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Kinetic Theory of Matter

Volume
★ The amount of space occupied by a
Diatomic Molecules substance
★ hydrogen, nitrogen, oxygen, uorine, and ★ Is a measure of the amount of space that
chlorine a substance or an object takes up
Noble Gases ★SI unit - cubic meter ( m3) ( cm3 , mL , L , )
★Amount of gas or number of Moles
★helium, neon, argon, krypton, xenon, and mole is a measure for the amount of
argon substance present in the given sample
★SI unit is mole
General properties of Gases ★ number of moles= mass of the gas
Using symbols n= mass
★Most gases exist as molecules usually molar mass
diatomic. Examples of these gases are
oxygen , (O2 ), iodine ( I2 ) Chlorine ( Cl2) Density
and hydrogen ( H2) ★ The density of gases are very small
★ Noble gases such as neon (Ne),argon compared with those solid and liquids.
(Ar) and helium (He) exist as individual ★ Computed by dividing the mass of the
atoms. They are called monatomic gases. gas by its volume.
★Gases have no de nite shape and volume. D= m/v
★Gases are easily compressed when Units ;
pressure is applied. g/L , g/ cc
★Gases expand when heated and contract Temperature
when cooled. u
★ A measure of the average kinetic energy
★Gases exert pressure. of the particles in an object
★The densities of gases are relatively small
compared to the densities of solid and ★Most common temperature scales
liquids. are Fahrenheit ( 0F), Celsius ( 0C), and
★The force of intermolecular attraction Kelvin ( K)
between gas particles is negligible.
★Gases mix evenly and completely when
contained in the same vessel.
Pressure
★Pressure is the force applied perpendicular
to the surface of an object per unit area
over which that force is distributed.
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temperature is inversely proportional to its
pressure.
✦Pressure is inversely proportional to the
volume or PV=k where P is the pressure of
the gas, V is the volume of the gas,
and k is a constant.
✦The relationship for Boyle’s Law can be
expressed as follows: P1V1 = P2V2, where
P1 and V1 are the initial pressure and
volume values, and P2 and V2 are the
values of the pressure and volume of the
gas after change.

✦ Boyle’s law refers to a relation concerning


the compression and expansion of a gas at
constant temperature.
✦ Boyle’s Law holds true only if the number
of molecules (n) and the temperature (T)
are both constant.
✦ Boyle’s Law is used to predict the result of
introducing a change in volume and
pressure only, and only to the initial state of
a xed quantity of gas.
Example:
Boyles Law 1. An ideal gas occupying a 2.0 L ask at
✦Robert Boyle was an Anglo-Irish chemist 760 torr is allowed to expand to a volume
who was able to investigate the of 6,000 mL. Calculate the nal pressure
relationship between pressure and volume in atm.
at constant temperature.
✦When gas is under pressure it takes up
less space
✦The higher the pressure the smaller the
volume
✦Boyle’s Law tells us the relationship
between the volume of a gas and its
pressure at constant temperature
✦Boyle’s Law, states that the volume of a
given mass of gas held at constant
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2. A sample of gas has an initial pressure of
44 atm and an initial volume of 4.01 L. Its
pressure changes to 1.93 atm. What is the
new volume if temperature and amount are
kept constant?

Charles’ Law
★French physicist, performed an experiment
using a balloon, hot water, and cold water
★He found out that various gases expanded
by the same amount when heated through
the same temperature interval.
★He proposed the Charles’ Law which
states that the Kelvin temperature and the
volume of a gas are directly related when
there is no change in pressure.
★States that the volume of a xed mass of
gas is directly proportional to its Kelvin
temperature if the pressure is kept
constant.
Example:
1. A balloon in ated in a room at 24oC has a
volume of 4.00 L. The balloon is then
heated to a temperature of 58oC. What is
the new volume if the pressure remains
constant?

