18308apni Kaksha

JEE ADVANCED PAPER – 2
CLASS 11th APNI KAKSHA STAR BATCH
TIME : 3 Hours Maximum Marks : 180

ANSWER KEY
&
SOLUTION WITH EXPLANATION
Solution Sheet Available Only for 24 Hours

PART – 1 : MATHEMATICS
SECTION - 1 (Maximum Marks : 12)

• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
• For each question, choose the option corresponding to the correct answer.
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +𝟑 If ONLY the correct option is chosen;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟏 In all other cases.
sin([𝑥]𝜋) 1
1. If 𝑓: 𝑅 → 𝑅, 𝑓(𝑥) = 𝑥 2 +2𝑥+3 + 2𝑥 − 1 + √𝑥(𝑥 − 1) + 4 (where [𝑥] denotes greatest integral for
value less than or equal to 𝑥) denotes a function, then number of real solutions of equation
𝑓(𝑥) = 𝑓 −1 (𝑥) is
(A) 0 (B) 1 (C) 2 (D) 3
Ans. (B)
2. The system of linear equations
3x − 2y − kz = 10
2x − 4y − 2z = 6
x + 2y − z = 5m
is inconsistent if:
4 4
(A) k = 3, m ≠ 5 (B) k ≠ 3, m ≠ 5
4
(C) k = 3, m = 5 (D) k ≠ 3, m ∈ R
Ans. (A)
3. Let S be set of all value of ' a ' which the inequality x 2 + |x − a| − 3 < 0 is satisfied by at least
one negative ' x '. Which of the following can be subset of S ?
(A)(−3,2) (B) (0,4) (C) (−4,1) (D) (−1,4)
Ans. (A)
x
4. The number of solutions of the equation sin (2) + 2πx = x 2 + π2 + 1 is :
(A)1 (B) 2 (C) 0 (D) 3
Ans. (A)
APNI KAKSHA 1

• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
Full Marks : + 𝟒 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : + 𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : + 𝟐 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : + 𝟏 If two or more options are correct but ONLY one option is chosen and it
is a correct option;
Zero Marks : 0 If unanswered;
Negative Marks : −𝟐 In all other cases.
5. A parabola touches x-axis and y-axis at (1,0) and (0,1) respectively then :
(A) Equation of parabola is (y − x)2 = 2x + 2y − 1
1 1
(B) Coordinates of focus parabola is (2 , 2)
(C) Equation of directrix of parabola is x + y = 0
(D) Length of latus rectum of parabola is 2
Ans. (ABC)
6. Let curve C1 be the locus of mid-points of all chords of ellipse E: x 2 + 2y 2 = 2, that passes
through the point Q(−2,0). Further, curve C2 is the locus of the point P such that QA, QP and QB
are in A.P., where the line QP meets the ellipse E at points A and B. Now, choose the correct
statement(s) :-
(A) Curve C1 is a part of ellipse x 2 + 2x + 2y 2 = 0
(B) Curve C2 is a part of ellipse x 2 + 2x + 2y 2 = 0
(C) Putting aside origin, no point of curve C1 lies in Ist quadrant
(D) Putting aside origin, no point of curve C2 lies in IV th quadrant
Ans. (ABCD)
7. In a △ ABC its incircle touches sides AB, BC, CA at C1 , A1 , B1 respectively. If the arc length of
incircle along A1 B1 , C1 A1 and B1 C1 are 6,8,10 respectively. Then
12
(A)r = (where ' r ' is the radius of incircle of △ ABC )
π
(B) Angles A, B, C are in A.P.
6√2
(C)R = πsin15∘ (where ' R ' is the radius of circum circle of △ ABC )
(D) For the circumcircle of △ ABC arc lengths AB, CA, BC are in A.P.
Ans. (A, B, C, D)
APNI KAKSHA 2

• This section contains 𝐒𝐈𝐗(06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and
the on-screen virtual numeric keypad in the place designated to enter the answer.
Full Marks : +𝟒 If ONLY the correct integer is entered;
Zero Marks : 𝟎 In all other cases.
1 1 1 1
8. Let a, b, c and d are positive real numbers and 1+a4 + 1+b4 + 1+c4 + 1+d4 = 1. If the minimum
value of product ‘abcd’ be λ. Find the value of 10λ.

