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MH-CET CELL
Chemistry

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Total Questions : 90 Total Marks : 90
Roll No.
18-Jul-2021
XII - A Div 10:00 AM To 12:00 PM

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This is to certify that, the entry of Roll No. has been correctly written and verified.

Candidate’s Signature MH-CET Chemistry Invigilator’s Signature

Note :
i) All Questions are compulsory

a
ii) Darken ( ) the appropriate circle(#) of the most correct option/response with black ball point pen.

1) The following reaction is known as

____________. cl Amines

4) If on acylation, an amine produces only

monoacetyl derivative, then it must be
___________.
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A) primary amine

B) secondary amine
A) Mendius reduction
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C) tertiary amine
B) Hofmann elimination
D) quaternary ammonium salt
C) Hofmanns exhaustive alkylation 5) The products formed, when ethylamine reacts
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with acetic anhydride are N-ethylethanamide

D) Hofmann rearrangement and ____________.
2) Quaternary ammonium hydroxides on strong
heating undergo ___________ to give an alkene. A) CH3 CH2 COOH B) CH3 COOH
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A) β -elimination B) α -elimination C) H3 C − CH2 − NH2 D) CH3 CONH2

6) Gabriel phthalimide synthesis is used for the

C) substitution D) methylation preparation of ___________.
3) Which of the following can be used for
acylation of amines? A) primary aromatic amines
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A) Acetic anhydride B) Benzoyl chloride B) secondary amines

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C) Acetyl chloride D) All of these C) primary aliphatic amines

D) tertiary amines
 7) Ethanamine on acetylation using ethanoyl 12) Ethylamine reacts with HNO2 to form
chloride gives ____________. ___________.

A) N-ethylethanamide A) CH3 − CH2 − O − N = O

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B) N,N-diethylethanamide B) CH3 − CH2 − O − CH2 − CH3

C) N-methylethanamide C) CH3 CH2 OH

D) N,N-dimethylethanamide D) CH3 − CH2 − NO2

ss
8) Which of the following is FALSE regarding the 13) The gas evolved when aliphatic 1◦ amine reacts
acetylation of amines? with nitrous acid is ___________.

A) Acetylation can be carried out by acid anhydride A) NH3 B) SO2 C) H2 D) N2

a
or acetyl chloride.
14) Reaction given below is an example of
___________.
B) Ethylamine on acetylation gives
N-acetylethylamine.

C) Diethylamine on acetylation gives N-acety

ldiethy lamine. clA) addition reaction
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B) displacement reaction
D) Triethylamine on acetylation gives
N,N-Diacetylethylamine.
C) elimination reaction
9) Primary amines give _________ test.
D) rearrangement reaction
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A) iodoform B) Schiff"s
15) Which of the following can be categorised as
Sandmeyer reaction?
C) Lucas D) carbylamine

10) The foul smelling product of carbylamine

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reaction contains which of the following group?

A) −CN B) −NC

C) −O − N = O D) −N+
2X
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16) Identify Gattermann reaction from the following.

11) A nitrogen containing organic compound (X) on
heating with chloroform and alcoholic KOH,
formed foul smelling compound. The
compound (X) could be ___________.

A) N-methylmethanamine
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B) N,N-dimethylmethanamine 17) X is _______________.

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C) aniline

D) N,N-diethylethanamine
 A) benzene B) phenol A) 1 B) 2 C) 3 D) 4

24) Hinsbergs reagent is ____________.

C) benzyl alcohol D) cyclohexanol

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18) Which one is NOT the reaction of diazonium A) diethyl oxalate
salt?
B) benzyl chloride
A) Sandmeyer reaction
C) benzenesulphonyl chloride
B) Gattermann reaction

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D) benzenediazonium salt
C) Orange dye test
25) In Hinsbergs test, ethylamine forms
_____________.
D) Carbylamine reaction

a
19) Reaction between diazonium fluoroborate and A) a product which soluble in alkali
sodium nitrite in presence of copper replaces
diazonium group with ____________.

