Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic acid 299,5%, for synthesis article number: 6026 date of compilation: 2018-06-12 Version: 2.0 en Revision: 2022-05-27 Replaces version of: 2018-06-12 Version: (1) SECTION ee Ce ee Ue ee) ra 1.1 Product identifier Identification of the substance Propionic acid 299,5%, for synthesis Article number 6026 Registration number (REACH) 01-2119486971-24-00x Index number in CLP Annex VI 607-089-00-0 EC number 201-176-3, CAS number 79-09-4 1.2 Relevant identified uses of the substance or mixture and uses advised against Relevant identified uses: Laboratory chemical Laboratory and analytical use Uses advised against: Do not use for squirting or spraying. Do not use for products which come into direct contact with the skin, Do not use for products which come in- to contact with foodstuffs. Do not use for private purposes (household). 1.3. Details of the supplier of the safety data sheet, Carl Roth GmbH + Co KG Schoemperlenstr. 3-5 D-76185 Karlsruhe Germany Telephone:+49 (0) 721 - 56.060 Telefax: +49 (0) 721 - 56 06 149 e-mail: sicherheit@carlroth.de Website: www.cariroth.de Competent person responsible for the safety data :Department Health, Safety and Environment sheet: e-mail (competent person): sicherheit@carlroth.de 1.4 Emergency telephone number pros ees Pores Penny ‘National Poisons Information Beaumont Road ubing | 01 8092166 hetps Centre wu polsonsier Beaumont HospitalSafety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 pita poly 2.1. Classification of the substance or mixture Classification according to Regulation (EC) No 1272/2008 (CLP) De ue Le) pend es Cee ea ee egory erry pats 26 Flammable fquid 3 Flam. tig. 3 1226 32 ‘Shin corrsionsirfation ry Shin Corr 18 Haid 33 Serious eye damage/eye iritation 7 tyedamt Wai 3a | Spetitargetoreanondy- single posurerespat | 3 STOTSES 135 ‘ony tract reitation For fulltext of abbreviations: see SECTION 16 The most important adverse physicochemical, human health and environmental effects Skin corrosion produces an irreversible damage to the skin; namely, visible necrosis through the epi- dermis and into the dermis. The product is combustible and can be ignited by potential ignition sources 2.2 Label elements Labelling according to Regulation (EC) No 1272/2008 (CLP) Signal word Danger Pictograms GHS02, GHSO5, GHSO7 Hazard statements 1226 Flammable liquid and vapour #314 Causes severe skin burns and eye damage 1335 May cause respiratory irritation Precautionary statements Precautionary statements - prevention P210 Keep away from heat, sparks, open flames, hot surfaces. No smoking P260 Do not breathe mist/vapours/spray 280 Wear protective gloves/eye protection Precautionary statements - response P302+P352 IF ON SKIN: Wash with plenty of water P305+P351+P338_ IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P310 Immediately call a POISON CENTER/doctor Label 19 of packages where the contents de not exceed 125 mi Signal word: DangerSafety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 23 symbols) 314 Causes severe sin burns and eye damage. 260 Do not breathe mistivapours/spray 280 Wear protective glaves/eye protection P305+P3514P338 IF IN EVES: Rinse cautiously with water for several minutes, Remove contact lenses, I present and easy to de. Continue rinsing P20 Immediately call 2 POISON CENTER/doctor. Other hazards Results of PBT and vPvB assessment According to the results of its assessment, this substance is not a PBT or a vPvB. SECTION 3: Compo: 3A inne ea Substances Name of substance Propionic acid Molecular formula GHiO, Molar mass 74,08 Yonot REACH Reg. No 01-2119486971-24-1xx CAS No 79-09-4 ECNo 201-1763 Index No 607-089-00-0 Substance, Specific Conc. Limits, M-factors, ATE Peony M-Factors Pees Skin Corr, 18; #314: C= 25.9% - Skin Irn. 2; 395: 10% C< 25% Eye Dam, 1; H318: C= 25% ye rit. 2, R315: 1098 5 C<25% STOT SE 3, H335: C2 10% pita pte) fe ry 4a Description of first aid measures General notes Take off immediately all contaminated clothing, Self-protection of the first aider. Following inhalation Provide fresh air. In all cases of doubt, or when symptoms persist, seek medical advice. Following skin contact After contact with skin, wash immediately with plenty of water. Immediate medical treatment re- quired because corrosive injuries that are not treated are hard to cure.Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 Following eye contact In case of contact with eyes flush immediately with plenty of flowing water for 10 to 15 minutes hold- ing eyelids apart and consult an ophthalmologist. Protect uninjured eye. Following ingestion Rinse mouth immediately and drink plenty of water. Call a physician immediately. If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects). 4.2 Most important symptoms and effects, both acute and delayed Corrosion, Risk of blindness, Gastric perforation, Risk of serious damage to eyes, Irritation, Cough, Dyspnoea 4.3. Indication of any immediate medical attention and special treatment needed none SECTION 5: Firefighting measures 5.1 Extinguishing media ing media co-ordinate firefighting measures to the fire surroundings water spray, dry extinguishing powder, BC-powder, carbon dioxide (CO,) Unsuitable extinguishing media water jet 5.2 Special hazards arising from the substance or mixture Combustible. In case of insufficient ventilation and/or in use, may form flammable/explosive vapour- air mixture. Solvent vapours are heavier than air and may spread along floors. Places which are not ventilated, e.g. unventilated below ground level areas such as trenches, conduits and shafts, are par- ticularly prone to the presence of flammable substances or mixtures. Vapours are heavier than air, spread along floors and form explosive mixtures with air. Vapours may form explosive mixtures with air, Hazardous combustion products In case of fire may be liberated: Carbon monoxide (CO), Carbon dioxide (CO,) 5.3 Advice for firefighters In case of fire and/or explosion do not breathe fumes. Fight fire with normal precautions from a reas- onable distance. Wear self-contained breathing apparatus. Wear full chemical protective clothing, SECTION 6: Accidental release measures 61 Personal precautions, protective equipment and emergency procedures A For non-emergency personnel Use personal protective equipment as required. Avoid contact with skin, eyes and clothes, Do not breathe vapour/spray. Avoidance of ignition sources.Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 62 63 64 SECTION Environmental precautions Keep away from drains, surface and ground water. Danger of explosion. Methods and material for containment and cleaning up Advice on how to contain a spill Covering of drains. Advice on how to clean up a spill ‘Absorb with liquid-binding material (sand, diatomaceous earth, acid- or universal binding agents). Other information relating to spills and releases Place in appropriate containers for disposal. Ventilate affected area. Reference to other sections Hazardous combustion products: see section S. Personal protective equipment: see section 8, Incom- patible materials: see section 10. Disposal considerations: see section 13, Handling and storage 7A 72 73 Precautions for safe handling Provision of sufficient ventilation. Use extractor hood (laboratory). Handle and open container with care. Clear contaminated areas thoroughly. Measures to prevent fire as well as aerosol and dust generation Keep away from sources of ignition - No smoking, Take precautionary measures against static discharge Advice on general occupational hygiene Wash hands before breaks and after work. Keep away from food, drink and animal feedingstuffs. When using do not smoke. Conditions for safe storage, Keep container tightly closed. Incompatible substances or mixtures Observe hints for combined storage. including any incompatibilities Consideration of other advice: Ground/bond container and receiving equipment. Ventilation requirements Use local and general ventilation. Specific designs for storage rooms or vessels Recommended storage temperature: 15-25 °C Specific end use(s) No information available,Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 