Ans. 30
λ
9. If the sum of first 100 terms of series 1,2,2,3,3,3,4,4,4,4,……….. is λ. Then 63 is.
Ans. 15
10. Sum of all real values of m for which the equation

(5m − m2 )2 sin2 x − 10sinx(5m − m2 ) + 24 = 0 has exactly 3 solution in [0,2π] is :
Ans. 10
11. If line ax + by −1 = 0 intercepted between lines ax + y + 1 = 0&x + by = 0 subtends 90∘ at

origin (a, b ∈ R), then maximum possible value of 24a, is
Ans. 3
12. If coefficient of x 2 in the expansion of
(1 + 2x + x 2 + 2x 3 + x 4 + 2x 5 + ⋯ . . +2x 2019 )50 (1 − x + x 3 − x 5 + x 7 − ⋯ . . +x 2019 )100 is k,
then the value of k is equal to
Ans. -100
13. There are five different boxes and seven different balls. The number of ways in which these
balls can be distributed so that box 2 and box 4 contains only 1 ball each and at least 1 box is
empty is N. (Order of putting the balls in the boxes is NOT considered). Then the value of N
is___________.
Ans. 3906
APNI KAKSHA 3

• This section contains TWO (02) Paragraphs.
• Based on each paragraph, there are TWO (02) questions.
• The answer to each question is a NUMERICAL VALUE.
• For each question, enter the correct numerical value of the answer using the mouse and the on-
screen virtual numeric keypad in the place designated to enter the answer.
• If the numerical value has more than two decimal places, truncate/round-off the value to
TWO decimal places.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 If ONLY the correct numerical value is entered in the designated place;
Zero Marks : 0 In all other cases.
Paragraph-I
Consider a hyperbola 𝑥𝑦 = 4 and a line 𝑦 + 2𝑥 = 4. Point 𝑂 is the centre of the hyperbola.

Tangent at any point 𝑃 on the hyperbola intersects the coordinate axes at 𝐴 and 𝐵.
14. Locus of circumcenter of triangle 𝑂𝐴𝐵 is a hyperbola with eccentricity e then [e] is equal to
(where [.] denote greatest integer function)
Ans. 1
15. Let the given line intersect the 𝑥-axis at 𝑅. If a line through 𝑅, intersects the hyperbola at 𝑆 and
𝑇, then the minimum value of 𝑅𝑆 × 𝑅𝑇 is
Ans. 8
Paragraph -II
In a scalene △ 𝐴𝐵𝐶 perpendicular distances of circumcenter from the sides 𝐵𝐶, 𝐴𝐶, 𝐴𝐵 are
𝜆1 , 𝜆2 and 𝜆3 respectively. Distance of orthocenter from the vertices 𝐴, 𝐵, 𝐶 are 𝛼1 , 𝛼2 and 𝛼3
respectively. 𝑅, s are circumradius and semi-perimeter of the △ 𝐴𝐵𝐶. Let a, b, c are length of
sides BC, CA, AB respectively & 𝑅, s are circumradius and semi-perimeter of the △ 𝐴𝐵𝐶.
b(λ1 +λ3 )+c(λ1 +λ2 )+a(λ2 +λ3 )
16. The value of is equals to
𝑅𝑠
Ans. 2
α1 α2 α3
17. The value of equals to
λ1 λ2 λ3
Ans. 8
APNI KAKSHA 4
PART – 2 : PHYSICS

correct answer.
18. A truck is acceleration on horizontal road with an acceleration 20 m/s2 . A block placed against
the rear wall of the truck as shown has a mass of 100 kg and coefficient of friction between it
and the wall is 0.8.
(A) Acceleration of the box is 20 m/s2

(B) The friction acting on the block is 1600 N
(C) The friction acting on the block is 500 N
(D) The contact force between the wall and block is 1000 N
Ans. (A)
Sol. N = 100 × 20 = 2000 ⇒ fmax = 2000 × 0.8 = 1600
f = mg = 1000 ⇒ √f 2 + N2 = 1000√5 N
19. Figure shows a block of mass m projected with velocity v0 towards a wedge. Consider all the
surfaces to be smooth. Block does not have sufficient energy to negotiate (over come) wedge.
Mark the correct option(s):
APNI KAKSHA 5
(A) when block is at the maximum height on wedge, block and wedge have velocity equal to
velocity of centre of mass of block wedge system
(B) wedge acquires minimum speed with respect to ground when block returns to lowest point
on wedge
(C) momentum of wedge and block is conserved at all times
(D) centre of mass of wedge and block remains stationary
Ans. (A)
Sol. (i) in horizontal direction momentum is conserved.
(ii) when block is at maximum height it would be stationary w.r.t. plank.
So vblock = vplank = vcm
(iii) PE + KE = constant
(iv) vcm ≠ 0
20. In the figure the block on the smooth table is set into motion in a circular orbit of radius r
around the centre hole. The hanging mass is identical to the mass on the table and remains in
equilibrium. Neglect friction. The string connecting the two blocks is massless and inextensible.
Select the correct answer.
g
(A) The angular speed ω of the block in its circular motion is √2r
(B) Kinetic energy as function of r is given by mgr

