XI IIT IC FTM-04 24-07-2023 Key Sol

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Sec: XI_STU_IC_IIT Date:24-07-2023

Time: 3 Hrs. FTM – 04 Max.Marks:300


JEE MAIN 2022 Model
KEY SHEET
PHYSICS
1 2 3 4 5 6 7 8 9 10
B D D B C C A B A C
11 12 13 14 15 16 17 18 19 20
D A B A C A B A D B
21 22 23 24 25 26 27 28 29 30
1560 4 120 20 15 9 15 360 45 1000

CHEMISTRY
31 32 33 34 35 36 37 38 39 40
C A B B D B C A C D
41 42 43 44 45 46 47 48 49 50
C C C C D D C B B A
51 52 53 54 55 56 57 58 59 60
36 3 125 3 2 1 2 5 4 1

MATHEMATICS
61 62 63 64 65 66 67 68 69 70
B A D A A D A D D B
71 72 73 74 75 76 77 78 79 80
A D A A A C A A A A
81 82 83 84 85 86 87 88 89 90
1 0 2 7 2 8 0 4 2 4
XI_IIT_IC_FTM–4_24-07-2023
Hints and Solutions
1. (B) 3. (D)

Equation of trajectory is

y   x   x2 ________(i)

Comparing this with


2
g x 
y  x tan     , we get
2  V0 cos  
 Hy
tan   
H
tan 60o 
1000   tan 1 

H  1000 tan 60o y will be maximum, when


dy
 0 and
dx
2
g x  d2y
y  x tan     0.
2  V0 cos   dx 2
2
  y   x   x2
9.8  1000 
 1000 tan 60o   
2  400  1  dy
 2      2x _______(ii)
dx
 H  4.9  25
dy
 Hy When 0
dx
 4.9  25   2 x  0
 122.5 m 
x
2
2. (D)

In projectile motion the horizontal component From equation (i)

of velocity remains constant. d2y


 2 
dx 2

 dy d2y
When x  ,  0 and 0
2  dx dx 2


Therefore y will be maximum when x 
2
v cos   u cos 
2
     
u cos  ymax     
v  2   2 
cos 

2
XI_IIT_IC_FTM–4_24-07-2023
    u  350 m/s
ymax      
2  2  6. (C)

  O  At school
H .
2 2
From the graph it is clear that
2 xB  x A

4

  tan 1 

2
H
4

4. (B)

Here, 1   2  900

V02 sin 21 V02 sin 2 2 B lives closes to the school [(B) is correct]
R 
g g
A takes lesser time to reach home [(C) is
2 2
V sin 1
0 correct]
h1 
2g
Position-time graph slope represents velocity.
V02 sin 2  2
h2  Slope of line A > Slope of line B
2g
Velocity of A > Velocity of B
2

R 0
2
V sin 21 V
 0  2sin 1 cos 1 
A travels faster than B. [(D) is correct]
g g
7. (A)
 V 2 sin 2 1  V02 cos 2 1 
R2  4  0  
g g Galileo observed that for a freely falling
  
objective near earth’s surface (neglecting air
 V sin 1  V0 cos  90   2  
2 2
2 2 0
0 resistance)
 4  
 g   g 
(i) the change in velocity per unit distance

V02 sin 2  2 decreases with increase in distance of fall, and


 4  2h1 
g (ii) the change in velocity per unit time does

 4  2h1  2h2  not change with increase in time

8. (B)
R 2  16h1h2 g  girl
e  escalator
5. (C) E  Earth
2  0.1   length of escalator
50  ut  u t1  90 s
9.8

2
XI_IIT_IC_FTM–4_24-07-2023
2
t 2  60 s g x 
y  x tan     , we get
2  V0 cos  

tan   3

  60o

V02 cos 2 60o  1

When the escalator is stationary and the girl is V02  22


moving
 
t1   Vge  ........(i) V0  2 m / s
Vge t1
Vge  velocity of girl with respect to 11. (D)
escalator
When the escalator is moving and the girl is tOB
tOA  t AB 
stationary with respect to escalator 2
 
t2   VeE  .......(ii) 12. (A)
VeE t2
VeE  velocity of escalator with respect to
Earth
The time taken by the girl to walk up the
moving escalator is
 
t  VgE  .......(iii)
VgE t
VgE  velocity of girl with respect to Earth
Motion of A relative to B along line AB
We have vAB  v A  vB
VgE  Vge  VeE
 v    v cos 60o 
  
  v
t t1 t2 v
2
tt 3v
t 12 
t2  t1 2
90  60 Relative distance
t Time, t 
60  90 Relative speed
3  60 a
 = 36 s 
5 3v
9. (A) 2
2a
For the given situation, the trajectory of the 
3v
bomb is a parabola. Path length covered by each particle
 vt
10. (C) 2a

g 2 3
y  3x  x
2

Comparing this with


3
XI_IIT_IC_FTM–4_24-07-2023
0
13. (B)  u cos 60

D  maximum distance from the inclined u



plane 2

H  maximum height above the inclined 15. (C)

plane

D
cos   
H VA  20 km/h along west
D 
H VB  20 km/h along north
cos 
  
u 2 sin 2  VBA  VB  VA
D
2 g cos   2 2
VBA   20   20  2  20  20  cos900
u 2 sin 2 
H
2 g cos2   20 2 km/h
14. (A)

