Ftre 2023 Sample Paper Class Xi p2 PCM

FIITJEE TALENT REWARD EXAM - 2023
for Students presently in Class XI (Paper 2)

Time: 3 Hours SAMPLE PAPER Maximum Marks: 225
Instructions:
Caution: Class, Paper, Code as given above MUST be correctly marked on the answer OMR sheet
before attempting the paper. Wrong Class, Paper or Code will give wrong results.
1. You are advised to devote 30 Minutes on Section-I, 30 Minutes on Section-II and

120 Minutes on Section-III.
2. This Question paper consists of 3 sections. Marking scheme is given in table below:
Marking Scheme for each question
Section Subject Question no.
Correct answer Wrong answer
PHYSICS (PART-A) 1 to 5 +3 –1
SECTION – I CHEMISTRY (PART-B) 6 to 10 +3 –1
MATHEMATICS (PART-C) 11 to 15 +3 –1
SECTION – II CHEMISTRY (PART-B) 21 to 25 +3 –1
SECTION – III CHEMISTRY (PART-B) 46 to 60 +3 –1
3. Answers have to be marked on the OMR sheet. The Question Paper contains blank spaces for your rough
work. No additional sheets will be provided for rough work.
4. Blank papers, clip boards, log tables, slide rule, calculator, cellular phones, pagers and electronic devices,
in any form, are not allowed.
5. Before attempting paper write your OMR Answer Sheet No., Registration Number, Name and Test
Centre in the space provided below.
Note: Please check this Question Paper contains all 75 questions in serial order. If not so, exchange for the correct Question Paper.
OMR Answer Sheet No. : ____________________________________________________________
Registration Number : ____________________________________________________________
Name of the Candidate : ____________________________________________________________
Test Centre : ____________________________________________________________
FIITJEE Ltd., FIITJEE House, 29-A, Kalu Sarai, Sarvapriya Vihar, New Delhi -110016 (website: www.fiitjee.com)
FTRE-2023-SAMPLE PAPER-C-XI-(Paper-2)-PCM
Recommended Time: 30 Minutes for Section – I

Section – I
PHYSICS – (PART – A)
This part contains 5 Multiple Choice Questions number 1 to 5. Each question has 4 choices
(A), (B), (C) and (D), out of which ONLY ONE is correct.
1. A plate of mass m is placed on a frictionless surface. The plate is connected m

to block of mass M through a string over a massless pulley. m
A cylinder of mass m is placed on the plate which rolls without slipping. Find M
the frictional force acting on the cylinder :
(M  m)g mg
(A) (B)
6 6
Mmg 2(M  m)g
(C) (D)
3M  4m 3
2. In the head on elastic collision of a heavy vehicle moving with a velocity of 10 ms–1 and a small
stone at rest, the stone will fly away with a velocity equal to
(A) 5 ms–1 (B) 10 ms–1
–1
(C) 20 ms (D) 40 ms–1
3. A metal ball of mass 2 kg moving with speed of 36 km/h has a head-on collision with a stationary
ball of mass 3 kg. If after collision, both the balls move together, then the loss in kinetic energy
due to collision is
(A) 40 J (B) 60 J
(C) 100 J (D) 140 J
4. A projectile of mass m is thrown with velocity v making an angle of 30° with vertical. Neglecting
air resistance the magnitude of change in momentum between the starting point and at the
maximum height is
mv 3mv
(A) (B)
2 2
7mv
(C) mv (D)
2
5. A ball is attached to a string and moves in a vertical circle. The string is always taut and there are
absolutely no resistive forces. Which of the following statements is most correct:
(A) the net force on the ball is always vertical.
(B) the net force on the ball is always perpendicular to the velocity vector of the ball.
(C) the net force on the ball is always towards centre.
(D) the tension in the string is greatest when the ball is at its lowest point.
Space for Rough Work
Page No. 1
CHEMISTRY – (PART – B)
6. The stereochemical relationship between the following molecules is

Br Cl
Cl Br
(A) identical (B) enantiomers
(C) distereomers (D) constitutional isomer
7. The increasing order of acid strength of the following acid is