(C) Angular momentum about the hole is conserved even if hanging block is pulled down
(D) The block on table is in equilibrium
Ans. (C)
Sol. For (A), T = mg
mv 2 g
For (B), T = = mω2 r ⇒ mω2 r = mg, ⇒ ω = √
r r
2
1 1 g mgr
K.E. of system = m v2 = 2 (m) (√r ) =
2 A A 2
(c) Tension is central force on A, so angular momentum remains conserved.

APNI KAKSHA 6
21. Sachin (S) hits a ball along the ground with a speed u in a direction which makes an angle 30∘
with the line joining him and the fielder Prem (P). Prem runs to intercept the ball with a speed
2u
. At what angle θ should he run to intercept the ball?
3
√3
(A) sin−1 ( 2 )
2
(B) sin−1 (3)
3
(C) sin−1 (4)
4
(D) sin−1 (5)
Ans. (C)
Sol. Relative to P, the path of S should be along the line SP. So perpendicular to this path, relative
velocity should be zero.

APNI KAKSHA 7
22. S is a solid neutral conducting sphere. A point charge q of 1 × 10−6 C is placed at point A. C is
the centre of sphere and AB is a tangent. BC = 3 m and AB = 4 m.
(A) The electric potential of the conductor is 1.8kV

(B) The electric potential of the conductor is 2.25kV
(C) The electric potential at B due to induced charges on the sphere is −0.45kV.
(D) The electric potential at B due to induced charges on the sphere is 0.45kV.
Ans. (A, C)
Sol. Distance AC is given by, AC = 5 m
Potential at due to charge q at A is given by
kq 9 × 109 × 1 × 10−6
V = = = 1.8 × 103 = 1.8kV
AC 5
Potential at B is given by
VB = (VB )due to q + (VB )induced
{(VB )1 = Potential at B due to induced charge }
kq
Thus 1.8 × 103 = AB + (VB )i ⇒ 1.8 × 103 = 2.25 × 103 + (VB )i
(VB )i = −0.45kV
So option (A) & (C) are correct.
23. A particle moves with an initial velocity 𝑣0 and retardation 𝛼𝑣, where 𝑣 is its velocity at any
time 𝑡. Select the correct statement(s).
𝑣0
(A) The particle will cover a total distance 𝛼
1
(B) The particle comes to rest after a time 𝛼
(C) The particle will continue to move for a very long time
𝑣0 1
(D) The velocity of the particle will become after a time 𝛼
2
Ans. (A,C)
dv 0 x v0
Sol. Since, v = −αv ⇒ ∫v dv = −α ∫0 0 dx ⇒ x0 =
dx 0 α
So, option (A) is correct.

dv v dv t
Also, dt = −αv ⇒ ∫v = −α ∫0 dt ⇒ v = v0 e−αt ⇒ v = 0 for t → ∞
0 v
So, option (C) is also correct.
APNI KAKSHA 8
24. The position of a particle varies according to the expression x = t(t − 1)(t − 2), then:
1 1
(A) Velocity will be zero at t 2 = 1 − second and t 2 = 1 + sec
√3 √3
(B) Acceleration changes its direction between t1 = 0 and t 2 = 2

(C) Acceleration remains constant in direction between t1 = 0 and t 2 = 2
(D) None of the above
Ans. (A, B)
Sol. x = t 3 − 3t 2 + 2t
dx
v= = 3t 2 − 6t + 2 = 0
dt
6±√36−24 6±√12 1
t= = = 1±√ sec
6 6 √3
dv
a= = 6t − 6 at t = 1, a = 0
dt
0 < t < 1 a is − ve
1 < t < 2a is + ve

