THE CASE

HOUCHHGN WATSON MODELS OF

OF EOUILIBRIUM ADBOR PTION.

O UNiMOLECULAR RREVERaIB E PEACTUON

A- B
A+S KA AS
k
As B.S a t linmtn9
B.9 BIS

-Ya =ky A

kAPA
14 kaCa t kg Po,
-Ta-kkaP Suhi n )
1+ kaPat kPe
 REACGUON BETNEe N
IRREVER1BE BI MDLECulR

SPECIEB O AME JYPE of SITE

ADSORBED

A+B e+D

A+S AS A deOYphon

B4S BS
(3wfaa
AS+BS
C9+DS YQochion')

cs C+SR, Desonption
DS J

-O
A A PA Ov=
14 ka Pa +ke Pet kee *kP
ke Pe
14 ka t
kp Pn 4kePeA koPb
Sub R in OD
-Ta kekaPa ke Pe
3
REACTUoN BeTWEON
RREVERGIBLE BlMOLUAR
DIFFERENT
TYPES oF SITES
SPECSs AD8De BCD

C+D
A +B
AS
A+S Adsoyptuovm
B S2 BS2
Sunkala
CS,+ D92
-

AS +BS2
CS C+S1 Desorhwew
DS D92

OA
14kA Da4 ke Pe tkrsPp kpb
-NA= kR h Dakes Pa
A eREVERS BE BIMOLE CULAR REACTUON BETWEeN

ADSORBeD Spec18S AND FLUID PHASE MDLECUL

T Callod as Eley -Rideal Meaa m.

A+9 AS
AS A dsovph on

AS
AS +R C + D - 3um6ot
RaduOm

CS CS DesomH on

-Ya kpfA
kAPa
14 ka Po 4 ke Pe

Y kR ka PA Ps

14A PA 4 ke Pe
 D
BeFWEeN ADsoR E
RE vERSBLE REACTONS ON
NO- Op MOlE8
Spie gs C wIT4 KHANNE IN

REACTON
A BC

A 4S AS

AS +S

Be B+S

C9 C AS

n Pg ke
14 4P tke,Pg + ke P
4 ka Pa. +, Petkee
Ta =
ta Pa kgPe ke Pe

YaA k Pa-PaP