NHCOCH3 CONHCH3
1 2
COOH COOH
OCOCH3 COOH
3 4
COOH
(A) 1 < 2 < 3 < 4 (B) 4 < 2 < 3 < 1
(C) 4 < 3 < 2 < 1 (D) 1 < 3 < 4 < 2
Page No. 2
8. The maximum orbital angular momentum of an electron with n = 5 is

h h
(A) 6 (B) 12
2 2
h h
(C) 42 (D) 20
2 2
9. 10 mL of NaHC2O4 is oxidised by 10 mL of 0.02 M MnO4 in basic medium. Hence, 10mL of

NaHC2O4 is neutralised by
(A) 10 mL of 0.01 M NaOH (B) 10 mL of 0.02 M NaOH
(C) 10 mL of 0.1 M Ca(OH)2 (D) 10 mL of 0.05 M Ba(OH)2
10. H3PO4 is a tribasic acid and one of its salt is NaH2PO4. What volume of 1 M NaOH solution
should be added to 12g of NaH2PO4 to convert it into Na3PO4?
(A) 100 mL (B) 200 mL
(C) 80 mL (D) 300 mL
Page No. 3
MATHEMATICS – (PART – C)
11. The product of n positive numbers is unity. Then their sum is

(A) a positive integer (B) divisible by n
1
(C) equal to n  (D) never less than n
n
12. The least integral value of k such that (k –2)x2 + 8x + k + 4 is positive for all real values of x is
(A) 1 (B) 2
(C) 3 (D) 5
13. If z be any complex number such that |3z –2| + |3z +2| = 4, then locus of z is
(A) an ellipse (B) a circle
(C) a line-segment (D) None of these
1 1 1
14.   is equal to
log xy xyz log yz xyz log zx xyz
(A) 0 (B) 1
(C) 2 (D) log x xyz
15. The differential coefficient of f(loge x), where f(x)  loge x is

x
(A) (B) ( x log e x ) 1
log e x
loge x
(C) (D) none of these
x
Page No. 4
Recommended Time: 30 Minutes for Section – II
Section – II
16. A wire of length L, cross-sectional area A is made of a material of Young’s modulus Y. The wire is
stretched by an amount x, which lies well within the elastic limit. The work done (W) by the force
is
Yx 2 Yx 2
(A) W  (B) W 
L2 2L2
1 YAx 2 YAx 2
(C) W  (D) W 
2 L L
17. The coordinates of a moving particle at any time ‘t’ are given by x = t3 and y = 4t2, where x and y
are in metre and t in second. The acceleration of the particle at time t = 1s is given by
(A) 6 ms–2 (B) 8 ms–2
–2
(C) 10 ms (D) 14 ms–2
18. A uniform chain has a mass M and length L. It is placed on a frictionless table with length l0
hanging over the edge. The chain begins to slide down. The speed V with which the chain slides
away from the edge is given by
gl 0 gl 0
(A) V  L  l 0  (B) V  L  l 0 
L L
g 2 2
(C) V  L  l 0  (D) V  2 g L  l 0 
L
Page No. 5
19. A small particle of mass m is released from rest in the position l

shown and swings freely in vertical plane first about O and
O
then about a peg A (Vertically below the point O) after cord
comes in contact with the peg A. Find the value of OA if
particle just complete the circle about A (length of string is l and
string is massless and inextensible) R
(A) 0.6 l (B) 0.4 l A
(C) 0.5 l (D) 0.3 l
R
20. In the adjoining figure block A is of mass m and block B is

of mass 2m. The spring has a force constant k. All the A
surfaces are smooth and the system is released from rest
with spring unstretched, then B
4mg
(A) The maximum extension of the spring is
k
2mg m
(B) The speed of block A when extension in spring is , is 2 g
k k
g
(C) Net acceleration of block B when the extension in the spring is maximum, is .
2
2mg
(D) Tension in the thread for extension of in spring is mg.
k
Page No. 6
21. What volume of 0.1M H2SO4 will be required to produced 17.0 g of H2S by the following reaction?
5H2SO4  10NaI  4Na2SO 4  5I2  H2S  4H2O
(A) 2.5 L (B) 50.0 L
(C) 25.0 L (D) 5.0 L
22. The equilibrium constant for a reaction