25. A light elastic string on a smooth horizontal table has one of its ends fastened. The string of
force constant K, is stretched to twice its natural length of ℓ0 and is projected along the table at
right angles to the string with a speed v0 . If one-fifth of its initial energy is kinetic, and the rest
is potential energy of the string, and the string attains its natural length at some instant, the
plo
time for which it remains slack is qv then p + q = ?
0
Ans. 7
APNI KAKSHA 9
1
mv20 1
Sol. 1
2
1 =5
mv20 + kℓ20
2 2
⇒ 4mv02 = kℓ20 (When the string is slack, the motion will be a straight line.)
Also, mvt ℓ0 = 2mv0 ℓ

vt = 2vo
1 1 1 1
m(2v0 )2 + 2 mvr2 = 2 (kℓ20 ) + 2 mv02
2
⇒ vr = v0
1
tan α = 2, cos α =
√5
v = √vt2 + vr2 = √5v0

2ℓ0
AB = 2ℓ0 cos α =
√5
2ℓ
∴ Time = 5v0
0
26. A uniform spherical shell of mass m (in kg ) and radius R (in metre) starting from rest performs
pure rolling on a long inclined plane as shown in the figure. The angular momentum of the shell
about the point of contact after 1sec of starting is K mR Kgm2 s −1 then k =?
Ans. 5
1
Sol. L0 = lω + mvcm R = vcm R (R2 + m)
mgsin θ − f = ma
fR = lα
mgsin θ
a=
m + l/R2
mgsin θ g 2 g 3
v=( 2
) × 1 = [1/ (1 + )] = × = 3 m/sec
m + l/R 2 3 2 5
2 5
L0 = 3R ( m + m) = 3R ( m) = 5mR kg m2 s−1
3 3
APNI KAKSHA 10
27. Two identical particles collide in air inelastically. One moves horizontally & the other moves
vertically with equal speed just before collision. The fractional loss in kinetic energy of the
1
system of particles is equal to k then k = ?
Ans. 2
Sol. Conservation of linear momentum yields
v v
⃗′⇒v
mvî + mvĵ = (2m)v ⃗ ′ = 2 (î + ĵ) ⇒ v ′ =
√2
2 2
KEf (1/2)(2m)v′2 v′ 1 1
η= 1− =1− ⇒η =1−( ) = 1−( ) = .
KEi (1/2)mv2 +(1/2)mv2 v √2 2
28. A particle of mass ' m ' comes down on a smooth inclined plane from a point B at a height of h
from rest. The magnitude of change in momentum of the particle between the positions A and C
assuming the angle of inclination of the plane as θ with respect to the horizontal is
θ
km√kghsin then k =?
k
Ans. 2
Sol. The velocity of the particle when it reaches the point A from B is
v = √2gh, directed along BA.
(pi )x = mv cosθ ….(i)
(pi )y = mvsin θ ….(ii)
When the particle reaches the point C, the momentum is as shown in figure.
(Pf )x = mv ….(iv)
(pf )y = 0 …..(v)
Therefore
Δpx = (pf )fx − (pi )x = mv − mv cosθ ….(vi)
Similarly
Δpy = (pf )y − (pi )y = −mv sinθ …..(vi)
Therefore
2
Δp = √(Δpx )2 + (Δpy ) = √(mv − mv cosθ)2 + (−mv Sinθ)2
θ θ
= √2(mv)2 − 2(mv)2 Cos θ = √2mv√1 − Cosθ = √2m√2gh√2sin (2) = 2m√gh√2sin (2)
θ
Therefore, Δp = 2m√2ghsin (2)
APNI KAKSHA 11
29. Two identical rods are joined at one of their ends by a pin. Joint is smooth and rods are free to
rotate about the joint. Rods are released in vertical plane on a smooth surface as shown in the
figure. The displacement of the joint from its initial position to the final position is (i.e., when
(k2 +1)
the rods lie straight on the ground) is √ L then k = ?
k2
Ans. 4
L
Sol. Initially the centre of mass is at 4 distance from the vertical rod.
1
m( )+m(0) L
( As, xCM = 2
= 4)
m+m
Centre of mass does not move in x-direction as ΣFx = 0.