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B) a product which insoluble in alkali

A) −NO3 group B) −NO2 group C) a silver mirror

C) −NO group D) −NO2 group D) an orange dye

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20) X is ____________. 26) Identify the INCORRECT statement from the
following.

A) 1◦ , 2◦ and 3◦ amines can be differentiated

A) benzene B) nitrobenzene using Hinsbergs reagent.
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C) fluorobenzene D) aniline B) 1◦ Amines react with Hinsbergs reagent to form

a product which soluble in alkali.
21) Which of the following is azo group?
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C) 2◦ Amines on reaction with Hinsbergs reagent

A) −N = B) −N = N−
forms a product containing H-atom attached to
nitrogen.
C) −NH− D) −CO − NH−

22) Which of the following reaction involves D) 3◦ Amines do not react with Hinsbergs reagent.
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retention of diazo group?

27) −NH2 group in aniline is __________ group.

A) highly ring activating and o-/p-directing

B) weakly ring activating and o-/p-directing

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C) highly ring deactivating and m-directing

23) Azo coupling reaction with respect to aniline
takes place at position number ___________. D) weakly ring deactivating and m-directing
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28) Aniline reacts with bromine water at room

temperature to give ___________.
 A) bromobenzene A) isomers

B) 2-bromoaniline B) homologous

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C) 4-bromoaniline C) same

D) 2,4,6-tribromoaniline D) different primary amines

29) Direct nitration of aniline yields 33) In amines, the hybridisation state of N is

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_________ nitroaniline. __________.

A) ortho and para-substituted A) sp B) sp2 C) sp3 D) sp2 d

34) Example(s) of primary amine is(are)

B) meta substituted
__________.

a
C) para substituted
A) aniline B) isobutylamine
D) o-, m-, p-substituted

30) In order to get p−nitroaniline as major product

from aniline, which of the following sequence
will be effective?
cl C) sec-butylamine D) all of these

35) Secondary amine(s) from the following is/are

___________.
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A) Acetylation → nitration → hydrolysis

B) Nitration → acetylation → hydrolysis

C) Diazotization → nitration → hydrolysis

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D) Diazotization → acetylation → nitration

31) Aniline reacts with conc. H2 SO4 to give X, 36) Match the following.
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which on heating at 453-473 K gives

___________.

A) benzene sulfonic acid

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B) salicylic acid

C) anilinium hydrogen sulfate

A) i - d, ii - c, iii - b, iv - e
D) sulfanilic acid

32) In the reaction, the starting compound and B) i - e, ii - b, iii - d, iv - a

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product C are _____________.

C) i- c, ii - a, iii - b, iv - e
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D) i - e, ii - d, iii - b, iv - a

37) Which of the following is an example of

symmetrical amine?
 A) Methylpropylamine

B) Methylisopropylamine

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C) Diethylamine
A) N,N-dimethylpropan-2-amine
D) Ethyldimethylamine
B) N,N-dimethylaminoisopropane
38) Identify the simple 3◦ amine from the following.

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C) N,N-dimethylaminoethane
A) Ethyldimethylamine
D) N,N-dimethyl-2-aminobutane
B) Trimethylamine
43) The IUPAC name of the compound is
___________.

a
C) Ethylmethyln-propylamine

D) Dimethylamine

39) Match the following.

clA) N,N-dimethyl-N-propyl-3-propanamine

B) N-methyl-N-propylbutan-2-amine
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C) N-butylmethyl-n-propylamine
A) i- d, ii - a, iii - b, iv - c
D) N-ethyl-N-propylbutan-2-amine
B) i- b, ii - c, iii - d, iv - a
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44) The IUPAC name for (CH3 )2 NC(CH3 )3 is

_______________
C) i- b, ii - d, iii - a, iv - c
A) N,N-dimethyl-2-methylpropan-1 -amine
D) i- c, ii - d, iii - b, iv - a
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40) C3 H9 N can represent ____________. B) N,N-dimethyl-2-methylpropan-2-amine

A) primary amine B) secondary amine C) N,N-dimethylbutan-2-amine

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C) tertiary amine D) all of these D) N,N-dimethylpropanamine

41) IUPAC name of isopropylamine is ___________. 45) Ethyl bromide when heated with alcoholic NH3
in a sealed tube gives________. (I) ethylamine
A) propan-1-amine (II) diethylamine (III) triethylamine (IV)
tetraethylammonium bromide
B) 2-methylethanamine
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A) only I B) only III

C) 1-methylethanamine
C) I, II and III D) I, II, III and IV
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D) propan-2-amine 46) Triethylamine X is ________.

