Nama: Rhaisya Sabira

NIM: 08031282328029
Kelas: Kimia A
Mata Kuliah: Dasar Kimia Analis
Dosen Pengampu: Dra Fatma
Hari/Tanggal: Kamis, 15 Februari 2024
1. Buat Struktus dari indicator adsorpsi berikut:
Eosin, Thorin, Hijau Brom kresol, Methil ungu, Rhodamin 6G, Ortokrom T dan
Bromfenol biru
2. Hitung nilai pCl dan pAg untuk data berikut:

Untuk penambahan volume titran AgNO3 sebayak : ( 0, 10 , 20, 40, 60,80, 90, 95, 97,
99, 99,3; 99,5; 99,7; 99,8; 99,9; 100, 100,1; 100,2; 100,3; 100,5; 101, 105, 110 ) ml

1. a) Eosin

b) Thorin

c) Hijau Bromkresol
 d) Metil Ungu

e) Rhodamin 6G

f) Ortokrom T

g) Bromfenol Biru
2. Penambahan 0 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 100 𝑝𝐴𝑔 = −log 100 = 3
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3 = 6,9208
Penambahan 10 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 110 𝑝𝐴𝑔 = −log 110 = 0,0009
− log 0,0009 = 3,0457
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,0457 = 6,8751
Penambahan 20 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 120 𝑝𝐴𝑔 = −log 120 = 0,0008
− log 0,0008 = 3,0969
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,0969 = 6,8239
Penambahan 40 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 140 𝑝𝐴𝑔 = −log 140 = 0,0007
− log 0,0007 = 3,1549
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,1549 = 6,7659
Penambahan 60 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 160 𝑝𝐴𝑔 = −log 160 = 0,0006
− log 0,0006 = 3,2218
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,2218 = 6,699
Penambahan 80 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 180 𝑝𝐴𝑔 = −log 180 = 0,0005
− log 0,0005 = 3,3010
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,3010 = 6,619
Penambahan 90 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 190 𝑝𝐴𝑔 = −log 190 = 0,00052
− log 0,00052 = 3,2839
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,2839 = 6,6369
Penambahan 95 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 195 𝑝𝐴𝑔 = −log 195 = 0,00051
− log 0,00051 = 3,2924
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,2924 = 6,6284
Penambahan 97 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 197 𝑝𝐴𝑔 = −log 197 = 0,00050
− log 0,00050 = 3,3010
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,3010 = 6,6198
Penambahan 99 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 199 𝑝𝐴𝑔 = −log 199 = 0,000502
− log 0,000502 = 3,2992
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,2992 = 6,6216
Penambahan 99,3 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 199,3 𝑝𝐴𝑔 = −log 199,3 = 0,000501
 − log 0,000501 = 3,3001
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,3001 = 6,6207
Penambahan 99,5 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 199,5 𝑝𝐴𝑔 = −log 199,5 = 0,0005012
− log 0,0005012 = 3,2999
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,2999 = 6,6209
Penambahan 99,7 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 199,7 𝑝𝐴𝑔 = −log 199,7 = 0,000500
− log 0,000500 = 3,30102
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30102 = 6,6197
Penambahan 99,8 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 199,8 𝑝𝐴𝑔 = −log 199,8 = 0,000500
− log 0,000500 = 3,30102
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30102 = 6,6197
Penambahan 99,9 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 199,9 𝑝𝐴𝑔 = −log 199,9 = 0,000500
− log 0,000500 = 3,30102
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30102 = 6,6197
Penambahan 100 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 200 𝑝𝐴𝑔 = −log 200 = 0,0005
− log 0,0005 = 3,30102
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30102 = 6,61978
Penambahan 100,1 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 200,1 𝑝𝐴𝑔 = −log 200,1 = 0,000499
− log 0,000499 = 3 , 30189
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30189 = 6,61891
Penambahan 100,2 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 200,2 𝑝𝐴𝑔 = −log 200,2 = 0,0004995
− log 0,0004995 = 3,30146
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30146 = 6,61934
Penambahan 100,3 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 200,3 𝑝𝐴𝑔 = −log 200,3 = 0,0004992
− log 0,0004992 = 3 , 30172
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30172 = 6,61908
Penambahan 100,4 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 200,4 𝑝𝐴𝑔 = −log 200,4 = 0,0004990
− log 0,0004990 = 3,30189
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30189 = 6,61891
Penambahan 100,5 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 200,5 𝑝𝐴𝑔 = −log 200,5 = 0,000498
− log 0,000498 = 3,30277
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,30277 = 6,61803
Penambahan 101 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 201 𝑝𝐴𝑔 = −log 201 = 0,000497
− log 0,000497 = 3 , 3031
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,3031 = 6,6176
Penambahan 105 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 205 𝑝𝐴𝑔 = −log 205 = 0,000487
− log 0,000487 = 3 , 31247
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,31247 = 6,60833
Penambahan 110 mL AgNO3
0,1 0,1
[ Cl- ]sisa = 210 𝑝𝐴𝑔 = −log 210 = 0,000476
− log 0,000476 = 3 , 3223
→pCl = 𝑝𝐾𝑠𝑝 − 𝑃𝐴𝑔 = 9,9208 − 3,3223 = 6,5985