After they lie on the floor, the pin joint should be at L/4 distance from the origin shown in order
to keep the centre of mass at rest.
L
∴ Finally x-displacement of the pin is and y-displacement of the pin is obviously L.
4
L2 √17L
Hence net displacement = √L2 + 16 = 4
30. A particle is revolving in a circle of radius R with initial speed u. It starts retarding with
v2
retardation . Where v = instantaneous velocity. The number of complete revolutions it
4πR
8πR
makes in time is:
u
Ans. 2
Sol. Initial Velocity = u (say)
Velocity at time t = v
dv v2 dv dt 1 1 1
=− ⇒ −∫ 2 = ∫ ⇒ = t+C⇒ = 0+C
dt 4πR v 4πR v 4πR u
1 1 1
∴ = t+
v 4πR u
dt ut + 4πR dt ds 1 1
= ⇒∫ =∫ ⇒ ⋅ log e (ut + 4πR) = s+C
ds 4πRu ut + 4πR 4πRu u 4πRu
1 ut + 4πR s
⋅ log e (0 + 4πR) = 0 + C ⇒ log e ( )=
u 4πR 4πR
8πR
For t = ⇒ gives s = 4πR log e (3) = 2.2(2πR)
u
APNI KAKSHA 12

TWO decimal places.
PARAGRAPH-I
The kinetic energy is the capacity of the body to do work by virtue of its motion. For a body of
1
mass m moving with a velocity v, it is mathematically defined as KE = 2 mv 2 .
For conservative forces doing work, the kinetic energy always increases (or remains constant)
and for non-conservative forces doing work, the kinetic energy decreases. A plot of force vs
displacement is shown here. The conservative force is shown as positive and that due to non-
conservative force is shown as negative. Consider a body of mass 4 kg having a velocity of
20 ms−1 at the origin of the coordinates. Based on the above facts and figures, answer the
following questions.
31. The kinetic energy of the particle at the origin of the coordinates is
(A) 400 J (B) 600 J (C) 800 J (D) 1000 J
Ans. (C)
1
Sol. KE = 2 (4)(20)2
⇒ KE = 800 J
APNI KAKSHA 13
32. The kinetic energy of the body at B, x = 4 m is
(A) 376 J
(B) 576 J
(C) 776 J
(D) 824 J
Ans. (C)
Sol. Work done from OAB
1
Area = (4)(12) = 24 J
2
Since the force is non-conservative from 0 to A, so KE must decrease and hence KE at x = 4 m is
(800 − 24)J
⇒ KE|x=4 m = 776 J
PARAGRAPH-II
Two friends A and B (each weighing 40 kg ) are sitting on a frictionless platform some distance
d apart. A rolls a ball of mass 4 kg on the platform towards B, which B catches. Then B rolls the
ball towards A and A catches it. The ball keeps on moving back and forth between A and B.
The ball has a fixed speed of 5 ms−1 on the platform. Based on above information, answer the
following questions.
33. The speed of A after he rolls the ball for the first time is
(A) 0.25 ms −1 (B) 0.5 ms −1
(C) 1 ms−1 (D) 1.5 ms −1
Ans. (B)
34. The speed of A and B after the ball has made four round trips and is held by A are
50 25 40 20
(A) 11 ms −1 , 11 ms −1 (B) 11 ms −1 , 11 ms−1
30 25 50 30
(C) 11 ms −1 , 11 ms −1 (D) 11 ms −1 , 11 ms−1
Ans. (D)
Sol. Applying Law of Conservation of Linear Momentum, we get
40v + 4 × 5 = 0
1
⇒v=− ms −1 ⇒ |v
⃗ | = 0.5 ms −1
2
Applying Law of Conservation of Linear Momentum, we get
10 5
20 = 44v ⇒ v = 22 = 11 ms−1
APNI KAKSHA 14
PART – 3 : CHEMISTRY

