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Ics and Semiconductor Fabrication Processes
Ics and Semiconductor Fabrication Processes
Unit 1: IC Fabrication
Resist
Mat 2
Mat 1
Si Wafer
Mask
Resist
Mat 2
Mat 1
Si Wafer
Negative Resists
• Prior to 1985 or so, negative resist was popular. (Do you
know negatives of photo films?)
• Consists of inert polyisoprene rubber and photoactive
agent.
• Exposed resist forms cross linkages between rubber
molecules to enlarge it, making it less soluble.
• Oxygen is to be avoided.
• Exposed resist swells and distorts. Thus, it is not good for
small features.
Lithography 20
Positive Resist
• Consists of a resin and a photoactive compound (PAC) for
UV (i-line and g-line) ~400nm wavelength.
• Photoactive compound is dissolution inhibitor for
development step which does not dissolve unexposed resist.
• Exposure destroys inhibitor (makes inhibiter ineffective).
• Exposure makes exposed resist more soluble in developer.
• Very sensitive (energy-100mJcm-2, 300 to 400nm light).
• No swelling problem and hence better features (dimensions).
• The cross-sections above and most later use positive resist.
21
Lithography
Deep or Extreme UV (EUV 13.5nm wavelength) resists
• Chemically Amplified (CA) Resists are used.
• Very sensitive
• Here photons interact with Photo Acid Generator (PAG) in
the resist creating an acid molecule.
• Acid molecules are catalysts for changing resist properties
as required depending on positive or negative resist. Occurs
during post exposure bake (PEB). Hence PEB is a very
critical step here.
• Acid molecules are regenerated after each chemical reaction
and may participate in further reaction. Hence sensitivity is
excellent.
22
Lithography
Contact Printing
• Mask plate pressed against and directly in contact with resist
as shown in the figure. Here mask features are 1X.
• A thin 0.2mm flexible mask for better contact.
• In practice, up to 0.3μm features are possible in contact
printing.
• The major problem is that mask gathers defects.
13 defects/cm2 after 5 exposures.
37 defects/cm2 after 15 exposures.
24
Lithography
Proximity Printing
• Mask separated in 20 to 50μm range from resist. Mask life
increases. Here also mask features are 1X.
• Image is not very good.
• Minimum feature size achievable is about 2μm. Not so good.
25
Lithography
Projection Printing
• Fancy optics used for focusing. Aberrations must be
controlled in part per million (PPM). Image is focused.
• In practice, up to 0.1μm features are possible in stepper
projection printing when enhancement methods are used.
• Step and repeat projection in the figure is commonly used
in technologies today.
26
Lithography
27
Lithography
28
Lithography
29
Lithography
The positive resist exposed to UV light softens and can be dissolved in a developer to expose mat 2.
30
Lithography
Development
• The positive resist exposed to UV light softens and can be
dissolved in a developer to expose mat 2. Now, mat 2 and
mat 1 in the exposed area can be selectively
etched(removed) to do processing in the masked Silicon.
Exposed resist developed away
Resist
Mat 2
Mat 1
Si Wafer
Mat 2
Mat 1
Si Wafer
• The wet oxidation is much faster (about 10 times) than dry oxidation.
Oxidation 42
• The stability and ease of formation of SiO2 was one of the reasons that
Si replaced Ge as the semiconductor of choice.
• Batch processing of wafers is another benefit which increases
throughput as shown below.
Oxidation 43
(1) While oxidizing, about 50% of Si layer is consumed. Hence the oxide
Si
layer will have higher elevation than original Si and will eventually lead to
non-planar starting surfaces.
Added thickness
Oxide
Si
Si
Oxide Grown
Nitride Nitride
Oxide
Oxidation
Si
Si
Oxide Grown
Nitride Nitride
Oxide
Oxidation
Si
Si
Weff
Thin gate oxide
1000nm PETEOS
50nm Nitride
350nm SABPSG
P+ P+ N+ N+
N-Well P-Well
Oxidation 50
(3) Impurity Segregation: Due to high temperature during oxidation, the
impurities tend to diffuse deeper. The redistribution, however, is affected
by the presence of oxide – Si interface.
The concentration of Boron near the interface is reduced in Si compared to
normal concentration and affects the threshold voltage of MOSFET as it
depends on doping withing small depth below oxide.
Boron
Conc
Oxide
Si
Depth
Boron redistribution due to Segregation
51
Oxidation
The concentration of P and As is increased as shown.
Oxide
P
Conc
Si
Depth
Oxide
Slight lateral
Impurities enter diffusion
here
No impurities
Si Under oxide
61
Diffusion
• Even if this technique is not so much used in the present
implant age, the diffusion is still a part of processing life.
• The post implant anneal makes the implanted impurities
redistribute by diffusion and lateral (sideways) penetration of
dopants becomes worse compared to implant.
Impurity Oxide
profile after Redistribution
penetration. penetration.
Si
P N+ P
n Si n Si
• DIELECTRIC ISOLATION
n+ n+ n+ n+
p-substrate (bulk)
Device Isolation 67
Line of cross-section
Mat-1
Si
71
Process Sequence with Mask
i) Deposit Resist
Line of cross-section
Resist
Mat-1
Si
72
Process Sequence with Mask
ii) Softbake Resist ~ 600c, 1-3 minutes
iii) Exposure – Expose Resist through the mask. Either
the mask or its complement used depending on the effect
desired.
Mask
Resist
Mat-1
Si
73
Process Sequence with Mask
• iv) Hard Bake Resist ~ 800c, 1 - 6 minutes
Resist
Remaining Resist
Mat-1
Si
74
Process Sequence with Mask
Remaining Resist
Mat-1
Si
75
Process Sequence with Mask
• vii) If Boron is implanted, it can be done now with resist
present. If diffusion or oxidation is involved, the resist must
be removed at this stage. Implant Boron.
Boron
Remaining Resist
Mat- 1
P+
Si
76
Process Sequence with Mask
• If selective diffusion or oxidation is involved, the resist must
be removed at this stage.
• In selective oxidation case, material-1 must block oxidation
(material-1 -> Nitride).
• For selective diffusion (material-1-> Oxide).
Remaining Resist
-
Mat 1
P+
Si
77
Process Sequence with Mask
• viii) Remove the resist as selective job is finished
• ix) Wafer ready for the next step. The cross-section after
(viii) will be normally shown.
Mat-1
P+
Si
Thank You