18306apni Kaksha

JEE ADVANCED PAPER – 1
CLASS 11th APNI KAKSHA STAR BATCH
Time : 3 Hours Maximum Marks : 180

ANSWER KEY
&
SOLUTION WITH EXPLANATION
Solution Sheet Available Only for 24 Hours

PART – 1 : MATHEMATICS
SECTION - 1 (Maximum Marks : 12)

• This section contains THREE (03) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONE OR MORE THAN ONE of these four
option(s) is(are) correct answer(s).
• For each question, choose the option(s) corresponding to (all) the correct answer(s).
• Answer to each question will be evaluated according to the following marking scheme:
Full Marks : + 𝟒 ONLY if (all) the correct option(s) is(are) chosen;
Partial Marks : + 𝟑 If all the four options are correct but ONLY three options are chosen;
Partial Marks : + 𝟐 If three or more options are correct but ONLY two options are chosen,
both of which are correct;
Partial Marks : + 𝟏 If two or more options are correct but ONLY one option is chosen and it
is a correct option;
Zero Marks : 0 If none of the options is chosen (i.e. the question is unanswered);
Negative Marks : −𝟐 In all other cases.
1. Which of the following is/are correct

(A)(tanx)lnsinx > (cotx)lnsinx ∀ x ∈ (0, π/4)
(B) 4ln(cosecx) > 5ln(cosecx) ∀ x ∈ (0, π/2)
(C)(1/2)ln(cosx) < (1/3)ln(cosx) ∀ x ∈ (0, π/2)
(D) (1/2)ln(secx) > (1/3)ln(secx) ∀ x ∈ (0, π/2)
Ans. (A,C,D)
2. If the value of the product
(√3 + tan1∘ )(√3 + tan2∘ )(√3 + tan3∘ ) ⋯ ⋯ (√3 + tan29∘ ) is P then
(A) P is divisible by 3 (B)P is divisible by 2
(C)P is divisible by 220 (D) P is divisible by 315
Ans. (B,C)
APNI KAKSHA 1
x4 −6x3 −2x2 +18x+23
3. If ' y ' denotes the value of when x = √19 − 8√3 then which of the following is
x2 −8x+15
true
(A) y is odd prime (B) y 2 − y is divisible by 7
(C) y 2 − y is divisible by 10 (D) y is even number
Ans. (A,C)

• This section contains FOUR (04) questions.
• Each question has FOUR options (A), (B), (C) and (D). ONLY ONE of these four options is the
correct answer.
• For each question, choose the option corresponding to the correct answer.
Full Marks : +𝟑 If ONLY the correct option is chosen;
Negative Marks : −𝟏 In all other cases.
4. From a point 𝑃(0,5) on the circle 𝑥 2 + 𝑦 2 = 25 two equal chords 𝑃𝐴 and 𝑃𝐵 of length 8 units
are drawn. The equation of 𝐴𝐵 is
−7 −3 −7 −8
(A) 𝑦 = (B) 𝑦 = (C) 𝑦 = (D) 𝑦 =
3 5 5 5
Ans. (C)
5. Let a and b are positive integers such that a < b < 2009. If a, b and 2009 form a geometric
progression whose common ratio is an integer then the sum of digits of 𝑎 is
(A) 5 (B) 7 (C) 9 (D) 11
Ans. (A)
6. Let N = n(n + 1)(n + 2)(n + 3) and number of divisors of N is d, then ( n is a natural number)
(A) N is divisible by 24 and d is odd
(B) N is divisible by 24 and d can be odd
(C) N may not be divisible by 24
(D) d is even
Ans. (D)
7. If 𝑎𝑥 + 𝑦 − 16 = 0 and 𝑥 + 𝑎𝑦 − 6 = 0 represent two adjacent sides of a rhombus whose
diagonals intersect at (3,5) then sum of possible value of 𝑎 is
−9
(A) 4 (B) 2 (C) -2 (D) 4
Ans. (D)
APNI KAKSHA 2

• This section contains 𝐒𝐈𝐗(06) questions.
• The answer to each question is a NON-NEGATIVE INTEGER.
• For each question, enter the correct integer corresponding to the answer using the mouse and
the on-screen virtual numeric keypad in the place designated to enter the answer.
Full Marks : +𝟒 If ONLY the correct integer is entered;
Zero Marks : 𝟎 In all other cases.
8. Let N = (1 + cot 7∘ )(1 + cot 9∘ )(1 + cot 11∘ ) … (1 + cot 45∘ )(1 − cot 52∘ )(1 − cot 54∘ ) …
(1 − cot 88∘ ).
N
ln
Then the value of | 1024
| is
ln4
Ans. 5
9. Let α and β be roots of x 2 − 3x + 5 = 0. If Sn = αn−1 + αn−2 β + αn−3 β2 + ⋯ . +αβn−2 + βn−1 for
S2018 +5 S2016
n ≥ 1, then the value of is equal to:
S2017
Ans. 3
10. If P(x) is a polynomial of degree four with leading coefficient one such that
P(1) = 2, P(2) = 6, P(3) = 12, P(4) = 20. Also P(x) = 0 has roots α, β, γ and δ. Then the value
of |(α + 3)(β + 3)(γ + 3)(δ + 3) − 846| is :
Ans. 0
nπ
11. If 2tan2 x − 5secx is equal to 1 for exactly 7 distinct real values of x , x ∈ [0, ], n ∈ N. Then the
2
greatest value of n is
Ans. 𝟏𝟓
12. If one of the diameters of the circle x 2 + y 2 − 2x − 6y + 6 = 0 is a chord of another circle ' C ',
whose center is at (2,1), then its radius is
Ans. 3
13. If the area of the triangle formed by the x-axis, the normal and the tangent to the circle
(x − 2)2 + (y − 3)2 = 25 at the point (5,7) is A, then 24A is equal to
Ans. 1225
APNI KAKSHA 3