correct answer.
35. Solubility product constant (K sp ) of salts of type MX, M2 and M3 X at temperature ' T ' are
4.0 × 10−8 , 3.2 × 10−14 and 2.7 × 10−15 , respectively. Solubilities (mol, dm) of the salt at
temperature ' T ' are in the order
(A) MX > MX2 > M3 X (B) M3 X > MX2 > MX
(C) MX2 > M3 X > MX (D) MX > M3 X > MX2
Ans. (D)
Sol. MX: K sp = S 2 = 4 × 10−8 ⇒ S = 2 × 10−4
MX2 : K sp = 4S 3 = 3.2 × 10−14 ⇒ S = 2 × 10−5
M3 X: K sp = 27S 4 = 2.7 × 10−15 ⇒ S = 10−4
Order of solubility is MX > M3 X > MX2
36. The hyperconjugative stabilities of tert-butyl cation and 2-butene, respectively, are due to
(A) σ → p (empty) and σ → π⋆ electron delocalisations.
(B) σ → σ∗ and σ → π electron delocalisations.
(C) σ → p (filled) and σ → π electron delocalisations.
(D) p (filled) → σ⋆ and σ → π⋆ electron delocalisations.
Ans. (A)
Sol. Hyperconjugation is due to the interaction of the electrons in 𝜎 bond (C − H or C-C) with
adjacent empty or partly filled non-bonding p-orbital, antibonding 𝜋 orbital or filled 𝜋 orbital.
This result in extended molecular orbital and increases the stability of the system.
In case of tert-butyl cation, the hyperconjugation is due to the interaction of the electrons in the
𝜎 bond with adjacent empty p-orbital.
In case of 2-butene, the hyperconjugation is due to the interaction of 𝜎 orbital with antibonding
𝜋 orbital.
APNI KAKSHA 15
37. The dissolution of Al(OH)3 by a solution of NaOH results in the formation of:
(A) [Al(H2 O)4 (OH)2 ]+ (B) [Al(H2 O)3 (OH)3 ]
(C) [Al(H2 O)2 (OH)4 ]− (D) [Al(H2 O)6 (OH)3 ]
Ans. (C)
Sol. Al(OH)3 dissolves in NaOH solution to give Al(OH)−
4 ion which is supposed to have the
octahedral complex species [Al(OH)4 (H2 O)2 ]− in aqueous solution.

Al(OH)3 + NaOH(𝑎𝑞) ⟶ [Al(OH)4 (H2 O)2 ]− (𝑎𝑞) + Na+ (𝑎𝑞)
38. The correct order of acidity for the following compounds is
(A) I > II > III > IV (B) III > I > II > IV
(C) III > IV > II > I (D) I > III > IV > II
Ans. (A)
Sol. In general, whenever a group is present at ortho position of benzoic acid, irrespective of its
nature (EDG or EWG), it increases the acidic strength as compared to benzoic acid itself. Here in
option (I) and (II) we have ortho effect which will increase the acidity of compounds than (III)
and (IV).
Comparing (I) and (II), (I) is the most strong acid because it has more hydrogen bonding
compare to other. The two OH group in ortho position make hydrogen bonding with
carboxylate ion. This hydrogen bonding stabilise the conjugate base of this Compound.
In (I), one OH is present at one ortho position and it will have one hydrogen bonding with
carboxylate ion.
Stability of conjugate base ∝ Strength of acid
Hence (I) is more acidic and than (II).
Comparing (III) and (IV), OH at meta position does not show mesomeric effect but -I effect will
stabilise the negative charge on conjugate base. OH on para position show +𝑀 effect which will
increase the negative charge on carboxylate ion and destabilise the conjugate base. Hence (III)
is more acidic than (IV). Thus, the correct order of acidity is
I > II > III > IV
APNI KAKSHA 16

39. Which of the following is/are correct regarding root mean square speed (Urms ) & average
translation K.E. ( Eav ) of molecule in a gas at equilibrium.
(A) Eav is doubled when its temperature is increased 4 times
(B) Urms is inversely proportional to the square root of its molecular mass
(C) Eav at a given temperature doesn't depend on its molecular mass
(D) Urms is doubled when its temperature is increased 4 times
Ans. (BCD)
𝐸𝑎𝑣 at a given temperature does not depend on the molecular mass of the gas
𝑈𝑟𝑚𝑠 is doubled when its temperature is increased four times
𝑈𝑟𝑚𝑠 is inversely proportional to the square root of the molecular mass of the gas
3 3𝑅𝑇
We know, 𝐸𝑎𝑣 = 2 𝑘𝑏 𝑇 ⇒ 𝑈𝑟𝑚𝑠 = √ 𝑀
Thus.
𝐸𝑎𝑣 at a given temperature does not depend on molecular mass.
𝑈𝑟𝑚𝑠 is doubled when its temperature is increased four times.
𝐸𝑎𝑣 increases four times when its temperature is increased four times.
𝑈𝑟𝑚𝑠 is inversely proportional to the square root of molecular mass
3 3𝑅𝑇
𝐸𝑎𝑣 = 2 𝑅𝑇𝑈𝑟𝑚𝑠 = √ 𝑀
Eav does not depend on its molecular mass but depends upon absolute temperature.
APNI KAKSHA 17
40. Which of the following is/ are correct order ?
(A) Atomic radius : F < O < F– < O2–
(B) 2nd ionisation energy : C < N < F < O
(C) Electron affinity : I < Br < F < Cl
(D) Zeff (effective nuclear change): Al < Al+ < Al3+ < Al2+
Ans. (A,B,C)
1
Sol. (A) The radius of isoelectronic species 
Z
ratio
e
(B) Ionisation energy  1  Effective nuclear charge

size
1
(C) Normally the electron affinity (EA) 
size of atom
41. Which of the following order of stability of Intermediate are incorrect: -
(A)
(B)
(C)
(D)
Ans. (A, B)
APNI KAKSHA 18
Sol. (A) Correct order of stability
(B) Correct order of stability