42) The IUPAC name of the compound given below
is ____________.
 A) nitromethane B) nitroethane

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C) ethyl cyanide D) 1−nitropropane

47) N−Ethyl−N−methylethanamine Identify

compound X .
51) N-Ethyl-N-methylpropan-1-amine is a

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________ amine. [MH CET 2010]

A) primary B) secondary
A) Nitroethane B) Nitromethane
C) tertiary D) quaternary

a
C) 1−Nitropropane D) 2−Nitropropane
52) Which of the following amines can be prepared
48) 2−Chloropropane The compound Y is by Gabriel phthalimide reaction? [JEE (Main)

cl
____________. 2019]

A) Triethylamine B) n-Butylamine

A) (H3 C)2 CH−CH2 −NH2 C) t-Butylamine D) neo-Pentylamine

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53) Which of the following reactions is appropriate
B) (H3 C)2 CH−CONH2
for converting acetamide to methanamine?
[NEET (UG) 2017]
C) (H3 C)2 CH−CH3
A) Hofmann hypobromamide reaction
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D) (H3 C)2 CH−NH−CH3

49) N−Methylethanamine X is ____________. B) Stephens reaction

C) Gabriels phthalimide synthesis

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D) Carbylamine reaction
A) chloroethane B) chloromethane
54) Which of the following will give methylamine
C) n−propyl chloride D) isopropylchloride upon reaction with acetamide? [BCECE 2014]
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50) Indicate which nitrogen containing compound A) PCI5 B) NaOH + Br2

amongst the following would undergo
Hofmanns reaction (i.e., reaction with Br2 and C) Sodalime D) Hot conc. H2 SO4
conc. KOH) to furnish the primary amine
(R − NH2 ). 55) In the Hofmann bromamide degradation
reaction, the number of moles of NaOH and Br2
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used per mole of amine produced are ________.

[JEE (Main) 2016]
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 A) one mole of NaOH and one mole of Br2 A) (C2 H5 )NH > NH3 > C2 H5 NH2

B) four moles of NaOH and two moles of Br2 B) (C2 H5 )2 NH > C2 H5 NH2 > NH3

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C) two moles of NaOH and two moles of Br2 C) C2 H5 NH2 > NH3 > (C2 H5 )2 NH

D) four moles of NaOH and one mole of Br2 D) NH3 > C2 H5 NH2 > (C2 H5 )2 NH

56) Which of the following statements is 61) The CORRECT statement regarding the basicity

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INCORRECT in case of Hofmann bromamide of arylamines is _____________. [NEET P-I
degradation? [MHT CET 2017] 2016]

A) Reaction is useful for decreasing length of A) arylamines are generally more basic than
carbon chain by one carbon atom. alkylamines because of aryl group

a
B) It gives tertiary amine. B) arylamines are generally more basic than
alkylamines because the nitrogen atom in
C) It gives primary amine.

D) Aqueous or alcoholic KOH is used with bromine.

57) Which of the following is least soluble in water

cl arylamines is sp-hybridized

C) arylamines are generally less basic than

alkylamines because the nitrogen lonepair
electrons are delocalised by interaction with the
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at 298 K? [KCET 2019] aromatic ring π electron system

A) (CH3 )2 NH B) C6 H5 NH2 D) arylamines are generally more basic than

alkylamines because the nitrogen lonepair
C) CH3 NH2 D) (CH3 )3 N electrons are not delocalised by interaction with
the aromatic ring π electron system
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58) In aqueous phase, most basic among the

following is ___________. [MHT CET 2019] 62) Which one of the following compounds when
heated with KOH and a primary amine gives
A) ammonia B) trimethylamine carbylamine test? [Orissa JEE 2010]
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C) methylamine D) dimethylamine A) CHCI3 B) CH3 CI

