PINNAACLE CLASSES

26. (a)

3 c−2 e : B−H−B ; 2 c−2 e : H −B−H

27. (c)
B3 H 6 N 3
28. (c) Inorganic benzene is

29. (b) JEE Main 2019

Structure of B2 H 6 :

∴No. of 2 -centre- 2 electron bonds ¿ 4

No. of 3 -centre- 2 electron bonds ¿ 2.

30. (c): Boron does not have vacant ‐orbitals in its valence shell, so it cannot extend

its covalency beyond 4. i.e., ‘B’ cannot form the ions like

31. (c): Boric acid behaves as a Lewis acid, by accepting a pair of electrons from
ion of water thereby releasing a proton.

32. (a): In group 13 elements, stability of oxidation state decreases down the
group while that oxidation state increases due to inert pair effect. Hence,
stability oxidation state increases in the sequence: Al

33. (c): BN is known as inorganic graphite and has structure similar to graphite.

34. (c): Compounds that are electron deficient act as Lewis acids. Out of the given

hydrides satisfies this condition and is therefore a Lewis acid.

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 PINNAACLE CLASSES

35. (c) JEE Main 2021

Terminal bond angle is greater than that of bridge bond angle Bond angle
Bond order ∝S-character
1
∝
p−character
36. (b)

37. (d) BF 3 accept lone pair of electrons.

38. (d)
39. (d)
40. (a)
41. (b) Here the lone pair present over nitrogen atom is involved in conjugation thus
is sp2 hybrdized.

42. (c)

43. (b) contain 10  electrons. Azulene is a dipolar ion and has both rings
aromatic in its ionic form.

44. (c)
45. (d)

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