42. Aqueous solutions of HNO3 , KOH, CH3 COOH and CH3 COONa of identical concentrations are
provided.
Total number of pair(s) of solutions which form a buffer upon mixing is (are)
(I) HNO3 and CH3 COOH (II) KOH and CH3 COONa
(III) HNO3 and CH3 COONa (IV) CH3 COOH and CH3 COONa
Ans. 2
APNI KAKSHA 19
Sol. (C, D)
A buffer solution consists of a weak acid and its salt with a strong base or a weak base and its
salt with strong acid.
(III) In HNO3 and CH3 COONa combination, if HNO3 is present in a limiting amount, it will be
neutralised completely, leaving behind some excess of CH3 COONa. Now the solution contains
acetic acid (weak acid) and sodium acetate (salt with strong base NaOH ).
Hence, it is a buffer solution.
CH3 COONa + HNO3 → CH3 COOH + NaNO3
Buffer combination
(IV) Acetic acid (weak acid) and sodium acetate (salt with strong base NaOH ) form a buffer
solution.
43. The atomic masses of He and Ne are 4 and 20 a.m.u., respectively. The value of the de Broglie
wavelength of He gas at −73∘ C is " M " times that of the de Broglie wavelength of Ne at 727∘ C. M
is
Ans. (5)
Sol. de Broglies's wavelength of a particle when kinetic energy (K.E) and mass (m) are given:
ℎ
𝜆=
√2𝐾. 𝐸𝑚
Given:
Mass of He atom (𝑚He ) = 4amu
Mass of Ne atom (mNe ) = 20amu
Temperature of He(THe ) = −73∘ C = 200 K
Temperature of Ne(TNe ) = +727∘ C = 1000 K
We know that:
K.E  T
𝐾. 𝐸He 𝑇He 200 1
= = =
𝐾. 𝐸Ne 𝑇Ne 1000 5
Now, ratio of de Broglies wavelengths of Ne and He(𝜆He , 𝜆Ne ) :
𝜆He √2 K ⋅ ENe mNe 5 20

= =√ × =5
𝜆Ne √2 K ⋅ EHe mHe 1 4
∴ 𝜆He = 5 × 𝜆Ne
So, value of 𝑀 is 5
APNI KAKSHA 20
44. Amongst the following,
KCN, K 2 SO4 , (NH4 )2 C2 O4 NaCl, Zn(NO3 )2 , FeCl3 , K 2 CO3 , NH4 NO3 , LiCN
The total number of compounds whose aqueous solution turns red litmus paper blue is.
Ans. (3)
Sol. Basic salt solutions will have a pH > 7. These will change the colour of litmus paper from red to
blue.
Here KCN, K 2 CO3 and LiCN are the only basic salts. So, the answer will be 3.
45. If the ionization enthalpy and electron gain enthalpy of an element are 275 and 86 kcal mol−1
respectively, then the electronegativity of the element on the Pauling scale is :
Ans. (2.8)
Sol. I.E. + E. A. = 275 + 86 = 361kcalmol−1
= 361 × 4.184 = 1510.42 kJ mol−1
1510.42
∴ Electronegativity = = 2.797 = 2.8
540
46. Total number of Boron atoms in anionic part of borax which participate in
Back bonding.
Ans. (2)
Sol. Borax : 2Na+ [B4 O5 (OH)4 ]2− ⋅ 8H2 O
𝑠𝑝2 -hybridized Boron atoms only participate in 𝑝𝜋 − 𝑝𝜋 back bonding.

