PINNAACLE CLASSES

26. (d) JEE Main 2019

Wavelength of the energy absorbed by the coordination compound is inversely
proportional to ligand field strength of the given co-ordination compound. The strong
field ligand causes higher splitting of the d -orbitals. The decreasing order of ligand
field strength is NH 3> H 2 O>Cl . Therefore decreasing order of absorbed wavelength is
(I )>(II )>(III )

27. (b) JEE Main 2019

4 2
2+¿ t 2 g e g ¿
[ Fe ( H 2 O )6 ]
CFSE=(−4 × 0.4+ 2× 0.6) Δ0=−0.4 Δ 0
2
[ NiCl 4 ] 4 4
e t2
CFSE=(−4 × 0.4+ 2× 0.6) Δ0=−0.4 Δ 0

28. (d) JEE Main 2019

2 +¿ ( d8 ) ¿
3+¿ ( d 7) ¿
6 1
2+¿ ( d
8)

¿
t e
2g g
¿ →¿ ¿

3+¿ ( d ) ¿
6

2+¿ (d7 ) →Co

6 0

¿
t e
2g g

Co
6 1
t 2g e g

3+¿ ( d ) ¿
9

2+¿ ( d10 )→ Zn
6 3

¿
t e
2g g

Zn
6 4
t 2g e g

3+¿ ( d ) ¿
5

2 +¿ ( d6) → Fe
5 0

¿
t e
2g g

Fe
6 0
t e
2g g

So, only Fe2 +¿¿ will lose crystal field stabilisation energy upon oxidation to +3 , others will
gain crystal field stabilization energy.

29. (c) JEE Main 2019

Electronic configuration of Mn is
5

Mn 2+¿: 3 d ¿

Presence of 5 unpaired e−¿¿ shows that the complex of Mn 2+¿¿ has only weak field ligand ¿

30. (d)JEE Main 2020

Both complex can be high spin
Tetrahedral complex are generally high spin complex with any ligand is present

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Aqueous solution of Mn 2+¿¿ ions is pink in colour

Mn
2+¿+SFL → ¿
Iow spin complex

31. (b) JEE Main 2020

[¿( NH 3)2 Cl2 ]
¿2 +¿→ d sp ¿hybridisation
8 3

Tetrahedral complex
[¿(NH 3)2 Cl2 ]→cannot show isomerism.
[Pt (NH 3)2 Cl2 ]→ dsp →shows geometricalIsomerism
2

[¿( NH 3)4 ( H 2 O)2 ]

2+¿ →¿
Octahedral→showgeometrical isomerism
¿ ¿Octahedral→shows opticalisomerism

32. (d)JEE Main 2020

Crystal field stabilization energy (CFSE ) for high spin d 6 metal ion In octahedral

CFSE=[−0.4 nt 2 g +0.6 ne ] Δ 0
g

¿ [−0.4 ×4 +0.6 × 2] Δ0
¿−0.4 A 0
In tetrahedral fields

CFSE=(−0.6 neg +0.4 nt ) Δ t

2g

¿(−0.6 ×3+ 0.4 ×3) Δt

¿(−1.8+1.2) Δ t
¿−0.6 Δ t

33. (b)JEE Main 2020

Self-Explanatory

34. (b) JEE Main 2021

Red colour of ruby is due to presence ofCr O3 or C r + 6 not C O3 +¿¿

35. (d) JEE Main 2021

Fact Based
Density depend on many factor like atomic mass. atomic radius and packing efficiency.

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36. a JEE Main 2021

Complex
(a) [ Co ( NH 3 )6 ] ¿
(b) [ Co ( NH 3 )3 ( NO 2 )3 ]
(c) [ Cr ( H 2 O )6 ] Cl 3
(d) cis-[CrCl ¿ ¿
Type of Isomerism
(i) Co-ordination isomerism
(ii) Linkage isomerism
(iii) Solvate isomerism
(iv) Optical isomerism

37. (b)

38. (d)
4−
(a)[Fe(CN)6] → Pale yellow solution
(b)[Fe(SCN)6]4 → Blood red colour
(c)Fe4[Fe (CN6)]3⋅ H2O → Prussian blue
(d)[Fe(CN)5NOS]4− → Violet colour
39. (b)
(a)

C.N.=6 octahedral splitting

Hybridisation

(b)
strong field ligand

Hybridisation
Square planar splitting

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 PINNAACLE CLASSES

(c)
CO - Strong field ligand

(d)
weak
field ligand

C.N. 4
Tetrahedral
splitting

40. (c)
In presence of SFL means pairing occurs therefore
For

No of unpaired

[n=NO of unpaired ]
In is having configuration
Number of unpaired electron = 2 After formation of oxidised product
is obtained
and is strong field ligand
number of unpaired electrons = 0
The charge is 2-0=2

41. (a)
1.

Hybridisation: Magnetic nature: Paramagnetic (so this comple response to

external magnetic field)
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 PINNAACLE CLASSES

2.

Hybridisation: Magnetic nature: diamagnetic

3.

Hybridisation: Magnetic nature: diamagnetic.

4.

Hybridisation: Magnetic nature: diamagnetic

42. (b)
Complex is most stable complex among the given complex compounds
because more number of chelate rings are present in this complex as compare to
others.
(a) 1 chelate ring
(b) 3 chelate ring
(c) 2 chelate ring
(d) 0 chelate ring

43. (d)

Paramagnetic and having 4 unpaired electrons.

44. (d)

configuration, SFL configuration, SFL configuration, Chelating ligand All

will have larger splitting hence hybridisation
and
configuration, configuration, WFL WFL

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 PINNAACLE CLASSES

4unpaired 5 unpaired

electrons
45. (c)
is a strong field ligand so maximum splitting in d orbitals take place.

46. 6JEE Main 2020

¿ is ethylenediaminetetraacetate anion.
It is a hexadentate ligand.

It has six co-ordination sites.

47. 3 JEE Main 2021

K3 ¿
Chromium is in +3 oxidation state. Number of unpaired electrons in Cr +3 will be 3 .

48. (2)
The number of optical isomers for [Cr(C2O4)3]3−is two.

49. (2)

x + 6 × (−1) = −4 x = +2

and is a strong field ligand which can pair electron of central atom.

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It has one unpaired electron (n) in 4 d-subshell. So spin only magnetic moment

where n=number of unpaired electrons.

50. (6)

Secondary valency of Co=6

(C. N.)

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