Displacement
Vav 
Time

Here,   90 o  30 o = 60o

A is at rest and B is moving with 20 2 km/h


along north-east.
Smin
R sin 45o 
Vav  AB
T
1
u 2 sin 2 g S min  10 km 
  2
g 2u sin 

1  5 2 km
 u  2sin  cos  
2sin  The closest distance between A and B is 5 2
 u cos  km.

4
XI_IIT_IC_FTM–4_24-07-2023
16. (A)
 
VAB  VBA
 
VAB  VBA  0

17. (B)
  
aAB  a A  aB x  78  t
 
 gg 2 1960
x  78 
9.8
=0
  78  20
VAB  constant
 1560 m
Path of A observed by B is a straight line.
22. (4)
18. (A)
y – motion of projectile
For maximum range on the inclined plane
a   g sin 
o o
90  40
 V 0
2

= 25o

19. (D)

t  t2  t1

 30 o C

t  t2  t1

  0.5  0.5 oC
V  V0  at
 1 oC
0  V0  g sin  t
o o
Temperature difference = 30 C  1 C
V0
t
20. (B) g sin 

In presence of air resistance 20


 =4s
1
Time of ascent < Time of descent 10 
2
21. (1560)
23. (120)

V
aav 
t
5
XI_IIT_IC_FTM–4_24-07-2023
V2  V1

t2  t1


 
V C  5 m/s  ˆj

V BC  10 2 m/s iˆ 
  
V B  V BC  V C
 
 10 2 iˆ  5 ˆj m/s
2

V1   2 g  9.8
VB  10 2  2
  5  m/s
 15 m/s
V22 26. (9)
5
2g

V2  2 g  5

aav 

2 g  5   2 g  9.8 
0.2

100  196

0.2

10  14 0.3n  4.5  t

0.2
2  0.2n
2
0.3n  4.5 
 120 m/s g

24. (20) 0.3n  0.3n 2  0.2n



4.5  4.5 10
Here 1  35o and  2  55o
n9
1   2  90o
27. (15)
Therefore, R2  R1 = 20 m
u  14.7 m/s
25. (15)   30 o
C  Car
  30o
B  Bus
E  Earth

6
XI_IIT_IC_FTM–4_24-07-2023
 15   25

= 40 m/s

B is moving with respect to A with a speed of


40 m/s.

Length of train B = 40 × 9 m
AC  u cos      t AB
= 360 m
2u sin 
 u cos      29. (45)
g cos 
If we take vertically upward direction as
positive, then
2u 2 sin  cos    
 . VA  15 m/s
g cos2 
VB  30 m/s
2 14.7 14.7 1 1 4 aBA  aB  a A
   
9.8 2 2 3  g   g 
2 14.7  4.9 0
 VBA  constant
9.8
VBA  t   VBA  t  0 
= 14.7 m
 VB  t  0   VA  t  0 
= 15 m  30  15
  45 m/s
28. (360) Required speed = 45 m/s
VA  90 km/h 30. (1000)
Va  velocity of jet airplane relative to earth
5
 90  m/s V pa  velocity of products of combustion
18
relative to jet airplane
= 25 m/s V p  velocity of products of combustion
relative to earth
VB  54 km/h If we take positive direction along the
direction of motion of jet airplane, then
5 Va  500 km/h
 54  km/h
18 V pa  1500 km/h
= 15 m/s V p  V pa  Va
 1500  500
 1000 km/h
The speed of products of combustion relative
to earth is 1000 km/h
Answer (1000)

