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Propane - Wikipedia
Propane - Wikipedia
Propane
From Wikipedia, the free encyclopedia
Names
Contents Preferred IUPAC name
Propane[1]
1 History
2 Sources Systematic IUPAC name
3 Properties and reactions Tricarbane (never recommended[1])
3.1 Energy content Identifiers
3.2 Density
4 Uses CAS Number 74986 (http://www.commonc
4.1 Domestic and industrial fuel hemistry.org/ChemicalDetail.as
4.2 Refrigeration px?ref=74986)
4.2.1 In motor vehicles
3D model (Jmol) Interactive image (http://chema
4.3 Motor fuel
4.4 Improvised explosive devices pps.stolaf.edu/jmol/jmol.php?m
4.5 Other uses odel=CCC)
5 Hazards Beilstein Reference 1730718
6 Comparison with natural gas
ChEBI CHEBI:32879 (https://www.eb
7 Retail cost
7.1 United States i.ac.uk/chebi/searchId.do?chebi
8 See also Id=32879)
9 References ChEMBL ChEMBL135416 (https://www.
10 External links
ebi.ac.uk/chembldb/index.php/c
ompound/inspect/ChEMBL135
416)
History
ChemSpider 6094 (http://www.chemspider.c
Propane was first identified as a volatile component in gasoline om/ChemicalStructure.6094.ht
by Walter O. Snelling of the U.S. Bureau of Mines in 1910. The ml)
volatility of these lighter hydrocarbons caused them to be known ECHA InfoCard 100.000.753 (https://echa.europ
as "wild" because of the high vapor pressures of unrefined a.eu/substanceinformation//su
gasoline. On March 31, the New York Times reported on
bstanceinfo/100.000.753)
Snelling's work with liquefied gas and that "a steel bottle will
EC Number 2008279
carry enough gas to light an ordinary home for three weeks."[5]
E number E944 (glazing agents, ...)
Gmelin Reference 25044
KEGG D05625 (http://www.kegg.jp/en
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It was during this time that Snelling, in cooperation with Frank try/D05625)
P. Peterson, Chester Kerr, and Arthur Kerr, created ways to
PubChem 6334 (https://pubchem.ncbi.nl
liquefy the LP gases during the refining of natural gasoline.
m.nih.gov/compound/6334)
Together, they established American Gasol Co., the first
commercial marketer of propane. Snelling had produced RTECS number TX2275000
relatively pure propane by 1911, and on March 25, 1913, his UNII T75W9911L6 (http://fdasis.nl
method of processing and producing LP gases was issued patent m.nih.gov/srs/srsdirect.jsp?regn
#1,056,845.[6] A separate method of producing LP gas through o=T75W9911L6)
compression was created by Frank Peterson and its patent
UN number 1978
granted on July 2, 1912.[7]
InChI
The 1920s saw increased production of LP gas, with the first SMILES
year of recorded production totaling 223,000 US gallons
Properties[2]
(840 m3) in 1922. In 1927, annual marketed LP gas production
Chemical formula C3H8
reached 1 million US gallons (3,800 m3), and by 1935, the
annual sales of LP gas had reached 56 million US gallons Molar mass 44.10 g·mol−1
(210,000 m3). Major industry developments in the 1930s Appearance Colorless gas
included the introduction of railroad tank car transport, gas
Odor Odorless
odorization, and the construction of local bottlefilling plants.