N2 (g)  O2 (g)  2NO(g) is 4  104 at 2000 K. In the presence of catalyst, the equilibrium is
attained 10 times faster. The equilibrium constant in the presence of catalyst, at 2000 K is
(A) 40  10 4 (B) 4  104
(C) 4  102 (D) incomplete data
23. Two solid compounds X and Y dissociates at a certain temperature as follows

X(s)  A(g)  2B(g);KP1  9  103 atm3
Y(s)  2B(g)  C(g);KP2  4.5  103 atm3
The total pressure of gases over a mixture of X and Y is:
(A) 4.5 atm (B) 0.45 atm
(C) 0.6 atm (D) 60 atm
24. How many gm of solid KOH must be added to 100 mL of a buffer solution to make the pH of
solution 6.0, if it is 0.1 M each w.r.t weak acid HA and salt K A.
(A) 0.458 (B) 0.327
(C) 5.19 (D) 3.27
25. Which of the following species has the shortest bond length?
(A) NO2- (B) NO+
(C) NO (D) NO-
Page No. 7
26. Value of the expression 2sinx – cos2x is always

(A) greater than or equal to -3/2 (B) less than or equal to 3/2
(C) greater than or equal to -1/2 (D) none of these
4 4
27. Find minimum value of sin x + cos x ?
1
(A) 1 (B)
2
1
(C) (D) 0
4
28. If x + y = k is normal to parabola y2 = 12x. Find k?

(A) 3 (B) 9
(C) –9 (D) 3
29. Differentiation of sin 2x w.r.t. x is

2
(A) cot 2 x sin 2 x (B)
sin 2x
(C) 2cos 2x (D) none of these
30. The sum of an infinitely decreasing G.P. is equal to 4 and the sum of the cubes of its terms is
equal to 64/7. Then 5th term of the progression is
1 1
(A) (B)
4 8
1 1
(C) (D)
16 32
Page No. 8
Recommended Time: 120 Minutes for Section – III
Section – III
This part contains 15 Multiple Choice Questions number 31 to 45. Each question has 4
choices (A), (B), (C) and (D), out of which ONLY ONE is correct.
31. A light string of 70 cm has its two ends tied at the same level 50 cm
50 cm apart. A force of 100 N is applied at a distance of P Q
30 cm from P. The tension in part PR is 
(A) 18 N (B) 8 N 30 cm 90º 40 cm
(C) 0 N (D) 80 N R
100 N
32. A girl throws a ball with initial velocity v at an inclination of 45º. The ball strikes a smooth vertical
wall at a horizontal distance d from the girl and after rebouncing returns to her hand. The
coefficient of restitution between the wall and the ball is
gd v2
(A) 2 (B)
v gd
gd v 2  gd
(C) 2
(D)
v  gd v2
33. A mass 2m lying on a horizontal table is attached to a light inextensible string which passes over
a smooth pulley and carries a mass m at the other end. If the mass m is raised vertically through
a distance h and is then dropped, then the speed with which the mass 2m begins to rise is
gh
(A) (B) gh
2
2gh
(C) 2gh (D)
3
Page No. 9
34. The mass collides in air stick together. After how much time m Just dropped
combined mass will fall to the ground (calculate the time from the
starting when the motion was started)

(A) 1  2 s  20 m
(B) 2 2s 20 m/s

(C) 2  2 s 
(D) none of these m
35. A block of mass m is pushed towards a movable wedge of mass 2m and height h with a velocity
u. All surfaces are smooth. The minimum value of u for which the block will reach the top of the
wedge, is
(A) 2 gh (B) 3gh