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Biomolecules ★ Examples:
• Sugar cane and sugar beet, table sugar,
★ Any molecules that produced by a living • Manufactured foods, such as cakes,
organisms, including large macromolecules cookies, and dark chocolate, sweet root
such as proteins , carbohydrates , nucleic vegetables such as beetroot and carrots
acids or lipids ★ Three Disaccharides
• Sucrose (C12H12O11), glucose + fructose
1. Carbohydrates -commonly known as table sugar in the
free state throughout the plant kingdom.
★ ■Carbohydrates are the major source of Good sources of sucrose are sugar cane,
energy in our body sugar beets, maple syrup and sorghum.
★These are simple sugar, starch sugar and • Lactose (C12H12O11), glucose +
cellulose.
galactose-or milk sugar is found in nature
★All carbohydrates contain carbon, mainly in the milk of mammals. Human milk
hydrogen and oxygen
contains about 6.7% lactose and cow’s
Classifications of Carbohydrates milk contains about 4.5% of the same.
• Maltose, glucose + glucose-is found
1. Monosaccharides much less commonly in nature than either
★ “mono” means one and saccharides also sucrose or lactose. It is found in sprouting
known as carbohydrates. grains.
★They often called simple sugar that 3. Polysaccharides
cannot be hydrolyzed to simple sugar.
★ Are also called complex carbohydrates
★ Glucose (C6H12O6) is the most and can be hydrolyzed into many
important of the monosaccharides . It is monosaccharide units’, examples,
found in the free state in the plant and vegetables, fruit, nuts, cereal bran.
animal tissue. It is the major carbohydrates
of the body and it is carried by the ★ Most Important Polysaccharides
bloodstream to all parts of the body. It is ‣ Starch
sometimes known as blood sugar • A polymer of glucose.
because it is most abundant carbohydrates • It is found mainly in the seeds, roots and
in the blood found in urine of those who tubes of plants.
have diabetes mellitus (sugar diabetes). • The chief sources of starch are corn,
★ Examples: potatoes, rice, and cassava whose uses
• Honey, dried fruits such as apples, dates are for foods
and sultanas. ‣ Cellulose
• Canned fruits such as pineapple, ‣ like starch, is also a polymer of glucose
strawberry and plum, fresh fruits including • It di ers from starch in a way the cyclic
grapes, apples, pear, kiwi & banana glucose unit are linked together to form
• The most important monosaccharides in chains.
fruits and vegetables are the hexoses, • It is the chief structural components of
glucose and fructose plants and woods.
‣Glycogen
2. Disaccharides • The reserve carbohydrates of the animal
★ Are carbohydrates that yield two kingdom and it is often called animal
monosaccharide molecules upon starch.
hydrolysis • It is formed in the body by polymerization
★The three disaccharides that are of glucose and stored, especially, in the
separately important from the biological liver and muscle tissue.
point of view are sucrose ( table sugar),
lactose (milk sugar), and maltose ( malt
sugar)
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★Possibility of utilization by living
organisms.
Importance of Carbohydrates
★Carbohydrates are the main energy source
for human bodies. Our bodies either use
the energy from carbohydrates
immediately or store the energy for later
use
★Carbohydrates help fuel your brain,
kidneys, heart muscles, and central
nervous system. For instance, ber is a
carbohydrate that aids in digestion, helps
you feel full, and keeps blood cholesterol
levels in check.
★Counting carbohydrates (carbs)is a key
strategy for meeting blood glucose levels.