The year 1945 marked the first year that annual LP gas sales Density 2.0098 kg/m3 (at 0 °C, 101.3
reached a billion gallons. By 1947, 62% of all U.S. homes had kPa)
been equipped with either natural gas or propane for cooking.[6] Melting point −187.7 °C; −305.8 °F; 85.5 K
Boiling point −42.25 to −42.04 °C; −44.05 to
In 1950, 1,000 propanefueled buses were ordered by the
Chicago Transit Authority, and by 1958, sales in the U.S. had −43.67 °F; 230.90 to 231.11 K
Sources Specific
heat capacity (C)
73.60 J K−1 mol−1
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consumed each year, with about 70% of that coming from GHS hazard H220
Canada via pipeline and rail. The remaining 30% of imported statements
propane comes to the United States from other sources via ocean GHS precautionary P210
transport. statements
EU classification
F+
After it is produced, North American propane is stored in huge (DSD)
salt caverns. Examples of these are Fort Saskatchewan, Alberta;
Rphrases R12
Mont Belvieu, Texas and Conway, Kansas. These salt caverns
Sphrases (S2), S16
were hollowed out in the 1940s,[10] and they can store
NFPA 704
80,000,000 barrels (13,000,000 m3) or more of propane. When 4
the propane is needed, much of it is shipped by pipelines to 2 0
other areas of the United States. Propane is also shipped by
truck, ship, barge, and railway to many U.S. areas.[11]
Flash point −104 °C (−155 °F; 169 K)
Propane can also be produced as a biofuel.[12] Autoignition 470 °C (878 °F; 743 K)
temperature
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Density
Commercially available "propane" fuel, or LPG, is not pure. Typically in the United States and Canada, it is
primarily propane (at least 90%), with the rest mostly ethane, propylene, butane, and odorants including ethyl
mercaptan.[16][17] This is the HD5 standard, (Heavy Duty5% maximum allowable propylene content, and no
more than 5% butanes and ethane) defined by the American Society for Testing and Materials by its Standard 1835
(http://hd5propane.com) for internal combustion engines. Not all products labeled "LPG" conform to this standard
however. In Mexico, for example, gas labeled "LPG" may consist of 60% propane and 40% butane. "The exact
proportion of this combination varies by country, depending on international prices, on the availability of
components and, especially, on the climatic conditions that favor LPG with higher butane content in warmer
regions and propane in cold areas".[18]
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In North America, local delivery trucks with an average cylinder size of A local delivery truck, behind the
3,000 US gallons (11,000 L), fill up large cylinders that are permanently pickup truck
installed on the property, or other service trucks exchange empty cylinders
of propane with filled cylinders. Large tractortrailer trucks, with an
average cylinder size of 10,000 US gallons (38,000 L), transport the
propane from the pipeline or refinery to the local bulk plant. The bobtail
and transport are not unique to the North American market, though the
practice is not as common elsewhere, and the vehicles are generally called
tankers. In many countries, propane is delivered to consumers via small or
mediumsized individual cylinders, while empty cylinders are removed for
refilling at a central location.
Refrigeration
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Propane is also instrumental in providing offthegrid refrigeration, usually by means of a gas absorption
refrigerator.
Blends of pure, dry "isopropane" (R290a) (isobutane/propane mixtures) and isobutane (R600a) have negligible
ozone depletion potential and very low Global Warming Potential (having a value of 3.3 times the GWP of carbon
dioxide) and can serve as a functional replacement for R12, R22, R134a, and other chlorofluorocarbon or
hydrofluorocarbon refrigerants in conventional stationary refrigeration and air conditioning systems.[21]
In motor vehicles
Such substitution is widely prohibited or discouraged in motor vehicle air conditioning systems, on the grounds
that using flammable hydrocarbons in systems originally designed to carry nonflammable refrigerant presents a
significant risk of fire or explosion.[22][23][24][25][26][27][28][29]
Vendors and advocates of hydrocarbon refrigerants argue against such bans on the grounds that there have been
very few such incidents relative to the number of vehicle air conditioning systems filled with hydrocarbons.[30][31]
Motor fuel
Propane is also being used increasingly for vehicle fuels. In the U.S., over 190,000 onroad vehicles use propane,
and over 450,000 forklifts use it for power. It is the third most popular vehicle fuel in the world,[32] behind gasoline
and Diesel fuel. In other parts of the world, propane used in vehicles is known as autogas. In 2007, approximately
13 million vehicles worldwide use autogas.[32]
The advantage of propane in cars is its liquid state at a moderate pressure. This allows fast refill times, affordable
fuel cylinder construction, and price ranges typically just over half that of gasoline. Meanwhile, it is noticeably
cleaner (both in handling, and in combustion), results in less engine wear (due to carbon deposits) without diluting
engine oil (often extending oilchange intervals), and until recently was a relative bargain in North America. The
octane rating of propane is relatively high at 110. In the United States the propane fueling infrastructure is the most
developed of all alternative vehicle fuels. Many converted vehicles have provisions for topping off from "barbecue
bottles". Purposebuilt vehicles are often in commercially owned fleets, and have private fueling facilities. A
further saving for propane fuel vehicle operators, especially in fleets, is that pilferage is much more difficult than
with gasoline or Diesel fuels.
