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XI IIT IC FTM-04 24-07-2023 Key Sol
XI IIT IC FTM-04 24-07-2023 Key Sol
XI IIT IC FTM-04 24-07-2023 Key Sol
CHEMISTRY
31 32 33 34 35 36 37 38 39 40
C A B B D B C A C D
41 42 43 44 45 46 47 48 49 50
C C C C D D C B B A
51 52 53 54 55 56 57 58 59 60
36 3 125 3 2 1 2 5 4 1
MATHEMATICS
61 62 63 64 65 66 67 68 69 70
B A D A A D A D D B
71 72 73 74 75 76 77 78 79 80
A D A A A C A A A A
81 82 83 84 85 86 87 88 89 90
1 0 2 7 2 8 0 4 2 4
XI_IIT_IC_FTM–4_24-07-2023
Hints and Solutions
1. (B) 3. (D)
Equation of trajectory is
y x x2 ________(i)
dy d2y
When x , 0 and 0
2 dx dx 2
Therefore y will be maximum when x
2
v cos u cos
2
u cos ymax
v 2 2
cos
2
XI_IIT_IC_FTM–4_24-07-2023
u 350 m/s
ymax
2 2 6. (C)
O At school
H .
2 2
From the graph it is clear that
2 xB x A
4
tan 1
2
H
4
4. (B)
Here, 1 2 900
V02 sin 21 V02 sin 2 2 B lives closes to the school [(B) is correct]
R
g g
A takes lesser time to reach home [(C) is
2 2
V sin 1
0 correct]
h1
2g
Position-time graph slope represents velocity.
V02 sin 2 2
h2 Slope of line A > Slope of line B
2g
Velocity of A > Velocity of B
2
R 0
2
V sin 21 V
0 2sin 1 cos 1
A travels faster than B. [(D) is correct]
g g
7. (A)
V 2 sin 2 1 V02 cos 2 1
R2 4 0
g g Galileo observed that for a freely falling
objective near earth’s surface (neglecting air
V sin 1 V0 cos 90 2
2 2
2 2 0
0 resistance)
4
g g
(i) the change in velocity per unit distance
8. (B)
R 2 16h1h2 g girl
e escalator
5. (C) E Earth
2 0.1 length of escalator
50 ut u t1 90 s
9.8
2
XI_IIT_IC_FTM–4_24-07-2023
2
t 2 60 s g x
y x tan , we get
2 V0 cos
tan 3
60o
plane
D
cos
H VA 20 km/h along west
D
H VB 20 km/h along north
cos
u 2 sin 2 VBA VB VA
D
2 g cos 2 2
VBA 20 20 2 20 20 cos900
u 2 sin 2
H
2 g cos2 20 2 km/h
14. (A)
Displacement
Vav
Time
Here, 90 o 30 o = 60o
1 5 2 km
u 2sin cos
2sin The closest distance between A and B is 5 2
u cos km.
4
XI_IIT_IC_FTM–4_24-07-2023
16. (A)
VAB VBA
VAB VBA 0
17. (B)
aAB a A aB x 78 t
gg 2 1960
x 78
9.8
=0
78 20
VAB constant
1560 m
Path of A observed by B is a straight line.
22. (4)
18. (A)
y – motion of projectile
For maximum range on the inclined plane
a g sin
o o
90 40
V 0
2
= 25o
19. (D)
t t2 t1
30 o C
t t2 t1
0.5 0.5 oC
V V0 at
1 oC
0 V0 g sin t
o o
Temperature difference = 30 C 1 C
V0
t
20. (B) g sin
V
aav
t
5
XI_IIT_IC_FTM–4_24-07-2023
V2 V1
t2 t1
V C 5 m/s ˆj
V BC 10 2 m/s iˆ
V B V BC V C
10 2 iˆ 5 ˆj m/s
2
V1 2 g 9.8
VB 10 2 2
5 m/s
15 m/s
V22 26. (9)
5
2g
V2 2 g 5
aav
2 g 5 2 g 9.8
0.2
100 196
0.2
10 14 0.3n 4.5 t
0.2
2 0.2n
2
0.3n 4.5
120 m/s g
6
XI_IIT_IC_FTM–4_24-07-2023
15 25
= 40 m/s
Length of train B = 40 × 9 m
AC u cos t AB
= 360 m
2u sin
u cos 29. (45)
g cos
If we take vertically upward direction as
positive, then
2u 2 sin cos
. VA 15 m/s
g cos2
VB 30 m/s
2 14.7 14.7 1 1 4 aBA aB a A
9.8 2 2 3 g g
2 14.7 4.9 0
VBA constant
9.8
VBA t VBA t 0
= 14.7 m