• This section contains FOUR (04) Matching List Sets.
• Each set has ONE Multiple Choice Question.
• Each set has TWO lists: List-I and List-II.
• List-I has Four entries (A), (B), (C) and (D) and List-II has Five entries (P), (Q), (R), (S) and (T).
• FOUR options are given in each Multiple Choice Question based on List-I and List-II and ONLY
ONE of these four options satisfies the condition asked in the Multiple Choice Question.
Answer to each question will be evaluated according to the following marking scheme:
Full Marks : +3 ONLY if the option corresponding to the correct combination is
chosen;
14. Match the following

Column-I Column-II
(A) If x 2 + ax + b = 0 has roots α, β and (P) (1 − bq)2 = (a − pb)(p − aq)
x 2 + px + q = 0 has roots −α , γ, then
(B) If x 2 + ax + b = 0 has roots α , β and (Q) (4 − bq)2 = (4a + 2pb)(−2p − aq)
x 2 + px + q = 0 has roots 1/α , γ, then
(C) If x 2 + ax + b = 0 has roots α , β and (R) (1 − 4bq)2 = (a + 2bp)(−2p − 4aq)
x 2 + px + q = 0 has roots −2/α , γ, then
(D) If x 2 + ax + b = 0 has roots α , β and (S) (q − b)2 = (aq + bp)(−p − a)
−1
x 2 + px + q = 0 has roots 2α , γ, then (T) None
(A) (A) → (P), (B) → (S), (C) → (R), (D) → (Q)
(B)(A) → (S), (B) → (P), (C) → (R), (D) → (Q)
(C)(A) → (S), (B) → (P), (C) → (Q), (D) → (R)
(D)(A) → (P), (B) → (S), (C) → (Q), (D) → (R)
Ans. (C)
APNI KAKSHA 4
15.
Column-I Column-II
(A) If the sum of the first 2n terms of (P) 10
2 ,5 , 8, … is equal to the sum of the first
n terms of 57, 59, 61, … then n =
(B) The equation sin2 θ + cosθ + 12 = n has (Q) 11
two solutions in interval [0 , π] for
n , (n ∈ I) =
(C) If 2, a1 , a2 , a3 , … . a12 , 6 are in A.P. and (R) 12
2, h1 , h2 , h3 , … , h12 , 6 are in H.P. then
h3 a10 =
(D) If ∑nk=1 ∑kj=1 ∑j 2 = 572, then n − 1 = (S) 13
i=1
(T) 14
(A) (A) → (Q) ; (B) → (S) ; (C) → (R) ; (D) → (P)

(B) (A) → (S) ; (B) → (Q) ; (C) → (R) ; (D) → (P)
(C) (A) → (Q) ; (B) → (R) ; (C) → (S) ; (D) → (P)
(D) (A) → (Q) ; (B) → (S) ; (C) → (P) ; (D) → (R)
Ans (A)
16. Column-I Column-II

1
(A) If sinθ = 3sin(θ + 2α), then the value of tan(θ + α) + 2tanα = (P) − 4
p+a q−b 1
(B) If psinθ + qcosθ = a and pcosθ − qsinθ = b , then q+b + p−a + 1 = (Q) − 2
(C) The value of expression (R) 0

π 2π 10π π 3π 5π
cos cos cos − sin sin sin =
7 7 7 14 14 14
(D) The value of one root of the equation (S) 1
4(a + c − 2b)x 2 − 2(b + a − 2c)x + (c + b − 2a) = 0
(T) –2
(A) (A) → (R) ; (B) → (S) ; (C) → (Q) ; (D) → (P)
(B) (A) → (S) ; (B) → (R) ; (C) → (P) ; (D) → (Q)
(C) (A) → (R) ; (B) → (S) ; (C) → (P) ; (D) → (Q)
(D) (A) → (S) ; (B) → (R) ; (C) → (Q) ; (D) → (P)
Ans. (C)
APNI KAKSHA 5
17. Answer the following by appropriately matching the lists based on the information given in the
paragraph.
Let L(n, r) denotes the number of ways to select ' 𝑟 ' objects from ' n ' distinct objects placed in
a row, such that no two of the selected objects were consecutive, and let R (n, r) denotes the
number of ways to select ' 𝑟 ' objects from ' 𝑛 ' distinct objects placed on a circle, such that no
two of the selected objects were consecutive.
List-I List-II
(I) R(12,4) + L(8,2) = (P) 91
(II) R(14,5) + L(10,3) = (Q) 35
(III) L(10,4) = (R)252
(IV) R(13,5) = (S) 126
Which of the following is correct:

(A) I → (S), II → (R), III → (Q), IV → (P)
(B) I → (R), II → (S), III → (Q), IV → (P)
(C) I → (P), II → (R), III → (S), IV → (P)
(D) I → (S), II → (P), III → (Q), IV → (R)
Ans. (A)
APNI KAKSHA 6
PART – 2 : PHYSICS

18. Two long blocks m = 1 kg and M = 3 kg are placed as shown. The coefficient of friction
between the blocks is μ2 = 0.8 and between the floor and M is μ1 = 0.1. Initially M is at rest and
m is given a speed u = 28 m/s. Which of the following is/are correct?
(A) Mechanical energy dissipated out of the system of (m + M) due to friction at ground is 392 J
(B) Total work done by friction on m due to M is −392 J
(C) Total work done by friction applied by m on M is 56 J
(D) Mechanical energy dissipated out of the system of (m + M) due to friction between the
block is six time the loss due to friction at ground
Ans: (B, C, D)
Sol: Friction on m is 8 N left for t = 0 to t = 3 and during this time m will travel 48 m to right and
reach a speed of 4 m/s. During the same interval M will have a friction of 8 N on top towards
right and friction of 4 N to left from ground. It will travel 6 m to right and reach the same
common speed of 4 m/s. From t = 3 to t = 7 both blocks move together with friction between
becoming static at a value of 1 N. They travel an addition 8 m to right.
Work down by friction on m = (−8 × 48) + (−1 × 8) = −392 J
Work down by friction on M due to m = (8 × 6) + (1 × 8) = 56 J
Work down by ground friction on M = [−4 × (6 + 8)] = −56 J
APNI KAKSHA 7
19. A projectile is fired on a horizontal ground. Coefficient of restitution between the projectile and
T H
the ground is e. Let a, b and c be the ratio of time of flight (T1 ), maximum height (H1) and
2 2
R
horizontal range (R1 ) in first two collisions with the ground, then
2
1 1
(A) a = e (B) b = e2
1
(C) c = a2 (D) All of these
Ans: (𝐀, 𝐁)
Sol: In collision horizontal component vx remains unchanged while the vertical component uy now
2 usin θ 2uy
T= =
g g
T ∝ uy
T1 1
∴ =
T2 e
u2 sin2 θ u2y H1 1
H= = ∝ u2y ∴ = 2
2g 2g H2 e
u2 sin 2θ 2ux uy R1 1
R= = ∝y ∴ =
g g R2 e
20. A solid sphere of mass m is released on the plank of mass M which lies on an inclined plane of
inclination θ shown in figure. There is sufficient frictional force between sphere and plank and
the minimum value of co-efficient of friction between plank and surfaces is μ to keep the plank
at rest. Then
2
(A) Frictional force between sphere and plank is 7 mgsin θ, when plank is at rest.
7M+2m
(B) The value of μ is 7(M+m) tan θ
(C) If there is no friction between the plank and inclined plane, then acceleration of plank is
less than gsin θ
(D) If there is no friction between plank and inclined plane, then friction force on the sphere is
zero.
Ans: (A, B, D)
APNI KAKSHA 8
Sol.
Use force and torque equation for m and M.

Also use no slip condition

correct answer.
21. A small block of mass 1 kg is released from rest at the top of rough track. The track is circular
arc of radius 40 m. The block slides along the track without toppling and a frictional force acts
on it in the direction opposite to the instantaneous velocity. The work done in overcoming the
friction up to the point Q, as shown in the figure below, is 150 J.
(Take the acceleration due to gravity, g = 10 m/s−1 ).
The speed of the block when it reaches the point Q is

(A) 5 ms−1
(B) 10 ms −1
(C) 10√3 ms −1
(D) 20 ms −1
Ans: (B)
APNI KAKSHA 9
Sol: Using work energy theorem
1
mgRsin 30∘ + Wf = mv 2
2
v2
200 − 150 =
2
⇒ v = 10 m/s
22. A bead of mass m is sliding down the fixed inclined rod without friction. It is connected at a
point P on the horizontal surface with a light spring of spring constant k. The bead is initially
released form rest and the spring is initially unstressed and vertical. The bead just stops at the
bottom of the inclined rod. Find the angle which the inclined rod makes with horizontal.
2mg 2mg
(A) cot −1 (1 + √ ) (B) tan−1 (1 + √ kh )
kh
mg mg
(C) cot −1 (1 + √ kh ) (D) tan−1 (1 + √ kh )
Ans: (A)
Sol: Loss in gravitational P.E = gain in spring P.E
1 2mg
mgh = k(hcot α − h)2 or (cot α − 1) = √
2 kh
2mg
cot α = 1 + √
kh
23. A series of n identical balls is shown on a smooth horizontal surface. If number 1 moves
horizontally with speed u into number 2, which in turn collides with number 3 etc... and the
coefficient of restitution for each impact is e, determine the speed of the nth ball
(1+e)n−1 u (1+e)n u
(A) (B)
2n−1 2n
(1+e)n+1 u (1−e)n u
(C) (D)
2n+1 2n
Ans: (A)
APNI KAKSHA 10
Sol: Series of n identical ball, ball 1 collides with ball 2 with u, e
Mu = mv1 + mv2
eu = v2 − v1
v2 − v1
e=
u
u
(1 + e) = v2
2
u
v2 = (1 + e)
2
v2 (1 + e) (1 + e)u (1 + e)2
v3 = (1 + e) = =
2 2 2 22
(1 + e)n−1 u
vn =
2n−1
24. Three blocks are placed in contact on a horizontal frictionless surface. A constant force of 18 N
is applied to m1 . The coefficient of static friction between m2 and m3 is μs = 0.51. All three
blocks accelerate together to the right. What is the magnitude of friction force exerted by m2 on
m3 ?
(A) 9 N (B) 12 N (C) 4 N (D) 7 N