47. How many degree of unsaturation are there the following compound?
Ans. (11)
Sol. The Degree of unsaturation defined by the double or triple bond present in the compound,
it can be in the form of C = X or C = C form, here (X = O, N)
So total unsaturation is 1 + 1 + 6 + 1 + 2 = 11 {from right to left}
APNI KAKSHA 21

TWO decimal places.
Paragraph-I
The hydrogen-like species Li2+ is in a spherically symmetric state S1 with one radial node.
Upon absorbing light the ion undergoes transition to a state S2 . The state S2 has one radial node
and its energy is equal to the ground state energy of the hydrogen atom.
48. Energy of the state S1 in units of the hydrogen atom ground state energy is
Ans. (2.25)
Sol. Energy 𝑆1 state
−13.6×32 9
𝐸= = − 4 13.6eV
22
𝐸(1𝐻1 ) = 13.6 eV [Ground state]
So,energy = 2.25 × energy of e− in ground state in 1 H1
49. The orbital angular momentum quantum number of the state S2 is
Ans. (1)
Sol. S2 state is 3p orbital.
Orbital angular momentum quantum number of 3p is 1.
APNI KAKSHA 22
Paragraph-II
Double bond equivalent is the level of unsaturation present in an organic compound.

Unsaturation is defined as the presence of double bond or triple bond in the organic molecule.
Ring is also considered in unsaturation. It is represented as DBE. Primary (1°), secondary (2°),
tertiary (3°) and quaternary (4°) alkyl carbons are defined according to the number of carbons
directly attached to that carbon. Similar nomenclature can be used for carbocations.
50. How many 2∘ carbon in the following ?
Ans. 21
Sol.
51.
Sum of types of functional group and DBE value for given compound is X so the value of X − 10
is
Ans. (7)
Sol.
7 F.G " " D.B.E "value" : 10𝑥 = 10 + 7 = 17, is 𝑥 − 10 = 7
APNI KAKSHA 23

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JEE ADVANCED PAPER – 2

CLASS 11th APNI KAKSHA STAR BATCH

TIME : 3 Hours Maximum Marks : 180

Solution Sheet Available Only for 24 Hours

SECTION - 1 (Maximum Marks : 12)

SECTION - 2 (Maximum Marks : 12)

SECTION - 3 (Maximum Marks : 24)

value of product ‘abcd’ be λ. Find the value of 10λ.

10. Sum of all real values of m for which the equation

11. If line ax + by −1 = 0 intercepted between lines ax + y + 1 = 0&x + by = 0 subtends 90∘ at

SECTION - 4 (Maximum Marks : 12)

Consider a hyperbola 𝑥𝑦 = 4 and a line 𝑦 + 2𝑥 = 4. Point 𝑂 is the centre of the hyperbola.

SECTION - 1 (Maximum Marks : 12)

(A) Acceleration of the box is 20 m/s2

(B) Kinetic energy as function of r is given by mgr

(c) Tension is central force on A, so angular momentum remains conserved.

SECTION - 2 (Maximum Marks : 12)

(A) The electric potential of the conductor is 1.8kV

So, option (A) is correct.

So, option (C) is also correct.

(B) Acceleration changes its direction between t1 = 0 and t 2 = 2

SECTION - 3 (Maximum Marks : 24)

Also, mvt ℓ0 = 2mv0 ℓ

v = √vt2 + vr2 = √5v0

Centre of mass does not move in x-direction as ΣFx = 0.

SECTION - 4 (Maximum Marks : 12)

SECTION - 1 (Maximum Marks : 12)

octahedral complex species [Al(OH)4 (H2 O)2 ]− in aqueous solution.

SECTION - 2 (Maximum Marks : 12)

(A) Atomic radius : F < O < F– < O2–

(B) 2nd ionisation energy : C < N < F < O

(C) Electron affinity : I < Br < F < Cl

(B) Ionisation energy  1  Effective nuclear charge

41. Which of the following order of stability of Intermediate are incorrect: -

(B) Correct order of stability

SECTION - 3 (Maximum Marks : 24)

𝜆He √2 K ⋅ ENe mNe 5 20

𝑠𝑝2 -hybridized Boron atoms only participate in 𝑝𝜋 − 𝑝𝜋 back bonding.

SECTION - 4 (Maximum Marks : 12)

Sol. Energy 𝑆1 state

𝐸(1𝐻1 ) = 13.6 eV [Ground state]

So,energy = 2.25 × energy of e− in ground state in 1 H1

49. The orbital angular momentum quantum number of the state S2 is

Sol. S2 state is 3p orbital.

Orbital angular momentum quantum number of 3p is 1.

Double bond equivalent is the level of unsaturation present in an organic compound.

50. How many 2∘ carbon in the following ?

7 F.G " " D.B.E "value" : 10𝑥 = 10 + 7 = 17, is 𝑥 − 10 = 7

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