Motion of B with respect to A

VBA  VB  VA

7
XI_IIT_IC_FTM–4_24-07-2023
31. (C) 35. (D)
13.6 Conceptual
For a hydrogen atom, E  eV
n2
for first energy level, 36. (B)
13.6 hc
E1  eV  13.6 eV E  hv  , Given: v  8  1015 s 1
12 
for second energy level, c
thus   c  3  108 m / s
13.6 v
E2  eV  3.4 eV
22 3 108
Difference, E2- E1 = -3.4-( -13.6) = 10.19 eV  m  37.5nm
8 1015
for second energy level,
Closest value is 40nm
13.6
E2  eV  3.4 eV
22 37. (C)
for third energy level, The energy (in eV/atom) of electron in a
13.6 hydrogen atom in first, second, third, fourth
E3  eV  1.51eV
32 & fifth energy level are -13.6, -3.4, -1.51,
The difference E3 – E2 = -1.51 eV – (-3.4eV) -0.85 & -0.544 respectively. Hence, Energy
= 1.89 eV of a possible excited state of hydrogen is
10.19 27 -3.4 eV.
Ratio = 
1.89 5
32. (A) 38. (A)
hc hc
w  hv 0    330nm  330  109 m  E2  E1
0 0 
6.62 1034  3 108 hc 1 1 
w  6.0 1019 J . E  2.178 1018  Z 2  2  2   Z  1
330 109  1 2 
33. (B) 6.62 1034  3 108 4
0    1.214 107 m
e/m for neutron  0 2.17 10 18 3
1 39. (C)
2 Case I Case II
e/m for alpha particle   0.5
4 hc 3hc
   1eV    4eV  II
1  
e/m for proton   1
1  hc  3hc
3     1eV   3  3eV  I
1   
e/m for electron   1850
 1  n
from I & II eq , we get,   0.5eV .
 
 1850 
increasing order for the value of e/m is n, , 40. (D)
p, e. Case I Case II
4 E 3E E
34. (B) E  2 E  E  E E   
3 3 3
In 1st case , K .E  hv1  hv0  h(v1  v0 )
hc E hc
E 
In 2nd case, K .E  hv2  hv0  h(v2  v0 )  3 3
Given:- 3  is the answer.
h(v1  v0 ) 1
 41. (C)
h(v2  v0 ) k
Bond dissociation energy of I2 molecule is
v2  v0  k (v1  v0 )  kv1  kv0
246.5KJ/mol. Convert it into eV/atom or
kv  v bond.
v0  1 2
k 1 1 eV/atom= 96.5kJ/mol
246.5
 2.5 eV
96.5
8
XI_IIT_IC_FTM–4_24-07-2023
0
4000 A →we can write it into 400 nm. 49. (B)
E    1240 mass 100
Volume  
 in eV   in nm  density 1.4
1240  71.428ml , mass%  63%
E (eV )   3.1eV
400 Given wt. 1000
Remaining E  3  2.5  0.5eV Molarity =
M .wt  volume(ml )
0.5
 100  17% 63  1000
3.1 =  14 M
63  71.428
50. (A)
42. (C)
Conceptual N 2  3H 2  2 NH 3
1 mol N 2 requires 3 moles H2 for the
43. (C) formation of 2 moles NH 3 . N 2 & H 2 should
Conceptual
be in ratio 1:3.
56g of N 2 means 2 moles of N 2 & 10g of
44. (C)
1 2 H 2 means. 5 moles of H 2 . H 2 act as
K .E  mv I
2 limiting Reagent.
nh
mvr  51. (36)
2 Final gaseous mixture contains 1 mol CO
n2 h2 and 1 mol CO2 after reaction
(mv) 2 
4 2 r 2 1 28  1 44
Mavg   36 g / mole
1 n2 h2 11
mv 2   II
m 4 2 r 2 52. (3)
Put II in I
3.30 x 74.5g kcl present with 1000g water.
1 1 n2 h2 Mass of solution = 1245.85g; volume of
K .E    2 2
2 m 4 r solution = 1032.8
2
Now, n0  2, r1  a0 , r2  a0  (2)  4a0 3.3
Molarity   1000  3.17
1038.2
1 22 h 2 h2
K .E   2 
2 4 (4a0 ) 2 m 32 2 a02 m 53. (125)
45. (D) Molarity of 1st HNO3 solution= 0.5M
Conceptual. Molarity of 2nd HNO3 solution

46. (D) 9.45  10


=  1.5 M
Conceptual. 63
M 1V1  M 2V2  M f V f
47. (C) 0.5 X 250 + 1.5 X 750 = M f  1000
v Z x2
vn  1  x M f  1.25M
n 2

48. (B) 54. (3)


Using average molar mass, n2
rn  0.529   2.116
35( x ) + 37(1- x ) = 35.5 Z
x =0.75 n=2
1 - x =0.25 13.6 z 2 13.6 12
0.75 En    3.4 eV
 3 :1 n2 22
0.25 K.E= -En =+3.4 eV.