Ans: (A)
Sol:
Newton's 2nd Law

F − N = m1 a
N − Ff = m2 a
Ff = m3 a
Ff = 9 N; a = 3 m/s2
APNI KAKSHA 11

25. A block (B) is attached to two unstretched springs S1 and S2 with spring constants k and 4k,
respectively (see figure I). The other ends are attached to identical supports M1 and M2 not
attached to the walls. The springs and supports have negligible mass. There is no friction
anywhere. The block B is displaced towards wall 1 by a small distance x (figure II) and released.
The block returns and moves a maximum distance y towards wall 2. Displacements x and y are
x
measured with respect to the equilibrium position of the block B. The ratio y is
Ans: 2
1 1 x
Sol: kx 2 = 4ky 2 ⇒ y =
2 2 2
26. A movable sledge consists of a smooth track joined to a smooth circular track of radius
R = 56 cm. The entire sledge is moving with a constant acceleration starting from rest as
shown in the figure and initially a point mass P is placed on the sledge at a distance 2R from the
bottom of the circular track. Then what minimum initial horizontal speed should be given to
the point mass P such that it will reach the top most point on the circular track? [Take gravity
as 10 m/s2 ]
Ans: 7.00
APNI KAKSHA 12
Sol. Calculate the effective of weight and pseudo force in the sledge frame.
The critical point with minimum normal reaction will be a point with a radial vector making an
angle of 37∘ with the vertical.
27. A solid cylinder of diameter D is resting on a rough horizontal surface as shown in the figure. It
exerts a total normal force F uniformly distributed over it's base area. The friction coefficient is
μ and if the twisting torque that must be exerted by an external agent to cause rotary motion to
μFD
impend (about its symmetry axis) is . The value of k is
k
Ans: 3
Sol: Consider a small element of radius r and width dr.
F
Normal reaction dF = π × 2πrdr
D2
4
Frictional force dFf = μdF

Frictional moment dM = rdFf = rμdF
D/2 4F
Total moment M = ∫ dM = ∫0 rμ × πD2 × 2πrdr
4F (D/2)3
= × μ × 2π ×
πD2 3
μFD
M=
3
APNI KAKSHA 13
28. A uniform rod has mass m = 2 kg and length ℓ = 13 m. One end of the rod is pulled with a
constant velocity of v0 = 34 m/s along a frictionless horizontal floor in the negative x direction.
The other end is moving along a parabolic fixed curve. The equation of the parabola is x 2 =
20y. Find the angular velocity of the rod ( in rad/s) when the end point 'B' is at (10,5)
Ans: 2
V0 34
Sol: r0 = 17 ⇒ ω = = 17 = 2rad/s
r0
29. A rod of mass m and length L(= 50/3 m) is hinged on a plank of same mass m. The plank is
kept on a smooth horizontal surface and rod makes an angle θ with the vertical. The system is
released from θ = 0∘ . If the velocity (in m/s ) of plank when the rod makes θ = 180∘ (g =
n
10 m/s 2 ) is 'n'. Find 2.
Ans: 5
Sol: Use linear momentum conservation in x-direction combined with energy equation.
30. Two identical uniform discs roll without slipping on two different surfaces AB and CD (see
figure) starting at A C with linear speeds v1 and v2 , respectively, and always remain in contact
with the surfaces. If they reach B and D with the same linear speed v1 = 3 m/s, then v2 in m/s
is (g = 10 m/s 2 )
Ans: 7
1 1
Sol: mgh = 2 mv 2 + 2 Icm w 2 … (1)
V = Rω … (2)
APNI KAKSHA 14