VB t 0 VA t 0
= 15 m 30 15
45 m/s
28. (360) Required speed = 45 m/s
VA 90 km/h 30. (1000)
Va velocity of jet airplane relative to earth
5
90 m/s V pa velocity of products of combustion
18
relative to jet airplane
= 25 m/s V p velocity of products of combustion
relative to earth
VB 54 km/h If we take positive direction along the
direction of motion of jet airplane, then
5 Va 500 km/h
54 km/h
18 V pa 1500 km/h
= 15 m/s V p V pa Va
1500 500
1000 km/h
The speed of products of combustion relative
to earth is 1000 km/h
Answer (1000)
VBA VB VA
7
XI_IIT_IC_FTM–4_24-07-2023
31. (C) 35. (D)
13.6 Conceptual
For a hydrogen atom, E eV
n2
for first energy level, 36. (B)
13.6 hc
E1 eV 13.6 eV E hv , Given: v 8 1015 s 1
12
for second energy level, c
thus c 3 108 m / s
13.6 v
E2 eV 3.4 eV
22 3 108
Difference, E2- E1 = -3.4-( -13.6) = 10.19 eV m 37.5nm
8 1015
for second energy level,
Closest value is 40nm
13.6
E2 eV 3.4 eV
22 37. (C)
for third energy level, The energy (in eV/atom) of electron in a
13.6 hydrogen atom in first, second, third, fourth
E3 eV 1.51eV
32 & fifth energy level are -13.6, -3.4, -1.51,
The difference E3 – E2 = -1.51 eV – (-3.4eV) -0.85 & -0.544 respectively. Hence, Energy
= 1.89 eV of a possible excited state of hydrogen is
10.19 27 -3.4 eV.
Ratio =
1.89 5
32. (A) 38. (A)
hc hc
w hv 0 330nm 330 109 m E2 E1
0 0
6.62 1034 3 108 hc 1 1
w 6.0 1019 J . E 2.178 1018 Z 2 2 2 Z 1
330 109 1 2
33. (B) 6.62 1034 3 108 4
0 1.214 107 m
e/m for neutron 0 2.17 10 18 3
1 39. (C)
2 Case I Case II
e/m for alpha particle 0.5
4 hc 3hc
1eV 4eV II
1
e/m for proton 1
1 hc 3hc
3 1eV 3 3eV I
1
e/m for electron 1850
1 n
from I & II eq , we get, 0.5eV .
1850
increasing order for the value of e/m is n, , 40. (D)
p, e. Case I Case II
4 E 3E E
34. (B) E 2 E E E E
3 3 3
In 1st case , K .E hv1 hv0 h(v1 v0 )
hc E hc
E
In 2nd case, K .E hv2 hv0 h(v2 v0 ) 3 3
Given:- 3 is the answer.
h(v1 v0 ) 1
41. (C)
h(v2 v0 ) k
Bond dissociation energy of I2 molecule is
v2 v0 k (v1 v0 ) kv1 kv0
246.5KJ/mol. Convert it into eV/atom or
kv v bond.
v0 1 2
k 1 1 eV/atom= 96.5kJ/mol
246.5
2.5 eV
96.5
8
XI_IIT_IC_FTM–4_24-07-2023
0
4000 A →we can write it into 400 nm. 49. (B)
E 1240 mass 100
Volume
in eV in nm density 1.4
1240 71.428ml , mass% 63%
E (eV ) 3.1eV
400 Given wt. 1000
Remaining E 3 2.5 0.5eV Molarity =
M .wt volume(ml )
0.5
100 17% 63 1000
3.1 = 14 M
63 71.428
50. (A)
42. (C)
Conceptual N 2 3H 2 2 NH 3
1 mol N 2 requires 3 moles H2 for the
43. (C) formation of 2 moles NH 3 . N 2 & H 2 should
Conceptual
be in ratio 1:3.
56g of N 2 means 2 moles of N 2 & 10g of
44. (C)
1 2 H 2 means. 5 moles of H 2 . H 2 act as
K .E mv I
2 limiting Reagent.
nh
mvr 51. (36)
2 Final gaseous mixture contains 1 mol CO
n2 h2 and 1 mol CO2 after reaction
(mv) 2
4 2 r 2 1 28 1 44
Mavg 36 g / mole
1 n2 h2 11
mv 2 II
m 4 2 r 2 52. (3)
Put II in I
3.30 x 74.5g kcl present with 1000g water.