59) The CORRECT order of the basic strength of

C) CH3 OH D) CH3 CN
methyl substituted amines in aqueous solution
is _____________. [NEET (UG) 2019]
co

63) Which one of the following will give

carbylamine test? [Assam CEE 2015]
A) (CH3 )3 N > CH3 NH2 > (CH3 )2 NH
A) NH2 CONH2 B) CH3 CONH2
B) (CH3 )3 N > (CH3 )2 NH > CH3 NH2
C) C2 H5 NH2 D) All of these
C) CH3 NH2 > (CH3 )2 NH > (CH3 )3 N
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64) The reaction of aniline with chloroform under

D) (CH3 )2 NH > CH3 NH2 > (CH3 )3 N alkaline conditions leads to the formation of
___________. [WB JEEM 2014]
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60) In the following compounds, the decreasing

order of basic strength will be ____________. A) phenyl cyanide B) phenyl isonitrile
[JEE (Main) 2019]
C) phenyl cyanate D) phenyl isocyanate
 65) Acetic acid on heating with NH3 forms A.When
A reacts with LiAIH4 followed by hydrolysis
gives B. When B is heated with chloroform in
KOH medium gives C. What are B and C
respectively? [AP EAMCET (Engg.) 2019]

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A) CH3 CONH2 , CH3 CH2 NC

B) CH3 CH2 NH2 , CH3 CH2 NC

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C) CH3 CH2 NH2 , CH3 COOH

D) CH3 CH2 CH2 NH2 , CH3 CH2 NC

66) Select the compound which on treatment with

a
nitrous acid liberates nitrogen. [MHT CET 2016]

A) Nitroethane B) Triethylamine

C) Diethylamine D) Ethylamine

67) Which of the following is NOT formed by

Sandmeyer reaction? [GUJ CET 2015]
cl
69) The reagent with which the following reaction is
best accomplished is ___________. [WB JEEM
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2014]
A) C6 H5 CI B) C6 H5 I

C) C6 H5 Br D) C6 H5 CN

68) In the reaction the product E is __________.

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[JEE (Main) 2015]

A) H3 PO2 B) H3 PO3

C) H3 PO4 D) NaHSO3
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70) Identify Z in the following reaction: [TS

EAMCET (Engg.) 2015]
co
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71) In a reaction of aniline, a coloured product C

was obtained. The structure of C would be
[CBSE PMT (Prelims) 2010]
nc
 es
72) A given nitrogen-containing aromatic
75) Which of the following reactions does NOT

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compound A reacts with Sn/HCl, followed by
occur? [GUJ CET 2014]
HNO2 to give an unstable compound B . B , on
treatment with phenol, forms a beautiful
coloured compound C with the molecular A) Tripropylamine + benzenesulphonyl chloride
formula C12 H10 N2 O. The structure of compound

a
A is ________________. [NEET P-II 2016] B) Dipropylamine + benzenesulphonyl chloride

C) Propylamine + benzenesulphonyl chloride

clD) Propylamine + p-toluenesulphonyl chloride

76) An organic compound X having molecular

formula C4 H11 N reacts with p-toluenesulphonyl
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chloride to form a compound Y that is soluble
73) Consider the following reaction: The product X in aqueous KOH. Compound X is optically
is used ___________. [JEE (Main) 2020] active and reacts with acetyl chloride to form
compound Z ". Identify the compound Z". [MH
CET 2014]
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A) in protein estimation as an alternative to

ninhydrin
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B) in laboratory test for phenols

C) as food grade colourant

77) Identify the product C in the following reaction.

D) in acid base titration as an indicator
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[MHT CET 2018]

74) The amine that reacts with Hinsberg reagent to
give an alkali insoluble product is
____________. [NEET (Odisha) 2019]

A) Acetanilide
e

B) p−Bromoacetanilide
nc

C) p−Bromoaniline

D) o−Bromoaniline
 78) When aniline is nitrated with nitrating mixture
in ice cold condition, the major product
obtained is ____________. [WB JEE 2013]

A) p-nitroaniline B) 2,4-dinitroaniline

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C) o-nitroaniline D) m-nitroaniline

79) If aniline is treated with 1:1 mixture of conc.