3
(C) 6gh (D) gh
2
36. The moment of inertia of a uniform rod of length 2l and mass m about an axis xx passing through
its centre and inclined at an angle  is
ml 2 ml 2
(A) sin 2  (B) sin 2 
3 12
ml 2 ml 2
(C) cos 2  (D) cos 2 
6 2
Page No. 10
37. The moment of inertia of a rectangular lamina of mass ‘m’, length ‘’ and width ‘b’ about an axis
passing through its centre of mass, perpendicular to its diagonal and lies in the plane.
  2  b2  m  4  b 4 
(A) m   (B)  
 12  12   2  b2 
m   4  b4 
(C)   (D) none of these
6  2  b 2 
38. A disc is pulled by a force F acting at a point above the centre of mass of the disc. The direction
of frictional force  fr  acting on disc pushed on a rough surface will be represented by
F F
(A) C (B) C
f f
F
(C) C (D) Information is insufficient
F=0
39. The earth is an approximate sphere. If the interior contained matter which is not of the same
density everywhere, then on the surface of the earth, the acceleration due to gravity
(A) will be directed towards the centre but not the same every where
(B) will have the same value everywhere but not directed towards the centre
(C) will be the same everywhere in magnitude directed towards the centre
(D) cannot be zero at any point
(Comprehension for Q. No. 40 to 42)
The axle of a pulley of mass 1 kg is attached to the end of an elastic string of length 1m, cross-sectional
area 10–3 m3 and young’s modulus 2 × 105 Nm–2, whose other end is fixed to the ceiling. A rope of
negligible mass is placed on the pulley such that its end is fixed to the ground and its right end is hanging
freely, from the pulley which is at rest in equilibrium. Now the free end A of the rope is subjected to pulling
with constant force F = 10 N. Friction between the rope and the pulley can be neglected. (Given g = 10
ms–2)
1m
A
F
40. The elongation of the string before applying force is

(A) 50 cm (B) 5 cm
(C) 0.5 cm (D) 0.05 cm
Page No. 11
41. The greatest elongation of the string is

(A) 35 cm (B) 30 cm
(C) 25 cm (D) 20 cm
42. The maximum displacement of point A after applying F is

(A) 70 cm (B) 60 cm
(C) 40 cm (D) 50 cm
A shell is fired from point. A with some initial velocity and angle such that it just crosses a wall and falls
at point B. The dimension of wall is (25 m × 12.5 m). It is observed that shell makes an angle 45º at
point P with the horizontal. (g = 10 m/sec2).
43. Angle of projection at point A

(A) 30º (B) 45º
(C) 60º (D) 75º
44. Speed of projection at point A

(A) 5 10 m / sec (B) 10 5 m / sec
(C) 5 15 m / sec (D) 5 5 m / sec
45. Range of projectile

(A) 5 10 m (B) 25 3 m
(C) 5 15 m (D) 25 5 m
Page No. 12
46. Which aromatic acid among the following is weaker than simple benzoic acid-
COOH COOH
(A) (B)
Cl NO 2
COOH COOH
(C) (D)
CH 3 SO 3H
47. Which of the following is least stable?
(A) (B)
 

CH2
(C) HC  C (D)
Page No. 13
48. AB4  C2  C3  A 2

If the O.N. of B is -2. Choose the true statement for the above change-
(A) O.N. of A decreases by +2
(B) O. N. of C decreases by + 1
(C) O.N. of A decreases by +5 and that of C increases by + 1
(D) O.N. of A decreases by +5 and that of C decreases by + 1
49. In the sixth period, the orbitals that are filled are
(A) 6s, 4f, 5d, 6p (B) 6s, 5d, 5f, 6p
(C) 6s, 6p, 6d, 6f (D) 6s, 5f, 6d, 6p
50. Which one of the following is the correct order of the size of the ions?
(A) Na+ > Mg2+ > F– > O 2 (B) O 2  F   Na   Mg2 
(C) Mg2   Na   F   O2  (D) O 2  F   Mg2   Na
51. The correct order of increased C – O bond length of CO, CO23  and CO2
(A) CO23  < CO2 < CO (B) CO2 < CO23  < CO
(C) CO < CO23  < CO2 (D) CO < CO2 < CO23 
52. The dipole moment of LiH is found to be 2.0  10–29 C m. If the interatomic distance in LiH is 1.6
Å, then the percent ionic character of Li–H bond is nearly
(A) 80% (B) 60%
(C) 50% (D) 40%
53. 