Propane is also used as fuel for small engines, especially those used indoors or in areas with insufficient fresh air
and ventilation to carry away the more toxic exhaust of an engine running on gasoline or Diesel fuel. More
recently, there have been lawn care products like string trimmers, lawn mowers and leaf blowers intended for
outdoor use, but fueled by propane to reduce air pollution.
Propane and propane cylinders have been used as improvised explosive devices in attacks and attempted attacks
against schools and terrorist targets such as the Columbine High School massacre, 2012 Brindisi school bombing,
the Discovery Communications headquarters hostage crisis and in car bombs.
Other uses
Hazards
Propane is a simple asphyxiant.[33] Unlike natural gas, propane is denser than air. It may accumulate in low spaces
and near the floor. When abused as an inhalant, it may cause hypoxia (lack of oxygen), pneumonia, or cardiac
failure or arrest.[34][35] Propane has low toxicity since it is not readily absorbed and is not biologically active.
Commonly stored under pressure at room temperature, propane and its mixtures will flash evaporate at
atmospheric pressure and cool well below freezing. The cold gas, which appears white due to moisture condensing
from the air, may cause frostbite.
Propane is denser than air. If a leak in a propane fuel system occurs, the gas will have a tendency to sink into any
enclosed area and thus poses a risk of explosion and fire. The typical scenario is a leaking cylinder stored in a
basement; the propane leak drifts across the floor to the pilot light on the furnace or water heater, and results in an
explosion or fire. This property makes propane generally unsuitable as a fuel for boats.
A hazard associated with propane storage and transport is known as a BLEVE or boiling liquid expanding vapor
explosion. The Kingman Explosion involved a railroad tank car in Kingman, Arizona in 1973 during a propane
transfer. The fire and subsequent explosions resulted in twelve fatalities and numerous injuries.[36]
Retail cost
United States
As of October 2013, the retail cost of propane was approximately $2.37 per gallon, or roughly $25.95 per 1 million
BTUs.[38] This means that filling a 500gallon propane tank, which is what households that use propane as their
main source of energy usually require, costs $948 (80% of 500 gallons or 400 gallons), a 7.5% increase on the
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2012–2013 winter season average US price.[39] However, propane costs per gallon change significantly from one
state to another: the Energy Information Administration (EIA) quotes a $2.995 per gallon average on the East
Coast for October 2013,[40] while the figure for the Midwest was $1.860 for the same period.[41]
As of December 2015 the propane retail cost was approximately $1.97 per gallon.[42] This means that filling a 500
gallon propane tank to 80% capacity costs $788, a 16.9% decrease or $160 less from the November 2013 quote in
this section. Similar regional differences in prices are present with the December 2015 EIA figure for the East
Coast at $2.67 per gallon and the Midwest at $1.43 per gallon.[42]
See also
Blau gas Isopropyl alcohol
Dimethyl ether Propargyl alcohol
National Propane Gas Association
Isopropyl alcohol
References
1. Nomenclature of Organic Chemistry : IUPAC Recommendations and Preferred Names 2013 (Blue Book). Cambridge:
The Royal Society of Chemistry. 2014. p. 4. doi:10.1039/9781849733069FP001. ISBN 9780854041824. "Similarly,
the retained names ‘ethane’, ‘propane’, and ‘butane’ were never replaced by systematic names ‘dicarbane’, ‘tricarbane’,
and ‘tetracarbane’ as recommended for analogues of silane, ‘disilane’; phosphane, ‘triphosphane’; and sulfane,
‘tetrasulfane’."
