
or using compressed air. Use HEPA vacuum or thoroughly wet with water to clean-up dust.
STORAGE TEMPERATURE
- Unlimited
STORAGE PRESSURE
- Unlimited
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CLOTHING
- Promptly remove and launder clothing that is dusty or wet with slag or cement. Thoroughly
wash skin after exposure to dust or wet slag or cement
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8. EXPOSURE CONTROLS AND PERSONAL PROTECTION

ENGINEERING CONTROLS
- Use local exhaust or general dilution ventilation or other suppression methods to maintain
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dust levels below exposure limits

PERSONAL PROTECTIVE EQUIPMENT (PPE)
- Respiratory
Under ordinary conditions no respiratory protection is required. Wear a NIOSH
- Protection
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Approved respirator that is properly fitted and is in good condition when exposed to dust
above exposure limits
- Eye protection
Wear ANSI approved glasses or safety goggles when handling dust or wet slag to prevent
contact with eyes. Wearing contact lenses when using slag, under dusty conditions, is
not recommended
- Skin protection
Wear gloves, boot covers and protective clothing impervious to water to prevent skin
contact. Do not rely on barrier creams, in place of impervious gloves. Remove clothing and
protective equipment that becomes saturated with wet slag or cement and
immediately wash exposed areas.

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9. PHYSICAL AND CHEMICAL PROPERTIES

Freezing point : N/A Vapor pressure : N/A

Melting point : approx 1256 - 15620 F Vapor density : N/A
Boiling point : N/A Specific gravity (g/cc) : max 2.7
Sublimes : N/A % Volatiles : none
Evaporation : N/A
Appearance and odor : white crystalline and no odor

10. STABILITY AND REACTIVITY DATA

STABILITY
- Stable. Keep dry until use. Slag may react with water resulting in a slight release of heat,
depending on the amount of lime (calcium dioxide) present. Avoid contact with incompatible
materials.
INCOMPATIBILITY
- Slag is incompatible with acids, ammonium salts and aluminium metal. Slag and cement

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dissolves in hydrofluoric acid, producing corrosive silicon tetrafluoride gas. Slag and
cmenet reacts with water to form silicates and calcium hydroxide. Silicates react with
powerful oxidizers such as fluorine, boron trifluoride, chlorine trifluoride, manganese
trifluoride, and oxygen difluoride.
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HAZARDOUS POLYMERIZATION

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- None
HAZARDOUS DECOMPOSITION
- Hydrogen sulfide gas may be released from moist or wet slag with it is heated

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11. TOXICOLOGICAL INFORMATION
Routes of Entry : Inhalation. Ingestion.
Toxicity to Animals : Acute oral toxicity (LD50): 70 mg/kg [Mouse].
Chronic Effects on Humans : CARCINOGENIC EFFECTS: A4 (Not classifiable for human or
animal.) by ACGIH, 3 (Not classifiable for human.) by IARC.
Other Toxic Effects on Humans : Hazardous in case of skin contact (irritant), of ingestion,
of inhalation.
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Special Remarks on Toxicity to Animals : Not available.

Special Remarks on Chronic Effects on Humans : May cause cancer based on animal test
data. No human data found.
Special Remarks on other Toxic Effects on Humans :
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Acute Potential Health Effects: Skin: Causes mild to moderate skin irritation. Symptoms may
include redness, burning sensation (feeling), and sometimes ulcers. Eyes: Causes moderate
to severe irritation. Inhalation: It can irritate the nose,throat, lungs causing coughing,
wheezing and/or shortness of breath Ingestion: Harmful if swallowed. It is toxic by oral
exposure route. Symptoms of acute ingestion include a salty or soapy taste in the mouth,
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excessive salivation, nausea, abdominal cramps, vomiting, diarrhea, thirst. It may also affect
behavior/central nervous system (central nervous system depression, muscle weakness,
tremors or spasms, ataxia, convulsions) and may also cause disturbed color vision, kidney
damage, liver damage, bleeding from the stomach, shortness of breath, loss of conciousness
or death.
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Chronic Potential
Health Effects: Skin: Repeated or prolonged skin contact may produce pustular rash.
Inhalation or Ingestion: Prolonged or repeated exposure may cause excess respiratory,
cardiac, and gastrointestinal disturbances, and chronic bronchitis. It may also cause liver
and kidney damage, fluorosis and osteosclerosis. Fluorosis can cause mottling of teeth

12. ECOLOGICAL INFORMATION

Ecotoxicity : Not available.
BOD5 and COD :Not available
Special Remarks : When working with fluoride containing salts it is advisable : to wear eye
protection, a NIOSH approved respirator, and gloves to limit exposure. Contact with the
actual material should be minimized. Always wash thoroughly prior to eating or smoking.

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13. DISPOSAL CONSIDERATIONS
Dispose of waste and containers in compliance with applicable Federal, State, Provincial and
Local regulations

14. TRANSPORT INFORMATION

The data provided in this section is for information only and may not be specific to your
package size or mode of transport. You will need to apply the appropriate regulations to
properly classify your shipment for transportation. International transport regulations is not
regulated.

15. OTHER REGULATORY INFORMATION

Not regulated as dangerous products.
This material is not regulated by the DOT for land transportation.
Other Special Considerations : Not available

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Fire 0

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Re a c t iv it y 0
P e rs o n a l A
P ro t e c tion

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OTHER INFORMATION

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DATE PREPARED : 2011
DATE REVISED2nd : NOVEMBER 2017

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DEFINITIONS :
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CAS : Chemical Abstracts Service Registry Number
NIOSH : National Institute for Occupational Safety and Health
OSHA : Occupational Safety and Health Administration
PEL : Permissible Exposure Limit
TLV :Threshold Limit Values ( ACGIH, American Conference of Governmental Industrial
Hygienists )
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