chosen;
31. A block A of mass m kg lies on block B of same mass. B in turn lies on smooth horizontal plane.
The coefficient between A and B is μ. Both the blocks are initially at rest. A horizontal force F is
applied to upper block A at t = 0 such that there is relative motion between A and B. If the
duration from t = 0 second till the lower block B undergoes a displacement of magnitude L is
large enough, match the statements in Column-I with results in Column-II.
Column - I Column - II
(A) Work done by friction force on block A is (P) Positive
(B) Work done by friction force on block B is (Q) Negative
(C) Work done by friction on block A plus work (R) More than μmgL in magnitude
done by friction on block B is
(D) Work done by force F on block A is (S) Equal to μmgL in magnitude
(A) A - QR; B - S; C - Q; D - PR
(B) A - QR; B - PS; C - Q; D – PR
(C) A - P; B - Q; C - P; D – S
(D) A - R; B - P; C - P; D - Q
Ans: (B)
APNI KAKSHA 15
32. Configuration of L shaped block and two other blocks are shown. System is set free to move. At
any moment, match the following parameters. (g = 10 m/s2 )
(A) Friction force between block A and B (P) 50 N
(B) Tension in string (Q) 70 N
(C) Normal reaction on block A by block B (R) 20 N
(D) Normal reaction on block B by table (S) 10 N
(A) A - Q; B - S; C - P; D - R
(B) A - S; B - P; C - R; D – Q
(C) A - P; B - Q; C - S; D – R
(D) A - R; B - Q; C - P; D - S
Ans: (B)
Sol: Use the principle of conservation of energy and force equation for vertical circular motion.
33. A bob of mass 2 kg is suspended from a vehicle by a rope of length ℓ = 5 m, the vehicle and the
bob are moving at a constant speed v0 . The vehicle is suddenly stopped by a bumper and the
bob swings out a maximum angle of 60∘ . Match the following:
APNI KAKSHA 16
(A) Net force acting on the bob at lowest point just (P) 5√3 vehicle is stopped
after the hitting
(B) Acceleration of the bob at lowest point (Q) 10
(C) Net force acting on the bob at its highest point (R) 20
(D) Acceleration of the bob at its highest point (S) 10√3
The correct option is:
(A) A - R; B - Q; C - S; D - P (B) A - Q; B - P; C - S; D – R
(C) A - S; B - R; C - P; D - Q (D) A - P; B - S; C - R; D - Q
Ans: (D)
Sol: Conceptual
34. A uniform disc of radius r and mass m is at rest inside a cylindrical room of radius R with its flat
surface lying on the floor of room and its periphery just touching the wall of the room. Figure
shows the top view of the room and disc. There is no friction between floor and disc. The
friction coefficient between wall and disc is μ. The disc is given an impulse, which imparts a
velocity V0 to its centre of mass, tangential to wall of room and initial angular velocity is zero.
Given that V0 = 20 m/s, m = 2 kg, μ = 0.5, R = 5 m and r = 1 m and g = 10 m/s2 . Which of the
following is correct?
Column-I Column-II
(A) The time at which disc starts pure rolling is (P) 40
3
(B) The speed of centre of mass of disc when it starts pure (Q) 4
rolling is 20
(C) The angular velocity of disc about its centre after it (R) 800
starts pure rolling is 9
(D) Normal force acting on the disc when it starts pure (S) 820
rolling is 9
(T) 10
3
APNI KAKSHA 17
(A) A − P, B − P, C − Q, D − S
(B) A - Q, B - P, C - P, D – S
(C) A - Q, B - S, C - P, D – P
(D) A - S, B - Q, C - P, D - P
Ans: (B)
Sol: Let V be the speed of disc at any instant
mV 2
N=
(R − r)
μmV 2 dv μmV 2 μ
f = μN = −m = − ∫ V 2 dv = ∫ dt
(R − r) dt (R − r) R−r
1 v μ
| = t
V v0 R − r
1 1 μt
− =
V V0 (R − r)
(R − r)V0 dv μv 2
or V(t) = − =
(R − r) + μtV0 dt R − r
mr2 mrα
fr = α or μN =
2 2
rω
mV 2 dω dv r r ω
or 2μ = mrα = mr − = − ∫ dv = ∫ dω
(R − r) dt dω 2 v0 2 0
When pure rolling starts say at t = t 0
V = rω
(R−r)
(A) ⇒ t 0 = 2rμV
0
(R−r)V0
(B) V(t=t0) = (R−r)+μt
0 V0
V
(C) ω = r
(D) N0 = √N12 + N22
APNI KAKSHA 18
PART – 3 : CHEMISTRY

35. For the reaction; PCl5 ( g) PCl3 ( g) + Cl2 ( g) The forward reaction at constant temperature
is favoured by:
(A) Introducing an inert gas at constant volume
(B) Introducing chlorine gas at constant volume
(C) Introducing an inert gas at constant pressure
(D) Increasing the volume of the container
Ans. (C,D)
Sol. C. Adding inert gas at constant pressure increases the overall volume, reduces the
concentration of all reactants, changing the partial pressure. The system tries to undo that
change and to increase the concentration goes in the direction where moles increase, which is
the forward direction in this case
D. This has a similar effect as adding an inert gas at constant volume. The concentration
decreases, decreasing the partial pressure, the reaction moves forward to increase the number
of moles.
APNI KAKSHA 19
36. The IUPAC name(s) of the following compound is(are):
(A) 4-chlorotoluene (B) 4-methylchlorobenzene

(C) 1-chloro-4-methylbenzene (D) 1-methyl-4-chlorobenzene
Ans. AC
Sol. IUPAC name is 1 - chloro - 4 – methylbenzene
It can be also written as 4-chlorotoluene
37. Identify the binary mixture (s) that can be separated into individual compounds, by differential
extraction, as shown in the given scheme.
(A) C6H5OH and C6H5COOH (B) C6H5COOH and C6H5CH2OH