2. Record of Propane (http://gestisen.itrust.de/nxt/gateway.dll?f=id$t=default.htm$vid=gestiseng:sdbeng$id=010020) in the
GESTIS Substance Database of the IFA
3. "NIOSH Pocket Guide to Chemical Hazards #0524". National Institute for Occupational Safety and Health (NIOSH).
4. http://cameochemicals.noaa.gov/chemical/9018
5. "GAS PLANT IN STEEL BOTTLE.; Dr. Snelling's Process Gives Month's Supply in Liquid Form.". The New York
Times. April 1, 1912. p. 9. Retrieved 20071222.
6. National Propane Gas Association. "The History of Propane". Archived from the original on January 11, 2011. Retrieved
20071222.
7. "The First Fifty Years of LPGas: An Industry Chronology" (PDF). LPGA Times. January 1962., Page 17.
8. Propane Education & Research Council. "Fact Sheet – The History of Propane". Archived from the original on February
16, 2004. Retrieved 20071222.
9. "Online Etymology Dictionary entry for propane". Etymonline.com. Retrieved 20101029.
10. Argonne National Laborator (1999). "Salt Cavern Information Center". Retrieved 20071222.
11. Propane Education & Research Council. "History of Propane". Retrieved 22 May 2012.
12. MIT Technology Review. "A New Biofuel: Propane". Retrieved 20150715.
13. Propane (http://webbook.nist.gov/cgi/cbook.cgi?ID=C74986&Units=SI&Mask=1#ThermoGas). NIST Standard
Reference Data referring to Pittam, D. A.; Pilcher, G. (1972). "Measurements of heats of combustion by flame
calorimetry. Part 8.—Methane, ethane, propane, nbutane and 2methylpropane". Journal of the Chemical Society,
Faraday Transactions 1: Physical Chemistry in Condensed Phases. 68: 2224. doi:10.1039/f19726802224. and Rossini,
F.D. (1934). "Calorimetric determination of the heats of combustion of ethane, propane, normal butane, and normal
pentane". J. Res. NBS. 12: 735–750.
14. Bossel, Ulf (2003) WelltoWheel Studies, Heating Values, and the Energy Conservation Principle (http://web.archive.or
g/web/20120717085922/http://www.efcf.com/reports/E10.pdf), Proceedings of Fuel Cell Forum.
15. Ҫengel, Yunus A.; Boles, Michael A. (2006). Thermodynamics: An Engineering Approach (Fifth ed.). McGrawHill.
p. 925. ISBN 9780072884951.
16. Amerigas. "Amerigas Material Safety Data Sheet for Odorized Propane" (PDF). Retrieved 20111024.
17. Suburban Propane. "Suburban Propane Material Safety Data Sheet for Commercial Odorized Propane" (PDF). Retrieved
20111024.
18. Mexican Ministry of Energy. "Liquefied Petroleum Gas Market Outlook 2008 – 2017" (PDF). Mexican Ministry of
Energy. Retrieved 20120517.
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19. Sloan, Michael & Meyer, Richard. "2009 Propane Market Outlook" (PDF). Propane Education and Research Council.
Retrieved 28 May 2012.
20. ASTM D1835 (http://www.astm.org/Standards/D1835.htm)
21. "European Commission on retrofit refrigerants for stationary applications" (PDF). Archived from the original on August
5, 2009. Retrieved 20101029.
22. "U.S. EPA hydrocarbonrefrigerants FAQ". Epa.gov. Retrieved 20101029.