pita poly a1 Bae eke eee) Control parameters National limit values Occupational exposure limit values (Workplace Exposure Limits) en Per cg aay oy Ipp LO) Core Set ae cn Ae as ce pp 3) on irks ara cul Nota- cry pares Peers propionicacid | 70-09-4 | ror | 10 | 31 | 20 | 62 20001/39/ 1 | propionicacd | 79-094] oe | to | 31 | 20 | oz Sie, G19 0f 2001 Notation Celling-C Ceiling value is a limit value above which expasure should not occur Stel? Shortterm exposure limita lmit value above which exposure should not occur and which i related to 2 15 minute period (unless atnerwise specified) TWA —_Timecwisighted Sverage long-term exposure limit: measured or calculated in relation to a reference period of 8 hours time-weighted average (unless otherwise specified) Human health values Relevant DNELs and other threshold levels Secon rT eri See rr pore ety NEL 0,26 mg/kg human, dermal worker (industry) chronie-local effects NEL G2mgin? | human, inhalatory worker (industry) acute -systemic effects NEL 73mgime | _ human, inhalatory worker (industa) “chronic systemic effects NEL SH mgim? | _ human, inhalatory worker (industry) chronie local effects NEL @2mgin? | human, inhalatory ‘worker (indus) ‘acute focal effects one, 2nsmgagbw [ human, dermal worker (industny) ‘chronic systemic effects ay Environmental values Relevant PNECs and other threshold levels. End- Threshold ed Cee teas See Ponta Tevel pening PNEC 0575) aquatic organisms freshwater short-term (singe insta PNEC 0.057% ‘aquatic organisms marine water Short-term (single Instance) PNEC 5707, aquatic organisms Sewage treatment plant | short-term (ingle Instance) (ste) PNEC | 1.86 %q aquatic organisms freshwater sediment | short-term (single instane PREC | 0186 ™%y aquatic organisms Tmarine sediment Shoreterm (ingle instance) PNEC | 0.126"%g ‘Terrestrial organisms sol Shoreterm (ingle instance)Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 82 Exposure controls Individual protection measures (personal protective equipment) Eye/face protection OW Use safety goggle with side protection. Wear face protection. protection + hand protection Wear suitable gloves. Chemical protection gloves are suitable, which are tested according to EN 374. Check leak-tightness/impermeability prior to use. For special purposes, it is recommended to check the resistance to chemicals of the protective gloves mentioned above together with the supplier of these gloves. The times are approximate values from measurements at 22 ° C and permanent con- tact. Increased temperatures due to heated substances, body heat etc, and a reduction of the effect- ive layer thickness by stretching can lead to a considerable reduction of the breakthrough time. If in doubt, contact manufacturer. At an approx. 1.5 times larger / smaller layer thickness, the respective breakthrough time is doubled / halved. The data apply only to the pure substance. When transferred ‘to substance mixtures, they may only be considered as a guide. + type of material Butyl caoutchouc (butyl rubber) + material thickness 0,5 mm. + breakthrough times of the glove material >480 minutes (permeation: level 6) + other protect Take recovery periods for skin regeneration. Preventive skin protection (barrier creams/ointments) is recommended. n measures Respiratory protection a) Respiratory protection necessary at: Aerosol or mist formation. Type: A (against organic gases and va- pours with a boiling point of > 65 °C,, colour code: Brown). Environmental exposure controls Keep away from drains, surface and ground water.Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic acid 299,5%, for synthesis article number: 6026 pita poly a4 92 hy: Sr cuo oae Information on basic physical and chemical properties Physical state Colour Odour Melting point/freezing point Boiling point or initial bolling point and boiling range Flarnmability Lower and upper explosion limit Flash point Auto-ignition temperature Decomposition temperature PH (value) Kinematic viscosity Dynamic viscosity Solul ity(ies) Water solubility Partition coefficient Partition coefficient n-octanol/water (log value): Soil organic carbon/water (log KOC) Vapour pressure Density and/or relative density Density Relative vapour density Particle characteristics Other safety parameters Oxidising properties Other informa in Information with regard to physical hazard classes: liquid colourless pungent 21°C 140,7 -141,4°C at 1.013 hPa (ECHA) flammable liquid in accordance with GHS criteria 2,1 voll (LEL) - 12 voll (UEL) 50°C 440 °C at 1,013 hPa (ECHA) not relevant 2,5 (in aqueous solution: 100 9%, 20 °C) not determined 1 mpPas at 25°C not determined 0,33 (exp. (TOXNET) 0,079 (ECHA) ShPa at 20°C 23 hPa at 50°C 0,99 Ym at 20 °C 2,56 (air=1) not relevant (liquid) none There is no additional information.Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 Barc m 10.1 10.2 103 10.6 Other safety characteristics Temperature class (EU, acc. to ATEX) 2 Maximum permissible surface temperature on the equipment: 300°C tability and reacti to Reactivity It's a reactive substance, Risk of ignition. If heated Risk of ignition, Vapours may form explosive mixtures with alr Chemical stability The material is stable under normal ambient and anticipated storage and handling conditions of tem- perature and pressure. Possibility of hazardous reactions Violent reaction with: strong oxidiser, Reducing agents, Strong alkali, Phosphorus trichloride, Iron, Zine, Magnesium, Lead, Metal catalyst Conditions to avoid Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Incompatible materials iron, different plastics, copper, zinc, Brass Hazardous decomposition products Hazardous combustion products: see section 5. Bete Co) re ea m4 Information on hazard classes as defined in Regulation (EC) No 1272/2008 Classification according to GHS (1272/2008/EC, CLP) Acute toxicity Shall not be classified as acutely toxic Acute toxicity Se ne es Value py ere ped oral woso 3.55 ig nt ECHA inhalation: vapour eso 337 "5th rat ECHA dermal ose 3.35 "hg mt ECHA Skin corrosion/irritation Causes severe skin burns and eye damage. Serious eye damage/eye irritation Causes serious eye damage. Respiratory or skin sensitisation Shall not be classified as a respiratory or skin sensitiser.Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 Germ cell mutagenicity Shall not be classified as germ cell mutagenic. Carcinogenicity Shall not be classified as carcinogenic. Reproductive toxicity Shall not be classified as a reproductive toxicant. Specific target organ toxicity - single exposure May cause respiratory irritation, Specific target organ toxicity - repeated exposure Shall not be classified as a specific target organ toxicant (repeated exposure). Aspiration hazard Shall not be classified as presenting an aspiration hazard. Symptoms related to the physical, chemical and toxicological characteristics “If swallowed If swallowed danger of perforation of the esophagus and the stomach (strong corrosive effects) “If in eyes causes burns, Causes serious eye damage, risk of blindness “Ifinhaled Irritation to respiratory tract, cough, Dyspnoea *Ifon skin causes severe burns, causes poorly healing wounds + Other information none 11.2. Endocrine disrupting properties Not listed, 11.3 Information on other hazards There is no additional information. SECTION 12: Ecological informa’ 12.4 Toxicity Shall not be classified as hazardous to the aquatic environment. Aquatic toxicity (acute) Errn rary Pen pares Les >10.0008/, fish CHA ECs0 35007% ‘aquatic invertebrates ECHA 8h Biodegradation Data are not available.Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 12.2 123 12.4 125 126 127 Process of degradability Theoretical Oxygen Demand: 1,51 %/ Theoretical Carbon Diowide: 1,782 "Sing Process of degradability Process Eee ecunery bioticfabiotie 74% 30d Bioaccumulative potential Does not significantly accumulate in organisms, n-octanol/water (log KOW) 0,33 (Exp. (TOXNEN) Mobility in soit Henry's law constant 0,07 7 ™ fyi at 25 °C (ECHA) The Organic Carbon normalised adsorption _| 0,079 (ECHA) coefficient Results of PBT and vPvB assessment Data are not available. Endocrine disrupting properties Not listed, Other adverse effects Data are not available. SECTION 1 tr eee eli 1341 13.2 133 Waste treatment methods ro ‘+ This material and its container must be disposed of as hazardous waste. Dispose of contents/contain- er in accordance with local/regional/national/international regulations. Sewage disposal-relevant information Do not empty into drains. Waste treatment of containers/packagings Itis a dangerous waste; only packagings which are approved (e.g. acc. to ADR) may be used. Relevant provisions relating to waste The allocation of waste identity numbers/waste descriptions must be carried out according to the EEC, specific to the industry and process. Waste catalogue ordinance (Germany). Remarks Waste shall be separated into the categories that can be handled separately by the local or national waste management facilities. Please consider the relevant national or regional provisions.Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic acid 299,5%, for synthesis article number: 6026 SECTION 14: Transport information 141 UN number or ID number ADRRID UN 3463 IMDG-Code UN 3463 IcAO-TI UN 3463 14.2 UN proper shipping name ‘ADRRID PROPIONIC ACID IMDG-Code PROPIONIC ACID ICAO-TI Propionic acid 14.3 Transport hazard class(es) ‘ADRRID 803) IMDG-Code 8) ICAO-TI 803) 14.4 Packing group ADRRID 1 IMDG-Code ICAO-TI r 145 Environmental hazards non-environmentally hazardous ace. to the dan- gerous goods regulations 14.6 Special precautions for user Provisions for dangerous goods (ADR) should be complied within the premises. 14.7 Maritime transport in bulk according to IMO instruments The cargo is not intended to be carried in bulk. 14.8 Information for each of the UN Model Regulations Transport of dangerous goods by road, rail and inland waterway (ADR/RID/ADN) - Additional information Proper shipping name PROPIONIC ACID Particulars in the transport document UN3463, PROPIONIC ACID, 8 (3), Il, (O/E) Classification code cr Danger label(s) 813 Excepted quantities (EQ) 82 Limited quantities (LQ) aL Transport category (TC) 2 Tunnel restriction code (TRC) DieSafety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic acid 299,5%, for synthesis article number: 6026 Hazard identification No 83 Regulations concerning the International Carriage of Dangerous Goods by Rall (RID)Additional fo mation Classification code Danger labels) oe Excepted quantities (EQ) Limited quantities (LQ) Transport category (TC) Hazard identification No faa 843 £2 aL 2 83 International Maritime Dangerous Goods Code (IMDG) - Additional information Proper shipping name Particulars in the shipper’s declaration Marine pollutant Danger labels) oe Excepted quantities (EQ) Limited quantities (LQ) Ems Stowage category Segregation group PROPIONIC ACID UN3463, PROPIONIC ACID, 8 (3), II, 50°C c.c. 843, 2 aL FE SC A 1 Acids International Civil Aviation Organization (ICAO-IATA/DGR) - Additional information Proper shipping name Particulars in the shipper's declaration Danger labels) oe Excepted quantities (EQ) Limited quantities (LQ) Propionic acid UN3463, Propionic acid, 8 (3), I 843 e2 OSLSafety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic acid 299,5%, for synthesis article number: 6026 SECTION 15: Regulatory information 15.1 Safety, health and environmental regulations/legislation speci for the substance or mixture Relevant provisions of the European Union (EU) Restrictions according to REACH, Annex XVII Dangerous substances with restrictions (REACH, Annex XVII) eer Pees Co ce me) Propionic acid this product meets the criteria for Ra 3 classification in accordance with Reg- Ulbtion No 1272/2008/EC. Propionic acd flammable /pyrophoric a0 0 Propionic acd ‘Substances in tatoo inks and perman’ RS ent makeup Legend Ra ao 1. Shall not be used in ‘ehamenta les tended to produce light or colour eects by means of different phases for example in orna- manta lampeand 9a " andfoe seimendeato beusea , ' “games for one br mare partipants, or any ate intended tobe use ag such even with omamental specs hes no comply ng eth prag"aph Sal nee flced