(C) C6H5CH2OH and C6H5OH (D) C6H5CH2OH and C6H5CH2COOH
Ans. (B,D)
Sol. The correct options are
B C6 H5 COOH and C6 H5 CH2 OH
D C6 H5 CH2 OH and C6 H5 CH2 COOH
For separation by differential extraction one of the component must form salt with the given
base so that the salt will be extracted in aqueous layer leaving other component in organic
layer.
(a) Both phenol and benzoic acid forms salt with NaOH, hence this mixture can't be separated.
(b) Benzoic acid forms salt with NaOH while benzyl alcohol does not, hence the mixture can be
separated using NaOH. Also benzoic acid forms salt with NaHCO3 but benzyl alcohol does not,
hence NaHCO3 can be used for separation.
(c) Neither benzyl alcohol nor phenol forms salt with NaHCO3 , mixture cannot be separated
using NaHCO3 .
(d) C6 H5 CH2 COOH forms salt with NaOH, C6 H5 CH2 OH does not, hence mixture can be
separated using NaOH. C6 H5 CH2 COOH forms salt with NaHCO3 . C6 H5 CH2 OH does not, hence
mixture can be separated using NaHCO3 .
APNI KAKSHA 20

correct answer.
38. If the distribution of molecular speeds of gas is as per the figure shown below, then the ratio of
the most probable, the average, and the root mean square speeds, respectively, is
(a) 1: 1: 1 (b) 1: 1: 1.224 (c) 1: 1.128: 1.224 (d) 1: 1.128: 1
Ans. (b)
Sol. As a symmetrical graph is given, the average value of speed will be the middle symmetrical
speed which is also the most probable speed.
When we are calculating the rms speed we have to take the average of square of speeds and its
root. In square of speed, higher speeds will give more contribution so the value will be more
than the average value.
39. In which of the following species maximum atom can lie in same plane?
(A) XeF2O2 (B) PCl5
+
(C) AsH4 (D) XeF4
Ans. (D)
APNI KAKSHA 21
Sol.
Maximum atoms that → 3 4 3 5
can lie in a plane
40. Which one of the following structures has the IUPAC name 3-ethynyl-2hydroxy-4-methylhex-3-
en-5-ynoic acid?
(A) (B)
(C) (D)
Ans. (D)
Sol. 3-ethynyl-2-hydroxy-4-methylhex-3-en-5-ynoic acid
41. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [ a0 is Bohr
radius]
h2 h2 h2 h2
(A) 4π2ma2 (B) 16π2ma2 (C) 32π2ma2 (D) 64π2ma2
0 0 0 0
Ans. (C)
h2
The correct option is C 32π2 ma2
0
According to Bohr's model,
nh n2 h2 1 n2 h2
mvr = 2π ⇒ (mv)2 = 4π2 r2 ⇒ K.E. = 2 mv 2 = 8π2r2 m
Also, Bohr's radius for H-atom is, r = n2 a0

Substituting ' r ' in Eq. (i) gives
h2 h2
K.E. = when n = 2, K. E. =
8π2 n2 a20 m 32π2 a20 m
APNI KAKSHA 22

42. Mole fraction of urea in 900 gram water is 0.05 . Density of Solution is 1.2 g/cm3 . Find molarity
of Solution. (Nearest integer)
Ans. 3
Sol. Number of moles of H2 O = 900/18 = 50
n1 /(n1 + 50) = 0.05 ( n1 is No. of moles of urea)
⇒ n1 = 2.63
Weight of urea = 2.63 × 60 = 157.8 g
Total weight = 157.8 + 900 = 1057.8 g
Volume = 1057.8/1.2 = 881.5 cm3
Molarity = 2.63/0.8 = 2.99
43. The total number of contributing structures showing hyperconjugation (involving C − H bonds)
for the following carbocation is
Ans. (6)
Sol. Number of a − H ∝ Number of hyperconjugative structures
The given carbocation has 6 -H. Therefore, total 6 contributing structures showing
hyperconjugation are possible for the given carbocation.
APNI KAKSHA 23
44. The volume (in mL ) of 0.1MAgNO3 required for complete precipitation of chloride ions present
in 30 mL of 0.01M solution of [Cr(H2 O)5 Cl− Cl2, as silver chloride is close to
Ans. (6)
Sol. m mol of the complex = 30 × 0.01 = 0.3mmol
[Cr(H2 O)5 Cl− Cl2 → [Cr(H2 O)5 Cl2+ + 2Cl−
∵ 1 mole of the complex gives two moles of chloride ions when dissolved in a solution.
∴ 0.3m mol of complex produces 0.6mmol of Cl− .
Hence, 0.6mmol of Ag + would be required for precipitation.
0.6
Volume of AgNO3 required = 0.1 = 6 Ml
45. H2 S (5 moles) reacts completely with acidified aqueous potassium permanganate solution. In
this reaction, the number of moles of water produced is 𝐱, and the number of moles of electrons
involved is 𝐲. The value of (x + y) is
(Hint: KMnO4 + H2 SO4 + H2 S → K 2 SO4 + MnSO4 + S + H2 O
Ans. (18)
H+
Sol. KMnO4 → Mn+2
0
S −2 ⟶ S ∴ nfactor of KMnO4 = 5
nfactor of S −2 (H2 S) = 2
(nKMnO4 × 5) = (5 × 2)H2 S
[(GEN)KMnO4 = (GEP)H2 S ] ∴ nKMnO4 = 2
∴ 2KMnO4 + 3H2 SO4 + 5H2 S → K 2 SO4 + 2MnSO4 + 5 S + 8H2 O
Number of moles of water produced = ' 8 '
Number of moles of electrons involved = 10
∴ x = 8, y = 10 ⇒ (x + y) = 18
APNI KAKSHA 24
46. A gas has a compressibility factor of 0.5 and a molar volume of 0.4dm3 mol−1 at a temperature
of 800 K and pressure 𝐱 atm. If it shows ideal gas behaviour at the same temperature and
pressure, the molar volume will be 𝐲dm3 mol−1 . The value of 𝐱/𝐲 is
[Use: Gas constant, R = 8 × 10−2 L atm K −1 mol−1 ]
Ans. 100
V
Sol. Compressibility factor (Z) = V real = 0.5
ideal
Vreal = 0.4dm3 mol−1 = 0.4 L/mol