23. Compendium of hydrocarbonrefrigerant policy statements, October 2006 (http://web.archive.org/web/20080719055123/ht
tp://www.vasa.org.au/pdf/memberlibrary/hydrocarbons/hc_white_paper.pdf). vasa.org.au
24. "MACS bulletin: hydrocarbon refrigerant usage in vehicles" (PDF). Retrieved 20101029.
25. "Society of Automotive Engineers hydrocarbon refrigerant bulletin". Sae.org. 20050427. Retrieved 20101029.
26. "Shade Tree Mechanic on hydrocarbon refrigerants". Shadetreemechanic.com. 20050427. Retrieved 20101029.
27. "Saskatchewan Labour bulletin on hydrocarbon refrigerants in vehicles". Labour.gov.sk.ca. 20100629. Retrieved
20101029.
28. VASA on refrigerant legality & advisability (http://web.archive.org/web/20080719134349/http://www.vasa.org.au/content/
refriggas/index.php#Bookmark%202). vasa.org.au
29. "Queensland (Australia) government warning on hydrocarbon refrigerants" (PDF). Energy.qld.gov.au. Archived from the
original on December 17, 2008. Retrieved 20101029.
30. "New South Wales (Australia) Parliamentary record, 16 October 1997". Parliament.nsw.gov.au. 19971016. Retrieved
20101029.
31. "New South Wales (Australia) Parliamentary record, 29 June 2000". Parliament.nsw.gov.au. Retrieved 20101029.
32. Propane Education & Research Council. "Autogas". PERC. Archived from the original on June 26, 2012. Retrieved
20120517.
33. "Propane". The National Institute for Occupational Safety and Health (NIOSH). Retrieved 20160512. "Propane is a
simple asphyxiant and does not present an IDLH hazard at concentrations below its lower explosive limit (LEL). The
chosen IDLH is based on the LEL of 21,000 ppm rounded down to 20,000 ppm."
34. "Inhalants – Facts and Statistics". Greater Dallas Council on Alcohol & Drug Abuse. March 4, 2006. Archived from the
original on 20090408.
35. "Inhalants". National Inhalant Prevention Coalition.
36. "The Disaster Story". Kingman Historic District. Retrieved 1 July 2013.
37. "Propane Vapor Pressure". The Engineering ToolBox. 2005. Retrieved 20080728.
38. US Energy Information Administration (November 12, 2013). "Heating Oil and Propane Prices".
39. Propane Deal (November 12, 2013). "Current Propane Prices".
40. US Energy Information Administration (November 12, 2013). "East Coast Heating Oil and Propane Prices".
41. US Energy Information Administration (November 12, 2013). "Midwest Heating Oil and Propane Prices".
42. US Energy Information Administration (December 12, 2015). "Residential Propane: Weekly Heating Oil and Propane
Prices (October March)".
External links
Canadian Propane Association (http://www.propane.ca)
Direct synthesis of propane from synthesis gas (syngas) (http://cat.ini Wikimedia Commons has
media related to Propane.
st.fr/?aModele=afficheN&cpsidt=19971197)
International Chemical Safety Card 0319 (http://www.inchem.org/do
cuments/icsc/icsc/eics0319.htm)
National Propane Gas Association (U.S.) (http://www.npga.org/i4a/pages/index.cfm?pageid=1)
NIOSH Pocket Guide to Chemical Hazards (http://www.cdc.gov/niosh/npg/npgd0524.html)
Propane Education & Research Council (U.S.) (http://www.propanecouncil.org)
Propane Properties Explained (http://www.propane101.com/aboutpropane.htm) Descriptive Breakdown of
Propane Characteristics
UKLPG: Propane and Butane in the UK (http://www.uklpg.org)
US Energy Information Administration (http://www.eia.gov/)
World LP Gas Association (WLPGA) (http://www.worldlpgas.com)
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Categories: Alkanes Aerosol propellants Refrigerants Fuel gas Hydrocarbons Industrial gases
GABAA receptor positive allosteric modulators
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