HNO3 and conc. H2 SO4 , p-nitroaniline and

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m-nitroaniline are formed nearly in equal
amounts. This is due to _____________. [KCET
2019]

A) m- and p-directing property of −NH2 group

a
B) isomerization of some p-nitroaniline into
m-nitroaniline

C) m-directing property of −NH2 group

D) protonation of −NH2 which causes deactivation

of benzene ring
cl
ng
82) In case of substituted aniline the group which
80) The product(s) obtained when t-butyl bromide decreases the basic strength is ____________.
is treated with alcoholic ammonia is [MHT CET 2017]
____________. [MHT CET 2019]
A) −OCH3 B) −CH3
A) (CH3 )3 C − NH+ −
3 OH + HBr
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C) −NH2 D) −C6 H5
B) (CH3 )2 C = CH2 + NH4 Br
83) The CORRECT increasing order of basic
strength for the following compounds is
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C) (CH3 )3 C − OH + NH4 Br
___________. [NEET (UG) 2017]
D) (CH3 )3 C − NH+
3 Br

81) Coupling of benzene diazonium chloride with

1-naphthol in alkaline medium will give
co

______________. [JEE (Main) 2019]

A) III < I< II B) III < II< I

C) II < I< III D) II < III< I

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84) 1 mole of ethylamine on reaction with excess of

nitrous acid gives how many grams of
nitrogen? (atomic weight of nitrogen = 14) [MH
nc

CET 2011]
 A) eight B) seven

C) fourteen D) twenty eight

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85) Which of the following is the most stable
diazonium salt? [AIPMT 2014; MH CET 2015;
KCET 2018]

A) C6 H5 CH2 N+
2X
− B) CH3 N+
2X
−

ss
C) CH3 CH2 N+
2X
− D) C6 H5 N+
2X
−

86) How many isomeric amines are possible for

C3 H9 N ? [BCECE 2014]

a
A) 2 B) 3 C) 4 D) 5 89) What is the product P in the following
sequence of reactions? [TS EAMCET (Med.)
87) Method by which aniline CANNOT be prepared 2019]
is ____________. [AIPMT Re-Test 2015]

A) reduction of nitrobenzene with H2 /pd in ethanol

B) potassium salt of phthalimide treated with

cl
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chlorobenzene followed by hydrolysis with
aqueous NaOH solution

C) hydrolysis of phenyl isocyanide with acidic

solution
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D) degradation of benzamide with bromine in

alkaline solution

88) Identify Z in the following sequence of

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reactions. [AP EAMCET (Engg.) 2019]

90) In the sequence of following reactions: The

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starting compound P is ___________. [KCET

2015]

A) o-nitrotoluene B) m-nitrotoluene

C) o-bromotoluene D) p-nitrotoluene
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 Answer Sheet

Chemistry : Amines
Total Questions : 90 Total Marks : 90

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1 B 2 A 3 D 4 B 5 B 6 C 7 A 8 D 9 D 10 B 11 C 12 C
13 D 14 B 15 A 16 B 17 B 18 D 19 B 20 C 21 B 22 B 23 D 24 C

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25 A 26 C 27 A 28 D 29 D 30 A 31 D 32 C 33 C 34 D 35 D 36 A
37 C 38 B 39 B 40 D 41 D 42 A 43 B 44 B 45 D 46 B 47 B 48 A
49 A 50 C 51 C 52 B 53 A 54 B 55 D 56 B 57 D 58 D 59 D 60 B

a
61 C 62 A 63 C 64 B 65 B 66 D 67 B 68 C 69 A 70 C 71 B 72 C
73 D 74 B 75 A 76 B 77 C 78 A 79 D 80 B 81 B 82 D 83 C 84 D
85 D 86 C 87 B 88 D 89 D 90 D

cl
ng
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ac
co
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