Lipids
★ Derived from a Greek word “lipos” which
means fat
★ Lipids are diverse organic compound,
Two types of fatty acids
found to be water insoluble (hydrophobic), 1. Saturated fats
but they are found to be soluble in fat
solvent ★Acids are solid at room temperature. They
are mostly found in animals. Lard,
★ Have the “job” of storing energy for later margarine, and butter are examples of
use. saturated fatty acids
★ Lipids are not generally classed as
macromolecules, even though they share 2. Unsaturated fatty
some features of macromolecules ■Lipids ★ acids occur in liquid state at room
are molecules that consist of hydrocarbons temperature.
and bring up the building blocks of the ★■They are found mostly in plants.
composition and function of living cells. Vegetable oil and corn oil are examples of
★Examples of lipids involve fats, oils, unsaturated fatty acids.
waxes, certain vitamins (such as A, D, E ★■ Unsaturated fats are believed to be
and K), hormones and nearly all the cell healthier sources of fats compared to
membrane that is not made up of protein. saturated forms.
★A common lipid is made of 3 fatty acids
chains connected to a glycerol a type of
Classification of Lipids
alcohol. The backbone of fats. 1. Simple Lipids
Characteristics of Lipids as ★Are divided into two classes namely,
Neutral fats and waxes. It contained esters
compound of fatty acids with various alcohols.
★They are insoluble in water. A.Neutral fats / True fats
★Solubility in one or more organic solvents, ★ Esters of fatty acids with glycerol.
such as ether, chloroform, Benzene, Triacylglycerol is an example for Neutral
Acetone which are generally called as fat fats. Oils are fats in the liquid state.
"solvents". B. Waxes
★Some relationship to the fatty acids as
esters either actual or potential. ★ Waxes are esters of fatty acids with higher
mono hydroxy aliphatic alcohols. True
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waxes, cholesterol esters and vitamin A lipoprotein particles that consist of
and D esters are example for waxes. triglycerides.
★Waxes are found almost everywhere. • Triglycerides are fat molecules that make
★Fruits and leaves of many plants have up most of your body fat and the fat found
waxy coatings, that can protect them from in food.
small predators and dehydration. • High triglyceride levels can increase your
★Fur of a few animals and the feathers of risk for heart disease, stroke, and nerve
birds keep same coatings serving as water damage. There is a link between
repellants. chronically elevated triglyceride levels and
★Carnauba wax is known for its water atherosclerosis as well as insulin resistance
resistance and toughness (signi cant for • VLDL-Very-low-density lipoprotein is
car wax). produced in the liver and released into the
2. Complex Lipids bloodstream to supply body tissues with a
type of fat (triglycerides).
★ They are the esters of fatty acids • HDL- High-density lipoproteins “Good
containing groups, other than and in cholesterol”, is stable and carries a “bad
addition, to an alcohol and fatty acids. cholesterol” away from the arteries.
A. Phospholipids • LDL- Low-density lipoproteins “Bad
★In addition to fatty acids and alcohol Cholesterol.
presence, they also contain phosphorous, • Trans fat free, it does not mean it is free of
nitrogenous bases and other substitution trans fats. It means the food has less than
groups. Lecithin and cephalins are 0.5g of trans fat per serving.
examples for phospholipids
B. Glycolipids Nucleic Acids
★Lipids containing carbohydrates are ✦!“PCR” stands for “polymerase chain
referred as glycolipids. They contain a reaction” which is a way of amplifying the
special alcohol moiety called sphingosine nucleic acids in your sample
or sphingoid and nitrogenous base. They ✦!According to the FDA (Food and Drug
do not have phosphorous. Administration), the polymerase chain
★Gangliosides and cerebrosides are reaction converts any virus RNA in your
examples of compounds lipids sample into DNA and “ampli es” it by
making millions of copies of the DNA
C. Sulpholipids which the molecular test can then detect.
★Lipids with sulfate groups are referred as ✦ ◦It is the largest and the most complex.
sulpholipids organic molecules
★Also called sulfatides or cerebroside ✦Friedrich Miescher discovered nucleic
sulfate acids in 1871.
★Present in low levels in kidney , liver , ✦Nucleic Acid was rst discovered in the
lungs , spleen, skeletal muscle and heart nuclei of cells. He called this substance
★its function is not yet established ‘nuclein,” because it seemed to be
D. Lipoproteins speci cally associated with the nucleus.
★When lipids contain protein then they are
known as lipoproteins. Proteins
★It is biochemical assembly that contains
both protein and lipids , bound to the ✦Protein is a complex nutrient essential to
protein which allows fats to move through many important functions in the body.
the water inside and outside cells ✦Proteins are made up of the elements
carbon, hydrogen, oxygen, nitrogen and
★Examples sulfur.
• Chylomicrons also known as ultra-low- ✦Di ers from carbohydrates and fats
density lipoproteins (ULDL), are because of the presence of nitrogen.
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✦The body has at least 30,000 types of
protein, each with a di erent job. Function of a Protein
✦The building blocks of all protein molecules 1. Build and maintain tissues
are amino acids. 2. Make important compounds
✦There are 20 di erent amino acids that 3. Regulate mineral and uid balance
create di erent combinations for speci c 4. Maintain acid-base balance
functions in the body.
✦The protein we consume can be altered 5. Carry vital substances
and changed but can never return to its 6. Provide energy
initial form. This is called denaturation.
✦ This can be seen when you add heat to an
egg (it changes from a runny uid to a solid
mass). The shapes of the protein
molecules in these foods have changed
Factors that cause denaturation
1. Heat
2. Acids
3. Bases
4. Alcohol
Types of Amino Acids
1. Despensable Amino Acids:
✦Your body can produce these on its own.
✦Your body can synthesize 11 of the amino
acids from the other amino acids
2. Indespensable Amino Acids:
✦The remaining 9 amino acids must come
from your diet – also called essential amino
acids
✦You need all the amino acids to make the
proteins your body needs for good health
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