PART TEST-1

Date: 27/09/2023 Time: 3 hours

Subject: Chemistry (Class-11) Total Marks: 70

General Instructions:
1. All question are compulsory
2. Q 1 to 20 are very short answer objective type and each carries 1 mark each.
3. Q 21 to 27 are short answer question and carry 2 marks each.
4. Q 28 to 34 are also short answer question and carry 3 marks each.
5. Q 35 to 39 are long answer questions and carry 5 marks each. Solve 3 out of the 5
questions given in this section.
6. There is no overall choice. However internal choice have been provided in some
questions.
7. Use of log tables if necessary. Use of calculators is not allowed

Section A (20 X 1 = 20)

1 A solution is prepared by adding 2 g of a substance A to 18 g of water. Calculate [1]
the mass per cent of the solute.
2 What is the SI unit of mass? How is it defined? [1]
3 How many significant figures are present in the following? [1]
1. 0.0025

2. 208

3. 5005
4. 126,000

5. 500.0

6. 2.0034

4 What will be the wavelength of a ball of mass 0.1 kg moving with a velocity of 10 [1]
m s– ?
5 Calculate the mass of a photon with wavelength 3.6 . [1]
6 What is the wavelength of light emitted when the electron in a hydrogen atom [1]
undergoes a transition from an energy level with n = 4 to an energy level with n =
2?
7 Considering the atomic number and position in the periodic table, arrange the [1]
following elements in the increasing order of metallic character: Si, Be, Mg, Na, P.
8 Are the oxidation state and covalency of Al in [ AlCl(H O) the same? [1]
9 Which of the following species will have the largest and the smallest size? Mg, [1]
Mg , Al, Al .
10 Which of the following pairs of elements would have a more negative electron [1]
gain enthalpy?

1. O or F

2. F or Cl

11 In terms of period and group where will you locate the element with Z = 114? [1]
12 Which important property did Mendeleev use to classify the elements in this [1]
periodic table and did he stick to that?
13 Define the bond Length. [1]
14 The skeletal structure of CH COOH as shown below is correct, but some of the [1]
bonds are shown incorrectly. Write the correct Lewis structure for acetic acid.

15 How do you express the bond strength in terms of bond order? [1]
16 Write the favorable factors for the formation of the ionic bond. [1]
17 Calculate molecular mass of glucose (C H O ) molecule. [1]
18 Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in [1]
enough water to form 250 mL of the solution.
19 Calculate the molarity of NaOH in the solution prepared by dissolving its 4 g in [1]
enough water to form 250 mL of the solution.
20 How many moles of methane are required to produce 22g CO (g) after [1]
combustion?
Section B (7 X 2 = 14)
21 Calculate the amount of water (g) produced by the combustion of 16 g of [2]
methane.
22 Calculate the mass per cent of different elements present in sodium sulphate [2]
(Na SO )
23 Determine the empirical formula of an oxide of Iron which has 69.9° % iron and [2]
30.1% dioxygen by mass.
24 Calculate the number of protons, neutrons, and electrons in [2]
25 Calculate (a) wavenumber and (b) frequency of yellow radiation having [2]
wavelength 5800 .
26 The first ionization enthalpy ( H ) values of the third - period elements, Na, Mg, [2]
and Si are respectively 496, 737 and 786 kJ mol – . Predict whether the first H
value for Al will be more close to 575 or 760 kJ mol ? Justify your answer.
–

27 Draw the Lewis structures for the following molecules and ions:H S,SiCl BeF [2]
, CO , HCOOH
Section C (7 X 3 = 21)
28 The density of 3 M solution of NaCl is 1.25 g mL . Calculate the molality of the [3]
solution.
29 When electromagnetic radiation of wavelength 300 nm falls on the surface of [3]
sodium, electrons are emitted with a kinetic energy of 1.68 10 J mol – . What
is the minimum energy needed to remove an electron from sodium? What is the
maximum wavelength that will cause a photoelectron to be emitted?
30 The mass of an electron is 9.1 10 kg. If its kinetic energy is 3.0 10 J, [3]
calculate its wavelength.
31 A photon of wavelength 4 10 m strikes on the metal surface, the work [3]
function of metal being 2.13 eV. Calculate

1. the energy of the photon (eV),

2. the kinetic energy of emission,

3. the velocity of the photoelectron. (1 eV = 1.6020 10 J).

32 The electronic energy in hydrogen atom is given by E = ( - 2.18 10 )/n [3]

J.Calculate the energy required to remove an electron completely from the n = 2
orbit. What is the longest wavelength of light in cm that can be used to cause this
transition?
33 Although geometries of NH and H O molecules are distorted tetrahedral, the [3]
bond angle in water is less than that of ammonia. Discuss.
34 Define electro - negativity. How does it differ from electron gain enthalpy? [3]
Section D (3 X 5 = 15)
35 A welding fuel gas contains carbon and hydrogen only. Burning a small sample of [5]
it in oxygen gives 3.38 g carbon dioxide, 0.690 g of water and no other products.
A volume of 10.0 L (measured at S.T.P) of this welding gas is found to weigh 11.6
g.Calculate

1. empirical formula,
2. molar mass of the gas, and
3. molecular formula.
36 What do you understand by isoelectronic species? Name a species that will be [5]
isoelectronic with each of the following atoms or ions.

(i) F– (ii) Ar (iii) Mg (iv) Rb

37 The first ( H ) and the second ( H ) ionization enthalpies (in kJ mol – ) [5]
and the ( ) electron gain enthalpy (in kJ mol – ) of a few elements are given
below:

Which of the above elements is likely to be:

1. the least reactive element.

2. the most reactive metal.

3. the most reactive non - metal.

4. the least reactive non - metal.

5. the metal which can form a stable binary halide of the formula MX (X =
halogen).

6. the metal which can form a predominantly stable covalent halide of the
formula MX (X = halogen)?

38 Discuss the shape of the following molecules using the VSEPR model:BeCl , BCl [5]
, SiCl , AsF , H S, PH
39 1. Calculate the total number of electrons present in one mole of methane. [5]
2. Find (a) the total number and (b) the total mass of neutrons in 7 mg of C.
(Assume that mass of a neutron = 1.675 10 – kg).

3. Find (a) the total number and (b) the total mass of protons in 34 mg of
NH at STP. Will the answer change if the temperature and pressure are
changed?

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