on the matic. is 3. Shall not be placed on the market if they contain a colouring agent, unless required for fiscal reasons, or perfume, dr bof ins a Ganbe used 2s fuel in decorative oil amps for supaly tothe general public, and presenta ast? Narada ae Tabled i ean owt th {igapean Standard ‘bn Decerouve ol lamp EN 14058) adopted by the European Committe Tor Stahdsrdisuon Shut peur the mplemertain of oer Union provsons rating to theca, ling and pak acg’ dt substances srl bere supplrs soa ensure before the ploang brtne market tax the folowing requre- sank are met {lamp oi beled wth 1204, tended for supply to the general public are visibly legibly and indelibly marked as Fla eg amps led wh vs haul out of the reach of cre and by Beceber 20, usta pot rm reve sui fhe te amps no at eseatening ng amas (hari fds Sbtes ithi368 fence or up toe evel public are by and nde marked by {cemBe 2199 fons ust asp ti gir flay en oe treteing kg area, islarmps ols and gil lghers bei wid 128s tended or supph tothe sone pub ae paged in Back Spaque contatners not cessing tle by 1 December 2010 SPSRal nat be use. as evbsants ora mocures i aerovel dpensers where these aerosol penser are Intended tecupplea the gf ue fer entearment ana deck prunes shoe ow ‘Shetlic ite’ tented many for decoration “arta Show and ose “ithaopee’ con aon etree, 1 decorative fakes and foams, rafal cobs thou prejudice to the application of he classi aging and labeling of Substances, supplies shal ature before the placing on the market thatthe packaging of esol dispensers referred iSvare imate ty ea andincla wt 3° Byway of derogation, paragraphs 1 and shallot apply othe aerosol dispensers referred Counel Directive P/a24/EEC (2), 1°the aerosldapenaers elered (on paragraphs 1 and2 shallot be placed on the marke ules they conform to thereguements ndested Article 8 (1a) ofSafety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic aci id 299,5%, for synthesis article number: 6026 Legend RIS penis gee an SRS Beaa Coe ren ee Te tes ant cree teria Ieee ee eaten) es i ta a tahae oa , iiaiecea ein (Aer EPS cduagapled on micusmenraner, Wy Nee ati eta Buewinsree sci aera einen rates soured saree en eee RISC ed neue aod BaP eee eet i eats each nmap le atckey RS NSANG ns song ON Rea! Panaceins agranks oe SPAT oT eRe estes sie mtn mor han one pains )o of pagan he rie, deena eS ae ee as Ses he sae A, GR St EY ea Sapte unc uanany 2028 idence eR eS FEN APOC ae ” Gyan eueny rds kesosieseey owas) Peers ero ranean ena) S808 Serhan my 00 wnt areca aerate Saale et Sc au nah a Se Raa PRS ra HeLa a ia Stvcr ne ae uO Mecha EL nd he a Beaty acne Seca ceca Sar he ied clean re cng DSS Snel ta estan NSS ed oa 201 tage nein sinadb Ca ta teres er elas par eu Ghana ace no Seen ee hamden anon a ln Sha eH ad oe RE acon ese areas ed owas pa enlace ry Harter aN re aera cng Raa Weta pebes Tne roe eg rho kere Tastee eka watt ent i ce Popol patent ae nae efor teal pfs al ek, eros 202.6 ict dnedeaM Ne rs rte Brien nur eter aren teu By peeege nme ay acne Scie agente cr nanan ine any of coon nent Fees eae ee na es ea en AO Ra eae aR esate Gah Oe eae a an wiseiaat nam sie by sega Eanes Sages et ota "ge eae Bi ae sees Brey we Bebe oa ams Sn er tate Ucar ittchndle igascre Voerane stan ace og ne et ees hal te a wchcuchsn eels iat ush gunk Een WON at ie su soi MSY Benesch Esa acne 6 aes face Baap OW of agp Ee re eae an eee estan ern, ka aay concn Biearsriig eee aa Ihe SAD rin qn can cate aleglecins he ite cons enim 0 elon cane naar Kaas Uh SRO ane ada ey a ot aren equres tobe stated onthe bey Regus 0 No Flat sate dey ste sty abi and acinar nde Eee te ete cared onthe ec ea Se cota BUS pete sae wre cre acd ISSIR Sa earned Pues Herre Mente taba ez Bice TAN in mR Sade IRS US ea oa i Bhat do ocean the staan mitre fr eats or peanet mae" shale orSafety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 Legend 9. This entry does not apply to substances that are gases at temperature of 20 °C and pressure of 101.3 kPa, or gener~ aie a vapour pressure of more than 200 kha a temperature cf 0% wih te exception of frmvaldenjde (CAS No 30. ocd, ECNo 200-0018). ‘0. This entry does not apply to the placing on the market of a mixture for use for tattooing purposes, orto the use of a minture fof tattooing purposes, when placed on the market exclusively as a medieal device or an accessory to 8 ieaical device, within te meaning of Regulation (€U) 20:7/743, or when used exclusively as 2 mecical devi or an fecesiony toa medial device, ivan the same meaning, Where the Placing an the marke or use may not Be ex ively as » medical device or an accessory (a a medical device, Ine equirements of Regulation (20) 2047/748 ana of Regulation shall apply cumulatively List of substances subject to authorisation (REACH, Annex XIV)/SVHC - candidate list Not listed, Seveso Directive 2012/18/EU (Seveso III) ont er ner kote mcs plication of lower and upper-tier re- Poicurnty Pc flammable liquids (cat. 2,3) 5.000 50,000 5) Notation 51) Flammable liquids, categories 2 or 3 not covered by PSa and PSb Deco-Paint Directive VOC content 100 % 990 8% Industrial Emissions Directive (IED) VOC content 100% VOC content 990 9/, Directive on the restriction of the use of certain hazardous substances in electrical and electronic equipment (RoHS) not listed Regulation concerning the establishment of a European Pollutant Release and Transfer Register (PRTR) not listed Water Framework Directive (WFD) not listed Regulation on the marketing and use of explosives precursors not listed Regulation on drug precursors not listed Regulation on substances that deplete the ozone layer (ODS) not listed Regulation concerning the export and import of hazardous chemicals (PIC) not listed Regulation on persistent organic pollutants (POP)Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 15.2 not listed Other information Directive 94/33/EC on the protection of young people at work. Observe employment restrictions un- der the Maternity Protection Directive (82/85/EEC) for expectant or nursing mothers. National inventories Ceram oan AY AIC substance is listed a pst substance is sted w TeCsc substance islsted ay ESL substance is lsted eu REACH Reg. substance is isted P CScLENCS substance is listed Ke Kec substance sisted wx TNS substance is sted Nz Nzioc substance is sted PH PICs substance is sted Te cick substance is listed Ww Test substance is sted us TSCA substance is listed Legend Ace Chew linentaryand Controt Regulater” ESCL-ENCS ist of Existing and New Chemical Substances (CSCL-ENCS) Domestic Substances (ist (O31), Ee Ruwance invertor EONECS, LINCS, NLP) Inventory of Existing Chemical Substances Produced or Imported in China National inventory f Chemical Substances, Korea Existing Cremicals Inventory New Zealand inventory of Chemicals Philippine Inventory of Chemicals and Chemical Substances (PICCS) REACH registered substances Taiwan Chemical Substance Inventory Tonic Substance Control Act Chemical Safety Assessment No Chemical Safety Assessment has been carried out for this substance. SECTION 16: Other information Indication of changes (revised safety data sheet) Alignment to regulation: Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU Restructuring: section 9, section 14Safety data sheet according to Regulation (EC) No. 1907/2006 (REACH) Propionic acid 299,5%, for synthesis article number: 6026 Peng Former entry (text/value) Actual entry (text/value) Erog Pa Bd 24 Classification according to Regulation (EC) No | yes "1272/2008 (CLP) ‘change inthe listing (table) 2A ‘The mast important adverse physicochemical, | yes human health and environmental effets skin corrosion produces an irreversible darn age to the skin; namely, sible necrosis through the epidermis and into the dermis, The praduct Is combustible and can be ignited by potential ignition sources. 