The equilibrium constant (Kc) for the reaction HA + B 
+ –
 BH + A is 100. If the rate constant
for the forward reaction is 105, then rate constant for the backward reactions
(A) 107 (B) 103
–3
(C) 10 (D) 10–5
1
54. When lnK is plotted against using the van’t Hoff equation, a straight line is expected with a
T
slope equal to
(A) H0 RT (B)  H0 R
(C) Ho R (D) R Hº
Page No. 14
The electrons in a polyelectronic atoms are as filled one by one in order of increasing energy level. The
energy and orientation of sub shell depends upon the values of three quantum number (i.e. n,l and m
respectively) obtained from Schrodinger wave equation. The different orbitals of sub shell however
posses same energy level and are called degenerate but their energy level changes in presence of
magnetic field and the orbitals are non degenerate. A spectral line is noticed if an electron jumps from
one level to other
55. The correct combinations of quantum numbers for a 5g orbital is

(A) n = 5, l = 0, m = 0 (B) n = 5, l = 1, m = 0
(C) n = 5, l = 4, m = 1 (D) n = 5, l = 3, m = 1
56. Which of the following atomic orbital representation violates the Pauli’s exclusion principle,
Hund’s rule as well as Aufbau principle simultaneously?
2s 2p 4s 3d 4p
(A) (B)
4f 5d 3p 4s
(C) (D)
57. The number of line observed in visible region if electron switches from 5 - shell to ground state is
(A) 10 (B) 9
(C) 7 (D) 3
There are three cylinders of identical volume. A mixture of gases containing N2, NO and NO2 were taken
in the first cylinder at 12 atm and at a certain temperature. After treating the mixture with water, which
absorbs NO2 completely, the remaining gases were transferred to the second cylinder, in which the
pressure was 10 atm. The gases in the second cylinder were treated with FeSO4 solution, which
absorbed NO completely. The remaining gas was transferred to the third cylinder, in which the pressure
was 4 atm. All the operations were carried out at constant temperature.
58. The partial pressure of which of the above gases is maximum?

(A) NO2 (B) NO
(C) N2 (D) Unpredictable
59. What will be the ratio of rates of effusion of the gases  N2 : NO  from the second cylinder if a small
hole is made on the cylinder and the gases are allowed to effuse into vacuum?
(A) 0.43 (B) 0.69
(C) 1.23 (D) 0.28
60. What is the molecular mass of the mixture of gases in the first cylinder?
(A) 29 (B) 32
(C) 27 (D) 36
Page No. 15
100
61. Given that z  1  i 3   , then ratio of real part of z to imaginary part of z is
100
(A) 2 (B) 250
1
(C) (D) 3
3
62. Value of 3 cos ec20º  sec 20º is ?

(A) 2 (B) 4
4
(C) (D) 2 3
3
63. If x3+ax+1=0 and x4 + ax2 + 1 = 0 have a common root, then complete set of values of a is
(A) (, 2) (B) {2}
(C) (2, ) (D) none of these
64. 13  33  53  73  ....  993 equals

(A) 2500  4990 (B) 2500  4999
(C) 250  4999 (D) 2500  4900
sin 2x dy 
65. If y  e , find at x  ?
dx 12
3 2 3 2
(A) e (B) e
2 2
1 1
3 2 3 2
(C) e (D) e
2 2
2z  i
66. If z is a complex number such that  1, then locus of z is
z 1
(A) 3x 2  3y 2  2x  4y  0 (B) 3x 2  3y 2  2x  4y  0
(C) 3x 2  3y 2  4y  0 (D) 3x 2  3y 2  2y
x 1 2
67. If  , then
x2 3
(A) 7  x  10 (B) 7  x  2
(C) 7  x  8 (D) x  7 or x  2
Page No. 16
dy 
68. If y  cos x cos 2x cos 4x cos 8x, find at x  ?
dx 4
1 1
(A) (B)
2 2
(C) 2 (D) 2 2
log3 x 2  log3 x 2 10 1

69. If x  , then x is equal to
x2
(A) 3 (B) 9
(C) 27 (D) 81
Consider a variable line L , which passes through the point of intersection ' P ' of the lines
3 x  4 y  12  0 and x  2 y  5  0 meeting the coordinate axes at points A and B .
70. Locus of the middle point of the segment AB has the equation
(A) 3 x  4 y  4 xy (B) 3 x  4 y  3 xy
(C) 4 x  3 y  4 xy (D) 4 x  3 y  3 xy
71. Locus of the feet of the perpendicular from origin on the variable line L has the equation
(A) 2 x  y 2 2
  3x  4 y  0 
(B) 2 x  y
2 2
  4x  3y  0
2 2 2 2
(C) x  y  2 x  y  0 (D) x  y  x  2 y  0
72. Locus of the centroid of the variable triangle OAB has the equation (where ' O ' is the origin).
(A) 3 x  4 y  6 xy  0 (B) 4 x  3 y  6 xy  0
(C) 3 x  4 y  6 xy  0 (D) 4 x  3 y  6 xy  0
Page No. 17
2
A tangent is drawn at any point P on the parabola y  8 x and a point Q  ,   is taken on it from
2 2
which pair of tangents QA and QB are drawn to circle x  y  4.
2 2
73. The locus of point of concurrency of the chord of contact AB of the circle x  y  4 is :
2 2 2
(A) y  2 x  0 (B) y  x  4
2 2 2
(C) y  2 x  0 (D) y  2 x  4
74. The points from which perpendicular tangents can be drawn both to the given circle and the
parabola is :
(A)  4,  3  (B)  1, 2 
(C)   2,  2  (D)  2, 2 
75. The locus of circumcentre of AQB if P   8,8  is :