0.4
∴ Videal = = 0.8 L/mol
0.5
∴ y = 0.8 L/mol
Using ideal gas equation : PV = nRT
1 × 8 × 10−2 × 800
P=
0.8
x = 80 atm
x 80
∴ = = 100
y 0.8
47. For the following reaction, equilibrium constant K C at 298 K is 1.6 × 1017 .
Fe2+ 2−
(aq) + S(aq) ⇌ FeS(s)
When equal volume of 0.06MFe+2 and 0.2Ms−2 solution are mixed, then equilibrium
concentration of Fe+2 is found to be Y × 10−17 M. Y is: (Nearest integer)
Ans. 9
Sol. Fe2+ + S 2− → FeS
Ini 0.06 0.2 0
After mix 0.03 0.1
At 0q/m x 0.07
1
K C = (x)[0.07] = 1.6 × 1017
∴ [Fe2+ ] = 8.928 × 10−17

= y × 10−17
∴ y = 8.93 or 8.92
APNI KAKSHA 25

chosen;

(A) CO, CN− , NO+ , O2+
2 (P) All are paramagnetic
(B) N2+ , O+ −
2 , O2 , NO (Q) All are diamagnetic
(C) NO− , N22+ , C2 , B22− (R) All have intermixing of s and p-orbitals
(D) CN, C2+ , B2+ , N2− (S) All have same bond order
(T) All have fractional bond order
(A) A → Q,R; B→S, T; C → R, S;D→Q, R, T
(B) A → Q, S; B → P, T; C → R, S; D→P, R, T
(C) A → Q, T; B → R, T; C→ Q,S ; D → P, R,T
(D) A → Q, S ; B → R, T; C → Q, S ; D→S,T.
Ans. (B)
Sol. M.O. configuration for molecules having total number electron less or equal to 14
For molecules having total number of e− s greater than 14
APNI KAKSHA 26
Total No. No. of unpaired e−s and Mixing of s

S. Bond
species of lieff and
No. order
e− s unpaired e− s and lieff p-orbitals
a CO 14 diamagnetic Yes 3.0
CN − 14 diamagnetic Yes 3.0
NO+ 14 diamagnetic Yes 3.0
O2+
2 14 diamagnetic No 3.0
b N2+ 13 paramagnetic Yes 2.5
O+
2 15 paramagnetic No 2.5
O−
2 17 paramagnetic No 1.5
NO 15 paramagnetic Yes 2.5
c NO− 16 paramagnetic Yes 2.0
N22+ 13 diamagnetic Yes 2.0
C2
12 diamagnetic Yes 2.0
B22− 12 Yes 2.0
d CN 13 paramagnetic Yes 2.5
C2+ 11 paramagnetic Yes 1.5
B2+ 9 paramagnetic Yes 0.5
N2− 15 paramagnetic Yes 2.5
APNI KAKSHA 27
(A) Hypo phosphoric acid (P) All hydrogen are ionizable in water
(B) Pyro phosphoric acid (Q) Lewis acid
(C) Boric acid (R) Monobasic in water
(D) Hypo phosphorus acid (S) sp3 hybridized central atom
(A) A → P, Q, S; B → P, Q, S; C → Q, R; D → Q, R,S
(B) A → Q,S;B → P,Q; C → R,S; D →P,R,S
(C) A → P, R, S ; B → Q, S; C → P,R; D → Q, R, S
(D) A → P,Q,S ; B → S,Q ; C → P,R ; D → R,S
Ans. (A)
Sol. (A) Hypophosphoric acid (H4P2O6) (P)
(B) Pyrophosphoric acid (H4P2O5) (Q)
[B(OH )4 ]
−
(C) Boric acid (H3BO3) (R) H3BO3 + OH
(L.B.) (L.B.) borate ion
(D) Hypophosphorus acid (H3PO2) (S)
APNI KAKSHA 28
50. Match List-I with List-II.
LIST - I LIST - II
(P) (I) Spiro
compound
(Q) (II) Aromatic
compound
(R) (III) Non-planar
Heterocyclic
compound
(S) (IV) Bicyclo
compound
Choose the correct answer from the options given below :