9
XI_IIT_IC_FTM–4_24-07-2023
55. (2) 6.63  1019
1  2  1015 
2.188 106  6.63  1034
x 2  1.50
  1 1015 s 1 .
y 2.188 106  2
6 61. (B)
56. (1)
Excitation energy x 2  bx  1  0 
 have a common root.
1 1 x2  x  b  0 
= 13.6 12  2  2   10.2 2
1 n   1  b    b2  1 1  b 
1
 0.25  n  2  b2  2b  1  b2  b3  1  b
n2
no of waves = n(n+1)/2  b3  3b  0
=1 2/2 = 1  b  b 2  3  0
 b  0,  3 i
57. (2)
 hc  62. (A)
E  n 
  2 2  10
1000  6.626  10 34  3  108 
 n 
10  400  10 9  63. (D)
20
n = 2.01  10 | x  2 | 5| x  2 | 3  0
|x – 2| = 5, |x – 2| + 3  0
58. (5) x  5  2  x  7,  3
Max. K.E of ejected e’s
c  64. (A)
= hv  hv0  h   v0 
  Since 4 is a root of equation x 2  px  12  0
1  p  7
 9 1031  v 2
2 Now, x 2  px  q  0
 3  108 
 6.63  10 34  9
 4.3  1014   x2  7 x  q  0
 500  10  Given D  0  49  4q  0
v  5  105 ms 1 49
q
4
59. (4)
65. (A)
hc 6.6 10 34  3 108 1  sin x  1
E  J
 300 109
6.6 1034  3108 66. (D)
E  (ineV )   4.125 eV (x – 2)2 = sin y – 1  x = 2, sin y = 1
300 109 1.6 1019
For photoelectric effect to occur, the energy  y = /2
of photon must be greater than the work
function of the metal so, the number of
67. (A)
metals showing photoelectric effects will be
i.e Li, Na, K, Mg. 1 1 1 
an    
n  n  1  n n  1 
60. (1)  1 1 1 1 1 1 1 
a1  a2  a3  ...  an  1       ...   
K .E  h(v  v0 )  2 2 3 3 4 n n 1 
KE  1  n
v0  v   1  
h  n 1 n 1

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XI_IIT_IC_FTM–4_24-07-2023
68. (D)
 3 74. (A)
x  n  tan 1   , n  N
 10 
69. (D)

70. (B) 75. (A)



tan 3x = 1 = tan  3x  n
 c a  b
4 4 x = 1 satisfies, .1 
a b  c
n 
 x 
3 12
76. (C)
71. (A)
   a  b,   ab – c  ab    c
Given, 2sin 2   5sin   2  0
  2sin   1 sin   2  0 77. (A)
[where,      a ,   b;      a,   b
 sin   2   0,    R ]
78. (A)
a10  2a 8  a     2     
10 10 8 8


2a 9 2   9  9 
 8   2  2   8  2  2 
=
2   9  9 
1
  2sin   1  0  sin   8  6   8  6  6   9  9 
2 =  3
It is clear from the figure, 2   9  9  2   9  9 
    5  79. (A)
   0,    , 2 
 6  6  a b c
    (say)  a  b  c 9
72. (D) 1 3 5
 1 1 
y  sin x  cos x  2  sin x  cos x  80. (A)
 2 2    116  0 Roots are imaginary and
  conjugate to each other. Both roots are
 2 sin  x   common
 4
a 2b 3c
  
  2  y 2 3 8 15
a  3, b  4, c  5
 Range of y is   2, 2  ABC is right angle triangle c 2  a 2  b 2
73. (A)
81. (1)
We have. 2  a b  0 and 2  b a  0
sin x  sin y  2
  a – b    b – a   0   1
 sin x  1 and sin y  1
 
 x and y   x  y  
2 2

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XI_IIT_IC_FTM–4_24-07-2023
82. (0) 88. (4)
ax 2  bx  c  0
1  n
 ax n 1  bx n  cx n –1  0 sin x   sin x  sin  x  n   1
2 6 6
a  n 1  b  n  c  n –1  0
a  n 1  b  n  c  n –1  0 For 2  x  2
Adding above equations
 aSn 1  bSn  cSn –1  0  5 7 11
x , , ,
6 6 6 6
83. (2)  Number of points of intersection of two
x 2  2 | x | 3  0
given curves  4
 | x |2 2 | x | 3  0 ( |x|2 = x2) 89. (2)
 (| x | 3)(| x | 1)  0
Let y  x  1  cos x
 |x| = 3 ( |x| + 1  1)
 x  3 It is clear from the graph that two curves
interest at two points.
So there are two real solutions.

84. (7)
1 2 n  n  1 1 n  n  1 2n  1
n  5  n 
2

5 6
  2n  1  15  n7

85. (2)
Hence, number of solutions is 2.

90. (4)
 3cos x  2 cos x  1  0
2
cos x  or cos x  1
86. (8) 3
Using AM  GM , Total number of solution is 4.
a 5  a 4  a 3  a 3  a 3  1  a 8  a10
8
1
  a 5  a 4  a 3  a 3  a 3  1 a8  a10  8
 a5  a 4  3a3  1  a8  a10  8 1

87. (0)
We have,
 2 3
y  5x 2  2 x  3  5  x 2  x  
 5 5
2 2
 1 3 1   1  14
 5  x       5  x     2
 5  5 25   5 5
since y  2sin x  2, so there cannot be any
point of intersection.

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