(A) x  2 y  4  0 (B) x  2 y  4  0
(C) x  2 y  4  0 (D) x  2 y  4  0
Page No. 18
FIITJEE TALENT REWARD EXAM - 2023

for Students presently in Class XI (Paper 2)
ANSWER KEY (SAMPLE PAPER)
1. C 2. C 3. B 4. B
5. D 6. A 7. D 8. D
9. A 10. B 11. D 12. D
13. C 14. C 15. B 16. C
17. C 18. C 19. A 20. A
21. C 22. B 23. B 24. A
25. B 26. A 27. B 28. B
29. A 30. B 31. D 32. C
33. D 34. D 35. B 36. B
37. B 38. B 39. D 40. B
41. C 42. D 43. C 44. B
45. B 46. C 47. A 48. C
49. A 50. B 51. D 52. A
53. B 54. B 55. C 56. C
57. D 58. B 59. B 60. B
61. C 62. B 63. B 64. B
65. C 66. B 67. B 68. C
69. B 70. A 71. B 72. C
73. C 74. D 75. A
Page No. 19

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FIITJEE TALENT REWARD EXAM - 2023

for Students presently in Class XI (Paper 2)

1. You are advised to devote 30 Minutes on Section-I, 30 Minutes on Section-II and

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Recommended Time: 30 Minutes for Section – I

1. A plate of mass m is placed on a frictionless surface. The plate is connected m

6. The stereochemical relationship between the following molecules is

7. The increasing order of acid strength of the following acid is

8. The maximum orbital angular momentum of an electron with n = 5 is

9. 10 mL of NaHC2O4 is oxidised by 10 mL of 0.02 M MnO4 in basic medium. Hence, 10mL of

11. The product of n positive numbers is unity. Then their sum is

15. The differential coefficient of f(loge x), where f(x)  loge x is

Recommended Time: 30 Minutes for Section – II

19. A small particle of mass m is released from rest in the position l

20. In the adjoining figure block A is of mass m and block B is

22. The equilibrium constant for a reaction

23. Two solid compounds X and Y dissociates at a certain temperature as follows

26. Value of the expression 2sinx – cos2x is always

28. If x + y = k is normal to parabola y2 = 12x. Find k?

29. Differentiation of sin 2x w.r.t. x is

Recommended Time: 120 Minutes for Section – III

(A) 2 gh (B) 3gh

(C) C (D) Information is insufficient

(Comprehension for Q. No. 40 to 42)

40. The elongation of the string before applying force is

41. The greatest elongation of the string is

42. The maximum displacement of point A after applying F is

(Comprehension for Q. No. 43 to 45)

43. Angle of projection at point A

44. Speed of projection at point A

45. Range of projectile

47. Which of the following is least stable?

Space for Rough Work

48. AB4  C2  C3  A 2

Space for Rough Work

(Comprehension for Q. No. 55 to 57)

55. The correct combinations of quantum numbers for a 5g orbital is

(Comprehension for Q. No. 58 to 60)

58. The partial pressure of which of the above gases is maximum?

62. Value of 3 cos ec20º  sec 20º is ?

64. 13  33  53  73  ....  993 equals

log3 x 2  log3 x 2 10 1

(Comprehension for Q. No. 70 to 72)

(Comprehension for Q. No. 73 to 75)

75. The locus of circumcentre of AQB if P   8,8  is :

FIITJEE TALENT REWARD EXAM - 2023

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