1 1 n2 h2 Mass of solution = 1245.85g; volume of
K .E 2 2
2 m 4 r solution = 1032.8
2
Now, n0 2, r1 a0 , r2 a0 (2) 4a0 3.3
Molarity 1000 3.17
1038.2
1 22 h 2 h2
K .E 2
2 4 (4a0 ) 2 m 32 2 a02 m 53. (125)
45. (D) Molarity of 1st HNO3 solution= 0.5M
Conceptual. Molarity of 2nd HNO3 solution
9
XI_IIT_IC_FTM–4_24-07-2023
55. (2) 6.63 1019
1 2 1015
2.188 106 6.63 1034
x 2 1.50
1 1015 s 1 .
y 2.188 106 2
6 61. (B)
56. (1)
Excitation energy x 2 bx 1 0
have a common root.
1 1 x2 x b 0
= 13.6 12 2 2 10.2 2
1 n 1 b b2 1 1 b
1
0.25 n 2 b2 2b 1 b2 b3 1 b
n2
no of waves = n(n+1)/2 b3 3b 0
=1 2/2 = 1 b b 2 3 0
b 0, 3 i
57. (2)
hc 62. (A)
E n
2 2 10
1000 6.626 10 34 3 108
n
10 400 10 9 63. (D)
20
n = 2.01 10 | x 2 | 5| x 2 | 3 0
|x – 2| = 5, |x – 2| + 3 0
58. (5) x 5 2 x 7, 3
Max. K.E of ejected e’s
c 64. (A)
= hv hv0 h v0
Since 4 is a root of equation x 2 px 12 0
1 p 7
9 1031 v 2
2 Now, x 2 px q 0
3 108
6.63 10 34 9
4.3 1014 x2 7 x q 0
500 10 Given D 0 49 4q 0
v 5 105 ms 1 49
q
4
59. (4)
65. (A)
hc 6.6 10 34 3 108 1 sin x 1
E J
300 109
6.6 1034 3108 66. (D)
E (ineV ) 4.125 eV (x – 2)2 = sin y – 1 x = 2, sin y = 1
300 109 1.6 1019
For photoelectric effect to occur, the energy y = /2
of photon must be greater than the work
function of the metal so, the number of
67. (A)
metals showing photoelectric effects will be
i.e Li, Na, K, Mg. 1 1 1
an
n n 1 n n 1
60. (1) 1 1 1 1 1 1 1
a1 a2 a3 ... an 1 ...
K .E h(v v0 ) 2 2 3 3 4 n n 1
KE 1 n
v0 v 1
h n 1 n 1
10
XI_IIT_IC_FTM–4_24-07-2023
68. (D)
3 74. (A)
x n tan 1 , n N
10
69. (D)
2a 9 2 9 9
8 2 2 8 2 2
=
2 9 9
1
2sin 1 0 sin 8 6 8 6 6 9 9
2 = 3
It is clear from the figure, 2 9 9 2 9 9
5 79. (A)
0, , 2
6 6 a b c
(say) a b c 9
72. (D) 1 3 5
1 1
y sin x cos x 2 sin x cos x 80. (A)
2 2 116 0 Roots are imaginary and
conjugate to each other. Both roots are
2 sin x common
4
a 2b 3c
2 y 2 3 8 15
a 3, b 4, c 5
Range of y is 2, 2 ABC is right angle triangle c 2 a 2 b 2
73. (A)
81. (1)
We have. 2 a b 0 and 2 b a 0
sin x sin y 2
a – b b – a 0 1
sin x 1 and sin y 1
x and y x y
2 2
11
XI_IIT_IC_FTM–4_24-07-2023
82. (0) 88. (4)
ax 2 bx c 0
1 n
ax n 1 bx n cx n –1 0 sin x sin x sin x n 1
2 6 6
a n 1 b n c n –1 0
a n 1 b n c n –1 0 For 2 x 2
Adding above equations
aSn 1 bSn cSn –1 0 5 7 11
x , , ,
6 6 6 6
83. (2) Number of points of intersection of two
x 2 2 | x | 3 0
given curves 4
| x |2 2 | x | 3 0 ( |x|2 = x2) 89. (2)
(| x | 3)(| x | 1) 0
Let y x 1 cos x
|x| = 3 ( |x| + 1 1)
x 3 It is clear from the graph that two curves
interest at two points.
So there are two real solutions.
84. (7)
1 2 n n 1 1 n n 1 2n 1
n 5 n
2
5 6
2n 1 15 n7
85. (2)
Hence, number of solutions is 2.
90. (4)
3cos x 2 cos x 1 0
2
cos x or cos x 1
86. (8) 3
Using AM GM , Total number of solution is 4.
a 5 a 4 a 3 a 3 a 3 1 a 8 a10
8
1
a 5 a 4 a 3 a 3 a 3 1 a8 a10 8
a5 a 4 3a3 1 a8 a10 8 1
87. (0)
We have,
2 3
y 5x 2 2 x 3 5 x 2 x
5 5
2 2
1 3 1 1 14
5 x 5 x 2
5 5 25 5 5
since y 2sin x 2, so there cannot be any
point of intersection.
12