22 Pictograms: yes change in the listing (table) 22 Precautionary statements - prevention: ye ‘change inthe listing (fable), 22 Labeling of packages where the contents do | yes not exceed 125 mi: ‘change inthe listing (tale) 23 ‘Other hazards: Other hazards yes There is no additional informacion, 23 Results of PBT and vPvB assessment yes According to the results of fs assessment, this substance s nota PBT or 3 VPVB Abbreviations and acronyms 2000/39/EC | Commission Directive establishing a first Ist of indicative occupational exposure limit values in imple: ‘mentation of Council Directive 98/24/EC ABN) ‘Accord européen relatif au transport international des marchandises dangereuses par voles de naviga tlon intérieures (European Agreement concerning the international Carriage of Dangerous Goods by in Tand Waterways) ‘ADR ‘Accord relatif au transport international des marchandises dangereuses par route (Agreement concern: ing the International Carriage of Dangerous Goods by Road) ATE ‘Acute Toxicity Estimate cS Chemical Abstracts Service (service that molntains te most comprehensive Ist of chemical substances) Celling€ Celling value cP Regulation (EC) No 1272/2008 on classification, labeling and packaging of substances and mibcures Der Dangerous Goods Regulations (see JATA/DGR) NEL Derived No-efect Level cso fective Concentration 50 %, The ECS0 corresponds to the concentration ofa tested substance causing '50 8 changes in response (e.g, on growth) during a specified time interval EEN | The EC inventory (EINECS, ELINCS and the NLP-Isb isthe source for the sever-digit EC number, an ident Fer of substances commercially available within the £U European Union). EINECS European Inventory of Existing Commercial Chemical Substances LINCS Furopean List of Notified Chemical Substances ems Emergency ScheduleSafety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 ce HS Global Harmonized System of Clssfcaven and Labeling of Cheri" devloped by the United Na IATA international A Transport Association TATAIDGR, Dangerous Goods Regulations (OGR) forthe air transport (ATA) cao International Cw Avation Organization 1cho-TT Technical instructions for the safe transport of dangerous goods by ar TwDG International Maritime Dangerous Goods Code IMDG-Code International Maritime Dangerous Goods Code indexNo | the index number Is the ientfcation code given tothe substance in Part3 of Annex Vito Regulation (EC) No 127212008 ToEW ndicative occupational exposure limit value Lc50 | Lethal Concentration 503% the LC5O corresponds to the concentration of a tested substance causing 50% Tethalty during a specified time interval 1530 | Lethal Dose 50 the 1050 corresponds to the dose ofa tested substance causing 60% lethaly during @ Specified time interval ie Lower explosion limit (CEU) NUP ‘Ne-Longer Polymer Per Persistent, Bloaccumulative and Toxic PNEC Predicted No-ffect Concentration Per Parts per milion REACH Registration, Evaluation, Authorisation and Restrition of Chemicals RID Rglement concernant le transport international ferveviaire des marchandises Dangereuses Regula- ‘ions concerning the International carriage of Dangerous goods by Rall SI No. 619 f Safety, Health and Welfare at Work (Chemical Agents) Regulations 2001 SreL Shoreterm exposure limit Sve Substance of Very High Concern TWA Time-weighted average ue Upper explosion limit (UED) vor Volatile Organic Compounds ws Very Persistent and very Bioaccurmulatve Key literature references and sources for data Regulation (EC) No 1272/2008 on classification, labelling and packaging of substances and mixtures Regulation (EC) No. 1907/2006 (REACH), amended by 2020/878/EU. ‘Agreement concerning the International Carriage of Dangerous Goods by Road (ADR). Regulations concerning the International Carriage of Dangerous Goods by Rail (RID). International Maritime Dan- gerous Goods Code (IMDG), Dangerous Goods Regulations (DGR) for the air transport (IATA).Safety data sheet according to Regulation (EC) No. 1907/2006 ( :ACH) Propionic acid 299,5%, for synthesis article number: 6026 List of relevant phrases (code and full text as stated section 2 and 3) rn Text 1226 Flammable quid and vapour Hat ‘Causes severe skin burns and eye damage. Hate ‘Causes serious eye damage 155 May cause respratory tation Disclaimer This information is based upon the present state of our knowledge. This SDS has been compiled and is solely intended for this product.