(A) (P) − (II), (Q) − (I), (R) − (IV), (S) − (III)
(B) (P) − (IV), (Q) − (III), (R) − (I), (S) − (II)
(C) (P) − (III), (Q) − (IV), (R) − (I), (S) − (II)
(D) (P) − (IV),(Q) − (III),(R) − (II),(S) − (I)
Ans. (C)
APNI KAKSHA 29
51. Column (I) Column (II)
(a) (p) 1-butyl-4-methyl cyclohexane
(b) (q) 2-bromo-1,1-dichloro cyclohexane
(c) (r) 1-Bromo-1,2-dichloro cyclohexane
(d) (s) Ethyl-2-formyl cyclohexane carboxylate
(A) a − q; b − s; c − p; d − r
(B) a − q; b − p; c − s; d − r
(C) a − p; b − q; c − s; d − r
(D) a − q; b − p; c − r; d − s
Ans. (B) 𝐚 − 𝐪; 𝐛 − 𝐩; 𝐜 − 𝐬; 𝐝 − 𝐫
Sol.
Ethyl -2- formyl cyclohexane carboxylate
1-bromo l, 2- dichloro cyclohexane
2-Bromo 1,1 dicholo cyclohexance
Butyl 4-methyl cyclohexane.
APNI KAKSHA 30

18306apni Kaksha

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JEE ADVANCED PAPER – 1

CLASS 11th APNI KAKSHA STAR BATCH

Time : 3 Hours Maximum Marks : 180

Solution Sheet Available Only for 24 Hours

SECTION - 1 (Maximum Marks : 12)

1. Which of the following is/are correct

SECTION - 2 (Maximum Marks : 12)

SECTION - 3 (Maximum Marks : 24)

SECTION - 4 (Maximum Marks : 12)

14. Match the following

(A) (A) → (Q) ; (B) → (S) ; (C) → (R) ; (D) → (P)

16. Column-I Column-II

(C) The value of expression (R) 0

Which of the following is correct:

SECTION - 1 (Maximum Marks : 12)

Use force and torque equation for m and M.

SECTION - 2 (Maximum Marks : 12)

The speed of the block when it reaches the point Q is

(A) 9 N (B) 12 N (C) 4 N (D) 7 N

Newton's 2nd Law

SECTION - 3 (Maximum Marks : 24)

Frictional force dFf = μdF

SECTION - 4 (Maximum Marks : 12)

(A) Work done by friction force on block A is (P) Positive

(B) Work done by friction force on block B is (Q) Negative

done by friction on block B is

(D) Work done by force F on block A is (S) Equal to μmgL in magnitude

(A) Friction force between block A and B (P) 50 N

(B) Tension in string (Q) 70 N

(C) Normal reaction on block A by block B (R) 20 N

(D) Normal reaction on block B by table (S) 10 N

(D) N0 = √N12 + N22

SECTION - 1 (Maximum Marks : 12)

(A) 4-chlorotoluene (B) 4-methylchlorobenzene

(A) C6H5OH and C6H5COOH (B) C6H5COOH and C6H5CH2OH

SECTION - 2 (Maximum Marks : 12)

(a) 1: 1: 1 (b) 1: 1: 1.224 (c) 1: 1.128: 1.224 (d) 1: 1.128: 1

(A) XeF2O2 (B) PCl5

Maximum atoms that → 3 4 3 5

can lie in a plane

According to Bohr's model,

Also, Bohr's radius for H-atom is, r = n2 a0

SECTION - 3 (Maximum Marks : 24)

Sol. m mol of the complex = 30 × 0.01 = 0.3mmol

[Cr(H2 O)5 Cl− Cl2 → [Cr(H2 O)5 Cl2+ + 2Cl−

∴ 0.3m mol of complex produces 0.6mmol of Cl− .

Hence, 0.6mmol of Ag + would be required for precipitation.

(Hint: KMnO4 + H2 SO4 + H2 S → K 2 SO4 + MnSO4 + S + H2 O

[(GEN)KMnO4 = (GEP)H2 S ] ∴ nKMnO4 = 2

∴ 2KMnO4 + 3H2 SO4 + 5H2 S → K 2 SO4 + 2MnSO4 + 5 S + 8H2 O

Number of moles of water produced = ' 8 '

Number of moles of electrons involved = 10

Vreal = 0.4dm3 mol−1 = 0.4 L/mol

Ini 0.06 0.2 0

After mix 0.03 0.1

∴ [Fe2+ ] = 8.928 × 10−17

SECTION - 4 (Maximum Marks : 12)

48. Column-I Column-II

For molecules having total number of e− s greater than 14

Total No. No. of unpaired e−s and Mixing of s

a CO 14 diamagnetic Yes 3.0

CN − 14 diamagnetic Yes 3.0